ATE172708T1 - Stabilisierung von phosphiteliganden in das hydroformylierungsverfahren - Google Patents

Stabilisierung von phosphiteliganden in das hydroformylierungsverfahren

Info

Publication number
ATE172708T1
ATE172708T1 AT95113051T AT95113051T ATE172708T1 AT E172708 T1 ATE172708 T1 AT E172708T1 AT 95113051 T AT95113051 T AT 95113051T AT 95113051 T AT95113051 T AT 95113051T AT E172708 T1 ATE172708 T1 AT E172708T1
Authority
AT
Austria
Prior art keywords
rhodium
hydroformylation process
atom
phosphite
bonded
Prior art date
Application number
AT95113051T
Other languages
English (en)
Inventor
Anthony George Abatjoglou
David Robert Bryant
John Michael Maher
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Application granted granted Critical
Publication of ATE172708T1 publication Critical patent/ATE172708T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B01J2531/0288—Sterically demanding or shielding ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT95113051T 1994-08-19 1995-08-18 Stabilisierung von phosphiteliganden in das hydroformylierungsverfahren ATE172708T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/293,028 US5756855A (en) 1994-08-19 1994-08-19 Stabilization of phosphite ligands in hydroformylation process

Publications (1)

Publication Number Publication Date
ATE172708T1 true ATE172708T1 (de) 1998-11-15

Family

ID=23127321

Family Applications (1)

Application Number Title Priority Date Filing Date
AT95113051T ATE172708T1 (de) 1994-08-19 1995-08-18 Stabilisierung von phosphiteliganden in das hydroformylierungsverfahren

Country Status (6)

Country Link
US (2) US5756855A (de)
EP (1) EP0697391B1 (de)
AT (1) ATE172708T1 (de)
DE (1) DE69505612T2 (de)
DK (1) DK0697391T3 (de)
ES (1) ES2124940T3 (de)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
JP3812095B2 (ja) * 1997-10-28 2006-08-23 三菱化学株式会社 アルデヒド類の製造方法及びこれに用いるビスホスファイト
US6693219B2 (en) 2001-06-02 2004-02-17 Eastman Chemical Company Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process
US6831035B2 (en) * 2002-01-22 2004-12-14 Eastman Kodak Company Stabilization of fluorophosphite-containing catalysts
WO2003078444A2 (en) * 2002-03-11 2003-09-25 Union Carbide Chemicals & Plastics Technology Corporation Bisphosphite ligands for carbonylation processes
US7294729B2 (en) * 2002-10-15 2007-11-13 Union Carbide Chemicals & Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
US7301054B1 (en) 2006-09-29 2007-11-27 Eastman Chemical Company Process for the preparation of glycolaldehyde
US7420093B2 (en) * 2006-09-29 2008-09-02 Eastman Chemical Company Process for the preparation of glycolaldehyde
TWI432411B (zh) * 2007-04-05 2014-04-01 Dow Global Technologies Llc 用於氫甲醯化方法之杯芳烴雙亞磷酸酯配體
US8461366B2 (en) * 2008-01-15 2013-06-11 Dow Global Technologies Llc Sulfonated organophosphine compounds and use thereof in hydroformylation processes
US8394978B2 (en) * 2008-01-15 2013-03-12 Dow Global Technologies Llc Sulfonated organophosphine compounds and use thereof in hydroformylation processes
EP2242760B1 (de) 2008-01-15 2014-03-05 Dow Global Technologies LLC Sulfonierte organophosphin-verbindungen und ihre verwendung in hydroformylierungsverfahren
US7674937B2 (en) * 2008-05-28 2010-03-09 Eastman Chemical Company Hydroformylation catalysts
PL2323888T3 (pl) * 2008-08-15 2015-06-30 Artsana Usa Inc Wózek dziecięcy
JP5474971B2 (ja) * 2008-08-19 2014-04-16 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 生成物異性体に対する改善された制御のための、対称ビスホスファイトリガンドを用いるヒドロホルミル化方法
US8598390B2 (en) 2009-12-22 2013-12-03 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process
EP2624953B1 (de) 2010-10-05 2018-10-24 Dow Technology Investments LLC Hydroformylierungsverfahren
KR101309918B1 (ko) 2010-12-02 2013-09-17 주식회사 엘지화학 반응 중 촉매의 안정성이 개선된 하이드로포밀화 방법
US8513468B2 (en) 2010-12-30 2013-08-20 Eastman Chemical Company Process for removing degradation acids from hydroformylation reactions
EP2855016A1 (de) 2012-06-04 2015-04-08 Dow Technology Investments LLC Hydroformylierungsverfahren
CN103814006B (zh) 2012-06-04 2015-08-12 Lg化学株式会社 在反应中具有改善的催化剂稳定性的氢甲酰化方法
BR112015003762B1 (pt) 2012-08-29 2021-04-13 Dow Technology Investments Llc Processo para a formação de um catalisador de hidroformilação
PL2900373T3 (pl) 2012-09-25 2019-09-30 Dow Technology Investments Llc Sposób stabilizacji ligandu fosforynowego przeciwko degradacji
EP2740535A1 (de) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentat-Liganden für die Hydroformylation von Ethylen
US9382180B2 (en) 2012-12-06 2016-07-05 Dow Technology Investments Llc Hydroformylation process
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
DE102013214378A1 (de) 2013-07-23 2015-01-29 Evonik Industries Ag Phosphoramiditderivate in der Hydroformylierung von olefinhaltigen Gemischen
CN104513143A (zh) 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
EP3083542A1 (de) 2013-12-19 2016-10-26 Dow Technology Investments LLC Hydroformylierungsverfahren
CA2943211C (en) 2014-03-31 2022-03-22 Dow Technology Investments Llc Hydroformylation process
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
EP3147288A1 (de) * 2015-09-22 2017-03-29 Evonik Degussa GmbH Monophosphite, die ein cyclododecanol aufweisen
EP3374340B1 (de) 2015-11-10 2021-12-29 Dow Technology Investments LLC Verfahren zur herstellung von aldehyden
ES2901236T3 (es) 2016-02-11 2022-03-21 Dow Technology Investments Llc Procesos para convertir olefinas en alcoholes, éteres o combinaciones de los mismos
WO2017160956A1 (en) 2016-03-18 2017-09-21 Dow Technology Investments Llc Hydroformylation process
US9687837B1 (en) 2016-08-31 2017-06-27 Eastman Chemical Company Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product
US9975833B2 (en) 2016-08-31 2018-05-22 Eastman Chemical Company Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
CN111212826B (zh) 2017-10-25 2023-05-23 陶氏技术投资有限责任公司 减少在加氢甲酰化过程中形成的包含醛化合物的溶液中重物质形成的方法
US11033890B2 (en) 2017-11-13 2021-06-15 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
EP3801898A1 (de) 2018-05-30 2021-04-14 Dow Technology Investments LLC Katalysatorzusammensetzung mit kombination eines monophopsphins, eines tetraphosphinliganden und ein hydroformylierungsverfahren unter verwendung davon
CN112074347A (zh) 2018-05-30 2020-12-11 陶氏技术投资有限责任公司 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法
WO2019231611A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods of controlling hydroformylation processes
EP3990176A1 (de) 2019-06-27 2022-05-04 Dow Technology Investments LLC Verfahren zur herstellung einer lösung aus hydroformylierungsprozess zur rückgewinnung von edelmetallen
SE543296C2 (en) * 2019-07-05 2020-11-17 Perstorp Ab A use of epoxide in order to reduce the formation of heavy ends in a hydroformylation process
TW202126385A (zh) 2019-11-05 2021-07-16 美商陶氏科技投資有限公司 自氫甲醯化製程回收銠之方法
US11976017B2 (en) 2019-12-19 2024-05-07 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
MX2023006537A (es) 2020-12-22 2023-06-16 Dow Technology Investments Llc Procesos de reaccion de hidroformilacion.
CA3213539A1 (en) 2021-03-31 2022-10-06 Jason F. GILES Hydroformylation processes
EP4430218A1 (de) 2021-11-11 2024-09-18 Dow Technology Investments LLC Verfahren zur rückgewinnung von rhodium aus hydroformylierungsverfahren
WO2024129290A1 (en) 2022-12-13 2024-06-20 Dow Technology Investments Llc Process to minimize polyphosphine usage by making use of degradation products

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH348284A (de) * 1956-11-30 1960-08-15 Geigy Ag J R Verfahren zur Stabilisierung von Estern von Säuren des drei- oder fünfwertigen Phosphors oder von solche Ester enthaltenden Gemischen
US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3553298A (en) * 1967-10-20 1971-01-05 Hooker Chemical Corp Hydrolytic stabilized phosphite esters
US3597461A (en) * 1968-08-13 1971-08-03 American Cyanamid Co Hydride and carbonyl triphenylphosphine derivatives of ruthenium and osmium
US3661949A (en) * 1969-06-11 1972-05-09 Union Oil Co Hydrocarboxylation process utilizing an iron salt cocatalyst
US3876672A (en) * 1972-02-21 1975-04-08 Du Pont Hydroformylation of olefins
GB2000124B (en) * 1977-06-21 1982-03-24 Johnson Matthey Co Ltd Catalysts
FR2459683A1 (fr) * 1979-06-22 1981-01-16 Ugine Kuhlmann Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene
US4518809A (en) 1981-06-11 1985-05-21 Monsanto Company Preparation of pentyl nonanols
US4467116A (en) * 1981-11-20 1984-08-21 Shell Oil Company Process for the hydroformylation of olefins
US4453019A (en) * 1982-09-02 1984-06-05 Ashland Oil, Inc. Use of mixed metal catalysts in the hydroformylation of olefins to produce linear aldehydes and alcohols
US4539306A (en) * 1982-09-02 1985-09-03 Ashland Oil, Inc. Use of mixed metal catalysts in the hydroformylation of olefins to produce linear aldehydes and alcohols
US4528403A (en) 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
FR2544713B1 (fr) * 1983-04-22 1986-08-22 Ugine Kuhlmann Systeme catalytique pour l'hydroformylation des olefines. procede d'hydroformylation
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4650894A (en) * 1984-07-05 1987-03-17 Argus Chemical Corporation Tris-organophosphite compositions having improved hydrolytic stability
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5135901A (en) * 1989-06-29 1992-08-04 Eastman Chemical Company A catalyst composition comprising rhodium, ruthenium,and a promoter
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5102505A (en) 1990-11-09 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Mixed aldehyde product separation by distillation
TW213465B (de) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5196596A (en) * 1991-12-26 1993-03-23 Union Carbide Chemicals & Plastics Technology Corporation Higher aldehyde separation process
US5233093A (en) * 1992-07-20 1993-08-03 Arco Chemical Technology, L.P. Hydroformylation process and bimetallic catalyst therefor
US5364950A (en) * 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
US5288918A (en) * 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
CA2121308C (en) * 1993-04-19 2001-07-24 Toshihiro Omatsu Rhodium-containing catalyst
US5488174A (en) * 1993-08-19 1996-01-30 Shell Oil Company Hydroformylation process

Also Published As

Publication number Publication date
US5756855A (en) 1998-05-26
ES2124940T3 (es) 1999-02-16
DE69505612D1 (de) 1998-12-03
DE69505612T2 (de) 1999-05-20
EP0697391A1 (de) 1996-02-21
DK0697391T3 (da) 1999-07-05
EP0697391B1 (de) 1998-10-28
US5929289A (en) 1999-07-27

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