ATE144441T1 - Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen - Google Patents

Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen

Info

Publication number
ATE144441T1
ATE144441T1 AT94906734T AT94906734T ATE144441T1 AT E144441 T1 ATE144441 T1 AT E144441T1 AT 94906734 T AT94906734 T AT 94906734T AT 94906734 T AT94906734 T AT 94906734T AT E144441 T1 ATE144441 T1 AT E144441T1
Authority
AT
Austria
Prior art keywords
pct
epoxydation
hydrogen
nrd
independently
Prior art date
Application number
AT94906734T
Other languages
English (en)
Inventor
David Bell
Pinnacles
David Miller
Robin Patrick Attrill
Original Assignee
Smithkline Beecham Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB929216662A external-priority patent/GB9216662D0/en
Priority claimed from GB939308968A external-priority patent/GB9308968D0/en
Application filed by Smithkline Beecham Plc filed Critical Smithkline Beecham Plc
Application granted granted Critical
Publication of ATE144441T1 publication Critical patent/ATE144441T1/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56Nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/22Nitrogen atoms not forming part of a nitro radical
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D309/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/08Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D309/14Nitrogen atoms not forming part of a nitro radical
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D321/00Heterocyclic compounds containing rings having two oxygen atoms as the only ring hetero atoms, not provided for by groups C07D317/00 - C07D319/00
    • C07D321/02Seven-membered rings
    • C07D321/04Seven-membered rings not condensed with other rings
    • C07D321/061,3-Dioxepines; Hydrogenated 1,3-dioxepines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D493/00Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005Compounds without a metal-carbon linkage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72Epoxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Catalysts (AREA)
AT94906734T 1992-08-06 1993-08-05 Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen ATE144441T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB929216662A GB9216662D0 (en) 1992-08-06 1992-08-06 Novel compounds and process
GB939308968A GB9308968D0 (en) 1993-04-30 1993-04-30 Novel compounds and process

Publications (1)

Publication Number Publication Date
ATE144441T1 true ATE144441T1 (de) 1996-11-15

Family

ID=26301377

Family Applications (1)

Application Number Title Priority Date Filing Date
AT94906734T ATE144441T1 (de) 1992-08-06 1993-08-05 Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen

Country Status (17)

Country Link
US (1) US5616750A (de)
EP (1) EP0655950B1 (de)
JP (1) JP3322877B2 (de)
KR (1) KR100292137B1 (de)
CN (1) CN1043425C (de)
AT (1) ATE144441T1 (de)
AU (1) AU672995B2 (de)
CA (1) CA2141790A1 (de)
DE (1) DE69305645T2 (de)
DK (1) DK0655950T3 (de)
ES (1) ES2093523T3 (de)
GR (1) GR3021743T3 (de)
HK (1) HK1006289A1 (de)
MX (1) MX9304761A (de)
NZ (1) NZ254917A (de)
TW (1) TW418210B (de)
WO (1) WO1994003271A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9506864A (pt) * 1994-02-04 1997-09-09 Smithkline Beecham Plc Processo para epoxidar olefinas proquirais e um catalisador para as mesmas e intermdiários para produzir o catalisador
CA2214722A1 (en) * 1995-03-08 1996-09-12 Shell Canada Limited Bridged bis-amido group 4 metal compounds in a catalyst composition
US6713045B1 (en) 1995-06-02 2004-03-30 Research Corporation Technologies, Inc. Targeted magnetic resonance imaging agents for the detection of physiological processes
ZA981883B (en) * 1997-03-07 1998-09-01 Univ Kansas Catalysts and methods for catalytic oxidation
US20030017941A1 (en) 1997-03-07 2003-01-23 The Procter & Gamble Company Catalysts and methods for catalytic oxidation
ID22981A (id) 1997-03-07 1999-12-23 Procter & Gamble Komposisi pengelantang
TW420693B (en) * 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US5981424A (en) * 1997-07-31 1999-11-09 Sunoco, Inc. (R&M) Catalysts for hydroxylation and ammination of aromatics using molecular oxygen as the terminal oxidant without coreductant
NL1007776C2 (nl) * 1997-12-12 1999-06-15 Dsm Nv Katalysator voor de bereiding van chirale producten in optisch actieve vorm.
US6673333B1 (en) 2000-05-04 2004-01-06 Research Corporation Technologies, Inc. Functional MRI agents for cancer imaging
AU2001276956A1 (en) 2000-07-17 2002-01-30 California Institute Of Technology Macrocyclic mri contrast agents
CN1186125C (zh) * 2002-06-18 2005-01-26 中国科学院成都有机化学研究所 用于氧化偶联萘酚的手性催化剂
FR2875500A1 (fr) * 2004-09-21 2006-03-24 Centre Nat Rech Scient Complexe chiraux macrocycliques utilisables comme catalyseurs

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0023075A1 (de) * 1979-07-13 1981-01-28 Imperial Chemical Industries Plc Verfahren zur Herstellung von Cyclopropancarbonsäureestern
US5250285A (en) * 1985-05-08 1993-10-05 The General Hospital Corporation Hydroxy-aryl metal chelates for diagnostic NMR imaging
FR2588265B3 (fr) * 1985-10-04 1988-01-15 Inst Francais Du Petrole Procede d'adoucissement d'une charge d'hydrocarbures contenant des produits soufres
JPS6490150A (en) * 1987-09-30 1989-04-06 Soda Aromatic Production of 3,5,5-trimethylcyclohex-2-ene-1,4-dione
CA2077541C (en) * 1990-03-21 1998-08-18 Eric N. Jacobsen Chiral catalysts and epoxidation reactions catalyzed thereby
ES2156880T3 (es) * 1994-02-23 2001-08-01 Nissan Chemical Ind Ltd Procedimiento de epoxidacion asimetrica utilizando complejos de manganeso opticamente activos.

Also Published As

Publication number Publication date
US5616750A (en) 1997-04-01
KR100292137B1 (ko) 2001-10-24
EP0655950B1 (de) 1996-10-23
CA2141790A1 (en) 1994-02-17
DE69305645D1 (de) 1996-11-28
AU672995B2 (en) 1996-10-24
CN1043425C (zh) 1999-05-19
GR3021743T3 (en) 1997-02-28
HK1006289A1 (en) 1999-02-19
DE69305645T2 (de) 1997-06-05
MX9304761A (es) 1994-05-31
WO1994003271A1 (en) 1994-02-17
ES2093523T3 (es) 1996-12-16
AU4722393A (en) 1994-03-03
KR950702872A (ko) 1995-08-23
NZ254917A (en) 1996-11-26
CN1098415A (zh) 1995-02-08
EP0655950A1 (de) 1995-06-07
JP3322877B2 (ja) 2002-09-09
TW418210B (en) 2001-01-11
JPH08500099A (ja) 1996-01-09
DK0655950T3 (da) 1996-11-18

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