AR245925A1 - Procedimiento para la preparacion de derivados de acido benzoico. - Google Patents
Procedimiento para la preparacion de derivados de acido benzoico.Info
- Publication number
- AR245925A1 AR245925A1 AR88311489A AR31148988A AR245925A1 AR 245925 A1 AR245925 A1 AR 245925A1 AR 88311489 A AR88311489 A AR 88311489A AR 31148988 A AR31148988 A AR 31148988A AR 245925 A1 AR245925 A1 AR 245925A1
- Authority
- AR
- Argentina
- Prior art keywords
- manufacture
- benzoic acid
- alkyl
- salts
- derivatives
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
UN PROCEDIMIENTO PARA LA FABRICACION DE DERIVADOS DE ACIDO BENZOICO A PARTIR DE DERIVADOS DE TOLUENO POR UNA OXIDACION EN FASE LIQUIDA DE DERIVADOS DE TOLUENO USANDO UN GAS QUE CONTIENE OXIGENO,LLEVANDOSE A CABO EN PRESENCIA DE UN CATALIZADOR DE TRANSFERENCIA DE FASE Y VESTIGIOS DE UN SOLVENTE POLAR CAPAZ DE SOLUBILIZAR AL CATALIZADOR, DONDE LA REACCION DE OXIDACION SE PRODUCE EN PRESENCIA DE UN SISTEMA CATALITICO QUE COMPRENDE: (A) UNA SAL DE ONIO-CUATERNARIO QUE TIENE LA FORMULA (I),EN DONDE: R1 ES ALQUILO Y R2, R3 Y R4 PUEDEN SER IGUALES, DIFERENTES O ESTAR ENTRELAZADOS, Y SER ALQUILO, HIDROALQUILO, ARILO O ARALQUILO; Y PUEDE SER NITROGENO O FOSFORO Y X(-) ES F(-), CL(-), BR(-), OH(-), CH3COO(-) Y HSO4(-), A CONDICION DE QUE CUANDO BR(-) ESTA AUSENTE DEL SISTEMA SEAGREGA UN BROMURO O BROMO; Y (B) UNA SAL DE METAL DE TRANSICION; ESTANDO LA RELACION MOLAR ENTRE (A) Y (B) DENTRO DEL MARGEN DE 0,25:1 A 1,5:1.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL83293A IL83293A (en) | 1987-07-23 | 1987-07-23 | Process for the manufacture of benzoic acid and salts thereof by catalytic oxidation of toluene in the liquid phase in the presence of a phase transfer catalyst |
IL85976A IL85976A0 (en) | 1987-07-23 | 1988-04-05 | Process for the manufacture of derivatives of benzoic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
AR245925A1 true AR245925A1 (es) | 1994-03-30 |
Family
ID=26321700
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AR88311489A AR245925A1 (es) | 1987-07-23 | 1988-07-22 | Procedimiento para la preparacion de derivados de acido benzoico. |
Country Status (8)
Country | Link |
---|---|
US (1) | US4990659A (es) |
EP (1) | EP0300922B1 (es) |
JP (1) | JPH01287054A (es) |
AR (1) | AR245925A1 (es) |
CA (1) | CA1310666C (es) |
DE (1) | DE3870746D1 (es) |
ES (1) | ES2031259T3 (es) |
IL (1) | IL85976A0 (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5175352A (en) * | 1991-01-21 | 1992-12-29 | Mitsubishi Petrochemical Co., Ltd. | Process for preparing 2,6-naphthalenedicarboxylic acid |
GB9310699D0 (en) * | 1993-05-24 | 1993-07-07 | Zeneca Ltd | Chemical process |
DE4334431A1 (de) * | 1993-10-08 | 1995-04-13 | Hoechst Ag | Verfahren zur Herstellung von 5-Fluoranthranilsäure |
DE4441881A1 (de) * | 1994-11-24 | 1996-05-30 | Hoechst Ag | Verfahren zur Herstellung bromierter oder chlorierter aromatischer Carbonsäuren |
KR100508684B1 (ko) * | 2002-04-12 | 2005-08-17 | 한국화학연구원 | 방향족 카르복시산의 제조방법 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2865708A (en) * | 1955-08-26 | 1958-12-23 | Richfield Oil Corp | Process of recovering cobalt, cerium, and manganese catalysts |
US2883816A (en) * | 1957-05-24 | 1959-04-28 | Kroll Eberhard | Apparatus for automatically placing articles in layers in containers particularly fish in barrels |
US3210416A (en) * | 1960-09-22 | 1965-10-05 | Standard Oil Co | Manufacture of benzoic acid from toluene |
NL280020A (es) * | 1961-06-26 | |||
US3227752A (en) * | 1962-05-03 | 1966-01-04 | Union Oil Co | Oxidation of alkylaromatic hydrocarbons |
US4007228A (en) * | 1964-11-19 | 1977-02-08 | L'oreal | Substituted-2-nitro-paraphenylenediamines and processes for producing same |
US3816523A (en) * | 1968-10-11 | 1974-06-11 | Tenneco Chem | Process for the production and purification of benzoic acid |
US3665030A (en) * | 1969-12-11 | 1972-05-23 | Labofina Sa | Oxidation of alkyl aromatics |
DE2365131A1 (de) * | 1973-12-29 | 1975-07-10 | Dynamit Nobel Ag | Verfahren zur herstellung von p-nitrobenzoesaeure |
US4302401A (en) * | 1980-01-23 | 1981-11-24 | Exxon Research & Engineering Co. | Tetraalkyl phosphonium substituted phosphine and amine transition metal complexes |
IL84620A (en) * | 1987-11-27 | 1992-03-29 | Gadot Petrochem Ind | Process for the manufacture of aromatic dicarboxylic acids |
-
1988
- 1988-04-05 IL IL85976A patent/IL85976A0/xx unknown
- 1988-07-22 JP JP63181929A patent/JPH01287054A/ja active Pending
- 1988-07-22 CA CA000572871A patent/CA1310666C/en not_active Expired
- 1988-07-22 AR AR88311489A patent/AR245925A1/es active
- 1988-07-22 DE DE8888401922T patent/DE3870746D1/de not_active Expired - Lifetime
- 1988-07-22 EP EP88401922A patent/EP0300922B1/en not_active Expired
- 1988-07-22 ES ES198888401922T patent/ES2031259T3/es not_active Expired - Lifetime
-
1989
- 1989-07-20 US US07/384,064 patent/US4990659A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4990659A (en) | 1991-02-05 |
CA1310666C (en) | 1992-11-24 |
EP0300922B1 (en) | 1992-05-06 |
JPH01287054A (ja) | 1989-11-17 |
EP0300922A1 (en) | 1989-01-25 |
ES2031259T3 (es) | 1992-12-01 |
IL85976A0 (en) | 1988-09-30 |
DE3870746D1 (de) | 1992-06-11 |
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