ES2031259T3 - Procedimiento para la preparacion de derivados de acido benzoico. - Google Patents

Procedimiento para la preparacion de derivados de acido benzoico.

Info

Publication number
ES2031259T3
ES2031259T3 ES198888401922T ES88401922T ES2031259T3 ES 2031259 T3 ES2031259 T3 ES 2031259T3 ES 198888401922 T ES198888401922 T ES 198888401922T ES 88401922 T ES88401922 T ES 88401922T ES 2031259 T3 ES2031259 T3 ES 2031259T3
Authority
ES
Spain
Prior art keywords
procedure
benzoic acid
acid derivatives
chosen
interval
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888401922T
Other languages
English (en)
Inventor
Jihad Dakka
Amikam Zoran
Yoel Prof. Sasson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gadot Petrochemical Industries Ltd
Yissum Research Development Co of Hebrew University of Jerusalem
Original Assignee
Gadot Petrochemical Industries Ltd
Yissum Research Development Co of Hebrew University of Jerusalem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IL83293A external-priority patent/IL83293A/xx
Application filed by Gadot Petrochemical Industries Ltd, Yissum Research Development Co of Hebrew University of Jerusalem filed Critical Gadot Petrochemical Industries Ltd
Application granted granted Critical
Publication of ES2031259T3 publication Critical patent/ES2031259T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO PARA LA FABRICACION DE DERIVADOS DE ACIDO BENZOICO. EL PROCEDIMIENTO SE BASA EN LA REACCION DE UN DERIVADO DE TOLUENO EN FASE LIQUIDA, OXIDACION CON UN GAS QUE CONTIENE OXIGENO, EN PRESENCIA DE UN CATALIZADOR DE TRANSFERENCIA DE FASES (A), UNA SAL DE METAL DE TRANSICION (B) Y TRAZAS DE UN DISOLVENTE POLAR, TAL COMO AGUA, ESTANDO LA RELACION MOLAR ENTRE (A) Y (B) EN EL INTERVALO DE 0,25:1 A 1,5:1. EL CATALIZADOR DE TRANSFERENCIA DE FASES SE ELIGE DE SALES DE AMONIO Y FOSFONIO CUATERNARIO, QUE TIENEN UN TOTAL DE ATOMOS DE CARBONO EN EL INTERVALO DE 17-58, SIENDO ELEGIDO EL ANION ENLAZADO ENTRE BR-, F-, CL-, CH3COO- O HSO4. LOS DERIVADOS DE ACIDO BENZOICO OBTENIDOS SE CARACTERIZAN POR SU MUY ALTA PUREZA Y ALTA CONVERSION QUE ALCANZA GENERALMENTE VALORES SUPERIORES A 95 %.
ES198888401922T 1987-07-23 1988-07-22 Procedimiento para la preparacion de derivados de acido benzoico. Expired - Lifetime ES2031259T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IL83293A IL83293A (en) 1987-07-23 1987-07-23 Process for the manufacture of benzoic acid and salts thereof by catalytic oxidation of toluene in the liquid phase in the presence of a phase transfer catalyst
IL85976A IL85976A0 (en) 1987-07-23 1988-04-05 Process for the manufacture of derivatives of benzoic acid

Publications (1)

Publication Number Publication Date
ES2031259T3 true ES2031259T3 (es) 1992-12-01

Family

ID=26321700

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888401922T Expired - Lifetime ES2031259T3 (es) 1987-07-23 1988-07-22 Procedimiento para la preparacion de derivados de acido benzoico.

Country Status (8)

Country Link
US (1) US4990659A (es)
EP (1) EP0300922B1 (es)
JP (1) JPH01287054A (es)
AR (1) AR245925A1 (es)
CA (1) CA1310666C (es)
DE (1) DE3870746D1 (es)
ES (1) ES2031259T3 (es)
IL (1) IL85976A0 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5175352A (en) * 1991-01-21 1992-12-29 Mitsubishi Petrochemical Co., Ltd. Process for preparing 2,6-naphthalenedicarboxylic acid
GB9310699D0 (en) * 1993-05-24 1993-07-07 Zeneca Ltd Chemical process
DE4334431A1 (de) * 1993-10-08 1995-04-13 Hoechst Ag Verfahren zur Herstellung von 5-Fluoranthranilsäure
DE4441881A1 (de) * 1994-11-24 1996-05-30 Hoechst Ag Verfahren zur Herstellung bromierter oder chlorierter aromatischer Carbonsäuren
KR100508684B1 (ko) * 2002-04-12 2005-08-17 한국화학연구원 방향족 카르복시산의 제조방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2865708A (en) * 1955-08-26 1958-12-23 Richfield Oil Corp Process of recovering cobalt, cerium, and manganese catalysts
US2883816A (en) * 1957-05-24 1959-04-28 Kroll Eberhard Apparatus for automatically placing articles in layers in containers particularly fish in barrels
US3210416A (en) * 1960-09-22 1965-10-05 Standard Oil Co Manufacture of benzoic acid from toluene
NL280020A (es) * 1961-06-26
US3227752A (en) * 1962-05-03 1966-01-04 Union Oil Co Oxidation of alkylaromatic hydrocarbons
US4007228A (en) * 1964-11-19 1977-02-08 L'oreal Substituted-2-nitro-paraphenylenediamines and processes for producing same
US3816523A (en) * 1968-10-11 1974-06-11 Tenneco Chem Process for the production and purification of benzoic acid
US3665030A (en) * 1969-12-11 1972-05-23 Labofina Sa Oxidation of alkyl aromatics
DE2365131A1 (de) * 1973-12-29 1975-07-10 Dynamit Nobel Ag Verfahren zur herstellung von p-nitrobenzoesaeure
US4302401A (en) * 1980-01-23 1981-11-24 Exxon Research & Engineering Co. Tetraalkyl phosphonium substituted phosphine and amine transition metal complexes
IL84620A (en) * 1987-11-27 1992-03-29 Gadot Petrochem Ind Process for the manufacture of aromatic dicarboxylic acids

Also Published As

Publication number Publication date
EP0300922A1 (en) 1989-01-25
CA1310666C (en) 1992-11-24
EP0300922B1 (en) 1992-05-06
DE3870746D1 (de) 1992-06-11
JPH01287054A (ja) 1989-11-17
US4990659A (en) 1991-02-05
IL85976A0 (en) 1988-09-30
AR245925A1 (es) 1994-03-30

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