AR115476A1 - Emulsión para el tratamiento de fertilizantes de urea - Google Patents
Emulsión para el tratamiento de fertilizantes de ureaInfo
- Publication number
- AR115476A1 AR115476A1 ARP190101519A ARP190101519A AR115476A1 AR 115476 A1 AR115476 A1 AR 115476A1 AR P190101519 A ARP190101519 A AR P190101519A AR P190101519 A ARP190101519 A AR P190101519A AR 115476 A1 AR115476 A1 AR 115476A1
- Authority
- AR
- Argentina
- Prior art keywords
- emulsion
- component
- phase
- thio
- general formula
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title abstract 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract 6
- 239000004202 carbamide Substances 0.000 title abstract 5
- 239000003337 fertilizer Substances 0.000 title abstract 5
- 239000012071 phase Substances 0.000 abstract 7
- 229910052757 nitrogen Inorganic materials 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000003277 amino group Chemical group 0.000 abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- JLYVRXJEQTZZBE-UHFFFAOYSA-N ctk1c6083 Chemical compound NP(N)(N)=S JLYVRXJEQTZZBE-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 abstract 1
- 125000001831 (C6-C10) heteroaryl group Chemical group 0.000 abstract 1
- -1 2-nitrophenyl Chemical group 0.000 abstract 1
- FZQMJOOSLXFQSU-UHFFFAOYSA-N 3-[3,5-bis[3-(dimethylamino)propyl]-1,3,5-triazinan-1-yl]-n,n-dimethylpropan-1-amine Chemical compound CN(C)CCCN1CN(CCCN(C)C)CN(CCCN(C)C)C1 FZQMJOOSLXFQSU-UHFFFAOYSA-N 0.000 abstract 1
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical compound C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 1
- 125000000041 C6-C10 aryl group Chemical group 0.000 abstract 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- JADWVLYMWVNVAN-UHFFFAOYSA-N ctk0h5271 Chemical compound NP(N)(O)=S JADWVLYMWVNVAN-UHFFFAOYSA-N 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 abstract 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/41—Emulsifying
- B01F23/4105—Methods of emulsifying
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/42—Ethers, e.g. polyglycol ethers of alcohols or phenols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fertilizers (AREA)
Abstract
Reivindicación 1: Emulsión para el tratamiento de fertilizantes de urea, que contiene una fase acuosa B y una fase no-acuosa A emulsionada con la fase B, donde la fase A contiene al menos una triamida de ácido (tio)fosfórico de fórmula general (1) y/o diamida de ácido (tio)fosfórico de fórmula general (2): R¹R²N-P(X)(NH₂)₂ (1) R¹O-P(X)(NH₂)₂ (2) con el significado X oxígeno o azufre, R¹ y R² independientemente unos de otros, hidrógeno, en cada caso sustituido o no-sustituido 2-nitrofenilo, C₁₋₁₀-alquilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-heterocicloalquilo, C₆₋₁₀-arilo, C₆₋₁₀-heteroarilo o diaminocarbonilo, donde R¹ y R² pueden formar junto con el átomo de nitrógeno que los conecta también un radical heterocíclico saturado o insaturado de 5 ó 6 miembros, que puede contener en cada caso también uno o dos heteroátomos adicionales, seleccionados del grupo, consistente en nitrógeno, oxígeno y azufre, como Componente A1, disuelto en un disolvente orgánico no miscible con agua como componente A2, y donde la fase B contiene ácido 2-(N-3,4-dimetilpirazol)succínico, que existe preferentemente como sal dialcalina, sal alcalino-térrea, sal diamónica o mezcla de estas, como componente B1, disuelto en agua. Reivindicación 2: Emulsión según la reivindicación 1, caracterizado porque como triamida de ácido (tio)fosfórico de fórmula general (1) se utilizan triamidas de ácido N-alquiltiofosfóricas con los significados X = S y R² = H y/o triamidas de ácido N-alquilfosfórico con los significados X = O y R² = H. Reivindicación 3: Emulsión según una de las reivindicaciones 1 ó 2, caracterizada porque la fase A contiene al menos un compuesto conteniendo un grupo amino o un grupo amino sustituido con un punto de ebullición de más de 100ºC, preferentemente una amina, de manera especialmente preferente seleccionada entre metildietanolamina, tetrahidroxipropiletilendiamina, trimetilaminoetiletanolamina, N,N,N,N-tetrametil-1,6-hexanodiamina, N,N,N-tris(dimetilaminopropil)hexahidrotriazina, 2,2-dimorfolinildietiléter, N,N,N,N,N,N-hexa-metil-1,3,5-triazina-1,3,5(2H,4H,6H)-tripropanamina, N,N,N,N-tetraquis(2-hidroxipropil)etilendiamina o mezclas de estos, como componente A3 en preferentemente al menos 0,2 veces la cantidad molar del componente A1. Reivindicación 13: Procedimiento para la producción de fertilizantes de urea tratados, comprendiendo los pasos a) producir por separado las fases A y B, como se definen en una de las reivindicaciones 1 a 10, b) mezclar las fases A y B del paso a) para producir una emulsión de las fases A y B, c) aplicar la emulsión del paso b) sobre un fertilizante de urea particulado o Introducir la emulsión del paso b) en un fertilizante de urea particulado.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102018208770.9A DE102018208770A1 (de) | 2018-06-04 | 2018-06-04 | Emulsion zur Behandlung von harnstoffhaltigen Düngemitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR115476A1 true AR115476A1 (es) | 2021-01-20 |
Family
ID=66776322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP190101519A AR115476A1 (es) | 2018-06-04 | 2019-06-04 | Emulsión para el tratamiento de fertilizantes de urea |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20210214285A1 (es) |
| EP (1) | EP3807232B1 (es) |
| JP (1) | JP7270653B2 (es) |
| KR (1) | KR20210019466A (es) |
| CN (1) | CN112292366B (es) |
| AR (1) | AR115476A1 (es) |
| BR (1) | BR112020024656A2 (es) |
| CO (1) | CO2020016514A2 (es) |
| DE (1) | DE102018208770A1 (es) |
| ES (1) | ES2935747T3 (es) |
| MX (1) | MX2020013053A (es) |
| PL (1) | PL3807232T3 (es) |
| PT (1) | PT3807232T (es) |
| WO (1) | WO2019233905A1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3066991A1 (en) * | 2017-07-10 | 2019-01-17 | Basf Se | Mixtures comprising an urease inhibitor (ui) and a nitrification inhibitor such as 2-(3,4-dimethyl-1h-pyrazol-1-yl)succinic acid (dmpsa) or 3,4-dimethyl pyrazolium glycolate (dmpg) |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4530714A (en) | 1983-03-16 | 1985-07-23 | Allied Corporation | N-aliphatic and N,N-aliphatic phosphoric triamide urease inhibitors and urease inhibited urea based fertilizer compositions |
| DE3734184A1 (de) | 1987-10-09 | 1989-04-20 | Pelz & Co Kg W | Verfahren zur herstellung von wattetupfern und anlage zur durchfuehrung des verfahrens |
| ATE81253T1 (de) * | 1987-10-14 | 1992-10-15 | Dowelanco | Agrochemische zusammensetzungen auf basis von latex. |
| DE3840342A1 (de) | 1988-11-30 | 1990-05-31 | Basf Ag | Verfahren zur herstellung von 4-chlorpyrazolen |
| NZ238916A (en) | 1990-07-20 | 1993-09-27 | Buckman Labor Inc | Preparation of 1-hydroxymethylpyrazoles |
| DE4028393A1 (de) | 1990-09-07 | 1992-03-12 | Basf Ag | Verfahren zur herstellung von 3-methylpyrazol |
| US5497107A (en) | 1993-05-13 | 1996-03-05 | Texas Instruments Incorporated | Multiple, selectable PLAS having shared inputs and outputs |
| DE19503827A1 (de) | 1995-02-06 | 1996-08-08 | Basf Ag | Verwendung von schwerflüchtigen Pyrazolderivaten mit hydrophilen Gruppen als Nitrifikationsinhibitoren |
| US5698003A (en) | 1995-12-19 | 1997-12-16 | Imc-Agrico Company | Formulation for fertilizer additive concentrate |
| DE19631764A1 (de) | 1996-08-06 | 1998-02-12 | Basf Ag | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
| US5770771A (en) | 1997-01-21 | 1998-06-23 | Albemarle Corporation | Preparation of N-hydrocarbylthiophosphoric triamides |
| WO2000058317A1 (de) | 1999-03-25 | 2000-10-05 | Skw Stickstoffwerke Piesteritz Gmbh | (thio-) phosphorsäuretriamide, zur regulierung der enzymatischen harnstoff-hydrolyse |
| PT1183220E (pt) | 1999-04-08 | 2003-03-31 | Piesteritz Stickstoff | Meio para o melhoramento do aproveitamento de azoto de adubos minerais e/ou organicos contendo ureia |
| DE10024622A1 (de) | 2000-05-18 | 2001-11-22 | Piesteritz Stickstoff | N-(2-Pyrimidinyl)(thio)phosphorsäuretriamide, Verfahren zu ihrer Herstellung und deren Verwendung als Mittel zur Regulierung bzw. Hemmung der enzymatischen Harnstoff-Hydrolyse |
| DE10118322A1 (de) | 2001-04-12 | 2002-10-17 | Piesteritz Stickstoff | Heterozyklisch-substituierte (Thio)Phosphorsäuretriamide, Verfahren zu ihrer Herstellung und deren Verwendung als Mittel zur Regulierung bzw.Hemmung der enzymatischen Harnstoff-Hydrolyse |
| DE10317895A1 (de) * | 2003-04-17 | 2004-11-11 | Skw Stickstoffwerke Piesteritz Gmbh | 1,3,4-Oxa-und 1,3,4-Thiadiazol-2-yl(thio)phosphorsäuretriamide, Verfahren zu ihrer Herstellung und deren Verwendung als Mittel zur Regulierung bzw. Hemmung der enzymatischen Harnstoff-Hydrolyse |
| DE102004035742A1 (de) | 2004-07-23 | 2006-03-16 | Skw Stickstoffwerke Piesteritz Gmbh | N-Phenylphosphorsäuretriamide, Verfahren zu ihrer Herstellung und deren Verwendung als Mittel zur Regulierung bzw. Hemmung der enzymatischen Harnstoff-Hydrolyse |
| EP1820788A1 (de) | 2006-02-16 | 2007-08-22 | BASF Aktiengesellschaft | Zubereitungen mit verbesserter Urease-hemmender Wirkung und diese enthaltende harnstoffhaltige Düngemittel |
| CN101134697A (zh) * | 2006-09-01 | 2008-03-05 | 中国科学院沈阳应用生态研究所 | 一种硝化抑制剂及其在稳定肥料中的应用 |
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| DE102009060150B4 (de) | 2009-12-23 | 2013-06-06 | K+S Aktiengesellschaft | Verfahren zur Herstellung von Säureadditionssalzen von Pyrazolen |
| ES2925942T3 (es) | 2011-12-12 | 2022-10-20 | Rhodia Operations | Sistemas de disolventes de triamidas N-alquiltiofosfóricas y métodos de uso en aplicaciones agrícolas |
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| BR112017006352B1 (pt) * | 2014-09-30 | 2022-08-02 | Rhodia Operations | Solução de inibidor de triamida tiofosfórica urease e solvente, método para preparar um fertilizante à base de ureia e solução de diciandiamida e solvente |
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| EP3294690A1 (en) * | 2015-05-12 | 2018-03-21 | Basf Se | Thioether compounds as nitrification inhibitors |
| SI3109223T1 (sl) * | 2015-06-22 | 2018-11-30 | Eurochem Agro Gmbh | Zmes za obdelavo gnojil, ki vsebujejo sečnino |
| EP3325491B1 (en) * | 2015-07-20 | 2020-05-20 | SABIC Global Technologies B.V. | Fertilizer composition and methods of making and using same |
| MX2018014176A (es) * | 2016-05-18 | 2019-02-28 | Basf Se | Capsulas que comprenden bencilpropargileteres para usar como inhibidores de la nitrificacion. |
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| US20190248715A1 (en) * | 2018-02-15 | 2019-08-15 | Gary David McKnight | Compositions and Methods for Coating of Nitrification Inhibitors with a Solution Containing a High Concentration of Urease Inhibitors and For Improved Retention of the Nitrogen Content of Soil Through the Administration of Liquid Delivery Formulations of (Aminomethylene)Phosphinic Acids and/or their Salts |
| CA3066991A1 (en) * | 2017-07-10 | 2019-01-17 | Basf Se | Mixtures comprising an urease inhibitor (ui) and a nitrification inhibitor such as 2-(3,4-dimethyl-1h-pyrazol-1-yl)succinic acid (dmpsa) or 3,4-dimethyl pyrazolium glycolate (dmpg) |
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| CA3050114A1 (en) * | 2018-07-19 | 2020-01-19 | Koch Agronomic Services, Llc | Low temperature stable formulations of urease inhibitor-containing compositions |
| WO2020033575A1 (en) * | 2018-08-08 | 2020-02-13 | Tessenderlo Kerley, Inc. | Compositions comprising solid thiosulfates, polysulfides and/or (bi)sulfites with an urea compound and methods for preparing same |
| EP3972949A1 (en) * | 2019-05-20 | 2022-03-30 | Deltachem GmbH | Solution, aerosol for use as a fertilizer additive, use of an aqueous solution and/or of an aerosol as an additive to a fertilizer and a related composition |
-
2018
- 2018-06-04 DE DE102018208770.9A patent/DE102018208770A1/de active Pending
-
2019
- 2019-06-03 WO PCT/EP2019/064251 patent/WO2019233905A1/de unknown
- 2019-06-03 BR BR112020024656-5A patent/BR112020024656A2/pt unknown
- 2019-06-03 ES ES19728931T patent/ES2935747T3/es active Active
- 2019-06-03 JP JP2020567960A patent/JP7270653B2/ja active Active
- 2019-06-03 MX MX2020013053A patent/MX2020013053A/es unknown
- 2019-06-03 EP EP19728931.7A patent/EP3807232B1/de active Active
- 2019-06-03 PT PT197289317T patent/PT3807232T/pt unknown
- 2019-06-03 US US17/058,984 patent/US20210214285A1/en not_active Abandoned
- 2019-06-03 KR KR1020207038069A patent/KR20210019466A/ko unknown
- 2019-06-03 PL PL19728931.7T patent/PL3807232T3/pl unknown
- 2019-06-03 CN CN201980037138.XA patent/CN112292366B/zh active Active
- 2019-06-04 AR ARP190101519A patent/AR115476A1/es active IP Right Grant
-
2020
- 2020-12-28 CO CONC2020/0016514A patent/CO2020016514A2/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL3807232T3 (pl) | 2023-04-17 |
| MX2020013053A (es) | 2021-05-27 |
| EP3807232B1 (de) | 2022-11-16 |
| BR112020024656A2 (pt) | 2021-03-02 |
| JP7270653B2 (ja) | 2023-05-10 |
| KR20210019466A (ko) | 2021-02-22 |
| WO2019233905A1 (de) | 2019-12-12 |
| AU2019280606A1 (en) | 2021-01-07 |
| CN112292366B (zh) | 2022-08-26 |
| EP3807232A1 (de) | 2021-04-21 |
| PT3807232T (pt) | 2023-01-02 |
| US20210214285A1 (en) | 2021-07-15 |
| CO2020016514A2 (es) | 2021-04-08 |
| CN112292366A (zh) | 2021-01-29 |
| DE102018208770A1 (de) | 2019-12-05 |
| JP2021529146A (ja) | 2021-10-28 |
| ES2935747T3 (es) | 2023-03-09 |
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