AR100124A1 - Inhibidores de la nitrificación - Google Patents

Inhibidores de la nitrificación

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Publication number
AR100124A1
AR100124A1 ARP150101160A ARP150101160A AR100124A1 AR 100124 A1 AR100124 A1 AR 100124A1 AR P150101160 A ARP150101160 A AR P150101160A AR P150101160 A ARP150101160 A AR P150101160A AR 100124 A1 AR100124 A1 AR 100124A1
Authority
AR
Argentina
Prior art keywords
alkyl
substituted
aryl
independently selected
substituents
Prior art date
Application number
ARP150101160A
Other languages
English (en)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR100124A1 publication Critical patent/AR100124A1/es

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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
    • C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
    • C07C205/37—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/84—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/24—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • C07C233/25—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • C07C243/10—Hydrazines
    • C07C243/22—Hydrazines having nitrogen atoms of hydrazine groups bound to carbon atoms of six-membered aromatic rings
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    • C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
    • C07C243/26—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C243/28—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/74—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/76—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/54—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
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    • C07C255/00—Carboxylic acid nitriles
    • C07C255/63—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C255/65—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/40—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings
    • C07C271/42—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/44—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/40—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings
    • C07C271/58—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C275/32—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms
    • C07C275/34—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms having nitrogen atoms of urea groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/30—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/37—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups having the sulfur atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/02—Monothiocarbamic acids; Derivatives thereof
    • C07C333/08—Monothiocarbamic acids; Derivatives thereof having nitrogen atoms of thiocarbamic groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C335/00—Thioureas, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C335/04—Derivatives of thiourea
    • C07C335/16—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C335/18—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms
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    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
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    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/23—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/255—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/84—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
    • C07C69/92—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with etherified hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/30—Indoles; Hydrogenated indoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to carbon atoms of the hetero ring
    • C07D209/32—Oxygen atoms
    • C07D209/34—Oxygen atoms in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
    • C07D211/16—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms with acylated ring nitrogen atom
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    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
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    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D239/52—Two oxygen atoms
    • C07D239/54—Two oxygen atoms as doubly bound oxygen atoms or as unsubstituted hydroxy radicals
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    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract

Inhibidores de la nitrificación de la fórmula (1). Más aún, el uso de estos inhibidores de la nitrificación para reducir la nitrificación, así como mezclas agroquímicas y composiciones que comprenden los inhibidores de la nitrificación También métodos para reducir la nitrificación que comprende el tratamiento de plantas, suelo y/o loci con dichos inhibidores de la nitrificación y métodos para tratar un fertilizante o una composición por aplicación de dicho inhibidor de nitrificación. Reivindicación 1: Uso de un inhibidor de nitrificación para reducir la nitrificación, en donde dicho inhibidor de nitrificación es un compuesto de la fórmula (1) o uno de sus estereoisómeros, sales, tautómeros o N-óxidos, en donde A es arilo o hetarilo, en donde el anillo aromático puede estar, en cada caso, no sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de RA; R¹ y R² se seleccionan, de modo independiente entre sí, de H y alquilo C₁₋₂; y R³ es H, haloalquilo C₁₋₄, hidroxialquilo C₁₋₄, etinilhidroximetilo, fenilhidroximetilo o arilo, en donde el anillo aromático puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de RB; y en donde RA es (i) halógeno, CN, NRᵃRᵇ, ORᶜ, SRᶜ, C(=Y¹)Rᶜ, C(=Y¹)ORᶜ, C(=Y¹)SRᶜ, C(=Y¹)NRᵃRᵇ, Y²C(=Y¹)Rᶜ, Y²C(=Y¹)ORᶜ, Y²C(=Y¹)SRᶜ, Y²C(=Y¹)NRᵃRᵇ, Y³Y²C(=Y¹)Rᶜ, NRᵍN=C(Rᵈ)(Rᵉ), C(=N-ORᶜ)Rᵍ, C(=N-ORᶜ)Rᵍ, C(=N-SRᶜ)Rᵍ, C(=N-NRᵃRᵇ)Rᵍ, S(=O)₂Rᶠ, NRᵍS(=O)₂Rᶠ, S(=O)₂Y²C(=Y¹)Rᶜ, S(=O)₂Y²C(=Y¹)ORᶜ, S(=O)₂Y²C(=Y¹)SRᶜ, S(=O)₂Y²C(=Y¹)NRᵃRᵇ, NO₂, NON-CN, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₄, cianoalquilo C₁₋₄, hidroxialquilo C₁₋₄, alcoxi C₁₋₄, alquinil C₂₋₄-hidroxialquilo C₁₋₂, alquinil C₂₋₄-oxi; (ii) alquilen C₁₋₄-C(=Y¹)Rᶜ, alquenilen C₂₋₄-C(=Y¹)Rᶜ, alquilen C₁₋₄-C(=Y¹)ORᶜ, alquenilen C₂₋₄-C(=Y¹)ORᶜ, alquilen C₁₋₄-C(=Y¹)SRᶜ, alquenilen C₂₋₄-C(=Y¹)SRᶜ, alquilen C₁₋₄-C(=Y¹)NRᵃNRᵇ, alquenilen C₂₋₄-C(=Y¹)NRᵃNRᵇ, alquilen C₁₋₄-Y²-C(=Y¹)Rᶜ, alquenilen C₂₋₄-Y²-C(=Y¹)Rᶜ, alquilen C₁₋₄-NRᵃRᵇ, alquenilen C₂₋₄-NRᵃRᵇ, alquilen C₁₋₄-ORᶜ, alquenilen C₂₋₄-ORᶜ, alquilen C₁₋₄-SRᶜ, alquenilen C₂₋₄-SRᶜ, en donde la cadena de alquileno C₁₋₄ o alquenileno C₂₋₄ puede estar, en cada caso, no sustituido o puede estar parcial o totalmente sustituido con ORᵍ, CN, halógeno o fenilo; (iii) arilo, aril-alquilo C₁₋₂, hetarilo o hetaril-alquilo C₁₋₂, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de Rʰ; (iv) un carbociclo o heterociclo saturado o insaturado de 3 a 14 miembros, que puede contener 1, 2 ó 3 heteroátomos que se seleccionan, de modo independiente entre sí, de NR¹ᵇ, O y S, en donde S se puede oxidar y/o en donde el carbociclo o heterociclo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes que se seleccionan, de modo independiente entre sí, de Rⁱ; y en donde R¹ᵇ es H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-metilo u ORᵍ; o (v) L-B, en donde L es -CH₂-, -CH=CH-, -CºC-, -C(=O)- o -CH=, y B es arilo o hetarilo, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de Rʰ; o un carbociclo o heterociclo saturado o insaturado de 3 a 14 miembros, que puede contener 1, 2 ó 3 heteroátomos que se seleccionan, de modo independiente entre sí, de NR¹ᵇ, O y S, en donde S se puede oxidar y/o en donde el carbociclo o heterociclo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes que se seleccionan, de modo independiente entre sí, de Rⁱ; y en donde R¹ᵇ es H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-metilo u ORᵍ; o (vi) dos sustituyentes RA representan juntos un anillo carbocíclico o heterocíclico, que se fusiona con A y puede contener 1, 2 ó 3 heteroátomos que se seleccionan, de modo independiente entre sí, de NR¹ᶜ, O y S, en donde S se puede oxidar y/o en donde el carbociclo o heterociclo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes que se seleccionan, de modo independiente entre sí, de Rⁱ; y en donde R¹ᶜ es H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-metilo, heterociclilo C₃₋₆, heterociclilmetilo C₃₋₆ u ORᵍ; y en donde RB es NH-C(=O)-(alquilo C₁₋₄), NH-C(=O)-(alquenilo C₂₋₄), NH-C(=O)-(alcoxi C₁₋₂-alquilo C₁₋₂), NH-C(=O)-(cicloalquilo C₃₋₆), NH-S(=O)₂-(alquilo C₁₋₄) o NO₂; y en donde Y¹, Y² e Y³ se seleccionan, de modo independiente entre sí, de O, S y NR¹ᵃ, en donde R¹ᵃ es en cada caso, de modo independiente, H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-metilo, ORᵍ, SRᵍ o NRᵐRⁿ; Rᵃ y Rᵇ se seleccionan, de modo independiente entre sí, de (i) H, NRʲRᵏ, ORˡ, SRˡ, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, hidroxialquilo C₁₋₄, alcoxi C₁₋₄, C₍₌Y¹)Rˡ, C(=Y¹)ORˡ, C(=Y¹)SRˡ, C(=Y¹)NRʲRᵏ, C(=Y¹)C(=Y²)Rˡ, S(=O)₂Rᶠ; (ii) arilo o hetarilo, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de Rʰ; o Rᵃ y Rᵇ junto con el átomo de nitrógeno al que están unidos forman (iii) un grupo hetarilo que puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de Rʰ; o (iv) un heterociclo saturado o insaturado de 3 a 10 miembros, que puede contener 1, 2 ó 3 heteroátomos que se seleccionan, de modo independiente entre sí, de NR¹ᵇ, O y S, en donde S se puede oxidar y/o en donde el heterociclo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes que se seleccionan, de modo independiente entre sí, de Rⁱ; y en donde R¹ᵇ es H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-metilo u ORᵍ; Rᶜ es (i) H, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, C₍₌O₎ORˡ, C(=O)SRˡ, C(=O)NRʲRᵏ; (ii) alquilen C₁₋₄-C(=O)Rˡ, alquilen C₁₋₄-C(=O)ORˡ, en donde la cadena de alquileno C₁₋₄ puede estar, en cada caso, no sustituido o puede estar parcial o totalmente sustituido con ORᵍ, CN, halógeno o fenilo; (iii) arilo, aril-alquilo C₁₋₂, hetarilo o hetaril-alquilo C₁₋₂, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de Rʰ; o (iv) un carbociclo o heterociclo saturado o insaturado de 3 a 10 miembros, que puede contener 1, 2 ó 3 heteroátomos que se seleccionan, de modo independiente entre sí, de NR¹ᵇ, O y S, en donde S se puede oxidar y/o en donde el carbociclo o heterociclo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes que se seleccionan, de modo independiente entre sí, de Rⁱ; y en donde R¹ᵇ es H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₈-metilo u ORᵍ; Rᵈ y Rᵉ se seleccionan, de modo independiente, de alquilo C₁₋₄, haloalquilo C₁₋₄, NRʲRᵏ, ORˡ, SRˡ, CN, C(=Y¹)Rˡ, C(=Y¹)ORˡ, C(=Y¹)SRˡ o C(=Y¹)NRʲRᵏ; Rᶠ es alquilo C₁₋₄, haloalquilo C₁₋₄, NRʲRᵏ, ORˡ, SRˡ, arilo o hetarilo, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de Rʰ; Rᵍ es H o alquilo C₁₋₄; Rʰ esa halógeno, CN, NO₂, NRʲRᵏ, ORˡ, SRˡ, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, alquinil C₂₋₄-oxi, C(=Y¹)Rˡ, C(=Y¹)ORˡ, C(=Y¹)SRˡ, C(=Y¹)NRʲRᵏ, arilo, ariloxi, hetarilo y hetariloxi; Rⁱ es (i) halógeno, CN, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, haloalquilo C₁₋₄, haloalquenilo C₂₋₄; (ii) =NR¹ᵈ, en donde R¹ᵈ es H, alquilo C₁₋₄, alquenilo C₂₋₄, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-metilo u ORᵍ; (iii) =O, =S, NRʲRᵏ, ORˡ, SRˡ, C(=Y¹)Rˡ, C(=Y¹)ORˡ, C(=Y¹)SRˡ, C(=Y¹)NRʲRᵏ; (iv) arilo, aril-alquilo C₁₋₂, hetarilo o hetaril-alquilo C₁₋₂, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de halógeno, CN, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, alquinil C₂₋₄-oxi, ORᵍ y SRᵍ; o (v) cicloalquilo C₃₋₆ o heterociclilo de 3 a 6 miembros, en donde el anillo cicloalquilo o el anillo heterociclilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan cada uno, de modo independiente, de halógeno, CN, alquilo C₁₋₄, ORᵍ y SRᵍ; Rʲ y Rᵏ se seleccionan, de modo independiente, de H, ORᵍ, SRᵍ, C(=Y¹)Rᵍ, C(=Y¹)ORᵍ, C(=Y¹)SRᵍ, C(=Y¹)NRᵐRⁿ, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, haloalquilo C₁₋₄, arilo o hetarilo, en donde el anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan, de modo independiente, de halógeno, CN, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, alquinil C₂₋₄-oxi, ORᵍ y SRᵍ; Rˡ es H, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, haloalquilo C₁₋₄, C₍₌Y¹)Rᵍ, C(=Y¹)ORᵍ, C(=Y¹)SRᵍ, C(=Y¹)NRᵐRⁿ, arilo o hetarilo, en donde al anillo aromático del grupo arilo o hetarilo puede no estar sustituido o puede estar parcial o totalmente sustituido con sustituyentes, que se seleccionan, de modo independiente, de halógeno, CN, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, alquinil C₂₋₄-oxi, ORᵍ y SRᵍ; y Rᵐ y Rⁿ se seleccionan, de modo independiente, de H y alquilo C₁₋₄. Reivindicación 6: Una composición para reducir la nitrificación que comprende al menos un inhibidor de la nitrificación como se define en cualquiera de las reivindicaciones 1 a 6 y al menos un portador. Reivindicación 7: Una mezcla agroquímica que comprende (i) al menos un fertilizante; y (ii) al menos un inhibidor de la nitrificación como se define en cualquiera de las reivindicaciones 1 a 6 o la composición de acuerdo con la reivindicación 7. Reivindicación 10: Un método para reducir la nitrificación, que comprende el tratamiento de una planta que crece sobre el suelo o sustituyentes del suelo y/o el locus o suelo o sustituyentes del suelo, donde la planta está creciendo o pretende crecer con al menos un inhibidor de la nitrificación como se define en cualquiera de las reivindicaciones 1 a 6 o una composición según se define en la reivindicación 7. Reivindicación 14: La mezcla agroquímica de acuerdo con la reivindicación 8, el uso de acuerdo con la reivindicación 9 ó 10 o el método de acuerdo con cualquiera de las reivindicaciones 12 a 14, en donde dicho fertilizante es un fertilizante inorgánico que contiene amonio tales como un fertilizante NPK, amonio anhidro, nitrato de amonio, nitrato de calcio y amonio, sulfato nitrato de amonio, sulfato de amonio o fosfato de amonio; un fertilizante orgánico tales como estiércol liquido, estiércol semilíquido, estiércol de biogás, estiércol estable y estiércol de paja, humus de gusanos, compost, algas o guano o un fertilizante que contiene urea tales como urea, formaldehído urea, solución de urea y nitrato de amonio (UAN), urea sulfurada, urea estabilizada, fertilizantes NPK a base de urea o sulfato de amonio y urea.
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