AR094154A1 - Triazoles e imidazoles sustituidos y su uso como fungicidas - Google Patents

Triazoles e imidazoles sustituidos y su uso como fungicidas

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Publication number
AR094154A1
AR094154A1 ARP130104879A ARP130104879A AR094154A1 AR 094154 A1 AR094154 A1 AR 094154A1 AR P130104879 A ARP130104879 A AR P130104879A AR P130104879 A ARP130104879 A AR P130104879A AR 094154 A1 AR094154 A1 AR 094154A1
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AR
Argentina
Prior art keywords
alkyl
cycloalkyl
halogen
alkoxy
independently selected
Prior art date
Application number
ARP130104879A
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English (en)
Original Assignee
Basf Se
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Application filed by Basf Se filed Critical Basf Se
Publication of AR094154A1 publication Critical patent/AR094154A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

Compuestos de triazol e imidazol sustituidos de la fórmula (1) como se define en la descripción, a sus N-óxidos y sales, su preparación e intermediarios para prepararlos. También el uso de estos compuestos para combatir hongos dañinos, semillas recubiertas con al menos uno de dichos compuestos y también composiciones que comprenden al menos uno de dichos compuestos. Reivindicación 1: Compuestos de la fórmula (1) en donde el ciclo es cicloalquilo C₃₋₇ o un heterociclo saturado no aromático de 5 ó 6 miembros, en donde el heterociclo contiene 1, 2, 3 ó 4 heteroátomos seleccionados del grupo que consiste en O, N y S como miembros del anillo; A es CH o N; D es H, halógeno o SRD; en donde RD es hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆ o CN; R³ se selecciona independientemente de halógeno, CN, NO₂, OH, SH, alquilo C₁₋₆, alcoxi C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, cicloalquiloxi C₃₋₈, NH₂, NH(alquilo C₁₋₄), N(alquilo C₁₋₄)₂, NH(cicloalquilo C₃₋₆), N(cicloalquilo C₃₋₆)₂, S(O)ₚ(alquilo C₁₋₄), C(=O)(alquilo C₁₋₄), C(=O)(OH), C(=O)(O-alquilo C₁₋₄), C(=O)(NH(alquilo C₁₋₄)), C(=O)(N(alquilo C₁₋₄)₂), C(=O)(NH(cicloalquilo C₃₋₆)) y C(=O)-(N(cicloalquilo C₃₋₆))₂; en donde cada uno de R³ es no sustituido o sustituido adicionalmente con 1, 2, 3 ó 4 R³ᵃ; en donde R³ᵃ se selecciona independientemente de halógeno, CN, NO₂, OH, alquilo C₁₋₄, haloalquilo C₁₋₄, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alcoxi C₁₋₄ y halógeno-alcoxi C₁₋₄; n es 0, 1, 2, 3 ó 4; Y es un enlace directo o un grupo divalente seleccionado del grupo que consiste en -O-, -S-, -SO-, -SO₂-, -NH-, -N(alquil C₁₋₄)-, CR¹⁵R⁸-, -CR⁹R¹⁰-CR¹¹R¹²-, -CR¹³=CR¹⁴ y -CºC-; en donde R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵ se seleccionan independientemente de hidrógeno, halógeno, CN, nitro, OH, alquilo C₁₋₄, halógeno-alquilo C₁₋₄, alcoxi C₁₋₄ y halógeno-alcoxi C₁₋₄; Z es un heteroarilo de 5 ó 6 miembros, en donde el heteroarilo contiene 1, 2, 3 ó 4 heteroátomos seleccionados del grupo que consiste en O, N y S, o fenilo, en donde el heteroarilo o fenilo es no sustituido (m = 0) o sustituido con (R⁴)ₘ₁, en donde m es 0, 1, 2, 3, 4 ó 5; R⁴ se selecciona independientemente de halógeno, CN, NO₂, OH, SH, alquilo C₁₋₆, alcoxi C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, cicloalquiloxi C₃₋₈, NH₂, NH(alquilo C₁₋₄), N(alquilo C₁₋₄)₂, NH(cicloalquilo C₃₋₆), N(cicloalquilo C₃₋₆)₂, S(O)ₚ(alquilo C₁₋₄), C(=O)(alquilo C₁₋₄), C(=O)(OH), C(=O)(O-alquilo C₁₋₄), C(=O)(NH(alquilo C₁₋₄)), C(=O)(N(alquilo C₁₋₄)₂), C(=O)(NH(cicloalquilo C₃₋₆)) y C(=O)-(N(cicloalquilo C₃₋₆)₂; en donde cada uno de R⁴ es no sustituido o sustituido adicionalmente con 1, 2, 3 ó 4 R⁴ᵃ; en donde R⁴ᵃ se selecciona independientemente de halógeno, CN, NO₂, OH, alquilo C₁₋₄, haloalquilo C₁₋₄, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alcoxi C₁₋₄ y haloalcoxi C₁₋₄; p es 0, 1 ó 2; x es 0, 1, 2, 3 ó 4; R⁵ es H, halógeno, CN, NO₂, OH, SH, alquilo C₁₋₆, alcoxi C₁₋₆, alquil C₁₋₆tio, alquil C₁₋₆sulfinilo, alquil C₁₋₆sulfonilo, alquenilo C₂₋₆, alqueniloxi C₂₋₆, alquinilo C₂₋₆, alquiniloxi C₂₋₆, cicloalquilo C₃₋₈, cicloalquiloxi C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₄, NH₂, NH(alquilo C₁₋₄), N(alquilo C₁₋₄)₂, NH(cicloalquilo C₃₋₆), N(cicloalquilo C₃₋₆)₂, C(=O)-alquilo C₁₋₄, C₍₌O₎OH, C₍₌O₎₋O₋ₐₗqᵘⁱₗₒ C₁₋₄, C₍₌O₎₋NH₍ₐₗqᵘⁱₗₒ C₁₋₄), C(=O)-N(alquilo C₁₋₄)₂, C(=O)-NH(cicloalquilo C₃₋₆), C(=O)-N(cicloalquilo C₃₋₆)₂, fenilo, heteroarilo, fenil-alquilo C₁₋₄ y heteroaril-alquilo C₁₋₄, en donde el radical heteroarilo en los últimos grupos mencionados tiene 5 ó 6 miembros y en donde las porciones alifáticas, alicíclicas y aromáticas de R⁵ son no sustituidas o sustituidas con 1, 2, 3, 4 o hasta la mayor cantidad posible de R⁵ᵃ; en donde R⁵ᵃ se selecciona independientemente de halógeno, CN, NO₂, OH, SH, NH₂, alquilo C₁₋₆, haloalquilo C₁₋₆, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquil C₁₋₆tio, haloalquil C₁₋₆tio y alcoxi C₁₋₄-alquilo C₁₋₄; R⁶ es H o se selecciona de los sustituyentes definidos para R⁵, en donde las porciones alifáticas, alicíclicas y aromáticas de R⁶ son no sustituidas o sustituidas con 1, 2, 3, 4 o hasta la mayor cantidad posibles de R⁶ᵃ, en donde R⁶ᵃ se define como R⁵ᵃ; o es 0, 1, 2, 3 ó 4; R⁷ se selecciona independientemente de alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, en donde cada R⁷ es no sustituido o sustituido adicionalmente con 1, 2, 3 ó 4 R⁷ᵃ; en donde R⁷ᵃ se selecciona independientemente de halógeno, OH y alcoxi C₁₋₆; o dos sustituyentes R⁷: R⁷¹ y R⁷¹, junto con el átomo de carbono al que están unidos, forman un carbociclo o heterociclo saturado de 3, 4, 5, 6 ó 7 miembros, en donde el heterociclo contiene 1, 2, 3 ó 4 átomos O; y los N-óxidos y las sales de estos aceptables en la agricultura; siempre que x es 0, n no es 0, y R³ no es halógeno.
ARP130104879A 2012-12-19 2013-12-19 Triazoles e imidazoles sustituidos y su uso como fungicidas AR094154A1 (es)

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EP12198079 2012-12-19

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AR094154A1 true AR094154A1 (es) 2015-07-15

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US (1) US20150307460A1 (es)
EP (1) EP2935224A1 (es)
CN (1) CN104981459A (es)
AR (1) AR094154A1 (es)
BR (1) BR112015014303A2 (es)
UY (1) UY35219A (es)
WO (1) WO2014095547A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015086462A1 (en) 2013-12-12 2015-06-18 Basf Se Substituted [1,2,4]triazole and imidazole compounds
CA2939865A1 (en) 2014-03-26 2015-10-01 Basf Se Substituted [1,2,4]triazole and imidazole compounds as fungicides
EA033460B1 (ru) 2014-05-13 2019-10-31 Basf Se Замещенные [1,2,4]триазольные соединения в качестве фунгицидов
AR100743A1 (es) 2014-06-06 2016-10-26 Basf Se Compuestos de [1,2,4]triazol sustituido

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BR112015014303A2 (pt) 2017-07-11
US20150307460A1 (en) 2015-10-29

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