AR094626A1 - Proceso de fabricación de biocombustibles - Google Patents

Proceso de fabricación de biocombustibles

Info

Publication number
AR094626A1
AR094626A1 ARP130102941A ARP130102941A AR094626A1 AR 094626 A1 AR094626 A1 AR 094626A1 AR P130102941 A ARP130102941 A AR P130102941A AR P130102941 A ARP130102941 A AR P130102941A AR 094626 A1 AR094626 A1 AR 094626A1
Authority
AR
Argentina
Prior art keywords
glycerol
formal
composition
fatty acids
esters
Prior art date
Application number
ARP130102941A
Other languages
English (en)
Inventor
Bayarri Ferrer Natividad
Castells Boliart Josep
Estevez Company Carles
Original Assignee
Inst Univ Ciencia I Tecnologia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP12382441.9A priority Critical patent/EP2730567A1/en
Application filed by Inst Univ Ciencia I Tecnologia filed Critical Inst Univ Ciencia I Tecnologia
Priority to ARP130102941A priority patent/AR094626A1/es
Priority to BR112015010699A priority patent/BR112015010699A2/pt
Priority to JP2015541148A priority patent/JP6336462B2/ja
Priority to CN201380058613.4A priority patent/CN104812745B/zh
Priority to PCT/EP2013/073345 priority patent/WO2014072453A1/en
Priority to PL13789285.7T priority patent/PL2917199T3/pl
Priority to MYPI2015701451A priority patent/MY171741A/en
Priority to AU2013343475A priority patent/AU2013343475B2/en
Priority to NZ708442A priority patent/NZ708442A/en
Priority to PT137892857T priority patent/PT2917199T/pt
Priority to ES13789285.7T priority patent/ES2577112T3/es
Priority to DK13789285.7T priority patent/DK2917199T3/en
Priority to EP13789285.7A priority patent/EP2917199B1/en
Priority to CA2890805A priority patent/CA2890805A1/en
Priority to US14/441,686 priority patent/US9157039B1/en
Priority to SI201330195A priority patent/SI2917199T1/sl
Priority to MX2015005870A priority patent/MX359138B/es
Priority to IL238534A priority patent/IL238534A/en
Priority to CR20150281A priority patent/CR20150281A/es
Priority to ECIEPI201521231A priority patent/ECSP15021231A/es
Publication of AR094626A1 publication Critical patent/AR094626A1/es
Priority to HK15112715.2A priority patent/HK1211925A1/zh
Priority to CY20161100483T priority patent/CY1117590T1/el

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
    • C07D317/20—Free hydroxyl or mercaptan
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
    • C07D317/24—Radicals substituted by singly bound oxygen or sulfur atoms esterified
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
    • C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C10L1/1855—Cyclic ethers, e.g. epoxides, lactides, lactones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Lubricants (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

Procedimiento para la obtención simultánea de diversas composiciones comprendidas de ésteres alquílicos de ácidos grasos (biodiesel), glicerol formal y el bioéster de glicerol formal de ácidos grasos. También se refiere al uso de los mismos como biocombustibles. Reivindicación 1: Procedimiento para la obtención simultánea de diversas composiciones comprendidas de ésteres alquílicos de ácidos grasos (biodiesel), glicerol formal y el bioéster de glicerol formal de ácidos grasos, que comprende las siguientes etapas: (A) reacción entre el triglicérido, el glicerol y el dialcoximetano en presencia de un catalizador ácido, formando dos fases, donde la fase superior comprende una mezcla de ésteres alquílicos de ácidos grasos, ésteres de glicerol formal de ácidos grasos y un exceso de dialcoximetano y alcohol alquílico y la fase inferior comprende una mezcla de glicerol formal, el exceso de glicerol y el catalizador; (B1) separación del dialcoximetano y del alcohol alquílico de la fase superior para obtener la composición I que comprende ésteres alquílicos de ácidos grasos y ésteres de glicerol formal de ácidos grasos; (B2) separación del glicerol formal de la mezcla del glicerol en exceso y del catalizador que forman la fase inferior para obtener la composición II que comprende glicerol formal; (C) reacción de los compuestos de la fase superior obtenida según la etapa (A) o la composición I obtenida después de la etapa (B1) con una mezcla de alcohol alquílico y catalizador ácido para obtener una composición III que comprende ésteres alquílicos de ácidos grasos y una composición II que comprende glicerol formal; (D) reacción de transesterificación entre la composición I o la composición III y la composición II en presencia de un catalizador de transesterificación para formar la composición IV que comprende ésteres de glicerol formal de ácidos grasos.
ARP130102941A 2012-11-09 2013-08-20 Proceso de fabricación de biocombustibles AR094626A1 (es)

Priority Applications (23)

Application Number Priority Date Filing Date Title
EP12382441.9A EP2730567A1 (en) 2012-11-09 2012-11-09 Process for manufacturing biofuels
ARP130102941A AR094626A1 (es) 2012-11-09 2013-08-20 Proceso de fabricación de biocombustibles
ES13789285.7T ES2577112T3 (es) 2012-11-09 2013-11-08 Proceso para la fabricación de biocombustibles
EP13789285.7A EP2917199B1 (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
CN201380058613.4A CN104812745B (zh) 2012-11-09 2013-11-08 生产生物燃料的方法
PCT/EP2013/073345 WO2014072453A1 (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
PL13789285.7T PL2917199T3 (pl) 2012-11-09 2013-11-08 Sposób wytwarzania biopaliw
MYPI2015701451A MY171741A (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
AU2013343475A AU2013343475B2 (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
NZ708442A NZ708442A (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
PT137892857T PT2917199T (pt) 2012-11-09 2013-11-08 Processo para o fabrico de biocombustíveis
BR112015010699A BR112015010699A2 (pt) 2012-11-09 2013-11-08 processo para a obtenção simultânea de várias composições
DK13789285.7T DK2917199T3 (en) 2012-11-09 2013-11-08 PROCEDURE FOR MANUFACTURING BIOLOGIES
JP2015541148A JP6336462B2 (ja) 2012-11-09 2013-11-08 バイオ燃料を製造する方法
CA2890805A CA2890805A1 (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
US14/441,686 US9157039B1 (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels
SI201330195A SI2917199T1 (sl) 2012-11-09 2013-11-08 Proces za izdelavo biogoriv
MX2015005870A MX359138B (es) 2012-11-09 2013-11-08 Proceso de fabricacion de biocarburantes.
IL238534A IL238534A (en) 2012-11-09 2015-04-29 Organic fuel production process
CR20150281A CR20150281A (es) 2012-11-09 2015-05-27 Proceso de fabricación de biocarburantes
ECIEPI201521231A ECSP15021231A (es) 2012-11-09 2015-05-28 Proceso de fabricación de biocarburantes
HK15112715.2A HK1211925A1 (zh) 2012-11-09 2015-12-24 生產生物燃料的方法
CY20161100483T CY1117590T1 (el) 2012-11-09 2016-06-01 Μεθοδος για βιομηχανικη κατασκευη βιολογικων καυσιμων

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382441.9A EP2730567A1 (en) 2012-11-09 2012-11-09 Process for manufacturing biofuels
ARP130102941A AR094626A1 (es) 2012-11-09 2013-08-20 Proceso de fabricación de biocombustibles
PCT/EP2013/073345 WO2014072453A1 (en) 2012-11-09 2013-11-08 Process for manufacturing biofuels

Publications (1)

Publication Number Publication Date
AR094626A1 true AR094626A1 (es) 2015-08-19

Family

ID=49554256

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP130102941A AR094626A1 (es) 2012-11-09 2013-08-20 Proceso de fabricación de biocombustibles

Country Status (22)

Country Link
US (1) US9157039B1 (es)
EP (2) EP2730567A1 (es)
JP (1) JP6336462B2 (es)
CN (1) CN104812745B (es)
AR (1) AR094626A1 (es)
AU (1) AU2013343475B2 (es)
BR (1) BR112015010699A2 (es)
CA (1) CA2890805A1 (es)
CR (1) CR20150281A (es)
CY (1) CY1117590T1 (es)
DK (1) DK2917199T3 (es)
EC (1) ECSP15021231A (es)
ES (1) ES2577112T3 (es)
HK (1) HK1211925A1 (es)
IL (1) IL238534A (es)
MX (1) MX359138B (es)
MY (1) MY171741A (es)
NZ (1) NZ708442A (es)
PL (1) PL2917199T3 (es)
PT (1) PT2917199T (es)
SI (1) SI2917199T1 (es)
WO (1) WO2014072453A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2757140A1 (en) * 2013-01-17 2014-07-23 Institut Univ. de Ciència i Tecnologia, S.A. Formulation, preparation and use of a glycerol-based biofuel
PL411868A1 (pl) 2015-04-02 2016-10-10 Biotim Spółka Z Ograniczoną Odpowiedzialnością Instalacja do produkcji bioestrów metylowych z jednoczesnym przerobem surowej odpadowej fazy glicerynowej - metodą przemienną
JP7111625B2 (ja) * 2016-12-28 2022-08-02 株式会社カネカ アルコール化合物の製造法
WO2024089298A1 (es) 2022-10-24 2024-05-02 Selabtec Sciences, Slu Método para preparar una composición de biocombustible

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JPS56147739A (en) * 1980-04-17 1981-11-16 Seitetsu Kagaku Co Ltd Purification of methylal
JP2511407B2 (ja) * 1986-03-27 1996-06-26 日清製粉 株式会社 高度不飽和高級脂肪酸のモノグリセリドの製法
US4876368A (en) * 1988-05-24 1989-10-24 Hoechst Celanese Corporation Production of monohydroxy monocyclic acetals and their esters
DE19647395A1 (de) 1996-11-15 1998-05-20 Basf Ag Verfahren zur Herstellung von cyclischen Acetalen oder Ketalen
JP4754051B2 (ja) * 2000-08-29 2011-08-24 花王株式会社 モノグリセリドケタールの製造法
JP4578739B2 (ja) * 2000-12-04 2010-11-10 花王株式会社 モノグリセリドの製造法
US6548681B1 (en) 2001-06-26 2003-04-15 Board Of Trustees Of Michigan State University Process for the recovery of a polyol from an aqueous solution
FR2833607B1 (fr) * 2001-12-19 2005-02-04 Inst Francais Du Petrole Compositions de carburants diesel contenant des acetals de glycerol
FR2833606B1 (fr) 2001-12-19 2004-02-13 Inst Francais Du Petrole Compositions de carburants diesel contenant des carbonates d'acetals de glycerol
ES2201894B2 (es) * 2002-01-18 2005-03-01 Industrial Management, S.A Procedimiento para producir combustibles biodiesel con propiedades mejoradas a baja temperatura.
JP2004059435A (ja) * 2002-07-24 2004-02-26 Osaka Organic Chem Ind Ltd ジオキソラン化合物の製造法
ATE541223T1 (de) 2004-11-08 2012-01-15 Icx Radiation Gmbh Verfahren zur signaltrennung in szintillationsdetektoren
WO2006084048A1 (en) * 2005-02-02 2006-08-10 Jalin Technologies, Llc Bio-diesel fuel and manufacture of same
WO2006093896A1 (en) 2005-03-01 2006-09-08 Michigan State University Process for production of a composition useful as a fuel
CA2657431C (en) * 2006-07-12 2014-02-11 Carles Estevez Company Preparation of fatty acid esters of glycerol formal and its use as biofuel
US20100094027A1 (en) * 2008-08-20 2010-04-15 Todd Coleman Process for the Preparation of Glycerol Formal

Also Published As

Publication number Publication date
NZ708442A (en) 2016-07-29
MY171741A (en) 2019-10-27
US20150307794A1 (en) 2015-10-29
US9157039B1 (en) 2015-10-13
CY1117590T1 (el) 2017-04-26
MX359138B (es) 2018-09-17
IL238534A0 (en) 2015-06-30
JP2016501929A (ja) 2016-01-21
ECSP15021231A (es) 2016-01-29
EP2917199B1 (en) 2016-03-30
PT2917199T (pt) 2016-07-13
AU2013343475A1 (en) 2015-06-04
MX2015005870A (es) 2016-03-31
HK1211925A1 (zh) 2016-06-03
EP2917199A1 (en) 2015-09-16
CN104812745A (zh) 2015-07-29
JP6336462B2 (ja) 2018-06-06
EP2730567A1 (en) 2014-05-14
BR112015010699A2 (pt) 2017-07-11
SI2917199T1 (sl) 2016-07-29
DK2917199T3 (en) 2016-07-04
CN104812745B (zh) 2017-04-05
PL2917199T3 (pl) 2016-10-31
WO2014072453A1 (en) 2014-05-15
ES2577112T3 (es) 2016-07-13
AU2013343475B2 (en) 2017-07-13
IL238534A (en) 2017-06-29
CR20150281A (es) 2015-07-23
CA2890805A1 (en) 2014-05-15

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