AR089293A1 - Procedimiento para la preparacion de esteres a partir de formiatos y compuestos olefinicamente insaturados - Google Patents

Procedimiento para la preparacion de esteres a partir de formiatos y compuestos olefinicamente insaturados

Info

Publication number
AR089293A1
AR089293A1 ARP120104785A ARP120104785A AR089293A1 AR 089293 A1 AR089293 A1 AR 089293A1 AR P120104785 A ARP120104785 A AR P120104785A AR P120104785 A ARP120104785 A AR P120104785A AR 089293 A1 AR089293 A1 AR 089293A1
Authority
AR
Argentina
Prior art keywords
esters
preparation
compounds
olefinically
insatured
Prior art date
Application number
ARP120104785A
Other languages
English (en)
Inventor
Prof Franke Robert
Dr Hess Dieter
Prof Beller Matthias
Dr Jackstell Ralf
Cozzula Daniela
Dra Fleischer Ivana
Jennerjahn Reiko
Original Assignee
Evonik Industries Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Industries Ag filed Critical Evonik Industries Ag
Publication of AR089293A1 publication Critical patent/AR089293A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Indole Compounds (AREA)

Abstract

Un procedimiento para la preparación de ésteres a partir de formiatos y compuestos olefínicamente insaturados con catalizadores a base de compuestos con contenido de paladio. Además, se revela una mezcla de reacción multifásica, así como mezclas de ésteres nonilmetílicos preparadas según el procedimiento descripto. Reivindicación 1: Procedimiento para la preparación de ésteres por carbonilación, caracterizado porque se lleva a cabo i) usando al menos un compuesto con contenido de paladio, ii) al menos un compuesto olefínicamente insaturado, iii) al menos un ligando con contenido de fósforo, iv) al menos un formiato, v) al menos un alcohol, vi) al menos un ácido, vii) en un rango de temperaturas de 80 a 120ºC, viii) a una presión de reacción de 0,1 a 0,6 MPa.
ARP120104785A 2011-12-19 2012-12-18 Procedimiento para la preparacion de esteres a partir de formiatos y compuestos olefinicamente insaturados AR089293A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102011089008.4A DE102011089008B4 (de) 2011-12-19 2011-12-19 Verfahren zur Herstellung von Estern aus Formiaten und olefinisch ungesättigten Verbindungen

Publications (1)

Publication Number Publication Date
AR089293A1 true AR089293A1 (es) 2014-08-13

Family

ID=47358470

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP120104785A AR089293A1 (es) 2011-12-19 2012-12-18 Procedimiento para la preparacion de esteres a partir de formiatos y compuestos olefinicamente insaturados

Country Status (12)

Country Link
US (1) US9340485B2 (es)
EP (1) EP2794547B1 (es)
JP (1) JP5930348B2 (es)
KR (1) KR101978009B1 (es)
CN (1) CN103987690B (es)
AR (1) AR089293A1 (es)
DE (1) DE102011089008B4 (es)
ES (1) ES2720480T3 (es)
RU (1) RU2014129618A (es)
SG (1) SG11201403435XA (es)
TW (1) TWI543966B (es)
WO (1) WO2013092478A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2529007A (en) * 2014-02-28 2016-02-10 Dow Global Technologies Inc Process for making esters
CN106397484A (zh) 2015-07-23 2017-02-15 赢创德固赛有限公司 用于烷氧基羰基化的丁基‑桥连的二膦配体
EP3441383B1 (de) * 2017-08-08 2019-12-25 Evonik Operations GmbH Methoxycarbonylierung mit ameisensäure als co-quelle
EP3441384B1 (de) * 2017-08-08 2019-12-25 Evonik Operations GmbH Methoxycarbonylierung mit ameisensäure und methanol
EP3441137B1 (de) * 2017-08-08 2019-12-25 Evonik Operations GmbH Pd-katalysierten zersetzung von ameisensäure

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1239937A (en) * 1982-04-12 1988-08-02 Exxon Research And Engineering Company Process for converting olefins to carboxylic acids or esters using soluble iridium compounds
DE3366317D1 (en) * 1982-10-20 1986-10-23 Bp Chem Int Ltd Preparation of carboxylic acids and esters thereof
ZA837590B (en) * 1982-10-20 1985-05-29 Bp Chem Int Ltd Preparation of carboxylic acids and esters thereof
GB8521547D0 (en) * 1985-08-29 1985-10-02 British Petroleum Co Plc Production of esters
FR2659965B1 (fr) * 1990-03-26 1992-06-05 Norsolor Sa Catalyseur et procede pour la synthese d'esters carboxyliques satures.
JP3456491B2 (ja) * 1993-09-09 2003-10-14 三菱瓦斯化学株式会社 ジカルボン酸エステルの製造方法
DE19904200A1 (de) * 1999-02-03 2000-08-10 Basf Ag Verfahren zur Herstellung von 3-Alkensäureestern und ein Katalysator zur Durchführung des Verfahrens
MY127358A (en) * 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
DE10037961A1 (de) 2000-07-27 2002-02-07 Aventis Res & Tech Gmbh & Co Neue Phosphanliganden, deren Herstellung und ihre Verwendung in katalytischen Reaktionen
DE10100708A1 (de) 2001-01-10 2002-07-11 Oxeno Olefinchemie Gmbh Neue N-Phenylpyrrolbisphosphanverbindungen und deren Metallkomplexe
JP2005508390A (ja) * 2001-11-09 2005-03-31 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 不飽和化合物のカルボニル化のための二座配位子
GB0218613D0 (en) * 2002-08-10 2002-09-18 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds
GB0228018D0 (en) * 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
DE10322408A1 (de) 2003-05-16 2004-12-02 Degussa Ag Stickstoffhaltige monodentate Phosphine und deren Verwendung in der Katalyse
DE102005042464A1 (de) 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen

Also Published As

Publication number Publication date
RU2014129618A (ru) 2016-02-10
KR101978009B1 (ko) 2019-05-13
US9340485B2 (en) 2016-05-17
CN103987690B (zh) 2016-08-24
US20140309435A1 (en) 2014-10-16
ES2720480T3 (es) 2019-07-22
DE102011089008A1 (de) 2013-06-20
WO2013092478A1 (de) 2013-06-27
KR20140105471A (ko) 2014-09-01
SG11201403435XA (en) 2014-10-30
DE102011089008B4 (de) 2017-08-24
TWI543966B (zh) 2016-08-01
CN103987690A (zh) 2014-08-13
EP2794547B1 (de) 2019-02-06
JP5930348B2 (ja) 2016-06-08
TW201335134A (zh) 2013-09-01
EP2794547A1 (de) 2014-10-29
JP2015505858A (ja) 2015-02-26

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