AR086032A1 - Catalizadores para producir acidos acrilicos y acrilatos - Google Patents
Catalizadores para producir acidos acrilicos y acrilatosInfo
- Publication number
- AR086032A1 AR086032A1 ARP120101400A ARP120101400A AR086032A1 AR 086032 A1 AR086032 A1 AR 086032A1 AR P120101400 A ARP120101400 A AR P120101400A AR P120101400 A ARP120101400 A AR P120101400A AR 086032 A1 AR086032 A1 AR 086032A1
- Authority
- AR
- Argentina
- Prior art keywords
- additive
- catalyst composition
- titanium
- oxide
- vanadium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- 150000001253 acrylic acids Chemical class 0.000 title 1
- 239000000654 additive Substances 0.000 abstract 9
- 230000000996 additive effect Effects 0.000 abstract 9
- 239000000203 mixture Substances 0.000 abstract 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 5
- 239000010936 titanium Substances 0.000 abstract 5
- 229910052719 titanium Inorganic materials 0.000 abstract 5
- 229910052720 vanadium Inorganic materials 0.000 abstract 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 239000012018 catalyst precursor Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
En una realización, la presente se refiere a una composición catalizadora que comprende vanadio, titanio; y por lo menos un aditivo óxido. Por lo menos un aditivo óxido está presente en una cantidad de por lo menos 0,1% en peso en base al peso total de la composición catalizadora. La relación molar de titanio con el aditivo de metal en una fase activa de la composición catalizadora es por lo menos 0,05:1.Reivindicación 29: Un proceso para producir una composición catalizadora, en donde el proceso comprende: disolver por lo menos un aditivo óxido y ácido fosfórico para formar una solución aditiva que comprende por lo menos 0,04% en peso aditivo óxido; agregar un precursor de titanio y un precursor de vanadio a la solución aditiva para formar una mezcla de precursor de catalizador; y secar la mezcla de precursor de catalizador para formar una composición catalizadora no soportada que comprende: vanadio; titanio; y por lo menos un aditivo óxido en una cantidad de por lo menos 0,1% en peso; en donde la relación molar de aditivo óxido con respecto a titanio en una fase activa de la composición catalizadora es por lo menos 0,05:1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/105,558 US8642498B2 (en) | 2011-05-11 | 2011-05-11 | Catalysts for producing acrylic acids and acrylates |
Publications (1)
Publication Number | Publication Date |
---|---|
AR086032A1 true AR086032A1 (es) | 2013-11-13 |
Family
ID=46025972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP120101400A AR086032A1 (es) | 2011-05-11 | 2012-04-23 | Catalizadores para producir acidos acrilicos y acrilatos |
Country Status (10)
Country | Link |
---|---|
US (1) | US8642498B2 (es) |
EP (1) | EP2707136A1 (es) |
JP (1) | JP2014518759A (es) |
KR (2) | KR20140028067A (es) |
CN (1) | CN103517760B (es) |
AR (1) | AR086032A1 (es) |
BR (1) | BR112013028888A2 (es) |
MY (1) | MY166460A (es) |
TW (1) | TW201247318A (es) |
WO (1) | WO2012154396A1 (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8652988B2 (en) | 2011-04-27 | 2014-02-18 | Celanese International Corporation | Catalyst for producing acrylic acids and acrylates |
US8642498B2 (en) * | 2011-05-11 | 2014-02-04 | Celanese International Corporation | Catalysts for producing acrylic acids and acrylates |
US9573119B2 (en) | 2011-09-16 | 2017-02-21 | Eastman Chemical Company | Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8765629B2 (en) | 2011-09-16 | 2014-07-01 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8883672B2 (en) | 2011-09-16 | 2014-11-11 | Eastman Chemical Company | Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8993801B2 (en) | 2011-09-16 | 2015-03-31 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8802585B2 (en) * | 2011-09-22 | 2014-08-12 | Celanese International Corporation | Catalysts for producing acrylic acids and acrylates |
US8735314B2 (en) * | 2011-09-29 | 2014-05-27 | Celanese International Corporation | Catalysts for producing acrylic acids and acrylates |
CN104159670A (zh) * | 2012-03-13 | 2014-11-19 | 国际人造丝公司 | 用于产生丙烯酸和丙烯酸类的包含钒、钛和钨的催化剂 |
EP2825521B1 (en) * | 2012-03-13 | 2019-04-24 | Celanese International Corporation | Catalyst for producing acrylic acids and acrylates |
ES2804521T3 (es) * | 2012-08-24 | 2021-02-08 | Tronox Llc | Materiales de apoyo a catalizadores, catalizadores, métodos de su fabricación y usos de los mismos |
DE102015222198A1 (de) | 2015-11-11 | 2017-05-11 | Basf Se | Oxidische Zusammensetzung |
GB201616119D0 (en) | 2016-09-22 | 2016-11-09 | Johnson Matthey Davy Technologies Limited | Process |
GB201621985D0 (en) | 2016-12-22 | 2017-02-08 | Johnson Matthey Davy Technologies Ltd | Process |
GB201621975D0 (en) | 2016-12-22 | 2017-02-08 | Johnson Matthey Davy Technologies Ltd | Process |
CN107051576B (zh) * | 2017-05-05 | 2020-01-10 | 北京华福工程有限公司 | 用于乙炔合成丙烯酸或丙烯酸酯的催化剂及其制备方法和用途 |
SG11202109718RA (en) * | 2019-03-07 | 2021-10-28 | The Chugoku Electric Power Co Inc | Denitration catalyst, and production method therefor |
CN114292186A (zh) * | 2022-01-14 | 2022-04-08 | 万华化学集团股份有限公司 | 一种高纯度mma的制备方法 |
CN115888777A (zh) * | 2022-10-27 | 2023-04-04 | 潍坊科技学院 | 一种增强型改性vpo催化剂及其制备方法和应用 |
Family Cites Families (39)
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DE1294956B (de) | 1965-03-12 | 1969-05-14 | Hoechst Ag | Verfahren zur Herstellung von Acrylsaeuremethylester durch Oxydation von Methylacetat oder einer Mischung aus Methylacetat und Methanol |
US3541143A (en) | 1966-09-07 | 1970-11-17 | Mitsubishi Petrochemical Co | Process for the preparation of acrylic acid |
GB1285075A (en) | 1968-10-15 | 1972-08-09 | Mitsubishi Chem Ind | Catalyst and process for the preparation of maleic anhydride |
US4276197A (en) | 1979-12-19 | 1981-06-30 | Atlantic Richfield Company | Preparation of a titanium promoted VO(PO3)2 oxidation catalyst |
JPS57170646A (en) * | 1981-04-15 | 1982-10-20 | Nec Corp | Code conversion circuit |
US4447638A (en) * | 1982-08-02 | 1984-05-08 | Atlantic Richfield Company | Preparation of dialkyl oxalates by the oxidative carbonylation of alcohols with a heterogeneous Pd-V-P-Ti containing catalyst system |
US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
JPH0517392A (ja) * | 1991-03-29 | 1993-01-26 | Nippon Synthetic Chem Ind Co Ltd:The | アクリル酸の製造方法 |
KR950000615B1 (ko) * | 1991-11-05 | 1995-01-26 | 재단법인 한국화학연구소 | 아크릴산 제조용 고체촉매와 그를 이용한 아크릴산의 제조방법 |
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US5948726A (en) * | 1994-12-07 | 1999-09-07 | Project Earth Industries, Inc. | Adsorbent and/or catalyst and binder system and method of making therefor |
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IN192600B (es) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
DE19649426A1 (de) * | 1996-11-28 | 1998-06-04 | Consortium Elektrochem Ind | Schalenkatalysator zur Herstellung von Essigsäure durch Gasphasenoxidation von ungesättigten C¶4¶-Kohlenwasserstoffen |
US6232352B1 (en) | 1999-11-01 | 2001-05-15 | Acetex Limited | Methanol plant retrofit for acetic acid manufacture |
JP4426069B2 (ja) | 2000-06-12 | 2010-03-03 | 株式会社日本触媒 | アクリル酸の製造方法 |
US6627770B1 (en) | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
US6685754B2 (en) | 2001-03-06 | 2004-02-03 | Alchemix Corporation | Method for the production of hydrogen-containing gaseous mixtures |
US7115772B2 (en) | 2002-01-11 | 2006-10-03 | Celanese International Corporation | Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream |
US7005541B2 (en) | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
JP2004290924A (ja) | 2003-03-28 | 2004-10-21 | Sumitomo Chem Co Ltd | 触媒繊維およびその製造方法 |
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US7208624B2 (en) | 2004-03-02 | 2007-04-24 | Celanese International Corporation | Process for producing acetic acid |
WO2005115615A1 (de) * | 2004-05-29 | 2005-12-08 | Süd-Chemie AG | Katalysator sowie verfahren zur herstellung von phthalsäureanhydrid |
US7851398B2 (en) * | 2004-11-18 | 2010-12-14 | Basf Se | Catalytic titanium dioxide mixtures, catalysts and catalyst systems containing the same, processes for making the same, and uses therefor |
DE102005019000A1 (de) * | 2005-04-22 | 2006-10-26 | Degussa Ag | Katalytisch beschichteter Träger, Verfahren zu dessen Herstellung und damit ausgestatteter Reaktor sowie dessen Verwendung |
DE102010040921A1 (de) | 2010-09-16 | 2012-03-22 | Basf Se | Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure |
US8652988B2 (en) * | 2011-04-27 | 2014-02-18 | Celanese International Corporation | Catalyst for producing acrylic acids and acrylates |
US8642498B2 (en) * | 2011-05-11 | 2014-02-04 | Celanese International Corporation | Catalysts for producing acrylic acids and acrylates |
US20130053599A1 (en) * | 2011-08-22 | 2013-02-28 | Celanese International Corporation | Catalysts for producing acrylic acids and acrylates |
US8765629B2 (en) | 2011-09-16 | 2014-07-01 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8802585B2 (en) | 2011-09-22 | 2014-08-12 | Celanese International Corporation | Catalysts for producing acrylic acids and acrylates |
CN104159670A (zh) * | 2012-03-13 | 2014-11-19 | 国际人造丝公司 | 用于产生丙烯酸和丙烯酸类的包含钒、钛和钨的催化剂 |
-
2011
- 2011-05-11 US US13/105,558 patent/US8642498B2/en not_active Expired - Fee Related
-
2012
- 2012-04-23 JP JP2014510342A patent/JP2014518759A/ja active Pending
- 2012-04-23 KR KR1020137032729A patent/KR20140028067A/ko active Application Filing
- 2012-04-23 TW TW101114407A patent/TW201247318A/zh unknown
- 2012-04-23 BR BR112013028888A patent/BR112013028888A2/pt not_active IP Right Cessation
- 2012-04-23 WO PCT/US2012/034624 patent/WO2012154396A1/en active Application Filing
- 2012-04-23 EP EP12718542.9A patent/EP2707136A1/en not_active Withdrawn
- 2012-04-23 AR ARP120101400A patent/AR086032A1/es not_active Application Discontinuation
- 2012-04-23 MY MYPI2013702113A patent/MY166460A/en unknown
- 2012-04-23 KR KR1020197020581A patent/KR102038262B1/ko active IP Right Grant
- 2012-04-23 CN CN201280022567.8A patent/CN103517760B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
KR102038262B1 (ko) | 2019-10-29 |
TW201247318A (en) | 2012-12-01 |
WO2012154396A1 (en) | 2012-11-15 |
MY166460A (en) | 2018-06-27 |
KR20190087653A (ko) | 2019-07-24 |
US20120289743A1 (en) | 2012-11-15 |
KR20140028067A (ko) | 2014-03-07 |
EP2707136A1 (en) | 2014-03-19 |
US8642498B2 (en) | 2014-02-04 |
CN103517760A (zh) | 2014-01-15 |
JP2014518759A (ja) | 2014-08-07 |
CN103517760B (zh) | 2016-03-16 |
BR112013028888A2 (pt) | 2017-01-31 |
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