GB1285075A - Catalyst and process for the preparation of maleic anhydride - Google Patents

Catalyst and process for the preparation of maleic anhydride

Info

Publication number
GB1285075A
GB1285075A GB5017569A GB5017569A GB1285075A GB 1285075 A GB1285075 A GB 1285075A GB 5017569 A GB5017569 A GB 5017569A GB 5017569 A GB5017569 A GB 5017569A GB 1285075 A GB1285075 A GB 1285075A
Authority
GB
United Kingdom
Prior art keywords
mixture
catalyst
oct
vanadium
spray drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5017569A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP8685668A external-priority patent/JPS5313607B1/ja
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Publication of GB1285075A publication Critical patent/GB1285075A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

1285075 Oxidation catalyst MITSUBISHI KASEI KOGYO KK 13 Oct 1969 [15 Oct 1968 27 Nov 1968] 50175/69 Heading B1E [Also in Division C2] A particulate catalyst composition is formed by (i) preparing a mixture containing a vanadium compound; a phosphorus compound and an aqueous silica sol, (ii) spray drying the mixture and (iii) calcining, preferably at 200- 750‹C. The vanadium compound and the phosphorus compound used both are capable of being decomposed into their oxides by calcination. The mixture of compounds of step (i) may be a suspension or a solution, and oxalic acid may be added to bring the vanadium component into solution. The silica sol may be gelled to a small extent. The composition may also contain Ti, K, Cr, W, Mo, Co, B or Ni which are incorporated into the mixture before spray drying. The catalyst composition suitably has atomic ratios of components V:P:Si:Ti (if present) of 1:0.7-4:0.5-120:0.5-120. Suitably, the mean diameter of the particles is from 60-200 microns.
GB5017569A 1968-10-15 1969-10-13 Catalyst and process for the preparation of maleic anhydride Expired GB1285075A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP7510568 1968-10-15
JP8685668A JPS5313607B1 (en) 1968-11-27 1968-11-27

Publications (1)

Publication Number Publication Date
GB1285075A true GB1285075A (en) 1972-08-09

Family

ID=26416248

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5017569A Expired GB1285075A (en) 1968-10-15 1969-10-13 Catalyst and process for the preparation of maleic anhydride

Country Status (4)

Country Link
DE (1) DE1966418C3 (en)
FR (1) FR2022271A1 (en)
GB (1) GB1285075A (en)
NL (1) NL171414C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4407734A (en) 1981-08-10 1983-10-04 W. R. Grace & Co. Spray dried vanadia catalyst and method of preparing it
US4472527A (en) * 1982-03-31 1984-09-18 Mitsubishi Chemical Industries Ltd. Process for preparing an oxidation catalyst composition
WO2012154396A1 (en) * 2011-05-11 2012-11-15 Celanese International Corporation Catalysts for producing acrylic acids and acrylates

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4017521A (en) * 1972-06-19 1977-04-12 Chevron Research Company Process for the manufacture of maleic anhydride using high surface area catalyst
US4075232A (en) * 1975-03-06 1978-02-21 The Standard Oil Company Preparation of maleic anhydride from n-butene in a one-reactor, fluid-bed system using two different catalysts
US4351773A (en) 1980-12-31 1982-09-28 The Standard Oil Company Preparation of maleic anhydride from butane using fluidized vanadium-phosphorous-oxide containing catalysts
CA1197229A (en) * 1982-09-23 1985-11-26 Patricia R. Blum Attrition resistant microspheroidal fluid bed catalysts containing the mixed oxides of vanadium and phosphorus
US4677084A (en) * 1985-11-27 1987-06-30 E. I. Du Pont De Nemours And Company Attrition resistant catalysts, catalyst precursors and catalyst supports and process for preparing same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1844388A (en) * 1927-08-26 1932-02-09 Selden Co Catalytic oxidation of naphthalene
FR1034661A (en) * 1949-12-09 1953-07-29 Distillers Co Yeast Ltd Process for preparing maleic acid
FR1345558A (en) * 1961-09-18 1963-12-13 Petro Tex Chem Corp Process for the preparation of dicarboxylic acid anhydrides
GB1006795A (en) * 1962-02-21 1965-10-06 Yawata Chemical Industry Compa Vanadia onsilica oxidation catalysts

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4407734A (en) 1981-08-10 1983-10-04 W. R. Grace & Co. Spray dried vanadia catalyst and method of preparing it
US4472527A (en) * 1982-03-31 1984-09-18 Mitsubishi Chemical Industries Ltd. Process for preparing an oxidation catalyst composition
US4520127A (en) * 1982-03-31 1985-05-28 Mitsubishi Chemical Industries Ltd. Oxidation catalyst composition
WO2012154396A1 (en) * 2011-05-11 2012-11-15 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
CN103517760A (en) * 2011-05-11 2014-01-15 国际人造丝公司 Catalysts for producing acrylic acid and acrylates
US8642498B2 (en) 2011-05-11 2014-02-04 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
CN103517760B (en) * 2011-05-11 2016-03-16 国际人造丝公司 For the preparation of the catalyst of acrylic acid and acrylate
KR20190087653A (en) * 2011-05-11 2019-07-24 셀라니즈 인터내셔날 코포레이션 Catalysts for producing acrylic acids and acrylates

Also Published As

Publication number Publication date
NL171414C (en) 1983-04-05
NL6915555A (en) 1970-04-17
DE1951536B2 (en) 1976-09-02
DE1966418A1 (en) 1972-07-13
FR2022271A1 (en) 1970-07-31
DE1966418B2 (en) 1974-11-07
DE1966418C3 (en) 1975-06-19
DE1951536A1 (en) 1970-06-11

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years