AR084112A1 - Carbodiimidas biobasadas, un procedimiento para su preparacion y su uso - Google Patents

Carbodiimidas biobasadas, un procedimiento para su preparacion y su uso

Info

Publication number
AR084112A1
AR084112A1 ARP110101719A ARP110101719A AR084112A1 AR 084112 A1 AR084112 A1 AR 084112A1 AR P110101719 A ARP110101719 A AR P110101719A AR P110101719 A ARP110101719 A AR P110101719A AR 084112 A1 AR084112 A1 AR 084112A1
Authority
AR
Argentina
Prior art keywords
moiety
biobased
carbodiimide
case
coatings
Prior art date
Application number
ARP110101719A
Other languages
English (en)
Inventor
Armin Eckert
Franco Orsini
Wilhelm Laufer
Robert Eiben
Original Assignee
Rhein Chemie Rheinau Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhein Chemie Rheinau Gmbh filed Critical Rhein Chemie Rheinau Gmbh
Publication of AR084112A1 publication Critical patent/AR084112A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C267/00Carbodiimides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
    • C08G18/283Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/36Hydroxylated esters of higher fatty acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/29Compounds containing one or more carbon-to-nitrogen double bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Reivindicación 1: Carbodiimidas biobasadas que pueden obtenerse mediante la reacción de al menos una carbodiimida y al menos un compuesto H-ácido, aislado a partir de materias primas renovables o preparado a partir de las mismas, con una funcionalidad > 1 y más de 4 átomos de carbono y/o un éster de ácido hidroxicarboxílico con 2-24 átomos de carbono.Reivindicación 2: Carbodiimidas biobasadas según la reivindicación 1, caracterizadas porque, en el caso de la carbodiimida se trata de un compuesto de fórmula (1): R’-(-N=C=N-R-)m-R’’     (1) en la que R significa un resto aromático, alifático, cicloalifático o aralifático que, en el caso de un resto aromático o uno aralifático que en al menos en una posición orto al átomo de carbono aromático que porta el grupo carbodiimida, puede portar sustituyentes alifáticos y/o cicloalifáticos con al menos 2 átomos de carbono; R’ = alquilo C1-18, cicloalquilo C5-18, arilo, aralquilo C7-18 o R-NCO, R-NHCONHR1, R-NHCONR1R2 o R-NHCOOR3 y R’’ significa -NCO, en la que R1 y R2 en R’ son, independientemente entre sí, iguales o diferentes y representan un resto alquilo C1-6, cicloalquilo C6-10 o aralquilo C7-18 y R3 tiene uno de los significados de R1 o significa un resto poliéster o un resto poliamida y m corresponde a un número entero de 1 a 5.000, preferentemente de 1 a 500. Reivindicación 7: Procedimiento para preparar carbodiimidas biobasadas según una de las reivindicaciones 1 a 6 caracterizado porque se hace reaccionar al menos una carbodiimida con al menos un compuesto H-ácido, aislado a partir de materias primas renovables o preparado a partir de las mismas, con una funcionalidad > 1 y/o el éster de ácido hidroxicarboxílico y, dado el caso, polioles no biobasados a base de poliéter, poliéster o polieteréster a temperaturas de entre 20 y 200ºC, en forma de pasta y/o en solución, dado el caso en presencia de un catalizador. Reivindicación 8: Uso de carbodiimidas biobasadas según una de las reivindicaciones 1 a 6 en aplicaciones de poliuretano, para espuma dura/recubrimientos, espuma blanda, CASE (Coatings Adhesives, Sealants, Elastomers (recubrimientos, adhesivos, selladores, elastómeros)), termoplásticos, en aplicaciones de lubricantes, en aceites transformadores para la protección frente a la hidrólisis y para la reticulación de poliuretanos.
ARP110101719A 2010-05-21 2011-05-19 Carbodiimidas biobasadas, un procedimiento para su preparacion y su uso AR084112A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP10163621A EP2388284A1 (de) 2010-05-21 2010-05-21 Biobasierte Carbodiimide, ein Verfahren zu deren Herstellung und deren Verwendung

Publications (1)

Publication Number Publication Date
AR084112A1 true AR084112A1 (es) 2013-04-24

Family

ID=42941940

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP110101719A AR084112A1 (es) 2010-05-21 2011-05-19 Carbodiimidas biobasadas, un procedimiento para su preparacion y su uso

Country Status (11)

Country Link
US (2) US20130274506A1 (es)
EP (2) EP2388284A1 (es)
JP (1) JP5604587B2 (es)
KR (1) KR101451496B1 (es)
CN (1) CN102947363B (es)
AR (1) AR084112A1 (es)
ES (1) ES2658180T3 (es)
PT (1) PT2571915T (es)
TR (1) TR201802217T4 (es)
TW (1) TWI537239B (es)
WO (1) WO2011144717A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202011109841U1 (de) 2010-06-02 2012-05-08 Rhein-Chemie Rheinau Gmbh Neuartige flexible Verpackungen
WO2016132889A1 (ja) * 2015-02-20 2016-08-25 株式会社日本触媒 硬化性樹脂組成物及びそれを用いてなる封止材
NL2015266B1 (en) 2015-08-04 2017-02-21 Furanix Technologies Bv Poly(alkylene furandicarboxylate)-comprising polyester.
CN105294976A (zh) * 2015-11-20 2016-02-03 嘉兴洛克化学工业有限公司 一种耐水洗聚氨酯粘接剂及其制备方法
CN108715628B (zh) * 2018-06-22 2022-04-01 上海朗亿功能材料有限公司 一种脂环族聚碳化二亚胺抗水解剂及其制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1130594B (de) 1956-07-30 1962-05-30 Du Pont Verfahren zur Herstellung von gegebenenfalls modifizierten Polykondensationsprodukten mití¬N?C?N-Brueckengliedern
US2941956A (en) 1956-08-15 1960-06-21 Socony Mobil Oil Co Inc Regeneration of contact material
FR1180370A (fr) 1957-07-30 1959-06-03 Perfectionnements apportés aux compositions de métallisation de textile
DE4018184A1 (de) * 1990-06-07 1991-12-12 Bayer Ag Verfahren zur stabilisierung von estergruppen enthaltenden kunststoffen
JP3733170B2 (ja) * 1996-04-02 2006-01-11 日清紡績株式会社 ポリウレタン樹脂
DE10000656A1 (de) * 2000-01-11 2001-07-12 Basf Ag Carbodiimide mit Carboxyl- oder Carboxylatgruppen
DE10015658A1 (de) * 2000-03-29 2001-10-04 Rhein Chemie Rheinau Gmbh Blockcopolymere auf Basis von Polycarbodiimiden, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Hydrolysestabilisatoren
US7125950B2 (en) 2003-04-30 2006-10-24 Board Of Trustees Of Michigan State University Polyol fatty acid polyesters process and polyurethanes therefrom
JP2005082642A (ja) 2003-09-05 2005-03-31 Nisshinbo Ind Inc エステル基を有する樹脂用の耐加水分解安定剤及び熱可塑性樹脂組成物
JP4643154B2 (ja) * 2004-02-17 2011-03-02 ユニチカ株式会社 熱可塑性樹脂組成物、およびそれを成形してなる成形体。
US7989647B2 (en) 2005-03-03 2011-08-02 South Dakota Soybean Processors, Llc Polyols derived from a vegetable oil using an oxidation process
US7566406B2 (en) 2005-05-05 2009-07-28 L&P Property Management Company Bonded foam product manufactured with vegetable oil polyol and method for manufacturing
JP2008031197A (ja) * 2006-07-26 2008-02-14 Nippon Polyurethane Ind Co Ltd 中空糸膜モジュールに用いられるシール材用ポリウレタン樹脂形成性組成物、及び該組成物を用いた中空糸膜モジュール用シール材
WO2010021920A1 (en) * 2008-08-20 2010-02-25 Rhein Chemie Corporation Polyol compositions

Also Published As

Publication number Publication date
US20140323754A1 (en) 2014-10-30
TR201802217T4 (tr) 2018-03-21
EP2388284A1 (de) 2011-11-23
JP2013526643A (ja) 2013-06-24
EP2571915B1 (de) 2017-11-22
EP2571915A1 (de) 2013-03-27
WO2011144717A1 (de) 2011-11-24
JP5604587B2 (ja) 2014-10-08
KR20130040918A (ko) 2013-04-24
TWI537239B (zh) 2016-06-11
TW201209022A (en) 2012-03-01
ES2658180T3 (es) 2018-03-08
CN102947363A (zh) 2013-02-27
KR101451496B1 (ko) 2014-10-15
US9452975B2 (en) 2016-09-27
CN102947363B (zh) 2015-02-11
US20130274506A1 (en) 2013-10-17
PT2571915T (pt) 2018-02-07

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