AR078634A1 - Procedimiento para la preparacion de un polimero organico de silicio foto-protector progresivo; polimero obtenido; su uso para la preparacion de composiciones y como precursor fotoquimico de los absorbentes uv; com-posicion cosmetica o dermatologica que comprende dicho polimero; proce-dimiento para - Google Patents
Procedimiento para la preparacion de un polimero organico de silicio foto-protector progresivo; polimero obtenido; su uso para la preparacion de composiciones y como precursor fotoquimico de los absorbentes uv; com-posicion cosmetica o dermatologica que comprende dicho polimero; proce-dimiento paraInfo
- Publication number
- AR078634A1 AR078634A1 ARP100103750A ARP100103750A AR078634A1 AR 078634 A1 AR078634 A1 AR 078634A1 AR P100103750 A ARP100103750 A AR P100103750A AR P100103750 A ARP100103750 A AR P100103750A AR 078634 A1 AR078634 A1 AR 078634A1
- Authority
- AR
- Argentina
- Prior art keywords
- branched
- linear
- alkyl
- cycloalkyl
- preparation
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title abstract 2
- 239000002537 cosmetic Substances 0.000 title abstract 2
- 229920000620 organic polymer Polymers 0.000 title abstract 2
- 230000000750 progressive effect Effects 0.000 title abstract 2
- 229910052710 silicon Inorganic materials 0.000 title abstract 2
- 239000010703 silicon Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 2
- 239000002250 absorbent Substances 0.000 title 1
- 239000002243 precursor Substances 0.000 title 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 22
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 22
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 abstract 12
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 8
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract 4
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 4
- -1 COOR10 Chemical group 0.000 abstract 1
- 101100516568 Caenorhabditis elegans nhr-7 gene Proteins 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 abstract 1
- 229910006074 SO2NH2 Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 abstract 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920001558 organosilicon polymer Polymers 0.000 abstract 1
- 230000003711 photoprotective effect Effects 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 125000000565 sulfonamide group Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/16—Emollients or protectives, e.g. against radiation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Polymers & Plastics (AREA)
- Dermatology (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Toxicology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Cosmetics (AREA)
- Silicon Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La presente solicitud se refiere a polímeros orgánicos de silicio que contienen ésteres del ácido benzoico en forma de partículas, el procedimiento para su preparacion, las composiciones cosméticas o dermatologicas que los contienen, así como su uso para proteger a los seres humanos o animales de la radiacion UV. Reivindicacion 1: Procedimiento para la preparacion de un polímero orgánico de silicio fotoprotector progresivo, caracterizado porque comprende la reaccion de un monomero de formula (1) donde R se selecciona del grupo que consiste en formulas (2) a (5), R1, R2, R3, R4 y R5 se seleccionan independientemente del grupo que consiste en H, alquilo C1-6 lineal o ramificado, cicloalquilo C3-6, OR6, NH2, NHR7, NR8R9, COOH, COOR10, CONH2, CONHR11, CONR12R13, SO2NH2, SO2NHR14 y SO2NR15R16; R6 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R7 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R8 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R9 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6;o R8 y R9 tomados conjuntamente con el átomo de nitrogeno al cual están unidos forman un anillo de pirrolidina, piperidina o morfolina; R10 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R11 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R12 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R13 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6;o R12 y R13 tomados conjuntamente con el átomo de nitrogeno al cual están unidos forman un anillo de pirrolidina, piperidina o morfolina; R14 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R15 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R16 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6, o R15 y R16 tomados conjuntamente con el átomo de nitrogeno al cual están unidos forman un anillo de pirrolidina, piperidina o morfolina; A es H, alquilo C1-6 lineal o ramificado o cicloalquilo C3-6, OR'1, NH2, NHR'2 o NR'3R'4; L es un enlace sencillo, -CH2-, o -CH2-CH(RL)-; Z es NH o O; Ra es alquilo C1-6 lineal o ramificado, alquenilo C2-6 lineal o ramificado, cicloalquilo C3-6 o fenilo; Rb es alquilo C1-6 lineal o ramificado, alquenilo C2-6 lineal o ramificado, cicloalquilo C3-6 o fenilo; Rc es alquilo C1-6 lineal o ramificado, alquenilo C2-6 lineal o ramificado, cicloalquilo C3-6 o fenilo; R'1 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R'2 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R'3 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; R'4 es alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; o R'3 y R'4 tomados conjuntamente con el átomo de nitrogeno al cual están unidos forman un anillo de pirrolidina, piperidina o morfolina; RL es H, alquilo C1-6 lineal o ramificado o cicloalquilo C3-6; n es un numero entero seleccionado entre 0 y 1; p es un numero entero seleccionado entre 2, 3 y 4; s es un numero entero seleccionado entre 0 y 1; t es un numero entero seleccionado entre 0 y 1; con un compuesto de formula (6) donde Rd es un alquilo C1-6 lineal o ramificado; Re, Rf y Rg son independientemente un alquilo C1-6 lineal o ramificado, alquenilo C2-6 lineal o ramificado, cicloalquilo C3-6 o fenilo, W1 y W2 son independientemente 0 o 1, en una mezcla de alcanol/agua, donde el alcanol es un alcanol lineal o ramificado C1-6.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09173122A EP2311844A1 (en) | 2009-10-15 | 2009-10-15 | Silyl polymeric benzoic acid ester compounds, uses, and compositions thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR078634A1 true AR078634A1 (es) | 2011-11-23 |
Family
ID=41610003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP100103750A AR078634A1 (es) | 2009-10-15 | 2010-10-14 | Procedimiento para la preparacion de un polimero organico de silicio foto-protector progresivo; polimero obtenido; su uso para la preparacion de composiciones y como precursor fotoquimico de los absorbentes uv; com-posicion cosmetica o dermatologica que comprende dicho polimero; proce-dimiento para |
Country Status (24)
| Country | Link |
|---|---|
| US (3) | US8945522B2 (es) |
| EP (2) | EP2311844A1 (es) |
| JP (2) | JP5758394B2 (es) |
| KR (1) | KR101754340B1 (es) |
| CN (2) | CN102639543B (es) |
| AR (1) | AR078634A1 (es) |
| AU (1) | AU2010305776B2 (es) |
| BR (1) | BR112012008761B1 (es) |
| CA (1) | CA2777418C (es) |
| CL (1) | CL2012000923A1 (es) |
| CY (1) | CY1116781T1 (es) |
| DK (1) | DK2488537T3 (es) |
| ES (1) | ES2549915T3 (es) |
| HK (2) | HK1173155A1 (es) |
| HU (1) | HUE025422T2 (es) |
| MX (1) | MX2012004364A (es) |
| PE (1) | PE20121355A1 (es) |
| PL (1) | PL2488537T3 (es) |
| PT (1) | PT2488537E (es) |
| RU (1) | RU2550029C9 (es) |
| SI (1) | SI2488537T1 (es) |
| TW (2) | TWI602826B (es) |
| UY (1) | UY32944A (es) |
| WO (1) | WO2011045389A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2551085T3 (es) | 2009-03-23 | 2015-11-16 | Glenmark Pharmaceuticals S.A. | Proceso para preparar derivados de pirimidina-diona condensados, útiles como moduladores de TRPA1 |
| KR101541848B1 (ko) | 2012-11-12 | 2015-08-13 | 현대모비스 주식회사 | 인휠 모터 시스템 |
| AR100211A1 (es) * | 2014-05-19 | 2016-09-21 | Interquim Sa | Procedimiento para la preparación de un polímero fotoprotector progresivo de organosilicio; polímero fotoprotector progresivo de organosilicio, su uso, composición que lo comprende, monómero precursor, procedimientos para la preparación de dicho monómero precursor |
| DE102015211793A1 (de) | 2015-06-25 | 2016-12-29 | Beiersdorf Ag | Alkandiol-haltige Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxydibenzoylmethan |
| DE102015211792A1 (de) | 2015-06-25 | 2016-12-29 | Beiersdorf Ag | Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxydibenzoylmethan |
| DE102015211790A1 (de) | 2015-06-25 | 2016-12-29 | Beiersdorf Ag | Ethanolisches Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxydibenzoylmethan |
| DE102015216959A1 (de) | 2015-09-04 | 2017-03-09 | Beiersdorf Ag | Parfümiertes Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxydibenzoylmethan |
| DE102015225570A1 (de) | 2015-12-17 | 2017-06-22 | Beiersdorf Ag | Allerneustes Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxy-di-ben-zoylmethan |
| DE102015225568A1 (de) | 2015-12-17 | 2017-06-22 | Beiersdorf Ag | Neustes Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxydibenzoylmethan |
| DE102015225567A1 (de) | 2015-12-17 | 2017-06-22 | Beiersdorf Ag | Neues Sonnenschutzmittel mit Ausgangsstoff für die Bildung von 4-(tert.-Butyl)-4'-methoxydibenzoylmethan |
| DE102016000800A1 (de) | 2016-01-27 | 2017-07-27 | Beiersdorf Ag | Sonnenschutzmittel mit Tricyclodecanmethylisononanoat |
| KR101881815B1 (ko) * | 2016-02-03 | 2018-08-24 | 한국생산기술연구원 | 알콕시실릴기 및 활성 에스테르기를 갖는 화합물, 이의 제조방법, 이를 포함하는 조성물 및 용도 |
| DE102019203077A1 (de) * | 2019-03-06 | 2020-09-10 | Henkel Ag & Co. Kgaa | Verfahren zur Herstellung von Haarbehandlungsmitteln mit organischen C1-C6-Alkoxy-Silanen |
| DE102019203074A1 (de) * | 2019-03-06 | 2020-09-10 | Henkel Ag & Co. Kgaa | Verfahren zur Herstellung von Haarbehandlungsmitteln mit organischen C1-C6-Alkoxy-Silanen |
| WO2023079046A1 (en) * | 2021-11-05 | 2023-05-11 | Fundació Eurecat | Compounds as sun protection agents |
| GB2623090A (en) | 2022-10-04 | 2024-04-10 | Sublino Ltd | Method of colouring |
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| US4328346A (en) | 1980-08-01 | 1982-05-04 | General Electric Company | Silane-functionalized ultraviolet screen precursors |
| US4372835A (en) * | 1980-08-01 | 1983-02-08 | General Electric Co. | Silane-functionalized ultraviolet screen precursors |
| US4495360A (en) * | 1982-04-30 | 1985-01-22 | General Electric Company | Ultraviolet light absorbing agents, method for making, compositions and articles containing same |
| KR840000980B1 (ko) | 1982-09-16 | 1984-07-02 | 손순식 | 다접점 조명등의 점멸 스위치 |
| JPS6377940A (ja) * | 1986-09-19 | 1988-04-08 | Toshiba Silicone Co Ltd | 真球状ポリメチルシルセスキオキサン粉末およびその製造方法 |
| FR2636338B1 (fr) | 1988-09-09 | 1990-11-23 | Rhone Poulenc Chimie | Diorganopolysiloxane a fonction benzalmalonate |
| FR2642968B1 (fr) | 1989-02-15 | 1991-06-07 | Oreal | Utilisation en cosmetique de diorganopolysiloxanes a fonction benzotriazole et nouvelles compositions cosmetiques contenant ces composes, destinees a la protection de la peau et des cheveux |
| US5252628A (en) | 1989-12-07 | 1993-10-12 | Lions Eye Institute Of Western Australia, Inc. | Method of making photoprotective hydrophilic polymers and ocular devices thereof |
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| JPH0827273A (ja) * | 1994-07-12 | 1996-01-30 | Toshiba Silicone Co Ltd | 紫外線吸収性シリコーン樹脂粉体の製造方法 |
| FR2727114B1 (fr) * | 1994-11-17 | 1996-12-27 | Oreal | Nouveaux filtres solaires, compositions cosmetiques photoprotectrices les contenant et utilisations |
| FR2746397B1 (fr) * | 1996-03-22 | 1998-04-30 | Oreal | Nouveaux derives silicies de l'acide salicylique a proprietes desquamantes |
| US6274133B1 (en) | 1998-12-22 | 2001-08-14 | Bausch & Lomb Incorporated | Method for treating extended-wear contact lenses in the eyes |
| JP2002275416A (ja) * | 2001-03-16 | 2002-09-25 | Sumitomo Metal Mining Co Ltd | 紫外線遮蔽膜形成用塗布液と紫外線遮蔽膜およびこの紫外線遮蔽膜を有する積層体 |
| ATE544493T1 (de) | 2003-12-04 | 2012-02-15 | Dsm Ip Assets Bv | Mikrokapseln mit uv-filter-wirkung udn verfahren zu ihrer herstellung |
| KR100596740B1 (ko) * | 2004-04-30 | 2006-07-12 | 주식회사 사임당화장품 | 자외선 흡수기를 가진 폴리실세스퀴옥산 구형 입자 및 그제조방법 |
| US20080260664A1 (en) | 2004-06-08 | 2008-10-23 | Thomas Walenzyk | Particles Functionalized with Organic Compounds |
| EP1707558A1 (en) * | 2005-03-21 | 2006-10-04 | Ferrer Internacional, S.A. | Benzoic acid ester compounds, compositions, uses and methods related thereto |
| JP2009138015A (ja) * | 2007-12-03 | 2009-06-25 | Nikko Rika Kk | かご状シルセスキオキサンおよびその製造方法、シリコーン粒子およびその製造方法 |
| WO2009101016A2 (de) | 2008-02-12 | 2009-08-20 | Basf Se | Modifizierte hybride nanopartikel |
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