AR050590A1 - Metodos para fabricar catalizadores, catalizadores obtenidos, usos de los mismos, e intermediario - Google Patents
Metodos para fabricar catalizadores, catalizadores obtenidos, usos de los mismos, e intermediarioInfo
- Publication number
- AR050590A1 AR050590A1 ARP050101889A ARP050101889A AR050590A1 AR 050590 A1 AR050590 A1 AR 050590A1 AR P050101889 A ARP050101889 A AR P050101889A AR P050101889 A ARP050101889 A AR P050101889A AR 050590 A1 AR050590 A1 AR 050590A1
- Authority
- AR
- Argentina
- Prior art keywords
- cobalt
- phase
- solution
- hydrotalcite
- iii
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 12
- 239000010941 cobalt Substances 0.000 abstract 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 12
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 abstract 6
- 229910001701 hydrotalcite Inorganic materials 0.000 abstract 6
- 229960001545 hydrotalcite Drugs 0.000 abstract 6
- 229910052596 spinel Inorganic materials 0.000 abstract 6
- 239000011029 spinel Substances 0.000 abstract 6
- 150000001869 cobalt compounds Chemical class 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- UCFZBOCMNGFLQX-UHFFFAOYSA-N [Co]N Chemical compound [Co]N UCFZBOCMNGFLQX-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/15—X-ray diffraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/007—Mixed salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un método de fabricar un catalizador de cobalto, que comprende los pasos de formar una solucion acuosa de un complejo amino-cobalto, oxidar dicha solucion de manera tal que la concentracion de Co(III) en la solucion oxidada sea mayor que la concentracion de Co(III) en la solucion no oxidada, y luego descomponer el complejo amino-cobalto por calentamiento de la solucion a una temperatura entre 80 y 110sC durante tiempo suficiente para permitir que un compuesto insoluble de cobalto precipite a partir de la solucion. También se describen un intermediario de catalizador que comprende un compuesto de cobalto que tiene una fase de hidrotalcita Co (II)/Co (III) y una fase de espinela de cobalto Co3O4, donde la relacion de fase de hidrotalcita de cobalto:fase de espinela de cobalto es menor que 0,6:1, siendo dicha fase de hidrotalcita de cobalto y dicha fase de espinela de cobalto medidas por difractrometría de rayos X. Reivindicacion 23: Un método como se reivindica en cualquiera de las reivindicaciones 1 a 22, caracterizado porque comprende además el paso de reducir los compuestos de cobalto a cobalto metálico en una corriente de un gas con contenido de hidrogeno a una temperatura en el rango de 250- 600sC. Reivindicacion 25: El uso de un catalizador como se reivindica en la reivindicacion 24 caracterizado porque es para la síntesis de hidrocarburos a partir de un gas de síntesis que comprende hidrogeno y monoxido de carbono. Reivindicacion 27: Un intermediario de catalizador caracterizado porque comprende un compuesto de cobalto, donde dicho compuesto de cobalto comprende una fase de hidrotalcita Co (II)/Co (III) y una fase de espinela de cobalto Co3O4, donde la relacion de fase de hidrotalcita de cobalto:fase de espinela de cobalto es menor que 0,6:1, siendo dicha fase de hidrotalcita de cobalto y dicha fase de espinela de cobalto medidas por difractometría de rayos X.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0410408.9A GB0410408D0 (en) | 2004-05-11 | 2004-05-11 | Catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR050590A1 true AR050590A1 (es) | 2006-11-08 |
Family
ID=32526766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP050101889A AR050590A1 (es) | 2004-05-11 | 2005-05-10 | Metodos para fabricar catalizadores, catalizadores obtenidos, usos de los mismos, e intermediario |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7655593B2 (es) |
| EP (1) | EP1744829B1 (es) |
| JP (1) | JP4980891B2 (es) |
| CN (1) | CN1950144B (es) |
| AR (1) | AR050590A1 (es) |
| AU (1) | AU2005240405B2 (es) |
| CA (1) | CA2564702C (es) |
| DK (1) | DK1744829T3 (es) |
| EA (1) | EA009254B1 (es) |
| GB (1) | GB0410408D0 (es) |
| IN (1) | IN2012DN01680A (es) |
| MY (1) | MY143504A (es) |
| WO (1) | WO2005107942A1 (es) |
| ZA (1) | ZA200608781B (es) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0426473D0 (en) * | 2004-12-03 | 2005-01-05 | Johnson Matthey Plc | Catalysts |
| GB0501783D0 (en) * | 2005-01-28 | 2005-03-09 | Johnson Matthey Plc | Catalysts and preparation method |
| EP2097167A2 (en) * | 2006-12-12 | 2009-09-09 | Shell Internationale Research Maatschappij B.V. | Process for preparing a catalyst |
| GB0704003D0 (en) * | 2007-03-01 | 2007-04-11 | Oxford Catalysts | Promoted carbide-based fischer-tropsch catalyst, method for its preparation and uses thereof |
| WO2009154753A2 (en) * | 2008-06-18 | 2009-12-23 | Massachusetts Institute Of Technology | Catalytic materials, electrodes, and systems for water electrolysis and other electrochemical techniques |
| US7608744B1 (en) * | 2008-07-31 | 2009-10-27 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
| GB0819849D0 (en) * | 2008-10-30 | 2008-12-03 | Johnson Matthey Plc | Cobalt catalyst precursor |
| GB0819847D0 (en) * | 2008-10-30 | 2008-12-03 | Johnson Matthey Plc | Cobalt catalysts |
| JP5795483B2 (ja) * | 2011-03-31 | 2015-10-14 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 活性化されたフィッシャー・トロプシュ合成反応用触媒および炭化水素の製造方法 |
| RU2458736C1 (ru) * | 2011-05-10 | 2012-08-20 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор и способ получения углеводородов из монооксида углерода и водорода (варианты) |
| RU2612498C2 (ru) * | 2011-11-21 | 2017-03-09 | Релайанс Индастриз Лтд. | Каталитическая композиция для дегидрирования углеводородов и способ ее получения |
| JP5698851B2 (ja) * | 2012-09-21 | 2015-04-08 | Ｊｘ日鉱日石エネルギー株式会社 | フィッシャー・トロプシュ合成用触媒及びその製造方法、並びに炭化水素の製造方法 |
| BR112017012496B1 (pt) * | 2014-12-12 | 2022-05-17 | Bp P.L.C. | Processo para a conversão de uma alimentação compreendendo uma mistura de hidrogênio e monóxido de carbono de hidrocarbonetos, uso de um catalisador e catalisador de fischer-tropsch |
| EP3368215A4 (en) * | 2015-10-27 | 2019-06-26 | W.R. Grace & Co.-Conn. | ACID-RESISTANT CATALYST SUPPLEMENTS AND CATALYSTS |
| WO2017131232A1 (ja) * | 2016-01-29 | 2017-08-03 | Ｊｘエネルギー株式会社 | フィッシャー・トロプシュ合成用触媒、フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法 |
| CN110636901A (zh) * | 2017-05-17 | 2019-12-31 | 巴斯夫公司 | 底部残留物改质和低焦炭流化催化裂化催化剂 |
| CN108517537B (zh) * | 2018-04-11 | 2019-05-24 | 北京化工大学 | 一种氮掺杂碳负载双尺度过渡金属磷化物及其制备方法和应用 |
| US11376567B2 (en) * | 2019-12-05 | 2022-07-05 | GM Global Technology Operations LLC | Methods for preparing catalytic systems |
| CN113457708B (zh) * | 2021-06-30 | 2023-10-20 | 常州大学 | CoN@C多孔材料及其制备方法以及在芳香族腈类化合物的合成中的应用 |
| WO2023173352A1 (zh) * | 2022-03-17 | 2023-09-21 | 无锡东恒新能源科技有限公司 | 一种催化裂解甲醇或丙烯制备碳纳米管的方法 |
| IL303685B1 (en) * | 2023-06-13 | 2024-10-01 | Electriq Global Energy Solutions Ltd | Ceramic catalyst, a method for its preparation and its uses |
| CN117756190B (zh) * | 2023-12-13 | 2024-07-09 | 江苏海洋大学 | 一种利用废旧锂离子电池制备钴催化剂并用于电催化升级pet的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3235515A (en) | 1962-04-27 | 1966-02-15 | Chemetron Corp | Method of preparing a hydrogenation catalyst composition consisting of the oxides of zirconium and an iron group metal |
| US4029601A (en) * | 1975-04-29 | 1977-06-14 | Exxon Research And Engineering Company | Novel oligomerization catalysts and their preparation |
| JPH0576758A (ja) * | 1991-06-25 | 1993-03-30 | Tonen Corp | 水素化処理用触媒 |
| GB9415554D0 (en) * | 1994-08-02 | 1994-09-21 | Unilever Plc | Cobalt on alumina catalysts |
| EA005420B1 (ru) * | 2000-05-19 | 2005-02-24 | Джонсон Мэтти Плс | Катализаторы с большой площадью поверхности кобальта |
| US7452844B2 (en) * | 2001-05-08 | 2008-11-18 | Süd-Chemie Inc | High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis |
| GB0222240D0 (en) * | 2002-09-25 | 2002-10-30 | Ici Plc | Cobalt catalysts |
-
2004
- 2004-05-11 GB GBGB0410408.9A patent/GB0410408D0/en not_active Ceased
-
2005
- 2005-05-10 WO PCT/GB2005/001780 patent/WO2005107942A1/en active Application Filing
- 2005-05-10 AU AU2005240405A patent/AU2005240405B2/en not_active Ceased
- 2005-05-10 CA CA2564702A patent/CA2564702C/en not_active Expired - Fee Related
- 2005-05-10 EP EP05741963.2A patent/EP1744829B1/en active Active
- 2005-05-10 IN IN1680DEN2012 patent/IN2012DN01680A/en unknown
- 2005-05-10 MY MYPI20052106A patent/MY143504A/en unknown
- 2005-05-10 DK DK05741963.2T patent/DK1744829T3/en active
- 2005-05-10 JP JP2007512331A patent/JP4980891B2/ja not_active Expired - Fee Related
- 2005-05-10 AR ARP050101889A patent/AR050590A1/es unknown
- 2005-05-10 EA EA200602089A patent/EA009254B1/ru not_active IP Right Cessation
- 2005-05-10 CN CN2005800150046A patent/CN1950144B/zh not_active Expired - Fee Related
- 2005-05-10 US US11/579,894 patent/US7655593B2/en active Active
-
2006
- 2006-10-20 ZA ZA200608781A patent/ZA200608781B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200608781B (en) | 2008-10-29 |
| JP4980891B2 (ja) | 2012-07-18 |
| US7655593B2 (en) | 2010-02-02 |
| DK1744829T3 (en) | 2018-03-05 |
| US20080139381A1 (en) | 2008-06-12 |
| EA009254B1 (ru) | 2007-12-28 |
| CN1950144B (zh) | 2010-05-05 |
| WO2005107942A1 (en) | 2005-11-17 |
| MY143504A (en) | 2011-05-31 |
| JP2007537035A (ja) | 2007-12-20 |
| IN2012DN01680A (es) | 2015-06-05 |
| GB0410408D0 (en) | 2004-06-16 |
| CA2564702C (en) | 2012-06-26 |
| CA2564702A1 (en) | 2005-11-17 |
| AU2005240405A1 (en) | 2005-11-17 |
| EA200602089A1 (ru) | 2007-04-27 |
| CN1950144A (zh) | 2007-04-18 |
| EP1744829B1 (en) | 2017-12-13 |
| EP1744829A1 (en) | 2007-01-24 |
| AU2005240405B2 (en) | 2010-06-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |