AR042466A1 - Proceso de preparacion de alfa - olefinas lineales a partir de gas de sintesis derivado de gas natural sobre un catalizador cobalto no desplazante - Google Patents
Proceso de preparacion de alfa - olefinas lineales a partir de gas de sintesis derivado de gas natural sobre un catalizador cobalto no desplazanteInfo
- Publication number
- AR042466A1 AR042466A1 ARP030104628A ARP030104628A AR042466A1 AR 042466 A1 AR042466 A1 AR 042466A1 AR P030104628 A ARP030104628 A AR P030104628A AR P030104628 A ARP030104628 A AR P030104628A AR 042466 A1 AR042466 A1 AR 042466A1
- Authority
- AR
- Argentina
- Prior art keywords
- synthesis
- reactor
- synthesis gas
- linear alpha
- olefins
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0455—Reaction conditions
- C07C1/046—Numerical values of parameters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0485—Set-up of reactors or accessories; Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
- C07C27/06—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds by hydrogenation of oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Lubricants (AREA)
Abstract
Este proceso puede ser integrado en un proceso convencional de síntesis de hidrocarburos según Fischer-Tropsch que produce combustibles y aceites lubricantes. Reivindicación 1: Un proceso parea la conversión de gases, para producir alfa-olefinas lineales que tienen de cuatro a veinte átomos de carbono, que comprende hacer pasar un gas de síntesis que comprende una mezcla de H2 y CO producidos a partir de gas natural, al interior de un reactor de síntesis de alfa-olefinas lineales, en el cual dichos H2 y CO reaccionan entre sí en presencia de un catalizador no desplazante para la síntesis de hidrocarburos según Fischer-Tropsch que comprende un componente catalítico cobalto, bajo condiciones de reacción definidas por un Factor de Conversión (FC) superior o igual a 50, de manera de producir hidrocarburos, que incluyen una fracción de hidrocarburos C4-20 que comprende dichas alfa-olefinas lineales, estando dicho factor de condición definido como sigue: FC=200-0,6T + 0,03PH2O-0,6Xco-8(H2:CO) en la cual expresión: T = temperatura promedia en el reactor, en sC; PH2O: presión parcial del agua en el gas de síntesis introducido en el reactor, en kPa; Xco0 conversión de CO, expresada en forma porcentual; y H2:CO = relación molar entre el H2 y el CO en el gas de síntesis introducido en el reactor de las alfa-olefinas lineales
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/330,860 US6787576B2 (en) | 2002-12-27 | 2002-12-27 | Linear alpha olefins from natural gas-derived synthesis gas over a nonshifting cobalt catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
AR042466A1 true AR042466A1 (es) | 2005-06-22 |
Family
ID=32654607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP030104628A AR042466A1 (es) | 2002-12-27 | 2003-12-15 | Proceso de preparacion de alfa - olefinas lineales a partir de gas de sintesis derivado de gas natural sobre un catalizador cobalto no desplazante |
Country Status (14)
Country | Link |
---|---|
US (1) | US6787576B2 (es) |
EP (1) | EP1575883A1 (es) |
JP (1) | JP2006512393A (es) |
KR (1) | KR20050088481A (es) |
CN (1) | CN1732137A (es) |
AR (1) | AR042466A1 (es) |
AU (1) | AU2003295625B2 (es) |
BR (1) | BR0316839A (es) |
CA (1) | CA2507722A1 (es) |
MY (1) | MY127796A (es) |
NO (1) | NO20053633L (es) |
TW (1) | TWI296614B (es) |
WO (1) | WO2004060836A1 (es) |
ZA (1) | ZA200505106B (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7914764B2 (en) * | 2003-02-28 | 2011-03-29 | Exxonmobil Research And Engineering Company | Hydrogen manufacture using pressure swing reforming |
US7361619B2 (en) | 2003-04-11 | 2008-04-22 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
US7875402B2 (en) * | 2005-02-23 | 2011-01-25 | Exxonmobil Research And Engineering Company | Proton conducting solid oxide fuel cell systems having temperature swing reforming |
US7799314B2 (en) * | 2005-09-09 | 2010-09-21 | Exxonmobil Research And Engineering Company | Hydrogen production and use in an internal combustion engine system |
DE102005056784A1 (de) * | 2005-11-28 | 2007-05-31 | Basf Ag | Verfahren zur Herstellung von Olefinen aus Synthesegas in einer Reaktionskolonne |
US7815873B2 (en) * | 2006-12-15 | 2010-10-19 | Exxonmobil Research And Engineering Company | Controlled combustion for regenerative reactors with mixer/flow distributor |
WO2011054735A1 (de) | 2009-11-06 | 2011-05-12 | Basf Se | Eisen- und kupferhaltiger heterogenkatalysator und verfahren zur herstellung von olefinen durch umsetzung von kohlenmonoxid mit wasserstoff |
CN102711991B (zh) | 2009-11-06 | 2015-01-21 | 巴斯夫欧洲公司 | 含铁和锰的非均相催化剂和通过一氧化碳与氢气反应而制备烯烃的方法 |
CN102639234B (zh) | 2009-11-06 | 2014-07-30 | 巴斯夫欧洲公司 | 含铁的多相催化剂和通过用氢气转化一氧化碳制备烯烃的方法 |
EP3027553A2 (en) | 2013-07-31 | 2016-06-08 | Saudi Basic Industries Corporation | A process for the production of olefins through fischer-tropsch based synthesis |
CN105518111A (zh) | 2013-07-31 | 2016-04-20 | 沙特基础工业公司 | 通过基于费-托的合成产生烯烃的方法 |
CN104560191B (zh) * | 2013-10-28 | 2017-03-22 | 中国石油化工股份有限公司 | 低黏度润滑油基础油的制备方法 |
WO2016181266A1 (en) * | 2015-05-08 | 2016-11-17 | Sabic Global Technologies B.V. | Systems and methods related to syngas to olefin production |
CN106582698B (zh) * | 2015-10-20 | 2019-05-21 | 中国石油化工股份有限公司 | 一种负载型催化剂及其制备方法和应用以及由合成气制备α-烯烃的方法 |
WO2017093859A1 (en) * | 2015-12-02 | 2017-06-08 | Sabic Global Technologies B.V. | A two-step process of co2 assisted oxidative conversion of methane to syngas and methane assisted conversion of syngas to hydrocarbons |
CN109534939B (zh) * | 2018-11-12 | 2021-03-23 | 陕西师范大学 | 一种Co基催化剂催化合成气直接一步高选择性制α-烯烃的方法 |
KR102653716B1 (ko) * | 2020-03-03 | 2024-04-03 | 한국화학연구원 | 이산화탄소가 포함된 합성가스로부터 선형 알파 올레핀을 제조하기 위한 촉매 및 이를 이용한 선형 알파 올레핀의 제조방법 |
US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
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US4048250A (en) | 1975-04-08 | 1977-09-13 | Mobil Oil Corporation | Conversion of natural gas to gasoline and LPG |
US4279830A (en) | 1977-08-22 | 1981-07-21 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors |
NL7712952A (en) | 1977-11-24 | 1979-05-28 | Shell Int Research | Ethylene prodn. from carbon mon:oxide and hydrogen - by catalytic reaction of the feed stream and pyrolysis of the gaseous reaction prod. |
US4418155A (en) * | 1980-03-24 | 1983-11-29 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbons enriched in linear alpha-olefins |
DE3130988A1 (de) * | 1981-08-05 | 1983-02-24 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Katalysator und verfahren zur herstellung von olefinen - insbesondere linearen (alpha)-olefinen - aus synthesegas |
CA1196617A (en) | 1982-07-14 | 1985-11-12 | George E. Morris | Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas |
US4532229A (en) | 1983-12-14 | 1985-07-30 | Exxon Research And Engineering Co. | Process for preparing a Fe-Co catalyst slurry system for alpha olefin production |
US4544674A (en) | 1983-12-14 | 1985-10-01 | Exxon Research And Engineering Co. | Cobalt-promoted fischer-tropsch catalysts |
US4584323A (en) | 1983-12-14 | 1986-04-22 | Exxon Research And Engineering Co. | Fischer-Tropsch hydrocarbon synthesis with copper promoted iron/cobalt spinel catalyst |
US5118715A (en) | 1983-12-20 | 1992-06-02 | Exxon Research And Engineering Company | Selective fixed-bed fischer-tropsch synthesis with high surface area Cu and K promoted, iron/manganese spinels |
NL8401253A (nl) | 1984-04-18 | 1985-11-18 | Shell Int Research | Werkwijze voor de bereiding van koolwaterstoffen. |
US4579986A (en) | 1984-04-18 | 1986-04-01 | Shell Oil Company | Process for the preparation of hydrocarbons |
US4579830A (en) * | 1984-06-27 | 1986-04-01 | Union Carbide Corporation | Enhanced catalyst for converting synthesis gas to liquid motor fuels |
JPS6118433A (ja) | 1984-07-04 | 1986-01-27 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
GB2169614A (en) | 1984-12-31 | 1986-07-16 | Mobil Oil Corp | Producing alpha-olefins and their conversion into lubricants |
US4639431A (en) | 1985-07-11 | 1987-01-27 | Exxon Research And Engineering Company | Catalysts in Fischer-Tropsch process for producing olefins |
US6319960B1 (en) | 1986-10-03 | 2001-11-20 | Exxon Research & Engineering Company | Method for hydrocarbon synthesis reactions |
US5545674A (en) * | 1987-05-07 | 1996-08-13 | Exxon Research And Engineering Company | Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts |
US4874732A (en) * | 1987-07-13 | 1989-10-17 | Uop | Cobalt Fischer-Tropsch catalysts having improved selectivity |
US4801573A (en) * | 1987-10-23 | 1989-01-31 | 501 Den Norske Stats Oljeslenskap A.S. | Catalyst for production of hydrocarbons |
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US5100856A (en) | 1990-10-01 | 1992-03-31 | Exxon Research And Engineering Company | Iron-zinc based catalysts for the conversion of synthesis gas to alpha-olefins |
US5210060A (en) | 1991-07-30 | 1993-05-11 | Amoco Corporation | Catalyst for converting synthesis gas to paraffin wax |
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US5877378A (en) | 1995-06-14 | 1999-03-02 | Amoco Corporation | Process for selective utilization of alpha-olefins in mixtures containing non-alpha-olefins |
EG21174A (en) | 1996-04-16 | 2000-12-31 | Procter & Gamble | Surfactant manufacture |
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DE19825295B4 (de) | 1998-06-05 | 2006-10-26 | Linde Ag | Verfahren zur Gewinnung von hochreinen Alpha--Olefinen und Vorrichtung zu dessen Durchführung |
DE19833941B4 (de) | 1998-07-28 | 2006-11-02 | Linde Ag | Verfahren und Destillationsvorrichtung zur Gewinnung von 1-Okten |
GC0000088A (en) * | 1999-02-15 | 2004-06-30 | Shell Int Research | Process for the preparation of hydrocarbons from carbon monoxide and hydrogen. |
US6355593B1 (en) | 2000-09-01 | 2002-03-12 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst enhancement |
-
2002
- 2002-12-27 US US10/330,860 patent/US6787576B2/en not_active Expired - Lifetime
-
2003
- 2003-11-18 BR BR0316839-5A patent/BR0316839A/pt not_active IP Right Cessation
- 2003-11-18 KR KR1020057012151A patent/KR20050088481A/ko not_active Application Discontinuation
- 2003-11-18 WO PCT/US2003/036896 patent/WO2004060836A1/en active Application Filing
- 2003-11-18 EP EP03786824A patent/EP1575883A1/en not_active Withdrawn
- 2003-11-18 JP JP2004565018A patent/JP2006512393A/ja active Pending
- 2003-11-18 CA CA002507722A patent/CA2507722A1/en not_active Abandoned
- 2003-11-18 CN CNA2003801077903A patent/CN1732137A/zh active Pending
- 2003-11-18 AU AU2003295625A patent/AU2003295625B2/en not_active Ceased
- 2003-11-19 TW TW092132447A patent/TWI296614B/zh not_active IP Right Cessation
- 2003-12-04 MY MYPI20034646A patent/MY127796A/en unknown
- 2003-12-15 AR ARP030104628A patent/AR042466A1/es unknown
-
2005
- 2005-06-23 ZA ZA200505106A patent/ZA200505106B/en unknown
- 2005-07-26 NO NO20053633A patent/NO20053633L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
MY127796A (en) | 2006-12-29 |
TWI296614B (en) | 2008-05-11 |
EP1575883A1 (en) | 2005-09-21 |
KR20050088481A (ko) | 2005-09-06 |
US6787576B2 (en) | 2004-09-07 |
NO20053633L (no) | 2005-08-31 |
CN1732137A (zh) | 2006-02-08 |
BR0316839A (pt) | 2005-10-18 |
CA2507722A1 (en) | 2004-07-22 |
US20040127582A1 (en) | 2004-07-01 |
WO2004060836A1 (en) | 2004-07-22 |
NO20053633D0 (no) | 2005-07-26 |
ZA200505106B (en) | 2006-11-29 |
AU2003295625B2 (en) | 2009-11-26 |
AU2003295625A1 (en) | 2004-07-29 |
JP2006512393A (ja) | 2006-04-13 |
TW200422284A (en) | 2004-11-01 |
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