ZA200303812B - Cross-linked, water-swellable polymer and method for producing the same. - Google Patents
Cross-linked, water-swellable polymer and method for producing the same. Download PDFInfo
- Publication number
- ZA200303812B ZA200303812B ZA200303812A ZA200303812A ZA200303812B ZA 200303812 B ZA200303812 B ZA 200303812B ZA 200303812 A ZA200303812 A ZA 200303812A ZA 200303812 A ZA200303812 A ZA 200303812A ZA 200303812 B ZA200303812 B ZA 200303812B
- Authority
- ZA
- South Africa
- Prior art keywords
- water
- crosslinker
- polymer
- monomers
- meth
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims description 44
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000000178 monomer Substances 0.000 claims description 41
- 239000004971 Cross linker Substances 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- -1 allyl carbonates Chemical class 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- 150000007513 acids Chemical class 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 8
- 150000005846 sugar alcohols Polymers 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- 239000011261 inert gas Substances 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 238000012644 addition polymerization Methods 0.000 claims description 6
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- 238000010008 shearing Methods 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- 125000005336 allyloxy group Chemical group 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical group C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
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- 239000002184 metal Substances 0.000 claims description 3
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
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- 239000000499 gel Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 13
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- 150000001875 compounds Chemical class 0.000 description 8
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- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 8
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- 238000010924 continuous production Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000003505 polymerization initiator Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
- 235000010323 ascorbic acid Nutrition 0.000 description 4
- 229960005070 ascorbic acid Drugs 0.000 description 4
- 239000011668 ascorbic acid Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000012632 extractable Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- IAUGBVWVWDTCJV-UHFFFAOYSA-N 1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CCC(S(O)(=O)=O)NC(=O)C=C IAUGBVWVWDTCJV-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 3
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 2
- HXVJQEGYAYABRY-UHFFFAOYSA-N 1-ethenyl-4,5-dihydroimidazole Chemical class C=CN1CCN=C1 HXVJQEGYAYABRY-UHFFFAOYSA-N 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
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- 230000001590 oxidative effect Effects 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 2
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- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical group CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 1
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
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- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
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- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
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- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
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- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
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- CKSAKVMRQYOFBC-UHFFFAOYSA-N 2-cyanopropan-2-yliminourea Chemical compound N#CC(C)(C)N=NC(N)=O CKSAKVMRQYOFBC-UHFFFAOYSA-N 0.000 description 1
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- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
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- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- RZKYDQNMAUSEDZ-UHFFFAOYSA-N prop-2-enylphosphonic acid Chemical compound OP(O)(=O)CC=C RZKYDQNMAUSEDZ-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
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- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
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- VBOFDBONKAERAE-UHFFFAOYSA-M sodium;sulfenatooxymethanol Chemical compound [Na+].OCOS[O-] VBOFDBONKAERAE-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- RVEZZJVBDQCTEF-UHFFFAOYSA-N sulfenic acid Chemical class SO RVEZZJVBDQCTEF-UHFFFAOYSA-N 0.000 description 1
- SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 description 1
- 229960000909 sulfur hexafluoride Drugs 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- VSJBBIJIXZVVLQ-UHFFFAOYSA-N tert-butyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(C)(C)C VSJBBIJIXZVVLQ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10051940 | 2000-10-19 |
Publications (1)
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|---|---|
| ZA200303812B true ZA200303812B (en) | 2004-08-13 |
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|---|---|---|---|
| ZA200303812A ZA200303812B (en) | 2000-10-19 | 2003-05-16 | Cross-linked, water-swellable polymer and method for producing the same. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7393908B2 (fr) |
| EP (1) | EP1326898B1 (fr) |
| JP (1) | JP4018536B2 (fr) |
| KR (1) | KR100799401B1 (fr) |
| CN (1) | CN1254489C (fr) |
| AT (1) | ATE286915T1 (fr) |
| AU (1) | AU2002210553A1 (fr) |
| BR (1) | BR0114730A (fr) |
| CZ (1) | CZ297784B6 (fr) |
| DE (1) | DE50105082D1 (fr) |
| ES (1) | ES2234902T3 (fr) |
| WO (1) | WO2002032964A2 (fr) |
| ZA (1) | ZA200303812B (fr) |
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| DE10118020A1 (de) * | 2001-04-10 | 2002-10-17 | Stockhausen Chem Fab Gmbh | Löschwasser-Additive |
| DE10225943A1 (de) * | 2002-06-11 | 2004-01-08 | Basf Ag | Verfahren zur Herstellung von Estern von Polyalkoholen |
| CN100349957C (zh) * | 2002-06-11 | 2007-11-21 | 巴斯福股份公司 | 聚烷氧基化三羟甲基丙烷的(甲基)丙烯酸酯 |
| AU2003238476A1 (en) * | 2002-06-11 | 2003-12-22 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated trimethylolpropane |
| DE10358372A1 (de) * | 2003-04-03 | 2004-10-14 | Basf Ag | Gemische von Verbindungen mit mindestens zwei Doppelbindungen und deren Verwendung |
| DE10331456A1 (de) | 2003-07-10 | 2005-02-24 | Basf Ag | (Meth)acrylsäureester alkoxilierter ungesättigter Polyolether und deren Herstellung |
| DE10355401A1 (de) | 2003-11-25 | 2005-06-30 | Basf Ag | (Meth)acrylsäureester ungesättigter Aminoalkohole und deren Herstellung |
| US7629428B2 (en) * | 2004-01-28 | 2009-12-08 | Basf Aktiengesellschaft | Method for producing polymers |
| DE102004015686A1 (de) * | 2004-03-29 | 2005-10-27 | Basf Ag | Quellbare hydrogelbildende Polymere mit hoher Permeabilität |
| DE102004038015A1 (de) * | 2004-08-04 | 2006-03-16 | Basf Ag | Verfahren zur Nachvernetzung wasserabsorbierender Polymere mit zyklischen Carba-maten und/oder zyklischen Harnstoffen |
| JP4560087B2 (ja) * | 2004-09-28 | 2010-10-13 | ビーエーエスエフ ソシエタス・ヨーロピア | 架橋した微粒子状のゲル状ポリマーの製造方法 |
| DE102005002412A1 (de) * | 2005-01-18 | 2006-07-27 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
| DE102005042608A1 (de) * | 2005-09-07 | 2007-03-08 | Basf Ag | Polymerisationsverfahren |
| DE102005042609A1 (de) * | 2005-09-07 | 2007-03-08 | Basf Ag | Polymerisationsverfahren |
| WO2007116778A1 (fr) * | 2006-03-27 | 2007-10-18 | Nippon Shokubai Co., Ltd. | Résine absorbant l'eau dotée d'une structure interne améliorée et procédé de fabrication associé |
| RU2480481C2 (ru) * | 2006-07-19 | 2013-04-27 | Басф Се | Способ получения дополнительно сшитых водопоглощающих полимерных частиц с высоким поглощением путем полимеризации капель мономерного раствора |
| CN101528789B (zh) * | 2006-10-19 | 2010-12-29 | 巴斯夫欧洲公司 | 生产超吸收剂的方法 |
| US20080292692A1 (en) * | 2007-05-21 | 2008-11-27 | Shira Pilch | Impermeable Capsules |
| EP2257574A1 (fr) * | 2008-03-20 | 2010-12-08 | Basf Se | Procédé pour produire des particules polymères hydrophiles ayant une faible capacité de rétention après centrifugation |
| KR200443281Y1 (ko) * | 2008-06-17 | 2009-02-05 | 김진성 | 고흡수성 수지가 충전된 봉제완구 |
| US8535644B2 (en) * | 2008-10-10 | 2013-09-17 | Massachusetts Institute Of Technology | Tunable hydrogel microparticles |
| CN104321136B (zh) * | 2012-05-07 | 2017-02-22 | 巴斯夫欧洲公司 | 一种用于操作混合捏和机的方法 |
| TWI631145B (zh) * | 2014-01-07 | 2018-08-01 | 日本Ｅｘｌａｎ工業股份有限公司 | 乙烯系聚合物粒子及含它之組成物 |
| CN111808578B (zh) * | 2020-07-02 | 2022-10-28 | 中国海洋石油集团有限公司 | 一种强封堵疏水型高性能水基钻井液 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4536554A (en) * | 1984-02-22 | 1985-08-20 | Barnes-Hind, Inc. | Hydrophilic polymers and contact lenses made therefrom |
| DE3537276A1 (de) * | 1985-10-19 | 1987-04-23 | Basf Ag | Verfahren zur kontinuierlichen herstellung von vernetzten feinteiligen gelfoermigen polymerisaten |
| US4742135A (en) * | 1985-12-30 | 1988-05-03 | Exxon Research And Engineering Company | Terpolymers of acrylamide, alkylacrylamide and betaine monomers |
| WO1990015830A1 (fr) * | 1989-06-12 | 1990-12-27 | Weyerhaeuser Company | Polymere hydrocolloidal |
| DE19543368C2 (de) * | 1995-11-21 | 1998-11-26 | Stockhausen Chem Fab Gmbh | Wasserabsorbierende Polymere mit verbesserten Eigenschaften, Verfahren zu deren Herstellung und deren Verwendung |
| DE19646484C2 (de) * | 1995-11-21 | 2000-10-19 | Stockhausen Chem Fab Gmbh | Flüssigkeitsabsorbierende Polymere, Verfahren zu deren Herstellung und deren Verwendung |
| DE19955861A1 (de) | 1999-11-20 | 2001-05-23 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von vernetzten feinteiligen gelförmigen Polymerisaten |
-
2001
- 2001-10-17 BR BR0114730-7A patent/BR0114730A/pt not_active Application Discontinuation
- 2001-10-17 JP JP2002536345A patent/JP4018536B2/ja not_active Expired - Fee Related
- 2001-10-17 KR KR1020037005420A patent/KR100799401B1/ko not_active IP Right Cessation
- 2001-10-17 US US10/399,185 patent/US7393908B2/en not_active Expired - Fee Related
- 2001-10-17 ES ES01978432T patent/ES2234902T3/es not_active Expired - Lifetime
- 2001-10-17 CN CNB018175562A patent/CN1254489C/zh not_active Expired - Fee Related
- 2001-10-17 WO PCT/EP2001/012031 patent/WO2002032964A2/fr active IP Right Grant
- 2001-10-17 EP EP01978432A patent/EP1326898B1/fr not_active Expired - Lifetime
- 2001-10-17 AU AU2002210553A patent/AU2002210553A1/en not_active Abandoned
- 2001-10-17 DE DE50105082T patent/DE50105082D1/de not_active Expired - Lifetime
- 2001-10-17 AT AT01978432T patent/ATE286915T1/de not_active IP Right Cessation
- 2001-10-17 CZ CZ20031084A patent/CZ297784B6/cs not_active IP Right Cessation
-
2003
- 2003-05-16 ZA ZA200303812A patent/ZA200303812B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE50105082D1 (de) | 2005-02-17 |
| ES2234902T3 (es) | 2005-07-01 |
| JP2004511633A (ja) | 2004-04-15 |
| CN1254489C (zh) | 2006-05-03 |
| EP1326898A2 (fr) | 2003-07-16 |
| WO2002032964A3 (fr) | 2002-11-28 |
| JP4018536B2 (ja) | 2007-12-05 |
| AU2002210553A1 (en) | 2002-04-29 |
| ATE286915T1 (de) | 2005-01-15 |
| KR20030051723A (ko) | 2003-06-25 |
| CN1469885A (zh) | 2004-01-21 |
| CZ297784B6 (cs) | 2007-03-28 |
| EP1326898B1 (fr) | 2005-01-12 |
| US20040014901A1 (en) | 2004-01-22 |
| US7393908B2 (en) | 2008-07-01 |
| CZ20031084A3 (cs) | 2003-09-17 |
| BR0114730A (pt) | 2004-07-06 |
| WO2002032964A2 (fr) | 2002-04-25 |
| KR100799401B1 (ko) | 2008-01-30 |
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