ZA200101694B - A composition for use in converting hydrocarbons, its preparation and use. - Google Patents
A composition for use in converting hydrocarbons, its preparation and use. Download PDFInfo
- Publication number
- ZA200101694B ZA200101694B ZA200101694A ZA200101694A ZA200101694B ZA 200101694 B ZA200101694 B ZA 200101694B ZA 200101694 A ZA200101694 A ZA 200101694A ZA 200101694 A ZA200101694 A ZA 200101694A ZA 200101694 B ZA200101694 B ZA 200101694B
- Authority
- ZA
- South Africa
- Prior art keywords
- composition
- process according
- weight percent
- catalyst composition
- total
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 170
- 229930195733 hydrocarbon Natural products 0.000 title claims description 69
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 69
- 238000002360 preparation method Methods 0.000 title description 3
- 238000000034 method Methods 0.000 claims description 87
- 239000003054 catalyst Substances 0.000 claims description 86
- 239000010457 zeolite Substances 0.000 claims description 58
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 48
- 229910021536 Zeolite Inorganic materials 0.000 claims description 47
- 239000004215 Carbon black (E152) Substances 0.000 claims description 35
- 239000012530 fluid Substances 0.000 claims description 32
- -1 zinc borate compound Chemical class 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 239000011701 zinc Substances 0.000 claims description 24
- 150000001336 alkenes Chemical class 0.000 claims description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 19
- 239000011230 binding agent Substances 0.000 claims description 19
- 229910052796 boron Inorganic materials 0.000 claims description 19
- 229910052725 zinc Inorganic materials 0.000 claims description 19
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 16
- 239000003502 gasoline Substances 0.000 claims description 14
- 238000009835 boiling Methods 0.000 claims description 10
- XJHDQNJFJJUIJX-UHFFFAOYSA-N nonazinc;hexaborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] XJHDQNJFJJUIJX-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000012084 conversion product Substances 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 4
- 239000000440 bentonite Substances 0.000 claims 4
- 229910000278 bentonite Inorganic materials 0.000 claims 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims 4
- 239000008119 colloidal silica Substances 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims 4
- 238000010025 steaming Methods 0.000 claims 3
- 239000005995 Aluminium silicate Substances 0.000 claims 2
- SOLJBLVDYLYYME-UHFFFAOYSA-N O.O.O.O.O.O.O.[Zn+2].[Zn+2].OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)[O-].[O-]B([O-])[O-] Chemical compound O.O.O.O.O.O.O.[Zn+2].[Zn+2].OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)[O-].[O-]B([O-])[O-] SOLJBLVDYLYYME-UHFFFAOYSA-N 0.000 claims 2
- FPVMZVNFQLFESF-UHFFFAOYSA-N O.O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound O.O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] FPVMZVNFQLFESF-UHFFFAOYSA-N 0.000 claims 2
- 239000004115 Sodium Silicate Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims 2
- 235000012211 aluminium silicate Nutrition 0.000 claims 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 2
- 238000005336 cracking Methods 0.000 claims 2
- ZDBIRLVOKWMSNU-UHFFFAOYSA-N dizinc dioxidoboranyloxy(dioxido)borane dihydrate Chemical compound O.O.[Zn+2].[Zn+2].[O-]B([O-])OB([O-])[O-] ZDBIRLVOKWMSNU-UHFFFAOYSA-N 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims 2
- 238000005550 wet granulation Methods 0.000 claims 2
- IWICSRYJAGVVDQ-UHFFFAOYSA-N [Zn+2].OB(O)O.OB(O)O.OB([O-])[O-] Chemical compound [Zn+2].OB(O)O.OB(O)O.OB([O-])[O-] IWICSRYJAGVVDQ-UHFFFAOYSA-N 0.000 claims 1
- CMUVJPKBRDWPPA-UHFFFAOYSA-N [Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] CMUVJPKBRDWPPA-UHFFFAOYSA-N 0.000 claims 1
- MPVDXIMFBOLMNW-UHFFFAOYSA-N chembl1615565 Chemical compound OC1=CC=C2C=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C2=C1N=NC1=CC=CC=C1 MPVDXIMFBOLMNW-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000007908 dry granulation Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000011261 inert gas Substances 0.000 claims 1
- 150000004682 monohydrates Chemical class 0.000 claims 1
- 238000000197 pyrolysis Methods 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- WEFPFZNYLYONNH-UHFFFAOYSA-N tetrazinc boric acid hydrogen borate diborate heptahydrate Chemical compound O.O.O.O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[Zn+2].OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] WEFPFZNYLYONNH-UHFFFAOYSA-N 0.000 claims 1
- CFABDZIBBSYZDE-UHFFFAOYSA-N zinc boric acid hydrogen borate hydrate Chemical compound O.[Zn+2].OB(O)O.OB(O)O.OB([O-])[O-] CFABDZIBBSYZDE-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000571 coke Substances 0.000 description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 8
- 238000004939 coking Methods 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000008030 elimination Effects 0.000 description 3
- 238000003379 elimination reaction Methods 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 238000005899 aromatization reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G61/00—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen
- C10G61/02—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only
- C10G61/06—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only the refining step being a sorption process
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/144,940 US6077984A (en) | 1998-09-01 | 1998-09-01 | Process for making zeolite containing zinc borate composition, the composition and the use thereof in hydrocarbon conversion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200101694B true ZA200101694B (en) | 2002-07-04 |
Family
ID=22510845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200101694A ZA200101694B (en) | 1998-09-01 | 2001-02-28 | A composition for use in converting hydrocarbons, its preparation and use. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6077984A (ja) |
| EP (1) | EP1109762A4 (ja) |
| JP (1) | JP2003503169A (ja) |
| KR (1) | KR20010079705A (ja) |
| CN (1) | CN1315929A (ja) |
| AU (1) | AU748708B2 (ja) |
| BR (1) | BR9913369A (ja) |
| CA (1) | CA2336810A1 (ja) |
| ID (1) | ID28345A (ja) |
| WO (1) | WO2000012450A1 (ja) |
| ZA (1) | ZA200101694B (ja) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6162352A (en) * | 1999-12-20 | 2000-12-19 | Phillips Petroleum Company | Gasoline upgrade |
| US6162353A (en) * | 1999-12-21 | 2000-12-19 | Phillips Petroleum Company | Process and catalyst for upgrading liquid hydrocarbons |
| JP4496633B2 (ja) * | 2000-09-29 | 2010-07-07 | 東ソー株式会社 | トリエチレンジアミン製造用成形体触媒とその製造法及びトリエチレンジアミンの製造方法 |
| DE10356184A1 (de) * | 2003-12-02 | 2005-07-07 | Basf Ag | Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung |
| DE102004029544A1 (de) * | 2004-06-18 | 2006-01-05 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) |
| US7435855B2 (en) * | 2004-06-18 | 2008-10-14 | Basf Se | Process for the continuous synthesis of methylamines |
| DE102005059711A1 (de) * | 2005-12-12 | 2007-06-14 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur kontinuierlichen Synthese von Methylaminen |
| US9211525B2 (en) * | 2008-07-30 | 2015-12-15 | Saudi Arabian Oil Company | Metallic clay based FCC gasoline sulfur reduction additive compositions |
| US20110230333A1 (en) * | 2010-03-16 | 2011-09-22 | Uop Llc | Olefin Cracking Catalyst and Manufacturing Process |
| US9181146B2 (en) | 2010-12-10 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
| US8680344B2 (en) | 2011-01-25 | 2014-03-25 | Zeochem Llc | Molecular sieve adsorbent blends and uses thereof |
| US9181147B2 (en) | 2012-05-07 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
| US8937205B2 (en) | 2012-05-07 | 2015-01-20 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes |
| US8921633B2 (en) | 2012-05-07 | 2014-12-30 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
| US20140044625A1 (en) * | 2012-08-08 | 2014-02-13 | Ford Global Technologies, Llc | Hydrocarbon trap having improved adsorption capacity |
| JP6130852B2 (ja) * | 2012-10-25 | 2017-05-17 | Ｊｘｔｇエネルギー株式会社 | オレフィン及び単環芳香族炭化水素の製造方法、並びにエチレン製造装置 |
| CN104736679B (zh) * | 2012-10-25 | 2016-08-17 | 吉坤日矿日石能源株式会社 | 烯烃及单环芳香族烃的制造方法以及它们的制造装置 |
| CN104557378B (zh) * | 2013-10-29 | 2018-07-31 | 中国石油化工股份有限公司 | 一种石脑油催化裂解产丙烯的方法 |
| CN104557400B (zh) * | 2013-10-29 | 2017-01-04 | 中国石油化工股份有限公司 | 一种石脑油催化裂解产丙烯的方法 |
| JP6620106B2 (ja) * | 2014-02-25 | 2019-12-11 | サウディ ベーシック インダストリーズ コーポレイション | コークス化を利用した、混合炭化水素元からｂｔｘを製造する方法 |
| CN105524650B (zh) * | 2014-10-21 | 2017-09-29 | 中国石油化工股份有限公司 | 石脑油催化裂解产丙烯的方法 |
| CN105585399B (zh) * | 2014-10-21 | 2018-02-23 | 中国石油化工股份有限公司 | 一种石脑油催化裂解产丙烯的方法 |
| US9896631B2 (en) | 2014-12-10 | 2018-02-20 | Uop Llc | Methods for removing impurities from hydrocarbons |
| US10150104B2 (en) | 2015-11-09 | 2018-12-11 | Chevron Phillips Chemical Company Lp | Method for preparing aromatization catalysts |
| CN108192666A (zh) * | 2018-02-14 | 2018-06-22 | 彭杰 | 一种石脑油加氢裂化制备高辛烷值汽油的方法 |
| CN110180525B (zh) * | 2019-05-10 | 2021-12-21 | 重庆第二师范学院 | 一种Zn4B6O13的固相制备方法及在抗生素降解中的用途 |
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| US3649172A (en) * | 1970-12-21 | 1972-03-14 | United States Borax Chem | Zinc borate of low hydration and method for preparing same |
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| US4049573A (en) * | 1976-02-05 | 1977-09-20 | Mobil Oil Corporation | Zeolite catalyst containing oxide of boron or magnesium |
| US4206042A (en) * | 1978-03-31 | 1980-06-03 | Uop Inc. | Hydrocarbon dehydrocyclization with an acidic multimetallic catalytic composite |
| US4313821A (en) * | 1978-09-11 | 1982-02-02 | Mobil Oil Corporation | Processing of coal liquefaction products |
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| US4238320A (en) * | 1979-04-19 | 1980-12-09 | Gulf Research & Development Company | Denitrogenation of shale oil |
| US4429174A (en) * | 1982-08-06 | 1984-01-31 | Exxon Research & Engineering Co. | Process for dehydrocoupling toluene using a modified faujasite zeolite catalyst composition |
| US4665253A (en) * | 1984-06-13 | 1987-05-12 | Mobil Oil Corporation | Conversion of aromatics over novel catalyst composition |
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| US4751339A (en) * | 1987-01-23 | 1988-06-14 | Mobil Oil Corporation | Zeolite catalysis process for conversion of diene-containing olefins to aromatic hydrocarbons |
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| AU7388798A (en) * | 1997-06-17 | 1999-01-04 | Phillips Petroleum Company | Zeolite composition and use in hydrocarbon conversion process |
| US5898089A (en) * | 1997-07-09 | 1999-04-27 | Phillips Petroleum Company | Hydrocarbon aromatization process using a zeolite |
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| US6063974A (en) * | 1998-04-15 | 2000-05-16 | Phillips Petroleum Company | Silylated water vapor treated zinc or gallium promoted zeolite and use thereof for the conversion of non-aromatic hydrocarbons to olefins and aromatic hydrocarbons |
| US6126812A (en) * | 1998-07-14 | 2000-10-03 | Phillips Petroleum Company | Gasoline upgrade with split feed |
| US6124227A (en) * | 1998-08-28 | 2000-09-26 | Phillips Petroleum Company | Hydrocarbon conversion catalyst composition and processes therefor and therewith |
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1998
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1999
- 1999-08-12 AU AU56741/99A patent/AU748708B2/en not_active Ceased
- 1999-08-12 CN CN99810366A patent/CN1315929A/zh active Pending
- 1999-08-12 WO PCT/US1999/018472 patent/WO2000012450A1/en not_active Application Discontinuation
- 1999-08-12 CA CA002336810A patent/CA2336810A1/en not_active Abandoned
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| AU748708B2 (en) | 2002-06-13 |
| AU5674199A (en) | 2000-03-21 |
| EP1109762A4 (en) | 2004-07-07 |
| CN1315929A (zh) | 2001-10-03 |
| WO2000012450A1 (en) | 2000-03-09 |
| BR9913369A (pt) | 2001-06-05 |
| JP2003503169A (ja) | 2003-01-28 |
| CA2336810A1 (en) | 2000-03-09 |
| ID28345A (id) | 2001-05-17 |
| US6077984A (en) | 2000-06-20 |
| EP1109762A1 (en) | 2001-06-27 |
| KR20010079705A (ko) | 2001-08-22 |
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