YU46461B - Postupak ekstrakcije germanijuma iz rastvora - Google Patents

Postupak ekstrakcije germanijuma iz rastvora

Info

Publication number
YU46461B
YU46461B YU105288A YU105288A YU46461B YU 46461 B YU46461 B YU 46461B YU 105288 A YU105288 A YU 105288A YU 105288 A YU105288 A YU 105288A YU 46461 B YU46461 B YU 46461B
Authority
YU
Yugoslavia
Prior art keywords
germanium
extraction
procedure
solution
solutions
Prior art date
Application number
YU105288A
Other languages
English (en)
Other versions
YU105288A (en
Inventor
F.J.S. Menendez
V.A. Fernandez
F.M.S. Menendez
A.C. Herrera
F.A. Tamargo
M.R. Valcarcel
L.P. Lorenzo
Original Assignee
Asturiana De Zinc S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asturiana De Zinc S.A. filed Critical Asturiana De Zinc S.A.
Publication of YU105288A publication Critical patent/YU105288A/xx
Publication of YU46461B publication Critical patent/YU46461B/sh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B41/00—Obtaining germanium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G17/00—Compounds of germanium
    • C01G17/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40—Mixtures
    • C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

POSTUPAK EKSTRAKCIJE GERMANIJUMA IZ RASTVORA, naznačen time, što se rastvor germanijuma, koji se sastoji od: Germanijuma: 0,05-1,5 g/l Ferogvoždja: 0-30 g/l Bakra: 0-5 g/l Cinka: 0-130 g/l Aluminijuma: 0-10 g/l pri vrednosti pH od 0,5 do 2 na sobnoj temperaturi (15 stepeni do 40 stepeni približno), tretira organskim rastvorom jednog amina, kao ekstraktantom u prisustvu reagensa koji obrazuje kompleks koji obuhvata polihidroksikarboksilnu kiselinu, da bi se dobio jedan organski ekstrakt bogat germanijumom i vodena faza koja je praktično oslobodjena germanijuma; ispiranje sa vodom pomenutog organskog ekstrakta bogatog germanijumom; elutiranje germanijuma iz pomenutog organskog ekstrakta sa bazičnim vodenim rastvorom na sobnoj temperaturi od 15 stepeni C do 40 stepeni C približno, da bi se dobila organska faza oslobodjena germanijuma i bazična vodena faza bogata germanijumom; i obradu pomenute bazične vodene faze bogate germanijumom sumpornom kiselinom, do pH vrednosti od 8 do 11 približno, da bi se taložio germanijum u obliku poligermanata, osetljiv za kasniju obradu transformacije u metalni germanijum, ili u germanijum dioksid, konvencionalnim postupcima. Prijava sadrži još 10 patentnih zahteva.
YU105288A 1987-07-15 1988-05-31 Postupak ekstrakcije germanijuma iz rastvora YU46461B (sh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES8702072A ES2004642A6 (es) 1987-07-15 1987-07-15 Procedimiento para la recuperacion de recuperacion de germanio de soluciones que lo contienen

Publications (2)

Publication Number Publication Date
YU105288A YU105288A (en) 1990-04-30
YU46461B true YU46461B (sh) 1993-10-20

Family

ID=8251753

Family Applications (1)

Application Number Title Priority Date Filing Date
YU105288A YU46461B (sh) 1987-07-15 1988-05-31 Postupak ekstrakcije germanijuma iz rastvora

Country Status (16)

Country Link
US (1) US4886648A (sh)
EP (1) EP0299901B1 (sh)
JP (1) JPS6424018A (sh)
KR (1) KR950013190B1 (sh)
CN (1) CN1020711C (sh)
AT (1) ATE92894T1 (sh)
AU (1) AU598671B2 (sh)
BR (1) BR8802757A (sh)
CA (1) CA1335756C (sh)
DE (1) DE3883103T2 (sh)
ES (1) ES2004642A6 (sh)
FI (1) FI91086C (sh)
IN (1) IN171952B (sh)
MX (1) MX170525B (sh)
NO (1) NO180295C (sh)
YU (1) YU46461B (sh)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5277882A (en) * 1989-04-28 1994-01-11 Union Miniere S.A. Process for recovering germanium
US5279879A (en) * 1989-12-28 1994-01-18 Tonen Corporation Hybrid prepreg containing carbon fibers and at least one other reinforcing fiber in specific positions within the prepreg
WO1999033756A1 (en) 1997-12-31 1999-07-08 Corning Incorporated Germanium-containing particulate capture from an exhaust gas stream of a glass production system
US6337057B1 (en) 1999-06-23 2002-01-08 Lucent Technologies, Inc. Process for the direct production of germanium tetrachloride from hydrated germanate-containing solids using gaseous hydrogen chloride
US6238462B1 (en) 1999-07-14 2001-05-29 Corning Incorporated Methods for the separation of compounds from acidic aqueous solutions
ES2293831B2 (es) * 2006-07-03 2008-12-16 Universidad De Sevilla Procedimiento para la recuperacion del germanio presente en cenizas de carbon.
CN102267770B (zh) * 2011-07-27 2013-04-03 南京师范大学 一种去除氯化亚铁酸性废水中的铅与锌元素的方法
CN103388086B (zh) * 2012-05-09 2014-12-10 深圳市格林美高新技术股份有限公司 一种从含锗废弃元件中提取锗的方法
CN103952575B (zh) * 2014-05-13 2016-05-11 中南大学 一种从含锗物料中回收锗的方法
EP3401283B1 (en) 2017-05-10 2019-11-06 ITM Isotopen Technologien München AG Method for the manufacture of highly purified 68ge material for radiopharmaceutical purposes
CN109554554B (zh) * 2018-12-26 2021-04-16 中南大学 一种从硫酸盐溶液中回收锗的方法
CN109929997B (zh) * 2019-03-14 2021-05-18 贵州宏达环保科技有限公司 一种用n235萃取剂生产锗精矿的方法
CN110921905A (zh) * 2019-12-12 2020-03-27 四川高锗再生资源有限公司 一种高纯二氧化锗生产中含锗液的回收系统及方法
CN112481504B (zh) * 2020-11-09 2022-05-27 昆明理工大学 一种添加剂的制备方法
CN112695212B (zh) * 2020-12-10 2023-05-05 衢州华友钴新材料有限公司 一种从高铁高砷硫酸盐溶液中三元协萃分离锗的方法
CN114277264B (zh) * 2021-12-28 2023-10-24 广东先导稀材股份有限公司 一种萃取回收锗的方法
CN115109929B (zh) * 2022-01-21 2023-11-10 昆明理工大学 一种单宁锗渣直接制备粗二氧化锗的方法
CN114921665B (zh) * 2022-06-01 2023-08-22 朝阳金美镓业有限公司 萃取法从含锗盐酸溶液中再生锗和盐酸的方法
CN115537584B (zh) * 2022-11-29 2023-03-10 昆明理工大学 一种超声协同单宁酸改性强化单宁沉锗的方法
CN116065041B (zh) * 2023-02-16 2023-12-15 昆明理工大学 一种超声强化分段酸洗纯化单宁锗渣制备高品位锗精矿的方法
CN117089728B (zh) * 2023-08-21 2024-05-28 广西大学 一种高效吸附回收锗的方法
CN117210688B (zh) * 2023-11-09 2024-01-19 昆明理工大学 一种单宁锗渣分质回收利用的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB938035A (en) * 1960-01-16 1963-09-25 Ledoga Spa A process for the recovery of germanium
NL6511264A (sh) * 1965-08-28 1967-03-01
US4389379A (en) * 1980-08-15 1983-06-21 Societe Miniere Et Metallurgique De Penarroya Process for selective liquid-liquid extraction of germanium
LU83449A1 (fr) * 1981-06-22 1983-04-06 Metallurgie Hoboken Procede pour separer du germanium d'une solution aqueuse a l'aide d'un alpha-hydroxyoxime

Also Published As

Publication number Publication date
IN171952B (sh) 1993-02-20
FI91086B (fi) 1994-01-31
JPH0556288B2 (sh) 1993-08-19
CA1335756C (en) 1995-06-06
NO882638D0 (no) 1988-06-15
NO882638L (no) 1989-01-16
ATE92894T1 (de) 1993-08-15
NO180295B (no) 1996-12-16
FI882395A0 (fi) 1988-05-20
BR8802757A (pt) 1989-02-08
DE3883103D1 (de) 1993-09-16
YU105288A (en) 1990-04-30
FI882395A (fi) 1989-01-16
EP0299901B1 (en) 1993-08-11
AU598671B2 (en) 1990-06-28
EP0299901A3 (en) 1990-01-24
KR890002431A (ko) 1989-04-10
US4886648A (en) 1989-12-12
AU1613088A (en) 1989-01-19
EP0299901A2 (en) 1989-01-18
JPS6424018A (en) 1989-01-26
NO180295C (no) 1997-03-26
MX170525B (es) 1993-08-30
KR950013190B1 (ko) 1995-10-25
ES2004642A6 (es) 1989-01-16
FI91086C (fi) 1994-05-10
CN1020711C (zh) 1993-05-19
DE3883103T2 (de) 1994-02-03
CN1030562A (zh) 1989-01-25

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