YU148579A - Process for obtaining aluminium modified silicon dioxide - Google Patents
Process for obtaining aluminium modified silicon dioxideInfo
- Publication number
- YU148579A YU148579A YU01485/79A YU148579A YU148579A YU 148579 A YU148579 A YU 148579A YU 01485/79 A YU01485/79 A YU 01485/79A YU 148579 A YU148579 A YU 148579A YU 148579 A YU148579 A YU 148579A
- Authority
- YU
- Yugoslavia
- Prior art keywords
- silicon dioxide
- modified silicon
- aluminium
- derivative
- gallium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Silicon Compounds (AREA)
Abstract
Aluminium-or gallium modified silica or germania is prepared by reacting an aluminium (or gallium) derivative and a silicon (or germanium) derivative with a clathrating substance with the possible addition of a mineralising agent and an inorganic base, and crystallising the mixture thus obtained, so that a compound is formed which has the general formula: Si.(0.0012 - 0.0050)Al.Oy Ge.(0.0012 to 0.0050)Al.Oy Si.(0.0012 to 0.0050) Ga.Oy Ge.(0.0012 to 0.0050)Ga.Oy in which y is from 2.0018 to 2.0075. The modified silicas and the analogous compounds are efficient catalysts for a large number of reactions. A zeolite of formula (0.9+/-0.2)M2/n0.W2O3(5-100)YO2-2H2O in which M is H<+>, NH4<+>, metallic cations or cations derived from amino alcohols, W is Al or Ga, Y is Si or Ge and z is 0-40 of ZSM-5 type is referred to as a modification.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
YU261282A YU261282A (en) | 1978-06-22 | 1982-11-23 | Process for the alkylation of hydrocarbons |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT24843/78A IT1096778B (en) | 1978-06-22 | 1978-06-22 | MODIFIED SILICA WITH ALUMINUM |
IT3088478A IT1160353B (en) | 1978-12-15 | 1978-12-15 | Aluminium or gallium modified silica or germania zeolite(s) - useful as catalysts, esp. for alkylation or as adsorbents |
IT2263979A IT1166823B (en) | 1979-05-14 | 1979-05-14 | Aluminium or gallium modified silica or germania zeolite(s) - useful as catalysts, esp. for alkylation or as adsorbents |
Publications (2)
Publication Number | Publication Date |
---|---|
YU148579A true YU148579A (en) | 1983-01-21 |
YU40370B YU40370B (en) | 1985-12-31 |
Family
ID=27273301
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
YU1485/79A YU40370B (en) | 1978-06-22 | 1979-06-22 | Process for obtaining aluminium-modified silicon dioxide |
Country Status (25)
Country | Link |
---|---|
AT (1) | AT374770B (en) |
AU (1) | AU531124B2 (en) |
CA (1) | CA1131206A (en) |
CH (1) | CH645076A5 (en) |
DD (2) | DD151877A5 (en) |
DE (1) | DE2924870C2 (en) |
DK (1) | DK155176C (en) |
EG (1) | EG13897A (en) |
ES (1) | ES482160A1 (en) |
FR (1) | FR2429041A1 (en) |
GB (1) | GB2023562B (en) |
GR (1) | GR72245B (en) |
IE (1) | IE48184B1 (en) |
IL (1) | IL57583A (en) |
IN (1) | IN151533B (en) |
LU (1) | LU81416A1 (en) |
NL (1) | NL188787C (en) |
NO (2) | NO792058L (en) |
PH (1) | PH14502A (en) |
PL (1) | PL118729B1 (en) |
PT (1) | PT69798A (en) |
RO (1) | RO78794A (en) |
SE (2) | SE439437B (en) |
TR (1) | TR21702A (en) |
YU (1) | YU40370B (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0042225B1 (en) * | 1980-06-12 | 1984-02-01 | Imperial Chemical Industries Plc | Zeolite synthesis |
ZA817189B (en) * | 1980-10-22 | 1983-05-25 | British Petroleum Co | Synthetic modified crystalline silica |
ATE14869T1 (en) | 1980-12-12 | 1985-08-15 | Exxon Research Engineering Co | XYLENE ISOMERIZATION. |
EP0055044B1 (en) * | 1980-12-12 | 1985-09-18 | Exxon Research And Engineering Company | Composite zeolite |
IT1137176B (en) * | 1981-06-02 | 1986-09-03 | Anic Spa | PROCESS FOR THE PRODUCTION OF DIMETHYLETER |
NZ202099A (en) * | 1981-10-21 | 1986-07-11 | Ici Plc | Preparation of zeolite nu-10 |
IT1150142B (en) * | 1982-01-22 | 1986-12-10 | Montedison Spa | PROCESS FOR OBTAINING DIRECTLY FROM LOW SODIUM ZEOLITES OF ZEOLITI TYPE ZSOL-5 |
DE3217322A1 (en) * | 1982-05-08 | 1983-11-10 | Hoechst Ag, 6230 Frankfurt | CRYSTALLINE ALUMINOSILICATE ZEOLITE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE |
CA1209981A (en) * | 1982-09-04 | 1986-08-19 | Dennis Young | Crystalline gallosilicates, a process for producing them and their use as catalysts |
DE3240869A1 (en) * | 1982-11-05 | 1984-05-10 | Hoechst Ag, 6230 Frankfurt | ZEOLITES CONTAINING TITANIUM, ZIRCONIUM AND / OR HAFNIUM AND METHOD FOR THE PRODUCTION THEREOF AND THEIR USE |
GB8308684D0 (en) * | 1983-03-29 | 1983-05-05 | British Petroleum Co Plc | Production of gallium loaded hydrocarbon conversion catalyst |
US4732747A (en) * | 1983-04-11 | 1988-03-22 | The Dow Chemical Company | Magnesium silicate compositions and process for making |
EP0164045B1 (en) * | 1984-06-02 | 1989-04-05 | Hoechst Aktiengesellschaft | Process for the isomerisation of mono- or dichlorotoluene |
US4968650A (en) * | 1985-09-17 | 1990-11-06 | Mobil Oil Corporation | ZSM-5 catalysts having predominantly framework gallium, methods of their preparation, and use thereof |
IN171677B (en) * | 1987-08-31 | 1992-12-05 | Mobil Oil Corp | |
FR2629444B1 (en) * | 1988-04-01 | 1990-12-07 | Rhone Poulenc Chimie | SILICA AND GERMANIUM OXIDE ZEOLITES AND PROCESS FOR THE SYNTHESIS THEREOF |
DE69223680T2 (en) * | 1991-05-17 | 1998-07-30 | Asahi Chemical Ind | Process for producing a particulate zeolite |
KR100385653B1 (en) * | 1995-06-06 | 2003-10-10 | 엑손모빌 오일 코포레이션 | Zykhorus ZSM-5, its synthesis method and its use |
US6784333B2 (en) * | 2002-08-06 | 2004-08-31 | Saudi Basic Industries Corporation | Catalyst for aromatization of alkanes, process of making and using thereof |
FR2860224B1 (en) * | 2003-09-26 | 2006-06-02 | Inst Francais Du Petrole | CRYSTALLIZED SOLID IM-12 AND PROCESS FOR PREPARING THE SAME |
CN108946757B (en) * | 2017-05-26 | 2020-06-09 | 中国石油化工股份有限公司 | Molecular sieve SCM-13, its synthesis method and use |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2419272A (en) * | 1944-04-26 | 1947-04-22 | Socony Vacuum Oil Co Inc | Process of forming a silicacontaining hydrogel |
DE1963439A1 (en) * | 1969-12-18 | 1971-06-24 | Dynamit Nobel Ag | Process for the production of porous silica |
US3709833A (en) * | 1970-08-21 | 1973-01-09 | Owens Illinois Inc | Process for preparing high purity silicon oxide porous beads doped with small quantities of other oxides |
US3941871A (en) * | 1973-11-02 | 1976-03-02 | Mobil Oil Corporation | Crystalline silicates and method of preparing the same |
US4073865A (en) * | 1976-09-27 | 1978-02-14 | Union Carbide Corporation | Silica polymorph and process for preparing same |
US4209498A (en) * | 1976-11-05 | 1980-06-24 | Imperial Chemical Industries Limited | Silica-containing material FU-1 |
-
1979
- 1979-06-11 DK DK243279A patent/DK155176C/en active
- 1979-06-13 GR GR59329A patent/GR72245B/el unknown
- 1979-06-17 IL IL57583A patent/IL57583A/en unknown
- 1979-06-18 PH PH22658A patent/PH14502A/en unknown
- 1979-06-19 ES ES482160A patent/ES482160A1/en not_active Expired
- 1979-06-20 DE DE2924870A patent/DE2924870C2/en not_active Expired
- 1979-06-20 AU AU48233/79A patent/AU531124B2/en not_active Ceased
- 1979-06-20 SE SE7905453A patent/SE439437B/en not_active IP Right Cessation
- 1979-06-20 NO NO792058A patent/NO792058L/en unknown
- 1979-06-21 CA CA330,302A patent/CA1131206A/en not_active Expired
- 1979-06-21 LU LU81416A patent/LU81416A1/en unknown
- 1979-06-21 TR TR21702A patent/TR21702A/en unknown
- 1979-06-21 GB GB7921621A patent/GB2023562B/en not_active Expired
- 1979-06-21 AT AT0438179A patent/AT374770B/en not_active IP Right Cessation
- 1979-06-21 DD DD79221479A patent/DD151877A5/en unknown
- 1979-06-21 PT PT69798A patent/PT69798A/en unknown
- 1979-06-21 FR FR7915999A patent/FR2429041A1/en active Granted
- 1979-06-21 DD DD79213814A patent/DD144397A5/en not_active IP Right Cessation
- 1979-06-22 IN IN641/CAL/79A patent/IN151533B/en unknown
- 1979-06-22 YU YU1485/79A patent/YU40370B/en unknown
- 1979-06-22 RO RO7997929A patent/RO78794A/en unknown
- 1979-06-22 PL PL1979216528A patent/PL118729B1/en unknown
- 1979-06-22 CH CH586979A patent/CH645076A5/en not_active IP Right Cessation
- 1979-06-22 NL NLAANVRAGE7904908,A patent/NL188787C/en not_active IP Right Cessation
- 1979-06-23 EG EG371/79A patent/EG13897A/en active
- 1979-08-08 IE IE1168/79A patent/IE48184B1/en unknown
-
1984
- 1984-06-12 SE SE8403138A patent/SE8403138D0/en not_active Application Discontinuation
-
1985
- 1985-11-28 NO NO854781A patent/NO854781L/en unknown
Also Published As
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