WO2024100713A1 - 監視装置 - Google Patents

監視装置 Download PDF

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Publication number
WO2024100713A1
WO2024100713A1 PCT/JP2022/041370 JP2022041370W WO2024100713A1 WO 2024100713 A1 WO2024100713 A1 WO 2024100713A1 JP 2022041370 W JP2022041370 W JP 2022041370W WO 2024100713 A1 WO2024100713 A1 WO 2024100713A1
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Prior art keywords
membrane
filtration
sensor
treated water
particles
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Ceased
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PCT/JP2022/041370
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English (en)
French (fr)
Japanese (ja)
Inventor
優香子 石原
康信 岡島
健 吉崎
健 田中
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Kubota Corp
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Kubota Corp
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Application filed by Kubota Corp filed Critical Kubota Corp
Priority to IL319065A priority Critical patent/IL319065A/en
Priority to PCT/JP2022/041370 priority patent/WO2024100713A1/ja
Priority to CN202280100213.4A priority patent/CN119894593A/zh
Priority to JP2024556846A priority patent/JPWO2024100713A1/ja
Priority to EP22965040.3A priority patent/EP4616928A1/en
Publication of WO2024100713A1 publication Critical patent/WO2024100713A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/10—Testing of membranes or membrane apparatus; Detecting or repairing leaks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/10—Testing of membranes or membrane apparatus; Detecting or repairing leaks
    • B01D65/109—Testing of membrane fouling or clogging, e.g. amount or affinity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/60—Specific sensors or sensor arrangements

Definitions

  • the present invention relates to a monitoring device that detects leakage of monitored particles during wastewater treatment.
  • Patent Documents 1 and 2 disclose devices for detecting the integrity of a filtration membrane.
  • the device disclosed in Patent Document 1 receives the permeate of the filtration membrane, and detects damage to the filtration membrane based on the pressure on the supply side of the first sensor membrane, the pressure between the first and second sensor membranes, and the pressure on the permeate side of the second sensor membrane.
  • the first sensor membrane is installed parallel to the flow of the permeate of the filtration membrane.
  • the device described in Patent Document 1 employs a cross-flow filtration method.
  • the device disclosed in Patent Document 2 receives the permeate from the filtration membrane in a first chamber, and detects damage to the filtration membrane based on the pressure measured by a pressure gauge provided on the supply side of the sensor membrane and the pressure measured by a pressure gauge provided on the permeate side of the sensor membrane.
  • the sensor membrane provided between the first and second chambers is installed parallel to the flow of the permeate from the filtration membrane.
  • the device described in Patent Document 2 employs a cross-flow filtration method.
  • devices that adopt a cross-flow filtration method such as those described in Patent Documents 1 and 2 have a sensor membrane with a membrane surface that is installed parallel to the flow of treated water supplied to the sensor membrane, so that the flow can suppress the deposition of particles on the membrane surface of the sensor membrane.
  • This has the advantage of suppressing clogging of the sensor membrane, so that the frequency of replacing the sensor membrane can be reduced.
  • the sensor membrane does not filter the entire amount of particles to be monitored contained in the treated water supplied to the sensor membrane, only a portion of the particles to be monitored contained in the treated water supplied to the sensor membrane can be captured. Therefore, there is room for improvement in devices that adopt a cross-flow filtration method in that it is difficult to improve the sensitivity in detecting particles to be monitored contained in treated water obtained by wastewater treatment.
  • a device that employs a dead-end filtration method has a sensor membrane with a membrane surface that intersects with the flow of treated water supplied to the sensor membrane, and filters the entire amount of treated water supplied to the sensor membrane. This has the advantage of being able to capture the entire amount of particles to be monitored contained in the treated water supplied to the sensor membrane, improving the sensitivity in detecting particles to be monitored contained in the treated water obtained by wastewater treatment.
  • it compared to devices that employ a cross-flow filtration method, it also captures many particles other than the ones to be monitored.
  • the present invention was made in consideration of the above circumstances, and aims to provide a monitoring device that can improve the sensitivity in detecting particles to be monitored that are contained in treated water obtained by wastewater treatment.
  • the first aspect of the present invention is a monitoring device that detects leakage of monitored particles during wastewater treatment, comprising: a branch pipe branched off from a pipe that guides treated water obtained by the wastewater treatment; a membrane sensor that is installed in a direction that crosses the flow of the treated water flowing through the branch pipe and has a filtration membrane that filters the treated water; and a pressure sensor that measures the differential pressure between a first pressure of the treated water upstream of the membrane sensor and a second pressure of the treated water downstream of the membrane sensor, the filtration membrane having a pore size smaller than the particles to be monitored.
  • the filtration membrane that filters the treated water flowing through the branch pipe is installed in a direction that crosses the flow of the treated water.
  • the monitoring device employs a dead-end filtration method.
  • the filtration membrane has a pore size smaller than the particles to be monitored, the particles to be monitored can be captured more reliably. Therefore, the monitoring device can improve the sensitivity in detecting the particles to be monitored.
  • the second aspect of the present invention is a monitoring device according to the first aspect of the present invention, characterized in that the filtration membrane is a track-etched membrane.
  • the filtration membrane is a track-etched membrane, so the pore size distribution of the pores formed in the filtration membrane is uniform. Therefore, the monitoring device can reduce false positives regarding leakage of the particles to be monitored and improve the sensitivity in detecting the particles to be monitored.
  • the third aspect of the present invention is a monitoring device according to the first or second aspect of the present invention, characterized in that the pore size is formed to allow proteins smaller than the particles to be monitored to pass through.
  • the filtration membrane allows proteins smaller than the particles to be monitored to pass through. In other words, fewer particles can be captured by the filtration membrane per unit time. As a result, the monitoring device can extend the time before the filtration membrane needs to be replaced, thereby improving the sensitivity in detecting the particles to be monitored while reducing the frequency of replacement of the filtration membrane.
  • the fourth aspect of the present invention is a monitoring device according to any one of the first to third aspects of the present invention, characterized in that the protein adsorption rate of the filtration membrane is smaller than the protein adsorption rates of cellulose acetate (CA), polyvinylidene fluoride (PVDF), and polytetrafluoroethylene (PTFE).
  • CA cellulose acetate
  • PVDF polyvinylidene fluoride
  • PTFE polytetrafluoroethylene
  • the protein adsorption rate of the filtration membrane is smaller than a predetermined value. This makes it possible to further prevent proteins from adsorbing to the filtration membrane and clogging the filtration membrane. As a result, the monitoring device can further improve the sensitivity in detecting particles to be monitored while reducing the frequency of replacing the filtration membrane.
  • the fifth aspect of the present invention is a monitoring device according to any one of the first to fourth aspects of the present invention, characterized in that the pressure sensor calculates the filtration resistance by dividing the differential pressure by the filtration flux, and detects the leakage based on the ratio between the time average value of the filtration resistance at a first timing and the time average value of the filtration resistance at a second timing that is later than the first timing.
  • the monitoring device can detect leakage of monitored particles with higher accuracy, regardless of temporal fluctuations in the flow rate of the treated water flowing through the branch pipe.
  • the sixth aspect of the present invention is a monitoring device according to any one of the first to fourth aspects of the present invention, characterized in that the pressure sensor calculates the filtration resistance only from the differential pressure and detects the leakage based on the filtration resistance.
  • the monitoring device can detect leakage of monitored particles with higher accuracy.
  • the seventh aspect of the present invention is a monitoring device according to any one of the first to sixth aspects of the present invention, further comprising an air vent valve that is provided upstream of the membrane sensor and vents air that has become mixed into the treated water flowing through the branch pipe toward the membrane sensor.
  • the monitoring device can remove air that has become mixed into the treated water and reduce the variation in the value of the monitoring index (e.g., filtration resistance). This allows the monitoring device to detect the particles to be monitored with higher accuracy and detect leakage of the particles to be monitored with higher accuracy.
  • the monitoring index e.g., filtration resistance
  • the eighth aspect of the present invention is a monitoring device according to any one of the first to seventh aspects of the present invention, further comprising a concentration equalization means provided upstream of the membrane sensor for equalizing the concentration of the treated water.
  • the concentration equalization means can equalize the concentration throughout the treated water obtained by wastewater treatment. This allows the monitoring device to reduce the concentration polarization of solids throughout the treated water obtained by wastewater treatment. Therefore, even if the flow rate of the treated water flowing through the branch pipe is relatively small compared to the total flow rate of the treated water obtained by wastewater treatment, the leakage of the monitored particles can be detected with higher accuracy.
  • the present invention provides a monitoring device that can improve the sensitivity in detecting particles to be monitored that are contained in treated water obtained by wastewater treatment.
  • FIG. 1 is a block diagram illustrating a monitoring device according to an embodiment of the present invention.
  • 2 is a schematic cross-sectional view showing a filtration membrane of the membrane sensor of the present embodiment.
  • FIG. FIG. 2 is a schematic cross-sectional view showing a filtration membrane of a membrane sensor of a comparative example.
  • 1 is a graph illustrating an example of the results of a study conducted by the present inventors.
  • FIG. 1 is a block diagram showing a monitoring device according to an embodiment of the present invention.
  • the monitoring device 4 according to the present embodiment detects leakage of particles to be monitored in wastewater treatment.
  • the wastewater treatment includes biological treatment and membrane treatment.
  • the wastewater treatment of the present embodiment does not necessarily include biological treatment and membrane treatment, and may include, for example, a general turbidity removal process using sand filtration, fiber filtration, and a thread-wound filter.
  • a case in which the wastewater treatment includes biological treatment and membrane treatment is taken as an example.
  • the monitoring device 4 according to the present embodiment detects leakage of particles to be monitored due to damage to a membrane used in membrane treatment 3 in wastewater treatment that performs biological treatment 2 and membrane treatment 3.
  • the biological treatment 2 process shown in FIG. 1 is a process of introducing water to be treated into a biological reactor where biological treatment is carried out to obtain biologically treated water.
  • Biological treatment 2 is not particularly limited as long as it treats the water to be treated introduced into the biological reactor in the presence of microorganisms. That is, biological treatment 2 may be aerobic biological treatment or anaerobic biological treatment. In other words, the microorganisms may be aerobic microorganisms or anaerobic microorganisms.
  • Examples of biological treatment 2 include the activated sludge method (including the membrane separation activated sludge method), the carrier method, and the fixed bed biofilm method.
  • biologically treated water is obtained in which the organic water pollutants contained in the treated water have been reduced.
  • the membrane treatment 3 shown in FIG. 1 may be performed after the biological treatment 2, or may be performed at the same stage as the biological treatment 2.
  • the membrane separation device (not shown) used in the membrane treatment 3 may be provided outside the biological reaction tank used in the biological treatment 2, or may be provided inside the biological reaction tank.
  • the membrane separation device separates the biological treated water obtained by the step of the biological treatment 2 into solid and liquid to obtain membrane treated water.
  • the membrane separation device when the membrane separation device is provided inside the biological reaction tank, the membrane separation device separates the liquid inside the biological reaction tank into solid and liquid to obtain membrane treated water.
  • the membrane treated water of this embodiment is an example of the "treated water" of the present invention.
  • the membrane used in membrane process 3 i.e., the membrane installed in the membrane separation device, is not particularly limited as long as it can separate the biological treatment water and the liquid inside the biological reaction tank into solid and liquid.
  • Examples of the membrane used in membrane process 3 include microfiltration membranes (MF membranes) and ultrafiltration membranes (UF membranes).
  • MF membranes microfiltration membranes
  • UF membranes ultrafiltration membranes
  • Examples of the shape of the membrane used in membrane process 3 include hollow fiber membranes, tubular membranes, and flat membranes.
  • Examples of the material of the membrane used in membrane process 3 include organic membranes such as cellulose acetate, polyvinylidene fluoride, polyolefin, chlorinated polyethylene, polyamide, polyacrylonitrile, and polytetrafluoroethylene, and inorganic membranes such as ceramics (e.g., mullite, alumina, and zirconia).
  • organic membranes such as cellulose acetate, polyvinylidene fluoride, polyolefin, chlorinated polyethylene, polyamide, polyacrylonitrile, and polytetrafluoroethylene
  • inorganic membranes such as ceramics (e.g., mullite, alumina, and zirconia).
  • the wastewater treatment of this embodiment does not necessarily have to include membrane treatment.
  • the biologically treated water may be obtained by solid-liquid separation using solid-liquid separation means other than a membrane separation device (e.g., a settling tank).
  • the biologically treated water of this embodiment is an example of the "treated water" of the present invention.
  • the monitoring device 4 shown in FIG. 1 includes a pipe 401, a branch pipe 402, a water supply switching valve 42, a membrane sensor 45, a differential pressure sensor 46, and a flow rate sensor 47.
  • the pipe 401 guides the membrane-treated water obtained by the membrane process 3.
  • the branch pipe 402 branches off from the pipe 401 and guides at least a portion of the membrane-treated water flowing through the pipe 401 toward the membrane sensor 45.
  • the water supply switching valve 42 is provided in the branch pipe 402 and switches between a state in which at least a portion of the membrane-treated water flowing through the pipe 401 flows toward the membrane sensor 45 and a state in which the membrane-treated water flowing through the pipe 401 is stopped from flowing toward the membrane sensor 45. In other words, when the water supply switching valve 42 is open, at least a portion of the membrane-treated water flowing through the pipe 401 flows toward the membrane sensor 45. On the other hand, when the water supply switching valve 42 is closed, the membrane-treated water flowing through the pipe 401 does not flow toward the membrane sensor 45, but is guided to a subsequent process of the monitoring device 4.
  • the membrane sensor 45 has a filtration membrane, and filters the membrane-treated water flowing through the branch pipe 402 using the filtration membrane.
  • the filtration membrane of the membrane sensor 45 is installed in a direction intersecting the flow of the membrane-treated water, and filters the entire amount of the membrane-treated water flowing through the branch pipe 402, capturing the particles to be monitored.
  • the membrane sensor 45 employs a dead-end filtration method.
  • the filtration membrane of the membrane sensor 45 has a pore size smaller than the particles to be monitored.
  • the term “dead-end filtration method” refers to a method in which a filtration membrane that filters treated water such as membrane-treated water or biologically treated water is installed in a direction that intersects (specifically, perpendicular to) the flow of the treated water flowing through the branch pipe 402, and filters the entire amount of treated water flowing through the branch pipe 402.
  • the term “cross-flow filtration method” refers to a method in which a filtration membrane that filters treated water such as membrane-treated water or biologically treated water is installed in a direction that is parallel to the flow of the treated water flowing through the branch pipe 402, and filters a portion of the treated water flowing through the branch pipe 402.
  • the particles to be monitored that are captured by the filtration membrane of the membrane sensor 45 are particles that are not contained in the membrane-treated water when the membrane used in the membrane process 3 is not damaged, and are particles with a diameter of, for example, about 3 ⁇ m or more.
  • Examples of the particles to be monitored that are captured by the filtration membrane of the membrane sensor 45 include Cryptosporidium and Giardia.
  • the particles other than the particles to be monitored that are captured by the filtration membrane of the membrane sensor 45 are particles that are contained in the membrane-treated water even when the membrane used in the membrane process 3 is not damaged, and are particles with a diameter of, for example, less than about 1 ⁇ m.
  • Examples of the particles other than the particles to be monitored that are captured by the filtration membrane of the membrane sensor 45 include proteins, etc. The filtration membrane of the membrane sensor 45 will be described in detail later.
  • the differential pressure sensor 46 measures the differential pressure between a first pressure of the membrane-treated water at a first position A1 on the upstream side (i.e., the primary side) of the membrane sensor 45 and a second pressure of the membrane-treated water at a second position A2 on the downstream side (i.e., the secondary side) of the membrane sensor 45.
  • the differential pressure sensor 46 of this embodiment is an example of a "pressure sensor" of the present invention.
  • the first position A1 is an arbitrary position of the branch pipe 402 on the upstream side of the membrane sensor 45.
  • the second position A2 is an arbitrary position of the branch pipe 402 on the downstream side of the membrane sensor 45.
  • the differential pressure sensor 46 calculates the filtration resistance as a monitoring index, and detects leakage of the particles to be monitored based on the filtration resistance. For example, the differential pressure sensor 46 calculates the filtration resistance by dividing the pressure difference between the first pressure and the second pressure by the filtration flux.
  • the "filtration flux" refers to the amount of membrane filtrate water per unit membrane area and unit time (m 3 /(m 2 ⁇ d) or m/d), and for example, refers to the amount of membrane filtrate water per membrane area (1 m 2 ) per day (m 3 /d).
  • the differential pressure sensor 46 detects leakage of the particles to be monitored based on the ratio between the time average value of the filtration resistance at the first timing and the time average value of the filtration resistance at the second timing later than the first timing.
  • the second timing is a time that is more than 1 hour and less than 6 hours later than the first timing.
  • the differential pressure sensor 46 may calculate the filtration resistance based only on the differential pressure between the first pressure and the second pressure, and detect leakage of the monitored particles based on the filtration resistance.
  • the filtration flux in the membrane sensor 45 of this embodiment is, for example, about 5 m/d, which is higher than the filtration flux in a typical membrane separation activated sludge process (generally 1 m/d or less).
  • a first pressure sensor that measures the first pressure of the membrane-treated water at the first position A1 and a second pressure sensor that measures the second pressure of the membrane-treated water at the second position A2 may be provided.
  • the control unit calculates the differential pressure between the first pressure and the second pressure based on the detection signal related to the first pressure received from the first pressure sensor and the detection signal related to the second pressure received from the second pressure sensor.
  • the flow sensor 47 measures the flow rate of the membrane-treated water flowing through the branch pipe 402 downstream of the membrane sensor 45 (i.e., the secondary side).
  • the monitoring device 4 uses a dead-end filtration type membrane sensor 45, the flow rate of the membrane-treated water flowing through the branch pipe 402 is almost the same everywhere. Therefore, the location of the flow sensor 47 is not limited to the downstream side of the membrane sensor 45, but may be upstream of the membrane sensor 45.
  • the monitoring device 4 may further include a concentration equalization means 41, a water supply adjustment valve 43, a water supply pump 44, and an air vent valve 48.
  • the concentration equalizing means 41 is provided upstream of the membrane sensor 45. Specifically, the concentration equalizing means 41 is provided in the pipe 401 upstream of the portion where the branch pipe 402 is connected to the pipe 401 (i.e., the branch portion).
  • the concentration equalizing means 41 can equalize the concentration of the membrane-treated water. Examples of the concentration equalizing means 41 include a line mixer and an agitator.
  • the water supply rate adjustment valve 43 is provided in the branch pipe 402 between the water supply switching valve 42 and the water supply pump 44, and adjusts the flow rate of the membrane-treated water flowing through the branch pipe 402.
  • the water supply rate adjustment valve 43 may be placed on the discharge side of the water supply pump 44 as long as it can adjust the flow rate of the membrane-treated water flowing through the branch pipe 402.
  • the water supply rate adjustment valve 43 may not be provided, and the flow rate of the membrane-treated water flowing through the branch pipe 402 may be adjusted by the water supply switching valve 42.
  • the water supply rate adjustment valve 43 can be omitted when a variable flow rate constant flow pump is used as the water supply pump 44, or when a flow rate varying means such as an inverter is provided in the water supply pump 44.
  • the water supply pump 44 is provided in the branch pipe 402 between the water supply rate adjustment valve 43 and the membrane sensor 45, and draws the membrane-treated water from the pipe 401 toward the branch pipe 402 and sends the drawn membrane-treated water toward the membrane sensor 45.
  • the air vent valve 48 is provided in the air exhaust pipe 403, and can vent air that has become mixed in the membrane-treated water flowing through the branch pipe 402 toward the membrane sensor 45 through the air exhaust pipe 403.
  • the air exhaust pipe 403 is connected to the branch pipe 402 upstream of the membrane sensor 45. By opening the air vent valve 48, air that has become mixed in the membrane-treated water can be vented through the air exhaust pipe 403.
  • Air mixed in the membrane-treated water flowing through the branch pipe 402 toward the membrane sensor 45 is lighter than the membrane-treated water, which is liquid, and therefore tends to accumulate at the top of the branch pipe 402 in the vertical direction. Therefore, it is desirable to install the air vent valve 48 at the top of the branch pipe 402 in the vertical direction.
  • the pipe (branch pipe 402 in FIG. 1) that leads the membrane-treated water to the membrane sensor tends to be longer than the case of the cross-flow filtration method as described above in Patent Document 1 and Patent Document 2, so air is likely to accumulate inside the pipe that leads the membrane-treated water to the membrane sensor.
  • the air vent valve 48 can eliminate air accumulation in the branch pipe 402, thereby improving the measurement accuracy of the differential pressure sensor 46. Therefore, the detection accuracy of the membrane sensor 45 can be improved.
  • the membrane sensor 45 of this embodiment employs a dead-end filtration method. Therefore, the filtration membrane of the membrane sensor 45 can capture more particles to be monitored than a membrane sensor that employs a cross-flow filtration method. This allows the monitoring device 4 of this embodiment to improve the sensitivity in detecting particles to be monitored. However, since the sensor membrane that employs the dead-end filtration method filters the entire amount of treated water, it also captures more particles other than the particles to be monitored than a membrane sensor that employs a cross-flow filtration method.
  • a membrane sensor that employs the dead-end filtration method may require more frequent replacement of the filtration membrane that captures the particles to be monitored, or may be more likely to erroneously detect leakage of the particles to be monitored, compared to a membrane sensor that employs a cross-flow filtration method.
  • the filtration membrane of the membrane sensor 45 has a pore size smaller than the particles to be monitored.
  • the pore size distribution of the holes formed in the filtration membrane of the membrane sensor 45 is narrower than a predetermined distribution. Since the dead-end filtration method is adopted and the pore size of the filtration membrane of the membrane sensor 45 is more uniform, the filtration membrane of the membrane sensor 45 can transmit particles other than the particles to be monitored (e.g., proteins smaller than the particles to be monitored), while more reliably capturing the particles to be monitored (e.g., Cryptosporidium, Giardia, etc.).
  • the monitoring device 4 can suppress false detection of leakage of the particles to be monitored and improve the sensitivity in detecting the particles to be monitored.
  • the protein adsorption rate of the filtration membrane of the membrane sensor 45 is smaller than a predetermined value. Therefore, it is possible to suppress the adsorption of proteins contained in the treated water as particles other than the particles to be monitored to the filtration membrane of the membrane sensor 45. As a result, the monitoring device 4 according to this embodiment can reduce the frequency of replacing the filtration membrane of the membrane sensor 45.
  • FIG. 2 is a schematic cross-sectional view showing the filtration membrane of the membrane sensor of the present embodiment.
  • FIG. 3 is a schematic cross-sectional view showing a filtration membrane of a membrane sensor of a comparative example. 2(a) and 3(a) show the state before the monitored particle 52 is trapped by the filtration membrane, while Fig. 2(b) and 3(b) show the state after the monitored particle 52 is trapped by the filtration membrane.
  • the particle size of the protein mentioned above as an example of particles 51 other than the target of monitoring is smaller than the target particle 52.
  • proteins are known to adsorb to the surfaces of materials such as plastics, glass, and metals when dissolved in water.
  • the protein concentration is higher not only in the water to be treated but also in treated water such as biologically treated water and membrane treated water, compared to when the water to be treated is inorganic wastewater.
  • the filtration membrane 451A of the membrane sensor 45A of the comparative example will be described with reference to Figures 3(a) and 3(b).
  • the pore size distribution of the pores formed in the filtration membrane 451A is relatively wide. In other words, the diameters of the pores formed in the filtration membrane 451A are relatively non-uniform.
  • materials for the filtration membrane 451A of the comparative example include cellulose acetate (CA), polyvinylidene fluoride (PVDF), and polytetrafluoroethylene (PTFE).
  • the filtration membrane 451A of the comparative example When the pore size distribution is relatively wide, i.e., when the pore size is relatively non-uniform, as in the filtration membrane 451A of the comparative example, many particles 51 other than the monitored object, such as proteins, are captured by the filtration membrane 451A. That is, as shown in FIG. 3(a), even if the membrane used in the membrane process 3 is not damaged, many particles 51 other than the monitored object are captured by the filtration membrane 451A. Therefore, even if the membrane used in the membrane process 3 is not damaged, the differential pressure between the first pressure and the second pressure described above with reference to FIG. 1 may become the same differential pressure as when the membrane used in the membrane process 3 is damaged.
  • the differential pressure sensor 46 may erroneously detect that the membrane used in the membrane process 3 is damaged.
  • many particles 51 other than the monitored particles are captured by the filtration membrane 451A. Therefore, as shown in FIG. 3B, when the membrane used in the membrane process 3 is damaged and the monitored particles 52 are captured by the filtration membrane 451A, the pressure difference between the first pressure and the second pressure, in other words, the filtration resistance as a monitoring index, may not show an inflection point.
  • the filtration membrane 451A may be clogged with particles 51 other than the monitored particles, the replacement frequency of the filtration membrane 451A may increase.
  • the filtration membrane 451 of the membrane sensor 45 of this embodiment has holes 452 with a smaller diameter than the particle 51 to be monitored.
  • the pore size distribution of the holes 452 formed in the filtration membrane 451 is narrower than a predetermined distribution. In other words, the diameter of the holes 452 formed in the filtration membrane 451 is relatively uniform.
  • the pore size distribution of the holes 452 formed in the filtration membrane 451 is narrower than the pore size distribution of cellulose acetate (CA), polyvinylidene fluoride (PVDF), and polytetrafluoroethylene (PTFE).
  • CA cellulose acetate
  • PVDF polyvinylidene fluoride
  • PTFE polytetrafluoroethylene
  • the filtration membrane 451 of this embodiment may be a track-etched membrane made of polycarbonate (PC), polyester (PEs), or the like.
  • PC polycarbonate
  • PEs polyester
  • the term "track-etched membrane” refers to a filtration membrane manufactured using an etching process using an ion beam.
  • the track-etched membrane has characteristics such as a narrow pore size distribution and a thin membrane thickness compared to polytetrafluoroethylene (PTFE) and the like.
  • PTFE polytetrafluoroethylene
  • an example of the material for the filtration membrane 451 is Isopore (registered trademark) manufactured by Merck & Co.
  • the pore size of the filtration membrane 451 of the membrane sensor 45 of this embodiment is large enough to capture particles to be monitored, such as cryptosporidium and giardia, and also large enough to allow particles not to be monitored, such as proteins, to pass through.
  • the filtration membrane 451 of this embodiment can allow many particles 51 other than the target particles 51, such as proteins, whose particle size is smaller than the target particles 52, to pass through the holes 452. Also, as shown in FIG. 2(b), the filtration membrane 451 can capture the target particles 52 more reliably. Therefore, the monitoring device 4 according to this embodiment can suppress false detection of leakage of the target particles 52 and improve the sensitivity in detecting the target particles 52.
  • the protein adsorption rate of the filtration membrane 451 is smaller than a predetermined value.
  • the protein adsorption rate of the filtration membrane 451 is smaller than the protein adsorption rates of cellulose acetate (CA), polyvinylidene fluoride (PVDF), and polytetrafluoroethylene (PTFE).
  • the protein adsorption rate of Isopore manufactured by Merck is 3 ⁇ g/cm 2 , which is smaller than the protein adsorption rate (4 ⁇ g/cm 2 ) of Omnipore (registered trademark), a hydrophilic polytetrafluoroethylene (PTFE) manufactured by Merck.
  • the monitoring device 4 can reduce the frequency of replacement of the filtration membrane 451 provided in the membrane sensor 45.
  • the differential pressure sensor 46 calculates the filtration resistance by dividing the differential pressure between the first pressure and the second pressure by the filtration flux, and detects leakage of the monitored particles 52 based on the ratio between the time average value of the filtration resistance at the first timing and the time average value of the filtration resistance at the second timing that is later than the first timing. This allows the monitoring device 4 according to this embodiment to detect leakage of the monitored particles 52 with higher accuracy, regardless of temporal fluctuations in the flow rate of the membrane-treated water flowing through the branch pipe 402.
  • the differential pressure sensor 46 may calculate the filtration resistance based only on the differential pressure between the first pressure and the second pressure, and detect leakage of the monitored particles 52 based on the filtration resistance. Even in this case, the monitoring device 4 according to this embodiment can detect leakage of the monitored particles 52 with higher accuracy.
  • the air vent valve 48 opens for approximately one minute about once a day. This allows the monitoring device 4 of this embodiment to vent air that has become mixed in the membrane-treated water and suppress variation in the filtration resistance value, which is a monitoring index. This allows the monitoring device 4 to detect the particles 52 to be monitored with higher accuracy and detect leakage of the particles 52 to be monitored with higher accuracy.
  • the concentration equalizing means 41 is provided upstream of the membrane sensor 45, and can equalize the concentration of the membrane-treated water.
  • the monitoring device 4 according to this embodiment can reduce the concentration polarization of solids in the entire membrane-treated water. Therefore, even if the flow rate of the membrane-treated water flowing through the branch pipe 402 is relatively small compared to the total flow rate of the membrane-treated water flowing through the pipe 401, leakage of the monitored particles 52 can be detected with higher accuracy.
  • FIG. 4 is a graph illustrating an example of the results of a study carried out by the present inventors.
  • the horizontal axis of the graph shown in Fig. 4 represents the filtration time (min), and the vertical axis of the graph shown in Fig. 4 represents the filtration resistance (kPa/(m/d)).
  • Isopore (material: PC) manufactured by Merck is a track-etched membrane.
  • first material 455" and Omnipore (material: PTFE) manufactured by Merck will be referred to as the "second material 456.”
  • the nominal pore size of the first material 455 is 1.2 ⁇ m, which is approximately the same as the nominal pore size (1.0 ⁇ m) of the second material 456.
  • the protein adsorption rate of the first material 455 is lower than that of the second material 456, but is approximately the same.
  • the pore size distribution of the first material 455 is narrower than that of the second material 456.
  • the diameter of the filtration membrane is ⁇ 47 mm.
  • the liquid to be filtered is tap water.
  • the inventor added sludge to the tap water 60 to 90 minutes after the start of filtration.
  • the sludge has an MLSS of 10,790 mg/L.
  • the sludge addition rate is 100 ppm.
  • the turbidity of the liquid to be filtered passed through the filtration membrane of the first material 455 is 0.12 NTU.
  • the turbidity of the liquid to be filtered passed through the filtration membrane of the first material 455 is 0.44 NTU.
  • the turbidity of the liquid to be filtered passed through the filtration membrane of the second material 456 is 0.10 NTU.
  • the turbidity of the liquid to be filtered passed through the filtration membrane of the second material 456 is 0.48 NTU.
  • the temperature of the liquid to be filtered passing through the filtration membrane of the first material 455 is 21.2°C.
  • the temperature of the liquid to be filtered passing through the filtration membrane of the second material 456 is 22.5°C.
  • the filtration flux is 40 m/d.
  • the inventor used a portable turbidity meter 2100P manufactured by HACH as the turbidity meter.
  • the inventor also used a pressure sensor instead of a differential pressure sensor.
  • the inventors also calculated the filtration resistance R using the following formula.
  • R(kPa/(m/d)) ((Pf1-Pf2)-(Ps1-Ps2))/F
  • R Filtration resistance
  • Pf1 Primary filtration pressure during filtration [kPa]
  • Pf2 secondary pressure during filtration [kPa]
  • Ps1 Primary filtration pressure when filtration is stopped [kPa]
  • Ps2 Filtration secondary pressure when filtration is stopped [kPa]
  • F filtration flux [m / d]
  • Primary filtration side The water to be filtered side, i.e., the upstream side of the filtration membrane
  • Secondary filtration side The membrane-filtered water side, i.e., the downstream side of the filtration membrane
  • the nominal pore size and protein adsorption rate of the first material 455 are approximately the same as the nominal pore size and protein adsorption rate of the second material 456, so the difference in the change in filtration resistance over time shown in FIG. 4 is thought to be due to the narrowness of the pore size distribution.
  • the capture rate of particles smaller than the pore size is lower than that in the second material 456. Therefore, the progress of clogging of the filtration membrane is slower than in the second material 456.
  • the clogging mechanism of the filtration membrane of the first material 455 is different from that of the second material 456. Therefore, it is believed that a clear inflection point has occurred in the filtration resistance of the first material 455.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
PCT/JP2022/041370 2022-11-07 2022-11-07 監視装置 Ceased WO2024100713A1 (ja)

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IL319065A IL319065A (en) 2022-11-07 2022-11-07 Monitoring device
PCT/JP2022/041370 WO2024100713A1 (ja) 2022-11-07 2022-11-07 監視装置
CN202280100213.4A CN119894593A (zh) 2022-11-07 2022-11-07 监视装置
JP2024556846A JPWO2024100713A1 (https=) 2022-11-07 2022-11-07
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JPS6025510A (ja) * 1983-07-22 1985-02-08 Asahi Chem Ind Co Ltd 「ろ」
JPH0621728U (ja) * 1992-08-26 1994-03-22 水道機工株式会社 透過膜によるろ過装置
JPH0634730U (ja) * 1992-10-01 1994-05-10 エヌオーケー株式会社 濾過装置
JPH06182164A (ja) * 1992-12-16 1994-07-05 Kurita Water Ind Ltd 膜分離装置
JPH0760073A (ja) * 1993-08-27 1995-03-07 Kurita Water Ind Ltd 膜分離装置
JPH07248290A (ja) * 1994-03-09 1995-09-26 Maezawa Ind Inc 膜濾過装置における膜破損時のリーク検出器
JPH08252440A (ja) * 1995-03-16 1996-10-01 Japan Organo Co Ltd 膜破損検出方法及び装置
JP2000279769A (ja) * 1999-03-29 2000-10-10 Nkk Corp 膜破損検知方法、その装置、および膜分離装置
JP2005185944A (ja) * 2003-12-25 2005-07-14 Tsukishima Kikai Co Ltd 濾過膜破損検出装置
JP2007190467A (ja) * 2006-01-18 2007-08-02 Hitachi Ltd 破断検出装置を有する膜ろ過装置及び膜破断検出方法
US8135547B2 (en) 2006-05-10 2012-03-13 Nanyang Technological University Detection apparatus and method utilizing membranes and ratio of transmembrane pressures
WO2015146682A1 (ja) * 2014-03-28 2015-10-01 シャープ株式会社 濾過用具
US10159941B2 (en) 2010-11-01 2018-12-25 Nanyang Technological University Membrane sensor and method of detecting fouling in a fluid

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JPS59183807A (ja) * 1983-04-04 1984-10-19 Asahi Chem Ind Co Ltd 膜ろ過方法
JPS6025510A (ja) * 1983-07-22 1985-02-08 Asahi Chem Ind Co Ltd 「ろ」
JPH0621728U (ja) * 1992-08-26 1994-03-22 水道機工株式会社 透過膜によるろ過装置
JPH0634730U (ja) * 1992-10-01 1994-05-10 エヌオーケー株式会社 濾過装置
JPH06182164A (ja) * 1992-12-16 1994-07-05 Kurita Water Ind Ltd 膜分離装置
JPH0760073A (ja) * 1993-08-27 1995-03-07 Kurita Water Ind Ltd 膜分離装置
JPH07248290A (ja) * 1994-03-09 1995-09-26 Maezawa Ind Inc 膜濾過装置における膜破損時のリーク検出器
JPH08252440A (ja) * 1995-03-16 1996-10-01 Japan Organo Co Ltd 膜破損検出方法及び装置
JP2000279769A (ja) * 1999-03-29 2000-10-10 Nkk Corp 膜破損検知方法、その装置、および膜分離装置
JP2005185944A (ja) * 2003-12-25 2005-07-14 Tsukishima Kikai Co Ltd 濾過膜破損検出装置
JP2007190467A (ja) * 2006-01-18 2007-08-02 Hitachi Ltd 破断検出装置を有する膜ろ過装置及び膜破断検出方法
US8135547B2 (en) 2006-05-10 2012-03-13 Nanyang Technological University Detection apparatus and method utilizing membranes and ratio of transmembrane pressures
US10159941B2 (en) 2010-11-01 2018-12-25 Nanyang Technological University Membrane sensor and method of detecting fouling in a fluid
WO2015146682A1 (ja) * 2014-03-28 2015-10-01 シャープ株式会社 濾過用具

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See also references of EP4616928A1

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IL319065A (en) 2025-04-01

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