WO2023217486A1 - Infrarot-Strahler mit einer auf eine Reflektorschicht aus Metall aufgebrachten emissiven Schicht und Verwendung der emissiven Schicht - Google Patents
Infrarot-Strahler mit einer auf eine Reflektorschicht aus Metall aufgebrachten emissiven Schicht und Verwendung der emissiven Schicht Download PDFInfo
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- WO2023217486A1 WO2023217486A1 PCT/EP2023/059777 EP2023059777W WO2023217486A1 WO 2023217486 A1 WO2023217486 A1 WO 2023217486A1 EP 2023059777 W EP2023059777 W EP 2023059777W WO 2023217486 A1 WO2023217486 A1 WO 2023217486A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- radiator
- infrared
- emissive layer
- reflector
- Prior art date
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Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
- H05B3/42—Heating elements having the shape of rods or tubes non-flexible
- H05B3/44—Heating elements having the shape of rods or tubes non-flexible heating conductor arranged within rods or tubes of insulating material
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/26—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/002—Heaters using a particular layout for the resistive material or resistive elements
- H05B2203/003—Heaters using a particular layout for the resistive material or resistive elements using serpentine layout
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/013—Heaters using resistive films or coatings
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/032—Heaters specially adapted for heating by radiation heating
Definitions
- Infrared emitter with an emissive layer applied to a metal reflector layer and use of the emissive layer
- the invention relates to an infrared radiator, comprising a radiator shaped body with a reflector layer made of metal applied thereon.
- the invention further relates to the use of an emissive layer with an emissivity which is in the range from 0.81 to 0.99 in the wavelength range from 0.78 pm to 5 pm.
- Infrared emitters within the meaning of the invention are designed to emit radiation in the infrared spectral range. They have a shaped radiator body and can be divided into short-wave, medium-wave and long-wave infrared emitters according to their main emission wavelength.
- Typical radiator moldings of known infrared radiators have a cylindrical shape, for example tube, plate or tile shape.
- Tubular infrared emitters can be stretched or curved, for example in a U or ring shape.
- Plate or tile-shaped spotlight moldings have two opposite sides that can be flat or curved.
- Known infrared radiators also include a radiation emitter, for example a heating band or a heating coil or a resistance element arranged within a radiator tube, which is applied, for example, to a plate-shaped radiator molding or incorporated into it.
- the radiator molding is often made of quartz glass or ceramic.
- the radiator molding serves the protection of the radiation emitter, for example against mechanical or chemical stress, and can contribute to the emission of infrared radiation and the distribution of radiation.
- a shaped radiator body in the form of a radiator tube can be open or closed. In the latter case, it is often filled with an inert gas to protect the radiation emitter from oxidation.
- the radiator molded body has a radiation surface for emitting infrared radiation.
- the radiating surface and the reflector layer do not overlap each other; they are regularly arranged on opposite sides of the radiator molding.
- Infrared emitters are used to heat items to be heated in a wide variety of industrial manufacturing processes. It is often desirable to operate the infrared radiators with the greatest possible electrical power density.
- infrared emitters are often assigned a reflector. This causes the radiation emission to be reduced in certain spatial directions and increased in other spatial directions. This can be done with an external, separate reflector.
- an infrared radiator with a reflector layer applied to the radiator molding has a particularly compact design.
- a short-wave infrared emitter with a gold reflector applied to the emitter tube is known, for example, from DE 10 2013 104 577 B3.
- the limited thermal stability of the metal layer proves to be a disadvantage. This is especially true if the infrared heater has a large electrical power density is to be operated and, in addition, the reflector layer is applied to the radiator shaped body, which is already exposed to high temperatures.
- cooling of the reflector layer is regularly necessary at operating temperatures above 800 ° C - as described in DE 40 22 100 C1.
- Air or water cooling also has the disadvantage that turbulence can occur, which can impair the heating of the material to be heated.
- a reflector layer made of metal instead of reflector layers made of metal, layers made of other materials are used, for example a reflector layer made of opaque quartz glass, as proposed in DE 102006 062 166 A1.
- a layer made of opaque quartz glass acts as a diffuse reflector. With diffuse reflectors, radiation losses can occur due to multiple reflections, which can affect the radiation efficiency of the infrared emitter.
- a specularly reflective layer made of metal is also characterized by a smaller layer thickness.
- the reflector layer shows limited thermal stability.
- the reflector layer temperature above which the infrared radiator needs to be cooled with great effort, depends on the metal from which the reflector layer is made.
- a reflector layer made of gold cooling is required from a reflector layer temperature of more than 800 ° C, with a reflector layer made of silver from a reflector layer temperature of more than 700 ° C and with a reflector layer made of aluminum from a reflector layer temperature of 400 °C.
- the invention is based on the object of specifying a new use for an emissive layer whose emissivity is in the range from 0.81 to 0.99 in the wavelength range from 0.78 pm to 5 pm.
- this task is solved according to the invention, starting from an infrared radiator of the type mentioned at the outset, in that an emissive layer is applied to the reflector layer, the emissivity of which is at least a factor of 10 greater over a wavelength range of 0.78 pm to 5 pm as the emissivity of the reflector layer at the same wavelength and temperature.
- the electrical power density with which the infrared emitters can be operated at their maximum (with or without additional cooling) over a reasonable period of time is limited.
- the reason for this is the limited thermal stability of the reflector layer made of metal, which can show signs of decomposition due to evaporating metal particles above a temperature that depends on the respective metal.
- the present invention is based on the idea of counteracting the evaporation of metal particles by increasing the energy radiation of the reflector layer, namely by covering the reflector layer with an emissive layer. This is based on the following consideration:
- metal reflector layers regularly have a high degree of reflection and a low degree of absorption and transmission.
- a reflector layer made of gold in the above-mentioned wavelength range regularly shows a reflectance of over 0.95 and a total absorption and transmittance of less than 0.05.
- the degree of absorption a corresponds to the degree of emissivity £.
- the reflector layer therefore has a comparatively low emissivity £.
- the emissivity £ has a significant influence on the temperature of the radiator molding and the infrared radiator as a whole.
- the reflector layer - as proposed according to the invention - is coated with an emissive layer whose emissivity £ is greater than that of the reflector layer, the overall radiation of the infrared radiator increases, as a result of which the surface of the infrared radiator is passively cooled.
- the reflector layer and the emissive layer together form a layer composite with good radiation, which as a whole has a higher overall emissivity than the reflector layer alone.
- the reflector layer is the lower, inner layer of the layer composite facing the radiator molding.
- the emissive layer forms the upper, outer layer.
- the emissive layer increases emissions compared to the reflector layer. This allows either - the infrared emitter can be fed with a greater electrical power until the same temperature is reached, or
- the temperature of the infrared radiator can be reduced so that cooling that would otherwise be necessary can be reduced.
- This has the particular advantage of reduced convection when cooling with air or water, which can have a detrimental effect on an irradiation process.
- the reflector layer is located between the radiator molding and the emissive layer. Since the emissive layer is closed and covers the reflector layer, it prevents or reduces the evaporation of particles from the reflector layer and thus contributes to extending the lamp's service life.
- the emissivity £ of the emissive layer is increased by at least a factor of 10, preferably by at least a factor of 25, particularly preferably by at least a factor of 40, over a wavelength range from 0.78 pm to 5 pm. is greater than the emissivity £ of the reflector layer at the same wavelength and temperature.
- the wavelength range from 0.78 pm to 5 pm captures the main emission wavelengths of short-wave, medium-wave and long-wave infrared emitters. Factor deviations in the wavelength ranges below 0.78 pm and above 5 pm are therefore only of minor importance when using an emissive layer on a reflector layer of an infrared emitter.
- the reflector layer is preferably coated with a black emissive layer, because a black emissive layer regularly shows a good emissivity £ over a wide wavelength range.
- the emissivity £ of the emissive layer is in the range from 0.81 to 0.99 in the wavelength range from 0.78 pm to 5 pm.
- Such an emissive layer has a high emissivity £.
- a standard reflector layer made of gold with an emissivity £ of 0.02 This corresponds to a factor of more than 40.
- a standard reflector layer made of aluminum with an emissivity £ of 0.05 this corresponds to a factor of 16.
- Such an emissive layer is ideal for passive cooling of a reflector layer applied to a shaped radiator body.
- the emissivity £ of the emissive layer is advantageously at least 0.85.
- the emissive layer advantageously contains an inorganic color pigment.
- the emissive layer is preferably made from a coating material that contains a color pigment or a precursor substance for it.
- the coating material is, for example, a paste or a varnish.
- the color pigment is thermally stable and is fixed on the deposition surface, for example by baking.
- the color pigment can also be formed by thermal decomposition or chemical reaction of a precursor substance during or before baking.
- the color pigment emits infrared radiation either in a wide wavelength range, for example from 2,000 nm to 8,000 nm, in particular from 2,000 nm to 4,700 nm, with an emissivity £ of 0.81 or higher, or in a narrow wavelength range, for example around 2,750 nm with an emissivity £ of 0.81 or higher, preferably at least 0.9.
- the color pigment contains black mineral particles and is alkali-free.
- the emissive layer is preferably a black ceramic-based lacquer layer.
- Color pigments that appear black in the visible wavelength range usually also absorb (and emit) light in the relevant infrared wavelength range. It has proven useful if the color pigment contains black mineral particles, such as copper chromium, black spinel or manganese femt black pigment and if it is alkali-free.
- the alkali-free nature of the coating material has the advantage that a surface made of glass, in particular made of quartz glass, does not devitrify when heated in contact with the coating material, i.e. does not crystallize and thereby loses its optical quality. It has proven useful if the emissive layer comprises opaque quartz glass.
- Such an at least partially opaque quartz glass is in the
- QRC Quadrat Reflective Coating
- the QRC reflector layer is produced using a slip process in which a highly filled, pourable, aqueous SiO2 slip is produced which contains amorphous SiO2 particles. This is applied as a layer of slip on a base, and then the layer of slip is dried and vitrified to form a more or less opaque layer of quartz glass.
- the color pigment-containing coating material and the opaque quartz glass complement each other in their emissivity, and the opaque quartz glass can act as an adhesion promoter to the coating material, particularly in the case of a base body made of quartz glass.
- the opaque quartz glass preferably forms a lower layer and the color pigment-containing coating material forms an upper layer of the emissive layer.
- the lower layer made of opaque quartz glass can itself act as a reflector and, on the other hand, it contributes to improving the adhesion of the upper layer made of the coating material.
- the layer underneath also absorbs some of the infrared radiation and re-emits it.
- the additional upper layer made of the coating material causes an increase in the emissivity £ in the relevant wavelength range. In addition, it also causes a higher absorption of the short-wave or medium-wave primary radiation and thus enables the infrared heater to heat up more quickly (and thus be ready for use earlier).
- the lower layer made of opaque quartz glass shows, on the one hand, a certain transmission for the short-wave or medium-wave primary radiation and, on the other hand, it can also act as a diffuse reflector for the primary radiation. It has proven useful if the emissive layer has a layer thickness in the range from 1 pm to 200 pm, preferably in the range from 30 pm to 100 pm.
- a layer thickness of less than 1 pm With a layer thickness of less than 1 pm, the passive cooling effect of the emissive layer is lost.
- a layer thickness of more than 200 pm can only be achieved by applying multiple layers.
- the risk that the emissive layer will peel off when it is exposed to temperature differences during operation increases.
- the emissive layer is heat-resistant up to at least 1,000°C, preferably at least up to 1,200°C. It has been shown that good heat resistance of the emissive layer is associated with a longer service life of the reflector layer and thus of the infrared emitter.
- the infrared emitter is advantageously designed uncooled under standard conditions to generate an electrical power density of up to 80 W/cm: for example, in the case of a twin tube with a diameter of 23 mm x 11 mm, to generate an electrical power density of up to 80 W /cm and in the case of a round tube with a 10 mm diameter up to 40 W/cm.
- the radiator molding is a radiator tube made of quartz glass.
- the radiator tube preferably surrounds a radiation emitter provided with a power connection in the form of a heating coil or a heating band.
- the radiator tube has, for example, a round, oval or polygonal cross section or it is designed as a so-called twin tube radiator, which has a cross section in the form of a horizontally lying figure of eight.
- the outer wall of the radiator tube is, for example, smooth or roughened.
- Short-wave infrared emitters in particular have a piston-shaped emitter tube that is closed on both sides, with the power supply being led out at one end or at both ends.
- the radiator tube material is, for example, quartz glass and has a comparatively low inherent emissivity for infrared radiation, especially in the wavelength range around 2,200 nm to 3,100 nm.
- the radiator tube has a radiation surface, which is usually located on the radiator tube jacket surface.
- the reflector layer lies opposite the radiating surface. By completely coating the reflector layer with an emissive layer, the reflector layer is
- the radiating surface, the reflector layer and the emissive layer each cover, for example, a partial surface of the radiator tube jacket surface, with the radiating surface not overlapping with the surface of the reflector layer and not with the surface of the emissive layer. It is advantageous if the radiation surface, the surface of the reflector layer and the surface of the emissive layer overlapping the reflector surface complement each other in such a way that they cover the entire lateral surface.
- the emissive layer covers at least 80% of the reflector layer.
- the emissive layer preferably completely covers the reflector layer.
- the emissive layer is dimensioned such that it protrudes beyond the reflector layer on all sides. This ensures that the reflector layer is completely protected by the emissive layer even in the event of an unintentional, for example production-related, minimal displacement of the emissive layer relative to the reflector layer. This increases the thermal stability of the reflector layer.
- both the radiating surface and the reflector layer surface and the surface of the emissive layer each have a straight side running parallel to the longitudinal axis of the radiator tube and a curved side running in a radiator tube cross-sectional plane, whereby the straight side extends over the entire length of the radiator tube or part of it.
- the curved side can be described by the position of the radiator tube's longitudinal axis as the center point by the center angle in the cross-sectional plane and the outer radius of the radiator tube.
- the reflector surface extends over a center angle in the range from 0 degrees to 270 degrees, particularly preferably over a center angle in the range from 0 degrees to 180 degrees.
- the curved side of the emissive layer is 5% larger than the curved side of the reflector layer, with the emissive layer being arranged in relation to the reflector layer in such a way that it overlaps the reflector layer on both sides.
- the surface covered with the emissive layer particularly preferably extends over a center angle between 0 degrees and 275 degrees, particularly preferably between 0 degrees and 195 degrees.
- At least part of the radiator tube jacket surface has a surface roughness - defined as the arithmetic mean roughness R a - with R a in the range of 0.5 pm to 5 pm, preferably in the range from 0.8 pm to 3.2 pm, of which a first peripheral section is covered with the reflector layer.
- the roughness with an R a value of 0.8 pm corresponds to roughness class 6 and is typically achieved during rough grinding, and the R a value of 3.2 pm corresponds to roughness class 8, which defines roughed surfaces.
- the tube surface of the cladding tube is preferably only roughened where the reflector layer or the emissive layer is to be applied. The roughening improves the adhesion of the reflector layer and the emissive layer, particularly in the case of an emissive layer in the form of a coating material containing color pigment, such as a lacquer or a paste.
- the surface is roughened, for example, mechanically or chemically, in particular by grinding, sandblasting or etching.
- the radiator molded body is designed in the form of a tile made of a material that emits infrared radiation when heated, the tile having opposing flat sides, of which the first flat side has the reflector layer and the emissive Layer is occupied, and the other, second plan side is the radiation surface determined.
- the second plan side is preferably applied with an electrical contact for supplying a heating current to a heating conductor track made of a resistance material connected thereto.
- Tile-shaped infrared radiators are surface radiators with generally predominantly two-dimensional radiation characteristics.
- the tile material is preferably a ceramic, in particular Al2O3 or ZrO2, or it comprises a composite material, in particular a matrix made of quartz glass, in which elemental silicon or carbon is embedded.
- the possible size of the tile surface depends on the properties of the material and the required dimensional stability.
- the pigment-containing coating material and the opaque quartz glass lose little or no of their emissivity even at high temperatures up to, for example, 1,100 ° C.
- the emissivity £ indicates how much radiation a body emits compared to a black body. According to Kirchhoff's radiation law, the radiation power emitted by any body is equal to that of the black body of the same temperature multiplied by the emissivity of the arbitrary body. The following applies:
- the emissivity £ is determined as follows:
- the emissivity at room temperature is measured with an integrating sphere. This allows the measurement of the directional hemispheric spectral reflectance R g h and the directional hemispheric spectral transmittance T g h, from which the normal spectral emissivity is calculated.
- the measurement of the degree of reflection and transmittance in the wavelength range of 0.78 pm - 2.5 pm can be done, for example, with a Perkin Elmer Lambda 950 grating spectrometer. In the wavelength range from 1.4 pm to 18 pm, for example, a Bruker IFS 66v Fourier transform infrared (FTIR) spectrometer can be used.
- FTIR Fourier transform infrared
- the emissivity is measured at higher temperatures in the wavelength range from 0.7 to 5 pm using an FTIR spectrometer, for example a Bruker IFS 66v Fourier transform infrared spectrometer (FTIR)), to which a black body is attached via additional optics Boundary Conditions (BBC) sample chamber is coupled.
- FTIR Bruker IFS 66v Fourier transform infrared spectrometer
- BCC Boundary Conditions
- the intensity recorded by the detector is composed of an emission, a reflection and a transmission component, namely intensity that is emitted by the sample itself, intensity that falls on the sample from the front half-space and is reflected by it, and intensity , which falls from the rear half-space onto the sample and is transmitted by it.
- intensity which falls from the rear half-space onto the sample and is transmitted by it.
- the standard conditions are 298.15 K (25°C, 77°F) for temperature and 100 kPa (14.504 psi, 0.986 atm) for absolute pressure.
- total irradiance also: optical power refers to the ratio of the vertically incident radiation power to the impact area. It is measured in the unit W/m 2 .
- the arithmetic mean roughness R a is determined according to EN ISO 25178. It is a line roughness parameter. To determine the measured value R a , the surface of a defined measuring section is scanned (with a fine needle) and all height and depth differences in the surface are recorded. After calculating the definite integral of this roughness curve on the measuring section, the result is divided by the length of the measuring section.
- Figure 1 shows an embodiment of an infrared emitter with a reflector layer made of gold and an emissive layer applied thereon, in cross section and in a schematic representation
- Figure 2a is a photo of an embodiment of an infrared emitter with a twin tube on which a reflector layer made of gold and an emissive layer are applied
- Figure 2b schematically shows the infrared radiator from Figure 2a in a perspective view
- Figure 3 shows a diagram in which the emissivity £ of an emissive layer at different temperatures (25 ° C, 200 ° C, 600 ° C, 800 ° C, 900 ° C and 1,000 ° C) is shown as a function of the wavelength X is,
- FIG. 4 shows a temperature-time diagram in which the temperature profile on the reflector side of an infrared emitter according to the invention coated with a black lacquer and the temperature profile on the reflector side of a conventional infrared emitter are entered,
- FIG. 5 shows a temperature-time diagram in which the temperature profile on the radiation exit side of an infrared emitter according to the invention coated with a black lacquer and the temperature profile on the radiation exit side of a conventional infrared emitter are entered,
- Figure 6 is an irradiance-time diagram in which the irradiance curve of an infrared emitter according to the invention coated with a black lacquer and the irradiance curve of a conventional infrared emitter are entered, and the
- Figures 7, 8 show a second embodiment of an infrared radiator with a planar, plate-shaped radiator molded body.
- Figure 1 shows schematically an infrared radiator according to the invention in cross section, to which the reference number 1 is assigned overall.
- the illustration is not to scale; In particular, the thicknesses of the components and layers can be shown thicker for reasons of better visibility.
- the infrared emitter 1 has a emitter tube 2 made of quartz glass.
- the radiator tube 2 is cylindrical and has a length of 80 mm and a width of 23 mm and a height of 11 mm.
- the radiator tube 2 is closed at both ends; it surrounds a tungsten heating wire (not shown) which is provided with an electrical connection and can be heated to temperatures up to 2,300°C.
- the lateral surface of the radiator tube 2 is semi-tubular (180°) coated with a reflector layer 3 made of gold.
- the reflector layer 3 is made of aluminum or silver.
- the reflector layer 3 has a layer thickness of 0.2 pm and an emissivity of 0.02; it reduces the emissivity in the gold-coated area and causes very good reflection of incident radiation, so that the radiation emitted by the heating wire is essentially emitted in the direction of the lateral surface that is not provided with the reflector layer 3.
- the reflector layer 3 is also coated with an emissive layer 4 made of a black, ceramic-based high-temperature paint, so that the reflector no longer visually appears golden, but black.
- the emissive layer 4 can, under certain circumstances, flake off at high temperatures over several hundred hours.
- the radiator tube surface is roughened before the reflector layer is applied. The area of roughening 6 is symbolized by a dashed line.
- Roughening is done mechanically by sandblasting or grinding or chemically: by treatment with an etching solution.
- a suitable etching solution (NH4 + HF + acetic acid) and its use for roughening a quartz glass surface is described in DE 197 13 014 C2.
- the average roughness depth R a is preferably in the range from 5 pm to 50 pm; in the exemplary embodiment it is 25 pm.
- the emissive layer 4 retains its black color - and thus also its emission spectrum - when heated to 800 ° C and beyond; it is temperature-resistant up to 1,200°C.
- the emissivity of the emissive layer 4 is 0.9.
- the thickness of the emissive layer 4 is approximately 40 pm.
- the uncoated lateral surface of the radiator tube 2 forms the actual radiation surface 5 of the infrared radiator 1. Even at a reflector layer temperature above 600 ° C, gold can evaporate from the reflector layer 3.
- the emissive layer 4 applied to the reflector layer 3 heats up to up to 780° C. during operation with an electrical power density of 2x40 W/cm.
- the emissive layer 4 passively cools the reflector layer 3 by means of radiation during operation of the infrared emitter 1; It thereby counteracts the evaporation of gold particles from the reflector layer 3 and serves as an evaporation barrier and protective varnish.
- the emissive layer 4 not only increases the service life of the infrared emitter 1, but also when the infrared emitter 1 is operated with higher electrical power densities, the radiation output remains stable, whereby the infrared emitter 1 can be used advantageously, particularly in temperature-sensitive processes.
- the reflector layer 3 is created by applying a gold-containing emulsion (gold resinate) to the surface of the radiator tube 2 with a brush. The emulsion is then baked by heating. During baking, the gold resinate breaks down into metallic gold and resin acid, which in turn, like the other components of the paste, are volatilized by the high baking temperature. What remains is a closed, reflective gold layer 4, which acts as a reflector and whose thickness is preferably in the range from 50 nm to 300 nm, depending on the reflectance requirement. The thicker the layer, the greater its reflectance.
- the emissive layer 4 is created by spraying or brushing on a thermal paint.
- the thermal paint is alkali-free. It contains an aluminosilicate solution (10 to 20% by weight), copper chromite black spinel as a mineral color pigment (25 to 35% by weight) and water (40 to 60% by weight).
- Suitable thermal paints are commercially available as oven paints, for example from the companies ULFALUX Lackfabrikation GmbH (e.g. Ulfalux® thermal coating 1590ST) and Aremco Products Inc., with other organic ingredients listed: xylene, ethyl acetate, butyl acetate, ethylbenzene. Repeated painting ensures a completely closed layer.
- the thermal paint After spraying, the thermal paint is dried at 250°C and is then touch-tested.
- the lacquer layer 3 gets its final state by heating to 1,200 ° C. This heating can take place when the infrared heater is put into operation. Ceramic components are sintered onto the lamp tube surface and a solid, cohesive connection is created, so that the emissive layer 4 is largely scratch-resistant.
- the photo of Figure 2a shows a further embodiment of an infrared emitter according to the invention, to which the reference number 21 is assigned.
- the infrared radiator 21 has a radiator tube 22 in the form of a twin tube made of two quartz tubes arranged next to one another.
- the quartz tubes each have a width of 23 mm, a height of 11 mm and a length of 200 mm; they are fused together in the direction of their longitudinal axes and together form a component.
- the twin tube structure enables high radiation density and good mechanical stability. Both quartz tubes of the twin tube each surround a tungsten heating wire (not shown).
- the radiator tube 22 is closed at its two tube ends 25a, 25b.
- the heating tapes are connected in series (not shown) in such a way that the electrical connections 26a, 26b for electrically contacting the heating tapes are led out of the radiator tube 22 via a crimp at one of the radiator tube ends 25b.
- the opposite radiator tube end 25a is fused.
- a gold layer (not visible) is applied to the radiator tube 22 and is covered with an emissive layer 24.
- the emissivity of the gold layer is 0.02 in the wavelength range from 780 nm to 5 pm.
- the emissivity of the emissive layer 24 is 0.85.
- Figure 2b shows a schematically simplified and perspective view of the structure of the infrared emitter 21 from Figure 2a. If the same reference numbers as in FIG. 2a are used in the embodiment of FIG. 2b, this denotes structurally identical or equivalent components and components, as explained in more detail above based on the description of FIG. 2a.
- the carbon heating strips 28a, 28b are connected in series. Their electrical contact is made via the electrical connections 26a, 26b, which are each electrically connected to one of the carbon heating strips 28a, 28b.
- the electrical connections 26a, 26b are each provided with a metal plate of small thickness, preferably made of molybdenum.
- the carbon heating strips 28a, 28b are connected to one another in an electrically conductive manner via the connecting element 27.
- the gold layer 23 has a layer thickness of 0.1 pm to 0.2 pm. It covers the lateral surface of the radiator tube 22 by approximately 50%.
- the emissive layer 24 is applied to the gold layer.
- the emissive layer 24 completely covers the gold layer; it covers approximately 55% of the lateral surface of the radiator tube 22.
- the emissive layer is a color layer made of black thermal dispersion paint with the following composition:
- FIG. 3 shows a diagram in which the emissivity £ of this emissive layer at different temperatures (25 ° C, 200 ° C, 600 ° C, 800 ° C, 900 ° C and 1,000 ° C) is shown as a function of the wavelength X .
- the curve (a) shows the emission curve before heating the paint layer, and (b) the emission curve after heating the paint layer to 1000 ° C and subsequent cooling.
- a temperature change in the above-mentioned range is therefore accompanied by small changes in the emissivity. Due to its good temperature stability combined with low changes in emissivity and at the same time good adhesion properties on a metal layer - in particular made of gold, silver or aluminum - the black emissive layer described above is suitable for use on a radiator tube of an infrared radiator.
- the temperature-time diagram of Figure 4 shows the temperature curves recorded on the reflector side in a conventional infrared radiator with a gold reflector on the one hand and an infrared radiator according to the invention with a coated gold reflector on the other hand.
- the infrared emitter 21 described in FIGS. 2A and 2B was used as the infrared emitter according to the invention; an identical infrared emitter with a reflector layer 23 made of gold, but without an emissive layer 24, served as the conventional infrared emitter.
- the curve 401 was recorded using the conventional infrared emitter without an emissive layer. At temperature equilibrium, the operating temperature T ss is « 857°C.
- the curve 402 was recorded with the infrared radiator 21 according to the invention.
- the emissive layer 24 provided according to the invention shows a good one radiation emission; it acts as passive cooling for the reflector.
- Figure 5 shows in a further temperature-time diagram the temperature curves on the radiation exit side opposite the reflector side, both in a conventional infrared radiator with a gold reflector and in an infrared radiator according to the invention with a coated gold reflector. The measurement with the same measuring arrangement as already described for Figure 4.
- the curve 501 represents the temperature on the radiation exit side of the conventional infrared radiator
- the curve 502 represents the temperature on the radiation exit side of the infrared emitter 21 according to the invention.
- lower operating temperatures are on the radiation exit side in temperature equilibrium reached. This is because the radiation exit side shows high transmission and therefore less radiation is absorbed.
- the same effect of the emissive layer 24 on the reflector layer 23 is also evident on the radiation exit side, namely a reduction in the infrared radiator temperature through passive cooling.
- the diagram shown in Figure 6 shows the integrated total irradiance in the half-space from 90° to 270°, i.e on the radiation exit side, based on the operating time.
- an infrared emitter 21, as described above in detail with reference to FIGS. 2A and 2B, and an identical infrared emitter without an emissive layer 24 were operated for 2,250 hours with a nominal voltage ÜNenn of 100 V and the integrated total irradiance in each case determined.
- the curve 601 was obtained; the curve 602 was obtained with the conventional infrared emitter. It turns out that the integrated total irradiance decreases faster and more strongly with a conventional infrared heater than with an infrared heater whose gold reflector layer is covered with an emissive layer. The emissive layer is therefore associated with an extended service life of the infrared emitter. Lifespan tests have shown that the paint layer or the infrared radiator can achieve an operating life of up to 10,000 hours without any visual or functional impairment.
- FIG 7 shows a side view and Figure 8 shows a sectional view of a second embodiment of an infrared emitter according to the invention, to which the reference number 71 is assigned overall.
- the infrared radiator 71 has a plate-shaped radiator molded body 72, which comprises a matrix 72a made of quartz glass, a conductor track 72c applied to the matrix 72a and a cover layer 72b.
- the plate-shaped radiator molding 72 has a rectangular shape with a plate thickness of 2.5 mm. It consists of a matrix 72a made of quartz glass. The matrix 72a appears visually translucent to transparent. When viewed microscopically, it shows no open pores and at most closed pores with maximum dimensions of less than 10 pm on average.
- the conductor track 72c is made of tantalum.
- the conductor track 72c has a cross-sectional area of at least 0.02 mm 2 with a width of 1 mm and a thickness of 20 pm.
- contacts 72d made of tantalum are welded to the conductor track 72c.
- the contacts 72d have a cross-sectional area of at least 0.5 mm 2 . Because the contacts have a larger cross-sectional area than the conductor track, they show a lower electrical resistance than the conductor track 72c; They are therefore heated less than the conductor track 72c when current flows through them. The contacts therefore lower the temperature, so that electrical contacting of the conductor track 72c via the contacts 72d is simplified.
- the conductor track 72c is firmly connected to that of the matrix 72a by applying a cover layer 72b made of glass to the surface of the matrix 72a provided with the conductor track 72c.
- the cover layer 72b is made of a glass whose Coefficient of thermal expansion in a range between
- the cover layer 72b has an average layer thickness of 1.8 mm.
- the cover layer 72b covers the entire heating area of the radiator shaped body 72. It completely covers the conductor track 72c and thus shields the conductor track 72c from chemical or mechanical influences from the environment.
- a reflector layer 73 made of gold with a layer thickness of 60 pm is applied to the cover layer 72b.
- the reflector layer 73 is coated with an emissive layer 74 with a layer thickness of 100 ⁇ m; it consists of the same thermal paint as mentioned in the description of the embodiment of Figure 1.
- the radiation surface of the infrared radiator 71 is marked with the reference number 75.
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- Surface Treatment Of Glass (AREA)
Abstract
Description
Claims
Priority Applications (3)
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JP2023579433A JP2024525011A (ja) | 2022-05-12 | 2023-04-14 | 金属から成る反射体層に塗布された放射層を有する赤外線放射器及び放射層の使用 |
EP23720065.4A EP4327625A1 (de) | 2022-05-12 | 2023-04-14 | Infrarot-Strahler mit einer auf eine Reflektorschicht aus Metall aufgebrachten emissiven Schicht und Verwendung der emissiven Schicht |
CN202380012846.4A CN117643173A (zh) | 2022-05-12 | 2023-04-14 | 具有施加至由金属制成的反射器层的发射层的红外线辐射器以及该发射层的用途 |
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DE102022111985.8 | 2022-05-12 | ||
DE102022111985.8A DE102022111985A1 (de) | 2022-05-12 | 2022-05-12 | Infrarot-Strahler mit einer auf eine Reflektorschicht aus Metall aufgebrachten emissiven Schicht und Verwendung der emissiven Schicht |
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PCT/EP2023/059777 WO2023217486A1 (de) | 2022-05-12 | 2023-04-14 | Infrarot-Strahler mit einer auf eine Reflektorschicht aus Metall aufgebrachten emissiven Schicht und Verwendung der emissiven Schicht |
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EP (1) | EP4327625A1 (de) |
JP (1) | JP2024525011A (de) |
CN (1) | CN117643173A (de) |
DE (1) | DE102022111985A1 (de) |
WO (1) | WO2023217486A1 (de) |
Citations (11)
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GB1541980A (en) * | 1977-12-08 | 1979-03-14 | Electricity Council | Electric radiant heaters |
DE4022100C1 (de) | 1990-07-11 | 1991-10-24 | Heraeus Quarzglas Gmbh, 6450 Hanau, De | |
DE4021798A1 (de) * | 1990-07-09 | 1992-02-06 | Heraeus Quarzglas | Infrarotstrahler mit geschuetzter reflexionsschicht und verfahren zu seiner herstellung |
US5276763A (en) * | 1990-07-09 | 1994-01-04 | Heraeus Quarzglas Gmbh | Infrared radiator with protected reflective coating and method for manufacturing same |
DE19713014C2 (de) | 1997-03-27 | 1999-01-21 | Heraeus Quarzglas | Bauteil aus Quarzglas für die Verwendung bei der Halbleiterherstellung |
US20040175162A1 (en) * | 2003-03-04 | 2004-09-09 | Heraeus Noblelight Gmbh | Infrared emitter element and its use |
DE102004051846A1 (de) | 2004-08-23 | 2006-03-02 | Heraeus Quarzglas Gmbh & Co. Kg | Bauteil mit einer Reflektorschicht sowie Verfahren für seine Herstellung |
DE102006062166A1 (de) | 2006-12-22 | 2008-06-26 | Heraeus Quarzglas Gmbh & Co. Kg | Quarzglas-Bauteil mit Reflektorschicht sowie Verfahren zur Herstellung desselben |
DE102013104577B3 (de) | 2013-05-03 | 2014-07-24 | Heraeus Noblelight Gmbh | Vorrichtung zum Trocknen und Sintern metallhaltiger Tinte auf einem Substrat |
US20190174580A1 (en) * | 2016-07-27 | 2019-06-06 | Heraeus Noblelight Gmbh | Infrared panel radiator and process for production of the infrared panel radiator |
US20190206671A1 (en) * | 2016-09-22 | 2019-07-04 | Heraeus Noblelight Gmbh | Infrared radiating element |
-
2022
- 2022-05-12 DE DE102022111985.8A patent/DE102022111985A1/de active Pending
-
2023
- 2023-04-14 JP JP2023579433A patent/JP2024525011A/ja active Pending
- 2023-04-14 WO PCT/EP2023/059777 patent/WO2023217486A1/de active Application Filing
- 2023-04-14 EP EP23720065.4A patent/EP4327625A1/de active Pending
- 2023-04-14 CN CN202380012846.4A patent/CN117643173A/zh active Pending
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
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GB1541980A (en) * | 1977-12-08 | 1979-03-14 | Electricity Council | Electric radiant heaters |
DE4021798A1 (de) * | 1990-07-09 | 1992-02-06 | Heraeus Quarzglas | Infrarotstrahler mit geschuetzter reflexionsschicht und verfahren zu seiner herstellung |
US5276763A (en) * | 1990-07-09 | 1994-01-04 | Heraeus Quarzglas Gmbh | Infrared radiator with protected reflective coating and method for manufacturing same |
DE4022100C1 (de) | 1990-07-11 | 1991-10-24 | Heraeus Quarzglas Gmbh, 6450 Hanau, De | |
DE19713014C2 (de) | 1997-03-27 | 1999-01-21 | Heraeus Quarzglas | Bauteil aus Quarzglas für die Verwendung bei der Halbleiterherstellung |
US20040175162A1 (en) * | 2003-03-04 | 2004-09-09 | Heraeus Noblelight Gmbh | Infrared emitter element and its use |
DE102004051846A1 (de) | 2004-08-23 | 2006-03-02 | Heraeus Quarzglas Gmbh & Co. Kg | Bauteil mit einer Reflektorschicht sowie Verfahren für seine Herstellung |
DE102006062166A1 (de) | 2006-12-22 | 2008-06-26 | Heraeus Quarzglas Gmbh & Co. Kg | Quarzglas-Bauteil mit Reflektorschicht sowie Verfahren zur Herstellung desselben |
DE102013104577B3 (de) | 2013-05-03 | 2014-07-24 | Heraeus Noblelight Gmbh | Vorrichtung zum Trocknen und Sintern metallhaltiger Tinte auf einem Substrat |
US20190174580A1 (en) * | 2016-07-27 | 2019-06-06 | Heraeus Noblelight Gmbh | Infrared panel radiator and process for production of the infrared panel radiator |
US20190206671A1 (en) * | 2016-09-22 | 2019-07-04 | Heraeus Noblelight Gmbh | Infrared radiating element |
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JP2024525011A (ja) | 2024-07-09 |
DE102022111985A1 (de) | 2023-11-16 |
CN117643173A (zh) | 2024-03-01 |
EP4327625A1 (de) | 2024-02-28 |
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