WO2023157507A1 - プリプレグ、繊維強化複合材料、繊維強化複合材料製管状体、ゴルフクラブシャフトおよび釣り竿 - Google Patents

プリプレグ、繊維強化複合材料、繊維強化複合材料製管状体、ゴルフクラブシャフトおよび釣り竿 Download PDF

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Publication number
WO2023157507A1
WO2023157507A1 PCT/JP2023/000271 JP2023000271W WO2023157507A1 WO 2023157507 A1 WO2023157507 A1 WO 2023157507A1 JP 2023000271 W JP2023000271 W JP 2023000271W WO 2023157507 A1 WO2023157507 A1 WO 2023157507A1
Authority
WO
WIPO (PCT)
Prior art keywords
epoxy resin
component
mass
parts
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2023/000271
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
恩村康之
平野公則
佐野健太郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to CN202380020905.2A priority Critical patent/CN118715270B/xx
Priority to KR1020247026107A priority patent/KR20240151748A/ko
Priority to JP2023503119A priority patent/JP7666581B2/ja
Priority to US18/728,312 priority patent/US20250092211A1/en
Publication of WO2023157507A1 publication Critical patent/WO2023157507A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00—Golf clubs
    • A63B53/10—Non-metallic shafts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C08G59/245—Di-epoxy compounds carbocyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/44—Amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/04—Epoxynovolacs
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K87/00—Fishing rods
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00—Characteristics of used materials
    • A63B2209/02—Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C08J2363/04—Epoxynovolacs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Definitions

  • the fiber-reinforced composite material of the present invention is a fiber-reinforced composite material obtained by curing the prepreg.
  • the fishing rod of the present invention is a fishing rod using the fiber-reinforced composite material tubular body.
  • diaminodiphenylmethane-type epoxy resins include ELM434 (manufactured by Sumitomo Chemical Co., Ltd.), “Araldite (registered trademark)” MY720, MY721, MY9512, and MY9663 (manufactured by Huntsman Advanced Materials Co., Ltd.), “Epotato (registered trademark)” YH-434 (manufactured by Nippon Steel Chemical & Materials Co., Ltd.), “jER (registered trademark)” 604 (manufactured by Mitsubishi Chemical Corporation), and the like.
  • the fiber-reinforced composite material tubular body of the present invention is formed by molding the above-described prepreg having excellent tackiness, so that when it is formed into a tubular shape, it has less winding peeling and less defects such as voids. can get. Moreover, when the prepreg according to the present invention is used, the cured product thereof has excellent mechanical properties, so that the fiber-reinforced composite material tubular body of the present invention exhibits excellent bending strength.
  • Example 8 A cured epoxy resin and a prepreg were produced in the same manner as in Example 1, except that the resin composition was changed as shown in Table 1. The flexural strength, flexural modulus, transparency and prepreg tack of the cured epoxy resin were good. However, the content of [A3] in 100 parts by mass of the total epoxy resin exceeds 10 parts by mass, and the condition (3) is not satisfied. was poor.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
  • Golf Clubs (AREA)
PCT/JP2023/000271 2022-02-16 2023-01-10 プリプレグ、繊維強化複合材料、繊維強化複合材料製管状体、ゴルフクラブシャフトおよび釣り竿 Ceased WO2023157507A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN202380020905.2A CN118715270B (zh) 2022-02-16 2023-01-10 预浸料坯、纤维增强复合材料、纤维增强复合材料制管状体、高尔夫球杆杆身及钓竿
KR1020247026107A KR20240151748A (ko) 2022-02-16 2023-01-10 프리프레그, 섬유 강화 복합 재료, 섬유 강화 복합 재료제 관상체, 골프 클럽 샤프트 및 낚싯대
JP2023503119A JP7666581B2 (ja) 2022-02-16 2023-01-10 プリプレグ、繊維強化複合材料、繊維強化複合材料製管状体、ゴルフクラブシャフトおよび釣り竿
US18/728,312 US20250092211A1 (en) 2022-02-16 2023-01-10 Prepreg, fiber-reinforced composite material, tubular body made of fiber-reinforced composite material, golf club shaft, and fishing rod

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2022-021921 2022-02-16
JP2022021921 2022-02-16

Publications (1)

Publication Number Publication Date
WO2023157507A1 true WO2023157507A1 (ja) 2023-08-24

Family

ID=87578079

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2023/000271 Ceased WO2023157507A1 (ja) 2022-02-16 2023-01-10 プリプレグ、繊維強化複合材料、繊維強化複合材料製管状体、ゴルフクラブシャフトおよび釣り竿

Country Status (5)

Country Link
US (1) US20250092211A1 (https=)
JP (1) JP7666581B2 (https=)
KR (1) KR20240151748A (https=)
TW (1) TWI912578B (https=)
WO (1) WO2023157507A1 (https=)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001181375A (ja) * 1999-10-13 2001-07-03 Ajinomoto Co Inc エポキシ樹脂組成物並びに該組成物を用いた接着フィルム及びプリプレグ、及びこれらを用いた多層プリント配線板及びその製造法
JP2007291227A (ja) * 2006-04-25 2007-11-08 Toto Kasei Co Ltd 難燃性炭素繊維強化複合材料
JP2017226745A (ja) * 2016-06-22 2017-12-28 三菱ケミカル株式会社 エポキシ樹脂組成物、並びにこれを用いたフィルム、プリプレグ及び繊維強化プラスチック
WO2018003691A1 (ja) * 2016-06-28 2018-01-04 東レ株式会社 エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
WO2019181402A1 (ja) * 2018-03-20 2019-09-26 東レ株式会社 プリプレグおよび繊維強化複合材料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001181375A (ja) * 1999-10-13 2001-07-03 Ajinomoto Co Inc エポキシ樹脂組成物並びに該組成物を用いた接着フィルム及びプリプレグ、及びこれらを用いた多層プリント配線板及びその製造法
JP2007291227A (ja) * 2006-04-25 2007-11-08 Toto Kasei Co Ltd 難燃性炭素繊維強化複合材料
JP2017226745A (ja) * 2016-06-22 2017-12-28 三菱ケミカル株式会社 エポキシ樹脂組成物、並びにこれを用いたフィルム、プリプレグ及び繊維強化プラスチック
WO2018003691A1 (ja) * 2016-06-28 2018-01-04 東レ株式会社 エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
WO2019181402A1 (ja) * 2018-03-20 2019-09-26 東レ株式会社 プリプレグおよび繊維強化複合材料

Also Published As

Publication number Publication date
JP7666581B2 (ja) 2025-04-22
TW202336069A (zh) 2023-09-16
US20250092211A1 (en) 2025-03-20
TWI912578B (zh) 2026-01-21
JPWO2023157507A1 (https=) 2023-08-24
KR20240151748A (ko) 2024-10-18
CN118715270A (zh) 2024-09-27

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