WO2023122510A1 - Thermoelectric cooling in microelectronics - Google Patents

Thermoelectric cooling in microelectronics Download PDF

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Publication number
WO2023122510A1
WO2023122510A1 PCT/US2022/081858 US2022081858W WO2023122510A1 WO 2023122510 A1 WO2023122510 A1 WO 2023122510A1 US 2022081858 W US2022081858 W US 2022081858W WO 2023122510 A1 WO2023122510 A1 WO 2023122510A1
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WO
WIPO (PCT)
Prior art keywords
microelectronic device
substrate
thermoelectric
thermoelectric unit
disposed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/US2022/081858
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English (en)
French (fr)
Inventor
Rajesh Katkar
Belgacem Haba
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Adeia Semiconductor Bonding Technologies Inc
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Adeia Semiconductor Bonding Technologies Inc
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Filing date
Publication date
Application filed by Adeia Semiconductor Bonding Technologies Inc filed Critical Adeia Semiconductor Bonding Technologies Inc
Priority to JP2024537072A priority Critical patent/JP2024547066A/ja
Priority to EP22912609.9A priority patent/EP4454440A4/en
Priority to CN202280090492.0A priority patent/CN118614163A/zh
Priority to KR1020247024546A priority patent/KR20240128916A/ko
Publication of WO2023122510A1 publication Critical patent/WO2023122510A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W40/00Arrangements for thermal protection or thermal control
    • H10W40/20Arrangements for cooling
    • H10W40/28Arrangements for cooling comprising Peltier coolers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N10/00Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
    • H10N10/10Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N10/00Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
    • H10N10/10Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
    • H10N10/17Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the structure or configuration of the cell or thermocouple forming the device
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N19/00Integrated devices, or assemblies of multiple devices, comprising at least one thermoelectric or thermomagnetic element covered by groups H10N10/00 - H10N15/00
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W40/00Arrangements for thermal protection or thermal control
    • H10W40/20Arrangements for cooling
    • H10W40/22Arrangements for cooling characterised by their shape, e.g. having conical or cylindrical projections
    • H10W40/226Arrangements for cooling characterised by their shape, e.g. having conical or cylindrical projections characterised by projecting parts, e.g. fins to increase surface area
    • H10W40/228Arrangements for cooling characterised by their shape, e.g. having conical or cylindrical projections characterised by projecting parts, e.g. fins to increase surface area the projecting parts being wire-shaped or pin-shaped
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W40/00Arrangements for thermal protection or thermal control
    • H10W40/20Arrangements for cooling
    • H10W40/25Arrangements for cooling characterised by their materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/90Bond pads, in general
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W80/00Direct bonding of chips, wafers or substrates
    • H10W80/701Direct bonding of chips, wafers or substrates characterised by the pads after the direct bonding
    • H10W80/732Direct bonding of chips, wafers or substrates characterised by the pads after the direct bonding having shape changed during the connecting
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W90/00Package configurations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W90/00Package configurations
    • H10W90/701Package configurations characterised by the relative positions of pads or connectors relative to package parts
    • H10W90/791Package configurations characterised by the relative positions of pads or connectors relative to package parts of direct-bonded pads
    • H10W90/794Package configurations characterised by the relative positions of pads or connectors relative to package parts of direct-bonded pads between a chip and a stacked insulating package substrate, interposer or RDL
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W90/00Package configurations
    • H10W90/701Package configurations characterised by the relative positions of pads or connectors relative to package parts
    • H10W90/791Package configurations characterised by the relative positions of pads or connectors relative to package parts of direct-bonded pads
    • H10W90/796Package configurations characterised by the relative positions of pads or connectors relative to package parts of direct-bonded pads between a chip and a stacked lead frame, conducting package substrate or heat sink

Definitions

  • the field relates to dissipating heat and managing hot spots in microelectronic s .
  • microelectronics With the miniaturization and the high density integration of electronic components, the heat flux density in microelectronics is increasing.
  • the microelectronic components are typically operated below certain rated temperature to ensure optimal operation. If the heat generated during the operation of microelectronics is not dissipated, distriuted or extracted enough, the microelectronics may not operate reliably, its performance may be affected, and it may even shut down or bum out. In particular, thermal dissipation is a serious problem in high-power devices, and the problem worsens with chip stacking.
  • FIG. 1A, FIG. IB and FIG. 1C schematically illustrate an example microelectronic system according to the disclosed technology.
  • FIG. 2 schematically illustrates another example microelectronic system according to the disclosed technology.
  • FIG. 3A and FIG. 3B schematically illustrate alternative thermalelectric units according some embodiments of the disclosed technology.
  • FIG. 4 schematically illustrates a cross-sectional view of yet another example microelectronic device according to the disclosed technology.
  • FIG. 5 schematically illustrates a cross-sectional view of yet another example microelectronic device according to the disclosed technology.
  • FIGs. 6A, 6B, 6C, 6D and 8C schematically illustrate various arrangements of thermoelectric units according to the disclosed technology.
  • FIG. 7 illustrates an example control circuit for controlling thermoelectric units according to the disclosed technology.
  • FIG. 8A illustrates stacked thermoelectric elements in an example chip stack.
  • FIG. 8B illustrates stacked thermoelectric elements in another example chip stack.
  • Microelectronic elements e.g., dies/chips
  • chip joining methods such as adhesive bonding, flip chip interconnections, etc.
  • Methods and structures are provided for redirecting thermal flows in die stacks, for example redirecting the heat out from a central location on a die to the periphery of the die or die stack, where heat could be extracted out to heat dissipation structures (e.g., heat sinks/heat pipes), or simply redirecting the heat from one location (e.g., a hot spot) to another location on the die or spread the hotspot to a wider area, or for redirecting heat from a lower die to a heat sink without increasing the temperature of any intervening dies.
  • heat dissipation structures e.g., heat sinks/heat pipes
  • a disclosed microelectronic device 100 may include thermoelectric elements 103 that direct heat in a lateral direction (as indicated by the left-right arrow) with respect to a die/chip 101 or 102 (i.e., along the larger dimensions of a die), as illustrated in FIG. 1A.
  • a disclosed microelectronic device 100 in FIG. 1A may utilize a thermoelectric element 103 having a plurality of cascaded thermoelectric units such as 1030, 1031 and 1032, as shown in FIG. IB, to laterally transfer heat to the periphery of the device 100 from lower dies (e.g., 101) in the device 100.
  • cascaded thermoelectric units such as 1030, 1031 and 1032 may be disposed in (or on) a substrate (not shown).
  • the substrate may have a smallest dimension along a first direction (e.g., z direction), where the smallest dimension can comprise a thickness of the substrate.
  • the cascaded thermoelectric units such as 1030, 1031 and 1032 may include Peltier elements comprising N- or P-doped regions formed in the substrate, such as a thermoelectric substrate (e.g., Bi2Te3), as described in U.S. Provisional Application No. 63/265,765, filed December 20, 2021, titled “THERMOELECTRIC COOLING FOR DIE PACKAGES”, the content of which is incorporated by reference in its entirety.
  • the thickness is no more than 100 microns, or preferably no more than 50 microns.
  • the thermoelectric units 103 may be configured to transfer heat along a second, lateral direction (e.g., x direction) orthogonal to the first direction.
  • the thermoelectric element 103 can help remove heat from the device 100 and actively redirect the heat flow within the device 100, for example actively lower the temperature of a certain chip in the device or of a certain hot spot in a chip.
  • the thermoelectric element 103 may comprise a Peltier element which includes two materials with different Peltier coefficients joined together at a junction.
  • the Peltier element may utilize the Peltier effect to create a net heat flux at the junction of the two different materials when supplied with electrical energy (e.g., a DC electric current), due to the imbalance of the Peltier heat flowing in and out of the junction.
  • the Peltier element may include a plurality of pairs of p-type and n-type semiconductor pellets, elements or chips connected electrically in series (for example, the p-type and n-type semiconductor pellets in the thermoelectric unit 1031 are connected by way of the electrical connection 1081) and thermally in parallel, such that the charge carriers and heat may all flow in the same direction through the pellets.
  • the thermoelectric element 103 is not bonded to other elements of the device 100 by an adhesive or thermal interface material (TIM), which may interfere with heat transfer. Rather, the thermoelectric element 103 may be directly bonded to another element in the device 100, thus improving heat transfer efficiency. For example, a plurality of p-type and n-type semiconductor pellet pairs may be directly bonded to an active chip (e.g., 101 or 102). In some embodiments, the thermoelectric element 103 can be direct hybrid bonded to another element, such that conductive contact(s) and an insulating layer are directly bonded to corresponding conductive contact(s) and insulating layer of the other element.
  • TIM thermal interface material
  • thermoelectric element 103 can be directly bonded to the other element with only direct insulator-to-insulator bonds.
  • An active chip e.g., 101 or 102
  • the active circuitry can include one or more transistors.
  • a plurality of p-type and n-type semiconductor thermoelectric pellet pairs can be divided into many groups (such as 1030, 1031 and 1032), and each group may be controlled independently.
  • a sensor e.g., diode
  • the group of thermoelectric pellet or element pairs associated with that location e.g., 1031
  • the group of thermoelectric pellet or element pairs associated with that location may be activated by applying an electrical current through a pair of electrical contact pins/pads 1091 (for example, each of the electrical contact pins/pads may be applied a voltage of +V or -V).
  • the temperature in a device may be locally monitored and controlled.
  • thermoelectric element 103 may be configured for zoned cooling control and local thermal dissipation in response to measured hot spot distribution of a chip.
  • signals measured by temperature sensors may be used to control the thermoelectric element 103, and the temperature sensors may be located in an active chip (e.g., 101 or 102) to be cooled or within the thermoelectric element 103.
  • control of the thermoelectric element 103 may be done by in an active chip to be cooled (e.g., 101 or 102), within the thermoelectric element 103, or by an external chip on the system board.
  • FIG. IB schematically illustrates an isometric view of a portion of the example microelectronic device 100 shown in FIG. 1A having a lower carrier 101 (which can comprise a die/chip, wafer, interposer, or other suitable element) and a thermoelectric element 103 arranged in a way that can direct heat laterally for the lower element 101.
  • a lower carrier 101 which can comprise a die/chip, wafer, interposer, or other suitable element
  • thermoelectric element 103 arranged in a way that can direct heat laterally for the lower element 101.
  • charge carriers can move from hot plates in the XY and YZ planes (1021 and 1005, respectively) to a cold plate in the YZ plane (1007), and heat may be extracted to move in one direction and bend/turn to change the direction for horizontal distribution of thermal energy.
  • thermoelectric element 103 may be actuated by an exemplary control circuit as shown in FIG. 1C.
  • a thermoelectric element 103 may include a plurality of thermoelectric units such as 1030, 1031 and 1032 (disposed/formed in a Bi2Te3 wafer, for example), and a unit 1031 (e.g., having a pair of p-type and n-type semiconductor Peltier pellet) may collect heat from a left unit 1030 (or a right unit 1032, depending on the location of the hot spot) and the bottom chip 101 (and also the top chip 102, in some cases) and send the heat to the cold plate/surface 1007 to the right (or the left, depending on the direction of current provided to the thermolelectric units or pais).
  • a unit 1031 e.g., having a pair of p-type and n-type semiconductor Peltier pellet
  • thermoelectric units such as 1030, 1031 and 1032 may be arranged as a X-Y matrix, radially or any other suitable uniform (periodic) or non-uniform distribution based on the thermal map provided during actual experimentation or thermal simulation for the chip or chip stack.
  • FIG. 2 shows an example microelectronic device 200 similar to that shown in FIG. 1A and FIG. IB, where like features are referenced by like reference numbers, while each thermoelectric unit (such as 1030, 1031 and 1032) may direct heat bi-directionally, depending on the polarity of applied voltage bias.
  • thermally conductive but electrically insulating plates 2070 e.g., formed of TiN, Aluminum Nitride, etc.
  • two adjacent thermoelectric units e.g., between 1030 and 1031 and/or between 1031 and 1032
  • FIG. 2 shows the plates 2070 and the thermoelectric units in an exploded view, but in reality there may be no gap between a plate 2070 and its adjacent thermoelectric units.
  • FIG. 3 A and FIG. 3B show example thermoelectric units similar to those shown in FIG. IB, where like features are referenced by like reference numbers.
  • separate electrodes e.g., 3091 and 3092
  • vertical and horizontal hot plates 1005 and 1021
  • a cold plate 1007 may effectively affect the direction of charge carrier flow between one or both hot plates (1005 and/or 1021) and a cold plate 1007. This allows the heat extraction either from the bottom and move laterally or only move laterally (i.e., without any direct active extraction from bottom).
  • the separate electrodes may be independent and can be used to optimize thermal flow.
  • the voltages applied to the electrodes 3091 and 3092 may all be diff ererent.
  • connected electrodes e.g. 3099
  • the overall charge carrier flow may be diagonal with respect to the pellets of the thermoelectric unit 303 IB.
  • FIG. 4 schematically illustrates a cross-sectional view of an example microelectronic device 400 having stacked dies and a thermoelectric element 403 (as described in connection with any of the previous figures) which directs heat laterally for a bottom chip (401).
  • the thermoelectric element 403 may include Peltier elements embedded in a substrate, such as a thermoelectric substrate (e.g., Bi2Te3).
  • the Peltier elements may include N- or P-doped regions formed in the substrate, as described in U.S. Provisional Application No. 63/265,765, filed December 20, 2021, titled “THERMOELECTRIC COOLING FOR DIE PACKAGES”, the content of which is incorporated by reference in its entirety.
  • a thermal path 467, or thermally conductive block, may dissipate heat from the thermoelectric element 403 to a heat sink 405 at the top of the die stack.
  • the microelectronic device 400 may further include a few other chips (e.g., 4001 and 4002) that are thermally isolated from the bottom chip (401).
  • the thermoelectric element 403 may be powered by electrical contacts connecting to the bottom chip 401, e.g., to through-substrate vias in the bottom chip 401.
  • the bottom chip 401 may be in electrical communication with chip 4001and/or chip 4002 by through-substrate vias.
  • thermoelectric element 403 can be direct hybrid bonded to another element, such that conductive contact(s) and an insulating layer are directly bonded to corresponding conductive contact(s) and insulating layer of the other element. In other embodiments, the thermoelectric element 403 can be directly bonded to the other element with only direct insulator-to-insulator bonds.
  • FIG. 5 schematically illustrates a cross-sectional view of an example microelectronic device 500 having stacked chips and thermoelectric elements 5031, 5032 and 5033 which direct heat laterally at one or multiple layers of the device 500.
  • a thermal path 567, or thermally conductive block, may dissipate heat from the thermoelectric element 5033 to a heat sink 505 at the periphery of the device 500.
  • cascaded thermoelectric units 5031, 5032 and 5033 can dissipate heat all the way to the edge of a chip (e.g., 5011, 5012, 5013, 5014 or 5015) to get extracted (e.g., by heat sink 505, or sideway/edge extraction by a heat spreader or vertical extraction by an exposed surface).
  • such thermoelectric elements 5031, 5032 and 5033 can distribute/spread/dissipate heat spots, reducing the impact of heat spots on the device performance by reducing the peak temperature.
  • thermoelectric elements 5031, 5032 and 5033 may be used for thermal management within a small region compared to the whole chip, for example carry heat from one location to another or distribute or spread a hot spot to a wider area.
  • the thermoelectric elements 5031, 5032 and 5033 can be direct hybrid bonded to another element, such that conductive contact(s) and an insulating layer are directly bonded to corresponding conductive contact(s) and insulating layer of the other element.
  • the thermoelectric elements 5031, 5032 and 5033 can be directly bonded to the other element with only direct insulator-to- insulator bonds.
  • thermoelectric units 603 can be arranged in various patterns to be able to drive heat flow in a specific direction as optimized by the controller based off of a thermal map.
  • thermoelectric units 603 can be arranged in a grid, as shown in FIG. 6A or FIG. 6B, or radially, as shown in FIG. 6C, and can dissipate heat laterally for a bottom die. Any other suitable uniform/periodic or non-uniform distribution of the Thermoelectric elements may also be arranged.
  • Ths arrangement may be based on actual thermal maps from an exemplary device or a thermal simulation.
  • the thermoelectric units 603 may be powered through conductive vias within the bottom die or may be powered separately by an external chip.
  • FIG. 6D shows a plan view of thermoelectric units 603 arranged in a plane orthogonal to the direction of the thickness of a wafer in which the thermoelectric units 603 are disposed, the thermoelectric units 603 associated with electrical contacts for optimized positional control and thermal dissipation.
  • the thickness is no more than 100 microns, or preferably no more than 50 microns.
  • thermoelectric units 603 are configured to transfer heat along a pathway within the plane of the thermoelectric units 603, the pathway including at least one turn within the plane. Although shown to carry heat in the XY plane along XX or YY directions (as indicated by the arrows) in FIG. 6D, thermoelectric units can be arranged in other directions, as shown in FIG. 8C.
  • FIG. 7 illustrates an example control circuit/control logic 700 for controlling thermoelectric units 703 and heat dissipation in a disclosed device as described in connection with any of the previous figures.
  • the disclosed control circuit 700 may turn on the units 703 sequentially with a slight delay to drive the heat flow.
  • the control circuit 700 may also activate the units 703 in any suitable optimized pattern (by location or time) for efficient thermal distribution, in some examples.
  • the disclosed control circuit 700 can monitor the heat map of the die (e.g., with thermal sensors internal or external to the thermoelectric element or embedded in chip) and can drive the heat flow by activating one or more groups or zones of thermoelectric unit 703 or pairs and improve the thermal dissipation/distribution by driving heat flow towards one or more optimal locations.
  • thermoelectric units 703 can be connected in parallel, and therefore temperature control at different locations on a die may be managed independently.
  • a disclosed device may include a combination of several thermoelectric elements 703 connected in parallel to form a block and then several such blocks connected in series.
  • a disclosed device may include a combination of several thermoelectric elements 703 connected in series to form a block and then several such blocks are connected in parallel. Any suitable distribution of the and combination of thermoelectric elements 703 may be arranged.
  • a separate independent controller chip may be part of the device chip stack.
  • FIG. 8A illustrates stacked thermoelectric elements in a chip stack 800A (e.g., including a top die 802 and a bottom die 801). Heat may be extracted upwards in some cases, as indicated by the arrows, e.g., around extreme hot spots, via another layer of thermoelectric element 8035 stacked on a layer of laterally cascaded thermoelectric units 803.
  • FIG. 8B illustrates a chip stack 800B (e.g., including a top die 802 and a bottom die 801) having thermoelectric units arranged in a way that allows extraction of heat both laterally and vertically.
  • thermoelectric units 8035 that can extract heat upwards (or downwards), as indicated by the arrows, may be embeded within a layer of laterally cascaded thermoelectric units 803.
  • the disclosed device may further include a thermal barrier/insulator layer to shield the heat going to a top die 802.
  • the thermoelectric elements 803 and 8035 can be direct hybrid bonded to another element, such that conductive contact(s) and an insulating layer are directly bonded to corresponding conductive contact(s) and insulating layer of the other element.
  • the thermoelectric elements 803 and 8035 can be directly bonded to the other element with only direct insulator-to-insulator bonds.
  • a semiconductor element can comprise, for example, any suitable type of integrated device die.
  • the integrated device dies can comprise an electronic component such as an integrated circuit (such as a processor die, a controller die, or a memory die), a microelectromechanical systems (MEMS) die, an optical device, or any other suitable type of device die.
  • the electronic component can comprise a passive device such as a capacitor, inductor, or other surface-mounted device.
  • Circuitry (such as active components like transistors) can be patterned at or near active surface(s) of the die in various embodiments. The active surface may be on a side of the die which is opposite the backside of the die. The backside may or may not include any active circuitry or passive devices.
  • An integrated device die can comprise a bonding surface and a back surface opposite the bonding surface.
  • the bonding surface can have a plurality of conductive bond pads including a conductive bond pad, and a non-conductive material proximate to the conductive bond pad.
  • the conductive bond pads of the integrated device die can be directly bonded to the corresponding conductive pads of the substrate or wafer without an intervening adhesive
  • the non-conductive material of the integrated device die can be directly bonded to a portion of the corresponding non-conductive material of the substrate or wafer without an intervening adhesive. Directly bonding without an adhesive is described throughout U.S. Patent Nos.
  • Various embodiments disclosed herein relate to directly bonded structures in which two elements can be directly bonded to one another without an intervening adhesive.
  • Two or more electronic elements which can be semiconductor elements (such as integrated device dies, wafers, etc.), may be stacked on or bonded to one another to form a bonded structure.
  • Conductive contact pads of one element may be electrically connected to corresponding conductive contact pads of another element. Any suitable number of elements can be stacked in the bonded structure.
  • the contact pads may comprise metallic pads formed in a nonconductive bonding region, and may be connected to underlying metallization, such as a redistribution layer (RDL).
  • RDL redistribution layer
  • the elements are directly bonded to one another without an adhesive.
  • a non-conductive or dielectric material of a first element can be directly bonded to a corresponding non-conductive or dielectric field region of a second element without an adhesive.
  • the non-conductive material can be referred to as a nonconductive bonding region or bonding layer of the first element.
  • the non-conductive material of the first element can be directly bonded to the corresponding non-conductive material of the second element using dielectric-to-dielectric bonding techniques.
  • dielectric-to-dielectric bonds may be formed without an adhesive using the direct bonding techniques disclosed at least in U.S. Patent Nos.
  • Suitable dielectric materials for direct bonding include but are not limited to inorganic dielectrics, such as silicon oxide, silicon nitride, or silicon oxynitride, or can include carbon, such as silicon carbide, silicon oxycarbonitride, silicon carbonitride or diamond-like carbon. In some embodiments, the dielectric materials do not comprise polymer materials, such as epoxy, resin or molding materials.
  • hybrid direct bonds can be formed without an intervening adhesive.
  • dielectric bonding surfaces can be polished to a high degree of smoothness.
  • the bonding surfaces can be cleaned and exposed to a plasma and/or etchants to activate the surfaces.
  • the surfaces can be terminated with a species after activation or during activation (e.g., during the plasma and/or etch processes).
  • the activation process can be performed to break chemical bonds at the bonding surface, and the termination process can provide additional chemical species at the bonding surface that improves the bonding energy during direct bonding.
  • the activation and termination are provided in the same step, e.g., a plasma or wet etchant to activate and terminate the surfaces.
  • the bonding surface can be terminated in a separate treatment to provide the additional species for direct bonding.
  • the terminating species can comprise nitrogen.
  • the bonding surfaces can be exposed to fluorine. For example, there may be one or multiple fluorine peaks near layer and/or bonding interfaces. Thus, in the directly bonded structures, the bonding interface between two dielectric materials can comprise a very smooth interface with higher nitrogen content and/or fluorine peaks at the bonding interface. Additional examples of activation and/or termination treatments may be found throughout U.S. Patent Nos. 9,564,414; 9,391,143; and 10,434,749, the entire contents of each of which are incorporated by reference herein in their entirety and for all purposes.
  • conductive contact pads of the first element can also be directly bonded to corresponding conductive contact pads of the second element.
  • a hybrid direct bonding technique can be used to provide conductor-to-conductor direct bonds along a bond interface that includes covalently direct bonded dielectric-to- dielectric surfaces, prepared as described above.
  • the conductor-to- conductor (e.g., contact pad to contact pad) direct bonds and the dielectric-to-dielectric hybrid bonds can be formed using the direct bonding techniques disclosed at least in U.S. Patent Nos. 9,716,033 and 9,852,988, the entire contents of each of which are incorporated by reference herein in their entirety and for all purposes.
  • dielectric bonding surfaces can be prepared and directly bonded to one another without an intervening adhesive as explained above.
  • Conductive contact pads (which may be surrounded by nonconductive dielectric field regions) may also directly bond to one another without an intervening adhesive.
  • the respective contact pads can be recessed below exterior (e.g., upper) surfaces of the dielectric field or nonconductive bonding regions, for example, recessed by less than 30 nm, less than 20 nm, less than 15 nm, or less than 10 nm, for example, recessed in a range of 2 nm to 20 nm, or in a range of 4 nm to 10 nm.
  • the nonconductive bonding regions can be directly bonded to one another without an adhesive at room temperature in some embodiments in the bonding tool described herein and, subsequently, the bonded structure can be annealed. Annealing can be performed in a separate apparatus. Upon annealing, the contact pads can expand and contact one another to form a metal-to-metal direct bond.
  • hybrid bonding techniques such as Direct Bond Interconnect, or DBI®, available commercially from Adeia of San Jose, CA, can enable high density of pads connected across the direct bond interface (e.g., small or fine pitches for regular arrays).
  • the pitch of the bonding pads, or conductive traces embedded in the bonding surface of one of the bonded elements may be less 40 microns or less than 10 microns or even less than 2 microns.
  • the ratio of the pitch of the bonding pads to one of the dimensions of the bonding pad is less than 5, or less than 3 and sometimes desirably less than 2.
  • the width of the conductive traces embedded in the bonding surface of one of the bonded elements may range between 0.3 to 5 microns.
  • the contact pads and/or traces can comprise copper, although other metals may be suitable.
  • a first element can be directly bonded to a second element without an intervening adhesive.
  • the first element can comprise a singulated element, such as a singulated integrated device die.
  • the first element can comprise a carrier or substrate (e.g., a wafer) that includes a plurality (e.g., tens, hundreds, or more) of device regions that, when singulated, form a plurality of integrated device dies.
  • the first element can be considered a host substrate and is mounted on a support in the bonding tool to receive the second element from a pick-and-place or robotic end effector.
  • the second element of the illustrated embodiments comprises a die.
  • the second element can comprise a carrier or a flat panel.or substrate (e.g., a wafer).
  • the first and second elements can be directly bonded to one another without an adhesive, which is different from a deposition process.
  • a width of the first element in the bonded structure can be similar to a width of the second element.
  • a width of the first element in the bonded structure can be different from a width of the second element.
  • the width or area of the larger element in the bonded structure may be at least 10% larger than the width or area of the smaller element.
  • the first and second elements can accordingly comprise non-deposited elements.
  • directly bonded structures unlike deposited layers, can include a defect region along the bond interface in which nanovoids are present.
  • the nanovoids may be formed due to activation of the bonding surfaces (e.g., exposure to a plasma).
  • the bond interface can include concentration of materials from the activation and/or last chemical treatment processes.
  • a nitrogen peak can be formed at the bond interface.
  • an oxygen peak can be formed at the bond interface.
  • the bond interface can comprise silicon oxynitride, silicon oxycarbonitride, or silicon carbonitride.
  • the direct bond can comprise a covalent bond, which is stronger than van Der Waals bonds.
  • the bonding layers can also comprise polished surfaces that are planarized to a high degree of smoothness.
  • the bonding layers may have a surface roughness of less than 2 nm root mean square (RMS) per micron, or less than 1 nm RMS per micron.
  • RMS root mean square
  • metal-to-metal bonds between the contact pads in direct hybrid bonded structures can be joined such that conductive features grains, for example copper grains on the conductive features grow into each other across the bond interface.
  • the copper can have grains oriented along the 111 crystal plane for improved copper diffusion across the bond interface.
  • the bond interface can extend substantially entirely to at least a portion of the bonded contact pads, such that there is substantially no gap between the nonconductive bonding regions at or near the bonded contact pads.
  • a barrier layer may be provided under the contact pads (e.g., which may include copper). In other embodiments, however, there may be no barrier layer under the contact pads, for example, as described in US 2019/0096741, which is incorporated by reference herein in its entirety and for all purposes.
  • the disclosed technology relates to a microelectronic device comprising: a substrate having a thickness in a first direction; and at least one thermoelectric unit disposed in or on the substrate; wherein the thermoelectric unit is configured to transfer heat along a second lateral direction orthogonal to the first direction.
  • the substrate is directly bonded (e.g., direct hybrid bonded) to a semiconductor element.
  • the substrate comprises a surface configured for direct hybrid bonding.
  • the substrate further comprises an opposite surface configured for direct hybrid bonding.
  • at least one additional thermoelectric unit is disposed in the substrate, the at least one additional thermoelectric unit configured to transfer heat along the second direction.
  • a thermally conductive plate is disposed between the at least one thermoelectric unit and the at least one additional thermoelectric unit. In one embodiment, the thermally conductive plate is electrically insulating. In one embodiment, the at least one thermoelectric unit is disposed in the substrate.
  • At least one additional thermoelectric unit is disposed in the substrate, the at least one additional thermoelectric unit configured to transfer heat along a third direction non-parallel to the second direction and the first direction.
  • a thermally conductive plate is disposed between the at least one thermoelectric unit and the at least one additional thermoelectric unit.
  • the thermally conductive plate is electrically insulating.
  • at least one additional thermoelectric unit is disposed in the substrate, the at least one additional thermoelectric unit configured to transfer heat along the first direction.
  • a thermally conductive plate is disposed between the at least one thermoelectric unit and the at least one additional thermoelectric unit.
  • the thermally conductive plate is electrically insulating.
  • the thickness is no more than 100 microns.
  • the thermoelectric unit is further configured to transfer heat along the first direction.
  • the thermoelectric unit is associated with an electrical contact pair configured to drive an electrical current along both the first and/or the second directions in the thermoelectric unit.
  • the thermoelectric unit is associated with two electrical contact pairs, each electrical contact pair configured to drive an electrical current along one of the first and the second directions in the thermoelectric unit.
  • the disclosed technology relates to a microelectronic device comprising: a substrate having a thickness in a first direction; and at least one thermoelectric unit disposed in or on the substrate; wherein the thermoelectric unit is configured to transfer heat radially in a plane orthogonal to the first direction.
  • the substrate is directly bonded (e.g., direct hybrid bonded) to a semiconductor element.
  • the substrate comprises a surface configured for direct hybrid bonding.
  • the substrate further comprises an opposite surface configured for direct hybrid bonding.
  • the thickness is no more than 100 microns.
  • At least one additional thermoelectric unit is disposed in the substrate, the at least one additional thermoelectric unit configured to transfer heat along the first direction, along a second direction orthogonal to the first direction, or along a third direction non-parallel to the second direction and the first direction.
  • a thermally conductive structure is disposed between the at least one thermoelectric unit and the at least one additional thermoelectric unit.
  • the thermally conductive structure is electrically insulating.
  • the at least one thermoelectric unit is disposed in the substrate.
  • the disclosed technology relates to a microelectronic device comprising: a lower semiconductor element; a substrate disposed on the semiconductor element, the substrate having a thickness in a first direction; and at least one thermoelectric unit disposed in or on the substrate; wherein the thermoelectric unit is configured to transfer heat laterally along at least a second direction orthogonal to the first direction.
  • a plurality of thermoelectric units is configured to transfer heat along a pathway within a plane orthogonal to the first direction, the pathway including at least one turn within the plane.
  • the thermoelectric unit is configured to transfer heat bidirectionally along the second direction.
  • the thermoelectric unit is configured to transfer heat radially in a plane orthogonal to the first direction.
  • thermoelectric unit is configured to transfer heat along a third direction nonparallel to the second direction and the first direction.
  • the substrate is directly bonded to the semiconductor element without an adhesive.
  • the semiconductor element comprises silicon, ceramic, Silicon Carbide, Gallium Nitride, or glass.
  • the semiconductor element is devoid of active circuitry.
  • the at least one thermoelectric unit is disposed in the substrate.
  • the semiconductor element comprises a integrated device die having active circuitry.
  • the interface between the semiconductor element and the substrate comprises conductor-to-conductor direct bonds.
  • the interface between the semiconductor element and the substrate further comprises non-conductor to non-conductor direct bonds.
  • a heat sink is disposed over at least the substrate.
  • heat is dissapated from the substrate to the heat sink during operation of the thermoelectric unit.
  • a thermally conductive element is disposed between the substrate and the heat sink.
  • the thermally conductive element is devoid of active circuitry.
  • the thermally conductive element element comprises silicon or ceramic.
  • the substrate is directly bonded to the thermally conductive element without an adhesive.
  • the interface between the substrate and the thermally conductive element comprises dielectric-to-dielectric direct bonds.
  • heat is dissapated from the substrate to the heat sink through the thermally conductive element during operation of the thermoelectric unit.
  • the disclosed technology relates to a microelectronic device comprising: a first integrated device die; a substrate disposed on the first integrated device die; at least one thermoelectric unit disposed in or on the substrate; and a second integrated device die disposed on the substrate; wherein the thermoelectric unit transfers heat lateraly from at least one of the first and second integrated device dies.
  • the substrate has a thickness in a first direction, wherein the thermoelectric unit is configured to transfer heat along at least a second direction orthogonal to the first direction.
  • the thermoelectric unit is electrically connected with through-substrate vias in the first integrated device die such that the thermoelectric unit is is controlled by the first integrated device die.
  • the substrate is directly bonded to the first integrated device die without an adhesive.
  • the second integrated device die is directly bonded to the substrate without an adhesive.
  • a heat sink is disposed over at least the substrate.
  • a thermally conductive element is disposed between the substrate and the heat sink.
  • the thermoelectric unit transfers heat laterally from the first and second integrated device dies to a thermal path that vertically transfers heat to the heat sink.
  • a third integrated device die is disposed on the substrate.
  • the second integrated device die or a third integrated device die is electrically connected to the at least one thermoelectric unit.
  • the first and second integrated device dies are in electrical communication by way of through- substrate vias.
  • the at least one thermoelectric unit is disposed in the substrate.
  • the disclosed technology relates to a microelectronic device comprising: a semiconductor element; a substrate disposed on the semiconductor element, the substrate having a thickness in a first direction; and a plurality of thermoelectric units disposed in the substrate; wherein a first portion of thermoelectric units are configured to transfer heat along the first direction, and a second portion of thermoelectric units are configured to transfer heat laterally along a second direction orthogonal to the first direction.
  • the first portion of thermoelectric units are disposed on the second portion of thermoelectric units.
  • both the first and the second portion of thermoelectric units are disposed on the semiconductor element.
  • the thermoelectric unit is electrically connected with through-substrate vias in the semiconductor element.
  • the substrate is directly bonded to the semiconductor element without an adhesive.
  • the thermoelectric unit is electrically connected with through-substrate vias in the semiconductor element.
  • the disclosed technology relates to a microelectronic device comprising: an semiconductor element; a substrate disposed on the semiconductor element,; a plurality of thermoelectric units disposed in the substrate; and a plurality of temperature sensors configured to detect a local temperature in the semiconductor element.
  • the plurality of thermoelectric units are configured to transfer heat along a pathway within a plane orthogonal to a direction along the thickness of the substrate, the pathway including at least one turn within the plane.
  • the thermoelectric units are configured to transfer heat away from a local hot spot.
  • the substrate has a thickness in a first direction, wherein the thermoelectric units are configured to transfer heat along a second direction orthogonal to the first direction.
  • the plurality of temperature sensors are disposed in the semiconductor element or the substrate.
  • the microelectronic device further comprises a plurality of electrical contact pairs, each electrical contact pair independently controlling a portion of the plurality of thermoelectric units.
  • the thermoelectric units are actuated by the semiconductor element, the substrate, or an external chip.
  • the disclosed technology relates to a microelectronic device comprising: a semiconductor element; a substrate disposed on the semiconductor element; and a plurality of thermoelectric units disposed in the substrate, wherein the substrate is configured for zoned control of cooling the semiconductor element by independently controlling subgroups of the plurality of thermoelectric units.
  • the substrate has a thickness in a first direction, wherein the thermoelectric units are configured to transfer heat along a second direction orthogonal to the first direction.
  • a plurality of temperature sensors is disposed in the semiconductor element or the substrate, wherein each temperature sensor is associated with electrical contacts for actuating a portion of the thermoelectric units.
  • the microelectronic device further comprises a plurality of electrical contact pairs, each electrical contact pair independently controlling a portion of the thermoelectric units.
  • the thermoelectric units are actuated by the semiconductor element, the substrate, or an external chip.
  • the words “comprise,” “comprising,” “include,” “including” and the like are to be construed in an inclusive sense, as opposed to an exclusive or exhaustive sense; that is to say, in the sense of “including, but not limited to.”
  • the word “coupled”, as generally used herein, refers to two or more elements that may be either directly connected, or connected by way of one or more intermediate elements.
  • the word “connected”, as generally used herein, refers to two or more elements that may be either directly connected, or connected by way of one or more intermediate elements.
  • the words “herein,” “above,” “below,” and words of similar import when used in this application, shall refer to this application as a whole and not to any particular portions of this application.
  • first element when a first element is described as being “on” or “over” a second element, the first element may be directly on or over the second element, such that the first and second elements directly contact, or the first element may be indirectly on or over the second element such that one or more elements intervene between the first and second elements.
  • words in the above Detailed Description using the singular or plural number may also include the plural or singular number respectively.
  • the word “or” in reference to a list of two or more items that word covers all of the following interpretations of the word: any of the items in the list, all of the items in the list, and any combination of the items in the list.
  • conditional language used herein such as, among others, “can,” “could,” “might,” “may,” “e.g.,” “for example,” “such as” and the like, unless specifically stated otherwise, or otherwise understood within the context as used, is generally intended to convey that certain embodiments include, while other embodiments do not include, certain features, elements and/or states. Thus, such conditional language is not generally intended to imply that features, elements and/or states are in any way required for one or more embodiments.

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EP22912609.9A EP4454440A4 (en) 2021-12-20 2022-12-16 THERMOELECTRIC COOLING IN MICROELECTRONICS
CN202280090492.0A CN118614163A (zh) 2021-12-20 2022-12-16 微电子中的热电冷却
KR1020247024546A KR20240128916A (ko) 2021-12-20 2022-12-16 마이크로전자기기에서의 열전 냉각

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