Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
  • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/86—Polyethers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
  • A61Q1/02—Preparations containing skin colorants, e.g. pigments
  • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
  • A61Q1/02—Preparations containing skin colorants, e.g. pigments
  • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

Definitions

• the present invention relates to a cosmetic coloring material that produces bright fluorescent color and has transparency (clear feeling), and cosmetics using the same. More specifically, the present invention relates to a cosmetic coloring material obtained by combining a dye having a specific structure and a predetermined material, and a cosmetic containing the same.
• Lip cosmetics such as lipsticks and glosses that color the lips, and makeup cosmetics such as cheeks (blushers) and eye shadows are cosmetics that exert such an important cosmetic effect as to completely change the impression of the user's appearance. Color is one of the key factors in choosing a product. BACKGROUND ART In recent years, there has been a demand for makeup cosmetics that give vivid and transparent (clear) impressions.
• Coloring materials blended in cosmetics include organic synthetic pigments (also called tar pigments) and inorganic pigments, and organic synthetic pigments are classified into dyes and organic pigments. Among them, dyes are often used as raw materials for coloring materials exhibiting fluorescent coloration. Attempts have been made to obtain excellent fluorescent color development by combining specific materials with specific dyes.
• One of such dyes is a dye having a fluorescein skeleton.
• Red No. 218, Orange No. 201 and the like are generally known as dyes having a fluorescein skeleton.
• coloring materials in which inorganic materials such as hydroxyapatite and calcium carbonate are combined with dyes, and specific polyglycerol fatty acid esters are combined Patent Documents 1 and 2).
• Patent Documents 1 and 2 the properties of the resulting colorant vary greatly depending on the materials combined with the dye.
• such a coloring material is used as a coloring material for cosmetics, it is required that the properties required for the cosmetic are satisfied and at the same time, the fluorescent color development excellent as the cosmetic is exhibited.
• the cosmetic coloring material according to the present invention has been studied from such a point of view, and one of its purposes is to realize a color and brightness different from those of conventional coloring materials as a cosmetic coloring material, To provide cosmetics that meet the needs of users by increasing variations as materials. Another object is to develop a coloring material that is less subject to such restrictions, since the solubility of the coloring material in water, oil, etc. changes depending on the material combined with the dye, which may limit the application of the coloring material. to provide.
• R 1 is a hydrocarbon group having 1 to 6 carbon atoms which may be substituted with a hydroxyl group, or a hydrogen atom
• X is —CH 2 — or —N(R 2 )—, wherein R 2 is a hydrocarbon group having 1 to 6 carbon atoms which may be substituted with a hydroxyl group, or a hydrogen atom
• n1 is an integer from 1 to 3
• R 2 is an alkylene chain having 1 to 5 carbon atoms
• n2 is an integer from 1 to 3
• a cosmetic coloring material comprising a compound selected from the group consisting of: [2] The coloring material according to [1], wherein the component (A) is oil-soluble. [3] The colorant of [1] or [2], wherein component (A) is selected from the group consisting of fluorescein, carboxylated fluorescein, halogenated fluorescein, and salts thereof. [4] Component (B) is a compound selected from the group consisting of hydroxyethylimidazolidinone, 1-piperidinepropionic acid, glycylglycine, and PEG/poly-1,2-butanediol-52/32 dimethyl ether The colorant according to any one of [1] to [3].
• a cosmetic comprising one or more compounds selected from the group consisting of [6]
• the cosmetic according to [5] wherein the content of component (A) is 0.0001 to 5.0% by mass based on the total mass of the cosmetic.
• the cosmetic according to any one of [5] to [7] which is an oily cosmetic.
• the cosmetic according to any one of [5] to [7] which is an aqueous cosmetic, an oil-in-water cosmetic, or a water-in-oil cosmetic in which the coloring material is blended.
• the cosmetic according to any one of [5] to [9] which is substantially free of powder.
• the cosmetic coloring material according to the present invention can provide vivid color development, particularly fluorescent color development and transparency (clear feeling), and cosmetics using it can provide novel cosmetic effects. It is a thing.
• This coloring material can be combined with a wide range of base materials for cosmetics, and can provide a higher degree of freedom in designing cosmetics.
• the cosmetic coloring material according to the present invention is It contains (A) a dye having a fluorescein skeleton and (B) a specific material, and exhibits vivid color development, particularly fluorescence color development. Each of these components is described below.
• the (A) component blended in the cosmetic colorant according to the present invention is a dye having a fluorescein skeleton.
• Component (A) is not particularly limited as long as it is a dye having a fluorescein skeleton, but is preferably selected from the group consisting of fluorescein, carboxylated fluorescein, halogenated fluorescein, and salts thereof, since it exhibits particularly excellent color development. . More specific examples include tetrachlorotetrabromofluorescein (Red No. 218), tetrabromofluorescein (Red No. 223), dibromofluorescein (Orange No.
• halogenated fluoresceins such as tetrachlorotetrabromofluorescein (Red No. 218), tetrabromofluorescein (Red No. 223), and dibromofluorescein (Orange No. 201) are particularly preferred.
• Coloring materials containing these halogenated fluoresceins and derivatives thereof have high oil solubility and are suitable for use in oily cosmetics. In addition, it can be easily blended into the oil phase of a water-in-oil type cosmetic or an oil-in-water type cosmetic.
• fluorescein, carboxylated fluorescein, and salts thereof tend to exhibit strong fluorescent coloration even when combined with an aqueous solvent, they can also be used in aqueous cosmetics. In addition, it can be easily blended into the aqueous phase of a water-in-oil type cosmetic or an oil-in-water type cosmetic.
• (A) component can also combine two or more types of dyes as needed. New colors can be achieved by combining dyes.
• (B) Component The (B) component blended in the cosmetic colorant according to the present invention, when combined with the (A) component, achieves characteristic coloration, particularly fluorescent coloration.
• This component (B) is that it has an amide group, an amino group, a quaternary ammonium structure, a lactam ring structure, a polyoxyalkylene structure, etc., but if it has them, it does not necessarily produce an effect. do not have.
• excellent fluorescent color development can be achieved by using at least one of the following (B1) to (B4) as the component (B).
• the component (B1) that can be used in the coloring material according to the present invention is represented by formula (b1).
• R 1 is a hydrocarbon group having 1 to 6 carbon atoms which may be substituted with a hydroxyl group, or a hydrogen atom
• X is —CH 2 — or —N(R 2 )—
• R 2 is a hydrocarbon group having 1 to 6 carbon atoms which may be substituted with a hydroxyl group, or a hydrogen atom
• n1 is an integer from 1 to 3
• the above hydrocarbon group is not particularly limited, and may be, for example, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a cycloalkylalkyl group, a haloalkyl group, an alkoxyalkyl group, or an alkoxycarbonylalkyl group, preferably is an alkyl group.
• R 1 is a hydroxyalkyl group having 1 to 3 carbon atoms
• X is —CH 2 — or —NH— and n1 is 1.
• cyclic carboxamide derivative represented by formula (b1) include the following.
• the most preferred component (B1) is 1-(2-hydroxyethyl)-2-imidazolidinone.
• (B2) Cyclic Amino Group-Containing Carboxylic Acid Derivative or Its Salt
• the component (B2) that can be used in the coloring material according to the present invention is represented by formula (b2).
• R 2 is an alkylene chain having 1 to 5 carbon atoms
• n2 is an integer from 1 to 3
• R 2 is methylene, ethylene, or propylene, n2 is 2;
• the most preferred (B2) component is piperidine propionic acid.
• (B3) a glycylglycine derivative or a salt thereof
• the (B3) component that can be used in the coloring material according to the present invention is represented by the formula (b3).
• R 3 is hydrogen, an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, an acyl group having 2 to 7 carbon atoms, or an aroyl group having 7 to 11 carbon atoms
• a preferred form is (b3) in which R 3 is hydrogen, methyl, or ethyl.
• the most preferred (B3) component is glycylglycine where R3 is hydrogen.
• (B4) an alkylene oxide derivative
• the (B4) component that can be used in the coloring material according to the present invention is represented by the formula (b4).
• R 4 O—[BO) l (EO) m (BO) n ]—R 4 (b4)
• R 4 is each independently hydrogen or a hydrocarbon group having 1 to 4 carbon atoms
• BO is an oxybutylene group
• EO is an oxyethylene group
• m and n are the average added moles of BO and EO, respectively; 1 ⁇ m ⁇ 70, 1 ⁇ l + n ⁇ 70,
• the ratio of EO to the total number of BO and EO is 20-80% by mass.
• this alkylene oxide derivative has a block-type polymer main chain in which EO, which is an oxyethylene group, and BO, which is an oxybutylene group, form blocks.
• R4 is preferably hydrogen, a methyl group, or an ethyl group.
• BO can have a linear or branched structure. Specifically, BO can have a structure derived from an alkyldiol having 4 carbon atoms. Specifically, derived from 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2-methyl-1,3-propanediol, 1-dimethyl-1,2-ethanediol takes an oxyalkylene structure.
• m is preferably 5 to 150.
• the most preferred (B4) component is PEG/poly-1,2-butanediol-52/32 dimethyl ether.
• the component (B) may be a salt of the compounds represented by the formulas (b1) to (b4) other than those described above.
• the type of salt is not particularly limited as long as it is a pharmacologically acceptable salt, and may be an inorganic salt or an organic salt.
• inorganic salts include hydrochlorides, sulfates, phosphates, hydrobromides, sodium salts, potassium salts, magnesium salts, calcium salts, magnesium salts, ammonium salts and the like.
• organic salts include acetates, lactates, maleates, fumarates, tartrates, methanesulfonates, p-toluenesulfonates, triethanolamine salts, amino acid salts and the like.
• the component (B) can be blended either alone or in combination of two or more.
• the cosmetic colorant according to the present invention contains a combination of the above-described components (A) and (B). These generally exhibit fluorescent coloration when they come into contact with each other in solution or dispersion. Therefore, the cosmetic coloring material is generally in the form of a solution or a dispersion liquid, but may be in the form of a powder mixture containing no solvent or dispersion medium. Further, when it is blended in cosmetics, it may be blended in the form of a solution or dispersion with other ingredients of the cosmetic, or it may be blended in the form of a powder mixture. ) components may be blended separately.
• the solvent or dispersion medium used when the cosmetic coloring material according to the present invention takes the form of a solution or dispersion can be arbitrarily selected from those used for cosmetics.
• water or an organic solvent, especially an oily component generally used in cosmetics is preferably used.
• the oily component includes liquid oil, solid oil and semi-solid oil. These are classified according to their hardness, and when the hardness at 25° C. is 0.1 to 10 N, they are classified as semi-solid oils. This hardness can be measured with a rheometer manufactured by Rheotec, with a pressure-sensitive axis of 5 ⁇ , a penetration speed of 2 cm/min, and a penetration of 3 mm.
• Liquids such as olive oil, avocado oil, camellia oil, macadamia nut oil, evening primrose oil, jojoba oil, rapeseed oil, egg yolk oil, sesame oil, castor oil, safflower oil, cottonseed oil, soybean oil, teaseed oil, rice bran oil, or germ oil Fats and oils; Hydrocarbon oils such as squalane, isododecane, hydrogenated polyisobutene, hydrogenated polydecene, or liquid paraffin; Pentaerythrityl tetraethylhexanoate, di(phytosteryl/octyldodecyl) lauroyl glutamate, triisostearin, glyceryl diisostearate, triethylhexanoin, dimer dilinoleic acid (phytosteryl/behenyl), dimer dilinoleic acid (phytosteryl/isostearyl/cet
• Solid or semi-solid oils include solid oils, waxes, hydrocarbons, higher alcohols and fatty acids.
• Solid oils such as Japanese wax, cocoa butter, or hydrogenated castor oil
• Waxes such as carnauba wax, beeswax, candelilla wax, rice bran wax, or jojoba wax:
• Hydrocarbon waxes and semi-solid oils such as polyethylene wax, paraffin wax, ceresin, ozokerite, microcrystalline wax, or petrolatum;
• Higher alcohols such as behenyl alcohol, cetanol, or batyl alcohol; Dipentaerythrityl hexahydroxystearate, macadamia nut fatty acid phytosteryl, tetra (behenate/benzoate/ethylhexanoate) pentaerythrityl, dimer dilinoleate (phytosteryl/behenyl), or macadamia nut oil polyglyceryl-6 ester subbehenate semi-solid
• the cosmetic coloring material according to the present invention exhibits fluorescent coloration due to interaction between the components (A) and (B)
• the compounding ratio of the components (A) and (B) must be within a specific range. is preferred.
• the ratio of the content of component (B) to the content of component (A) is preferably 0.002 to 120,000, more preferably 0.05 to 2,500. is more preferable.
• the form of the formulation is not particularly limited. That is, the cosmetic according to the present invention can take any form such as an oily cosmetic, an aqueous cosmetic, an oil-in-water emulsified cosmetic, or a water-in-oil emulsified cosmetic. Moreover, the cosmetic according to the present invention may be a liquid cosmetic or a solid cosmetic. Depending on the solubility of the cosmetic coloring material, it can be blended in the cosmetic oil phase or in the aqueous phase. However, since the cosmetic colorant according to the present invention is generally highly oil-soluble, it is preferably blended with oily solid cosmetics and oily liquid cosmetics.
• emulsified cosmetics it is preferable to blend the cosmetic coloring material according to the present invention in the oil phase.
• the cosmetic according to the present invention exhibits excellent fluorescent color development in any form, oil-based cosmetics or aqueous cosmetics tend to achieve better transparency than emulsified cosmetics, and are therefore preferable.
• the cosmetic according to the present invention can give a unique and vivid impression due to fluorescence coloration, it is preferably a makeup cosmetic, particularly lipstick, lip gloss, eye shadow, or mascara. It is preferably a makeup cosmetic.
• the cosmetic according to the present invention contains various components to be described later.
• the content of component (A) should be 0.0001 based on the total weight of the cosmetic. is preferably from 0.001 to 1.0% by mass, preferably from 0.001 to 1.0% by mass, and preferably from 0.01 to 15% by mass, It is more preferably 0.05 to 13% by mass.
• the cosmetic according to the present invention can contain various ingredients that can be generally used in cosmetics, depending on the form of the formulation.
• oily components oily thickeners, ultraviolet absorbers, moisturizing agents, film-forming agents, water-soluble polymers, water-soluble agents, oil-soluble agents, sequestering agents, antioxidants, water, perfumes, and cosmetics according to the present invention.
• a coloring material or the like different from the coloring material can be appropriately blended as needed.
• oil-based component those listed in the section on the cosmetic colorant can be used.
• Oily thickeners include dextrin palmitate, dextrin stearate, dextrin palmitate stearate, dextrin isostearate, (palmitate/2-ethylhexanoate) dextrin, silica silylate, disteardimonium hectorite, dimethylalkyl ammonium hectorite, distearyldimethylammonium chloride-treated aluminum magnesium silicate, and the like.
• UV absorbers include benzoic acid UV absorbers such as para-aminobenzoic acid, anthranilic acid UV absorbers such as methyl anthramylate, salicylic acid UV absorbers such as octyl salicylate and phenyl salicylate, isopropyl paramethoxycinnamate, Octyl paramethoxycinnamate (ethylhexyl methoxycinnamate), cinnamic acid UV absorbers such as glyceryl mono-2-ethylhexanoate di-paramethoxycinnamate, 2,4-dihydroxybenzophenone, 2-hydroxy-4 -Methoxybenzophenone, benzophenone UV absorbers such as 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, urocanic acid, 2-(2'-hydroxy-5'-methylphenyl)benzotriazole, 4-tert-butyl -4'-Methoxybenzoylmethane and the like
• Moisturizers include 1,3-butylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, hexylene glycol, hexanediol, glycerin, diglycerin, xylitol, maltitol, maltose, and D-mannite.
• Coating agents include pullulan tri(trimethylsiloxy)silylpropylcarbamate, polymethylsilsesquioxane, polypropylsilsesquioxane, trimethylsiloxysilicate, (acrylates/dimethicone) copolymer, (ethylene/propylene) copolymer, isostearic acid.
• Silicone resins such as dextrin, fluorine-modified silicone and acrylic silicone, latexes of polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate and polyvinyl acetate, dextrin, cellulose derivatives such as alkyl cellulose and nitrocellulose, and the like.
• Water-soluble polymers include plant-based polymers such as gum arabic, carrageenan, pectin, agar, quince seed (quince), starch, algae colloid (brown algae extract), microbial-based polymers such as dextran and pullulan, collagen, and casein. , animal polymers such as gelatin, starch polymers such as carboxymethyl starch and methylhydroxypropyl starch, alginic acid polymers such as sodium alginate, vinyl polymers such as carboxyvinyl polymer (CARBOPOL, etc.), polyoxyethylene acrylic polymers such as polyoxyethylene-polyoxypropylene copolymers, sodium polyacrylate, polyacrylamide, and polymethyl methacrylate; molecules and the like.
• plant-based polymers such as gum arabic, carrageenan, pectin, agar, quince seed (quince), starch, algae colloid (brown algae extract), microbial-based polymers such as dextran and pullulan, collagen, and casein.
• Water-soluble drugs include inosit, pyridoxine hydrochloride, benzyl nicotinate, nicotinamide, dl- ⁇ -tocopherol nicotinate, magnesium ascorbate phosphate, ascorbate 2-glucoside, vitamin D2 (ergocasiferol), dl- ⁇ - Vitamins such as tocopherol 2-L ascorbic acid phosphate potassium salt, pantothenic acid, biotin, anti-inflammatory agents such as allantoin and glycyrrhetinic acid, whitening agents such as arbutin, astringents such as zinc oxide and tannic acid, sulfur, Examples include lysozyme chloride, pyridoxine hydrochloride, ⁇ -oryzanol and the like.
• Oil-soluble drugs include vitamin A, retinol, retinol palmitate, dl- ⁇ -tocopherol, dl- ⁇ -tocopherol acetate, azulene, glucosylhesperidin, and stearyl glycyrrhetinate.
• Sequestering agents include sodium edetate, sodium metaphosphate, phosphoric acid, and the like.
• Antioxidants include ascorbic acid, ⁇ -tocopherol, dibutylhydroxytoluene, and butylhydroxyanisole.
• dispersants examples include surfactants for stably dispersing oily ingredients and powder ingredients in cosmetics.
• the surfactant can be arbitrarily selected from cationic, anionic, nonionic, amphoteric surfactants, etc. according to the purpose.
• the cosmetic according to the present invention contains a coloring material obtained by combining the components (A) and (B), but may contain other coloring materials, such as dyes, in order to adjust the coloring.
• powdered ingredients are sometimes added to common cosmetics.
• powders include inorganic powders, organic powders, copolymer resin powders, inorganic pigments and organic pigments.
• these powders can also be blended as needed, but the powders may impair the vividness and transparency of the fluorescent coloration of the cosmetic of the present invention. Therefore, when the cosmetic according to the present invention contains a powder component, it is preferable that the blending ratio of the powder component is 5% by mass or less based on the total mass of the cosmetic, and it is particularly preferred that the powder component is not included at all. preferable.
• non-colored powders other than pigments have a strong tendency to impair the fluorescent color development of the cosmetic composition according to the present invention, so the blending ratio thereof is preferably small. Therefore, when a powder component is blended into the cosmetic according to the present invention, the blending ratio of the non-colored powder is preferably 5% by mass or less based on the total mass of the powder component.
• the non-colored powder is a colorless or white powder, such as polyamide powder, hydroxyapatite, and calcium carbonate.
• Examples 101-107, Comparative Examples 101-105 An oily solid cosmetic was prepared by blending the components shown in Table 1 below.
• a panel of 10 persons evaluated the "appearance color development", “transparency”, “applied color”, and “staining" of the cosmetics of each example according to the following criteria.
• D 5 or less judged to be effective.
• Examples 201 to 205, Comparative Example 201 Aqueous cosmetics were prepared by blending the components shown in Table 2 below. The cosmetics of each example were evaluated according to the same criteria as in Example 101.
• Examples 301-304, Comparative Examples 301-303 An oily cosmetic was prepared by blending the components shown in Table 3 below. The cosmetics of each example were evaluated according to the same criteria as in Example 101.
• Example 401 An oily cosmetic was prepared by blending the components shown in Table 4 below. The cosmetics of each example were evaluated according to the same criteria as in Example 101.
• Examples 501-503, Comparative Example 501 An oil-in-water cosmetic was prepared by blending the components shown in Table 5 below. The cosmetics of each example were evaluated according to the same criteria as in Example 101.
• Examples 601-603 A water-in-oil type cosmetic was prepared by blending the components shown in Table 6 below. The cosmetics of each example were evaluated according to the same criteria as in Example 101.

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• 2022
  • 2022-11-30 JP JP2023567666A patent/JPWO2023112671A1/ja active Pending
  • 2022-11-30 CN CN202280075560.6A patent/CN118251205A/zh active Pending
  • 2022-11-30 WO PCT/JP2022/044100 patent/WO2023112671A1/ja not_active Ceased

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