WO2023111605A1 - Sublimation device for protecting honey bees against insects - Google Patents

Sublimation device for protecting honey bees against insects Download PDF

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Publication number
WO2023111605A1
WO2023111605A1 PCT/HU2022/050089 HU2022050089W WO2023111605A1 WO 2023111605 A1 WO2023111605 A1 WO 2023111605A1 HU 2022050089 W HU2022050089 W HU 2022050089W WO 2023111605 A1 WO2023111605 A1 WO 2023111605A1
Authority
WO
WIPO (PCT)
Prior art keywords
pot
inside space
outlet tube
vapour
tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/HU2022/050089
Other languages
English (en)
French (fr)
Inventor
János FENYŐSY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP2024535631A priority Critical patent/JP2024544280A/ja
Priority to CA3240013A priority patent/CA3240013A1/en
Priority to AU2022410540A priority patent/AU2022410540A1/en
Priority to HRP20251691TT priority patent/HRP20251691T1/hr
Priority to CN202280081182.2A priority patent/CN118368976B/zh
Priority to ES22862322T priority patent/ES3059733T3/es
Priority to PL22862322.9T priority patent/PL4447659T3/pl
Priority to US18/716,026 priority patent/US20250031675A1/en
Priority to EP22862322.9A priority patent/EP4447659B1/en
Publication of WO2023111605A1 publication Critical patent/WO2023111605A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M13/00—Fumigators; Apparatus for distributing gases
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K51/00—Appliances for treating beehives or parts thereof, e.g. for cleaning or disinfecting

Definitions

  • the invention relates to an oxalic acid sublimation device that is adapted to be utilised in apiaries and comprises a pot, at least one heating means, and a vapour outlet tube.
  • the sublimation device according to the invention is able to optimise the sublimation process and to drastically reduce the risk of oxalic acid condensation in the outlet tube. As a result, the oxalic acid sublimation device allows easier, quicker and more energy efficient operation and needs less maintenance.
  • the Asian honey bee mite is one of the most widespread pests of honey bees. It is very important to control varroa mites (i.e., keep their number under a given threshold) because they degrade the health of bee colonies by spreading viral diseases, and their uncontrolled proliferation very often leads to the loss of the colony.
  • oxalic acid sublimation or vaporisation (various terms are in use; in the English-language literature the term “vaporisation” is applied more frequently, while in Hungarian the method is widely called “sublimation”, hereinafter the latter term is used) wherein crystalline oxalic acid (H2C2O4 2H2O) is sublimated at high temperature (usually 190-230 °C) in a sublimation device, and the generated vapour is introduced into the interior of the hive.
  • H2C2O4 2H2O crystalline oxalic acid
  • the hot oxalic acid vapour cools off and takes up external humidity, it condenses and forms a thin oxalic acid crystalline layer on the inside surfaces of the hive, thus providing the mite control effect.
  • Oxalic acid dihydrate starts to sublimate at a temperature of 157 °C; if it is heated above a temperature of 235-240 °C it increasingly transforms into formic acid, which is
  • Beekeepers apply suitably configured devices for performing the oxalic acid treatment described above.
  • the prior art contains various technical solutions for sublimation; the present invention improves the solution wherein - except for an outlet tube - the heated pot is hermetically sealed in the course of the sublimation process, the oxalic acid dihydrate sublimating due to heating generating overpressure inside the pot, and the oxalic acid vapour being released from the pot and introduced into the beehive through the outlet tube of the pot.
  • the pot 4 of the devices is made of a metal with favourable heat conduction properties.
  • the most frequently applied heating element is a tubular band heater (also called clamp heater) that is attached to the outside of the pot 4.
  • a temperature sensor is disposed in a bore 7 disposed at the bottom of the cylindrical pot 4. The sensor is applied for controlling the band heater by switching it on and off and thus keeping the pot 4 at the desired temperature.
  • the upper outlet tube 9 through which the oxalic acid vapour is released under pressure is disposed at the cylindrical side surface of the pot 4 near the lid of the pot 4.
  • the oxalic acid is released through the upper outlet tube 9 (such a solution is applied in the Oxalika PRO device that is presented on the internet site htj.ps://www.talitha-info.com/?lang ⁇ hu ).
  • the oxalic acid leaves the device through a curved outlet tube 10 (such a solution is applied in the devices SzublimOx, Varroa-Ox, Provap, etc. that can be found at the internet site
  • the curved outlet tube 10 extending from the top horizontally or at an angle is bent downwards and is again bent at 90 degrees at the point where it reaches the bottom of the pot 4, thereby allowing that the device can be applied for performing sublimation treatment also through the low-lying entrance to the hive (that is fitted with a landing board).
  • the upper outlet tube 9 is attached to the relatively thin cylindrical wall of the pot 4, it cannot be heated sufficiently, i.e., its end tends to cool down to the critical temperature at which some of the oxalic acid vapour flowing through it undergoes condensation, which (sooner or later) blocks the tube. Removing the oxalic acid condensate is a time-consuming task. Unfavourable (cold and windy) weather further increases the frequency of blockages.
  • the arrangement of the upper outlet tube 9 is not optimal, because in order to ensure that the oxalic acid is released exclusively in vapour state, the outlet pipe must be situated at the top portion of the pot 4, but the end of the outlet tube is preferably located at the bottom portion of the device such that it can access the exit of the beehive above the landing board. The result is the same in case - as with the second solution - the oxalic acid vapour is introduced into the hive through a curved outlet tube 10.
  • the length of the curved outlet tube 10 run situated in the outside space, and also its curved shape increase the tendency of the curved outlet tube 10 to cool off, and thus its tendency to get blocked, while the curved shape makes cleaning the tube (which is time-consuming by itself) even more difficult and cumbersome.
  • the bending, brazing and/or welding of the curved outlet tube 10 are labour-intensive and time-consuming operations.
  • Another drawback of the solution comprising a curved outlet tube 10 is that in order to achieve its required curved shape the tube is made of a soft metal, usually soft copper, which has a tendency to become even softer over time and break off during use.
  • the objective of the invention is to provide - by eliminating the drawbacks of prior art solutions - an improved outlet tube for releasing oxalic acid vapour and implement a more optimal heating system and a pot that has these improved features and can be serially produced.
  • the invention is based on the recognition that sublimation through the hive exit can be implemented in a more preferable manner in case the outlet tube is disposed near the bottom of the pot, and in case the outlet tube is as short as possible and has as simple configuration as possible, while being made of a material of sufficient strength.
  • the interior of the pot can be configured such that the boiling oxalic acid dihydrate is not able to flow out through the outlet tube disposed at the bottom, i.e., such that only the oxalic acid vapour is able to leave the device.
  • providing as short an outlet run as possible and arranging it as close to the heating means as possible results in expedient temperature conditions, so the temperature required for preventing oxalic acid condensation can be ensured appropriately.
  • the technical solution according to the invention is therefore a sublimation device for protecting honey bees against arthropod pests, the device comprising a pot with a heated inside space a lid at least one heating means and with a vapour outlet tube.
  • the invention is characterised in that the pot has a thickened bottom. Two intersecting blind holes are formed in the thickened bottom such that the axes thereof lie at an angle with respect to each other, where one of the holes opens either directly from the bottom of the pot or through the side wall of the pot to the heated inside space, and the other of the holes opens to the space outside the pot.
  • a bottom outlet tube is disposed in the blind hole opening to the space outside the pot.
  • a vapour release tube is disposed in the blind hole opening directly from the bottom of the pot to the heated inside space. The end of the vapour release tube opening to the inside space is disposed under the lid spaced apart therefrom.
  • the intersecting blind holes are perpendicular to each other.
  • the vapour release tube is constituted by the blind hole opening through the side wall of the pot to the heated inside space, or a vapour release tube is disposed in said blind hole.
  • heating means is implemented as at least one, and preferably at least two heating cartridges that are preferably disposed beside the bottom outlet tube.
  • the lid comprises an oxalic acid drop tube adapted for facilitating the feeding of oxalic acid into the device.
  • a hole adapted for receiving a temperature sensor is disposed under the heated inside space of the pot.
  • Fig. 1 shows a sectional view of a currently commercially available prior art solution comprising a top-mounted straight outlet tube
  • Fig. 2 shows a sectional view of a currently widely applied prior art solution comprising a curved outlet tube
  • Fig. 3 shows the axonometric sectional view of the pot of the device according to the invention
  • Fig. 4 shows a sectional view of the pot of the device according to the invention
  • Fig. 5 shows the bottom outlet of the pot of the device according to the invention and the location of the heating cartridges.
  • Figs. 1 and 2 show the configuration of a pot applied in a prior art device that was described above in the section on background art.
  • the pot 4 of the sublimation device according to the invention comprises a thickened bottom having a thickness of 7-50 mm; in the exemplary embodiment, preferably 30 mm, and includes a heated inside space 6.
  • Two intersecting blind holes 11 are formed in the thickened bottom of the pot 4 such that the axes of the blind holes 11 lie at an angle with respect to each other - expediently they are perpendicular to each other, where one of the holes opens - either directly or through the side wall of the pot 4 - to the heated inside space 6, and the other of the holes opens to the space outside the pot 4.
  • a bottom outlet tube 5 is disposed in the (preferably horizontal) blind hole 11 opening to the space outside the pot 4.
  • the bottom outlet tube 5 is adapted for conveying the oxalic acid vapour to the hive entrance.
  • at least one, but preferably two heating cartridges 8 are disposed at each side of the bottom outlet tube 5 (see Fig. 5) such that the cartridges encompass the bottom outlet tube 5, heating it at close range.
  • the heating means can also be a band heater because by arranging the tubes according to the invention the required functionality can also be achieved applying band heating.
  • a vapour release tube 2 is arranged in the (preferably vertical) blind hole 11 opening directly to the heated inside space 6 arranged.
  • the vapour release tube 2 is constituted by this blind hole 11.
  • the vapour release tube 2 and the bottom outlet tube 5 can be fixed in the blind holes 11 by pressing, by threaded connection, or any other manner that is obvious to a person skilled in the art. Due to the intersecting configuration of the blind holes 11, the oxalic acid vapour under pressure can freely escape through them.
  • the length of the vapour release tube 2 is chosen such that it does not contact the lid 3 attached to the pot 4, i.e., it is spaced apart therefrom.
  • the hole communicates with the inside space 6 through an opening disposed spaced apart from the lid 3 underneath it.
  • This configuration ensures that the oxalic acid vapour 2 can enter the vapour release tube, and at the same time the liquid oxalic acid boiling in the crystal water due to the heating can be prevented from outflowing through the tube.
  • an oxalic acid drop tube 1 is disposed in the lid 3 for facilitating the feeding of oxalic acid into the device. After the oxalic acid has been fed into the device, the drop tube 1 is sealed such that the pot 4 can be pressurised, and the oxalic acid vapour can escape only through the bottom outlet tube 5.
  • a hole 7 is disposed under the heated inside space 6 of the pot 4 near the heating means - in our example, the two heating cartridges 8 - switching them on and off on the basis of the measured temperature values.
  • the vapour release tube 2 is situated in the heated inside space 6, and therefore it is not able to cool down and the oxalic acid will not condense in it.
  • the bottom outlet tube 5 starts from the thickened bottom of the pot 4 and is situated directly between the two heating cartridges 8, so it is less prone to cooling off, and thus the oxalic acid is not able to condense in it.
  • the bottom outlet tube 5 is easily machinable, as it is configured to be separate from the release tube and is not curved/bent. It is therefore expediently made of such strong materials (e.g., copper, brass, etc.) that are also able to withstand the mechanical loads caused by the weight of the device during operation as it is adapted to support the entire weight of the device.
  • strong materials e.g., copper, brass, etc.
  • the device according to the invention can be manufactured applying generic CNC machining technology, i.e., it does not require manual work, soldering or welding.
  • the configuration can be modified such that the separately machined vapour release tube 2 shown in the drawings can expediently also be manufactured by moulding, or even as a cavity formed in the wall of the pot 4.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Insects & Arthropods (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Cookers (AREA)
  • Catching Or Destruction (AREA)
PCT/HU2022/050089 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects Ceased WO2023111605A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP2024535631A JP2024544280A (ja) 2021-12-14 2022-12-14 ミツバチを虫から守るための昇華装置
CA3240013A CA3240013A1 (en) 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects
AU2022410540A AU2022410540A1 (en) 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects
HRP20251691TT HRP20251691T1 (hr) 2021-12-14 2022-12-14 Uređaj za sublimaciju za zaštitu medonosnih pčela od insekata
CN202280081182.2A CN118368976B (zh) 2021-12-14 2022-12-14 用于保护蜜蜂免受昆虫侵害的升华设备
ES22862322T ES3059733T3 (en) 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects
PL22862322.9T PL4447659T3 (pl) 2021-12-14 2022-12-14 Urządzenie sublimacyjne do ochrony pszczół miodnych przed owadami
US18/716,026 US20250031675A1 (en) 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects
EP22862322.9A EP4447659B1 (en) 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HUP2100431A HU231527B1 (hu) 2021-12-14 2021-12-14 Szublimáló készülék a házi méhek kártevő rovarok elleni védelmére
HUP2100431 2021-12-14

Publications (1)

Publication Number Publication Date
WO2023111605A1 true WO2023111605A1 (en) 2023-06-22

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ID=89993478

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/HU2022/050089 Ceased WO2023111605A1 (en) 2021-12-14 2022-12-14 Sublimation device for protecting honey bees against insects

Country Status (11)

Country Link
US (1) US20250031675A1 (cg-RX-API-DMAC7.html)
EP (1) EP4447659B1 (cg-RX-API-DMAC7.html)
JP (1) JP2024544280A (cg-RX-API-DMAC7.html)
CN (1) CN118368976B (cg-RX-API-DMAC7.html)
AU (1) AU2022410540A1 (cg-RX-API-DMAC7.html)
CA (1) CA3240013A1 (cg-RX-API-DMAC7.html)
ES (1) ES3059733T3 (cg-RX-API-DMAC7.html)
HR (1) HRP20251691T1 (cg-RX-API-DMAC7.html)
HU (1) HU231527B1 (cg-RX-API-DMAC7.html)
PL (1) PL4447659T3 (cg-RX-API-DMAC7.html)
WO (1) WO2023111605A1 (cg-RX-API-DMAC7.html)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202300016128A1 (it) * 2023-07-31 2023-10-31 Talitha Srls Dispositivo per la vaporizzazione di acido ossalico comprendente un condotto per la diffusione di acido ossalico vaporizzato
WO2025027664A1 (en) * 2023-07-31 2025-02-06 Talitha S.R.L.S. Device for vaporizing oxalic acid containing a conduit for diffusing vaporized oxalic acid

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180044498A (ko) * 2016-10-22 2018-05-03 윤현호 꿀벌 병해충 방제용 훈증기
CA2985267A1 (en) * 2017-11-10 2019-05-10 Techtoba Inc Forced air pesticide vaporizer with heatsink vaporization chamber and offset exhaust chamber
US10757921B1 (en) * 2016-02-09 2020-09-01 Christopher Garrett Wood Beehive treatment systems

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL32728C (cg-RX-API-DMAC7.html) * 1930-10-16
CN205505505U (zh) * 2016-03-16 2016-08-24 宁波奥克斯空调有限公司 空调蒸发器
CN206713719U (zh) * 2017-04-24 2017-12-08 郑州中道智联云科技有限公司 一种家畜养殖场温控换气系统
TW202027603A (zh) * 2019-01-24 2020-08-01 王金德 除蜂蟎裝置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10757921B1 (en) * 2016-02-09 2020-09-01 Christopher Garrett Wood Beehive treatment systems
KR20180044498A (ko) * 2016-10-22 2018-05-03 윤현호 꿀벌 병해충 방제용 훈증기
CA2985267A1 (en) * 2017-11-10 2019-05-10 Techtoba Inc Forced air pesticide vaporizer with heatsink vaporization chamber and offset exhaust chamber

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202300016128A1 (it) * 2023-07-31 2023-10-31 Talitha Srls Dispositivo per la vaporizzazione di acido ossalico comprendente un condotto per la diffusione di acido ossalico vaporizzato
WO2025027664A1 (en) * 2023-07-31 2025-02-06 Talitha S.R.L.S. Device for vaporizing oxalic acid containing a conduit for diffusing vaporized oxalic acid

Also Published As

Publication number Publication date
ES3059733T3 (en) 2026-03-23
HU231527B1 (hu) 2024-08-28
AU2022410540A1 (en) 2024-06-20
HUP2100431A1 (hu) 2023-06-28
US20250031675A1 (en) 2025-01-30
JP2024544280A (ja) 2024-11-28
CN118368976A (zh) 2024-07-19
PL4447659T3 (pl) 2026-04-13
EP4447659C0 (en) 2025-10-22
CN118368976B (zh) 2026-02-06
HRP20251691T1 (hr) 2026-02-27
EP4447659A1 (en) 2024-10-23
CA3240013A1 (en) 2023-06-22
EP4447659B1 (en) 2025-10-22

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