WO2023054434A1 - 眼鏡レンズ、防汚剤組成物、及び眼鏡レンズの製造方法 - Google Patents

眼鏡レンズ、防汚剤組成物、及び眼鏡レンズの製造方法 Download PDF

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Publication number
WO2023054434A1
WO2023054434A1 PCT/JP2022/036083 JP2022036083W WO2023054434A1 WO 2023054434 A1 WO2023054434 A1 WO 2023054434A1 JP 2022036083 W JP2022036083 W JP 2022036083W WO 2023054434 A1 WO2023054434 A1 WO 2023054434A1
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WO
WIPO (PCT)
Prior art keywords
group
compound
spectacle lens
carbon atoms
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2022/036083
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
雄輔 関口
宏典 川上
正和 石川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoya Lens Thailand Ltd
Original Assignee
Hoya Lens Thailand Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoya Lens Thailand Ltd filed Critical Hoya Lens Thailand Ltd
Priority to JP2023551573A priority Critical patent/JP7796761B2/ja
Priority to KR1020247010222A priority patent/KR20240046796A/ko
Priority to CN202280066509.9A priority patent/CN118043729A/zh
Priority to EP22876300.9A priority patent/EP4411459A4/en
Priority to US18/696,239 priority patent/US20240392141A1/en
Publication of WO2023054434A1 publication Critical patent/WO2023054434A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/10—Block or graft copolymers containing polysiloxane sequences
    • C09D183/12—Block or graft copolymers containing polysiloxane sequences containing polyether sequences
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14—Protective coatings, e.g. hard coatings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G02C7/02—Lenses; Lens systems ; Methods of designing lenses

Definitions

  • each component in the antifouling agent composition is a value converted when the silyl group is a trimethoxysilyl group when a component having a silyl group is included.
  • Ra is preferably Formula (a1): or formula (a2): (wherein R a1 , R a2 , R a3 and R a4 are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms). R a1 , R a2 , R a3 and R a4 are preferably hydrogen atoms. R a is more preferably a group represented by formula (a1).
  • the content ratio of compound (A) to compound (B) in the antifouling agent composition is preferably from 0.1 to 8, more preferably from 0.1 to 8. It is 2 to 4, more preferably 0.5 to 2.
  • the refractive index ne of the lens substrate is preferably 1.53 or higher, more preferably 1.55 or higher, and still more preferably 1.60 or higher.
  • the upper limit of the refractive index ne of the lens substrate is not particularly limited, but may be, for example, 1.80 or less.
  • resins for lens substrates include urethane-based resins, episulfide resins, polycarbonate resins, and acrylic resins.
  • the resin is preferably at least one selected from polythiourethane resins, polysulfide resins and polyurethane resins, more preferably at least one selected from the group consisting of polythiourethane resins and polysulfide resins.
  • a silicon compound is, for example, a silicon compound having a hydrolyzable group such as an alkoxy group.
  • the silicon compound is preferably a silane coupling agent having an organic group and a hydrolyzable group bonded to silicon atoms.
  • the organic group bonded to the silicon atom is preferably an organic group having a functional group such as an epoxy group such as a glycidoxy group, a vinyl group, a methacryloxy group, an acryloxy group, a mercapto group, an amino group, a phenyl group, etc.
  • An organic group having an epoxy group is more preferred.
  • the silicon compound may have an alkyl group bonded to silicon.
  • Example 1 Comparative Examples 1 to 3
  • Anti-fouling agent vapor deposition on mirror lens In a glass container, 90 parts by mass of colloidal silica (Snowtex-40, Nissan Chemical Industries, Ltd.), 81.6 parts by mass of organosilicon compound methyltrimethoxysilane, ⁇ -glycidoxypropyltrimethoxysilane 176 parts by mass, A solution obtained by adding 2.0 parts by mass of 0.5N hydrochloric acid, 20 parts by mass of acetic acid and 90 parts by mass of water was stirred at room temperature for 8 hours and then allowed to stand at room temperature for 16 hours to obtain a hydrolyzed solution.
  • colloidal silica Snowtex-40, Nissan Chemical Industries, Ltd.
  • organosilicon compound methyltrimethoxysilane 81.6 parts by mass
  • organosilicon compound methyltrimethoxysilane methyltrimethoxysilane
  • ⁇ -glycidoxypropyltrimethoxysilane ⁇ -glycidoxypropyl

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Ophthalmology & Optometry (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Eyeglasses (AREA)
PCT/JP2022/036083 2021-09-30 2022-09-28 眼鏡レンズ、防汚剤組成物、及び眼鏡レンズの製造方法 Ceased WO2023054434A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2023551573A JP7796761B2 (ja) 2021-09-30 2022-09-28 眼鏡レンズ、防汚剤組成物、及び眼鏡レンズの製造方法
KR1020247010222A KR20240046796A (ko) 2021-09-30 2022-09-28 안경 렌즈, 방오제 조성물, 및 안경 렌즈의 제조 방법
CN202280066509.9A CN118043729A (zh) 2021-09-30 2022-09-28 眼镜镜片、防污剂组合物、以及眼镜镜片的制造方法
EP22876300.9A EP4411459A4 (en) 2021-09-30 2022-09-28 EYEGLASSES LENS, ANTI-SOILING AGENT COMPOSITION AND PROCESS FOR PRODUCING AN EYEGLASSES LENS
US18/696,239 US20240392141A1 (en) 2021-09-30 2022-09-28 Spectacle lens, antifouling agent composition, and method for manufacturing spectacle lens

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2021161404 2021-09-30
JP2021-161404 2021-09-30

Publications (1)

Publication Number Publication Date
WO2023054434A1 true WO2023054434A1 (ja) 2023-04-06

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ID=85782778

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2022/036083 Ceased WO2023054434A1 (ja) 2021-09-30 2022-09-28 眼鏡レンズ、防汚剤組成物、及び眼鏡レンズの製造方法

Country Status (6)

Country Link
US (1) US20240392141A1 (https=)
EP (1) EP4411459A4 (https=)
JP (1) JP7796761B2 (https=)
KR (1) KR20240046796A (https=)
CN (1) CN118043729A (https=)
WO (1) WO2023054434A1 (https=)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009036818A (ja) * 2007-07-31 2009-02-19 Konica Minolta Opto Inc 防眩性フィルム、防眩性反射防止フィルム、偏光板および画像表示装置
JP2010508541A (ja) * 2006-10-31 2010-03-18 エシロール アテルナジオナール カンパニー ジェネラーレ デ オプティック 防汚膜を有する光学物品
JP2010539534A (ja) * 2007-09-14 2010-12-16 エシロール アテルナジオナール カンパニー ジェネラーレ デ オプティック 防汚皮膜を具えたレンズの面を該レンズのエッジングのために準備する方法
JP2013014762A (ja) * 2011-06-30 2013-01-24 Xerox Corp フッ素化構造化有機フィルム組成物
JP2018004921A (ja) 2016-06-30 2018-01-11 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ 眼鏡レンズ及び眼鏡レンズの製造方法
WO2020241282A1 (ja) * 2019-05-29 2020-12-03 ダイキン工業株式会社 表面処理剤
JP2020204736A (ja) * 2019-06-18 2020-12-24 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ 眼鏡レンズの製造方法、眼鏡レンズ及び撥水材料組成物
WO2021090111A1 (en) * 2019-11-04 2021-05-14 3M Innovative Properties Company Fluoropolymer compositions comprising a curing agent with ethylenically unsaturated and electron donor groups, and substrates coated therewith

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3849673B2 (ja) 2003-06-10 2006-11-22 セイコーエプソン株式会社 防汚性眼鏡レンズ
JP2014148658A (ja) * 2013-01-30 2014-08-21 Dow Corning Corp 表面処理用組成物、表面処理された物品の調製方法及び表面処理された物品
JP6164144B2 (ja) * 2014-03-31 2017-07-19 信越化学工業株式会社 含フッ素コーティング剤及び該コーティング剤で処理された物品

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010508541A (ja) * 2006-10-31 2010-03-18 エシロール アテルナジオナール カンパニー ジェネラーレ デ オプティック 防汚膜を有する光学物品
JP2009036818A (ja) * 2007-07-31 2009-02-19 Konica Minolta Opto Inc 防眩性フィルム、防眩性反射防止フィルム、偏光板および画像表示装置
JP2010539534A (ja) * 2007-09-14 2010-12-16 エシロール アテルナジオナール カンパニー ジェネラーレ デ オプティック 防汚皮膜を具えたレンズの面を該レンズのエッジングのために準備する方法
JP2013014762A (ja) * 2011-06-30 2013-01-24 Xerox Corp フッ素化構造化有機フィルム組成物
JP2018004921A (ja) 2016-06-30 2018-01-11 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ 眼鏡レンズ及び眼鏡レンズの製造方法
WO2020241282A1 (ja) * 2019-05-29 2020-12-03 ダイキン工業株式会社 表面処理剤
JP2020204736A (ja) * 2019-06-18 2020-12-24 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ 眼鏡レンズの製造方法、眼鏡レンズ及び撥水材料組成物
WO2021090111A1 (en) * 2019-11-04 2021-05-14 3M Innovative Properties Company Fluoropolymer compositions comprising a curing agent with ethylenically unsaturated and electron donor groups, and substrates coated therewith

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP4411459A4

Also Published As

Publication number Publication date
EP4411459A4 (en) 2026-02-25
KR20240046796A (ko) 2024-04-09
JP7796761B2 (ja) 2026-01-09
EP4411459A1 (en) 2024-08-07
US20240392141A1 (en) 2024-11-28
CN118043729A (zh) 2024-05-14
JPWO2023054434A1 (https=) 2023-04-06

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