WO2023048242A1 - 封止フィルム、電極リード線部材および電池 - Google Patents

封止フィルム、電極リード線部材および電池 Download PDF

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Publication number
WO2023048242A1
WO2023048242A1 PCT/JP2022/035403 JP2022035403W WO2023048242A1 WO 2023048242 A1 WO2023048242 A1 WO 2023048242A1 JP 2022035403 W JP2022035403 W JP 2022035403W WO 2023048242 A1 WO2023048242 A1 WO 2023048242A1
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WIPO (PCT)
Prior art keywords
sealing film
adhesive layer
layer
hydrogen
lead wire
Prior art date
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Ceased
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PCT/JP2022/035403
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English (en)
French (fr)
Japanese (ja)
Inventor
俊輔 竹山
喬規 櫻木
敦史 目黒
崇 清水
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Zacros Corp
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Fujimori Kogyo Co Ltd
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Publication date
Application filed by Fujimori Kogyo Co Ltd filed Critical Fujimori Kogyo Co Ltd
Priority to KR1020247009218A priority Critical patent/KR20240065089A/ko
Priority to US18/694,298 priority patent/US20240396135A1/en
Priority to JP2023549754A priority patent/JPWO2023048242A1/ja
Priority to CA3232500A priority patent/CA3232500A1/en
Priority to EP22872993.5A priority patent/EP4407761A4/en
Priority to CN202280063290.7A priority patent/CN117981147A/zh
Publication of WO2023048242A1 publication Critical patent/WO2023048242A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/19—Sealing members characterised by the material
    • H01M50/193—Organic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/105—Pouches or flexible bags
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/116—Primary casings; Jackets or wrappings characterised by the material
    • H01M50/121—Organic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/116—Primary casings; Jackets or wrappings characterised by the material
    • H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/116—Primary casings; Jackets or wrappings characterised by the material
    • H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
    • H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
    • H01M50/129—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers with two or more layers of only organic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/172—Arrangements of electric connectors penetrating the casing
    • H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
    • H01M50/178—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for pouch or flexible bag cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/184—Sealing members characterised by their shape or structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/186—Sealing members characterised by the disposition of the sealing members
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/186—Sealing members characterised by the disposition of the sealing members
    • H01M50/188—Sealing members characterised by the disposition of the sealing members the sealing members being arranged between the lid and terminal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/19—Sealing members characterised by the material
    • H01M50/197—Sealing members characterised by the material having a layered structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/19—Sealing members characterised by the material
    • H01M50/198—Sealing members characterised by the material characterised by physical properties, e.g. adhesiveness or hardness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/547—Terminals characterised by the disposition of the terminals on the cells
    • H01M50/55—Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/552—Terminals characterised by their shape
    • H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to a sealing film, an electrode lead wire member and a battery.
  • This application claims priority based on Japanese Patent Application No. 2021-155742 filed in Japan on September 24, 2021, the contents of which are incorporated herein.
  • the battery includes, for example, a battery main body, a container for housing the battery main body, and electrode lead wires connected to the battery main body.
  • the storage container is produced using a battery exterior laminate having excellent waterproof and light shielding properties.
  • the battery exterior laminate is, for example, a laminate obtained by laminating a substrate layer made of polyamide or the like and an aluminum foil.
  • the electrode lead wire is sealed in the housing container with a portion including one end drawn out from the housing container.
  • the film for sealing described in Patent Document 1 suppresses a decrease in adhesive strength of the film by adding an inorganic filler such as heavy calcium carbonate.
  • hydrogen fluoride generated in the electrolyte may react with calcium carbonate or the like in the film to generate water. Therefore, it is feared that the generated water reacts with the components in the electrolytic solution to generate hydrogen fluoride, and the hydrogen fluoride reduces the bonding strength between the sealing film and the electrode lead wire.
  • An object of the present invention is to provide a sealing film, an electrode lead wire member, and a battery that can suppress a decrease in adhesive strength due to hydrogen fluoride.
  • the present invention includes the following aspects.
  • thermoplastic resin layers are provided, and the plurality of thermoplastic resin layers are a first thermoplastic resin layer that is a first adhesive layer that adheres to the electrode lead wire, and a first thermoplastic resin layer that adheres to the container. a second thermoplastic resin layer that is a second adhesive layer, and a third thermoplastic resin layer that is a base layer provided between the first adhesive layer and the second adhesive layer. , the sealing film according to [1], wherein the hydrogen-bonding resin is contained in at least one of the first to third thermoplastic resin layers.
  • An electrode lead wire member comprising the sealing film according to any one of [1] to [9] and the electrode lead wire extending in one direction. A portion of the sealing film may be adhered to the electrode lead wire.
  • a battery comprising the electrode lead wire member according to [10]. The battery includes a battery body, a container that houses the battery body, and the electrode lead wire member. A part of the sealing film is adhered to the electrode lead wire, and the sealing film is Other parts may be adhered to the container.
  • the present invention it is possible to provide a sealing film, an electrode lead wire member, and a battery that can suppress a decrease in adhesive strength due to hydrogen fluoride.
  • FIG. 4 is an enlarged cross-sectional view taken along line II in FIG. 3;
  • FIG. It is a cross-sectional enlarged view which shows the sealing film of other embodiment.
  • FIG. 1 A sealing film, an electrode lead wire member, and a battery according to an embodiment will be described below with reference to FIGS. 1 to 4.
  • FIG. 1 the dimensions and ratios of constituent elements may differ from the actual ones.
  • FIG. 1 is an enlarged cross-sectional view showing a sealing film 1 of an embodiment.
  • FIG. 2 is a perspective view showing the electrode lead wire member 10 of the embodiment.
  • the electrode lead wire member 10 includes an electrode lead wire 11 made of a conductor such as a metal, and a pair of sealing films 1 intersecting the electrode lead wire 11 and adhered at the center thereof.
  • the sealing film 1 includes a first adhesive layer 2 , a second adhesive layer 3 and a base layer 4 .
  • the first adhesive layer 2 is a layer that is fused (adhered) to the electrode lead wire 11 (see FIG. 2) by heating and pressing.
  • the surface of the first adhesive layer 2 is one surface 1 a of the sealing film 1 .
  • the first adhesive layer 2 is a thermoplastic resin layer containing a thermoplastic resin.
  • the first adhesive layer 2 is an example of the "first thermoplastic resin layer”.
  • the first adhesive layer 2 mainly contains, for example, acid-modified polyolefin.
  • the fact that the first adhesive layer 2 “mainly contains acid-modified polyolefin” means that the content of the acid-modified polyolefin is the highest among the resins constituting the first adhesive layer 2 .
  • the first adhesive layer 2 preferably contains 50% by mass or more of the acid-modified polyolefin with respect to the total amount of the first adhesive layer 2 .
  • the first adhesive layer 2 preferably contains more than 50% by mass, more preferably 80% by mass or more, of the acid-modified polyolefin with respect to the total amount of the first adhesive layer 2 .
  • polyolefins constituting the first adhesive layer 2 examples include polypropylene, polyethylene, poly-1-butene, and polyisobutylene. Among them, polypropylene is preferable as the polyolefin constituting the first adhesive layer 2 because of its excellent flexibility.
  • polypropylene may be abbreviated as "PP”.
  • the polyolefin may be a copolymer of propylene and ethylene (propylene-ethylene copolymer).
  • a copolymer of propylene and ethylene may be a block copolymer or a random copolymer, but a random copolymer is preferred.
  • Polyolefins may be copolymers of propylene and olefinic monomers. Olefinic monomers include 1-butene, isobutylene, 1-hexene and the like.
  • An acid-modified polyolefin is a polyolefin resin modified with an unsaturated carboxylic acid or a derivative of an unsaturated carboxylic acid.
  • Acid-modified polyolefins have acid functional groups such as carboxy groups and carboxylic acid anhydride groups in their molecular structures.
  • Acid-modified polyolefins are obtained by graft polymerizing unsaturated carboxylic acids or unsaturated carboxylic acid derivatives onto polyolefins, or by copolymerizing acid functional group-containing monomers with olefins. That is, in the acid-modified polyolefin, the repeating unit having an acid group may be contained in the side chain or may be contained in the main chain.
  • unsaturated carboxylic acids include acrylic acid and methacrylic acid.
  • Derivatives of unsaturated carboxylic acids include unsaturated carboxylic acid esters such as ethyl acrylate and acid anhydrides of unsaturated carboxylic acids such as maleic anhydride.
  • acid-modified polyolefin can enhance the adhesion of the first adhesive layer 2 to the electrode lead wire 11 (see FIG. 2).
  • Polyolefins and acid-modified polyolefins are thermoplastic resins.
  • acid-modified polypropylene As the acid-modified polyolefin, acid-modified polypropylene (acid-modified PP) is preferable because it has excellent heat resistance.
  • Acid-modified PP is, for example, a polymer obtained by graft-copolymerizing polypropylene or a propylene-ethylene copolymer with an unsaturated carboxylic acid or an unsaturated carboxylic acid derivative.
  • the acid-modified PP contains an ionomer obtained by neutralizing the carboxy acid groups of an acid-modified polypropylene polymer or an acid-modified propylene-ethylene copolymer with a metal hydroxide, alkoxide, lower fatty acid salt, or the like.
  • the acid group of acid-modified PP is preferably a maleic anhydride group. That is, maleic anhydride-modified PP is preferable as the acid-modified PP.
  • the first adhesive layer 2 may not contain a hydrogen-bonding resin (described later). In this case, in the first adhesive layer 2, it is possible to increase the ratio of materials having excellent adhesive strength. Thereby, the adhesive strength between the first adhesive layer 2 and the electrode lead wire 11 is improved.
  • the melting point of the resin (or resin composition) forming the first adhesive layer 2 is preferably 110° C. or higher and 150° C. or lower.
  • the melting point of the resin constituting the first adhesive layer 2 is 110° C. or higher, the first adhesive layer 2 is less likely to become excessively thin during thermocompression bonding, and it is easy to secure adhesive strength.
  • the melting point of the resin constituting the first adhesive layer 2 is 150° C. or less, the resin easily flows during thermocompression bonding. easy to seal.
  • the "melting point of the resin constituting the first adhesive layer 2" is the melting point of the polymer alloy constituting the first adhesive layer 2. means melting point.
  • optional components other than polyolefin include known additives such as stabilizers, antistatic agents, and colorants.
  • the thickness of the first adhesive layer 2 can be, for example, 5 or more and 90 or less, where the total thickness of the sealing film 1 is 100. That is, the thickness of the first adhesive layer 2 can be 5% or more and 90% or less of the total thickness of the sealing film 1 .
  • the thickness of the first adhesive layer 2 is preferably 25 or more and 70 or less when the entire thickness of the sealing film 1 is 100.
  • the thickness ratio of the layers when the total thickness of the encapsulating film 1 is 100 is referred to as the "thickness ratio".
  • the thickness ratio of the first adhesive layer 2 is 5 or more (preferably 25 or more), sufficient adhesive strength between the first adhesive layer 2 and the electrode lead wire 11 can be ensured.
  • the thickness ratio of the first adhesive layer 2 is 90 or less (preferably 70 or less), sufficient thickness can be imparted to the second adhesive layer 3 and the base material layer 4 . Therefore, it is possible to increase the adhesive strength between the second adhesive layer 3 and the container without lowering the electrolytic solution resistance of the sealing film 1 .
  • electrolytic solution resistance is resistance to the electrolyte solution.
  • the second adhesive layer 3 is, for example, a layer that is fused (bonded) to the container by heating and pressurization. The storage container will be described later.
  • the surface of the second adhesive layer 3 is the other surface 1 b of the sealing film 1 .
  • the second adhesive layer 3 is a thermoplastic resin layer containing a thermoplastic resin.
  • the second adhesive layer 3 is an example of a "second thermoplastic resin layer”.
  • the second adhesive layer 3 mainly contains polyolefin, for example.
  • the fact that the second adhesive layer 3 “mainly contains polyolefin” means that the content of polyolefin is the highest among the resins constituting the second adhesive layer 3 .
  • the second adhesive layer 3 contains 50% by mass or more, preferably more than 50% by mass, more preferably 80% by mass or more of polyolefin with respect to the total amount of the second adhesive layer 3 .
  • Polyolefins constituting the second adhesive layer 3 include polypropylene (PP), polyethylene, poly-1-butene, and polyisobutylene. Among them, PP is preferable as the polyolefin constituting the second adhesive layer 3 because of its excellent flexibility.
  • the polyolefin may be a copolymer of propylene and ethylene (propylene-ethylene copolymer).
  • a copolymer of propylene and ethylene may be a block copolymer or a random copolymer, but a random copolymer is preferred.
  • Polyolefins may be copolymers (eg, random copolymers) of propylene and olefinic monomers. Olefinic monomers include 1-butene, isobutylene, 1-hexene and the like.
  • the polyolefin that constitutes the second adhesive layer 3 may be an acid-modified polyolefin.
  • acid-modified polyolefin acid-modified PP is preferable because of its excellent heat resistance.
  • the acid-modified PP the acid-modified PP exemplified as the material of the first adhesive layer 2 is preferably used.
  • the acid-modified PP a polymer obtained by acid-modifying a random copolymer of propylene and ethylene is preferable because of its excellent flexibility. The use of acid-modified polyolefin can enhance the adhesion of the second adhesive layer 3 to the container.
  • the second adhesive layer 3 may contain both acid-modified PP and acid-modified polyethylene.
  • the melting point of the second adhesive layer 3 can be lowered, and the heating temperature when fusing the second adhesive layer 3 can be lowered. Therefore, deterioration of the first adhesive layer 2 can be suppressed.
  • the second adhesive layer 3 may not contain a hydrogen-bonding resin (described later). In this case, in the second adhesive layer 3, it is possible to increase the ratio of materials having excellent adhesive strength. Thereby, the adhesive strength between the second adhesive layer 3 and the container is improved.
  • the melting point of the resin (or resin composition) forming the second adhesive layer 3 is preferably 110°C or higher and 150°C or lower.
  • the melting point of the resin constituting the second adhesive layer 3 is 110° C. or higher, the second adhesive layer 3 is less likely to become excessively thin during thermocompression bonding, and it is easy to ensure adhesive strength. If the melting point of the resin forming the second adhesive layer 3 is 150° C. or lower, the resin will easily flow during the thermocompression bonding, so that the container and the electrode lead wire 11 can be easily sealed.
  • the "melting point of the resin constituting the second adhesive layer 3" is the melting point of the polymer alloy constituting the second adhesive layer 3. means melting point.
  • optional components other than the acid-modified polyolefin include known additives such as stabilizers, antistatic agents, and colorants.
  • the thickness (thickness ratio) of the second adhesive layer 3 can be, for example, 5 or more and 90 or less, with the total thickness of the sealing film 1 being 100. That is, the thickness of the second adhesive layer 3 can be 5% or more and 90% or less of the total thickness of the sealing film 1 .
  • the thickness ratio of the second adhesive layer 3 is preferably 5 or more and 50 or less.
  • the thickness ratio of the second adhesive layer 3 is 5 or more, sufficient adhesive strength can be secured between the second adhesive layer 3 and the container.
  • the thickness ratio of the second adhesive layer 3 is 90 or less (preferably 50 or less), sufficient thickness can be imparted to the first adhesive layer 2 and the base material layer 4 . Therefore, it is possible to increase the adhesive strength between the first adhesive layer 2 and the electrode lead wire 11 without lowering the electrolytic solution resistance of the sealing film 1 .
  • the base material layer 4 is interposed between the first adhesive layer 2 and the second adhesive layer 3 .
  • the base material layer 4 is a thermoplastic resin layer containing a thermoplastic resin.
  • the base material layer 4 is an example of the "third thermoplastic resin layer”.
  • the base material layer 4 mainly contains polyolefin, for example.
  • the fact that the base material layer 4 “mainly contains polyolefin” means that the content of polyolefin is the highest among the resins constituting the base material layer 4 .
  • the base material layer 4 contains 50% by mass or more of polyolefin with respect to the total amount of the base material layer 4, preferably more than 50% by mass, and more preferably 80% by mass or more.
  • Polyolefins that constitute the base material layer 4 include polypropylene (PP), polyethylene, poly-1-butene, and polyisobutylene. Among them, PP is preferable because of its excellent flexibility.
  • the polyolefin constituting the base material layer 4 may be a homopolymer of one olefin or a copolymer of two or more olefins. Homopolymers include homopolymers of propylene only (homo PP). Copolymers include copolymers of propylene and olefinic monomers (ethylene, 1-butene, isobutylene, 1-hexene, etc.), such as propylene-ethylene copolymers. As the polyolefin constituting the base material layer 4, each polymer exemplified as the polyolefin constituting the first adhesive layer 2 can be exemplified.
  • ICP impact copolymer
  • ICP has a phase-separated structure having a first phase and a second phase, for example, a sea-island structure.
  • the sea-island structure is a structure in which a plurality of second phases corresponding to "islands" are dispersed in a first phase corresponding to "sea”.
  • the first phase is composed of, for example, homopolymers of olefinic monomers such as propylene and ethylene.
  • the second phase is composed of a polymer different from the homopolymer that constitutes the first phase.
  • the second phase comprises, for example, a polymer of olefinic monomers such as propylene, ethylene, such as ethylene propylene rubber (EPR).
  • the second phase is composed of, for example, a main phase and a surface layer covering the surface of the main phase.
  • the main phase is composed of polyethylene, for example.
  • the surface layer is made of EPR, for example.
  • An ICP in which the homopolymer constituting the first phase is homoPP is called a polypropylene ICP or a polypropylene dispersion.
  • An ICP in which the homopolymer constituting the first phase is homoPP is a so-called block PP.
  • ICPs are also called heterophasic copolymers or block copolymers.
  • the base material layer 4 contains a hydrogen-bonding resin.
  • the base material layer 4 may contain, for example, a mixture of hydrogen-bonding resin and polyolefin.
  • the hydrogen-bonding resin is preferably a thermoplastic resin.
  • a hydrogen-bonding resin is a resin that contains a hydrogen-bondable structure in its molecule.
  • a hydrogen bond is, for example, a non-covalent bond in which a hydrogen atom covalently bonded to an atom with high electronegativity (negative atom) forms a nearby lone pair of electrons such as nitrogen, oxygen, sulfur, and fluorine. It is an attractive interaction. Since the electronegativity of the negative atoms is greater than that of the hydrogen atoms, a partial positive charge is produced on the hydrogen atoms and a partial negative charge is produced on the negative atoms.
  • the electronegativity of negative atoms (Pauling's electronegativity) is preferably 3.0 or more.
  • the electronegativity (Pauling's electronegativity) of the atom to which the hydrogen atom bonded to the negative atom forms a hydrogen bond is preferably 3.0 or more.
  • the structure capable of hydrogen bonding may be an atom group such as an amide bond, a urethane bond, or a diketone, or a functional group such as an amino group, a carbonyl group, a hydroxyl group, a thiol group, a carboxy group, a sulfonic acid group, or a phosphoric acid group.
  • an amide bond atom group and a urethane bond atom group are preferable.
  • the amide bond atom group (CO—NH) includes carbon and oxygen constituting “CO” and nitrogen and hydrogen constituting “NH” as constituents.
  • Hydrogen fluoride is formed by a covalent bond between fluorine, which is an electronegative atom, and hydrogen.
  • amide bond atomic group CO-NH
  • hydrogen Pauling electronegativity 2.1
  • nitrogen Pauling electronegativity 3.0
  • a hydrogen bond may be formed between the hydrogen atom of the amide bond atom group (CO—NH) and the fluorine lone electron pair of hydrogen fluoride. That is, as shown in formula (2), a hydrogen bond indicated by " may be formed between H and F indicated by "NH...FH".
  • hydrogen atoms contained in hydrogen-bondable structures may be covalently bonded to atoms with high electronegativity (for example, atoms with Pauling electronegativity of 3.0 or higher).
  • Hydrogen-bonding resins having amide bond atoms include polyamide-based resins.
  • a polyamide-based resin has an amide bond atomic group (CO—NH) as a repeating unit in its molecule.
  • Polyamide resins include aliphatic polyamide resins such as nylon resins. Examples of nylon resins include nylon 6, nylon 11, nylon 12, nylon 610, and nylon 612 represented by the following formula (3), and nylon 66, nylon 6/66, and nylon 66/12 represented by the following formula (4). , and blends of at least two of these, and the like.
  • An aromatic polyamide resin can also be used as the polyamide-based resin.
  • Aromatic polyamide resins include poly-p-phenylene terephthalamide, poly-p-phenylene isophthalamide, poly-m-phenylene isophthalamide, and nylon MXD6 represented by the following formula (5). Blends of at least two of these may be used.
  • the urethane bond atom group (NH-COO) contains nitrogen and hydrogen that constitute "NH” and carbon and oxygen that constitute “COO” as constituent elements.
  • urethane bond atom group (NH-COO)
  • hydrogen (Pauling electronegativity 2.1) is covalently bonded to nitrogen (Pauling electronegativity 3.0). Therefore, a hydrogen bond may be formed between the hydrogen atom of the urethane bond atom group (NH—COO) and the lone electron pair of fluorine in hydrogen fluoride. That is, a hydrogen bond indicated by "" may be formed between H and F indicated by "NH...FH".
  • Polyurethane-based resins are examples of hydrogen-bonding resins having urethane-bonded atomic groups.
  • a polyurethane resin has a urethane bond atom group (NH—COO) as a repeating unit in its molecule.
  • Examples of polyurethane-based resins include polyether-based polyurethane resins, polyester-based polyurethane resins, and polycarbonate-based polyurethane resins.
  • the polyurethane-based resin may be a urethane-based elastomer.
  • a urethane-based elastomer has, for example, a hard segment and a soft segment.
  • the hard segment is composed of polyurethane.
  • the soft segment is composed of polycarbonate-based polyols, ether-based polyols, caprolactone-based polyesters, adipate-based polyesters, and the like.
  • the addition amount (content rate) of the hydrogen bonding resin in the entire sealing film 1 is preferably 0.2% by mass or more and 30% by mass or less, more preferably 0.5% by mass or more and 20% by mass or less, and 1.0% by mass or more. % by mass or more and 10 mass % or less is more preferable.
  • the amount of the hydrogen-bonding resin added to the entire sealing film 1 is 0.2% by mass or more, the effect of reducing the influence of hydrogen fluoride on the electrode lead wires 11 can be enhanced. If the amount of hydrogen-bonding resin added to the entire encapsulating film 1 is 30% by mass or less, functional deterioration of the layer containing the hydrogen-bonding resin (base material layer 4 in this embodiment) can be suppressed. For example, deterioration of heat resistance, mechanical strength, etc. of the base material layer 4 can be suppressed.
  • the layer containing the hydrogen-bonding resin is at least one of the first adhesive layer 2 and the second adhesive layer 3, the amount of the hydrogen-bonding resin added to the entire sealing film 1 is 30% by mass or less. Then, deterioration of adhesiveness, mechanical strength, etc. of the adhesive layer can be suppressed.
  • the addition amount of the hydrogen bonding resin in the base material layer 4 is, for example, 0.5% by mass or more and 60% by mass or less (preferably 1.0% by mass or more and 40% by mass or less, more preferably 2.0% by mass or more and 20% by mass or more. mass% or less).
  • the layer containing the hydrogen-bonding resin may contain not only the hydrogen-bonding resin and polyolefin, but also other resin materials.
  • the layer containing the hydrogen-bonding resin (the substrate layer 4 in this embodiment) may be composed only of the hydrogen-bonding resin.
  • the thickness (thickness ratio) of the base material layer 4 is preferably 5 or more and 70 or less, with the total thickness of the sealing film 1 being 100. That is, the thickness of the base material layer 4 is preferably 5% or more and 70% or less of the total thickness of the sealing film 1 .
  • the thickness ratio of the base material layer 4 is 5 or more, the resin does not flow excessively, and the necessary fluidity is easily exhibited during pressure bonding.
  • the thickness ratio of the base material layer 4 is 5 or more (preferably 25 or more), there is an advantage that the electrolytic solution resistance and heat resistance of the sealing film 1 can be improved.
  • the thickness ratio of the base material layer 4 is 70 or less, the fluidity of the resin during thermocompression bonding can be suppressed within an appropriate range.
  • the thickness ratio of the base material layer 4 is 70 or less, the first adhesive layer 2 and the second adhesive layer 3 can be given a sufficient thickness, so the adhesive strength between the first adhesive layer 2 and the electrode lead wire 11 can be increased. , and the adhesive strength between the second adhesive layer 3 and the container can be increased.
  • the melting point of the resin (or resin composition) forming the base material layer 4 is preferably 150°C or higher and 170°C or lower.
  • the melting point of the resin constituting the base material layer 4 is 150° C. or higher, it is easy to ensure the electrolytic solution resistance of the sealing film 1 . Moreover, heat resistance can be imparted to the sealing film 1 .
  • the sealing film 1 can be given flexibility. Therefore, gaps are less likely to occur between the electrode lead wires 11 and the container, and the sealing film 1 .
  • the melting point M4 of the resin forming the base material layer 4 is higher than the melting point M2 of the resin forming the first adhesive layer 2 or the melting point M3 of the resin forming the second adhesive layer 3. That is, melting point M4 is higher than melting point M2 or melting point M3.
  • the melting point M4 is preferably higher than both the melting point M2 and the melting point M3. In other words, the melting point M4 is preferably higher than at least one of the melting points M2 and M3.
  • the melting point M4 When the melting point M4 is higher than the melting point M2, the fluidity of the resin does not become too low, and the fluidity of the resin during thermocompression bonding can be kept within an appropriate range. In addition, it becomes easier to ensure the electrolytic solution resistance of the sealing film 1 without lowering the adhesive strength between the first adhesive layer 2 and the electrode lead wire 11 .
  • the melting point M4 is higher than the melting point M3, the fluidity of the resin does not become too low, and the fluidity of the resin during thermocompression bonding can be kept within an appropriate range. Moreover, it becomes easy to ensure the electrolyte solution resistance of the sealing film 1, without reducing the adhesive strength of the 2nd contact bonding layer 3 and a container.
  • the melting point M4 When the melting point M4 is higher than the melting point M2 or the melting point M3, there is an advantage that the sealing film 1 can be easily imparted with heat resistance.
  • the hydrogen-bonding resin of the substrate layer 4 has low compatibility with other resins that constitute the substrate layer 4, uneven mixing (uneven mixing) and poor appearance due to undissolved residue may occur. .
  • all of the materials other than the hydrogen-bonding resin may be acid-modified polyolefin. 10 mass % or more is preferable.
  • adding a hydrogen-bonding resin to the first adhesive layer 2 it is desirable to add acid-modified polyolefin to the first adhesive layer 2 .
  • it is desirable to add acid-modified polyolefin to the second adhesive layer 3 it is desirable to add acid-modified polyolefin to the second adhesive layer 3 .
  • the electrode lead wire member 10 has electrode lead wires 11 and a pair of sealing films 1 .
  • the electrode lead wire 11 in this example has a strip shape with a constant thickness having both flat sides and extends linearly.
  • the sealing films 1 of this example have rectangular shapes with the same dimensions, and are arranged so that the central portions thereof are orthogonal to the electrode lead wires 11 .
  • the electrode lead wire member of the present invention is not limited to this shape, and can be appropriately modified as necessary.
  • a pair of sealing films 1 are arranged with the first adhesive layers 2 facing each other.
  • a pair of sealing films 1 sandwich an electrode lead wire 11 .
  • the pair of sealing films 1 are in contact with regions corresponding to one surface and the other surface of the electrode lead wire 11, respectively. Therefore, the pair of sealing films 1 are in contact with the entire circumference of the electrode lead wire 11 as a whole.
  • the electrode lead wire 11 has a lead wire body 111 and a surface treatment layer 112 .
  • the electrode lead wire 11 extends linearly in one direction.
  • the electrode lead wire 11 is made of metal.
  • the electrode lead wire 11 has conductivity.
  • the electrode lead wire 11 is electrically connected to a lithium ion battery 30 (see FIG. 3).
  • the electrode lead wire 11 conducts electricity between the lithium ion battery 30 and an external device.
  • Known metals such as aluminum, copper, nickel, iron, gold, platinum, and various alloys can be used as the material of the lead wire main body 111 .
  • aluminum and copper are preferable because they have excellent conductivity and are advantageous in terms of cost.
  • the surface of the lead wire body 111 may be nickel-plated.
  • the nickel plating of the lead wire body 111 may be formed by electroplating using a Watts bath containing nickel sulfate, nickel chloride, boric acid, or the like as a main component.
  • Nickel plating of the lead wire body 111 is preferably performed using a nickel sulfamate plating bath containing nickel sulfamate and boric acid as main components.
  • the plating film formed by this method has excellent flexibility and is less likely to crack.
  • the lead wire body 111 is preferably an aluminum plate or a nickel-plated copper plate.
  • the surface treatment layer 112 is formed on the surface of the lead wire main body 111 .
  • the surface treatment layer 112 has corrosion resistance. "Corrosion resistance” refers to the property of being resistant to corrosion by the electrolyte inside the battery.
  • an acid-resistant coating made of phosphate, chromate, fluoride, triazinethiol compound, or the like can be used.
  • the acid-resistant coating can be formed by subjecting the lead wire body 111 to a chemical conversion treatment.
  • the electrode lead wire may not have the surface treatment layer formed thereon.
  • the sealing film 1 contains a hydrogen-bonding resin. Therefore, when hydrogen fluoride is contained in the electrolytic solution, at least part of this hydrogen fluoride is captured by the sealing film 1 through hydrogen bonding with the hydrogen-bonding resin. Therefore, the influence of hydrogen fluoride on the electrode lead wire 11 can be reduced, and deterioration of the electrode lead wire 11 can be suppressed. Therefore, a decrease in adhesive strength of the sealing film 1 to the electrode lead wire 11 can be suppressed.
  • the sealing film 1 includes a first adhesive layer 2, a base material layer 4, and a second adhesive layer 3, which are laminated in order. Therefore, different properties can be imparted to each layer by selecting the constituent materials. Therefore, the base material layer 4 can enhance the resistance to the electrolytic solution and the heat resistance, and the adhesive layers 2 and 3 can enhance the adhesion to the electrode lead wire 11 and the container.
  • the hydrogen-bonding resin is contained only in the base material layer 4, it is possible to increase the ratio of materials excellent in adhesive strength in the adhesive layers 2 and 3. can enhance sexuality.
  • the electrode lead wire member 10 is provided with the sealing film 1, it is possible to suppress a decrease in the adhesive strength between the sealing film 1 and the electrode lead wire 11.
  • FIG. 3 is a schematic perspective view showing the battery 100 of the embodiment.
  • the battery 100 has the above-described electrode lead wire member 10, container 20, and lithium ion battery 30 (battery main body).
  • a battery main body 30 of this example has a flat rectangular parallelepiped shape, and a pair of electrode lead wire members 10 are connected to one end in the longitudinal direction so as to be parallel to each other.
  • the storage container 20 of this example has a flat rectangular parallelepiped shape corresponding to the battery main body 30 .
  • the battery of the present invention is not limited to this shape, and can be appropriately modified as necessary.
  • the container 20 has a container body 21 and a lid 22 .
  • the container main body 21 is obtained by drawing a laminate for battery exterior.
  • the container main body 21 has a molded portion 21a that forms a concave portion that accommodates the lithium ion battery 30 .
  • the battery exterior laminate will be described later.
  • the lid 22 is composed of a laminate for battery exterior, and has a plane view area equivalent to that of the container body 21 .
  • the storage container 20 is formed by stacking a container body 21 and a lid 22 and heat-sealing a peripheral edge portion 25 .
  • FIG. 4 is a cross-sectional view taken along line II in FIG.
  • the battery exterior laminate which is the constituent material of the container body 21 and the lid 22, includes a first film substrate 201, a second film substrate 202, a metal foil 203, and a sealant layer 204 in this order. It is a laminate laminated with
  • the resin that constitutes the first film substrate 201 and the second film substrate 202 polyamide, polyethylene terephthalate (PET), phenolic resin, polypropylene, and the like are suitable.
  • PET polyethylene terephthalate
  • metal foil 203 aluminum foil, stainless steel foil, copper foil, iron foil, or the like can be used.
  • the sealant layer 204 is heat-sealed in contact with the second adhesive layer 3 of the sealing film 1 .
  • a resin that can be fused with the sealing film 1 is selected as the resin that forms the sealant layer 204 .
  • the resin forming the sealant layer 204 include polypropylene-based resins and polyethylene-based resins.
  • the polypropylene-based resin a homopolymer of polypropylene, a copolymer of propylene and ethylene, or the like can be used.
  • Low-density polyethylene, linear low-density polyethylene, or the like can be used as the polyethylene-based resin.
  • the electrode lead wire member 10 is pulled out of the container 20 from the lithium ion battery 30 inside the container 20 (inside the molded portion 21a).
  • the electrode lead wire 11 is fused to the sealant layer 204 of the container 20 via the sealing film 1 .
  • the electrode lead wire member 10 since the electrode lead wire member 10 has the above-described sealing film 1, the deterioration of the electrode lead wire 11 due to hydrogen fluoride is suppressed, and the adhesion strength between the sealing film 1 and the electrode lead wire 11 is reduced. can be suppressed. Therefore, a highly reliable battery 100 can be realized.
  • the sealing film 1 shown in FIG. 1 includes a first adhesive layer 2 (first thermoplastic resin layer), a second adhesive layer 3 (second thermoplastic resin layer), and a substrate layer 4 (third Of the plastic resin layers), only the substrate layer 4 contains a hydrogen-bonding resin, but the sealing film is not limited to the structure shown in FIG.
  • the hydrogen-bonding resin should be contained in at least one of the first to third thermoplastic resin layers.
  • the hydrogen-bonding resin may be contained in any thermoplastic resin layer.
  • only the first adhesive layer 2 may contain the hydrogen bonding resin, or only the second adhesive layer 3 may contain the hydrogen bonding resin. It may contain a flexible resin.
  • the hydrogen-bonding resin may be contained in only two of the first adhesive layer 2, the second adhesive layer 3, and the base material layer 4.
  • the first adhesive layer 2 and the second adhesive layer 3 may contain a hydrogen-bonding resin
  • the first adhesive layer 2 and the substrate layer 4 may contain a hydrogen-bonding resin
  • the second adhesive layer 3 and the substrate layer 4 may contain a hydrogen-bonding resin.
  • the hydrogen-bonding resin may be contained in all of the first adhesive layer 2, the second adhesive layer 3, and the base material layer 4.
  • the amount of the hydrogen-bonding resin added the amount exemplified in the sealing film 1 shown in FIG. 1 can be adopted.
  • At least one of the first to third thermoplastic resin layers of the sealing film contains a hydrogen-bonding resin. At least part of the hydrogen is trapped in the sealing film by hydrogen bonding with the hydrogen-bonding resin. Therefore, a decrease in adhesive strength of the sealing film to the electrode lead wire can be suppressed.
  • thermoplastic resin layer contains a hydrogen-bonding resin includes the case where the thermoplastic resin layer is composed only of a hydrogen-bonding resin.
  • Hydrogen-bonding resins are not limited to homopolymers of monomers containing structures capable of hydrogen bonding, and may be copolymers of monomers containing structures capable of hydrogen bonding and monomers not containing structures capable of hydrogen bonding. good.
  • the sealing film 1 shown in FIG. 1 includes a first adhesive layer 2, a second adhesive layer 3, and a base material layer 4, but the sealing film of the embodiment is not limited to this structure.
  • FIG. 5 is a schematic cross-sectional view showing a sealing film of another embodiment.
  • the sealing film 401 shown in FIG. 5 has a two-layer structure including a first adhesive layer 102 (first thermoplastic resin layer) and a second adhesive layer 103 (second thermoplastic resin layer). there is The same reference numerals are given to the same components as those of the sealing film 1 shown in FIG. 1, and the description thereof is omitted.
  • the constituent material of the first adhesive layer 102 may be the material exemplified as the constituent material of the first adhesive layer 2 in the sealing film 1 shown in FIG.
  • the constituent material of the second adhesive layer 103 may be the material exemplified as the constituent material of the second adhesive layer 3 in the sealing film 1 shown in FIG.
  • a hydrogen-bonding resin is added to one or both of the first adhesive layer 102 and the second adhesive layer 103 .
  • the amount of the hydrogen-bonding resin added the amount exemplified for the sealing film 1 shown in FIG. 1 can be adopted.
  • the sealing film 401 contains a hydrogen-bonding resin, it is possible to suppress a decrease in adhesive strength to the electrode lead wire 11 .
  • FIG. 6 is a schematic cross-sectional view showing a sealing film of still another embodiment.
  • a sealing film 501 shown in FIG. 6 has a single-layer structure. The same reference numerals are given to the same components as those of the sealing film 1 shown in FIG. 1, and the description thereof is omitted.
  • the sealing film 501 is composed of one thermoplastic resin layer.
  • the constituent material of the sealing film 501 may be the material exemplified as the constituent material of the first adhesive layer 2 or the second adhesive layer 3 in the sealing film 1 shown in FIG.
  • a hydrogen-bonding resin is added to the sealing film 501 . As for the amount of the hydrogen-bonding resin added, the amount exemplified for the sealing film 1 shown in FIG. 1 can be adopted.
  • the sealing film 501 contains a hydrogen-bonding resin, it is possible to suppress a decrease in adhesive strength to the electrode lead wire 11 .
  • the first adhesive layer and the second adhesive layer may contain a resin other than polyolefin.
  • the sealing film may contain layers other than the first adhesive layer, the base material layer and the second adhesive layer.
  • a sealing film formed of only the substrate layer was produced as follows.
  • a sealing film was obtained by heating and melting a resin that is a raw material of the base material layer to form a film.
  • This sealing film was formed in a belt shape (width 15 mm, thickness 100 ⁇ m).
  • the sealing film (base material layer) is composed of a mixture of maleic anhydride-modified polypropylene (melting point 140°C) and nylon 6 (melting point 225°C).
  • Maleic anhydride-modified polypropylene is a polymer obtained by graft polymerizing maleic anhydride to a random copolymer of propylene and ethylene.
  • Nylon 6 is a hydrogen bonding resin because it contains amide bonding atoms. The amount of nylon 6 added to the entire sealing film is 0.2% by mass.
  • a sealing film in which a first adhesive layer, a substrate layer, and a second adhesive layer were laminated in this order was produced as follows.
  • a laminate was obtained by separately heating and melting the resins used as raw materials for each layer and performing simultaneous multilayer film formation using an extruder capable of simultaneous multilayer extrusion molding. This laminate was formed into a belt shape (width 15 mm, thickness 100 ⁇ m).
  • first adhesive layer maleic anhydride-modified polypropylene (melting point 140°C)
  • Base layer mixture of polypropylene ICP (melting point 161°C) and nylon 6 (melting point 225°C)
  • Second adhesive layer random copolymer of propylene and ethylene (melting point 140°C)
  • the maleic anhydride-modified polypropylene is the same as the maleic anhydride-modified polypropylene used in Example 1.
  • Polypropylene ICP has a structure (sea-island structure) in which the second phase is dispersed in the first phase.
  • the first phase consists of homo PP.
  • the second phase contains ethylene propylene rubber and polyethylene.
  • the thickness of the first adhesive layer is 10 ⁇ m.
  • the thickness of the base layer is 50 ⁇ m.
  • the thickness of the second adhesive layer is 40 ⁇ m.
  • the amount of nylon 6 added to the entire sealing film was 0.2% by mass.
  • the amount of nylon 6 added to the base material layer is 0.4% by mass.
  • the amount of nylon 6 added to the entire sealing film was 1% by mass.
  • the amount of nylon 6 added to the base material layer was 2% by mass.
  • Example 5 the amount of nylon 6 added to the entire sealing film was 5% by mass.
  • the amount of nylon 6 added to the base material layer was 10% by mass.
  • the amount of nylon 6 added to the entire sealing film was 10% by mass.
  • the amount of nylon 6 added to the base material layer was 20% by mass.
  • Example 7 the amount of nylon 6 added to the entire sealing film was 20% by mass. The amount of nylon 6 added to the base material layer was 40% by mass. In Example 8, the amount of nylon 6 added to the entire sealing film was 30% by mass. The amount of nylon 6 added to the base material layer was 60% by mass.
  • Example 3 A sealing film in which a first adhesive layer, a substrate layer, and a second adhesive layer were laminated in this order was produced as follows.
  • the constituent materials of the first adhesive layer, the base material layer, and the second adhesive layer are as follows.
  • First adhesive layer mixture of maleic anhydride-modified polypropylene (melting point 140 ° C.) and nylon 6
  • Base layer mixture of polypropylene ICP (melting point 161 ° C.) and nylon 6
  • Second adhesive layer random co-polymer of propylene and ethylene Mixture of Polymer (Melting Point 140° C.) and Nylon 6
  • the amount of nylon 6 added to the entire sealing film was 1% by mass.
  • the amount of nylon 6 added to each of the first adhesive layer, base layer, and second adhesive layer was 1% by mass. Other conditions are the same as in Example 2.
  • the amount of nylon 6 added to the entire sealing film was 30% by mass.
  • the amount of nylon 6 added to each of the first adhesive layer, the substrate layer, and the second adhesive layer was 30% by mass. Other conditions are the same as in Example 2.
  • Example 10 A sealing film in which the first adhesive layer and the second adhesive layer are laminated was produced as follows.
  • the constituent materials of the first adhesive layer and the second adhesive layer are as follows.
  • First adhesive layer mixture of maleic anhydride-modified polypropylene (melting point 140°C) and nylon 6
  • Second adhesive layer mixture of random copolymer of propylene and ethylene (melting point 140°C) and nylon 6
  • First adhesive layer is 20 ⁇ m thick.
  • the thickness of the second adhesive layer is 80 ⁇ m.
  • the amount of nylon 6 added to the entire sealing film is 30% by mass.
  • the amount of nylon 6 added to the first adhesive layer and the second adhesive layer was 30% by mass, respectively.
  • Other conditions are the same as in Example 3.
  • Examples 11 to 15 As in Examples 2 and 4 to 8, a sealing film in which a first adhesive layer, a base layer, and a second adhesive layer were laminated in this order was produced as follows.
  • a laminate was obtained by separately heating and melting the resins used as raw materials for each layer and performing simultaneous multilayer film formation using an extruder capable of simultaneous multilayer extrusion molding. This laminate was formed into a belt shape (width 15 mm, thickness 100 ⁇ m).
  • first adhesive layer maleic anhydride-modified polypropylene (melting point 140°C)
  • Base layer mixture of polypropylene ICP (melting point 161°C) and nylon MXD6 (melting point 240°C)
  • Second adhesive layer random copolymer of propylene and ethylene (melting point 140°C)
  • the maleic anhydride-modified polypropylene is the same as the maleic anhydride-modified polypropylene used in Example 1.
  • Polypropylene ICP has a structure (sea-island structure) in which the second phase is dispersed in the first phase.
  • the first phase consists of homo PP.
  • the second phase contains ethylene propylene rubber and polyethylene.
  • Nylon MXD6 is a hydrogen bonding resin because it contains amide bonding atoms.
  • the thickness of the first adhesive layer is 25 ⁇ m.
  • the thickness of the base layer is 50 ⁇ m.
  • the thickness of the second adhesive layer is 25 ⁇ m.
  • the amount of nylon MXD6 added to the entire sealing film is 0.5% by mass.
  • the amount of nylon MXD6 added to the base material layer was 1.0% by mass.
  • the amount of nylon MXD6 added to the entire sealing film is 0.8% by mass.
  • the amount of nylon MXD6 added to the base material layer was 1.5% by mass.
  • Example 13 the amount of nylon MXD6 added to the entire sealing film is 1.0% by weight.
  • the amount of nylon MXD6 added to the base material layer was 2.0% by mass.
  • the amount of nylon MXD6 added to the entire sealing film is 1.3% by weight.
  • the amount of nylon MXD6 added to the base material layer was 2.5% by mass.
  • the amount of nylon MXD6 added to the entire sealing film is 2.0% by weight.
  • Example 1 A sealing film was produced in the same manner as in Example 2, except that nylon 6 was not added to the base layer. The amount of nylon 6 added to the entire sealing film is 0% by mass.
  • a sealing film was produced in the same manner as in Example 2, except that the amount of nylon 6 added to the substrate layer was 80% by mass. The amount of nylon 6 added to the entire sealing film is 40% by mass.
  • Electrode lead wire having a lead wire body and a surface treatment layer formed on the surface of the lead wire body was produced.
  • ⁇ Test 1 Measurement of adhesive strength to electrode lead wire (non-immersion)>
  • the adhesive strength of the sealing films to the electrode lead wires was measured as follows. This test is a test under "non-immersion" conditions because the sample for measurement is not immersed in the electrolytic solution (described later). A sealing film and an electrode lead wire were overlapped and adhered by heat sealing to obtain a sample for measurement. The heat sealing conditions were 180° C., 0.5 MPa, and 10 seconds. The 180-degree peel strength (adhesive strength) of this measurement sample was measured using a tester (a desktop precision universal tester manufactured by Shimadzu Corporation: Autograph AGS-500NX) as follows.
  • Table 1 shows the measurement results of the sealing films of Examples 1 to 10, Comparative Example 1, and Reference Examples 1 to 3.
  • Table 2 shows the measurement results for the sealing films of Examples 11 to 15.
  • ⁇ Test 2 Measurement of adhesive strength to electrode lead wire (after immersion)>
  • the adhesive strength of the sealing films to the electrode lead wires was measured as follows. This test is a test under the condition of "after immersion” because the measurement is performed after the sample for measurement is immersed in the electrolytic solution.
  • a sample for measurement prepared in the same manner as in Test 1 was placed in this packaging bag and immersed in the electrolytic solution. After storing the packaging bag containing the sample for measurement in an oven at 85° C. for 7 days, the 180° peel strength (adhesive strength) was measured in the same manner as in Test 1.
  • Table 1 shows the measurement results of the sealing films of Examples 1 to 10, Comparative Example 1, and Reference Examples 1 to 3.
  • Table 2 shows the measurement results for the sealing films of Examples 11 to 15.
  • the mechanical strength of the sealing films of Examples 1 to 15, Comparative Example 1, and Reference Examples 1 to 3 was measured as follows. Using each sealing film, a type 5 dumbbell-shaped test piece specified in JIS K7127 was produced. This test piece was subjected to a tensile test according to JIS K7127 using a desktop precision universal testing machine Autograph AGS-X manufactured by Shimadzu Corporation. The chuck-to-chuck distance was 80 mm. The test speed (tensile speed) was 500 mm/min. The test environment was a temperature of 23° C. and a humidity of 50% RH. When the tensile strength (breaking strength) at the time of cutting was 25 MPa or more, it was judged as "good”. When the breaking strength was less than 25 MPa, it was determined as "low”. Table 1 shows the measurement results of the sealing films of Examples 1 to 10, Comparative Example 1, and Reference Examples 1 to 3. Table 2 shows the measurement results for the sealing films of Examples 11 to 15.
  • Tables 1 and 2 show the product of the added amount [mass%] of the hydrogen-bonding resin (nylon 6 or nylon MXD6) in each layer and the thickness [ ⁇ m] of the layer (added amount of hydrogen-bonding resin ⁇ Thickness) [mass % ⁇ m] and hydrogen-bonding resin added amount [mass %] of the entire sealing film are also shown.
  • the sealing film, the electrode lead wire member and the battery of the present invention it is possible to suppress the reduction in adhesive strength due to hydrogen fluoride, so the present invention can be applied industrially.

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EP22872993.5A EP4407761A4 (en) 2021-09-24 2022-09-22 SEALING FILM, ELECTRODE CONDUCTIVE WIRE ELEMENT AND BATTERY
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