WO2023037698A1 - ウエハ載置台 - Google Patents
ウエハ載置台 Download PDFInfo
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- WO2023037698A1 WO2023037698A1 PCT/JP2022/025141 JP2022025141W WO2023037698A1 WO 2023037698 A1 WO2023037698 A1 WO 2023037698A1 JP 2022025141 W JP2022025141 W JP 2022025141W WO 2023037698 A1 WO2023037698 A1 WO 2023037698A1
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- WIPO (PCT)
- Prior art keywords
- wafer mounting
- mounting table
- ceramic
- cooling
- wafer
- Prior art date
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- 238000001816 cooling Methods 0.000 claims abstract description 102
- 239000000919 ceramic Substances 0.000 claims abstract description 79
- 239000002826 coolant Substances 0.000 claims abstract description 71
- 239000000758 substrate Substances 0.000 claims abstract description 70
- 229910052751 metal Inorganic materials 0.000 claims abstract description 47
- 239000002184 metal Substances 0.000 claims abstract description 47
- 239000002131 composite material Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims description 83
- 229910010293 ceramic material Inorganic materials 0.000 claims description 3
- 235000012431 wafers Nutrition 0.000 description 112
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 12
- 229910000962 AlSiC Inorganic materials 0.000 description 10
- 230000002093 peripheral effect Effects 0.000 description 9
- 229910010271 silicon carbide Inorganic materials 0.000 description 9
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 238000009434 installation Methods 0.000 description 6
- 239000011156 metal matrix composite Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000011153 ceramic matrix composite Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018566 Al—Si—Mg Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68714—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
- H01L21/68721—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by edge clamping, e.g. clamping ring
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67103—Apparatus for thermal treatment mainly by conduction
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67109—Apparatus for thermal treatment mainly by convection
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6831—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using electrostatic chucks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68714—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
- H01L21/68757—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by a coating or a hardness or a material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68714—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
- H01L21/68785—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by the mechanical construction of the susceptor, stage or support
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3731—Ceramic materials or glass
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3736—Metallic materials
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
- H02N13/00—Clutches or holding devices using electrostatic attraction, e.g. using Johnson-Rahbek effect
Definitions
- the present invention relates to a wafer mounting table.
- a wafer mounting table in which a ceramic base material such as alumina in which an electrostatic chucking electrode is embedded and a cooling base material made of a metal such as aluminum are bonded via a resin layer (for example, Patent Document 1). reference). According to such a wafer mounting table, the effect of the difference in thermal expansion between the ceramic base and the cooling base can be mitigated by the resin layer.
- a wafer mounting table is also known in which a ceramic substrate and a cooling substrate having coolant flow paths are bonded using a metal bonding layer instead of a resin layer (for example, Patent Documents 2 and 3). Since the metal bonding layer has a higher thermal conductivity than the resin layer, it can realize the heat removal capability required when processing wafers with high-power plasma.
- Patent Documents 2 and 3 a metal matrix composite (MMC) having a small difference in thermal expansion coefficient from the ceramic substrate is used as the material for the cooling substrate.
- MMC metal matrix composite
- MMC does not have the malleability of metal, if a large temperature difference occurs in the vertical direction in the portion of the cooling base above the coolant channel, stress is generated in that portion and it breaks. I was afraid.
- the present invention has been made to solve such problems, and its main object is to prevent breakage due to stress in a wafer mounting table in which a ceramic substrate and a cooling substrate are bonded with a metal bonding layer. .
- the wafer mounting table of the present invention is a ceramic substrate having a wafer mounting surface on its upper surface and containing an electrode; a cooling base made of a metal-ceramic composite material having a coolant channel formed therein; a metal bonding layer that bonds the lower surface of the ceramic base and the upper surface of the cooling base; A wafer mounting table comprising The thickness of the cooling substrate below the coolant channel is 13 mm or more, or 43% or more of the total thickness of the cooling substrate.
- the thickness of the cooling substrate below the coolant channel is 13 mm or more, or 43% or more of the total thickness of the cooling substrate.
- the thickness of the cooling substrate above the coolant channel is relatively thin. Therefore, a large temperature difference in the vertical direction is less likely to occur in the portion of the cooling base above the coolant channel, and stress is less likely to occur in that portion. Therefore, it is possible to prevent the portion of the cooling base above the coolant channel from being damaged by stress.
- the present invention may be described using terms such as up and down, left and right, front and back, but up and down, left and right, and front and back are merely relative positional relationships. Therefore, when the orientation of the wafer table is changed, up and down may become left and right, or left and right may become up and down. Such cases are also included in the technical scope of the present invention.
- the cooling base has a thickness of 15 mm or more below the coolant channel, or the cooling base has a thickness of 15 mm or more. It is preferably 49% or more of the total thickness. In this way, the thickness of the cooling base above the coolant channel is relatively thin, and it becomes easier to prevent the portion of the cooling base above the coolant channel from being damaged by stress.
- the cooling base has a thickness of 5 mm or less above the coolant channel.
- a ceramic substrate having a wafer mounting surface on its upper surface and containing an electrode; a cooling base made of a metal-ceramic composite material having a coolant channel formed therein; a metal bonding layer that bonds the lower surface of the ceramic base and the upper surface of the cooling base;
- a wafer mounting table comprising A thickness of the cooling base material above the coolant channel is 5 mm or less.
- the cooling base may have a thickness of 3 mm or less above the coolant channel.
- the cooling base has a flange used for clamping the wafer mounting table on the lower surface side.
- the width of the flange portion is 3 mm or more, or the outer diameter of the flange portion is 101.8% or more of the outer diameter of the ceramic substrate.
- the width of the flange portion is 10 mm or more, or the outer diameter of the flange portion is 106% or more of the outer diameter of the ceramic base material. is more preferable. By doing so, the risk of warping or the like is reduced, the risk of damage to the product is reduced, and further improvement in heat uniformity can be expected.
- the ceramic base material may be an alumina base material
- the metal-ceramic composite material may be alumina.
- the absolute value of the linear thermal expansion coefficient difference between 40 and 570° C. may be 1 ⁇ 10 ⁇ 6 /K or less.
- Examples of such metal-ceramic composite materials include AlSiC and SiSiCTi.
- FIG. 4 is a longitudinal sectional view of the wafer mounting table 10 installed in the chamber 94;
- FIG. 2 is a plan view of the wafer mounting table 10;
- FIG. 4 is an explanatory view of symbols representing dimensions of the wafer mounting table 10;
- 4A to 4C are manufacturing process diagrams of the wafer mounting table 10;
- FIG. 4 is a vertical cross-sectional view of another embodiment of the wafer table 10;
- FIG. 1 is a longitudinal sectional view of the wafer mounting table 10 installed in the chamber 94 (a sectional view taken along a plane including the central axis of the wafer mounting table 10),
- FIG. 2 is a plan view of the wafer mounting table 10, and
- FIG. 2 is an explanatory diagram of symbols representing dimensions of the wafer mounting table 10.
- FIG. in this specification "-" indicating a numerical range is used to include the numerical values before and after it as lower and upper limits.
- the wafer mounting table 10 is used to perform CVD, etching, etc. on the wafer W using plasma, and is fixed to a mounting plate 96 provided inside a chamber 94 for semiconductor processing.
- the wafer mounting table 10 includes a ceramic substrate 20 , a cooling substrate 30 and a metal bonding layer 40 .
- the ceramic substrate 20 has an outer peripheral portion 24 having an annular focus ring mounting surface 24a on the outer periphery of a central portion 22 having a circular wafer mounting surface 22a.
- the focus ring may be abbreviated as "FR”.
- a wafer W is mounted on the wafer mounting surface 22a, and a focus ring 78 is mounted on the FR mounting surface 24a.
- the ceramic substrate 20 is made of a ceramic material typified by alumina, aluminum nitride, and the like.
- the FR mounting surface 24a is one step lower than the wafer mounting surface 22a.
- the central portion 22 of the ceramic base material 20 incorporates a wafer chucking electrode 26 on the side closer to the wafer mounting surface 22a.
- the wafer chucking electrode 26 is made of a material containing W, Mo, WC, MoC, or the like, for example.
- the wafer chucking electrode 26 is a disc-shaped or mesh-shaped unipolar electrostatic chucking electrode.
- a layer of the ceramic substrate 20 above the wafer chucking electrode 26 functions as a dielectric layer.
- a wafer chucking DC power source 52 is connected to the wafer chucking electrode 26 via a power supply terminal 54 .
- the power supply terminal 54 passes through an insulating tube 55 arranged in a through-hole vertically penetrating the cooling base material 30 and the metal bonding layer 40 so as to extend from the lower surface of the ceramic base material 20 to the wafer adsorption electrode 26 . is provided.
- a low-pass filter (LPF) 53 is provided between the DC power supply 52 for wafer attraction and the electrode 26 for wafer attraction.
- the cooling base material 30 is a disk member.
- a metal-ceramic composite material is preferable as the material of the cooling substrate 30 .
- Metal-ceramic composite materials include metal matrix composites (metal matrix composites, MMC) and ceramic matrix composites (ceramic matrix composites, CMC).
- the cooling base material 30 has coolant channels 32 in which coolant can circulate.
- the coolant channel 32 is connected to a coolant supply channel and a coolant discharge channel (not shown), and the coolant discharged from the coolant discharge channel is returned to the coolant supply channel after its temperature is adjusted.
- the coolant flowing through the coolant channel 32 is preferably liquid and preferably electrically insulating. Examples of electrically insulating liquids include fluorine-based inert liquids.
- An upper corner portion 32a of the cross section of the coolant channel 32 is a rounded surface.
- the curvature radius of the R surface is preferably 0.5 to 2 mm, for example.
- the composite material used for the cooling base material 30 preferably has a linear thermal expansion coefficient difference of 1 ⁇ 10 ⁇ 6 /K or less from the ceramic material used for the ceramic base material 20 at 40 to 570° C. It is more preferably 0.5 ⁇ 10 ⁇ 6 /K or less, and even more preferably 0.2 ⁇ 10 ⁇ 6 /K or less.
- Specific examples of metal-ceramic composite materials include materials containing Si, SiC and Ti, materials in which SiC porous bodies are impregnated with Al and/or Si, and composite materials of Al 2 O 3 and TiC.
- SiSiCTi A material containing Si, SiC and Ti is referred to as SiSiCTi
- AlSiC a material obtained by impregnating a porous SiC body with Al
- SiSiC a material obtained by impregnating a porous SiC body with Si
- the composite material used for the cooling base material 30 is preferably AlSiC, SiSiCTi, or the like.
- the coefficient of linear thermal expansion at 40 to 570° C. is 7.7 ⁇ 10 ⁇ 6 /K for alumina, 7.5 ⁇ 10 ⁇ 6 /K for AlSiC, and 7.8 ⁇ 10 ⁇ 6 /K for SiSiCTi. is.
- Cooling substrate 30 is connected to RF power supply 62 via power supply terminal 64 .
- a high pass filter (HPF) 63 is arranged between the cooling substrate 30 and the RF power supply 62 .
- the cooling base material 30 has a flange portion 34 on the lower surface side thereof, which is used for clamping the wafer mounting table 10 to the mounting plate 96 .
- the thickness t1 of the cooling base material 30 below the coolant flow path 32 is 13 mm or more, or 43% or more of the total thickness B of the cooling base material 30 .
- This thickness t1 is preferably 15 mm or more, or 49% or more of the thickness B.
- the thickness t2 of the cooling base material 30 above the coolant channel 32 is preferably 5 mm or less, more preferably 3 mm or less.
- the thickness t2 is preferably 1 mm or more in consideration of workability.
- the width w of the flange portion 34 is preferably 3 mm or more, more preferably 10 mm or more.
- the outer diameter C of the flange portion 34 is preferably 101.8% or more of the outer diameter A of the ceramic substrate 20, and more preferably 106% or more.
- the metal joining layer 40 joins the lower surface of the ceramic base 20 and the upper surface of the cooling base 30 .
- the metal bonding layer 40 may be, for example, a layer made of solder or brazing metal.
- the metal bonding layer 40 is formed by TCB (Thermal Compression Bonding), for example.
- TCB is a known method in which a metal bonding material is sandwiched between two members to be bonded, and the two members are pressure-bonded while being heated to a temperature below the solidus temperature of the metal bonding material.
- the side surface of the outer peripheral portion 24 of the ceramic substrate 20, the outer periphery of the metal bonding layer 40, and the side surface of the cooling substrate 30 are covered with an insulating film 42.
- an insulating film 42 for example, a sprayed film such as alumina or yttria can be used.
- Such a wafer mounting table 10 is attached to an installation plate 96 provided inside the chamber 94 using clamp members 70 .
- the clamp member 70 is an annular member having a substantially inverted L-shaped cross section, and has an inner peripheral stepped surface 70a.
- the wafer mounting table 10 and the installation plate 96 are integrated by the clamp member 70 .
- the bolt 72 is inserted from the upper surface of the clamp member 70 and provided on the upper surface of the installation plate 96. is screwed into a threaded hole.
- the bolts 72 are attached to a plurality of locations (for example, 8 or 12 locations) provided at regular intervals along the circumferential direction of the clamp member 70 .
- the clamp member 70 and the bolt 72 may be made of an insulating material, or may be made of a conductive material (such as metal).
- FIG. 4A a disk-shaped ceramic sintered body 120, which is the base of the ceramic base material 20, is produced by hot-press firing a compact of ceramic powder (FIG. 4A).
- the ceramic sintered body 120 incorporates the wafer adsorption electrode 26 .
- a hole 27 is formed from the lower surface of the ceramic sintered body 120 to the wafer adsorption electrode 26 (FIG. 4B), and the power supply terminal 54 is inserted into the hole 27 to join the power supply terminal 54 and the wafer adsorption electrode 26 together. (Fig. 4C).
- the disk members 131, 136 are made of a metal-ceramic composite material.
- the disk members 131 and 136 are preferably made of SiSiCTi or AlSiC. This is because the thermal expansion coefficient of alumina is approximately the same as that of SiSiCTi and AlSiC.
- a disk member made of SiSiCTi can be produced, for example, as follows. That is, first, 39 to 51% by mass of silicon carbide raw material particles having an average particle diameter of 10 ⁇ m or more and 25 ⁇ m or less are contained, and one or more raw materials selected so as to contain Ti and Si are contained, and silicon carbide is added. A powder mixture having a Si/(Si+Ti) mass ratio of 0.26 to 0.54 is prepared for Si and Ti derived from the raw materials except for the Si and Ti. Silicon carbide, metal Si, and metal Ti, for example, can be used as raw materials. In that case, it is preferable to mix 39 to 51% by mass of silicon carbide, 16 to 24% by mass of metallic Si, and 26 to 43% by mass of metallic Ti. Next, the obtained powder mixture is uniaxially pressed to form a disk-shaped molded body, and the molded body is sintered at 1370 to 1460 ° C. by hot pressing in an inert atmosphere to obtain a SiSiCTi is obtained.
- a metal bonding material is placed between the lower surface of the upper disc member 131 and the upper surface of the lower disc member 136 and the metal bonding material is placed on the upper surface of the upper disc member 131 .
- Through holes communicating with the through holes 134 and 138 are provided in each metal bonding material.
- the power supply terminal 54 of the ceramic sintered body 120 is inserted into the through holes 134 and 138 of the disk members 131 and 136, and the ceramic sintered body 120 is placed on the metal bonding material arranged on the upper surface of the upper disk member 131.
- a laminate is obtained in which the lower disk member 136, the metal bonding material, the upper disk member 131, the metal bonding material, and the ceramic sintered body 120 are stacked in this order from the bottom.
- a joined body 110 is obtained (FIG. 4F).
- the bonded body 110 is obtained by bonding a ceramic sintered body 120 to the upper surface of a block 130 that is the base of the cooling base material 30 via a metal bonding layer 40 .
- the block 130 is formed by joining an upper disk member 131 and a lower disk member 136 with a metal bonding layer 135 interposed therebetween.
- the block 130 has a coolant channel 32 inside.
- TCB is performed, for example, as follows. That is, the laminate is pressurized and bonded at a temperature below the solidus temperature of the metal bonding material (for example, the temperature obtained by subtracting 20° C. from the solidus temperature and below the solidus temperature), and then returned to room temperature. As a result, the metal bonding material becomes a metal bonding layer.
- the metal bonding material at this time an Al--Mg system bonding material or an Al--Si--Mg system bonding material can be used.
- Al-Si-Mg-based bonding material (containing 88.5 wt% Al, 10 wt% Si, 1.5 wt% Mg, solidus temperature of about 560 ° C.) using TCB
- the laminated body is heated to 540 to 560° C. in a vacuum atmosphere and pressurized at a pressure of 0.5 to 2.0 kg/mm 2 for several hours.
- a metal bonding material having a thickness of about 100 ⁇ m.
- the ceramic base material 20 having the central portion 22 and the outer peripheral portion 24 is formed.
- the cooling base material 30 having the flange portion 34 is formed.
- an insulating tube 55 through which the power supply terminal 54 is inserted is arranged in the through holes 134 and 138 and the hole of the metal bonding material.
- the insulating film 42 is formed by thermally spraying the side surface of the outer peripheral portion 24 of the ceramic substrate 20, the periphery of the metal bonding layer 40, and the side surface of the cooling substrate 30 using ceramic powder (FIG. 4G).
- cooling base material 30 in FIG. 1 is described as a single piece, it may have a structure in which two members are joined by a metal bonding layer as shown in FIG. 4G, or three or more members may be made of metal. A structure joined by a joining layer may be used.
- the wafer mounting table 10 is fixed to the installation plate 96 of the chamber 94 by the clamp members 70 as described above.
- a shower head 98 is arranged on the ceiling of the chamber 94 to discharge the process gas into the chamber 94 from many gas injection holes.
- a focus ring 78 is mounted on the FR mounting surface 24a of the wafer mounting table 10, and a disk-shaped wafer W is mounted on the wafer mounting surface 22a.
- the focus ring 78 has a step along the inner circumference of the upper end so as not to interfere with the wafer W.
- the DC voltage of the wafer chucking DC power supply 52 is applied to the wafer chucking electrode 26 to chuck the wafer W onto the wafer mounting surface 22a.
- the inside of the chamber 94 is set to a predetermined vacuum atmosphere (or reduced pressure atmosphere), and the RF voltage from the RF power supply 62 is applied to the cooling substrate 30 while supplying the process gas from the shower head 98 .
- Plasma is then generated between the wafer W and the shower head 98 .
- the wafer W is subjected to CVD film formation or etching.
- the focus ring 78 is also worn out as the wafer W is processed with plasma. However, since the focus ring 78 is thicker than the wafer W, the replacement of the focus ring 78 is performed after a plurality of wafers W are processed. will be
- the metal bonding layer 40 with high thermal conductivity is used as the bonding layer between the ceramic substrate 20 and the cooling substrate 30, instead of the resin layer with low thermal conductivity. Therefore, the ability to remove heat from the wafer W (heat removal ability) is high. In addition, since the difference in thermal expansion between the ceramic substrate 20 and the cooling substrate 30 is small, even if the stress relaxation property of the metal bonding layer 40 is low, no problem is likely to occur. Furthermore, in the present embodiment, by devising the arrangement of the coolant flow paths 32 in the cooling base material 30 made of a metal-ceramic composite material, stress is generated in the portion of the cooling base material 30 above the coolant flow paths 32. is suppressed.
- the thickness t1 of the cooling substrate 30 on the lower side than the coolant channel 32 is 13 mm or more, or 43% or more of the total thickness B of the cooling substrate 30.
- the thickness t2 of the cooling base material 30 above the coolant flow paths 32 is relatively thin. Therefore, a large temperature difference in the vertical direction is less likely to occur in the portion of the cooling substrate 30 above the coolant channel 32, and stress is less likely to occur in that portion. Therefore, it is possible to prevent the portion of the cooling substrate 30 above the coolant channel 32 from being damaged by stress.
- the rigidity of the portion of the cooling base material 30 below the coolant flow path 32 is improved.
- the thickness t1 of the cooling base material 30 below the coolant flow path 32 is preferably 15 mm or more, or 49% or more of the total thickness B of the cooling base material 30 .
- the thickness t2 of the cooling base material 30 above the coolant flow paths 32 is relatively thin, and the portion of the cooling base material 30 above the coolant flow paths 32 is less likely to be damaged by stress. easier to prevent.
- the thickness t2 of the cooling base material 30 above the coolant flow path 32 is 5 mm or less. By doing so, the above-described effects can be obtained remarkably. If the thickness t2 is set to 3 mm or less, the above effect can be obtained more significantly.
- the width w of the flange portion 34 is 3 mm or more, or the outer diameter C of the flange portion 34 is 101.8% or more of the outer diameter A of the ceramic substrate 20 .
- the width w of the flange portion 34 is 10 mm or more, or the outer diameter C of the flange portion 34 is 106% or more of the outer diameter A of the ceramic substrate 20 .
- the upper corner portion 32a of the cross section of the coolant channel 32 is a rounded surface. As a result, it is possible to prevent cracks from occurring starting from the corner 32a.
- the metal-ceramic composite material is preferably AlSiC or SiSiCTi. This is because AlSiC and SiSiCTi have a small absolute value of difference in coefficient of linear thermal expansion from 40 to 570° C. with alumina.
- a hole penetrating the wafer mounting table 10 may be provided so as to reach the wafer mounting surface 22a from the lower surface of the cooling substrate 30.
- Such holes include a gas supply hole for supplying a heat-conducting gas (eg, He gas) to the rear surface of the wafer W, a lift pin hole for inserting a lift pin for moving the wafer W up and down with respect to the wafer mounting surface 22a, and the like. is mentioned.
- the heat transfer gas is supplied to a space formed by the wafer W and a large number of small projections (not shown) provided on the wafer mounting surface 22a (supporting the wafer W).
- Three lift pin holes are provided when the wafer W is supported by, for example, three lift pins.
- the height of the flange portion 34 of the cooling substrate 30 is lower than the bottom surface of the coolant channel 32.
- the rigidity of the cooling base material 30 is increased, so that the wafer mounting table 10 clamped to the installation plate 96 by the clamp member 70 can be easily prevented from warping.
- the wafer chucking electrode 26 is embedded in the central portion 22 of the ceramic substrate 20, but instead of or in addition to this, an RF electrode for plasma generation may be embedded.
- a high frequency power supply is connected to the RF electrode.
- a focus ring (FR) adsorption electrode may be incorporated in the outer peripheral portion 24 of the ceramic base material 20 .
- a DC power source is connected to the FR adsorption electrode.
- the ceramic sintered body 120 of FIG. 4A was produced by hot-press firing a compact of ceramic powder.
- it may be produced by a mold casting method, or may be produced by compacting ceramic powder.
- the ceramic base material 20 was an alumina base material, and had a central portion 22 with a diameter of 296 [mm], an overall outer diameter A of 335.8 [mm], and an overall thickness of 4.6 [mm].
- the cooling base material 30 is made of SiSiCTi, has a total thickness B of 30.12 [mm], and the distance from the upper surface of the cooling base material 30 to the upper surface of the flange portion 34 is 7.6 [mm].
- the cross section of the coolant channel 32 has a length (height) of 12.12 [mm], a width (width) of 8 [mm], and a curvature radius of the upper corner portion 32a of 1 [mm].
- the metal bonding layer 40 uses an Al-containing bonding material and has a thickness of 0.12 [mm].
- the thickness t1 of the cooling substrate 30 below the coolant channel 32, the thickness t2 of the cooling substrate 30 above the coolant channel 32, and the width w of the flange portion 34 are shown in Table 1 for each experimental example. The values shown in are adopted. Table 1 shows the ratio t1/B [%] of the thickness t1 to the overall thickness B of the cooling substrate 30, the ratio w/A [%] of the width w of the flange portion 34 to the outer diameter A of the ceramic substrate 20, The ratio C/A [%] of the outer diameter C of the flange portion 34 to the outer diameter A of the ceramic substrate 20 is also shown.
- Table 1 shows the temperature of the wafer mounting surface of the ceramic substrate 20, the temperature of the upper surface of the cooling substrate 30, and the temperature difference between the upper and lower portions of the cooling substrate 30 above the coolant channels 32.
- the upper surface temperature of the cooling base material 30 is the temperature of the bonding interface between the cooling base material 30 and the metal bonding layer 40 .
- the temperature difference between the upper and lower portions of the cooling base material 30 above the coolant channels 32 is the temperature of the joint interface between the cooling base material 30 and the metal bonding layer 40 and the temperature of the ceiling surface of the coolant channels 32 of the cooling base material 30 . The difference is the temperature.
- the thicker t1 in other words, the thinner t2
- the thinner t2 the smaller the upper-lower temperature difference in the upper part of the coolant flow path 32 in the cooling substrate 30 . Therefore, the reason why the maximum stress becomes smaller as the t1 becomes thicker is that as the t1 becomes thicker, the upper and lower temperature difference in the portion of the cooling substrate 30 above the coolant flow path 32 becomes smaller, and stress is less likely to occur in that portion. is thought to be a factor.
- Experimental Examples 2 and 4 have the same thickness t1 of 13 mm, and the width w of the flange portion 34 is different. From the results of Table 1, the width w of the flange portion 34 is 10 [mm] (w/A is 3.0 [%], C/A is 106.0 [%]). The maximum stress was smaller than in Experimental Example 2 in which the width w of the portion 34 was 3 [mm] (w/A was 0.9 [%] and C/A was 101.8 [%]).
- Experimental Examples 3 and 5 have the same thickness t1 of 15 mm, and the width w of the flange portion 34 is different. From the results of Table 1, the width w of the flange portion 34 is 10 [mm] (w/A is 3.0 [%], C/A is 106.0 [%]). The maximum stress was smaller than in Experimental Example 3 in which the width w of the portion 34 was 3 [mm] (w/A was 0.9 [%] and C/A was 101.8 [%]). Experimental example 5 had the lowest maximum stress among experimental examples 1-5.
- Experimental Example 6 was the same as Experimental Example 1 except that AlSiC was used instead of SiSiCTi as the metal-ceramic composite material for the cooling base material 30.
- Experimental Example 5 except that AlSiC was used instead.
- the maximum stress was obtained and evaluated in the same manner as in Experimental Examples 1 to 5, and the temperature of the wafer mounting surface of the ceramic substrate 20, the upper surface temperature of the cooling substrate 30, and the cooling A difference in temperature between the upper and lower portions of the base material 30 above the coolant channel 32 was obtained. Table 1 shows the results. The maximum stress of Experimental Example 7 was significantly smaller than that of Experimental Example 6.
- Experimental Examples 1 and 6 were evaluated as “poor”, Experimental Examples 2-4 were evaluated as “good”, and Experimental Examples 5 and 7 were evaluated as "particularly good”.
- Experimental Examples 1 and 6 correspond to comparative examples, and Experimental Examples 2 to 5 and 7 correspond to examples of the present invention.
- the present invention can be used, for example, in semiconductor manufacturing equipment.
- Wafer mounting table 20 Ceramic base material, 22 Central part, 22a Wafer mounting surface, 24 Peripheral part, 24a Focus ring mounting surface, 26 Wafer adsorption electrode, 27 Hole, 30 Cooling base material, 32 Coolant channel, 32a corner, 34 flange, 40 metal bonding layer, 42 insulating film, 52 DC power supply for wafer adsorption, 53 low-pass filter, 54 power supply terminal, 55 insulation tube, 62 RF power supply, 63 high-pass filter, 64 power supply terminal, 70 clamp Member 70a Inner peripheral step surface 72 Bolt 78 Focus ring 94 Chamber 96 Installation plate 98 Shower head 110 Joined body 120 Ceramic sintered body 130 Block 131, 136 Disk member 132 Groove 134 , 138 through holes, 135 metal bonding layers.
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Abstract
Description
上面にウエハ載置面を有し、電極を内蔵するセラミック基材と、
内部に冷媒流路が形成された金属セラミック複合材料製の冷却基材と、
前記セラミック基材の下面と前記冷却基材の上面とを接合する金属接合層と、
を備えたウエハ載置台であって、
前記冷却基材のうち前記冷媒流路よりも下側の厚みが、13mm以上であるか又は前記冷却基材の全体の厚みの43%以上
のものである。
上面にウエハ載置面を有し、電極を内蔵するセラミック基材と、
内部に冷媒流路が形成された金属セラミック複合材料製の冷却基材と、
前記セラミック基材の下面と前記冷却基材の上面とを接合する金属接合層と、
を備えたウエハ載置台であって、
前記冷却基材のうち前記冷媒流路よりも上側の厚みが、5mm以下
のものである。
実験例1~5として、上述したウエハ載置台10の寸法の異なるものでFEM(有限要素法)による解析を行った。実験例1~5において、以下の点は共通とした。セラミック基材20は、アルミナ基材とし、中央部22の直径を296[mm]、全体の外径Aを335.8[mm]、全体の厚みを4.6[mm]とした。冷却基材30は、SiSiCTi製とし、全体の厚みBを30.12[mm]、冷却基材30の上面からフランジ部34の上面までの距離を7.6[mm]とした。冷媒流路32の断面は、縦(高さ)を12.12[mm]、横(幅)を8[mm]、上側の角部32aの曲率半径を1[mm]とした。金属接合層40は、Al含有接合材を用い、厚さを0.12[mm]とした。
実験例6は、冷却基材30の金属セラミック複合材料としてSiSiCTiの代わりにAlSiCを使用したこと以外は実験例1と同じとし、実験例7は、冷却基材30の金属セラミック複合材料としてSiSiCTiの代わりにAlSiCを使用したこと以外は実験例5と同じとした。実験例6,7についても、実験例1~5と同様にして、最大応力を求めて評価を行うと共に、セラミック基材20のウエハ載置面温度と、冷却基材30の上面温度と、冷却基材30のうち冷媒流路32の上側部分の上下温度差を求めた。その結果を表1に示す。実験例7の最大応力は、実験例6に比べて顕著に小さかった。
Claims (9)
- 上面にウエハ載置面を有し、電極を内蔵するセラミック基材と、
内部に冷媒流路が形成された金属セラミック複合材料製の冷却基材と、
前記セラミック基材の下面と前記冷却基材の上面とを接合する金属接合層と、
を備えたウエハ載置台であって、
前記冷却基材のうち前記冷媒流路よりも下側の厚みが、13mm以上であるか又は前記冷却基材の全体の厚みの43%以上である、
ウエハ載置台。 - 前記冷却基材のうち前記冷媒流路よりも下側の厚みが、15mm以上であるか又は前記冷却基材の全体の厚みの49%以上である、
請求項1に記載のウエハ載置台。 - 前記冷却基材のうち前記冷媒流路よりも上側の厚みが、5mm以下である、
請求項1又は2に記載のウエハ載置台。 - 上面にウエハ載置面を有し、電極を内蔵するセラミック基材と、
内部に冷媒流路が形成された金属セラミック複合材料製の冷却基材と、
前記セラミック基材の下面と前記冷却基材の上面とを接合する金属接合層と、
を備えたウエハ載置台であって、
前記冷却基材のうち前記冷媒流路よりも上側の厚みが、5mm以下である、
ウエハ載置台。 - 前記冷却基材のうち前記冷媒流路よりも上側の厚みが、3mm以下である、
請求項3に記載のウエハ載置台。 - 前記冷却基材は、下面側に前記ウエハ載置台をクランプするのに用いられるフランジ部を有し、前記フランジ部の幅が3mm以上か又は前記フランジ部の外径が前記セラミック基材の外径の101.8%以上である、
請求項1又は2に記載のウエハ載置台。 - 前記フランジ部の幅が10mm以上か又は前記フランジ部の外径が前記セラミック基材の外径の106%以上である、
請求項6に記載のウエハ載置台。 - 前記冷媒流路の断面のうち上側の角部は、R面になっている、
請求項1又は2に記載のウエハ載置台。 - 前記金属セラミック複合材料は、前記セラミック基材を構成するセラミック材料との40~570℃の線熱膨張係数差の絶対値が1×10-6/K以下である、
請求項1又は2に記載のウエハ載置台。
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KR1020237006822A KR20230042114A (ko) | 2021-09-09 | 2022-06-23 | 웨이퍼 배치대 |
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JP2016096336A (ja) * | 2014-11-07 | 2016-05-26 | Toto株式会社 | 静電チャックおよびウェーハ処理装置 |
JP2017126641A (ja) * | 2016-01-13 | 2017-07-20 | 日本特殊陶業株式会社 | 保持装置 |
JP2017126640A (ja) * | 2016-01-13 | 2017-07-20 | 日本特殊陶業株式会社 | 保持装置 |
JP2017174853A (ja) * | 2016-03-18 | 2017-09-28 | 日本特殊陶業株式会社 | 保持装置の製造方法 |
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JPH04287344A (ja) | 1991-03-15 | 1992-10-12 | Kyocera Corp | 静電チャックの接合構造 |
JP6182082B2 (ja) | 2013-03-15 | 2017-08-16 | 日本碍子株式会社 | 緻密質複合材料、その製法及び半導体製造装置用部材 |
JP6182084B2 (ja) | 2013-03-25 | 2017-08-16 | 日本碍子株式会社 | 緻密質複合材料、その製法、接合体及び半導体製造装置用部材 |
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JP2016096336A (ja) * | 2014-11-07 | 2016-05-26 | Toto株式会社 | 静電チャックおよびウェーハ処理装置 |
JP2017126641A (ja) * | 2016-01-13 | 2017-07-20 | 日本特殊陶業株式会社 | 保持装置 |
JP2017126640A (ja) * | 2016-01-13 | 2017-07-20 | 日本特殊陶業株式会社 | 保持装置 |
JP2017174853A (ja) * | 2016-03-18 | 2017-09-28 | 日本特殊陶業株式会社 | 保持装置の製造方法 |
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TWI829212B (zh) | 2024-01-11 |
KR20230042114A (ko) | 2023-03-27 |
US20230197500A1 (en) | 2023-06-22 |
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