Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
  • A01M1/00—Stationary means for catching or killing insects
  • A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
  • A01M1/00—Stationary means for catching or killing insects
  • A01M1/20—Poisoning, narcotising, or burning insects
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
  • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
  • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
  • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
  • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
  • A01N25/06—Aerosols
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
  • A01N65/40—Liliopsida [monocotyledons]
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
  • A01P7/00—Arthropodicides
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
  • A01P7/00—Arthropodicides
  • A01P7/04—Insecticides

Definitions

• the present invention relates to a pest control composition containing natural pyrethrins and a method for controlling pests using the same.
• Ectobiidae consisting of the German cockroach (Blattella germanica); a group of the family Blattidae consisting of Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, and Blatta orientalis; Reticulitermes speratus, Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kanmonensis, A group of Termitidae, consisting of Nasutitermes takasagoens,
• arthropod pests are at least one arthropod pest of Diptera selected from the following group.
• a group of the Drosophilidae family consisting of Drosophila suzukii and Drosophila melanogaster
• a group of the Phoridae family consisting of Megaselia spiracularis
• a group of the Psychodidae family consisting of Clogmia albipunctata
• a group of the Sciaridae family consisting of Bradysia difformis
• a group of Cecidomyiidae consisting of Mayetiola destructor and Orseolia oryzae
• a group of the family Diopsidae consisting of Diopsis macrophthalma
• Glossinidae consisting of Glossina palpalis and Glossina morsitans
• Simuliidae group consisting of
• Arthropod pests include the German cockroach (Blattella germanica), the American cockroach (Periplaneta americana), the common termite (Coptotermes formosanus), the fire ant (Solenopsis invicta), the house ant (Monomorium pharaonis), the Occidentalis ant (Pogonomyrmex occidentalis), and the Culex aegypti (Culex). quinquefasciatus), Culex pipiens pipiens, Aedes aegypti, Anopheles gambiae, and Musca domestica. 11. The method for controlling harmful arthropods according to any one of 10. 19.
• Ectobiidae consisting of the German cockroach (Blattella germanica); a group of the family Blattidae consisting of Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, and Blatta orientalis; Reticulitermes speratus, Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kanmonensis, A group of Termitidae, consisting of Nasutitermes takasagoens,
• Paraponera clavata Indian ant (Ochetellus glaber), Common ant (Monomorium pharaonis), Argentinean ant (Linepithema humile), Black Japanese ant (Formica japonica), Mystic ant (Pristomyrmex punctutus), Giant ant (Pheidole noda), Black ant (Pheidole megacephala), Carpenter ant ( Camponotus japonicus), Camponotus spp. consisting of Camponotus obscuripes, Pogonomyrmex spp.
• arthropod pests are at least one arthropod pest of the order Cockroaches selected from the following group.
• the group Ectobiidae consisting of the German cockroach (Blattella germanica); a group of the family Blattidae consisting of Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, and Blatta orientalis;
• Reticulitermes speratus Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianu
• arthropod pests are at least one arthropod pest of the order Cockroaches selected from the following group.
• a group of the family Blattidae consisting of Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, and Blatta orientalis;
• Reticulitermes speratus Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kan
• arthropod pests are at least one arthropod pest of Hymenoptera selected from the following group.
• Solenopsis spp. consisting of fire ants (Solenopsis invicta), Solenopsis geminata, Atta spp. consisting of brown leaf cutting ants (Atta capiguara), Acromyrmex spp.
• Paraponera clavata Indian ant (Ochetellus glaber), Common ant (Monomorium pharaonis), Argentinean ant (Linepithema humile), Black Japanese ant (Formica japonica), Mystic ant (Pristomyrmex punctutus), Giant ant (Pheidole noda), Black ant (Pheidole megacephala), Carpenter ant ( Camponotus japonicus), Camponotus spp. consisting of Camponotus obscuripes, Pogonomyrmex spp.
• arthropod pests are at least one arthropod pest of Diptera selected from the following group.
• a group of the Drosophilidae family consisting of Drosophila suzukii and Drosophila melanogaster
• a group of the Phoridae family consisting of Megaselia spiracularis
• a group of the Psychodidae family consisting of Clogmia albipunctata
• a group of the Sciaridae family consisting of Bradysia difformis
• a group of Cecidomyiidae consisting of Mayetiola destructor and Orseolia oryzae
• a group of the family Diopsidae consisting of Diopsis macrophthalma
• Glossinidae consisting of Glossina palpalis and Glossina morsitans
• Simuliidae group consist
• Arthropod pests include the German cockroach (Blattella germanica), the American cockroach (Periplaneta americana), the common termite (Coptotermes formosanus), the fire ant (Solenopsis invicta), the house ant (Monomorium pharaonis), the Occidentalis ant (Pogonomyrmex occidentalis), and the Culex aegypti (Culex). quinquefasciatus), Culex pipiens pipiens, Aedes aegypti, Anopheles gambiae, and Musca domestica. 67. The method for controlling harmful arthropods according to any one of 67. 76.
• the arthropod pest has reduced sensitivity to at least one insecticide selected from the group consisting of a GABAergic chloride ion channel blocker, a sodium channel modulator, and a nicotinic acetylcholine receptor competitive modulator.
• a GABAergic chloride ion channel blocker a GABAergic chloride ion channel blocker
• a sodium channel modulator a sodium channel modulator
• a nicotinic acetylcholine receptor competitive modulator 98.
• 99. The method for controlling harmful arthropods according to any one of the preceding items 82 to 99, wherein the composition for controlling harmful arthropods further contains a dill extract.
• the aerosol agent according to any one of the preceding items 83-86 and 89-100.
• the pump spray agent according to any one of the preceding items 87-
• a composition for controlling harmful arthropods containing natural pyrethrin and azadirachtin as active ingredients 2 A method for controlling arthropod pests, which comprises treating a site where arthropod pests occur so that the amount of each active ingredient is 0.01 to 1000 mg. 104.1m 2 103.
• the method for controlling harmful arthropods according to the preceding item 103 or 104, wherein the place where the harmful arthropods are generated is at least one selected from the group consisting of buildings, outdoors, food, and daily necessities. 106. 106.
• arthropod pests are at least one arthropod pest of the order Cockroaches selected from the following group.
• a group of the family Blattidae consisting of Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, and Blatta orientalis;
• Reticulitermes speratus Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kan
• arthropod pests are at least one arthropod pest of Diptera selected from the following group. a group of the Drosophilidae family consisting of Drosophila suzukii and Drosophila melanogaster; a group of the Phoridae family consisting of Megaselia spiracularis; a group of the Psychodidae family consisting of Clogmia albipunctata; a group of the Sciaridae family consisting of Bradysia difformis; a group of Cecidomyiidae consisting of Mayetiola destructor and Orseolia oryzae; a group of the family Diopsidae consisting of Diopsis macrophthalma; a group of Glossinidae, consisting of Glossina palpalis and Glossina morsitans; Simul
• Arthropod pests include the German cockroach (Blattella germanica), the American cockroach (Periplaneta americana), the common termite (Coptotermes formosanus), the fire ant (Solenopsis invicta), the house ant (Monomorium pharaonis), the Occidentalis ant (Pogonomyrmex occidentalis), and the Culex aegypti (Culex). quinquefasciatus), Culex pipiens pipiens, Aedes aegypti, Anopheles gambiae, and Musca domestica.
• the method for controlling harmful arthropods according to any one of 106. 115.
• the pests are arthropod pests, mollusc pests, and nematodes pests with reduced susceptibility to at least one insecticide, acaricide, molluscicide, and nematicide.
• a pest control composition containing natural pyrethrins and machine oil as active ingredients, it is possible to control insects of the order Hemiptera, Lepidoptera, Thysanoptera, Diptera, and Coleoptera.
• the pest is arthropod pest, mollusc pest, and nematode pest with reduced susceptibility to at least one insecticide, acaricide, molluscicide, and nematicide. Control method.
• pyrethrin I synerin I
• jasmolin I pyrethrin II
• synerin II jasmolin II
• weight ratios are as follows.
• Natural pyrethrins are selected from the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i), It can be mixed or used together with one or more components selected from the group consisting of group (j) and group (k) (hereinafter referred to as this component).
• the mixed use or combined use means using the present compound and the present component at the same time, separately or with a time interval.
• the present compound and the present ingredient may be contained in separate formulations, respectively, or may be contained in one formulation.
• Group (g) is a group of molluscicidal components.
• Group (k) is a group of plant extracts and plant-derived ingredients.
• anthraquinone + natural pyrethrins chloralose + natural pyrethrins, acrep + natural pyrethrins, butopyronoxyl + natural pyrethrins, carboxide + natural pyrethrins, dibutyl phthalate + natural Pyrethrins, deet + natural pyrethrins, dimethyl carbate + natural pyrethrins, dimethyl phthalate + natural pyrethrins, dibutyl succinate + natural pyrethrins, dibutyl adipate + natural pyrethrins, ethohexadiol + natural pyrethrins, hexamide + natural pyrethrins, icaridin + natural pyrethrins, methoquin-butyl + natural pyrethrins, methylneodecanamide
• strain EG7841 p. Kurstaki strain EG7841 + natural pyrethrin, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + natural pyrethrin, Bacillus thuringiensis christaki subsp. Kurstaki strain F810) + natural pyrethrin, Bacillus thuringiensis subspecies HD-1 strain (Bacillus thuringiensis subsp. Kurstaki strain HD-1) + natural pyrethrin, Bacillus thuringiensis christaki subspecies PB54 strain (Bacillus thuringiensis Kurstaki strain PB54) + natural pyrethrin, Bacillus thuringiensis subsp.
• darmstadiensis strain 24-91 + natural pyrethrins, Bacillus thuringiensis subsp. var. dendrolimus + natural pyrethrins, Bacillus thuringiensis subsp. var. galleriae) + natural pyrethrin, Bacillus thuringiensis israelensis subsp. BMP144 strain (Bacillus thuringiensis subsp. israelensis strain BMP144) + natural pyrethrin, Bacillus thuringiensis israelensis subsp. israelensis strain AM65-52) + natural pyrethrin, Bacillus thuringiensis subsp. var.
• No.B-30145 strain Streptomyces sp. strain NRRL No.B-30145
• natural pyrethrin Streptomyces sp. WYE20 strain
• natural pyrethrin Streptomyces sp. WYE 324 strain
• native pyrethrins Streptomyces venezuelae + native pyrethrins, Subulura spp.
• Trichoderma album rma album Natural pyrethrins, Trichoderma album rma album) + natural pyrethrins, Trichoderma asperelloides strain JM41R + natural pyrethrins, Trichoderma asperellum strain ICC012 + natural pyrethrins, Trichoderma asperellum T25 strain + natural pyrethrins , Trichoderma asperellum strain T34 + natural pyrethrins, Trichoderma asperellum strain SKT-1 + natural pyrethrins, Trichoderma asperellum strain TV1 + natural pyrethrins, Trichoderma atroviride strain CNCM 1-1237 + natural pyrethrin, Trichoderma atroviride strain LC52 + natural pyrethrin, Trichoderma atroviride strain IMI 206040 + Natural pyrethrins, Trichoderma atroviride strain SC1 + natural pyrethrins, Tri
• Components selected from group (j) are usually prepared by culture methods known in the art.
• the ingredients selected from group (j) are bacteria or fungi, they are prepared using media and fermentation methods known in the art.
• the preparation contains 1 ⁇ 10 4 to 1 ⁇ 10 13 CFU (colony forming units) per gram, preferably 1 ⁇ 10 8 to 1 ⁇ 10 12 CFU of the ingredient.
• the preparation should contain 1 ⁇ 10 4 to 1 ⁇ 10 13 occluded bodies (sometimes referred to as Obs), preferably 1 ⁇ 10 8 to 1 ⁇ , per gram. Contains this component of 10 12 occlusal bodies (sometimes referred to as Obs).
• the preparation contains 1 ⁇ 10 4 to 1 ⁇ 10 13 , preferably 1 ⁇ 10 8 to 1 ⁇ 10 12 individuals per gram of the component.
• Weight ratio [(natural pyrethrin):(this component)] 1:10 ⁇ 15 to 10 ⁇ 15:1, specifically, for example, about 1:10 ⁇ 15, 1:10 ⁇ 14, 1:10 ⁇ 13, 1:10 ⁇ 12, 1:10 ⁇ 11, 1:10 ⁇ 10, 1:10 ⁇ 9, 1:10 ⁇ 8, 1:10 ⁇ 7, 1:10 ⁇ 6, 1:10 ⁇ 5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1:900, 1:800, 1: 700, 1:600, 1:500, 1:400, 1:350, 1:300, 1:250, 1:200, 1:150, 1:100, 1:90, 1:80, 1:70, 1:60, 1:50, 1:40, 1:30, 1:20, 1:19, 1:18, 1:17, 1:16, 1:15, 1:14, 1:13, 1: 12, 1:11, 1:10, 1:9, 1:8, 1:7, 1:6, 1:5, 2:9, 1:4, 2:7, 3:
• composition B is, for example, a spray agent (aerosol agent (direct spray type, space spray type, metered spray type, one-push type, total amount spray type, intermittent spray type, etc.), pump spray agent, electric spray agent ( Ultrasonic vibration type, electrostatic spray type, etc.)), poison bait (liquid, paste, solid, etc.), burning agent (incense stick, paper, resin, etc.), heating transpiration agent (electric mosquito mat, liquid mosquito repellent) preparations, etc.), ventilation type transpiration agents (fan type, fan installation type, air conditioner installation type, ventilation fan installation type, etc.), fumigants (self-combustion fumigants, chemical reaction fumigants, porous ceramic plate fumigants etc.), fumigants, fume agents, ULV agents, mist agents, foaming agents, paste formulations, paints, wood protection paints, sealants, carbon dioxide formulations, sheet formulations, tape formulations, paper formulations, non-woven fabric formulations, animal formulations (shampoos, lotions, spot-
• amphoteric surfactants include betaine, alkylbetaine, alkyldimethylbetaine, imidazoline, taurine, alkyltaurine, dodecyldimethylammonioacetate, 4-carboxy-N,N,N-trimethyl-1-butanaminium, 1-carboxy-N,N,N-2-tetramethyl-1-propanaminium, N-alkyl (or alkenyl) (C12-18) glycine and its salts, N-dodecylglycine and its salts, and derivatives thereof is mentioned.
• Acids such as acetic acid, propionic acid, malonic acid, succinic acid, glutaric acid, adipic acid, azelaic acid, sorbic acid, benzoic acid, and phosphoric acid and salts thereof;
• Binders polysaccharides (xanthan gum, cellulose ester, cellulose ether, Carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay), minerals (bentonite), synthetic polymers (polycarboxylic acid or its salt, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salt), wax (vegetable fat, animal fat, and derivatives thereof, paraffin, olefin, etc.); Adhesive/spreading agent: surfactants and liquid carriers
• a coloring agent can be added to make it easier to identify the granules and fine granules during and after application.
• a coloring agent can be added to facilitate confirmation of application.
• Specific product forms include futon covers, pillowcases, protective covers, product packages, curtains, mattresses, sofa members, animal collars , animal ear tags, clothing, protective caps, arm/leg covers, lanyards, gardening posts, crop protection films, agricultural mulch, greenhouse films, screen doors, mosquito nets, garbage bags, garbage storage nets, drain nets, disposal It can be used in the form of material members, trash cans, drainage members, cushioning materials, foam materials, heat insulating materials, various tubes, exhaust pipes, packing, and the like.
• the composition B can be kneaded into the resin during molding, and can also be obtained by subjecting the composition B to post-treatment (coating, impregnation, etc.) after the resin has been molded.
• Examples of the base material of the poison bait include cereal flour, vegetable oil, sugar, crystalline cellulose and the like, and if necessary, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, and preservatives such as dehydroacetic acid.
• Ingredients such as red pepper powder, anti-ingestion agents for children and pets, and attractive fragrances are added.
• a plant cultivation carrier is a support for plants, and may be any material that allows plants to grow, for example, soil, seedling mats, and water.
• Specific materials for soil and seedling mats include, for example, sand, pumice, vermiculite, diatomaceous earth, gel substances, polymeric substances, rock wool, glass wool, wood chips and bark.
• the interior of the building for example, space, entrance, corridor, toilet, washroom, bath, dressing room, veranda, balcony, roof, attic, floor, ceiling, ceiling, wall, stairs, door, chimney, garage , Warehouse, Window, Screen, Sash, Shutter, Veranda, Balcony, Attic Storage, Underfloor Storage, Food Storage, Library, Floor Heating, fireplace, Pillar, Wall, Wallpaper, Closet, Closet, Vase, Living Room, Bedroom, and dining room.
• Examples of living organisms include large animals (bovine, horse, pig, sheep, goat, boar, bear, panda, monkey, elephant, giraffe, zebra, lion, tiger, leopard, cheetah, bison, hyena, wolf, raccoon dog, foxes, etc.), chickens, etc.), small animals (dogs, cats, rats, mice, guinea pigs, hedgehogs, etc.), birds (chickens, quails, pigeons, sparrows, geese, ducks, ducks, peacocks, swans, flamingos, parrots, parakeets , eagles, hawks, kites, etc.) and other creatures (snakes, frogs, lizards, crocodiles, newts, geckos).
• composition B When composition B is used for controlling arthropod pests in non-agricultural fields, the amount of one active ingredient per 1 m2 of treated area is usually 0.01 to 1000 mg, preferably 0.01 to 1000 mg. is 10 to 500 mg, more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg , 400 mg). and usually 0.01 to 500 mg.
• the amount of one active ingredient per liter of water volume is usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg.
• Application rates for treatment on the animal body are generally in the range of 0.01 to 1000 mg of one active ingredient per kg of animal body weight.
• composition B By applying composition B to the body surface of humans and animals, it can be used for the purpose of suppressing the biting behavior and unpleasant behavior of harmful arthropods such as mosquitoes and flies. In addition, it can be used for the purpose of suppressing the emergence and growth of flies and the like generated in excrement by mixing it with feed and giving it orally to animal bodies.
• treatment methods for composition B include foliage treatment, soil treatment, root treatment, shower treatment, smoke treatment, water surface treatment, hydroponic solution treatment, and seed treatment.
• the foliage treatment includes, for example, a method of treating the surface of foliage, tree trunk, fruit, flower or panicle with Composition B.
• Examples of the root treatment include a method of immersing the roots in a chemical solution containing the composition B and a method of attaching a solid preparation containing the composition B to the roots of the plant.
• Soil treatments include, for example, soil spraying, soil admixture, and chemical irrigation of the soil.
• Places for soil treatment include, for example, planting holes, rows, near planting holes, near rows, the entire surface of the cultivation area, the plant edge, between plants, under the tree trunk, main ridge, culture soil, nursery box, and nursery seedlings. Examples include trays, seedbeds, and the like.
• the treatment time includes, for example, before sowing, at sowing, after sowing, raising seedlings, before planting, at planting, and growing season after planting.
• the composition B may be applied to the plants at the same time, or a solid fertilizer such as a paste fertilizer containing the composition B may be applied to the soil.
• it may be mixed with the irrigation liquid, for example, injection into irrigation equipment (irrigation tube, irrigation pipe, sprinkler, etc.), mixing with inter-row flooding liquid, mixing with hydroponic liquid, and the like.
• the irrigation solution and the active ingredient can be mixed in advance, and treated by using the above-mentioned irrigation method or other appropriate irrigation methods such as sprinkling and flooding.
• Plants endowed with abiotic stress tolerance are exposed to drought, high salinity, high light intensity, high UV irradiation, chemical pollution (e.g. high heavy metal concentrations), low or high temperature, limited nutrients (i.e. nitrogen, phosphorus). plants exhibiting increased tolerance to abiotic stress conditions such as unbalanced feeding and population stress (see for example WO 2000/004173, WO2007/131699, CA2521729 and US2008/0229448).
• the plants are fruits (e.g. tomatoes, vines, melons, papaya, bananas, peppers, raspberries and strawberries); stone fruits (e.g. cherries, apricots and peaches); pear); and citrus fruits (e.g. citron, lime, orange, pomelo, grapefruit and mandarin), more preferably selected from tomatoes, melons, papaya, vines, apples, bananas, oranges and strawberries, Most preferred are tomato, melon and papaya.
• fruits e.g. tomatoes, vines, melons, papaya, bananas, peppers, raspberries and strawberries
• stone fruits e.g. cherries, apricots and peaches
• pear e.g. citron, lime, orange, pomelo, grapefruit and mandarin
• Plants whose traits related to plant growth and yield have been modified include, for example, plants with enhanced growth ability. Plants whose traits related to growth and yield have been modified by genetic recombination technology, for example, by introducing a gene (bbx32) that encodes a transcription factor derived from Arabidopsis thaliana that regulates diurnal characteristics, plant growth is enhanced, resulting in soybean, which is expected to have high yield as a soybean; Arabidopsis thaliana-derived homeodomain-leucine 14 zipper (HD-Zip) family Class II (HD-Zip II) transcription factor gene (athb17) increased ear weight, As a result, corn with high yield potential has been developed.
• a gene bbx32
• a gene that encodes a transcription factor derived from Arabidopsis thaliana that regulates diurnal characteristics
• the low polyphenol oxidase (enzyme that causes browning) production gene sequence GEN-03 isolated from apples is introduced into a new apple cultivar.
• Arctic registered trademark
• Tomato base with salt tolerance is an example of imparting the properties of GM rootstock, which is a breed improvement technology using grafting, to scions. Examples include tomatoes obtained by imparting salt tolerance to non-transgenic scion tomatoes using trees (see Physiol Plantarum, 124, 465-475, 2005).
• High temperature ripening resistance genes dul3, qAC9.3, rsr1, Wx and Wx1-1, etc. hypoamylose genes; AP01, SCM2, Sd1, etc. lodging resistance genes; Gene; Cold tolerance genes such as CTB1, CTB2, qLTG3-1; Drought tolerance genes such as Dro1; DEP1, Cn1a, GPS, SPIKE, PTB1, TAWAWA1, WFP, IPA1, GS3, GS5, GS6, GL3.1, GW2, GW8, qGL3, qSS7, qSW5 and other genes related to the number of rice or seed shape; Hd1, Ghd8, DTH8 and other genes regulating day length responsiveness; FLO4, PDIL1, etc. lipoxygenase-deficient genes such as LOX3 (reducing the smell of old rice); and genes related to amylopectin chain length such as Alk. Rice cultivars into which one or more of these genes are integrated simultaneously have been developed or marketed.
• Composition B can effectively control a wide range of targets in cereal fields, vegetable fields, flower fields, orchards or non-agricultural lands where normal or no-tillage cultivation is performed.
• a sugarcane stalk fragment cut to have one node may be used. 15 cm, preferably 3 to 8 cm may be used.
• Techniques for cultivating sugarcane using such stem fragments are known (WO09/000398, WO09/000399, WO09/000400, WO09/000401, WO09/000402) and are practiced under the trade name Plene (registered trademark). be.
• the time of application is not particularly limited as long as it is during the seedling raising period from rice seeding to transplantation.
• the composition B may be applied to the nursery box at the time of sowing, not only on the day of sowing, but also several days before or several days after sowing.
• the timing of applying composition B to the nursery box at the time of transplantation may be not only the day of transplantation, but also any day from several days before transplantation to the day of transplantation.
• the seedlings to be transplanted are young seedlings (seedlings around the 2.5 leaf stage), medium seedlings (seedlings around the 3.5 leaf stage), or mature seedlings (seedlings around the 4.5 leaf stage).
• composition B When the composition B is applied to paddy fields, it may be used for transplanted rice or direct-seeded rice.
• the method of application to paddy fields is not particularly limited, but examples include a method of applying Composition B to the stems and leaves of rice, a method of applying to paddy soil, and a method of applying to the water surface of flooded paddy fields. be done.
• a chemical solution such as an emulsion or a flowable solution to a source of water flowing into a paddy field, such as a water outlet or an irrigation system, it can be applied in a labor-saving manner along with the supply of water.
• the application to the stems and leaves of rice may be carried out at any time from the nursery stage to harvest.
• a mixture of calcium peroxide, gypsum of Paris, and mineral powder is available as a commercial product, for example, Kalper powder granules 16 (manufactured by Hodogaya UPL Co., Ltd.).
• rice seeds refer to rice seeds before being sown in soil such as paddy fields.
• the rice seeds When rice seeds are treated with composition B, the rice seeds can be directly sown in dry fields, wet fields, and paddy fields for cultivation, and can also be sown and cultivated in nursery boxes.
• Examples of the above-mentioned paddy fields include paddy fields that are in a flooded or soaked state.
• a flooded paddy field means a paddy field that has been plowed, filled with water, puddled, etc., and then filled with water as necessary.
• a paddy field in a submerged state refers to a paddy field in which the water content is maintained at the same level as in the submerged state and the surface of the soil is exposed by performing drainage treatment or the like from the submerged state.
• composition B can be applied to the rice seeds, or the rice seeds before sprouting can be immersed in a solution containing the composition B, or the sprouted rice seeds can be soaked in a solution containing the composition B. can also be sprayed.
• composition B may also contain one or more phytotoxicity-reducing ingredients selected from group (d).
• composition B When the composition B is applied to rice seeds, it may be mixed with calcined gypsum.
• gypsum of Paris may be used as an adjuvant.
• Such calcined gypsum may be powdery calcium sulfate 1/2 hydrate (CaSO 4 .1/2H 2 O), and such calcined gypsum is commercially available. (manufactured by Yoshino Gypsum Sales Co., Ltd.) and KTS-25 (manufactured by Yoshino Gypsum Sales Co., Ltd.).
• a mixture of the coating material A and plaster of Paris may also be used, and such a mixture is available as a commercial product, for example, DAE1K mix (manufactured by DOWA IP Creation Co., Ltd.).
• Rice seed dressing treatment using the coating material A can take various forms, but usually a known method as a rice seed dressing treatment method using iron powder ("Iron Coating Flooded Direct Sowing Manual 2010", Independent Administrative agency National Agriculture and Food Research Organization, March 2010, ISBN978-4-903078-05-2) is performed by the same operation. Specifically, dry rice seeds before germination are immersed in water (sometimes referred to as seed soaking), and after draining, the rice seeds are coated with coating material A and, if necessary, calcined gypsum. do. As for the order of treatment of the coating material A and the gypsum of Paris, either one may be treated first, or a mixture of the coating material A and the gypsum of Paris may be treated at the same time. After these treatments, if necessary, it is further coated with calcined gypsum as a finishing touch, and then it is usually placed on a flat mat or the like and dried in the shade.
• the amount of coating material A used for rice seeds is usually 100 to 2000 g of coating material A per 1000 g of dry weight of rice seeds.
• the amount of calcined gypsum in the case of further coating with calcined gypsum is usually 5 to 100 g with respect to 1000 g of the dry weight of rice seeds, and the amount of calcined gypsum in the case of further coating with calcined gypsum as a finish.
• the amount is usually 0-50 g per 1000 g dry weight of rice seeds.
• Molybdenum and molybdenum compounds include, for example, molybdenum simple substance, molybdenum oxide, molybdic acid and its salts, molybdophosphoric acid and its salts, and molybdosilicic acid and its salts.
• Salts of molybdate include, for example, calcium molybdate, magnesium molybdate, ammonium molybdate, sodium molybdate, and potassium molybdate.
• Molybdophosphates include ammonium molybdophosphate, sodium molybdophosphate, and potassium molybdophosphate.
• Such molybdenum and molybdenum compounds are commercially available, and examples thereof include molybdenum trioxide (Nippon Inorganic Chemical Industry Co., Ltd.).
• the treatment of rice seeds using molybdenum and molybdenum compounds can take various forms, but it is usually carried out by the same operation as a known method for treating rice seeds using molybdenum and molybdenum compounds (WO2011/093341). . Specifically, it is adhered to the rice seed surface using an adhesive such as polyvinyl alcohol, prepared into a solution and immersed in the rice seed, or mixed with a coating material containing iron powder and/or calcium peroxide. For example, the rice seeds are coated with powder.
• an adhesive such as polyvinyl alcohol
• molybdenum compounds such as molybdenum trioxide, iron oxide powder (sometimes called red iron oxide powder), and water-resistant polyvinyl alcohol are mixed to coat rice seeds, known as ⁇ bengara molybdenum coating'' (Yoshitaka Hara 2013. Improvement of Rice Seedling Establishment on Sulfate-Applied Submerged Soil by Seed Coating with Poorly Soluble Molybdenum Compounds. Plant Prod. Sci.
• composition A includes, in particular, isotianil, furametpyr, impilfluxam, ethaboxam, benomyl, oxolinic acid, clothianidin, fenitrothion, cartap hydrochloride, oxazosulfil, tetraniliprole, chloro Lantraniliprole, cyantraniliprole, triflumezopyrim, flupyrimine and ethiprole are preferred.
• weeds growing in paddy fields can be controlled by treatment with one or more herbicidal components selected from groups (i) and (j).
• the timing of application of the component having herbicidal activity is not particularly limited as long as the herbicidal component does not pose a problem of phytotoxicity to rice plants.
• herbicidally active ingredients selected from group (i) that can be used in paddy fields include azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flucetosulfuron, and halosulfuron-methyl.
• Composition A containing one or more herbicidally active ingredients selected from groups (i) and (j) and one or more plant growth regulating ingredients selected from group (c) is composed of It may be contained in one formulation, may be multiple formulations consisting of a formulation containing one active ingredient and a formulation containing multiple active ingredients, or all active ingredients may be in separate formulations. good too. When multiple formulations are applied, the formulations may be applied to the arthropod pest, arthropod habitat, plant or soil at the same time or at different times. For example, before and after planting seeds or plant reproductive organs treated with one or more plant growth regulating components selected from group (c) into soil, a component having herbicidal activity selected from groups (i) and (j) is applied.
• the timing of treatment of the ingredients with herbicidal activity is preferably between immediately after sowing or planting and up to 50 days after sowing or planting, more preferably between immediately after sowing or planting and up to 3 days after sowing or planting.
• the timing of treatment with the component having herbicidal activity is, for example, from before emergence to the 12-leaf stage. , preferably from pre-emergence to 8-leaf stage, more preferably from pre-emergence to 6-leaf stage.
• the leaf age of maize is determined by the Leaf Collar Method.
• the period of treatment with the component having herbicidal activity is from 50 days before sowing to just before sowing. preferably from 30 days before sowing to just before sowing, more preferably from 20 days before sowing to just before sowing.
• the period of treatment with the component having herbicidal activity is from immediately after sowing to 70 days after sowing. preferably from 30 days after sowing to 50 days after sowing, for example, from before the emergence of cotton to the flowering period, preferably from the start of lignification at the base of the cotton stem until the lignification is 20 cm from the base.
• composition B improves the seedling rate of plants, improves the growth of plants, improved resistance to physical stress (for example, improved resistance or tolerance to high or low temperatures; improved resistance to drought, overhumidity, or salinity contained in water or soil; improved resistance to osmotic stress; resistance to drought stress improved resistance to ozone exposure, improved resistance to UV stress, improved resistance to wind stress, and improved resistance to solar stress), improved flowering capacity, improved ease of harvest, accelerated maturity, increased harvest Increased quantity, increased number of seeds or fruits, increased size or weight, improved leaf green color, increased number of healthy leaves, reduced plant lodging, earlier flowering, increased number of flowers or fruits set, seed set rate , improved quality and/or increased nutritional value of the harvested product (e.g.
• the application amount of the composition B is usually 5000 g or less, preferably 1000 g or less per 10a of the sowing area (cultivation area), and is included in the composition B.
• the total amount of the compound or composition A is usually 1000 g or less, preferably 500 g or less.
• the total amount of the present compound or composition A contained in composition B is usually 0.05 to 1000 g, preferably 0.5 to 200 g, per 1 m 2 of a place where rice seedlings are raised.
• Hemiptera Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, Peregrinus maidis, Javesella pellucida, Perkinsiella saccharicida, Tagosodes orizicolus, etc.
• Thysanoptera Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips , Echinothrips americanus, Scirtothrips perseae, etc.; Phlaeothripidae, such as Haplothrips aculeatus.
• Anthomyiidae such as Delia platura, Delia antiqua, and Pegomya cunicularia
• Ulidiidae such as Tetanops myopaeformis Agromyzidae, such as Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, and Chromatomyia horticola
• Chloropidae such as Chlorops oryzae
• Bactrocera cucurbitae Bactrocera dorsalis, Bactrocera latifrons, Bactrocera oleae, Bactrocera tryoni, Ceratitis capitata, Rhagoletis pomonella, Rjapachla fruit fly ), etc.
• Drosophilidae such as Drosophila melanogaster
• Phoridae such as Megaselia spiracularis
• Psychodidae such as Clogmia albipunctata
• Diabrotica spp. e.g. Western Corn Rootworm (Diabrotica virgifera virgifera), Southern Corn Rootworm (Diabrotica undecimpunctata howardi), Northern Corn Rootworm (Diabrotica barberi), Mexican Corn Rootworm (Diabrotica virgifera zeae)), banded cucumber beetle (Diabrotica balteata), cucumber beetle (Diabrotica speciosa) and other bean leaf beetles (Cerotoma trifurcata), neck beetle (Oulema melanopus), cucumber beetle (Aulacophora femoralis), broccoli beetle (Phyllotreta striolata), cabbage free beetle (Phyllotreta cruciferae), western black free beetle (Phyllotreta pusilla), cabbage stem free beetle (Psylliodes chrysocephala), hop free beetle (P
• Blattodea Ectobiidae, such as Blattella germanica; Blatta orientalis); Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticutermes miyatakei), Reticulitermes kanmonensis, Nasutitermes takasagoensis, Pericapritermes nitobei, Sinocapritermes mushae, and Cornitermes cumulans.
• Thysanura Lepismatidae, such as Ctenolepisma villosa and Lepisma saccharina.
• Gastropoda Limacidae, such as Limax marginatus and Limax flavus; Philomycidae, such as Meghimatium bilineatum; Pomacea canaliculata, etc. Lymnaeidae, such as Austropeplea ollula.
• Nematoda Aphelenchoididae such as Aphelenchoides besseyi; Pratylenchidae; Meloidogyne javanica, Meloidogyne incognita, guava root-knot nematodes (Meloidogyne enterolobii), Meloidogyne hapla, Heterodera glycines, potato cyst nematode ( Heteroderidae such as Globodera rostochiensis and Globodera pallida; Hoplolimidae such as Rotylenchus reniformis; Anguinidae); Tylenchulidae such as Tangerine nematode (Tylenchulus semipenetrans); Longidoridae such as Xiphinema index; Trichodoridae; Parasitaphelenchidae.
• Aphelenchoididae such as Aphelencho
• Group a1 Acetylcholinesterase inhibitors Group 1A carbamate and group 1B organophosphorus compounds of the action classification according to IRAC, such as alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxy butocarboxim, butoxycarbboxim, carbaryl (NAC), carbofuran, carbosulfan, ethiofencarb, fenobucarb (BPMC), formetanate, furatiocarb ( furathiocarb, isoprocarb (MIPC), methiocarb, methomyl, methoxychlor, metolcarb, oxamyl, pirimicarb, promecarb, propoxur (PHC) ), thiodicarb, thiofanox, triazamate, trimetacarb, xylylcarb; acephate, azamethiphos, azinphos-ethyl, azin
• acrinathrin allethrin, bifenthrin, kappa-bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin , cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, sigma-cypermethrin cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucitrinate ( flucythrinate, flumethrin, flu
• Group a4 Nicotinic acetylcholine receptor competitive modulators Group 4A neonicotinoids, 4B nicotine, 4C butenolides, 4D sulfoximines and 4E mesoionics of the action classification according to IRAC, e.g. acetamiprid, clothianidin, Dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, flupyradifurone, sulfoxaflor, cycloxaprid, triflumezopyrim, dichloromesothia The group consisting of dichloromezotiaz and flupyrimine.
• IRAC e.g. acetamiprid, clothianidin, Dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, flupyradifurone, sulfoxaflor, cycloxaprid, triflu
• Group a7 Juvenile Hormone Mimic Group 7A juvenile hormone analogues of action classification by IRAC, Group 7B phenoxycarb and 7C pyriproxyfen, such as hydroprene, kinoprene, methoprene, fenoxycarb ( fenoxycarb) and pyriproxyfen.
• Group a8 Chordotonal TRPV Channel Modulators
• Group 9 of the action classification according to IRAC the group consisting of pyridine azomethine derivatives, eg Pymetrozine and Pyrifluquinazon.
• Group a9 Group 11A Bacillus thuringiensis, Group 11B Bacillus sphaericus, for example, Bacillus sphaericus, Bacillus thuringiensis BD#32 strain (Bacillus thuringiensis strain BD#32), Bacillus thuringiensis strain AQ52, Bacillus thuringiensis subsp. aizawai strain ABTS-1857, Bacillus thuringiensis subsp.
• Bacillus thuringiensis subsp. kurstaki strain HD-1 Bacillus thuringiensis subsp. kurstaki strain BMP123, Bacillus thuringiensis subsp. kurstaki strain BMP123, Bacillus thuringiensis subsp. thuringiensis subsp. Tenebriosis strain NB176), Bacillus thuringiensis var. israelensis, Bacillus thuringiensis var. aegypti, Bacillus thuringiensis var. thuringiensis var. colmeri), Bacillus thuringiensis var. darmstadiensis, Bacillus thuringiensis var. dendrolimus, Bacillus thuringiensis var.
• Cry1Ab, Cry1Ac, Cry1F fused hybrid protein Cry2Ab2, Cry2Ae, Cry9C, Vip3A, Vip3Aa20
• delta-endotoxins that confer resistance to coleopteran insects e.g. Cry3A, mCry3A (modified Cry3A), Cry3Bb1 , Cry34Ab1, Cry35Ab1
• delta-endotoxins eg Cry1A, Cry4A, Cry4B, Cry11A with insecticidal activity against Cucurbitaceae.
• Group a10 oxidative phosphorylation uncouplers that disrupt the proton gradient
• Group 13 of the action classification according to IRAC eg, the group consisting of chlorfenapyr and sulfluramid.
• Group a11 Nicotinic Acetylcholine Receptor Channel Blocker Agents
• Group 14 nereistoxin analogues of action classification according to IRAC, e.g. bensultap, cartap, cartap hydrochloride, thiocyclam, thiosultap The group consisting of disodium salts (thiosultap-disodium) and thiosultap-monosodium salts.
• Group a14 Ecdysone receptor agonist agent
• Group 18 of the action classification by IRAC diacylhydrazines for example, chromafenozide, halofenozide, methoxyfenozide and tebufenozide.
• Group a15 The group consisting of Group 22A oxadiazines and Group 22B semicarpazones, such as indoxacarb and metaflumizone, in the action classification according to voltage-dependent sodium channel blockers IRAC.
• Group a16 Acetyl-CoA carboxylase inhibitors
• Group a17 Group 28 diamides of the ryanodine receptor modulators IRAC action classification, e.g. chlorantraniliprole, cyantraniliprole, cycloniliprole, flubendiamide, The group consisting of tetraniliprole, cyhalodiamide and tetrachlorantraniliprole.
• Factors that reduce susceptibility include [1] amino acid substitution of target proteins, [2] reduction of target proteins, [3] enhanced metabolism, [4] decreased skin permeability, and [5] excretion by membrane transporters. is enhanced.
• the target protein may have one or more amino acid substitutions.
• the enhancement of metabolism in [3] means an increase in the activity of metabolic enzymes (also called detoxifying enzymes) such as cytochrome P450, carboxylesterase, and glutathion-S-transferase.
• the factors that reduce susceptibility include [1] amino acid substitution of target proteins, [2] reduction of target proteins, [3] metabolic enhancement, [4] decreased skin permeability, and [5] excretion function by membrane transporters. You may have any one or more of the enhancement of
• Examples of reduced susceptibility harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes include the following. Hemiptera with reduced susceptibility to one or more compounds selected from group a2; Hemiptera with reduced susceptibility to one or more compounds selected from group a4; Hemiptera with reduced susceptibility to one or more compounds selected from group a8; Hemiptera with reduced susceptibility to one or more compounds selected from group a12; Hemiptera with reduced susceptibility to one or more compounds selected from group a2 and one or more compounds selected from group a4; Hemiptera with reduced susceptibility to one or more compounds selected from group a2 and one or more compounds selected from group a8; Hemiptera with reduced susceptibility to one or more compounds selected from group a2 and buprofezin belonging to group a12; Hemiptera with reduced susceptibility to one or more compounds selected from group
• Examples of harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes whose susceptibility has been reduced by amino acid substitution of the target protein include the following.
• Aphid gossypii having an amino acid substitution of R81T in the beta subunit of the nicotinic acetylcholine receptor;
• a green peach aphid having an amino acid substitution of R81T in the beta subunit of the nicotinic acetylcholine receptor; diamondback moth with a G4946E amino acid substitution in the ryanodine receptor; diamondback moth with an F1845Y or V1848I amino acid substitution in the sodium channel;
• Aphid gossypii having S431F and/or A302S amino acid substitutions in acetylcholinesterase; tobacco whitefly with L925I and/or
• Examples of harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes whose susceptibility has decreased due to a decrease in the target protein include the following. House flies with reduced expression of the ⁇ 2 subunit of the nicotinic acetylcholine receptor.
• Factors that increase the activity of metabolic enzymes include, for example, overexpression of metabolic enzyme genes (also referred to as quantitative mutation), and improved affinity for drugs due to amino acid substitution of metabolic enzymes (also referred to as qualitative mutation). It may have one or a plurality of factors that increase the activity of these metabolic enzymes.
• Examples of harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes in which metabolic enzyme activity is increased by overexpression of metabolic enzyme genes include the following. Brown planthopper with overexpression of CYP6ER1 (one of the cytochrome P450 genes); Amrasca biguttula biguttula in which the glutathione-S-transferase gene is overexpressed; Aphid gossypii overexpressing the cytochrome P450 monooxygenase gene; Bemisia tabaci overexpressing CYP6CM1 (one of the cytochrome P450-dependent monooxygenase genes); Bemisia tabaci overexpressing the cytochrome P450-dependent monoxygenase gene; corn borer with overexpression of carboxylesterase gene and/or microsomal-O-demethylase gene; Codling moss overexpressing the glutathion-S-transferase gene and/or the cytochrome P450 mono
• Harmful insects, harmful arthropods such as harmful mites, harmful molluscs, and harmful nematodes that have multiple factors for increasing the activity of metabolic enzymes for example, by having CYP6ER1vA and CYP6ER1vB in addition to overexpression of CYP6ER1 Brown planthopper with reduced susceptibility to imidacloprid.
• Examples of harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes that have decreased susceptibility due to reduced skin permeability include the following.
• Bollworm moths with reduced susceptibility to pyrethroids e.g., cypermethrin, esfenvalerate, etc.
• Bed bugs with reduced susceptibility to pyrethroids such as beta-cyfluthrin
• overexpression of C2, C10, and/or C13 one of the putative epidermal protein genes.
• harmful insects harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes whose susceptibility is reduced due to enhanced excretion by membrane transporters include the following.
• the present compounds and composition A can also be used to protect plants from plant diseases caused by insect-borne viruses or insect-borne bacteria.
• Insect-borne viruses include, for example: Rice tungro spherical virus, Rice tungro bacilliform virus, Rice grassy stunt virus, Rice ragged stunt virus, Rice striped virus Rice stripe virus, Rice black streaked dwarf virus, Southern rice black-streaked dwarf virus, Rice gall dwarf virus, Rice hoja blanca virus, Rice yellow stunt virus, Rice yellow mottle virus, Rice dwarf virus, Northern cereal mosaic virus, Barley yellow dwarf virus , Barley mild mosaic virus, Barley yellow dwarf virus (PAV), Cereal yellow dwarf virus (RPS), Wheat yellow leaf virus , Oat sterile dwarf virus, Wheat streak mosaic virus, Maize dwarf mosaic virus, Maize stripe virus, Maize chlorotic mottle virus, Maize chlorotic dwarf virus, Maize rayado fino virus, Sugarcane mosaic virus, Fiji disease virus, Sugarcane yellow leaf virus, Soybean mild mosaic virus , Cycas necrotic stunt virus, Soybean dwarf virus, Milk vetch dwarf virus, Soybean mosaic virus, Alfalfa mosaic virus , Bean
• Insect vector bacteria include, for example: Candidatus Phytoplasma oryzae, Candidatus Phytoplasma asteris, Maize bushy stunt phytoplasma, Candidatus Liberbacter asiaticus, Candidatus Liberbacter africanus, Citrus greening America type (Candidatus Liberbacter americanus), Pierce's disease (Xylella fastidiosa), etc.
• composition of the present invention can also be used to protect humans from diseases caused by arthropod-borne viruses.
• Examples of human diseases caused by arthropod-borne viruses for which the composition of the present invention has control efficacy include the following.
• composition of the present invention can also be used to protect animals from animal diseases caused by arthropod-borne viruses.
• animal diseases caused by arthropod-borne viruses for which the composition of the present invention has control efficacy include the following.
• Enzootic encephalitis Vesicular stomatitis, Rift Valley fever, bluetongue, Akabane disease, Chuzan disease, Lumpyskin disease ( Lumpy skin disease, Bovine leukosis, Aino virus infection, Ibaraki disease, Bovine ephemeral fever, Kenya sheep disease, sheep pox Sheep pox, Goat pox, Equine infectious anemia, African horse sickness, Fowl pox, Myxomatosis, etc.
• Tularemia Anaplasmosis, Rickettsiosis, Ehrlichiosis, Lyme disease, Pseudofarcy in horses, etc.
• the present compound and composition A also have feeding damage inhibitory effect, repellent effect, spawning inhibitory effect, infertility effect, next-generation production inhibitory effect, mating behavior inhibitory effect, molting inhibitory effect, and eclosion inhibitory effect.
• crops can be protected from damage by harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes.
• Composition A contains fungi, Oomycete, and Phytomyxea when it contains one or more fungicidal components selected from groups (b) and (j) as the present component. ), and can control plant diseases caused by phytopathogenic microorganisms such as bacteria.
• Fungi include, for example, Ascomycota, Basidiomycota, Blasocladiomycota, Chytridiomycota, Mucoromycota and Olpidiomycota. Specifically, the following are mentioned, for example. Parentheses indicate the scientific name of the phytopathogenic microorganism that causes each disease.
• Rice diseases Pyricularia oryzae, Cochliobolus miyabeanus, Rhizoctonia solani, Gibberella fujikuroi, Sclerophthora macrospora, Sclerophthora macrospora, and Epicoccum nigrum, Trichoderma viride, Rhizopus oryzae; Wheat diseases: Powdery mildew (Blumeria graminis), Fusarium graminearum, Fusarium avenaceum, Fusarium culmorum, Microdochium nivale, Yellow rust (Puccinia striiformis), Black rust (Puccinia graminis), Red rust (Puccinia recondita) ), red snow rot (Microdochium nivale, Microdochium majus), snow rot (Typhula incarnata, Typhula ishikariensis), naked smut (Ustilago tritici), raw smut (Tilletia
• Intraspecies variation is not particularly limited for the above plant pathogenic microorganisms. That is, it also includes those that have decreased sensitivity (also referred to as exhibiting resistance) to a specific fungicide. Decreased susceptibility may be due to mutations at the target site (point-of-action mutations) or due to non-point-of-action mutations (non-point-of-action mutations).
• Non-action point mutations include, for example, enhancement of the excretion function of ABC transporters, MFS transporters, and the like, which excrete the fungicide that has flowed into the cells to the outside of the cells. It also includes detoxification through metabolism of fungicides.
• polyoxin-based fungicides polyoxin-based fungicides, carboxylic acid amide-based fungicides), melanin synthesis inhibitors (e.g., MBI-R fungicides, MBI-D fungicides, MBI-P fungicides), and other fungicides (e.g., cyanoacetamide oxime-based fungicides, phenylacetamide-based fungicides).
• melanin synthesis inhibitors e.g., MBI-R fungicides, MBI-D fungicides, MBI-P fungicides
• other fungicides e.g., cyanoacetamide oxime-based fungicides, phenylacetamide-based fungicides.
• Composition A which contains one or more fungicidal components selected from groups (b) and (j) as this component, have a plurality of the above amino acid substitutions.
• the multiple amino acid substitutions may be in the same protein or in different proteins.
• it may have a plurality of non-acting point mutations and acting point mutations.
• Phytophthora infestans having an amino acid substitution of F382Y, P980S or V1476G in RPA190; Pythium spp. having an amino acid substitution of F382Y, P980S or V1476G in RPA190; Having L733W, S768I/F/K/Y, G770A/I/P/V/L, G818/F819 ⁇ , N837I/F/Y/ ⁇ , G839W, P861H, L863W/F or I877F/Y amino acid substitutions in ORP1 Phytophthora infestans; Phytophthora sojae having L733W, S768F/Y, G770V, N837F/Y/ ⁇ , G839W, P861H, L863W or I877Y amino acid substitutions in ORP1; Phytophthora capsici having a G700V or G769W amino acid substitution in ORP1; Plasmopara viticola
• Zymoseptoria tritici means the same species as Septoria tritici.
• Microsphaera diffusa means the same species as Erysiphe diffusa.
• Urticaceae Weeds Urtica urens Polygonaceae: Polygonum convolvulus, Polygonum lapathifolium, Polygonum pensylvanicum, Polygonum persicaria, Polygonum longisetum, Polygonum aviculare, Polygonum arenastrum , Polygonum cuspidatum, Rumex japonicus, Rumex crispus, Rumex obtusifolius, Rumex acetosa Purslane family weed (Portulacaceae): Purslane (Portulaca oleracea) Caryophyllaceae: Stellaria media, Stellaria aquatica, Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, Silene gallica Molluginaceae Weeds: Mollugo verticillata Chenopodiaceae: Chenopodiaceae: Chenopodium album, Chenopodium ambrosioides, Kochi
• Fabaceae Aeschynomene indica, Aeschynomene rudis, Sesbania exaltata, Cassia obtusifolia, Cassia occidentalis, Desmodium tortuosum, Desmodium adscendens, Desmodium illinoense, Trifolium repens, Pueraria lobata, Vicia angustifolia, Indigofera hirsuta, Indigofera truxillensis, wild cowpea ( Vigna sinensis)
• Oxalidaceae Oxalis corniculata, Oxalis stricta, Oxalis oxyptera
• Geraniaceae American Geranium carolinense, Dutch Geranium cicutarium
• Euphorbiaceae Euphorbia helioscopia, Euphorbia maculata, Euphorbia humistrata, Euphorbia esula, Euphorbia heterophylla, Hyssop leaf sandmat (Euphorbia brasi
• Malvaceae Abutilon theophrasti, Sida rhombifolia, Sida cordifolia, Sida spinosa, Sida glaziovii, Sida santaremnensis ), Hibiscus trionum, Anoda cristata, Malvastrum coromandelianum Onagraceae: Ludwigia epilobioides, Ludwigia octovalvis, Ludwigia decurrens, Oenothera biennis, Oenothera laciniata Sterculiaceae: Waltheria indica Violaceae weeds (Violaceae): Viola violet (Viola arvensis), wild pansy (Viola tricolor) Cucurbitaceae: Cucurbitaceae (Sicyos angulatus), wild cucumber (Echinocystis lobata), wild bitter gourd (Momordica charantia) Lythraceae: Ammannia multiflora, Ammann
• Apiaceae Apiaceae: Apiaceae (Oenanthe javanica), Daucus carota, Conium maculatum Araliaceae Weeds (Araliaceae): Hydrocotyle sibthorpioides, Brazilian Hydrocotyle ranunculoides Ceratophyllaceae: Matsumo (Ceratophyllum demersum) Cabombaceae Weeds: Cabomba caroliniana Haloragaceae: Myriophyllum aquaticum, Myriophyllum verticillatum, Water Milfoils (Myriophyllum spicatum, Myriophyllum heterophyllum, etc.) Sapindaceae Weeds: Cardiospermum halicacabum Primulaceae Weeds (Primulaceae): Anagallis arvensis Asclepiadaceae: Asclepias syriaca, honeyvine milkweed (Ampel
• Convolvulaceae Ipomoea nil, Ipomoea hederacea, Ipomoea purpurea, Ipomoea hederacea var. integriuscula, Ipomoea lacunosa, Ipomoea triloba , Ipomoea acuminata, Ipomoea hederifolia, Ipomoea coccinea, Ipomoea quamoclit, Ipomoea grandifolia, Ipomoea aristolochiaefolia, Ipomoea cairica , Convolvulus arvensis, Calystegia hederacea, Calystegia japonica, Merremia hederacea, Merremia aegyptia, Roadside Woodrose (Merremia cissoides), Jacquemontia tamnifolia Boraginaceae: Forget-me-nots (Myos
• Solanaceae Datura stramonium, Solanum nigrum, Solanum americanum, Solanum ptycanthum, Solanum sarrachoides, Solanum rostratum , Solanum aculeatissimum, Wild tomato (Solanum sisymbriifolium), Solanum carolinense, Physalis anulata, Smooth ground cherry (Physalis subglabrata), Nicandra physalodes Scrophulariaceae: Veronica hederaefolia, Veronica persica, Veronica arvensis, Lindernia procumbens, Lindernia dubia, Lindernia angustifolia, Bacopa rotundifolia, horsefly (Dopatrium junceum), Giant Abalone (Gratiola japonica) Plantaginaceae: Plantago asiatica, Plantago lanceolata, Plantago major, Callitriche palustris
• Asteraceae Xanthium pensylvanicum, Xanthium occidentale, Xanthium italicum, Helianthus annuus, Matricaria chamomilla, Matricaria perforata, Chrysanthemum segetum ), Matricaria matricarioides, Artemisia princeps, Artemisia vulgaris, Chinese mugwort (Artemisia verlotorum), Solidago altissima, Taraxacum officinale, Galinsoga ciliata (Galinsoga parviflora), Senecio vulgaris, Senecio brasiliensis, Senecio grisebachii, Conyza bonariensis, Conyza smatrensis, Conyza canadensis, Ambrosia artefolia , Ambrosia trifida, Bidens tripartita, Bidens pilosa, Bidens frondosa, Bidens subaltern
• Alismataceae Sagittaria pygmaea, Sagittaria trifolia, Sagittaria sagittifolia, Sagittaria montevidensis, Sagittaria aginashi, Alisma canaliculatum, Alisma plantago- aquatica)
• Limnocharitaceae Weeds Limnocharis flava Hydrocharitaceae: frogbit (Limnobium spongia), black moth (Hydrilla verticillata), common water nymph (Najas guadalupensis)
• Araceae Pistia stratiotes Lemnaceae weeds (Lemnaceae): Lemna aoukikusa, Lemna paucicostata, Lemna aequinoctialis, Spirodela polyrhiza, Wolffia spp.
• Potamogetonaceae Potamogeton distinctus, Pondweeds (Potamogeton crispus, Potamogeton illinoensis, Stuckenia pectinata, etc.)
• Liliaceae Weeds Wild Onion (Allium canadense), Wild Garlic (Allium vineale), Nobile (Allium macrostemon)
• Pontederiaceae Eichhornia crassipes, Heteranthera limosa, Monochoria korsakowii, Monochoria vaginalis
• Commelinaceae weeds Commelina communis, Commelina benghalensis, Commelina erecta, Murdannia keisak
• Echinochloa crus-galli Echinochloa oryzicola, Echinochloa crus-galli var. formosensis, Echinochloa oryzoides, Echinochloa colona, Gulf cockspur (Echinochloa crus-pavonis), Setaria viridis, Setaria faberi, Setaria glauca, Setaria geniculata, Digitaria ciliaris, Large crabgrass (Digitaria sanguinalis), Jamaican crabgrass (Digitaria horizontalis), silver crabgrass (Digitaria insularis), goosegrass (Eleusine indica), bluegrass (Poa annua), bluegrass bluegrass (Poa trivialis), long-billed grass (Poa pratensis), blue-eyed trumpet (Alopecurus aequalis), blackgrass (Alopecurus myosuroides), Avena fatua, Sorghum halepense, S
• Cyperaceae weeds (Cyperaceae): Cyperus microiria, Cyperus iria, Cyperus compressus, Cyperus difformis, Cyperus flaccidus, Cyperus globosus, Cyperus nipponicus, King Cyperus odoratus, Cyperus serotinus, Cyperus rotundus, Cyperus esculentus, Kyllinga gracillima, Kyllinga brevifolia, Fimbristylis miliacea, Fimbristylis dichotoma, Eleocharis acicularis, Eleocharis kuroguwai, Schoenoplectiella hotarui, Schoenoplectiella juncoides, Schoenoplectiella wallichii, Schoenoplectiella muatus, Schoenoplectiella triangulatus, Schoenoplectiella nipponicus, Schoenoplectiella nippo
• intraspecific variation is not particularly limited. In other words, it also includes those that have decreased sensitivity (also referred to as exhibiting resistance) to a specific herbicide.
• Decreased susceptibility may be due to mutations at the target site (point-of-action mutations) or due to non-point-of-action mutations (non-point-of-action mutations).
• mutations in the nucleic acid sequence (open reading frame) corresponding to the amino acid sequence of the protein cause amino acid substitutions in the target site protein, deletion of suppressor sequences in promoter regions, and enhancer sequences or overexpression of the protein at the target site due to mutation such as an increase in the copy number of the gene.
• Non-action point mutations include metabolic enhancement, malabsorption, translocation, and excretion.
• Metabolic enhancement factors include increased activity of metabolic enzymes such as cytochrome P450 monooxygenase, arylacyl amidase, esterase, and glutathione S-transferase.
• Out-of-system excretion includes transport to vacuoles by ABC transporters.
• Weeds that can be controlled by Composition A which contains one or more herbicidally active components selected from Group (i) and Group (j) as this component, may have a plurality of the above amino acid substitutions. .
• the multiple amino acid substitutions may be in the same protein or in different proteins. Moreover, it may have a plurality of non-acting point mutations and acting point mutations.
• Weeds with point-of-action mutations include, for example: PPX2 having an amino acid substitution of G210 ⁇ , R98M, R98G or G399A.
• Water hemp having an amino acid substitution of G210 ⁇ , R98M, R98G or G399A in PPX2; Ragweed with an amino acid substitution of R98L in PPX2; P.
• Pseudophyllum japonicum, water hemp, and ragweed which have the above-mentioned point-of-action mutations in PPX2, show resistance to PPO inhibitors such as lactofen, fomesafen, and flumioxazin.
• Weeds having multiple amino acid substitutions above include, for example, glyphosate-resistant goosegrass, ratgrass, mulberry, silvergrass, redgrass, and red rice with T102I and P106S amino acid substitutions.
• weeds include: Overexpression of the EPSP gene reduces susceptibility to glyphosate: Kohimebie with reduced sensitivity to glyphosate due to increased expression of aldoketo reductase; ABC transporter-mediated glyphosate-reduced resistance to wormwood, artichoke, and artichoke.
• natural pyrethrins + spinetoram means a combination of natural pyrethrins and spinetoram.
• Group 2 consists of Composition A consisting of 2 parts of natural pyrethrins and 1.5 parts of this ingredient, where the combination of natural pyrethrins and this ingredient is any of the combinations listed in the "2 Active Ingredients List” above. be done.
• Group 3 consists of Composition A consisting of 1 part natural pyrethrins and 1 part of this ingredient, where the combination of natural pyrethrins and this ingredient is any combination of the above "2 Active Ingredient List” .
• Group 4 consists of Composition A consisting of 1 part natural pyrethrins and 2 parts this ingredient, where the combination of natural pyrethrins and this ingredient is any of the combinations listed in the "Two Active Ingredients List” above. .
• Group 8 consists of Composition A consisting of 1 part natural pyrethrins and 3 parts this ingredient, where the combination of natural pyrethrins and this ingredient is any combination from the above "2 Active Ingredient List” .
• Group 9 consists of Composition A consisting of 5 parts natural pyrethrins and 6.6 parts of this ingredient, where the combination of natural pyrethrins and this ingredient is any combination from the "2 Active Ingredients List” above be done.
• Group 10 consists of Composition A consisting of 1 part natural pyrethrins and 4 parts this ingredient where the combination of natural pyrethrins and this ingredient is any combination from the above "2 Active Ingredient List” .
• Group 11 consists of Composition A consisting of 5 parts natural pyrethrins and 8 parts of this ingredient where the combination of natural pyrethrins and this ingredient is any combination from the "2 Active Ingredients List” above .
• Group 12 includes natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the following "3 Active Ingredient Lists", 2 parts of natural pyrethrins, 0.5 parts of Ingredients 1 and 1 Composed of Composition A consisting of .5 parts of this ingredient 2;
• natural pyrethrin + allethrin + cypermethrin means a combination of natural pyrethrin, allethrin and cypermethrin, where component 1 is allethrin and component 2 is cypermethrin.
• “List of 3 Active Ingredients” does not include specific combinations, but the following compounds may be used for Component 1 and Component 2. acrinathrin, benfluthrin, cycloprothrin, cyflumetofen, flufenoprox, halfenprox, heptafluthrin, kadethrin, capateflu kappa-tefluthrin, kappa-bifenthrin, tefluthrin, abamectin, acephate, acequinocyl, acetoprole, acinonapyr, aphidopyropen , alanycarb, aldicarb, alpha-endosulfan, aluminum phosphide, azinphos-ethyl, azinphos-methyl, azocyclotin, benfuracarb , bensultap, benzoximate, benzpyrimoxan, bifenazate,
• Group 13 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists", 2 parts natural pyrethrins, 0.5 parts of Ingredients 1 and 2 It is composed of composition A consisting of this component 2 in part.
• Group 14 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists” and 2 parts natural pyrethrins, 0.5 parts of Ingredients 1 and 4 It is composed of composition A consisting of this component 2 in part.
• Group 15 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists" and 2 parts natural pyrethrins, 0.5 parts of Ingredients 1 and 7 It is composed of composition A consisting of this component 2 in part.
• Group 16 includes 2 parts natural pyrethrins, 1.5 parts ingredients 1 and 2 where the combination of natural pyrethrins, Ingredient 1 and Ingredient 2 is any combination from the "3 Active Ingredients List” above. It is composed of composition A consisting of this component 2 in part.
• Group 17 includes 2 parts natural pyrethrins, 1.5 parts ingredients 1 and 4 where the combination of natural pyrethrins, ingredient 1 and ingredient 2 is any combination from the "3 Active Ingredients List” above.
• composition A consisting of this component 2 in part It is composed of composition A consisting of this component 2 in part.
• Group 18 includes 2 parts natural pyrethrins, 1.5 parts ingredients 1 and 7 where the combination of natural pyrethrins, ingredient 1 and ingredient 2 is any combination from the "3 Active Ingredients List” above. It is composed of composition A consisting of this component 2 in part.
• Group 19 includes 2 parts natural pyrethrins, 2 parts ingredients 1 and 2.5 where the combination of natural pyrethrins, this ingredient 1 and this ingredient 2 is any combination from the above "3 Active Ingredients List” It is composed of composition A consisting of this component 2 in part.
• Group 20 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in any combination of the above "3 Active Ingredients List", 1 part natural pyrethrins, 1 part Ingredients 1 and 2 It is composed of composition A consisting of component 2.
• Group 21 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in any combination from the above "3 Active Ingredients List", 0.1 part of natural pyrethrins, 0.5 parts of Ingredient 1 and 1.5 parts of Composition A consisting of this ingredient 2.
• Group 22 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in any combination from the above "3 Active Ingredients List” and 0.1 part of natural pyrethrins, 0.5 parts of Ingredient 1 and 0.3 parts of Component 2 of Composition A.
• Group 23 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists" and 0.1 part of natural pyrethrins, 2 parts of Ingredients 1 and 1 Composed of Composition A consisting of .5 parts of this ingredient 2;
• Group 24 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists” and 5 parts natural pyrethrins, 6.6 parts Ingredients 1 and 20 It is composed of composition A consisting of this component 2 in part.
• Group 30 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists", 1 part natural pyrethrins, 10 parts Ingredients 1 and 10 parts It is composed of composition A consisting of component 2.
• Group 31 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists", 10 parts natural pyrethrins, 1 part Ingredients 1 and 1 part It is composed of composition A consisting of component 2.
• Group 32 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists", 10 parts natural pyrethrins, 1 part Ingredients 1 and 10 parts It is composed of composition A consisting of component 2.
• Group 33 is a combination of natural pyrethrins, Ingredient 1 and Ingredient 2 in combination with any of the above "3 Active Ingredient Lists", 10 parts natural pyrethrins, 10 parts Ingredients 1 and 1 part It is composed of composition A consisting of component 2.
• the MX abbreviation means any one composition A selected from Groups 1-33.
• Formulation example 2 A formulation is obtained by pulverizing and mixing 50 parts of natural pyrethrins or 50 parts of MX, 3 parts of calcium ligninsulfonate, 2 parts of sodium lauryl sulfate, and 45 parts of silica.
• Formulation example 3 By mixing 5 parts of natural pyrethrin or 5 parts of MX, 9 parts of polyoxyethylene styryl phenyl ether, 5 parts of polyoxyethylene decyl ether (ethylene oxide addition number: 5), 6 parts of calcium dodecylbenzenesulfonate, and 75 parts of xylene, Obtain the formulation.
• Formulation example 4 2 parts of natural pyrethrin or 2 parts of MX, 1 part of silica, 2 parts of calcium lignosulfonate, 30 parts of bentonite, and 65 parts of kaolin clay were pulverized and mixed, kneaded with an appropriate amount of water, and granulated with a granulator. Afterwards, the formulation is obtained by drying.
• Formulation example 5 10 parts natural pyrethrins or 10 parts MX are mixed with a mixture of 18 parts benzyl alcohol and 9 parts DMSO to which 6.3 parts GERONOL® TE250, 2.7 parts Ethylan NS-500LQ®, and 54 parts of solvent naphtha are added and mixed to obtain a formulation.
• Formulation example 6 The formulation is obtained by mixing 10 parts of natural pyrethrins or 10 parts of MX, 5 parts of nonylphenol ethoxylate and 85 parts of propylene glycol.
• Formulation example 7 The formulation is obtained by mixing 10 parts of natural pyrethrins or 10 parts of MX and 20 parts of xylene and dispersing in 68 parts of water containing 2 parts of polyvinyl alcohol.
• Formulation example 8 30 parts of natural pyrethrin or 30 parts of MX, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and 65 parts of kaolin clay are pulverized and mixed, kneaded with an appropriate amount of water, and granulated with a granulator. The formulation is obtained by drying.
• Formulation example 9 35 parts of a mixture of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon (weight ratio 1:1), 10 parts of natural pyrethrin or 10 parts of MX, and 55 parts of water are mixed and finely pulverized by a wet pulverization method. The resulting mixture is granulated using a fluid bed granulator to obtain a formulation.
• Formulation example 10 A formulation is obtained by mixing 20 parts of natural pyrethrins or 20 parts of MX, 5 parts of polyoxyethylene nonylphenyl ether, 3 parts of carboxymethylcellulose and 72 parts of water.
• Formulation Example 11 10 parts natural pyrethrin or 10 parts MX, 0.2 parts hexamethylene diisocyanate, and 10 parts xylene are mixed and dispersed in 75.8 parts water containing 2 parts polyvinyl alcohol. A formulation is obtained by adding 2 parts of ethylenediamine and allowing the encapsulation reaction to proceed while mixing.
• Formulation example 12 A formulation is obtained by grinding and mixing 2 parts of natural pyrethrins or 2 parts of MX, 88 parts of kaolin clay, and 10 parts of talc.
• Formulation Example 13 0.1 part of natural pyrethrin or 0.1 part of MX and 39.9 parts of kerosene are mixed and dissolved, placed in an aerosol container, and liquefied petroleum gas (mixture of propane, isobutane and butane, saturated vapor pressure: 0.47 MPa (25°C)). A formulation is obtained by filling 60 parts.
• Formulation Example 14 0.02 parts of natural pyrethrin or 0.02 parts of MX, 0.18 parts of triethyl citrate, 3 parts of isopropyl myristate, 5.8 parts of paraffin solvent (Neothiosol, manufactured by Chuo Kasei Co., Ltd.), glyceryl oleate and propylene glycol 0.8 part of the compound (Rheodol MO-60, manufactured by Kao Corporation) and 0.2 part of polyoxyethylene sorbitan monooleate (Rheodol TW-0120, manufactured by Kao Corporation) are mixed and dissolved.
• paraffin solvent Neothiosol, manufactured by Chuo Kasei Co., Ltd.
• glyceryl oleate and propylene glycol 0.8 part of the compound
• Rheodol TW-0120 polyoxyethylene sorbitan monooleate
• the mixture and 40 parts of water are placed in an aerosol container, and 50 parts of dimethyl ether/liquefied petroleum gas (mixture of propane, butane and isobutane, saturated vapor pressure: 0.35 MPa (25° C.)) 1/1 (weight ratio) is filled. to obtain a formulation.
• dimethyl ether/liquefied petroleum gas mixture of propane, butane and isobutane, saturated vapor pressure: 0.35 MPa (25° C.)
• 1/1 weight ratio
• Formulation example 15 0.2 parts of natural pyrethrins or 0.2 parts of MX, 50 parts of pyrethrum extract lees powder, 30 parts of tab powder, and 19.8 parts of wood powder are mixed, kneaded with an appropriate amount of water, and extruded into a plate-like sheet. and spirally formed with a punch to obtain a formulation.
• Formulation Example 16 10 parts of natural pyrethrin or 10 parts of MX and 90 parts of a hydrocarbon solvent are mixed, and the resulting mixture is applied to a porous mat for impregnation of 35 mm length ⁇ 22 mm width ⁇ 2.8 mm thickness (a mixture of wood pulp and linter pulp is molded. The formulation is obtained by impregnating the
• Formulation Example 18 1.5 parts of natural pyrethrin or 1.5 parts of MX, 50 parts of diethylene glycol monobutyl ether, 1.8 parts of dibutylhydroxytoluene, and 46.7 parts of water are mixed and dissolved to obtain a chemical solution, which is filled in a plastic bottle, An electric liquid mosquito repellent is obtained by inserting a liquid absorbent wick whose upper part can be heated by a heater through an inner plug.
• Formulation Example 19 A preparation is obtained by supporting 100 parts of natural pyrethrin or 100 parts of MX on a porous solid carrier (woven fabric, knitted fabric, non-woven fabric, paper, etc.).
• a porous solid carrier woven fabric, knitted fabric, non-woven fabric, paper, etc.
• Formulation example 20 50 parts of natural pyrethrin or 50 parts of MX, 18 parts of white carbon (Carplex #80, manufactured by EVONIK: average particle size: 15 ⁇ m), ethylene-vinyl acetate copolymer (Ultrathen 710, manufactured by Tosoh Corporation: in copolymer 20 parts of vinyl acetate content: 28%) and 12 parts of LDPE (Suntec LDM6520, manufactured by Asahi Kasei Corporation) were kneaded at 120 to 140° C. to produce a pellet masterbatch. Next, 100 parts of the obtained pellets and 300 parts of the LDPE are kneaded at 120 to 140° C. and injection molded to obtain a formulation.
• white carbon Carplex #80, manufactured by EVONIK: average particle size: 15 ⁇ m
• ethylene-vinyl acetate copolymer Ultrathen 710, manufactured by Tosoh Corporation: in copolymer 20 parts of vinyl acetate content: 28%)
• Formulation Example 21 4.4 parts of natural pyrethrin or 4.4 parts of MX, 1.5 parts of diethylene glycol mono-2-ethylhexyl ether, and 4.4 parts of hydroxymethylpentylcyclohexene carboxamide were added to polyester nonwoven fabric (longitudinal direction 130 mm, transverse direction 64 mm, thickness A preparation is obtained by impregnating a predetermined amount of a 0.46 mm, basis weight of 170 g/m 2 ).
• Formulation example 22 22 parts of natural pyrethrin or 22 parts of MX, 0.1 part of linalool, 2 parts of pregelatinized starch (Amicol H, manufactured by Nitten Chemical Co., Ltd.), 0.5 parts of zinc oxide (manufactured by Seido Chemical Industry Co., Ltd.), and azodicarbonamide ( 75.4 parts of Uniform AZ, manufactured by Otsuka Chemical Co., Ltd.) are mixed, granulated and dried to obtain a cylindrical preparation (circular diameter of about 3 mm, length of about 7 mm).
• Formulation Example 23 0.5 part of natural pyrethrin or 0.5 part of MX, 4 parts of sesame oil, 25 parts of starch syrup, 35 parts of glycerin, 1 part of gellan gum and 34.5 parts of water are mixed to obtain a formulation.
• Formulation Example 24 100 parts natural pyrethrins or 100 parts MX, 68.75 parts lactose, 237.5 parts corn starch, 43.75 parts microcrystalline cellulose, 18.75 parts polyvinylpyrrolidone, 28.75 parts sodium carboxymethyl starch, and magnesium stearate.
• a formulation is obtained by mixing 2.5 parts and compression molding.
• Formulation example 25 The formulation is obtained by mixing 200 parts of natural pyrethrins or 200 parts of MX, 148 parts of lactose and 2 parts of magnesium stearate and filling hard gelatin capsules or hydroxypropyl methylcellulose capsules.
• Formulation Example 26 After mixing 1 part of natural pyrethrin or 1 part of MX, 74 parts of water for injection, and 25 parts of polyethylene glycol, the mixture is filled in a vial and sterilized in an autoclave to obtain a formulation.
• Formulation Example 27 After dissolving 5 parts of natural pyrethrin or 5 parts of MX in 70 parts of diethylene glycol monoethyl ether, 25 parts of 2-octyldodecanol are mixed to obtain a formulation.
• Formulation Example 28 200 parts of natural pyrethrin or 200 parts of MX, 50 parts of fumaric acid, 200 parts of sodium chloride, 15 parts of methylparaben, 5 parts of propylparaben, 2500 parts of granulated sugar, 1300 parts of sorbitol (70% solution), Veegum K (Vanderbilt Minerals, manufactured by LCC) A formulation is obtained by adding and mixing 10 parts, 3.5 parts of perfume, 50 parts of colorant and 6000 parts of water.
• Formulation Example 29 50 parts of natural pyrethrin or 50 parts of MX and 1.5 parts of dibutyl hydroxytoluene (Sumilizer BHT, manufactured by Sumitomo Chemical Co., Ltd.) were mixed to obtain 48.5 parts of porous silica (Carplex #80, manufactured by EVONIK, average particle size 15 ⁇ m).
• a silica capsule was manufactured by adding to the part and stirring and mixing. 31 parts of the silica capsule, 59.5 parts of linear low-density polyethylene (Sumikasen-L GA807, manufactured by Sumitomo Chemical Co., Ltd.; density: 0.912 kg/m 3 ), 5 parts of zinc stearate, and 4.5 parts of pigment.
• the mixture was extruded from an extruder and cut to produce resin pellets (diameter: 3 mm, length: 3 mm) containing the pest control component.
• 14 parts of the resin pellets, 85.4 parts of high-density polyethylene (Hi-Zex 5000S, manufactured by Mitsui Chemicals, Inc.; density: 0.950 kg/m 3 ), and 0.6 parts of zinc stearate are melt-spun at 220-240°C.
• a resin fiber was obtained by The fiber is raschel-knitted to obtain a net-like formulation.
• Formulation example 30 Ethanol is added to 2.291 g of natural pyrethrins or 2.291 g of MX to obtain a total volume of 200 mL of solution.
• ethanol is added to 18.94 g of a 44% acrylic acid ester copolymer emulsion to obtain a binder liquid with a total volume of 100 mL.
• 14.5 ml of the solution and 25 mL of the binder solution are added to ethanol to obtain a total impregnation solution of 100 mL.
• the impregnating solution is added to a multifilament polyester knitted fabric (length x width: 25 cm x 25 cm) and allowed to soak in, followed by drying overnight under light-shielding conditions to obtain a net-like preparation.
• Natural pyrethrins (mixture of 6 species (pyrethrin I + pyrethrin II + synerin I + synerin II + jasmolin I + and jasmolin II) containing a total content of 50.5% by weight) were weighed into a pressure-resistant glass container, and 10 cc of liquefied carbon dioxide gas was added at 20°C. was filled into the pressure-resistant glass container and stirred to prepare a formulation having a total pyrethrin content of 1.0% by weight.
• composition B to plant seeds.
• Application example 1 (application to sorghum seeds) 200 mL of one of the formulations obtained by the method described in Formulation Example 1 was smeared onto 100 kg of dried sorghum seeds using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH). , to obtain the treated seed.
• a rotary seed treatment machine seed dresser, manufactured by Hans-Ulrich Hege GmbH.
• Test example 17 A natural pyrethrin or MX is prepared according to the method described in Formulation Example 1. Similarly, triflumezopyrim, flupyradifuron, or flupyrimine are prepared according to the method described in Formulation Example 1, respectively.
• Spreading agent (trade name: Syndyne (registered trademark)) is applied to each of the above formulations so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm or 200 ppm. Dilute with water containing 0.05% by volume to obtain each dilution.
• Test example 18 A natural pyrethrin or MX is prepared according to the method described in Formulation Example 1. Similarly, flupyradifuron and flupyrimine are formulated according to the method described in Formulation Example 4, respectively.
• Spreading agent (trade name: Syndyne (registered trademark)) is added to each of the above formulations so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm or 200 ppm. Dilute with water containing 0.05% by volume.
• strains with reduced susceptibility used in this test are strains with reduced susceptibility to these compounds.
• natural pyrethrin or MX treated plots can be confirmed to have the same effect on susceptible strains even on reduced-susceptibility strains.
• Test example 23 A natural pyrethrin or MX is prepared according to the method described in Formulation Example 4. After puddling, a few grains of rice seeds coated with iron oxide powder were sown in the paddy fields that had been drained for several days with a riding seeder, and the above formulation was added at a rate of 1 kg/10 a to the sowing position. Apply to the position directly below, 1 cm deep. After that, rice is cultivated.
• Test example 24 A natural pyrethrin or MX is prepared according to the method described in Formulation Example 4. After puddling, rice seeds coated with Culper (registered trademark) granules 16 (calcium peroxide granules, Hodogaya UPL Co., Ltd.) were planted using a riding seeder in paddy fields that had been drained for several days. While seeding several grains, the above formulation is applied at a rate of 1 kg/10a to a position 3 cm laterally and 3 cm deep from the seeding position. After that, rice is cultivated.
• Culper registered trademark
• granules 16 calcium peroxide granules, Hodogaya UPL Co., Ltd.
• Two male adult cockroaches (Blattella germanica) are released into the polyethylene cup and the cup is covered. After 6 days, check whether the German cockroaches are alive or dead, and determine the mortality rate. As a result, the effect on the German cockroach can be confirmed.
• Test example 32 Prepare an acetone solution of natural pyrethrin or MX at a given concentration. After dripping 0.3 ⁇ l of the acetone solution onto the dorsal side of the thorax of Culex quinquefasciatus (Culex quinquefasciatus), the test insect was transferred to a plastic cup and left at 25° C. together with 3% sugar water as food. Observe the life and death of the test insects one day later, and determine the mortality rate. Ten Culex aegypti used for one test are transferred to one cup. As a result, the effect on Culex aegypti treated with natural pyrethrin or MX can be confirmed.
• Test example 34 Prepare an acetone solution of a given concentration of natural pyrethrins or MX. After dripping 0.3 ⁇ l of the acetone solution onto the dorsal side of the thorax of the adult female Aedes aegypti, the test insect was transferred to a plastic cup and left at 25° C. together with 3% sugar water as food. Observe the life and death of the test insects one day later, and determine the mortality rate. 10 Aedes aegypti tested per test are transferred to one cup. As a result, the effect on Aedes aegypti treated with natural pyrethrin or MX can be confirmed.
• Test example 35 Prepare an acetone solution of natural pyrethrin or MX at a given concentration. After dripping 0.3 ⁇ l of the acetone solution onto the dorsal side of the thorax of an adult female Anopheles gambiae, the test insect was transferred to a plastic cup and left at 25° C. with 3% sugar water as food. Observe the life and death of the test insects one day later, and determine the mortality rate. Ten Anopheles gambier mosquitoes are tested per test and transferred to one cup. As a result, the effect on Anopheles gambiae treated with natural pyrethrin or MX can be confirmed.
• Test example 37 5 mg of natural pyrethrin or MX is dissolved in 5 mL of propylene carbonate to a concentration of 0.1% w/v to prepare a drug solution for testing.
• mice are inoculated with 30 test mites (Ixodes pallidum, juvenile mites). Remove non-infested mites before drip treatment.
• 200 ⁇ L of the test drug solution is dripped onto the entire body surface of the mouse.
• 200 ⁇ L of propylene carbonate alone is administered to the control group. Three replicates per group are performed.
• Dead insect rate (%) 100 ⁇ (number of dead insects / number of parasites before dropping) As a result, it is possible to confirm the effect on the locust mites.
• the present invention can control harmful arthropods.

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