WO2022077644A1 - 一种纱用软化剂 - Google Patents

一种纱用软化剂 Download PDF

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Publication number
WO2022077644A1
WO2022077644A1 PCT/CN2020/126813 CN2020126813W WO2022077644A1 WO 2022077644 A1 WO2022077644 A1 WO 2022077644A1 CN 2020126813 W CN2020126813 W CN 2020126813W WO 2022077644 A1 WO2022077644 A1 WO 2022077644A1
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parts
water
yarn
softener
mix
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PCT/CN2020/126813
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English (en)
French (fr)
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王道印
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单县大道玻纤有限公司
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Publication of WO2022077644A1 publication Critical patent/WO2022077644A1/zh

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the invention relates to the field of glass fiber mesh, in particular to a softener for yarn.
  • the produced glass fiber alkali-free yarn and medium-alkali yarn cannot replace starch yarn and paraffin-type yarn.
  • the use range of yarn is narrow, and glass fiber alkali-free yarn and medium-alkali yarn cannot be used with high-speed rapier looms and air-jet looms, and cannot help glass fiber weaving enterprises to upgrade and transform by eliminating ordinary rapier looms.
  • the technical problem to be solved by the present invention is: to provide a yarn softener, which solves the problem that the existing glass fiber alkali-free yarn and medium alkali yarn cannot replace starch yarn and paraffin type yarn, and the use of glass fiber alkali-free yarn and medium alkali yarn
  • the scope is narrow, and the glass fiber alkali-free yarn and medium alkali yarn cannot be used with high-speed rapier looms and air-jet looms, and cannot help glass fiber weaving enterprises to eliminate ordinary rapiers and upgrade and transform.
  • a yarn softener characterized in that: it is made of the following raw materials:
  • the water is deionized water to prevent impurities in the water from affecting the quality of the softener
  • the water temperature in the described step 4 is normal temperature, which reduces the production cost of the softening agent
  • the softener obtained in step 4 is added to the infiltration tank on the wire drawing machine. After the glass wire drawn by the wire drawing furnace is infiltrated by the softener in the infiltration tank, the pulled glass wire is wound on the wire drawing cylinder by the winding machine, and the glass wire on the wire drawing cylinder is The twisting machine twists the fiberglass thread into the fiberglass thread, and the fiberglass thread is woven into the fiberglass mesh cloth by the loom.
  • the present invention selects peregrine, stearic acid, white oil, color fixing agent, epoxy resin 681, polyester resin SR-1 and water as the main raw materials, and the selected raw materials are few and the ratio is simple
  • the softener is used for the softening of glass fiber alkali-free yarn and medium-alkali yarn
  • the fiber yarn produced can replace 98% starch yarn, 100% paraffin type yarn
  • the tensile strength of the produced yarn is starch yarn and paraffin type yarn 2 times as high as , strong tensile strength, wide range of use, can be matched with high-speed rapier looms and air-jet looms, and can help glass fiber weaving enterprises to upgrade and transform by eliminating ordinary rapier looms.
  • a yarn softener characterized in that: it is made of the following raw materials:
  • the water is deionized water to prevent impurities in the water from affecting the quality of the softener
  • the water temperature in the described step 4 is normal temperature, which reduces the production cost of the softening agent
  • the softener obtained in step 4 is added to the infiltration tank on the wire drawing machine. After the glass wire drawn by the wire drawing furnace is infiltrated by the softener in the infiltration tank, the pulled glass wire is wound on the wire drawing cylinder by the winding machine, and the glass wire on the wire drawing cylinder is The twisting machine twists the fiberglass thread into the fiberglass thread, and the fiberglass thread is woven into the fiberglass mesh cloth by the loom.
  • a yarn softener characterized in that: it is made of the following raw materials:
  • the water is deionized water to prevent impurities in the water from affecting the quality of the softener
  • the water temperature in the described step 4 is normal temperature, which reduces the production cost of the softening agent
  • the softener obtained in step 4 is added to the infiltration tank on the wire drawing machine. After the glass wire drawn by the wire drawing furnace is infiltrated by the softener in the infiltration tank, the pulled glass wire is wound on the wire drawing cylinder by the winding machine, and the glass wire on the wire drawing cylinder is The twisting machine twists the fiberglass thread into the fiberglass thread, and the fiberglass thread is woven into the fiberglass mesh cloth by the loom.
  • a yarn softener characterized in that: it is made of the following raw materials:
  • the water is deionized water to prevent impurities in the water from affecting the quality of the softener
  • the water temperature in the described step 4 is normal temperature, which reduces the production cost of the softening agent
  • the softener obtained in step 4 is added to the infiltration tank on the wire drawing machine. After the glass wire drawn by the wire drawing furnace is infiltrated by the softener in the infiltration tank, the pulled glass wire is wound on the wire drawing cylinder by the winding machine, and the glass wire on the wire drawing cylinder is The twisting machine twists the fiberglass thread into the fiberglass thread, and the fiberglass thread is woven into the fiberglass mesh cloth by the loom.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

一种纱用软化剂，涉及玻璃纤维网布领域，由以下份数的原料制成：平平加1.5-2.5份、硬脂酸0.7-1份、白油5-6份、固色剂3-4.5份、环氧树脂681 2-3份、聚脂树脂SR-1 1-2份、水80-90份。

Description

一种纱用软化剂 技术领域
本发明涉及一种玻璃纤维网布领域，尤其涉及一种纱用软化剂。
背景技术
目前，在玻璃纤维纺织行业，生产出的玻璃纤维无碱纱和中碱纱不能替代淀粉纱、石蜡型纱，淀粉纱、石蜡型纱的抗拉力较弱，玻璃纤维无碱纱和中碱纱的使用范围较窄，玻璃纤维无碱纱和中碱纱不能与高速剑杆织机和喷气织机配套使用，不能帮助玻纤织布企业淘汰普通剑杆机从而升级转型。
发明内容
本发明所要解决的技术问题是：提供一种纱用软化剂，解决了现有玻璃纤维无碱纱和中碱纱不能替代淀粉纱、石蜡型纱，玻璃纤维无碱纱和中碱纱的使用范围较窄，玻璃纤维无碱纱和中碱纱不能与高速剑杆织机和喷气织机配套使用，不能帮助玻纤织布企业淘汰普通剑杆机从而升级转型的问题。
本发明为解决上述提出的问题所采用的技术方案是：
一种纱用软化剂，其特征在于：由以下份数的原料制成：
平平加1.5-2.5份、硬脂酸0.7-1份、白油5-6份、固色剂3-4.5份、环氧树脂6812-3份、聚脂树脂SR-11-2份、水80-90份；
其制备方法如下：
(1)平平加、硬脂酸、白油加入反应釜中加热至95-96℃保温混合30min，混合均匀得物料Ⅰ；
(2)固色剂、环氧树脂681、聚脂树脂SR-1单独加热至55-60℃，将固色剂、环氧树脂681、聚脂树脂SR-1依次加入到步骤1制得的物料Ⅰ中混合25min，混合均匀得物料Ⅱ；
(3)取10-15份水加热至95-100℃，将加热后的水加入到步骤2制得的物料Ⅱ中混合10min，混合均匀得物料Ⅲ；
(4)将剩余的水加入步骤3制得的物料Ⅲ中混合5min，混合均匀得软化剂；
所述的水为去离子水，防止水中有杂质，影响软化剂品质；
所述的步骤4中的水温为常温，降低软化剂的生产成本；
将步骤4制得的软化剂加入拉丝机上的浸润槽，拉丝炉拉出的玻璃丝经过浸润槽中的软化剂浸润后，拉出的玻璃丝经缠绕机缠绕在拉丝筒上，拉丝筒上的玻璃丝经捻线机捻成玻璃纤维线，玻璃纤维线被织机织成玻璃纤维网布。
本发明的有益效果在于：本发明选用平平加、硬脂酸、白油、固色剂、环氧树脂681、聚脂树脂SR-1、水为主要原料，选用的原材料较少，配比简单，软化剂用于玻璃纤维无碱纱和中碱纱的软化，生产的纤维纱能代替98％的淀粉纱，100％石蜡型纱，且生产的纱的抗拉力是淀粉纱和石蜡型纱的2倍，抗拉力强，使用范围广，能与高速剑杆织机和喷气织机相配套，能帮助玻纤织布企业淘汰普通剑杆机从而升级转型。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清 楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
一种纱用软化剂，其特征在于：由以下份数的原料制成：
平平加1.5份、硬脂酸0.7份、白油5份、固色剂3份、环氧树脂6812份、聚脂树脂SR-11份、水80份；
其制备方法如下：
(1)平平加、硬脂酸、白油加入反应釜中加热至95-96℃保温混合30min，混合均匀得物料Ⅰ；
(2)固色剂、环氧树脂681、聚脂树脂SR-1单独加热至55-60℃，将固色剂、环氧树脂681、聚脂树脂SR-1依次加入到步骤1制得的物料Ⅰ中混合25min，混合均匀得物料Ⅱ；
(3)取10份水加热至95-100℃，将加热后的水加入到步骤2制得的物料Ⅱ中混合10min，混合均匀得物料Ⅲ；
(4)将剩余的水加入步骤3制得的物料Ⅲ中混合5min，混合均匀得软化剂；
所述的水为去离子水，防止水中有杂质，影响软化剂品质；
所述的步骤4中的水温为常温，降低软化剂的生产成本；
将步骤4制得的软化剂加入拉丝机上的浸润槽，拉丝炉拉出的玻 璃丝经过浸润槽中的软化剂浸润后，拉出的玻璃丝经缠绕机缠绕在拉丝筒上，拉丝筒上的玻璃丝经捻线机捻成玻璃纤维线，玻璃纤维线被织机织成玻璃纤维网布。
实施例2：
一种纱用软化剂，其特征在于：由以下份数的原料制成：
平平加2份、硬脂酸0.8份、白油5.5份、固色剂4份、环氧树脂6812.5份、聚脂树脂SR-11.5份、水85份；
其制备方法如下：
(1)平平加、硬脂酸、白油加入反应釜中加热至95-96℃保温混合30min，混合均匀得物料Ⅰ；
(2)固色剂、环氧树脂681、聚脂树脂SR-1单独加热至55-60℃，将固色剂、环氧树脂681、聚脂树脂SR-1依次加入到步骤1制得的物料Ⅰ中混合25min，混合均匀得物料Ⅱ；
(3)取12份水加热至95-100℃，将加热后的水加入到步骤2制得的物料Ⅱ中混合10min，混合均匀得物料Ⅲ；
(4)将剩余的水加入步骤3制得的物料Ⅲ中混合5min，混合均匀得软化剂；
所述的水为去离子水，防止水中有杂质，影响软化剂品质；
所述的步骤4中的水温为常温，降低软化剂的生产成本；
将步骤4制得的软化剂加入拉丝机上的浸润槽，拉丝炉拉出的玻璃丝经过浸润槽中的软化剂浸润后，拉出的玻璃丝经缠绕机缠绕在拉丝筒上，拉丝筒上的玻璃丝经捻线机捻成玻璃纤维线，玻璃纤维线被 织机织成玻璃纤维网布。
实施例3：
一种纱用软化剂，其特征在于：由以下份数的原料制成：
平平加2.5份、硬脂酸1份、白油6份、固色剂4.5份、环氧树脂6813份、聚脂树脂SR-12份、水90份；
其制备方法如下：
(1)平平加、硬脂酸、白油加入反应釜中加热至95-96℃保温混合30min，混合均匀得物料Ⅰ；
(2)固色剂、环氧树脂681、聚脂树脂SR-1单独加热至55-60℃，将固色剂、环氧树脂681、聚脂树脂SR-1依次加入到步骤1制得的物料Ⅰ中混合25min，混合均匀得物料Ⅱ；
(3)取15份水加热至95-100℃，将加热后的水加入到步骤2制得的物料Ⅱ中混合10min，混合均匀得物料Ⅲ；
(4)将剩余的水加入步骤3制得的物料Ⅲ中混合5min，混合均匀得软化剂；
所述的水为去离子水，防止水中有杂质，影响软化剂品质；
所述的步骤4中的水温为常温，降低软化剂的生产成本；
将步骤4制得的软化剂加入拉丝机上的浸润槽，拉丝炉拉出的玻璃丝经过浸润槽中的软化剂浸润后，拉出的玻璃丝经缠绕机缠绕在拉丝筒上，拉丝筒上的玻璃丝经捻线机捻成玻璃纤维线，玻璃纤维线被织机织成玻璃纤维网布。
类似地，应当理解，为了精简本公开并帮助理解各个发明方面中 的一个或多个，在上面对本发明的示例性实施例的描述中，然而，并不应将该公开的方法解释成反映如下意图：即所要求保护的本发明要求比在每个权利要求中所明确记载的特征更多特征。更确切地说，如下面的权利要求书所反映的那样，发明方面在于少于前面公开的单个实施例的所有特征。因此，遵循具体实施方式的权利要求书由此明确地并入该具体实施方式，其中每个权利要求本身都作为本发明的单独实施例。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (4)

  1. 一种纱用软化剂，其特征在于：由以下份数的原料制成：
    平平加1.5-2.5份、硬脂酸0.7-1份、白油5-6份、固色剂3-4.5份、环氧树脂6812-3份、聚脂树脂SR-11-2份、水80-90份；
    其制备方法如下：
    (1)平平加、硬脂酸、白油加入反应釜中加热至95-96℃保温混合30min，混合均匀得物料Ⅰ；
    (2)固色剂、环氧树脂681、聚脂树脂SR-1单独加热至55-60℃，将固色剂、环氧树脂681、聚脂树脂SR-1依次加入到步骤1制得的物料Ⅰ中混合25min，混合均匀得物料Ⅱ；
    (3)取10-15份水加热至95-100℃，将加热后的水加入到步骤2制得的物料Ⅱ中混合10min，混合均匀得物料Ⅲ；
    (4)将剩余的水加入步骤3制得的物料Ⅲ中混合5min，混合均匀得软化剂。
  2. 如权利要求1所述的一种纱用软化剂，其特征在于：所述的水为去离子水。
  3. 如权利要求1所述的一种纱用软化剂，其特征在于：所述的步骤4中的水温为常温。
  4. 如权利要求3所述的一种纱用软化剂的制作方法，其特征在于：
    将步骤4制得的软化剂加入拉丝机上的浸润槽，拉丝炉拉出的玻璃丝经过浸润槽中的软化剂浸润后，拉出的玻璃丝经缠绕机缠绕在拉丝筒上，拉丝筒上的玻璃丝经捻线机捻成玻璃纤维线，玻璃纤维线被织机织成玻璃纤维网布。
PCT/CN2020/126813 2020-10-14 2020-11-05 一种纱用软化剂 WO2022077644A1 (zh)

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