WO2022068084A1 - Preparation method for moisture-wicking quick-drying antibacterial down-proof easy-clean fabric - Google Patents

Preparation method for moisture-wicking quick-drying antibacterial down-proof easy-clean fabric Download PDF

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Publication number
WO2022068084A1
WO2022068084A1 PCT/CN2020/136937 CN2020136937W WO2022068084A1 WO 2022068084 A1 WO2022068084 A1 WO 2022068084A1 CN 2020136937 W CN2020136937 W CN 2020136937W WO 2022068084 A1 WO2022068084 A1 WO 2022068084A1
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Prior art keywords
drying
quick
moisture
antibacterial
drilling
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PCT/CN2020/136937
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French (fr)
Chinese (zh)
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周观林
周鑫
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周观林
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Priority to PCT/CN2020/136937 priority Critical patent/WO2022068084A1/en
Publication of WO2022068084A1 publication Critical patent/WO2022068084A1/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507Polyesters

Definitions

  • the invention belongs to the technical field of textile weaving, and in particular relates to a preparation method of a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric.
  • the application number is CN201610679411.7 anti-drilling down moisture-conducting and quick-drying fabric, which is composed of an absorbing layer, a moisture-conducting layer, an antibacterial layer and an anti-ultraviolet layer. and the outer layer, a cavity is formed between the inner layer and the outer layer, and bamboo charcoal fiber particles are arranged in the cavity.
  • the back of the absorbing layer is provided with a lining fabric layer, and the lining fabric layer comprises a first fabric layer and a second fabric layer that are cross-woven, and the first fabric layer and the second fabric layer are connected to each other through the exchange of the outer and inner layers.
  • An intermediate line is formed at the layer for connecting the first fabric layer and the second fabric layer.
  • the fabric adopts double-layer knitted fabric, including outer layer and inner layer, the outer layer is hydrophilic yarn, and the inner layer is containing antibacterial substances.
  • the moisture-wicking and perspiration-wicking yarns are connected by a knitted weave structure between the outer yarns and the inner yarns.
  • the outer layer and inner layer of the double-layer knitted fabric mentioned above do not have the functions of hydrophilic and antibacterial at the same time, and the finishing process of hydrophilic and antibacterial is not described.
  • the application number is CN201710865210.0, a natural antibacterial, moisture-absorbing and quick-drying functional interwoven fabric, which prepares a moisture-absorbing and quick-drying/antibacterial composite finishing agent, and the composite finishing agent includes chemically modified ultrafine antibacterial powder UFAP and water-dispersible polyester.
  • WP using the same bath finishing technology to adsorb WP/UFAP into medical textile fabrics. It only adopts the method of hygroscopic and quick-drying finishing agent and antibacterial agent in the same bath finishing process, but it does not explain the washing resistance, air permeability, anti-drilling performance and easy decontamination performance, which cannot meet its use in hotel linen, medical The requirements for bedding and clothing inner and outer fabrics.
  • the prior art mainly imparts the functions of moisture absorption and quick drying, antibacterial, anti-drilling or easy decontamination to the fabric by changing the tissue structure of the fabric, and the disclosed technical solutions only bring the combination of the two functions.
  • the object of the present invention is to provide a preparation method of a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric, which adopts moisture-absorbing and quick-drying + antibacterial + anti-drilling + easy decontamination and the same bath finishing processing technology
  • the fabric has the functions of excellent moisture absorption and quick drying, antibacterial, anti-drilling and easy decontamination.
  • the fabric has the properties of washing resistance and breathability, and the preparation method is simple; the obtained fabric is completely safe and environmentally friendly, and does not contain any banned harmful substances, which can meet the The real situation has a comprehensive practical need for functional fabrics.
  • a preparation method of a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric comprising the following steps:
  • Soaping step After de-cooking, bleaching and mercerizing the fabric in advance, the impurities on the cloth surface, including alkali agents, hydrophilic penetrants, hydrophilic leveling agents and other impurities that may be contained, are removed through the soaping process, so as to avoid the influence of these hydrophilic impurities on the function.
  • Post-finishing affects, soaping and drying;
  • the fabrics dried in the soaping step are shaped and finished on a setting machine, dried and baked, so as to obtain moisture-absorbing, fast-drying, antibacterial, anti-drilling, and easy-to-use fabrics.
  • a working fluid containing moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling finishing agent and penetrating agent is equipped in the rolling groove of the setting machine to pad the fabric.
  • a further improvement scheme of the present invention is:
  • the preparation process of the working solution is as follows: adding a certain amount of tap water to the chemical tank for stirring, sequentially adding a moisture-absorbing and quick-drying finishing agent, an antibacterial finishing agent, an anti-drilling finishing agent, and a penetrating agent for stirring, and then adding tap water to continue stirring evenly.
  • concentration of the moisture-absorbing and quick-drying finishing agent in the working solution is 30-60g/L
  • concentration of the antibacterial finishing agent is 30-60g/L
  • the concentration of the anti-drilling finishing agent is 30-60g /L
  • the concentration of penetrant is 1-5g/L.
  • the concentration of the moisture-absorbing and quick-drying finishing agent is 38g/L, 45g/L, 50g/L, 55g/L, 58g/L
  • the concentration of the antibacterial finishing agent is 38g/L, 45g/L, 50g/L, 55g/L, 58g/L
  • the concentration of the anti-drill down finishing agent is 15g/L, 20g/L, 25g/L, 30g/L, 40g/L
  • the penetration The concentration of the agent is 1.5g/L, 2.0g/L, 2.5g/L, 3.0g/L, 4.0g/L.
  • the concentration of the soaping agent used is 0.1-2.0g/L
  • the soaping temperature is 60-90°C
  • the soaping time is 10-30min
  • an open-width continuous soap can be used. Wash or soap in the tub.
  • the cleaning time is 5-10 minutes, and the pH value of the cloth surface is adjusted to be between 6.5-7.5, and after washing, it is dried with a drum or a setting machine at 80-120°C.
  • the shaping finishing adopts the method of one dipping and one rolling or two dipping and two rolling, the speed of the shaping machine is controlled at 10 ⁇ 50m/min, the pressure of the pressing roller is controlled at 2 ⁇ 4kg, and the liquid rate of the fabric is controlled at 40 ⁇ 50m/min. 120%, the setting baking temperature is controlled at 135-180°C, and the baking time is controlled at 60-120S.
  • the drying can be done by a drum or a shaping machine.
  • the drying temperature is 80-120° C.
  • the time is 1-2 minutes
  • the vehicle speed is controlled at 10-40 m/min. .
  • the hygroscopic and quick-drying finishing agent is an ethoxylated carboxylic acid compound, such as a modified polyester compound, preferably, the hygroscopic and quick-drying finishing agent is Aquaresin SR-203C from Shanghai Zhanhe.
  • the compatibility of the agent is relatively good, and it does not contain formaldehyde and banned aromatic amines.
  • the antibacterial finishing agent is nano-silver dispersion, such as quaternary ammonium salts, special sulfur-nitrogen compounds, preferably, the antibacterial finishing agent is selected from the antibacterial agent Xian Shield 930 FLEX of Dow in the United States, and the antibacterial agent of Shanghai Zhanhe. PROTX 2WN.
  • the anti-drill down finishing agent is a cationic organosilicon special aliphatic windproof agent, a non-ionic anti-drill down auxiliary agent or a PU nano-polyurethane material, preferably, the anti-drill down finishing agent is selected from Wujiang Jintike. TK-803 of chemical industry, Baypret Nano PU of T Shanghai Tona of Wuxi Xingfeng Printing and Dyeing Auxiliary Co., Ltd.
  • the penetrant is the condensate of ethylene oxide and higher fatty alcohol, which is a non-ionic ethylene oxide penetrant, which not only has a very excellent penetration effect, but also does not affect the antibacterial and moisture absorption of the fabric.
  • the penetrant is MINEX SO from Japan's Meisei Chemicals.
  • the soaping agent selects a new type of active soaping agent, which has the characteristics of low foam, low temperature, high fastness, time saving, water saving, energy saving, emission reduction, environmental protection and the like; more importantly, it can quickly It removes various floating colors and hydrophilic substances on the fabric, and the soaping agent itself is also easy to clean. It does not contain prohibited substances specified in Oeko-Tex 100 and Reach regulations, and does not contain APEO, VOC, COD, etc., the preferred , The soaping agent is EX-961 or EX-750 of Shanghai Zhanhe Industrial Co., Ltd.
  • the fabric is all-cotton, polyester-cotton, cotton-polyester, polyester-cotton spandex blended, all-polyester or polyester/polyester (T/SP) fabric.
  • the value of ⁇ WF is also small and the value of ⁇ OF is large due to its strong interaction with water. Therefore, fibers with high hydrophilicity are easy to remove stains.
  • textiles In order to make oily stains easy to wash off in the washing process, textiles must have low ⁇ WF value and high ⁇ OF value, that is, textiles must have high hydrophilicity.
  • the present invention introduces hydrophilicity
  • the hygroscopic and quick-drying finishing agent not only solves the hygroscopic and quick-drying properties of the fabric, but also has excellent hydrophilic properties, so the easy decontamination effect of the fabric is very excellent.
  • the invention cooperates with the effects of hydrophilic, quick-drying and easy decontamination of fabrics, and selects suitable antibacterial finishing agents and anti-drilling finishing agents, which should be stable after being compounded with each other, and will not produce flocculation, demulsification, foaming, sticking and rolling, etc. Phenomenon.
  • the silver ion antibacterial agent By selecting the silver ion antibacterial agent, it destroys the metabolism of microorganisms, so it has a bactericidal effect. When the bacteria are killed, the silver ions can be freed again and contact with other colonies to carry out a new round of sterilization.
  • anti-drilling agent forms a film between the fibers, which can not only improve the anti-drilling performance of the fabric, but also effectively control the release of silver ions.
  • the present invention enables the fabric to simultaneously have the characteristics of moisture absorption and quick drying, antibacterial, anti-drilling, easy decontamination and breathability, and improves the previous single product on the market.
  • the easy decontamination function is combined with moisture-absorbing and quick-drying, antibacterial and anti-drilling down, which greatly expands the application scope of the fabric.
  • Continuous soaping of fabrics It is divided into 6 washing boxes in total.
  • the concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, respectively.
  • the soaping temperature of the first 5 The soaping time was 5min respectively.
  • the last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then the drum is dried at 100 to 120 ° C.
  • Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir.
  • Fabric continuous soaping it is divided into 6 washing boxes in total, the concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, the soaping temperature of the first 5 The soaping time is 4 minutes respectively; the last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then the drum is dried at 100 to 120 ° C.
  • Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir.
  • the fabric T/C/SP de-scouring, bleaching and mercerizing of the polyester-cotton spandex blended fabric is used, and the obtained fabric has a softer hand.
  • the specific preparation method is as follows:
  • Continuous fabric soaping it is divided into 6 washing boxes in total, the concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, the soaping temperature in the first 5 The soaping time was 5min respectively. The last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then dried with a setting machine at 100 °C.
  • Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir.
  • the 40S*40S/130*90 de-scouring and bleached fabric of all cotton is used, and the specific preparation method is as follows:
  • Continuous soaping of fabrics It is divided into 6 washing boxes in total.
  • the concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, respectively.
  • the soaping temperature of the first 5 The soaping time was 5min respectively.
  • the last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then the drum is dried at 100 to 120 ° C.
  • Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir.
  • Example 1 to Example 4 The moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics obtained from Example 1 to Example 4 are tested by a third party and wash-resistant.
  • the test results are as shown in Table 1 to Table 4.
  • the detection basis is: easy decontamination test IN house method -1013, Antibacterial Test Method: GB/T20944.2-2007 Part 2: Absorption Method, Moisture Absorption and Quick Dry Test Method: GB/T21655.1-2008, Air Permeability Test GB/T5453; Anti-drilling Down Performance Test GB/T12709 .2, washing method; hotel industry washing method; HL is the number of washing times.
  • the hygroscopic, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric provided by the preparation method of the present invention has the properties of moisture-absorbing and quick-drying, antibacterial, anti-drilling, easy to decontaminate, soft to the touch, and has a certain degree of resistance.
  • Washable and breathable; this fabric is completely environmentally friendly, meets the environmental protection requirements of ZDHC textiles and OEKO-TEX Standard 100, and does not contain any restricted substances specified in the CNTAC 8-2018 Textile Restriction List.
  • This fabric can be used in hotel linen products such as pillow cores, quilt cores, protective covers, and protective pads, as well as home textile bedding, underwear moisture-absorbing and quick-drying antibacterial fabrics, T-shirt fabrics and other related fabrics.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

A preparation method for a moisture-wicking quick-drying antibacterial down-proof easy-clean fabric, comprising the following steps: a soaping step: after pre-boiling, bleaching and mercerising of a fabric, removing impurities on the cloth surface by means of a soaping process, and drying after soaping; and a same-bath finishing processing step: setting and finishing the fabric dried in the soaping step on a setting machine, drying, and baking to thereby obtain the moisture-wicking quick-drying antibacterial down-proof easy-clean fabric; during setting, a padding tank of the setting machine is equipped with a working liquid for padding the fabric simultaneously containing a moisture-wicking quick-drying finishing agent, an antibacterial finishing agent, a down-proof finishing agent, and a penetrating agent. The preparation technique of the same-bath finishing processing enables the fabric to have excellent moisture-wicking, quick-drying, antibacterial, down-proof, and easy-clean functions; the fabric is also washable and breathable, and the preparation method is simple; the resulting fabric is safe and environmentally friendly, and does not contain any prohibited harmful substances.

Description

一种吸湿快干抗菌防钻绒易去污面料的制备方法A kind of preparation method of moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-decontamination fabrics 技术领域technical field
本发明属于纺织品织造技术领域,具体涉及一种吸湿快干抗菌防钻绒易去污面料的制备方法。The invention belongs to the technical field of textile weaving, and in particular relates to a preparation method of a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric.
背景技术Background technique
2020年国内外新冠肺炎的爆发,促使了医用行业、家纺行业、酒店布草行业、服装行业等对抗菌面料的需求量,这些面料在实际使用的过程中不仅仅需要抗菌性能,为了贴合人体的需要,需要具备一定的吸湿快干以及透气性能,才能够使人体感觉舒适;酒店、家纺产品做成羽绒枕芯、枕被后需要具有防钻绒的性能;无论是面料做成服装、家纺、汗布面料、酒店布草等,需要具有一定的易去污性能,使面料沾污后能够更加的易洗涤;所以,需研发一款同时具备吸湿快干+抗菌+防钻绒+易去污的面料,同时具备耐水洗与透气性能。The outbreak of new coronary pneumonia at home and abroad in 2020 has prompted the demand for antibacterial fabrics in the medical industry, home textile industry, hotel linen industry, clothing industry, etc. These fabrics not only need antibacterial properties in the actual use process, but also fit the human body. It is necessary to have certain moisture absorption, quick-drying and breathable properties to make the human body feel comfortable; hotels and home textile products need to have anti-drilling performance after they are made into down pillow cores and pillows; whether it is fabrics made into clothing, home textiles , jersey fabrics, hotel linens, etc., need to have a certain degree of easy decontamination, so that the fabric can be washed more easily after being stained; therefore, it is necessary to develop a product that has both moisture absorption and quick drying + antibacterial + anti-drilling + easy to remove Stain-resistant fabric, washable and breathable at the same time.
申请号为CN201610679411.7防钻绒导湿快干面料,其是通过吸收层、导湿层、抗菌层与抗紫外层复合而成,传导层形成一个个透气的小孔,抗菌层包括里层和外层,里层和外层之间形成空腔,空腔内设置竹炭纤维颗粒。所述吸收层背面设置有衬里织物层,该衬里织物层包括交叉织造的第一织物层和第二织物层,第一织物层和第二织物层通过表里换层相互接结,表里换层处形成用以连接第一织物层和第二织物层的间线。其发明专利没有说明具体的抗菌与导湿快干的具体整理工艺,也没有说明面料的透气与易去污效果。The application number is CN201610679411.7 anti-drilling down moisture-conducting and quick-drying fabric, which is composed of an absorbing layer, a moisture-conducting layer, an antibacterial layer and an anti-ultraviolet layer. and the outer layer, a cavity is formed between the inner layer and the outer layer, and bamboo charcoal fiber particles are arranged in the cavity. The back of the absorbing layer is provided with a lining fabric layer, and the lining fabric layer comprises a first fabric layer and a second fabric layer that are cross-woven, and the first fabric layer and the second fabric layer are connected to each other through the exchange of the outer and inner layers. An intermediate line is formed at the layer for connecting the first fabric layer and the second fabric layer. Its invention patent does not describe the specific finishing process of specific antibacterial and moisture-conducting and quick-drying, nor does it explain the air permeability and easy decontamination effect of the fabric.
申请号为CN103120398A可拆装领子的的吸湿快干和抗菌的短袖,所述织物采用双层针织织物,包括外层和内层,外层为亲水性纱线,内层为含有抗菌物质的导湿排汗纱线,外层纱线和内层纱线之间通过针织编织结构连接。其所述的双层针织织物采用的外层与内层,而不同时具有亲水与抗菌的功能,也没有说明亲水与抗菌的整理工艺。Application No. CN103120398A Moisture-absorbing, quick-drying and antibacterial short-sleeves with detachable collar, the fabric adopts double-layer knitted fabric, including outer layer and inner layer, the outer layer is hydrophilic yarn, and the inner layer is containing antibacterial substances. The moisture-wicking and perspiration-wicking yarns are connected by a knitted weave structure between the outer yarns and the inner yarns. The outer layer and inner layer of the double-layer knitted fabric mentioned above do not have the functions of hydrophilic and antibacterial at the same time, and the finishing process of hydrophilic and antibacterial is not described.
申请号为CN201710865210.0一种天然抗菌吸湿快干功能性交织面料,其制备出吸湿快干/抗菌复合整理剂,所述的复合整理剂包括化学修饰超细抗菌粉UFAP和水分散性聚酯WP;采用同浴整理技术,将WP/UFAP吸附到医用纺织 面料中。其只采用了吸湿快干整理剂与抗菌剂同浴整理加工的方式,但是其没有说明耐水洗性能,透气性能,防钻绒性能以及易去污性能,无法满足其用于酒店布草,医用床品以及服装内外衣面料的服用要求。The application number is CN201710865210.0, a natural antibacterial, moisture-absorbing and quick-drying functional interwoven fabric, which prepares a moisture-absorbing and quick-drying/antibacterial composite finishing agent, and the composite finishing agent includes chemically modified ultrafine antibacterial powder UFAP and water-dispersible polyester. WP; using the same bath finishing technology to adsorb WP/UFAP into medical textile fabrics. It only adopts the method of hygroscopic and quick-drying finishing agent and antibacterial agent in the same bath finishing process, but it does not explain the washing resistance, air permeability, anti-drilling performance and easy decontamination performance, which cannot meet its use in hotel linen, medical The requirements for bedding and clothing inner and outer fabrics.
现有技术主要通过对织物的组织结构的改变来赋予布料的吸湿快干、抗菌、防钻绒或者易去污的功能,而且公开的技术方案也只是带来两种功能的结合。The prior art mainly imparts the functions of moisture absorption and quick drying, antibacterial, anti-drilling or easy decontamination to the fabric by changing the tissue structure of the fabric, and the disclosed technical solutions only bring the combination of the two functions.
发明内容SUMMARY OF THE INVENTION
针对现有技术的不足,本发明的目的在于提供一种吸湿快干抗菌防钻绒易去污面料的制备方法,采用吸湿快干+抗菌+防钻绒+易去污同浴整理加工制备技术使布料同时具备优异的吸湿快干、抗菌、防钻绒以及易去污的功能,同时面料具备耐水洗与透气性能,制备方法简单;所得织物完全安全环保,不含任何禁用有害物质,可满足现实情况对功能面料的全面的实际需要。In view of the deficiencies of the prior art, the object of the present invention is to provide a preparation method of a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric, which adopts moisture-absorbing and quick-drying + antibacterial + anti-drilling + easy decontamination and the same bath finishing processing technology At the same time, the fabric has the functions of excellent moisture absorption and quick drying, antibacterial, anti-drilling and easy decontamination. At the same time, the fabric has the properties of washing resistance and breathability, and the preparation method is simple; the obtained fabric is completely safe and environmentally friendly, and does not contain any banned harmful substances, which can meet the The real situation has a comprehensive practical need for functional fabrics.
本发明是通过以下技术方案实现的:The present invention is achieved through the following technical solutions:
一种吸湿快干抗菌防钻绒易去污面料的制备方法,包括以下步骤:A preparation method of a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric, comprising the following steps:
皂洗步骤:将织物预先退煮漂丝光后,通过皂洗工艺去除布面上的杂质,可能含有的碱剂、亲水渗透剂、亲水匀染剂等杂质,避免这些亲水杂质对功能后整理造成影响,皂洗后烘干;Soaping step: After de-cooking, bleaching and mercerizing the fabric in advance, the impurities on the cloth surface, including alkali agents, hydrophilic penetrants, hydrophilic leveling agents and other impurities that may be contained, are removed through the soaping process, so as to avoid the influence of these hydrophilic impurities on the function. Post-finishing affects, soaping and drying;
吸湿快干+抗菌+防钻绒+易去污同浴整理加工步骤:将皂洗步骤烘干后的面料在定型机上定型整理、烘干焙烘整理,从而得到吸湿快干抗菌防钻绒易去污面料,定型时,定型机轧槽内配置了同时含有吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂的工作液对面料进行浸轧。Moisture-absorbing and quick-drying + antibacterial + anti-drilling + easy decontamination in the same bath finishing processing steps: the fabrics dried in the soaping step are shaped and finished on a setting machine, dried and baked, so as to obtain moisture-absorbing, fast-drying, antibacterial, anti-drilling, and easy-to-use fabrics. For decontamination fabrics, when setting, a working fluid containing moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling finishing agent and penetrating agent is equipped in the rolling groove of the setting machine to pad the fabric.
本发明的进一步改进方案为:A further improvement scheme of the present invention is:
所述工作液的制备过程为:化料槽内添加一定量的自来水搅拌,依次添加吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂搅拌,后再添加自来水继续搅拌均匀,以配制相应浓度的工作液;所述工作液中吸湿快干整理剂的浓度为30-60g/L,抗菌整理剂的浓度为30-60g/L,防钻绒整理剂的浓度为30-60g/L,渗透剂的浓度为1~5g/L。The preparation process of the working solution is as follows: adding a certain amount of tap water to the chemical tank for stirring, sequentially adding a moisture-absorbing and quick-drying finishing agent, an antibacterial finishing agent, an anti-drilling finishing agent, and a penetrating agent for stirring, and then adding tap water to continue stirring evenly. To prepare a working solution of corresponding concentration; the concentration of the moisture-absorbing and quick-drying finishing agent in the working solution is 30-60g/L, the concentration of the antibacterial finishing agent is 30-60g/L, and the concentration of the anti-drilling finishing agent is 30-60g /L, the concentration of penetrant is 1-5g/L.
进一步的,工作液中,所述吸湿快干整理剂的浓度为38g/L、45g/L、50g/L、 55g/L、58g/L,所述抗菌整理剂的的浓度为38g/L、45g/L、50g/L、55g/L、58g/L,所述防钻绒整理剂的的浓度为15g/L、20g/L、25g/L、30g/L、40g/L,所述渗透剂的的浓度为1.5g/L、2.0g/L、2.5g/L、3.0g/L、4.0g/L。Further, in the working solution, the concentration of the moisture-absorbing and quick-drying finishing agent is 38g/L, 45g/L, 50g/L, 55g/L, 58g/L, and the concentration of the antibacterial finishing agent is 38g/L, 45g/L, 50g/L, 55g/L, 58g/L, the concentration of the anti-drill down finishing agent is 15g/L, 20g/L, 25g/L, 30g/L, 40g/L, the penetration The concentration of the agent is 1.5g/L, 2.0g/L, 2.5g/L, 3.0g/L, 4.0g/L.
进一步的,所述的皂洗步骤中,所用的皂洗剂的浓度为0.1~2.0g/L,皂洗温度为60~90℃,皂洗时间为10~30min,可采用平幅连续式皂洗或进缸皂洗。Further, in the soaping step, the concentration of the soaping agent used is 0.1-2.0g/L, the soaping temperature is 60-90°C, and the soaping time is 10-30min, and an open-width continuous soap can be used. Wash or soap in the tub.
进一步的,所述的皂洗工艺后,需要清水冲洗,清洗时间为5~10min,并调节布面pH值为6.5~7.5之间,水洗后在80~120℃采用滚筒或者定型机烘干。Further, after the soaping process, it needs to be rinsed with clean water, the cleaning time is 5-10 minutes, and the pH value of the cloth surface is adjusted to be between 6.5-7.5, and after washing, it is dried with a drum or a setting machine at 80-120°C.
进一步的,所述定型整理采用一浸一轧或二浸二轧的方式,定型机的车速控制在10~50m/min,压辊的压力控制在2~4kg,织物带液率控制在40~120%,定型焙烘温度控制在135~180℃,焙烘时间控制在60~120S。Further, the shaping finishing adopts the method of one dipping and one rolling or two dipping and two rolling, the speed of the shaping machine is controlled at 10~50m/min, the pressure of the pressing roller is controlled at 2~4kg, and the liquid rate of the fabric is controlled at 40~50m/min. 120%, the setting baking temperature is controlled at 135-180°C, and the baking time is controlled at 60-120S.
进一步的,所述定型整理后需要先烘干再焙烘,烘干可采用滚筒或者定型机的烘干方式,烘干温度80~120℃,时间1~2min,车速控制在10~40m/min。Further, after the shaping and finishing, it needs to be dried first and then baked. The drying can be done by a drum or a shaping machine. The drying temperature is 80-120° C., the time is 1-2 minutes, and the vehicle speed is controlled at 10-40 m/min. .
进一步的,所述吸湿快干整理剂为乙氧基化羧酸化合物,如改性的聚酯化合物,优选的,吸湿快干整理剂选用上海湛和的Aquaresin SR-203C,其与各种助剂的相容性比较好,且完全不含有甲醛以及禁用芳香胺等物质。Further, the hygroscopic and quick-drying finishing agent is an ethoxylated carboxylic acid compound, such as a modified polyester compound, preferably, the hygroscopic and quick-drying finishing agent is Aquaresin SR-203C from Shanghai Zhanhe. The compatibility of the agent is relatively good, and it does not contain formaldehyde and banned aromatic amines.
进一步的,所述抗菌整理剂为纳米银分散液,如季铵盐类、特殊硫氮化合物类,优选的,抗菌整理剂选用美国陶氏的抗菌剂仙护盾930 FLEX,上海湛和的抗菌PROTX 2WN。Further, the antibacterial finishing agent is nano-silver dispersion, such as quaternary ammonium salts, special sulfur-nitrogen compounds, preferably, the antibacterial finishing agent is selected from the antibacterial agent Xian Shield 930 FLEX of Dow in the United States, and the antibacterial agent of Shanghai Zhanhe. PROTX 2WN.
进一步的,所述防钻绒整理剂为阳离子的有机硅特殊脂肪族类防风剂、非离子的防钻绒助剂或PU纳米的聚氨酯类物质,优选的,防钻绒整理剂选用吴江金泰克化工的TK-803、无锡兴峰印染助剂有限公司的T上海托纳的Baypret Nano PU。Further, the anti-drill down finishing agent is a cationic organosilicon special aliphatic windproof agent, a non-ionic anti-drill down auxiliary agent or a PU nano-polyurethane material, preferably, the anti-drill down finishing agent is selected from Wujiang Jintike. TK-803 of chemical industry, Baypret Nano PU of T Shanghai Tona of Wuxi Xingfeng Printing and Dyeing Auxiliary Co., Ltd.
进一步的,所述渗透剂为环氧乙烷和高级脂肪醇的缩合物,为非离子的环氧乙烷类渗透剂,其不仅有十分优异的渗透效果,且不会影响面料的抗菌以及吸湿快干的效果,优选的,渗透剂选用日本明成化学的MINEX SO。Further, the penetrant is the condensate of ethylene oxide and higher fatty alcohol, which is a non-ionic ethylene oxide penetrant, which not only has a very excellent penetration effect, but also does not affect the antibacterial and moisture absorption of the fabric. For quick-drying effect, preferably, the penetrant is MINEX SO from Japan's Meisei Chemicals.
进一步的,所述皂洗剂选用一种新型活性皂洗剂,其具有低泡、低温、高牢度、省时、省水、节能、减排、环保等特点;更重要的是其能够快速的去除 织物上存在的各种浮色以及亲水物质,皂洗剂本身也易清洗,其不含有Oeko-Tex 100、Reach法规中规定的禁用物质,且无APEO、VOC、COD等,优选的,皂洗剂选用上海湛和实业有限公司的EX-961或EX-750。Further, the soaping agent selects a new type of active soaping agent, which has the characteristics of low foam, low temperature, high fastness, time saving, water saving, energy saving, emission reduction, environmental protection and the like; more importantly, it can quickly It removes various floating colors and hydrophilic substances on the fabric, and the soaping agent itself is also easy to clean. It does not contain prohibited substances specified in Oeko-Tex 100 and Reach regulations, and does not contain APEO, VOC, COD, etc., the preferred , The soaping agent is EX-961 or EX-750 of Shanghai Zhanhe Industrial Co., Ltd.
进一步的,所述织物为全棉、涤棉、棉涤、涤棉氨纶混纺、全涤或涤氨(T/SP)面料。Further, the fabric is all-cotton, polyester-cotton, cotton-polyester, polyester-cotton spandex blended, all-polyester or polyester/polyester (T/SP) fabric.
本发明的有益效果为:The beneficial effects of the present invention are:
在洗涤过程中,除了诸如洗涤液的组成和洗涤条件之类的因素之外,面料表面的污物是否容易去掉,主要取决于织物的表面性质。污染的织物在洗涤液中,污垢与洗涤液和织物处于平衡状态:当平衡时,界面张力之间存在以下关系;γWF=γOF+γOWcosθ。γOF值应尽可能大,γWF和γOW应尽可能小。γOW的小值意味着从织物上分离的小油滴可以稳定地悬浮并分散在水中。γOW的大小由洗涤剂的类型和浓度决定,并且通常其值很小。对于极性纤维,由于其与水的强相互作用,γWF的值也很小,γOF的值很大。因此,具有高亲水性的纤维易于去污,为了使油性污渍在洗涤过程中易于洗掉,纺织品必须具有低γWF值和高γOF值,即纺织品必须具有高亲水性,本发明引入亲水吸湿快干整理剂不仅解决了面料的吸湿快干性能,同时面料具有十分优异的亲水性能,所以面料的易去污效果十分的优异。In the washing process, in addition to factors such as the composition of the washing liquid and the washing conditions, whether the dirt on the surface of the fabric is easy to remove mainly depends on the surface properties of the fabric. The soiled fabric is in the washing liquid, and the soil is in equilibrium with the washing liquid and the fabric: When in equilibrium, there is the following relationship between the interfacial tension; γWF=γOF+γOWcosθ. The value of γOF should be as large as possible, and γWF and γOW should be as small as possible. The small value of γOW means that the small oil droplets separated from the fabric can be stably suspended and dispersed in water. The magnitude of γOW is determined by the type and concentration of detergent and is usually small. For polar fibers, the value of γWF is also small and the value of γOF is large due to its strong interaction with water. Therefore, fibers with high hydrophilicity are easy to remove stains. In order to make oily stains easy to wash off in the washing process, textiles must have low γWF value and high γOF value, that is, textiles must have high hydrophilicity. The present invention introduces hydrophilicity The hygroscopic and quick-drying finishing agent not only solves the hygroscopic and quick-drying properties of the fabric, but also has excellent hydrophilic properties, so the easy decontamination effect of the fabric is very excellent.
本发明配合面料的亲水快干以及易去污的效果,筛选合适的抗菌整理剂与防钻绒整理剂,其相互复配后要稳定,不产生絮凝、破乳、起泡、粘滚等现象。通过选用银离子抗菌剂,其破坏了微生物的新陈代谢,从而具有杀菌作用,当菌体被杀灭后,银离子又可以游离出来,与其它菌落接触,进行新一轮的杀菌,配合防钻绒剂的使用,防钻绒剂在纤维之间成膜,不仅可以提高面料的防钻绒性能,也可以有效的控制银离子的释放。The invention cooperates with the effects of hydrophilic, quick-drying and easy decontamination of fabrics, and selects suitable antibacterial finishing agents and anti-drilling finishing agents, which should be stable after being compounded with each other, and will not produce flocculation, demulsification, foaming, sticking and rolling, etc. Phenomenon. By selecting the silver ion antibacterial agent, it destroys the metabolism of microorganisms, so it has a bactericidal effect. When the bacteria are killed, the silver ions can be freed again and contact with other colonies to carry out a new round of sterilization. The use of anti-drilling agent, the anti-drilling agent forms a film between the fibers, which can not only improve the anti-drilling performance of the fabric, but also effectively control the release of silver ions.
本发明通过采用吸湿快干+抗菌+防钻绒+易去污同浴整理,使面料同时具有吸湿快干、抗菌、防钻绒、易去污以及透气的特点,改善了以往市面上单一的吸湿快干+抗菌面料的或者吸湿快干+抗菌+防钻绒面料的缺陷,首次将易去污功能与吸湿快干、抗菌以及防钻绒同时结合,大大扩宽了布料的适用范围。By adopting moisture-absorbing and quick-drying + antibacterial + anti-drilling + easy decontamination and co-bath finishing, the present invention enables the fabric to simultaneously have the characteristics of moisture absorption and quick drying, antibacterial, anti-drilling, easy decontamination and breathability, and improves the previous single product on the market. For the defects of moisture-absorbing and quick-drying + antibacterial fabrics or moisture-absorbing and quick-drying + antibacterial + anti-drilling fabrics, for the first time, the easy decontamination function is combined with moisture-absorbing and quick-drying, antibacterial and anti-drilling down, which greatly expands the application scope of the fabric.
具体实施方式Detailed ways
实施例1Example 1
采用全棉的40S*40S/130*98退煮漂后的织物,所制得的面料具有较柔软的手感,其具体的制备方法如下:Using the 40S*40S/130*98 de-cooked and bleached fabric of all cotton, the obtained fabric has a softer hand. The specific preparation method is as follows:
织物连续式皂洗:一共分为6节水洗箱,前5节所用的皂洗剂EX-961的浓度分别为0.2g/L,前5节的皂洗温度分别为85℃,前5节的皂洗时间分别为5min。最后一节清水冲洗,清洗时间为5min,并调节布面pH值为6.5~7.5之间,后采用100~120℃的滚筒烘干。Continuous soaping of fabrics: It is divided into 6 washing boxes in total. The concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, respectively. The soaping temperature of the first 5 The soaping time was 5min respectively. The last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then the drum is dried at 100 to 120 ° C.
吸湿快干防钻绒易去污整理步骤,配置工作液:化料槽内添加一定量的自来水搅拌,依次添加吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂搅拌,后再添加自来水继续搅拌均匀,以配制相应浓度的工作液,其中,吸湿快干整理剂203C 40g/L、抗菌整理剂930 FLEX 60g/L、非离子防钻绒整理剂T 40g/L、渗透剂SO 1g/L,将工作液配置到定型机轧槽内,将皂洗烘干后的面料在定型机上一浸一轧定型加工,带液率65.0%,120℃滚筒烘干,后165℃定型机焙烘45-60S,得到吸湿快干抗菌防钻绒易去污面料。Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps, configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir. Then add tap water and continue to stir evenly to prepare working solution of corresponding concentration, among which, moisture-absorbing and quick-drying finishing agent 203C 40g/L, antibacterial finishing agent 930 FLEX 60g/L, non-ionic anti-drilling finishing agent T 40g/L, penetrant SO 1g/L, put the working liquid into the rolling groove of the setting machine, soak the fabric after soaping and drying on the setting machine, then dipping and rolling for setting processing, with a liquid rate of 65.0%, tumble drying at 120 °C, and then set at 165 °C Machine-baked for 45-60S to obtain moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics.
实施例2Example 2
采用全棉的40S*40S/110*90退煮漂丝光后的织物,所制得的面料具有较柔软的手感,其具体的制备方法如下:Using the 40S*40S/110*90 de-cooked, bleached and mercerized fabric of all cotton, the obtained fabric has a softer hand. The specific preparation method is as follows:
织物连续式皂洗:一共分为6节水洗箱,前5节所用的皂洗剂EX-961的浓度分别为0.2g/L,前5节的皂洗温度分别为80℃,前5节的皂洗时间分别为4min;最后一节清水冲洗,清洗时间为5min,并调节布面pH值为6.5~7.5之间,后采用100~120℃的滚筒烘干。Fabric continuous soaping: it is divided into 6 washing boxes in total, the concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, the soaping temperature of the first 5 The soaping time is 4 minutes respectively; the last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then the drum is dried at 100 to 120 ° C.
吸湿快干防钻绒易去污整理步骤,配置工作液:化料槽内添加一定量的自来水搅拌,依次添加吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂搅拌,后再添加自来水继续搅拌均匀,以配制相应浓度的工作液,其中,吸湿快干整理剂203C 35g/L、抗菌整理剂PROTX 2WN 50g/L、非离子防钻绒整理剂T 40g/L、渗透剂SO 1g/L,将工作液配置到定型机轧槽内,将皂洗烘干后的面料 在定型机上一浸一轧定型加工,带液率65.0%,120℃滚筒烘干,后165℃定型机焙烘45-60S,得到吸湿快干抗菌防钻绒易去污面料。Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps, configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir. Then add tap water and continue to stir evenly to prepare working solution of corresponding concentration, among which, moisture-absorbing and quick-drying finishing agent 203C 35g/L, antibacterial finishing agent PROTX 2WN 50g/L, non-ionic anti-drilling finishing agent T 40g/L, penetrating agent SO 1g/L, put the working liquid into the rolling groove of the setting machine, soak the fabric after soaping and drying on the setting machine, then dipping and rolling for setting processing, with a liquid rate of 65.0%, tumble drying at 120 °C, and then set at 165 °C Machine-baked for 45-60S to obtain moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics.
实施例3Example 3
采用涤棉氨纶混纺的织物T/C/SP退煮漂丝光后的织物,所制得的面料具有较柔软的手感,其具体的制备方法如下:The fabric T/C/SP de-scouring, bleaching and mercerizing of the polyester-cotton spandex blended fabric is used, and the obtained fabric has a softer hand. The specific preparation method is as follows:
织物连续式皂洗:一共分为6节水洗箱,前5节所用的皂洗剂EX-961的浓度分别为0.2g/L,前5节的皂洗温度分别为65℃,前5节的皂洗时间分别为5min。最后一节清水冲洗,清洗时间为5min,并调节布面pH值为6.5~7.5之间,后采用100℃的定型机烘干。Continuous fabric soaping: it is divided into 6 washing boxes in total, the concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, the soaping temperature in the first 5 The soaping time was 5min respectively. The last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then dried with a setting machine at 100 °C.
吸湿快干防钻绒易去污整理步骤,配置工作液:化料槽内添加一定量的自来水搅拌,依次添加吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂搅拌,后再添加自来水继续搅拌均匀,以配制相应浓度的工作液,其中,吸湿快干整理剂203C 50g/L、抗菌整理剂930 FLEX 50g/L、非离子防钻绒整理剂T 40g/L、渗透剂SO 1g/L,将工作液配置到定型机轧槽内,将皂洗烘干后的面料在定型机上一浸一轧定型加工,带液率65.0%,120℃滚筒烘干,后165℃定型机焙烘45-60S,得到吸湿快干抗菌防钻绒易去污面料。Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps, configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir. Then add tap water and continue to stir evenly to prepare working solution of corresponding concentration, among which, moisture-absorbing and quick-drying finishing agent 203C 50g/L, antibacterial finishing agent 930 FLEX 50g/L, non-ionic anti-drilling finishing agent T 40g/L, penetrant SO 1g/L, put the working liquid into the rolling groove of the setting machine, soak the fabric after soaping and drying on the setting machine, then dipping and rolling for setting processing, with a liquid rate of 65.0%, tumble drying at 120 °C, and then set at 165 °C Machine-baked for 45-60S to obtain moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics.
实施例4Example 4
采用全棉的40S*40S/130*90退煮漂后的织物,其具体的制备方法如下:The 40S*40S/130*90 de-scouring and bleached fabric of all cotton is used, and the specific preparation method is as follows:
织物连续式皂洗:一共分为6节水洗箱,前5节所用的皂洗剂EX-961的浓度分别为0.2g/L,前5节的皂洗温度分别为85℃,前5节的皂洗时间分别为5min。最后一节清水冲洗,清洗时间为5min,并调节布面pH值为6.5~7.5之间,后采用100~120℃的滚筒烘干。Continuous soaping of fabrics: It is divided into 6 washing boxes in total. The concentration of soaping agent EX-961 used in the first 5 sections is 0.2g/L, respectively. The soaping temperature of the first 5 The soaping time was 5min respectively. The last section is rinsed with clean water, the cleaning time is 5 minutes, and the pH value of the cloth surface is adjusted to be between 6.5 and 7.5, and then the drum is dried at 100 to 120 ° C.
吸湿快干防钻绒易去污整理步骤,配置工作液:化料槽内添加一定量的自来水搅拌,依次添加吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂搅拌,后再添加自来水继续搅拌均匀,以配制相应浓度的工作液,其中,吸湿快干整理剂203C 30g/L、抗菌整理剂PROTX 2WN 30g/L、非离子防钻绒整理剂T 40g/L、渗透剂SO 1g/L,将工作液配置到定型机轧槽内,将皂洗烘干后的面料 在定型机上一浸一轧定型加工,带液率65.0%,120℃滚筒烘干,后165℃定型机焙烘45-60S,得到吸湿快干抗菌防钻绒易去污面料。Moisture-absorbing, quick-drying, anti-drilling down, easy-to-decontaminate finishing steps, configure working fluid: add a certain amount of tap water to the chemical tank and stir, add moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling down finishing agent, and penetrant in sequence, and then stir. Then add tap water and continue to stir evenly to prepare the working solution of corresponding concentration, among which, hygroscopic and quick-drying finishing agent 203C 30g/L, antibacterial finishing agent PROTX 2WN 30g/L, non-ionic anti-drilling finishing agent T 40g/L, penetrant SO 1g/L, put the working liquid into the rolling groove of the setting machine, soak the fabric after soaping and drying on the setting machine, then dipping and rolling for setting processing, with a liquid rate of 65.0%, tumble drying at 120 °C, and then set at 165 °C Machine-baked for 45-60S to obtain moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics.
性能检测Performance testing
实施例1至实施例4所得的吸湿快干抗菌防钻绒易去污面料经第三方检测以及耐水洗测试,测试结果如表1~表4所示,检测依据:易去污测试IN house method-1013,抗菌检测方法:GB/T20944.2-2007第2部分:吸收法,吸湿快干检测方法:GB/T21655.1-2008,透气性能测试GB/T5453;防钻绒性能测试GB/T12709.2,水洗方法;酒店工业洗涤方法;HL为水洗次数。The moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics obtained from Example 1 to Example 4 are tested by a third party and wash-resistant. The test results are as shown in Table 1 to Table 4. The detection basis is: easy decontamination test IN house method -1013, Antibacterial Test Method: GB/T20944.2-2007 Part 2: Absorption Method, Moisture Absorption and Quick Dry Test Method: GB/T21655.1-2008, Air Permeability Test GB/T5453; Anti-drilling Down Performance Test GB/T12709 .2, washing method; hotel industry washing method; HL is the number of washing times.
表1实施例1所得的吸湿快干抗菌防钻绒易去污面料性能The performance of the moisture-absorbing, quick-drying, anti-drilling, anti-drilling, and easy-to-decontaminate fabrics obtained in Table 1 Example 1
Figure PCTCN2020136937-appb-000001
Figure PCTCN2020136937-appb-000001
表2实施例2所得的吸湿快干抗菌防钻绒易去污面料性能The performance of the moisture-absorbing, quick-drying, anti-drilling, anti-drilling, and easy-to-decontaminate fabrics obtained in table 2 Example 2
Figure PCTCN2020136937-appb-000002
Figure PCTCN2020136937-appb-000002
表3实施例3所得的吸湿快干抗菌防钻绒易去污面料性能The performance of the moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics obtained in table 3 Example 3
Figure PCTCN2020136937-appb-000003
Figure PCTCN2020136937-appb-000003
表4实施例4所得的吸湿快干抗菌防钻绒易去污面料性能The performance of the moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics obtained in table 4 Example 4
Figure PCTCN2020136937-appb-000004
Figure PCTCN2020136937-appb-000004
由表1~表4可知,本发明的制备方法提供的吸湿快干抗菌防钻绒易去污面料同时具有吸湿快干、抗菌、防钻绒、易去污,且手感柔软,具有一定的耐水洗及透气性能;此面料完全环保,符合ZDHC纺织品以及OEKO-TEX Standard 100环保要求,完全不含有CNTAC 8-2018纺织品限用清单中规定的限用物质。此面料可用于酒店布草类产品如:枕芯、被芯、保护套、保护垫,也可以用于家纺类的床品,内衣的吸湿快干抗菌面料,T恤面料以及其它相关面料。As can be seen from Tables 1 to 4, the hygroscopic, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric provided by the preparation method of the present invention has the properties of moisture-absorbing and quick-drying, antibacterial, anti-drilling, easy to decontaminate, soft to the touch, and has a certain degree of resistance. Washable and breathable; this fabric is completely environmentally friendly, meets the environmental protection requirements of ZDHC textiles and OEKO-TEX Standard 100, and does not contain any restricted substances specified in the CNTAC 8-2018 Textile Restriction List. This fabric can be used in hotel linen products such as pillow cores, quilt cores, protective covers, and protective pads, as well as home textile bedding, underwear moisture-absorbing and quick-drying antibacterial fabrics, T-shirt fabrics and other related fabrics.

Claims (10)

  1. 一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于,包括以下步骤:A preparation method for moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabrics, characterized in that it comprises the following steps:
    皂洗步骤:将织物预先退煮漂丝光后,通过皂洗工艺去除布面上的杂质,皂洗后烘干;Soaping step: after de-cooking, bleaching and mercerizing the fabric in advance, the impurities on the cloth surface are removed by the soaping process, and then dried after soaping;
    吸湿快干+抗菌+防钻绒+易去污同浴整理加工步骤:将皂洗步骤烘干后的面料在定型机上定型整理、烘干焙烘整理,从而得到吸湿快干抗菌防钻绒易去污面料,定型时,定型机轧槽内配置了同时含有吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂的工作液对面料进行浸轧。Moisture-absorbing and quick-drying + antibacterial + anti-drilling + easy decontamination in the same bath finishing processing steps: the fabrics dried in the soaping step are shaped and finished on a setting machine, dried and baked, so as to obtain moisture-absorbing, fast-drying, antibacterial, anti-drilling, and easy-to-use fabrics. For decontamination fabrics, when setting, a working fluid containing moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling finishing agent and penetrating agent is equipped in the rolling groove of the setting machine to pad the fabric.
  2. 根据权利要求1所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述工作液的制备过程为:化料槽内添加一定量的自来水搅拌,依次添加吸湿快干整理剂、抗菌整理剂、防钻绒整理剂、渗透剂搅拌,后再添加自来水继续搅拌均匀,以配制相应浓度的工作液;所述工作液中吸湿快干整理剂的浓度为30-60g/L,抗菌整理剂的浓度为30-60g/L,防钻绒整理剂的浓度为30-60g/L,渗透剂的浓度为1~5g/L。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to claim 1, wherein the preparation process of the working solution is as follows: adding a certain amount of tap water in the chemical tank to stir, and then adding Moisture-absorbing and quick-drying finishing agent, antibacterial finishing agent, anti-drilling finishing agent, and penetrating agent are stirred, and then tap water is added to continue stirring to prepare a working solution of corresponding concentration; the concentration of the moisture-absorbing and quick-drying finishing agent in the working solution is 30 -60g/L, the concentration of antibacterial finishing agent is 30-60g/L, the concentration of anti-drilling finishing agent is 30-60g/L, and the concentration of penetrant is 1-5g/L.
  3. 根据权利1所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述的皂洗步骤中,所用的皂洗剂的浓度为0.1~2.0g/L,皂洗温度为60~90℃,皂洗时间为10~30min,可采用平幅连续式皂洗或进缸皂洗。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling and easy-to-decontaminate fabric according to claim 1, characterized in that: in the soaping step, the concentration of the soaping agent used is 0.1-2.0 g/L, The soaping temperature is 60~90℃, and the soaping time is 10~30min. Open width continuous soaping or tank soaping can be used.
  4. 根据权利1或3任意一项所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述的皂洗工艺后,需要清水冲洗,清洗时间为5~10min,并调节布面pH值为6.5~7.5之间,水洗后在80~120℃采用滚筒或者定型机烘干。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to any one of claims 1 and 3, characterized in that: after the soaping process, it needs to be rinsed with clean water, and the cleaning time is 5 to 10 minutes. , and adjust the pH value of the cloth surface to be between 6.5 and 7.5. After washing, use a drum or a setting machine to dry at 80 to 120 ° C.
  5. 根据权利1所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述定型整理采用一浸一轧或二浸二轧的方式,定型机的车速控制在10~50m/min,压辊的压力控制在2~4kg,织物带液率控制在40~120%,定型焙 烘温度控制在135~180℃,焙烘时间控制在60~120S。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to claim 1, characterized in that: the shaping and finishing adopts a method of one dip and one rolling or two dips and two rollings, and the speed of the shaping machine is controlled at 10~50m/min, the pressure of the pressing roller is controlled at 2~4kg, the liquid rate of the fabric is controlled at 40~120%, the setting baking temperature is controlled at 135~180℃, and the baking time is controlled at 60~120S.
  6. 根据权利1所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述定型整理后需要先烘干再焙烘,烘干可采用滚筒或者定型机的烘干方式,烘干温度80~120℃,时间1~2min,车速控制在10~40m/min。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to claim 1, characterized in that: after the shaping and finishing, it needs to be dried first and then baked. Drying method, drying temperature is 80~120℃, time is 1~2min, and vehicle speed is controlled at 10~40m/min.
  7. 根据权利1所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述吸湿快干整理剂为乙氧基化羧酸化合物,抗菌整理剂为纳米银分散液,防钻绒整理剂为阳离子的有机硅特殊脂肪族类防风剂、非离子的防钻绒助剂或PU纳米的聚氨酯类物质,渗透剂为环氧乙烷和高级脂肪醇的缩合物。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling and easy-to-decontaminate fabric according to claim 1, wherein the moisture-absorbing and quick-drying finishing agent is an ethoxylated carboxylic acid compound, and the antibacterial finishing agent is a nano-silver dispersion Liquid, anti-drilling finishing agent is cationic silicone special aliphatic windproof agent, non-ionic anti-drilling agent or PU nano-polyurethane material, penetrant is the condensate of ethylene oxide and higher aliphatic alcohol.
  8. 根据权利3所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述皂洗剂为EX-961或EX-750。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to claim 3, wherein the soaping agent is EX-961 or EX-750.
  9. 根据权利7所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述吸湿快干整理剂为Aquaresin SR-203C,所述抗菌整理剂为仙护盾930 FLEX或PROTX 2WN,所述防钻绒整理剂为TK-803、非离子防钻绒助剂T或Baypret Nano PU,所述渗透剂为MINEX SO。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to claim 7, wherein the moisture-absorbing and quick-drying finishing agent is Aquaresin SR-203C, and the antibacterial finishing agent is Xianguardian 930 FLEX or PROTX 2WN, the anti-drilling finishing agent is TK-803, non-ionic anti-drilling agent T or Baypret Nano PU, and the penetrating agent is MINEX SO.
  10. 根据权利1所述的一种吸湿快干抗菌防钻绒易去污面料的制备方法,其特征在于:所述织物为全棉、涤棉、棉涤、涤棉氨纶混纺、全涤或涤氨面料。The method for preparing a moisture-absorbing, quick-drying, antibacterial, anti-drilling, and easy-to-decontaminate fabric according to claim 1, wherein the fabric is made of cotton, polyester-cotton, cotton-polyester, polyester-cotton spandex blended, all-polyester or polyester-spandex fabric.
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