WO2022062616A1 - 一种利用污泥发酵碳源实现晚期垃圾渗滤液深度脱氮及污泥减量的方法和装置 - Google Patents
一种利用污泥发酵碳源实现晚期垃圾渗滤液深度脱氮及污泥减量的方法和装置 Download PDFInfo
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- 239000010802 sludge Substances 0.000 title claims abstract description 95
- 238000000855 fermentation Methods 0.000 title claims abstract description 68
- 230000004151 fermentation Effects 0.000 title claims abstract description 67
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000000149 chemical water pollutant Substances 0.000 title claims abstract description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title abstract description 40
- 229910052757 nitrogen Inorganic materials 0.000 title abstract description 20
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 18
- 244000005700 microbiome Species 0.000 claims abstract description 12
- 239000005416 organic matter Substances 0.000 claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 10
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 9
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 239000002351 wastewater Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 116
- 230000002572 peristaltic effect Effects 0.000 claims description 36
- 238000005273 aeration Methods 0.000 claims description 22
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- 238000012806 monitoring device Methods 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 9
- 239000004576 sand Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 6
- 238000007906 compression Methods 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000006228 supernatant Substances 0.000 claims description 3
- 238000013022 venting Methods 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 1
- 239000013585 weight reducing agent Substances 0.000 claims 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 abstract description 21
- 230000000694 effects Effects 0.000 abstract description 3
- 239000010801 sewage sludge Substances 0.000 abstract 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 241001453382 Nitrosomonadales Species 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000021391 short chain fatty acids Nutrition 0.000 description 1
- 150000004666 short chain fatty acids Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/303—Nitrification and denitrification treatment characterised by the nitrification
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/301—Aerobic and anaerobic treatment in the same reactor
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/305—Nitrification and denitrification treatment characterised by the denitrification
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/307—Nitrification and denitrification treatment characterised by direct conversion of nitrite to molecular nitrogen, e.g. by using the Anammox process
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
- C02F11/04—Anaerobic treatment; Production of methane by such processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
- C02F2101/163—Nitrates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
- C02F2101/166—Nitrites
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/06—Contaminated groundwater or leachate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/04—Oxidation reduction potential [ORP]
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/22—O2
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/38—Gas flow rate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/006—Regulation methods for biological treatment
Definitions
- the application relates to a method and device for realizing deep denitrification of late-stage landfill leachate and reduction of excess sludge by utilizing a carbon source for sludge fermentation, belonging to the technical field of biological denitrification of late-stage landfill leachate with a low-carbon-nitrogen ratio.
- landfill leachate is a kind of wastewater containing high concentrations of organic matter and ammonia nitrogen.
- the treatment and disposal of a large amount of excess sludge is also another major problem.
- the excess sludge is rich in organic carbon sources, and a large amount of short-chain fatty acids can be produced through alkaline anaerobic fermentation. It can be used as a high-quality carbon source to be added to the landfill leachate treatment process. At the same time, it also reduces its own weight by 50%-60%.
- the sludge fermentation liquid produced by directly using the sludge fermentation mixture instead of the sludge fermentation product centrifugation saves the centrifugation cost of the sludge-water separation and saves the floor space.
- Method and device for deep denitrification and sludge reduction in late-stage landfill leachate by sludge fermentation It operates in aerobic mode. After the raw water enters the anoxic section, organic matter is used to convert a part of nitrite nitrogen and nitrate nitrogen remaining in the previous cycle into nitrogen; The remaining nitrite nitrogen is removed at the same time, and nitrate nitrogen is generated; then it enters the aerobic section, and the remaining ammonia nitrogen is converted into nitrite nitrogen; the effluent containing nitrite nitrogen and nitrate nitrogen is pumped into DN-SBR, At the same time, the excess sludge fermentation mixture was added. The reactor was operated in anaerobic/aerobic/anoxic mode.
- the carbon source required for denitrification was derived from the excess sludge fermentation mixture on the one hand, and from the anaerobic stage on the other hand.
- the storage of microorganisms and the release of carbon sources in the anoxic stage, the microorganisms in the activated sludge use two parts of the carbon sources for denitrification to remove nitrogen from the landfill leachate.
- the removal rate of TN in the effluent reaches 96.0%.
- the process uses excess sludge for fermentation as a carbon source, which not only saves the cost of excess sludge treatment and disposal, but also provides a carbon source for the deep denitrification of sewage treatment, and can achieve the effect of reducing excess sludge at the same time.
- the present application proposes a method and device for realizing deep denitrification and sludge reduction of late-stage landfill leachate by utilizing sludge fermentation carbon source, specifically, the late-stage landfill leachate first enters short-range nitrification/anaerobic
- the ammonia oxidation reactor operates in A/A/O (anoxic/anaerobic/aerobic) mode. After the raw water enters the anoxic section, organic matter is used to convert part of the nitrite nitrogen and nitrate nitrogen remaining in the previous cycle into nitrogen.
- the anaerobic ammonium oxidation reaction occurs, removing part of the ammonia nitrogen and the remaining nitrite nitrogen in the raw water at the same time, and generating nitrate nitrogen; then entering the aerobic stage, converting the remaining ammonia nitrogen into nitrite nitrogen ;
- the effluent containing nitrite nitrogen and nitrate nitrogen is pumped into DN-SBR, and the excess sludge fermentation mixture is added at the same time.
- This reactor is operated in A/O/A (anaerobic/aerobic/anoxic) mode, and the The carbon source required for nitrification is derived from the residual sludge fermentation mixture on the one hand, and the storage of microorganisms in the anaerobic stage on the other hand, and the carbon source is released in the anoxic stage; It can be reduced to nitrogen, so as to realize the deep denitrification and sludge reduction of the late landfill leachate.
- A/O/A anaerobic/aerobic/anoxic
- a device for realizing deep denitrification of late-stage landfill leachate and sludge reduction by utilizing a carbon source for sludge fermentation comprising a raw water tank (1), a short-range nitrification/anammox integrated reactor (2), an intermediate water tank (3) ), the residual sludge alkaline fermentation tank (4), the fermentation product storage tank (5), the denitrification reactor (6), and the effluent water tank (7).
- the raw water tank is provided with an overflow pipe (1.1) and a water outlet (1.2);
- the short-range nitrification/anammox integrated reactor (2) is provided with an air compressor (2.1), a gas flow meter (2.2), an air compressor (2.2), a Air sand head (2.10), first water inlet (2.3), first sampling port (2.8), first drain port (2.9), first vent pipe (2.6), first agitator (2.5), first Water inlet peristaltic pump (2.11), first water outlet peristaltic pump (2.12), pH/DO real-time monitoring device (2.7), ORP real-time monitoring device (2.4);
- the residual sludge alkaline fermentation tank (4) is completely sealed outside the Attached with insulation layer, equipped with temperature control device (4.1), first mud inlet (4.2), second agitator (4.3), pH/DO real-time monitoring device (4.4), first mud outlet (4.5);
- the denitrification reactor (6) is provided with an air compressor (6.1), a gas flow meter (6.2), an a
- the raw water tank (1) is connected to the first water inlet (2.3) of the short-path nitrification/anammox integrated reactor through the first water inlet peristaltic pump (2.11); the first outlet of the short-path nitrification/anammox integrated reactor
- the water outlet (2.9) is connected to the water inlet (3.1) of the intermediate water tank through the first water outlet peristaltic pump (2.12), and the air passes through the air compressor (2.1) and the gas flow meter (2.2) and finally enters the short-range through the aeration sand head (2.10).
- the second outlet peristaltic pump (6.12) is connected to the second water outlet (6.9) of the denitrification reactor.
- the device to utilize sludge fermentation carbon source to realize late-stage landfill leachate deep denitrification and sludge reduction, it is characterized in that, it includes the following process:
- the residual sludge alkaline fermentation tank is a semi-continuous reactor, the sludge residence time SRT is 8-10 days, the temperature is maintained at 35 ⁇ 0.5 ° C, and the reaction pH is monitored online. It is maintained at 10 ⁇ 0.2; according to the amount of the excess sludge fermentation mixture discharged to the excess sludge fermentation mixture storage tank per day by SBR, and an equal volume of fresh excess sludge is added to the excess sludge alkaline fermentation tank;
- mode operation that is, the following mode: open the first stirrer to enter the anoxic stage after the water inflow is completed, stir for 1h, and convert the remaining part of the nitrite nitrogen and nitrate nitrogen in the upper cycle of the reactor into nitrogen; After the biodegradable organic matter is used up, continue anaerobic stirring for 2 hours, and the anaerobic ammonia oxidation reaction will occur, and a part of ammonia nitrogen and unused nitrite nitrogen in the raw water will be removed at the same time, and nitrate nitrogen will be generated, and the first agitator will be closed.
- the first air compression pump to start aeration, a short-range nitrification reaction occurs, and the ammonia nitrogen is converted into nitrous nitrogen, the DO is maintained between 1-1.5mg/L by the real-time control device, and the pH is monitored in real time by the pH control device.
- the preset aeration time is 4-5h, and the aeration is stopped at the "ammonia valley point", that is, before the inflection point where the pH first drops and then rises during the nitrification process; sedimentation is 0.5h to separate the mud and water, and the first effluent peristaltic pump is turned on. Discharge into the intermediate water tank, the drainage ratio is 30%;
- this reactor operates in the mode of A/O/A (anaerobic/aerobic/anoxic), that is, the following way: after the water inflow is completed, open the second stirrer and start stirring for 3-4h, and make full use of
- the organic matter in the residual sludge fermentation mixture is denitrified, and the microorganisms are stored in the internal carbon source at the same time, and the second air compression pump is turned on after the stirring; Entering the aeration stage, the ammonia nitrogen brought in the fermentation mixture is converted into nitrite nitrogen,
- the dissolved oxygen is maintained at 0.5-1.5mg/L by the real-time control device, the pH is monitored in real time by the pH control device, and the preset aeration time is 1-2h.
- the late landfill leachate first enters the PNA-SBR and operates in the A/A/O (anoxic/anaerobic/aerobic) mode. After the raw water enters the anoxic section, the remaining part of the nitrite nitrogen and nitrate in the previous cycle is converted by organic matter. Nitrogen is converted into nitrogen; after entering the anaerobic stage, anaerobic ammonia oxidation reaction occurs, and part of the ammonia nitrogen and unused nitrite nitrogen in the raw water are removed at the same time, and nitrate nitrogen is generated; after entering the aerobic stage, the remaining ammonia nitrogen is removed.
- A/A/O anoxic/anaerobic/aerobic
- This reactor is A/O/A (anaerobic/aerobic/ After entering the anaerobic section, the nitrite nitrogen and nitrate nitrogen in the influent are denitrified by using a part of the organic matter in the sludge fermentation mixture, and the microorganisms store the internal carbon source at the same time; the aerobic section will ferment The ammonia nitrogen generated in the mixture is converted into nitrite nitrogen and nitrate nitrogen; the final anoxic stage reduces the nitrite nitrogen and nitrate nitrogen to nitrogen, and simultaneously completes the deep removal of nitrogen and excess sludge in the denitrification reactor. reduction.
- This application realizes the deep denitrification of late-stage landfill leachate in the true sense through the organic combination of short-range nitrification, anaerobic ammonia oxidation, excess sludge fermentation and endogenous denitrification, and achieves cost saving and deep denitrification.
- the short-path nitrification of ammonia oxidizing bacteria can save 60% of the aeration amount, and the anammox bacteria do not generate N2O during the metabolic process, so this process is a greenhouse gas Low emissions.
- both short-path nitrification and anammox process can be carried out.
- the device is simple and easy to operate.
- the carbon source required for the reaction comes from the internal carbon source stored in the anaerobic stage; , which greatly saves the required cost.
- This process does not have a reflux device, which saves costs and is easy to operate.
- Fig. 1 is a flow chart of a method and device for realizing deep denitrification of late-stage landfill leachate and sludge reduction by utilizing sludge fermentation carbon source
- a method and device for realizing deep denitrification of late-stage landfill leachate and sludge reduction by utilizing a carbon source for sludge fermentation including a raw water tank (1), a short-range nitrification/anammox integrated reactor (2), an intermediate water tank (3), a residual sludge alkaline fermentation tank (4), a fermentation product storage tank (5), a denitrification reactor (6), and a water outlet tank (7).
- the raw water tank is provided with an overflow pipe (1.1) and a water outlet (1.2);
- the short-range nitrification/anammox integrated reactor (2) is provided with an air compressor (2.1), a gas flow meter (2.2), an air compressor (2.2), a Air sand head (2.10), first water inlet (2.3), first sampling port (2.8), first drain port (2.9), first vent pipe (2.6), first agitator (2.5), first Water inlet peristaltic pump (2.11), first water outlet peristaltic pump (2.12), pH/DO real-time monitoring device (2.7), ORP real-time monitoring device (2.4);
- the residual sludge alkaline fermentation tank (4) is completely sealed outside the Attached with insulation layer, equipped with temperature control device (4.1), first mud inlet (4.2), second agitator (4.3), pH/DO real-time monitoring device (4.4), first mud outlet (4.5);
- the denitrification reactor (6) is provided with an air compressor (6.1), a gas flow meter (6.2), an a
- the raw water tank (1) is connected to the first water inlet (2.3) of the short-path nitrification/anammox integrated reactor through the first water inlet peristaltic pump (2.11); the first outlet of the short-path nitrification/anammox integrated reactor
- the water outlet (2.9) is connected to the water inlet (3.1) of the intermediate water tank through the first water outlet peristaltic pump (2.12), and the air passes through the air compressor (2.1) and the gas flow meter (2.2) and finally enters the short-range through the aeration sand head (2.10).
- the second outlet peristaltic pump (6.12) is connected to the second water outlet (6.9) of the denitrification reactor.
- the residual sludge alkaline fermentation tank is a semi-continuous reactor, the sludge residence time SRT is 8-10 days, the temperature is maintained at 35 ⁇ 0.5 ° C, and the reaction pH is monitored online. It is maintained at 10 ⁇ 0.2; according to the amount of the excess sludge fermentation mixture discharged to the excess sludge fermentation mixture storage tank per day by SBR, and an equal volume of fresh excess sludge is added to the excess sludge alkaline fermentation tank;
- mode operation that is, the following mode: open the first stirrer to enter the anoxic stage after the water inflow is completed, stir for 1h, and convert the remaining part of the nitrite nitrogen and nitrate nitrogen in the upper cycle of the reactor into nitrogen; After the biodegradable organic matter is used up, continue anaerobic stirring for 2 hours, and the anaerobic ammonia oxidation reaction will occur, and a part of ammonia nitrogen and unused nitrite nitrogen in the raw water will be removed at the same time, and nitrate nitrogen will be generated, and the first agitator will be closed.
- the first air compression pump to start aeration, a short-range nitrification reaction occurs, and the ammonia nitrogen is converted into nitrous nitrogen, and the DO is maintained between 1-1.5mg/L by the real-time control device, and the pH is monitored in real time by the pH control device.
- the preset aeration time is 4-5h, and the aeration is stopped at the "ammonia valley point", that is, before the inflection point where the pH first drops and then rises during the nitrification process; sedimentation is 0.5h to separate the mud and water, and the first effluent peristaltic pump is turned on. Discharge into the intermediate water tank, the drainage ratio is 30%;
- this reactor operates in the mode of A/O/A (anaerobic/aerobic/anoxic), that is, the following way: after the water inflow is completed, open the second stirrer and start stirring for 3-4h, and make full use of
- the organic matter in the residual sludge fermentation mixture is denitrified, and the microorganisms are stored in the internal carbon source at the same time, and the second air compression pump is turned on after the stirring; Entering the aeration stage, the ammonia nitrogen brought in the fermentation mixture is converted into nitrite nitrogen,
- the dissolved oxygen is maintained at 0.5-1.5mg/L by the real-time control device, the pH is monitored in real time by the pH control device, and the preset aeration time is 1-2h.
- the TN removal rate reaches 96.0% under the condition that the influent ammonia nitrogen, total nitrogen and COD concentrations are 1150 ⁇ 40mg/L, 1421 ⁇ 55mg/L and 1503 ⁇ 150mg/L respectively, and the TN removal rate can be up to 0.64kg/(m 3 ⁇ d).
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Abstract
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- 一种利用污泥发酵碳源实现晚期垃圾渗滤液深度脱氮及污泥减量的装置,其特征在于:包括原水水箱(1)、短程硝化/厌氧氨氧化一体化反应器(2)、中间水箱(3)、剩余污泥碱性发酵罐(4)、发酵物储存罐(5)、反硝化反应器(6)、出水水箱(7);原水水箱设有溢流管(1.1)和出水口(1.2);所述短程硝化/厌氧氨氧化一体化反应器(2)设有空气压缩机(2.1)、气体流量计(2.2)、曝气砂头(2.10)、第一进水口(2.3)、第一取样口(2.8)、第一排水口(2.9)、第一放空管(2.6)、第一搅拌器(2.5)、第一进水蠕动泵(2.11)、第一出水蠕动泵(2.12)、pH/DO实时监测装置(2.7)、ORP实时监测装置(2.4);所述剩余污泥碱性发酵罐(4)完全密封外附有保温层,设有温度控制装置(4.1)、第一进泥口(4.2)、第二搅拌器(4.3)、pH/DO实时监测装置(4.4)、第一出泥口(4.5);所述反硝化反应器(6)设有空气压缩机(6.1)、气体流量计(6.2)、曝气砂头(6.10)、第二进水口(6.3)、第二取样口(6.8)、第二排水口(6.9)、第二放空管(6.6)、第三搅拌器(6.5)、第二进水蠕动泵(6.11)、第二出水蠕动泵(6.12)、pH/DO实时监测装置(6.7);原水水箱(1)通过第一进水蠕动泵(2.11)与短程硝化/厌氧氨氧化一体化反应器第一进水口(2.3)相连;短程硝化/厌氧氨氧化一体化反应器第一出水口(2.9)通过第一出水蠕动泵(2.12)与中间水箱进水口(3.1)相连,空气经过空气压缩机(2.1)、气体流量计(2.2)最终通过曝气砂头(2.10)打入短程硝化/厌氧氨氧化一体化反应器(2);中间水箱出水口(3.3)通 过第二进水蠕动泵(6.11)与反硝化反应器(6)相连;剩余污泥碱性发酵罐(4)的第一出泥口(4.5)与发酵物储存罐(5)相连;发酵物储存罐(5)与反硝化反应器(6)第二进泥口(6.4)相连;出水水箱(7)通过第二出水蠕动泵(6.12)与反硝化反应器第二排水口(6.9)相连。
- 利用权利要求1所述装置进行利用污泥发酵碳源实现晚期垃圾渗滤液深度脱氮及污泥减量的方法,其特征在于,包括以下过程:1)剩余污泥碱性发酵罐的启动:剩余污泥碱性发酵罐为半连续反应器,污泥停留时间SRT为8-10天,温度维持在35±0.5℃,在线监测反应pH,将其维持在10±0.2;根据SBR每天排放剩余污泥发酵混合物至剩余污泥发酵混合物储存罐的量,并加入等体积新鲜的剩余污泥至剩余污泥碱性发酵罐;2)分别将短程硝化/厌氧氨氧化活性污泥、反硝化污泥投加至短程硝化/厌氧氨氧化反应器和反硝化反应器中,控制投加后各个反应器混合液污泥浓度分别为5000-7000mg/L和8000-15000mg/L;3)打开第一进水蠕动泵,将原水水箱中的晚期垃圾渗滤液泵入短程硝化/厌氧氨氧化反应器中,此反应器以A/A/O(缺氧/厌氧/好氧)的方式运行,即下述方式:进水完毕后打开第一搅拌器进入缺氧阶段,搅拌1h;将原水中可生物降解有机物利用完后,继续厌氧搅拌2h,关闭第一搅拌器;随后打开第一空气压缩泵,开始曝气,通过实时控制装置保持DO在1-1.5mg/L之间,通过pH控制装置实时监测pH,预设曝气时间在4-5h,在“氨谷点”,即在硝化过程中pH先下降后上升的拐点前停止曝气;沉淀0.5h使泥水分离,打开第一出水蠕动泵,将水排入中间水箱,排水比为30%;4)打开第二进水蠕动泵,将中间水箱中亚硝态氮和硝态氮废水泵入反硝化反应器,同时投加剩余污泥发酵混合物,进发酵物量为反硝化反应器有效体积的3%-5%,此反应器以A/O/A(厌氧/好氧/缺氧)的方式运行,即下述方式:进水完毕打开第二搅拌器开始搅拌3-4h,搅拌结束后打开第二空气压缩泵;进入曝气阶段,通过实时控制装置保持溶解氧维持在0.5-1.5mg/L,通过pH控制装置实时监测pH,预设曝气时间在1-2h,在“氨谷点”,即在硝化过程中pH先下降后上升的拐点前停止曝气;再次开启第二搅拌器,进入缺氧搅拌阶段,此时微生物释放厌氧阶段储存的碳源,进行反硝化,其终点由过程实时控制判断,当出现“亚硝酸盐肘”拐点,即ΔpH=pH2-pH1<0时停止搅拌,沉淀0.5h使泥水分离,打开第二出水蠕动泵,将上清液泵入出水水箱,排水比为30%。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103539317A (zh) * | 2013-10-28 | 2014-01-29 | 北京工业大学 | 反硝化脱氮除磷处理高氨氮厌氧氨氧化出水和生活污水的装置和方法 |
CN105036335A (zh) * | 2015-08-05 | 2015-11-11 | 北京工业大学 | 一种对晚期垃圾渗滤液自养深度脱氮生物处理装置与方法 |
JP2016077954A (ja) * | 2014-10-15 | 2016-05-16 | 新日鐵住金株式会社 | 生物学的窒素除去方法 |
CN108439595A (zh) * | 2018-04-04 | 2018-08-24 | 北京工业大学 | 利用污泥发酵物实现污水部分短程硝化-Anammox/反硝化的方法 |
CN109485149A (zh) * | 2018-12-22 | 2019-03-19 | 北京工业大学 | 一种实现晚期垃圾渗滤液深度脱氮和剩余污泥减量的装置与方法 |
CN112250178A (zh) * | 2020-09-24 | 2021-01-22 | 北京工业大学 | 一种利用污泥发酵碳源实现晚期垃圾渗滤液深度脱氮及污泥减量的方法和装置 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108585202B (zh) * | 2018-05-14 | 2021-04-30 | 北京工业大学 | 序批式反应器中实现部分短程硝化、污泥发酵耦合反硝化与厌氧氨氧化处理生活污水的工艺 |
CN109574218B (zh) * | 2018-12-22 | 2021-11-26 | 北京工业大学 | 短程硝化-发酵/反硝化-厌氧氨氧化工艺处理晚期垃圾渗滤液的装置与方法 |
-
2020
- 2020-09-24 CN CN202011011157.6A patent/CN112250178B/zh active Active
-
2021
- 2021-07-21 WO PCT/CN2021/107611 patent/WO2022062616A1/zh active Application Filing
- 2021-07-21 US US17/768,668 patent/US20240109798A1/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103539317A (zh) * | 2013-10-28 | 2014-01-29 | 北京工业大学 | 反硝化脱氮除磷处理高氨氮厌氧氨氧化出水和生活污水的装置和方法 |
JP2016077954A (ja) * | 2014-10-15 | 2016-05-16 | 新日鐵住金株式会社 | 生物学的窒素除去方法 |
CN105036335A (zh) * | 2015-08-05 | 2015-11-11 | 北京工业大学 | 一种对晚期垃圾渗滤液自养深度脱氮生物处理装置与方法 |
CN108439595A (zh) * | 2018-04-04 | 2018-08-24 | 北京工业大学 | 利用污泥发酵物实现污水部分短程硝化-Anammox/反硝化的方法 |
CN109485149A (zh) * | 2018-12-22 | 2019-03-19 | 北京工业大学 | 一种实现晚期垃圾渗滤液深度脱氮和剩余污泥减量的装置与方法 |
CN112250178A (zh) * | 2020-09-24 | 2021-01-22 | 北京工业大学 | 一种利用污泥发酵碳源实现晚期垃圾渗滤液深度脱氮及污泥减量的方法和装置 |
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