WO2022057518A1 - Utilisation d'un matériau composite de verre ayant un point de ramollissement élevé, un faible coefficient de dilatation thermique, une résistance élevée à l'usure et une faible conductivité thermique dans une turbine à gaz de moteur - Google Patents

Utilisation d'un matériau composite de verre ayant un point de ramollissement élevé, un faible coefficient de dilatation thermique, une résistance élevée à l'usure et une faible conductivité thermique dans une turbine à gaz de moteur Download PDF

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Publication number
WO2022057518A1
WO2022057518A1 PCT/CN2021/111675 CN2021111675W WO2022057518A1 WO 2022057518 A1 WO2022057518 A1 WO 2022057518A1 CN 2021111675 W CN2021111675 W CN 2021111675W WO 2022057518 A1 WO2022057518 A1 WO 2022057518A1
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WIPO (PCT)
Prior art keywords
powder
composite material
glass
glass composite
engine
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PCT/CN2021/111675
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English (en)
Chinese (zh)
Inventor
杨德宁
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深圳前海发维新材料科技有限公司
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Priority claimed from CN202010968954.7A external-priority patent/CN112145304A/zh
Priority claimed from CN202011507153.7A external-priority patent/CN112500172B/zh
Application filed by 深圳前海发维新材料科技有限公司 filed Critical 深圳前海发维新材料科技有限公司
Publication of WO2022057518A1 publication Critical patent/WO2022057518A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
    • C04B35/584—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00—Powdered glass; Bead compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C03C14/004—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of particles or flakes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
    • F01D25/24—Casings; Casing parts, e.g. diaphragms, casing fastenings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F1/00—Cylinders; Cylinder heads 
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient

Definitions

  • the invention relates to the field of new materials, in particular to a glass composite material.
  • Glass material 1 In the production process of glass, especially in the molding process after melting, homogenization and clarification above 1500 °C, a small amount of alumina crystals, zirconia crystals or silica crystals are melted due to high temperature, so that the The glass loses the properties of high hardness and high wear resistance of each crystal, which eventually leads to low hardness, poor wear resistance and low softening point (below 850 °C) of the glass material; 2 it is impossible to pass the melting and homogenization above 1500 °C , The clarified molding process produces glass-ceramic products with alumina crystals or zirconia crystals or silicon carbide crystals with a content of 20-90%, high hardness and high wear resistance, and it is even more impossible to produce alumina crystals or oxides.
  • the glass-ceramic product content of zirconium crystal or silicon carbide crystal is 20-90%, glass composite material with high hardness and high wear resistance properties.
  • Ceramic materials The thermal conductivity of ceramic materials is high, reaching 25-80w/[(m.K)], and the thermal insulation performance is poor.
  • Metal materials The thermal expansion rate of metal materials at 350-450°C is above 10 ( ⁇ 10-6/°C), and when it is higher than 350-450°C, the thermal expansion will increase exponentially, so it can only withstand instantaneous high temperatures, let alone Long-term exposure to higher temperatures, higher temperatures will cause large deformation of metal materials.
  • Natural mineral materials Natural mineral materials have low wear resistance, many cracks in agglomerated ore, and poor strength. Only when crushed into powder (small particles), there will be no cracks and the inherent strength of natural mineral materials.
  • Glass-ceramic material Glass-ceramic is crystallization and heat treatment under a certain temperature system, and a large number of tiny crystals are uniformly precipitated in the glass to form a dense multi-phase complex of crystallite and glass phase.
  • the crystal is pure crystal, and the glass-ceramic material has the following defects: 1
  • the content of alumina in the glass-ceramic phase of the glass-ceramic is very low, so the strength of the glass-ceramic material is very poor, and the glass phase cannot grow with high wear resistance.
  • High alumina-containing crystals such as total crystals of mullite and magnesia-aluminum spinel; 2 microcrystalline grains generated by nucleation and crystal growth, such as wollastonite, hectorite, hectorite, gamolite Stone, calcite feldspar, nepheline, etc. These microcrystalline grains have low hardness and low wear resistance, resulting in low hardness and low wear resistance of glass-ceramic materials; 3 The production process of glass-ceramic cannot be stored in the glass memory.
  • inorganic non-metallic materials made of natural or synthetic compounds by shaping and high temperature sintering, including silicon nitride or alumina or ceramic nuclei such as silicon oxide or zirconia, so it is even less likely to be obtained from glass-ceramic
  • silicon nitride ceramic crystals or alumina ceramic crystals or silicon oxide ceramic crystals or zirconia ceramic crystals are generated, and the proportion of ceramic crystals such as silicon nitride or alumina or silicon oxide or zirconia cannot be controlled according to the application scenario;
  • the glass-ceramic material does not have the hardness and wear resistance of silicon nitride or aluminum oxide or zirconia or silicon carbide; The nature of long-term work under working temperature conditions; 6
  • the current production process of glass-ceramic materials has low production efficiency and high energy consumption, and can only produce flat-shaped products, but cannot produce products with extremely complex shapes, such as: engines of cylinder liners and cylinder blocks.
  • Ceramic materials have the advantages of high hardness, high wear resistance, and can work under high temperature conditions for a long time. According to the advantages of ceramic materials, people also think of using ceramic materials to replace metal materials, such as: Europe, Japan, and the United States have studied and For cars that have produced ceramic engine blocks, in 1990, Shanghai's first water-cooled silicon nitride ceramic engine came out, and the gas inlet temperature could reach 1200 °C.
  • the fuel consumption efficiency is 213.56g/km.h, which is far lower than the current 380g/km.h of the 1.5L direct injection engine, which is reduced by 80%. 38%, an increase of 32%, making the thermal energy utilization rate of the ceramic engine reach 70%.
  • the fundamental problem of the ceramic engine block is that the functional ceramic material cannot be produced by the casting process of cast iron (after melting) or the die-casting process of aluminum alloy.
  • Functional ceramic materials are unable to produce special-shaped, complex-shaped products, including engine blocks.
  • the molding temperature of functional ceramic materials is about 1700 °C.
  • the isostatic pressing process of special-shaped and complex-shaped products cannot make the ceramic powder in each position of the special-shaped and complex-shaped products equal to the pressure. Therefore, the deformation of products with uneven density is also very large. For example, it is not easy to produce dozens of engine blocks by using functional ceramic materials. It is impossible to achieve industrialized large-scale and standardized production of special-shaped and complex-shaped products.
  • the engine cylinder block and cylinder liner are both made of metal materials.
  • the performance defects of high-strength alloy steel metal materials or cast iron materials are: 1
  • the thermal expansion rate at 350-450°C is above 10 ( ⁇ 10-6/°C), and when it is higher than 350-450°C, the thermal expansion will double. Therefore, it can only withstand instantaneous high temperature, and can not withstand high temperature of 800-1100 °C for a long time, otherwise the cylinder liner will be greatly deformed and the engine will be damaged;
  • the traditional engine cylinder block and cylinder liner must be lower than the limit deformation point of cast iron 350-450 °C , a high-speed coolant circulation system must be used to keep the working temperature of the engine cylinder block and cylinder liner below 100-250 °C.
  • thermo conductivity of the metal material is above 40-120w/[(mK)], the heat waste, so the utilization rate of heat energy can only be 30%-40%; 3 high-strength alloy steel metal materials or cast iron materials are not good in hardness and wear resistance, in terms of chemical resistance to corrosion and resistance to changes in cold and heat temperature differences, Also worse than ceramic materials.
  • the exhaust has heat energy loss, the heat energy is mainly dissipated through the metal cylinder wall of the engine, resulting in a heat engine type piston aircraft engine heat energy utilization rate of only 35%, the waste is too large, and the fuel cannot be fully burned. Affect the environment.
  • the existing heat engine turbine engine is the same as the heat engine piston aircraft engine, which requires four stages of intake, pressurization, combustion and exhaust.
  • the difference is that in the piston aircraft engine of the heat engine type, the four stages are carried out sequentially in time-sharing, but in the turbine engine of the heat engine type, it is carried out continuously, and the gas flows through each part of the turbine engine in turn, corresponding to four working positions of the piston engine.
  • the thermal energy utilization rate of the steam turbine can be greatly improved.
  • Traditional insulation materials include aerogel insulation materials, ceramic foam insulation materials and glass foam insulation materials; most of the current aerogel insulation materials are composite materials combining aerogel and reinforcing fibers.
  • the defects of the material are: very poor strength, very brittle, and easily broken; the defects of ceramic foam insulation materials are: very poor strength, very brittle, and easily broken; the defects of glass foam insulation materials are: very poor strength, very brittle, Breaks easily.
  • the present invention proposes a glass composite material.
  • the present invention provides a glass composite material
  • the glass composite material includes glass powder particles and filler particles
  • the filler particles are ceramic powder particles, natural mineral powder particles or metal powder particles
  • the glass powder particles are made by sintering. Bonding and wrapping the ceramic powder particles or the natural mineral powder particles or the metal powder particles, the softening temperature of the glass composite material is greater than 850°C, the diameter of the filled powder particles is less than 1 mm, and the natural mineral powder
  • the melting temperature of the powder particles and the metal powder particles is greater than 950°C
  • the ceramic powder particles are powder particles of a class of inorganic non-metallic materials made of natural or synthetic compounds through molding and high-temperature sintering; the glass powder particles are based on the weight percentage
  • the content of alumina is 12-48%
  • the content of magnesium oxide is 0-15%
  • the content of silicon oxide is 30-82%
  • the content of calcium oxide is 0-15%
  • the content of boron oxide is 0-15%.
  • the softening temperature of the glass composite material is >1100°C.
  • the content of alumina in the glass powder is 35-44%
  • the content of magnesium oxide is 5-15%
  • the content of silicon oxide is 26-40%
  • the content of calcium oxide is 6-15%
  • the content of boron oxide is 3-6%.
  • the content of the filler powder is 20-92%, and the content of the glass powder is 8-80% in terms of weight percentage.
  • the diameter of the filled powder particles is less than 0.01 mm.
  • the ceramic powder is alumina ceramic powder or zirconia ceramic powder or silicon nitride ceramic powder or silicon carbide ceramic powder or magnesium aluminum spinel ceramic powder.
  • the natural mineral powder is bauxite powder or quartzite powder or granite powder or silica sand powder or andalusite powder or kyanite powder or sillimanite powder.
  • the metal powder particles are copper alloy powder particles or gray cast iron powder particles or alloy steel powder particles or tungsten alloy powder particles or chromium alloy powder particles.
  • a production method of the glass composite material comprising the following steps:
  • a production method of the glass composite material comprising the following steps:
  • A1 Mix the glass powder with the ceramic powder or the natural mineral powder or the metal powder evenly to form a mixed powder
  • A2 heating the mixed powder particles to soften the glass powder particles to form a molten mixture
  • A3 The molten mixture is shaped by a calendering process, a hot pressing process or a pouring casting process, and finally the glass composite material is formed.
  • a method for spraying the glass composite material on the surface of a workpiece comprising the following steps:
  • B1 uniformly mix the glass powder with the ceramic powder or the natural mineral powder or the metal powder to form a mixed powder
  • a cylinder liner of a vehicle engine includes the glass composite material.
  • the cylinder liner of the vehicle engine is made of the glass composite material.
  • a cylinder liner of a marine engine comprising the glass composite material.
  • the cylinder liner of the marine engine is made of the glass composite material.
  • a heat engine type piston aircraft engine includes an engine cylinder liner, and the engine cylinder liner includes the glass composite material.
  • the engine cylinder liner is made of the glass composite material.
  • a heat engine type turbine engine includes the glass composite material.
  • the surfaces of the combustion chamber of the heat engine type turbine engine and the outer casing of the turbine are covered with a layer of the glass composite material.
  • a steam turbine including the glass composite material.
  • the steam chamber wall of the steam turbine and/or the surface layer of the cylinder layer and/or the surface layer of the steam nozzle and/or the surface layer of the steel plate and/or the surface layer of the blade and/or the surface layer of the cylinder body and/or the surface layer of the steam conveying pipe are covered with a layer the glass composite.
  • the surface of the cylinder liner of the piston engine of the generator and/or the casing of the turbocharging system component is covered with a layer of the glass composite material.
  • a heat engine type glass engine cylinder block includes a cylinder liner including the glass composite material.
  • the cylinder liner is made of the glass composite material.
  • a heat engine type engine block comprising the glass composite material.
  • the engine block of the heat engine is made of the glass composite material.
  • a heat engine type engine includes the glass composite material.
  • the surface of the casing of the turbocharger system component of the heat engine type engine is covered with a layer of the glass composite material.
  • the cylinder head and/or the piston and/or the piston pin and/or the connecting rod and/or the intake valve and/or the exhaust valve of the thermal engine type are made of the glass composite material.
  • the cylinder liner of the thermal engine includes an inner layer and an outer layer, the outer layer is made of the glass composite material, and the outer layer is sleeved on the periphery of the inner layer and is connected with the inner layer.
  • the inner layer is made of ceramic material.
  • a foamed glass material comprising the glass composite material.
  • a fiber-containing composite includes the glass composite.
  • a tubular material comprising the glass composite.
  • a flat plate material comprising the glass composite material.
  • the glass composite material proposed by the present invention also has high strength performance under high temperature, the performance of adapting to the temperature change of rapid cooling and rapid heating, low thermal expansion performance, low thermal conductivity 1-5w/[(mK)], ultra-high strength performance, 8 advantages of materials with high softening point (deformation point), high wear resistance and high hardness.
  • the present invention provides a glass composite material
  • the glass composite material includes glass powder particles and filler particles
  • the filler particles are ceramic powder particles, natural mineral powder particles or metal powder particles
  • the glass powder particles are made by sintering. Bonding and wrapping the ceramic powder particles or the natural mineral powder particles or the metal powder particles, the softening temperature of the glass composite material is greater than 850°C, the diameter of the filled powder particles is less than 1 mm, and the natural mineral powder
  • the melting temperature of the powder particles and the metal powder particles is greater than 950°C
  • the ceramic powder particles are powder particles of a class of inorganic non-metallic materials made of natural or synthetic compounds through molding and high-temperature sintering; the glass powder particles are based on the weight percentage
  • the content of alumina is 12-48%
  • the content of magnesium oxide is 0-15%
  • the content of silicon oxide is 30-82%
  • the content of calcium oxide is 0-15%
  • the content of boron oxide is 0-15%.
  • the diameter of the ceramic powder or the natural mineral powder or the metal powder is less than 1 mm so that the ceramic powder or the natural mineral powder or the metal powder can hold the material
  • the inherent mechanical properties of the glass composite material because the structure of the glass composite material is that the glass powder particles bond and wrap the ceramic powder particles or the natural mineral powder particles or the metal powder particles, so that the glass composite material
  • the softening point temperature of the glass powder is greater than or equal to the softening point temperature of the glass powder; glass materials with different softening points can be selected according to actual use requirements to make the glass powder, so that the glass composite material can meet different use requirements;
  • the glass powder particles are softened by heating, so that the glass powder particles bind and wrap the ceramic powder particles or the natural mineral powder particles or the metal powder particles to form the glass composite material.
  • the glass composite material is made by bonding and wrapping the ceramic powder particles with the glass powder particles, and the glass composite material simultaneously has glass materials, ceramic materials, natural mineral materials, metal materials and microscopic materials.
  • the advantages of crystal glass material are that it has high strength performance at high temperature, the performance of adapting to the temperature change of rapid cooling and heating, low thermal expansion performance, low thermal conductivity 1-5w/[(mK)], ultra-high strength performance, 8 advantages of materials with high softening point (deformation point), high wear resistance and high hardness properties, the glass composite material is especially suitable for various engines (cylinder liners, cylinder blocks and other components of the engine) in the field of heat engines, It is used in the field of foam insulation materials, thermal spray insulation materials, round pipe insulation materials, and plate insulation materials.
  • the content of alumina in the glass powder is 12-48%, the content of magnesium oxide is 0-15%, and the content of silicon oxide is 30-15% by weight percentage. 82%, the content of calcium oxide is 0-15%, and the content of boron oxide is 0-15%.
  • the softening point of the glass powder is greater than 850°C, preferably the glass powder has a softening point between 900-1350°C.
  • the content of alumina in the glass powder is 17%, the content of magnesium oxide is 6.3%, the content of silicon oxide is 66%, and the content of calcium oxide is 66%.
  • the content of boron oxide is 8.6%, and the content of boron oxide is 2.1%; under this composition, the softening point of the glass powder is 860 ° C, the strength of the glass powder is 170Mpa, and the thermal conductivity of the glass powder is 170Mpa.
  • the thermal expansion coefficient of the glass powder from 0-40°C(normal temperature) to 860°C is 4( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C) In between, that is, the deformation of the glass frit from 0-40°C to 910°C is between 4ppm and 9.5ppm.
  • the structure of the glass composite material is that the glass powder particles bond and wrap the ceramic powder particles, the natural mineral powder particles, or the metal powder particles.
  • the metal powder particles Enter the ceramic powder or the natural mineral powder or the metal powder, and finally enter the glass material layer formed by the glass powder, so even if the ceramic powder or the natural mineral powder or The thermal conductivity of the metal powder particles reaches 20-200w/[(mK)], and a glass material layer with a thermal conductivity of less than 9/[w/[(mK)] is also formed by the glass powder particles Block the heat.
  • the structure of the glass composite material is that the glass powder particles bond and wrap the ceramic powder particles, the natural mineral powder particles, or the metal powder particles.
  • the glass composite material also produces new properties, the thermal expansion rate of the glass composite material rises from 0-40 ° C to 900-1350 ° C in 4( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C), that is, the deformation of the glass composite material from 0-40°C to 900-1350°C is between 4ppm and 9.5ppm, compared with the aluminum alloy of the traditional engine.
  • the thermal expansion rate of cast iron metal material is between 15-24 ( ⁇ 10-6/°C) at 350-450°C, but in the very low temperature range of 350-450°C, it will produce high deformation, compared to traditional The aluminum alloy or cast iron metal material of the engine, the glass composite material has better material properties of resistance to rapid cooling and rapid heat changes.
  • the structure of the powder particles or the metal powder particles will be many times higher than the breaking strength of the glass material alone, and the glass material alone cracks unhindered because the cracks are in the glass, so the glass material alone is stronger than the glass composite material.
  • the breaking strength of the material will be several times lower; even if the glass composite is made with ceramic powders with poor breaking strength or natural mineral powders or metal powders, cracks will occur in thousands of ceramics.
  • the powder particles or natural mineral powder particles are constantly blocked and stagnant.
  • the glass composite material has a much higher advantage in breaking strength performance, so the glass composite material is especially suitable for use in: 1 heat engine type of various engines In the application field of cylinder block and/or cylinder liner; 2 In the application field of engine accessories; 3 In the application field of foam insulation materials; 4 In the application field of thermal spray insulation materials; 5 In the application field of round pipe insulation materials In the field of application; 6 In the field of application of flat-panel insulation materials.
  • the glass powder particles are based on weight percentage, and the content of alumina in the glass powder particles is 54%, the content of magnesium oxide is 5%, the content of silicon oxide is 30%, and the content of calcium oxide is 7%. %; boron oxide 4%; under this component, the softening point of the glass powder is 1350°C, the strength of the glass powder is 380Mpa, and the thermal conductivity of the glass powder is less than 9/[w/ [(mK)], the thermal expansion coefficient of the glass powder from 0-40°C (normal temperature) to 1350°C is between 3.8( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C), also That is, the deformation of the glass powder from 0-40°C to 1350°C is between 3.8 ppm and 9.5 ppm.
  • the ejector rod method of the German NETZSCH instrument is used to test the softening temperature of the glass composite material, and the test conditions are: a heating rate of 5°C/min.
  • the metal powder particles in the glass composite material are 70%, and the glass powder particles are 30%; the metal powder particles are alloy steel powder particles, and alloy steel powder particles
  • the diameter of the glass powder is less than 0.01mm; the glass powder has an alumina content of 17%, a magnesium oxide content of 6.3%, a silicon oxide content of 66%, and a calcium oxide content of 8.6% by weight in the glass powder. %; boron oxide 2.1%.
  • the melting temperature of the alloy steel powder is 1400°C; the softening point of the glass composite material is 860°C, the strength of the glass powder is 170Mpa, and the thermal conductivity of the glass powder is less than 9/[w/[(mK)].
  • the thermal expansion coefficient of the glass composite material from 0-40°C (normal temperature) to 910°C is between 4( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C), and also That is, the deformation of the glass composite from 0-40°C to 910°C is between 4ppm and 9.5ppm.
  • the smaller the diameter of the filler particles, the better the density of the glass composite material, and the diameter of the alloy steel particles is less than 0.01 mm.
  • the cracks are continuously blocked and stagnant among thousands of alloy steel powder particles; the glass powder particles wrap the alloy steel powder particles
  • the structure of the glass composite material will be more than 2.5 times higher than the breaking strength of the single glass material, and the strength of the glass composite material will increase from 170Mpa to 425Mpa; the softening point of the glass composite material is 860 °C, so the glass composite material is in It has high strength properties at high temperature; the thermal energy is mainly blocked by the glass material formed by the glass powder with thermal conductivity less than 9/[w/[(mK)], so the thermal conductivity of the glass composite structure is is less than 9w/[(mK)].
  • the glass composite material can be used as a thermal conductor in various application scenarios of 860°C for a long time.
  • the glass composite material is more resistant than the metal cylinder liner of the engine because the hardness of the bauxite powder is more than 3 times higher than that of the metal cylinder liner of the engine. Grinding and higher hardness.
  • the natural mineral powder in the glass composite material is 75%, and the glass powder is 25%; the natural mineral powder is quartz stone powder, quartz stone powder The diameter of the glass powder is less than 0.01mm; the glass powder has an alumina content of 28%, a magnesium oxide content of 6.3%, a silicon oxide content of 55%, and a calcium oxide content of 8.6% by weight. %; boron oxide 2.1%.
  • the melting temperature of the quartz stone powder is 1400°C; the softening point of the glass composite material is 910°C, the strength of the glass powder is 195Mpa, and the thermal conductivity of the glass powder is less than 8 /[w/[(mK)].
  • the thermal expansion coefficient of the glass composite material from 0-40°C (normal temperature) to 910°C is between 4( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C), and also That is, the deformation of the glass composite material from 0-40 °C to 1120 °C is between 4ppm and 9.5ppm, compared with the thermal expansion rate of aluminum alloy or cast iron metal material of traditional engine at 350-450°C. Between 15-24 ( ⁇ 10-6/°C), only in the very low temperature range of 350-450°C, it will produce high deformation. Compared with the aluminum alloy or cast iron metal materials of traditional engines, the glass The composite material has better material properties of resistance to rapid cooling and rapid thermal changes.
  • the breaking strength of the glass composite material will be more than 2.5 times higher than that of the single glass material, and the strength of the glass composite material will increase from 195Mpa to 487Mpa; the softening point of the glass composite material is 910 °C, so the glass composite material is in a high temperature state.
  • the thermal energy is mainly blocked by the glass material formed by the glass powder with a thermal conductivity of less than 8/[w/[(mK)], so the thermal conductivity of the glass composite structure is less than 8/[w/[(mK)] 8w/[(mK)].
  • the glass composite material can be used as thermal conductivity in various application scenarios of 910°C for a long time. It is used for high temperature heat insulation materials less than 8/[w/[(mK)]; and because the hardness of quartz stone powder is more than 2 times higher than that of various engine metal cylinder liners, the glass composite material is more durable than engine metal cylinder liners. Wear-resistant and higher hardness.
  • the glass composite material is based on the weight percentage, in the glass composite material, the ceramic powder is 80%, and the glass powder is 20%; the ceramic powder is alumina ceramic powder, alumina ceramic powder The diameter of the powder particles is less than 0.01mm; the glass powder particles are based on the weight percentage, and the content of alumina in the glass powder particles is 44%, the content of magnesium oxide is 7%; the content of silicon oxide is 34%; calcium oxide Content 8%; boron oxide 7%.
  • the melting temperature of the alumina ceramic powder is 1700°C; the softening point of the glass composite material is 1310°C, the strength of the glass powder is 330Mpa, and the thermal conductivity of the glass powder is Less than 7w/[(mK)].
  • the thermal expansion coefficient of the glass composite material from 0-40°C (normal temperature) to 1310°C is between 5( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C), and also That is, the deformation of the glass composite material from 0-40 °C to 1310 °C is between 5ppm and 9.5ppm, compared with the thermal expansion rate of aluminum alloy or cast iron metal material of traditional engine at 350-450°C. Between 15-24 ( ⁇ 10-6/°C), only in the very low temperature range of 350-450°C, it will produce high deformation. Compared with the aluminum alloy or cast iron metal materials of traditional engines, the glass The composite material has better material properties of resistance to rapid cooling and rapid thermal changes.
  • the cracks are continuously blocked and stagnant among thousands of alumina ceramic powder particles; the glass powder particles wrap the alumina ceramic particles
  • the structure of the powder particles will be more than 2.5 times higher than the breaking strength of the single glass material, and the strength of the glass composite material will increase from 330Mpa to 820Mpa; the softening point of the glass composite material is 1310 °C, so the glass composite material
  • the material has high strength properties at high temperature; the heat energy is mainly blocked by the glass material formed by the glass powder with a thermal conductivity of less than 7w/[(mK)], so the thermal conductivity of the glass composite structure is Less than 7w/[(mK)].
  • the glass composite material can be used as a heat sink in various application scenarios of 1310°C for a long time. It can be used as a high-temperature heat-resistant thermal insulation material with a conductivity of less than 7w/[(mK)]; and because the alumina ceramic powder is more than 3 times harder than various engine metal cylinder liner More wear-resistant, higher hardness.
  • the softening temperature of the glass composite material is >1100°C.
  • the content of alumina in the glass powder is 35-44%
  • the content of magnesium oxide is 5-15%
  • the content of silicon oxide is 26-40%
  • the content of calcium oxide is 6-15%
  • the content of boron oxide is 3-6%.
  • the glass powder particles are based on weight percentages, and the content of alumina in the glass powder particles is 35%, the content of magnesium oxide is 10%, the content of silicon oxide is 40%, and the content of calcium oxide is 40%.
  • the content of boron oxide is 11%, and the content of boron oxide is 4%; under this composition, the softening point of the glass powder is 1120 ° C, the strength of the glass powder is 235Mpa, and the thermal conductivity of the glass powder is less than 7w/[(mK)], the thermal expansion coefficient of the glass powder from 0-40°C(normal temperature) to 1120°C is 4( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C) In between, that is, the deformation of the glass frit from 0-40°C to 1120°C is between 4ppm and 9.5ppm.
  • the content of alumina is 44%
  • the content of magnesium oxide is 7%
  • the content of silicon oxide is 34%
  • the content of calcium oxide is 34% in the glass powder according to the weight percentage.
  • the content of boron oxide is 8%, and the content of boron oxide is 7%; under this composition, the softening point of the glass powder is 1310 ° C, the strength of the glass powder is 330Mpa, and the thermal conductivity of the glass powder is less than 7w/[(mK)], the thermal expansion rate of the glass powder from 0-40°C (normal temperature) to 1310°C is 5( ⁇ 10-6/°C)-9.5( ⁇ 10-6/°C) In between, that is, the deformation of the glass frit from 0-40°C to 1310°C is between 5ppm and 9.5ppm.
  • the content of the filler powder is 20-92%, and the content of the glass powder is 8-80% in terms of weight percentage.
  • the content of the glass powder particles is 20%, and the content of the ceramic powder particles is 80%, and the glass composite material can be produced by an isostatic pressing process.
  • the diameter of the filled powder particles is less than 0.01 mm.
  • the smaller the diameter of the filling powder particles, the better the density of the glass composite material, and the diameter of the filling powder particles is less than 0.01 mm.
  • the ceramic powder is alumina ceramic powder or zirconia ceramic powder or silicon nitride ceramic powder or silicon carbide ceramic powder or magnesium aluminum spinel ceramic powder.
  • the ceramic powder is preferably alumina ceramic powder or zirconia ceramic powder or silicon nitride ceramic powder or silicon carbide ceramic powder or magnesium aluminum spinel ceramic powder, alumina ceramic powder
  • the melting point of powder, zirconia ceramic powder, silicon nitride ceramic powder, silicon carbide ceramic powder, magnesium aluminum spinel ceramic powder is about 1500-1700 °C, and it also has high wear resistance, low specific gravity and high temperature. The advantage of high strength.
  • the natural mineral powder is bauxite powder or quartzite powder or granite powder or silica sand powder or andalusite powder or kyanite powder or sillimanite powder.
  • the natural mineral powders are preferably bauxite powders or quartzite powders or granite powders or silica sand powders or andalusite powders or kyanite powders or sillimanite powders, bauxite powders , Quartz stone powder, granite powder, silica sand powder, andalusite powder, kyanite powder, sillimanite powder melting point above 1100 °C, can meet various needs.
  • the metal powder particles are copper alloy powder particles or gray cast iron powder particles or alloy steel powder particles or tungsten alloy powder particles or chromium alloy powder particles.
  • the metal powder is preferably copper alloy powder or gray cast iron powder or alloy steel powder or tungsten alloy powder or chromium alloy powder, copper alloy powder, gray cast iron powder, alloy steel powder
  • the melting point of powder, tungsten alloy powder and chromium alloy powder is above 1100°C, which can meet various application requirements.
  • a production method of the glass composite material comprising the following steps:
  • step S4 an isostatic pressing process is adopted in step S4, and the glass composite material can be produced into a plate-shaped and tubular product.
  • a production method of the glass composite material comprising the following steps:
  • A1 Mix the glass powder with the ceramic powder or the natural mineral powder or the metal powder evenly to form a mixed powder
  • A2 heating the mixed powder particles to soften the glass powder particles to form a molten mixture
  • A3 The molten mixture is shaped by a calendering process or a hot pressing process or a pouring casting process, and finally the glass composite material is formed.
  • the casting process is adopted in step A3, and the glass composite material can be produced into special-shaped and complex-shaped products, such as an engine block and an engine cylinder liner.
  • a method for spraying the glass composite material on the surface of a workpiece comprising the following steps:
  • B1 uniformly mix the glass powder with the ceramic powder or the natural mineral powder or the metal powder to form a mixed powder
  • the glass composite material can be attached to the surface of a product with a special shape and a complex shape.
  • a cylinder liner of a vehicle engine includes the glass composite material.
  • the cylinder liner of the vehicle engine is made of the glass composite material.
  • the cylinder liner of the vehicle engine is made of the glass composite material;
  • the ceramic powder is preferably alumina ceramic powder or zirconia ceramic powder or silicon nitride ceramic powder or silicon carbide ceramic Powder;
  • the natural mineral powder is preferably quartzite ore, quartzite ore has a melting point above 1400 °C, and quartzite ore also has the advantages of high wear resistance, low specific gravity, high strength and low cost; the preferred softening point is
  • the glass composite material between 1100-1350 °C is used to make the cylinder liner of the vehicle engine.
  • the cylinder liner of the vehicle engine has the following advantages: 1 The thermal expansion rate is much lower For metal materials; 2 Can withstand high temperature of 1100-1350 °C for a long time, long-term work at 1100-1350 °C high temperature without deformation; 3 Thermal conductivity is less than 9w/[(mK)] much lower than metal materials; 4 Hardness and wear resistance , Corrosion resistance chemical properties, resistance to cold and heat temperature difference performance are better than metal materials.
  • the cylinder liner of the vehicle engine can withstand a high temperature of 1100-1350°C for a long time, especially because it has 2-3 times higher strength and 15-20 times higher thermal insulation efficiency than existing aluminum alloy or cast iron vehicle engines , the deformation is small at high temperature, so it can be used not only on traditional fuel vehicles, but also on fuel engines of gasoline-electric hybrid vehicles and extended-range electric vehicles.
  • the utilization rate of heat energy can be increased from 30-37% of the traditional technology to 75-85%, and the utilization rate of heat energy can be improved, and the fuel will be more fully burned, which will greatly reduce the harmful gas emitted by the car.
  • a cylinder liner of a marine engine comprising the glass composite material.
  • the cylinder liner of the marine engine is made of the glass composite material.
  • the cylinder liner of the marine engine is made of the glass composite material;
  • the ceramic powder is preferably alumina ceramic powder or zirconia ceramic powder or silicon nitride ceramic powder or silicon carbide ceramic Powder;
  • the natural mineral powder is preferably quartzite ore, quartzite ore has a melting point above 1400 °C, and quartzite ore also has the advantages of high wear resistance, low specific gravity, high strength and low cost; the preferred softening point is
  • the glass composite material between 1100-1350 °C is used to make the cylinder liner of the marine engine, and the cylinder liner of the marine engine has the following advantages compared with the cylinder liner made of traditional metal materials: 1 The thermal expansion rate is much lower For metal materials; 2 Can withstand high temperature of 1100-1350 °C for a long time, long-term work at 1100-1350 °C high temperature without deformation; 3 Thermal conductivity is less than 9w/[(mK)] much lower than metal materials; 4 Hardness and wear resistance , Cor
  • the cylinder liner of the marine engine can withstand a high temperature of 1100-1350°C for a long time, especially because it has 2-3 times higher strength and 15-20 times higher thermal insulation efficiency than the existing aluminum alloy or cast iron marine engine , the property of small deformation at high temperature, the thermal energy utilization rate of the engine using the cylinder liner of the marine engine can be increased from 30-37% of the traditional technology to 75-85%, and the thermal energy utilization rate is improved. The emission of harmful gases from ships is greatly reduced.
  • a heat engine type piston aircraft engine includes an engine cylinder liner, and the engine cylinder liner includes the glass composite material.
  • the engine cylinder liner is made of the glass composite material.
  • the engine cylinder liner is made of the glass composite material;
  • the ceramic powder is preferably alumina ceramic powder or zirconia ceramic powder or silicon nitride ceramic powder or silicon carbide ceramic powder ;
  • the natural mineral powder particles are preferably quartzite ore, which has a melting point above 1400 °C, and the quartzite ore also has the advantages of high wear resistance, low specific gravity, high strength and low cost; the preferred softening point is 1100-
  • the engine cylinder liner is made of the glass composite material at a temperature between 1350 °C and has the following advantages: 1 The thermal expansion rate is much lower than that of the metal material ; 2 Can withstand high temperature of 1100-1350 °C for a long time, and will not be deformed under high temperature of 1100-1350 °C for a long time; 3 The thermal conductivity is less than 9w/[(mK)], which is much lower than that of metal materials; 4 Hardness, wear resistance,
  • the engine cylinder liner can withstand a high temperature of 1100-1350°C for a long time, especially because it has 2-3 times higher strength and 15-20 times higher thermal insulation efficiency than existing aluminum alloy or cast iron engines. Due to the small deformation, the thermal energy utilization rate of the piston aircraft engine can be increased from 30-37% of the traditional technology to 75-85%.
  • a heat engine type turbine engine includes the glass composite material.
  • the surfaces of the combustion chamber of the heat engine type turbine engine and the outer casing of the turbine are covered with a layer of the glass composite material.
  • the thermal conductivity of the glass composite material is less than 9w/[(mK)], which can greatly reduce the heat conduction loss from the combustion chamber and the casing of the turbine, so that the heat engine type turbojet engine or turboprop engine can be greatly reduced.
  • the thermal energy utilization rate of the turboshaft engine can be increased from 50% of the traditional technology to 75-85%.
  • a steam turbine including the glass composite material.
  • the steam chamber wall of the steam turbine and/or the surface layer of the cylinder layer and/or the surface layer of the steam nozzle and/or the surface layer of the steel plate and/or the surface layer of the blade and/or the surface layer of the cylinder body and/or the surface layer of the steam conveying pipe are covered with a layer the glass composite.
  • the thermal conductivity of the glass composite material is less than 9w/[(mK)], which can greatly reduce the heat from the steam chamber wall and/or the cylinder layer surface layer and/or the steam nozzle surface layer and/or the steam turbine. Or the surface layer of the steel disk and/or the blade surface and/or the cylinder surface and/or the steam conveying pipe surface is conducted and lost, so that the thermal energy utilization rate of the steam turbine can be increased from 30-40% of the traditional technology to 75-85%.
  • the surface of the cylinder liner of the piston engine of the generator and/or the casing of the turbocharging system component is covered with a layer of the glass composite material.
  • the thermal conductivity of the glass composite material is less than 9w/[(mK)], and the surfaces of the cylinder liner of the piston engine of the generator and the casing of the turbocharging system component are covered with a layer of the The glass composite material can greatly reduce the heat conduction loss from the cylinder liner and the turbocharging system components, so that the thermal energy utilization rate of the generator can be increased from 30-37% of the traditional technology to 75-85%.
  • a heat engine type glass engine cylinder block includes a cylinder liner including the glass composite material.
  • the cylinder liner is made of the glass composite material.
  • the cylinder liner is made of the glass composite material, so that the fracture strength of the cylinder liner is much higher than that of the existing ceramic engine cylinder liner, and the cylinder liner also has the glass composite material. All the advantages of the material; the existing ceramic engine cylinder liner cannot be produced by the casting process of cast iron (after melting) or the die-casting process of aluminum alloy, the cylinder liner can be produced by the pouring casting process, the production yield is high, and the Industrialized large-scale, standardized production.
  • a heat engine type engine block comprising the glass composite material.
  • the engine block of the heat engine is made of the glass composite material.
  • the engine block of the heat engine is made of the glass composite material, and the engine block of the heat engine can be produced by a pouring and casting process, with a high production yield, and can be industrialized, large-scale, standardized Production; the engine block of the heat engine type has high temperature resistance performance, high strength performance, performance of adapting to the temperature change of rapid cooling and rapid heating, low thermal expansion performance, low thermal conductivity less than 9/[(mK)], ultra-high strength performance, It is superior to existing metal engine blocks in terms of high softening point, high wear resistance and high hardness.
  • a heat engine type engine includes the glass composite material.
  • the surface of the casing of the turbocharger system component of the heat engine type engine is covered with a layer of the glass composite material.
  • the surface of the casing of the turbocharger system component of the heat engine type engine is covered with a layer of the glass composite material, which can greatly reduce the conduction loss of heat from the casing of the turbocharger system component.
  • the cylinder head and/or the piston and/or the piston pin and/or the connecting rod and/or the intake valve and/or the exhaust valve of the thermal engine type are made of the glass composite material.
  • the cylinder head, piston, piston pin, connecting rod, intake valve and exhaust valve of the heat engine type engine are made of the glass composite material, thereby improving the insulation of the heat engine type engine. thermal performance.
  • the cylinder liner of the thermal engine includes an inner layer and an outer layer, the outer layer is made of the glass composite material, and the outer layer is sleeved on the periphery of the inner layer and is connected with the inner layer.
  • the inner layer is made of ceramic material.
  • the outer layer is sleeved on the periphery of the inner layer and forms a fixed connection with the inner layer, and the cylinder liner is a double-layer composite structure; the inner layer is in contact with the piston, and the inner layer is in contact with the piston.
  • the wear resistance of silicon nitride structural ceramics is particularly good, but the thermal conductivity is very high, 25-30w/[(mK)], and there is a disadvantage of poor thermal insulation.
  • the thermal conductivity of the glass composite material is less than 9w/[(mK)]
  • the outer layer is sleeved on the periphery of the inner layer and forms a fixed connection with the inner layer, which can overcome the
  • the disadvantage of poor thermal insulation of silicon nitride structural ceramics makes more thermal energy converted into kinetic energy, and can also highlight the advantages of high wear resistance and high strength of silicon nitride structural ceramics;
  • the cylinder liner is especially suitable for use in cylinders with relatively small diameters. It is used in large vehicles and large ship engines with large displacement.
  • the outer layer and the engine block material can be selected to be sintered together, or the cylinder liner of the thermal engine type can be selected to be a separate cylinder liner, which can be disassembled and replaced during maintenance.
  • a foamed glass material comprising the glass composite material.
  • the foamed glass material is made by adding a foaming agent, a modification additive, and a foaming accelerator on the basis of the components of the glass composite material, that is, the foamed glass material includes a foaming agent , modified additives, foaming accelerators, the glass powder particles and the ceramic powder particles or the natural mineral powder particles or the metal powder particles; the foaming agent, modification additives, foaming accelerators, all After the glass powder and the ceramic powder or the natural mineral powder or the metal powder are mixed uniformly, the foamed glass material is finally formed after re-sintering, and the foamed glass material is filled with numerous openings or The small closed pores and the thermal conductivity of the glass composite material are only 1-5w/[(mK)], so that the thermal conductivity of the foamed glass material is only 0.05-0.1w/[(mK)] ; Since the glass composite material has high strength and breaking strength, the foamed glass material also has high strength and breaking strength.
  • a fiber-containing composite includes the glass composite.
  • the fiber-containing composite material is composed of the glass composite material and fibers, and the fibers include carbon fibers or high-strength glass fibers, that is, the fiber-containing composite material includes fibers, the glass powder and the The ceramic powder or the natural mineral powder or the metal powder; the addition of fibers gives the fiber-containing composite material a higher strength than the glass composite material.
  • a tubular material comprising the glass composite.
  • the tubular material is made of the glass composite material; the tubular material has better thermal insulation properties and strength than other tubular materials.
  • a flat plate material comprising the glass composite material.
  • the flat plate material is made of the glass composite material; the flat plate material also has high strength properties under high temperature conditions, the properties of adapting to temperature changes of rapid cooling and rapid heating, low thermal expansion properties, and low thermal conductivity. 8 advantages of materials with a rate of less than 7w/[(mK)], ultra-high strength performance, high softening point (deformation point), high wear resistance, and high hardness; the flat material is produced by a sintering process and has high production efficiency. , the advantages of low cost and high flatness; the flat material can be used as a thermal insulation sheet, compared with the limit thermal insulation temperature of 280 °C of the traditional organic material thermal insulation sheet, the flat material can reach 1000-1300 °C the ultimate thermal insulation temperature.
  • the present invention may also have other various embodiments. Based on the present embodiment, those of ordinary skill in the art can obtain other embodiments without any creative work, which all belong to the protection scope of the present invention.

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Abstract

L'invention concerne l'utilisation d'un matériau composite de verre ayant un point de ramollissement élevé, un faible coefficient de dilatation thermique, une résistance élevée à l'usure et une faible conductivité thermique dans une turbine à gaz de moteur. Le matériau composite de verre comprend des particules de poudre de verre et des particules de poudre de remplissage, les particules de poudre de remplissage étant des particules de poudre céramique, des particules de poudre minérale naturelle ou des particules de poudre métallique, les particules de poudre de verre sont frittées pour lier et envelopper les particules de poudre céramique, les particules de poudre minérale naturelle ou les particules de poudre métallique, et la température de ramollissement du matériau composite de verre est > 850 °C. Le matériau composite de verre selon la présente invention présente les huit avantages d'une performance de résistance élevée dans un état à haute température, une performance de changement de température d'adaptation lors d'un refroidissement et d'un chauffage rapides, une faible performance de dilatation thermique, une faible conductivité thermique inférieure à 9 w/[(m.K)], une performance de résistance très élevée, un point de ramollissement élevé (point de déformation), une résistance élevée à l'usure et une performance de dureté élevée.
PCT/CN2021/111675 2020-09-15 2021-08-10 Utilisation d'un matériau composite de verre ayant un point de ramollissement élevé, un faible coefficient de dilatation thermique, une résistance élevée à l'usure et une faible conductivité thermique dans une turbine à gaz de moteur WO2022057518A1 (fr)

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CN202010968954.7 2020-09-15
CN202010968954.7A CN112145304A (zh) 2020-09-15 2020-09-15 一种具有高热能利用率的车辆
CN202010989365 2020-09-18
CN202010989365.7 2020-09-18
CN202011054021.3 2020-09-30
CN202011054021 2020-09-30
CN202011080648.6 2020-10-10
CN202011080648 2020-10-10
CN202011507153.7A CN112500172B (zh) 2020-05-11 2020-12-18 一种高软化点、低热膨胀系数、高耐磨、低热导率的玻璃复合材料在发动机气轮机中的应用
CN202011507153.7 2020-12-18

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PCT/CN2021/116667 WO2022057654A1 (fr) 2020-09-15 2021-09-06 Utilisation d'un matériau composite de verre de nitrure de silicium à faible dilatation thermique, à faible conductivité thermique, à faible coefficient de frottement et à faible diffusivité thermique dans un moteur
PCT/CN2021/116665 WO2022057653A1 (fr) 2020-09-15 2021-09-06 Utilisation d'une composition bicouche de matériau céramique de nitrure de silicium et matériau de verre dans un moteur

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PCT/CN2021/116665 WO2022057653A1 (fr) 2020-09-15 2021-09-06 Utilisation d'une composition bicouche de matériau céramique de nitrure de silicium et matériau de verre dans un moteur

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WO2022057518A1 (fr) * 2020-09-15 2022-03-24 深圳前海发维新材料科技有限公司 Utilisation d'un matériau composite de verre ayant un point de ramollissement élevé, un faible coefficient de dilatation thermique, une résistance élevée à l'usure et une faible conductivité thermique dans une turbine à gaz de moteur
CN114163244B (zh) * 2021-12-27 2022-10-14 中国科学院上海硅酸盐研究所 一种外硬内韧氮化硅陶瓷及其制备方法
CN116253299B (zh) * 2023-02-20 2024-06-14 安徽工业大学 一种利用含硅固废制备杂质包覆型Si2N2O的方法、制备所得Si2N2O及其应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0538565A (ja) * 1991-08-01 1993-02-19 Toyota Motor Corp 鋳ぐるみ用セラミツク焼成体
CN1483009A (zh) * 2001-11-05 2004-03-17 旭硝子株式会社 玻璃陶瓷组合物
CN102912163A (zh) * 2012-10-23 2013-02-06 陕西科技大学 一种玻璃/金属复合材料及其制备方法
CN105174972A (zh) * 2015-09-10 2015-12-23 电子科技大学 一种玻璃/陶瓷纳米复合材料的制备方法
EP3650427A1 (fr) * 2018-11-07 2020-05-13 Honeywell International Inc. Procédé de formation d'un revêtement protecteur sur une surface d'un substrat en céramique
CN112500172A (zh) * 2020-05-11 2021-03-16 深圳前海发维新材料科技有限公司 一种玻璃复合材料及其生产方法和应用

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0639940B2 (ja) * 1987-12-25 1994-05-25 いすゞ自動車株式会社 ピストン、シリンダヘツド等の内燃機関のエンジン部品
US5198302A (en) * 1990-04-23 1993-03-30 Corning Incorporated Coated inorganic fiber reinforcement materials and ceramic composites comprising the same
US5256603A (en) * 1992-11-19 1993-10-26 Corning Incorporated Glass bonded ceramic composites
DE69821608T2 (de) * 1997-03-21 2004-12-16 Electro-Science Laboratories, Inc. Siliziumnitridbeschichtungszusammensetzungen
JP2000039032A (ja) * 1998-04-21 2000-02-08 Carl Zeiss:Fa トルク伝達装置の摩擦ライニング
DE10000836B4 (de) * 2000-01-12 2005-03-17 Schott Ag Alkalifreies Aluminoborosilicatglas und dessen Verwendungen
US6630417B2 (en) * 2000-05-30 2003-10-07 Kyocera Corporation Porcelain composition, porcelain and method of producing the same, and wiring board and method of producing the same
CN1666969A (zh) * 2004-03-12 2005-09-14 常州华盛天龙机械有限公司 玻璃包覆热等静压制备高性能氮化硅陶瓷
DE102006056209B4 (de) * 2006-11-29 2009-09-10 Schott Ag Panzermaterial und Verfahren zu dessen Herstellung
JPWO2013125704A1 (ja) * 2012-02-22 2015-07-30 日本碍子株式会社 エンジン燃焼室構造、および流路の内壁構造
WO2013133300A1 (fr) * 2012-03-09 2013-09-12 旭硝子株式会社 Corps en vitrocéramique, stratifié, logement destiné à un équipement électronique portable et équipement électronique portable
CN103360078A (zh) * 2012-04-05 2013-10-23 深圳光启创新技术有限公司 一种氮化硅复合材料的制备方法及其制备的基板
EP2894137A4 (fr) * 2012-09-10 2016-04-20 Ngk Insulators Ltd Matériau composite de verre et de céramique
KR102370665B1 (ko) * 2014-03-05 2022-03-03 어플라이드 머티어리얼스, 인코포레이티드 챔버 입자들을 감소시키기 위한 중요 챔버 구성요소 표면 개선
CN105016738B (zh) * 2014-04-30 2017-07-14 广东工业大学 氮化硅陶瓷及其制备方法
EP3225351B1 (fr) * 2016-03-30 2020-05-06 General Electric Company Compositions de brasage de structures de brasure ductile et dispositifs et procédés associés
CN110028246B (zh) * 2019-05-08 2021-08-03 哈尔滨工业大学 一种玻璃焊料及其制备方法和应用
CN111233319A (zh) * 2019-12-26 2020-06-05 杨德宁 一种铝硼硅的玻璃组合物的应用
CN111348829A (zh) * 2020-04-29 2020-06-30 杨德宁 一种高软化点防火高温玻璃组合物的应用
CN111253065A (zh) * 2019-12-26 2020-06-09 杨德宁 一种高软化点的玻璃组合物的应用
CN112145304A (zh) * 2020-09-15 2020-12-29 深圳前海发维新材料科技有限公司 一种具有高热能利用率的车辆
CN111499189A (zh) * 2020-05-11 2020-08-07 杨德宁 一种高软化点玻璃材料在发动机气缸体的应用
WO2022057518A1 (fr) * 2020-09-15 2022-03-24 深圳前海发维新材料科技有限公司 Utilisation d'un matériau composite de verre ayant un point de ramollissement élevé, un faible coefficient de dilatation thermique, une résistance élevée à l'usure et une faible conductivité thermique dans une turbine à gaz de moteur

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0538565A (ja) * 1991-08-01 1993-02-19 Toyota Motor Corp 鋳ぐるみ用セラミツク焼成体
CN1483009A (zh) * 2001-11-05 2004-03-17 旭硝子株式会社 玻璃陶瓷组合物
CN102912163A (zh) * 2012-10-23 2013-02-06 陕西科技大学 一种玻璃/金属复合材料及其制备方法
CN105174972A (zh) * 2015-09-10 2015-12-23 电子科技大学 一种玻璃/陶瓷纳米复合材料的制备方法
EP3650427A1 (fr) * 2018-11-07 2020-05-13 Honeywell International Inc. Procédé de formation d'un revêtement protecteur sur une surface d'un substrat en céramique
CN112500172A (zh) * 2020-05-11 2021-03-16 深圳前海发维新材料科技有限公司 一种玻璃复合材料及其生产方法和应用

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