WO2021251723A1 - Composition de shampoing avec après-shampoing ayant une structure lamellaire - Google Patents

Composition de shampoing avec après-shampoing ayant une structure lamellaire Download PDF

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WO2021251723A1
WO2021251723A1 PCT/KR2021/007140 KR2021007140W WO2021251723A1 WO 2021251723 A1 WO2021251723 A1 WO 2021251723A1 KR 2021007140 W KR2021007140 W KR 2021007140W WO 2021251723 A1 WO2021251723 A1 WO 2021251723A1
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Prior art keywords
shampoo composition
weight
lamellar structure
composition
shampoo
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PCT/KR2021/007140
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English (en)
Korean (ko)
Inventor
최주희
노민주
김현나
강병하
이준배
박명삼
Original Assignee
코스맥스 주식회사
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Priority claimed from KR1020210073244A external-priority patent/KR102500882B1/ko
Application filed by 코스맥스 주식회사 filed Critical 코스맥스 주식회사
Publication of WO2021251723A1 publication Critical patent/WO2021251723A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a shampoo composition having a lamellar structure comprising an anionic surfactant, a nonionic surfactant, a higher alcohol and a conditioning agent.
  • the hair of modern people is polluted due to exposure to ultraviolet rays, contact with the surrounding environment such as dust, and sebum secreted from the hair follicles, and frequent perming, hair drying, dyeing, combing, etc. cause considerable damage. Damaged hair, when wet or dry, is difficult to handle, such as hard to comb due to severe tangles and stiffness, and shows an unsightly appearance due to lack of luster. Accordingly, consumers' demand and preference for conditioning products that improve the appearance and feel of hair and make it easier to handle are increasing day by day.
  • Conditioning shampoo refers to a product that has a cleansing effect that removes contamination from the hair and scalp and a conditioning effect that makes damaged hair easy to handle and shiny and soft. Accordingly, the conditioning shampoo composition is used for the purpose of improving the texture and visual benefits of hair, for example, softness, flexibility, gloss, anti-static, ease of combing, and the like, in addition to an appropriate cleaning effect.
  • Recent shampoos contain cationic surfactants, hydrocarbon oils, fatty alcohols or silicones as conditioning agents to impart a conditioning effect.
  • cationic surfactants reduce friction during rinsing to make hair smooth, and increase hair adsorption of other water-insoluble conditioning substances, they also stimulate the scalp and are complexes with anionic polymers used as stabilizers. tends to form and precipitate.
  • hydrocarbon oils and fatty alcohols are known to provide softness to the hair and prevent static electricity, but have a disadvantage of inhibiting air bubbles by forming a complex with an anionic surfactant used for washing.
  • non-volatile silicone oil and polymer silicone gum commonly used in hair conditioning agents give shine and flexibility to the hair and provide softness to the hair after drying, while lacking moisturizing properties and poor compatibility with other ingredients. Due to its compatibility, there is a limitation in its utility, and when used repeatedly for a long period of time, it accumulates on the hair, reducing softness and accelerating recontamination by dust and sebum.
  • the silicone oil acts as an antifoaming agent such as oil in the shampoo composition, remarkably lowering the cleaning ability of the anionic surfactant.
  • the present inventors made an effort to form a lamellar structure by mixing an anionic surfactant, a nonionic surfactant, a higher alcohol, and a conditioning agent in an appropriate amount, thereby making a shampoo composition having an excellent hair conditioning effect.
  • a conditioning shampoo composition having a lamellar structure comprising an anionic surfactant, a nonionic surfactant, a higher alcohol, and a conditioning agent.
  • the present invention relates to a conditioning shampoo composition having a lamellar structure comprising an anionic surfactant, a nonionic surfactant, a higher alcohol and a conditioning agent, and the present inventors provide an anionic surfactant, a nonionic surfactant, a higher alcohol, and a conditioning agent was formulated in an appropriate amount to form a lamellar structure, and through this, it was confirmed that an excellent hair conditioning effect was exhibited and the hair feeling was improved.
  • One example of the present invention relates to a shampoo composition comprising a lamellar structure composition.
  • the lamellar structure composition may include an anionic surfactant, a nonionic surfactant, and an oil phase.
  • the oil phase may include a higher alcohol and a conditioning agent.
  • a composition for forming a lamellar structure when a composition for forming a lamellar structure is prepared and used, such a composition may mean that it can play an important role in skin moisturizing and barrier function.
  • This is an emulsified form of a valve structure composed of phospholipids, and this may be due to the structural characteristics of the lamellar structure in which the oil layer and the aqueous layer are sequentially stacked blocks.
  • the lamellar structure is divided into a lamellar gel tissue and a lamellar liquid crystal, and the emulsion including this structure has high stability, drug release control, ease of manufacture, excellent feeling of use, maintenance of moisturizing effect, etc. has the advantage of Lamella is a plate-like structure composed of phospholipids, oily membranes, and aqueous membranes, and is very similar to the structure of intercellular lipids of the stratum corneum of the skin, and this structure prevents moisture evaporation of the skin.
  • the lamellar structure composition is 1.0 to 50.0% by weight, 1.0 to 45.0% by weight, 1.0 to 40.0% by weight, 1.0 to 35.0% by weight, 5.0 to 50.0% by weight, 5.0 to 45.0% by weight based on the total shampoo composition , 5.0-40.0 wt%, 5.0-35.0 wt%, 10.0-50.0 wt%, 10.0-45.0 wt%, 10.0-40.0 wt%, 10.0-35.0 wt%, 15.0-50.0 wt%, 15.0-45.0 wt%, 15.0 to 40.0% by weight, 15.0 to 35.0% by weight, 20.0 to 50.0% by weight, 20.0 to 45.0% by weight, 20.0 to 40.0% by weight, 20.0 to 35.0% by weight, for example, 32.0% by weight. it is not
  • the lamellar structure composition has a weight ratio of anionic surfactant and oil phase of 5:1 to 20:1, 5:1 to 18:1, 5:1 to 16:1, 5:1 to 14:1, 5.5 : 1 to 20:1, 5.5:1 to 18:1, 5.5:1 to 16:1, 5.5:1 to 14:1, 5.5:1 to 12:1, for example, it may be 5.56:1 , but is not limited thereto.
  • the lamellar structure composition contains 0.1 to 30.0 wt%, 0.1 to 28.0 wt%, 0.1 to 26.0 wt%, 0.1 to 20.0 wt%, 0.1 to 15.0 wt%, 0.1 of the anionic surfactant based on the total shampoo composition to 10.0 wt%, 0.1 to 5.0 wt%, 1.0 to 30.0 wt%, 1.0 to 28.0 wt%, 1.0 to 26.0 wt%, 1.0 to 20.0 wt%, 1.0 to 15.0 wt%, 1.0 to 10.0 wt%, 1.0 to 5.0-30.0 wt%, 5.0-28.0 wt%, 5.0-26.0 wt%, 10.0-30.0 wt%, 10.0-28.0 wt%, 10.0-26.0 wt%, 15.0-30.0 wt%, 15.0-28.0 wt%, 10.0-26.0 wt%, 15.0-30.0 wt%, 15.0-28.0 wt%,
  • the anionic surfactant is sodium cocoyl ethionate, disodium laureth sulfosuccinate, sodium C14-16 olefin sulfonate, sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate, ammonium Laureth Sulfate, Sodium Methyl Cocoyl Taurate, Sodium Lauroyl Glutamate, Sodium Myristoyl Glutamate, Potassium Cocoyl Glycinate, Sodium Cocoyl Glycinate, Sodium Cocoyl Alaninate, Potassium Cocoyl Glutamate and Sodium Lau It may be at least one selected from the group consisting of royl sarcosinate, but is not limited thereto.
  • the lamellar structure composition contains 0.01 to 5.0% by weight of a nonionic surfactant, 0.01 to 4.5% by weight, 0.01 to 4.0% by weight, 0.01 to 3.5% by weight, 0.01 to 3.0% by weight, based on the total shampoo composition, 0.01 to 2.5% by weight, 1.0 to 5.0% by weight, 1.0 to 4.5% by weight, 1.0 to 4.0% by weight, 1.0 to 3.5% by weight, 1.0 to 3.0% by weight, 1.0 to 2.5% by weight, 1.5 to 5.0% by weight, 1.5 to 4.5 wt%, 1.5 to 4.0 wt%, 1.5 to 3.5 wt%, 1.5 to 3.0 wt%, 1.5 to 2.5 wt%, 2.0 to 5.0 wt%, 2.0 to 4.5 wt%, 2.0 to 4.0 wt%, 2.0 to 3.5 wt% %, 2.0 to 3.0% by weight, for example, may be included in 2.5% by weight, but is not limited thereto.
  • the nonionic surfactant is cocamide MEA, lauramide MEA, lauramide mipa, cocamide mipa, decyl glucoside, coco glucoside, PG-3 caprylyl ether, lauryl glucoside, Isostearamide mipa, stearamide mipa, oleamide mipa, myristamide mipa, PG-3 cocamide DI and stearamide DI may be at least one selected from the group consisting of, but It is not limited.
  • the lamellar structure composition has a higher alcohol content of 0.01 to 5.0% by weight, 0.01 to 4.5% by weight, 0.01 to 4.0% by weight, 0.01 to 3.5% by weight, 0.01 to 3.0% by weight, 0.01 based on the total shampoo composition to 2.5 wt%, 1.0 to 5.0 wt%, 1.0 to 4.5 wt%, 1.0 to 4.0 wt%, 1.0 to 3.5 wt%, 1.0 to 3.0 wt%, 1.0 to 2.5 wt%, 1.5 to 5.0 wt%, 1.5 to 4.5 wt% wt%, 1.5-4.0 wt%, 1.5-3.5 wt%, 1.5-3.0 wt%, 1.5-2.5 wt%, 2.0-5.0 wt%, 2.0-4.5 wt%, 2.0-4.0 wt%, 2.0-3.5 wt% , 2.0 to 3.0% by weight, for example, may be included in 2.5% by weight, but is not limited thereto.
  • the higher alcohols may be at least one selected from the group consisting of cetearyl alcohol, cetyl alcohol, stearyl alcohol, lauryl alcohol, myristyl alcohol, behenyl alcohol and C14-22 alcohol, but It is not limited.
  • the lamellar structure composition contains a conditioning agent of 0.01 to 10.0% by weight, 0.01 to 8.0% by weight, 0.01 to 6.0% by weight, 0.01 to 4.0% by weight, 1.0 to 10.0% by weight, 1.0 to 8.0 based on the total shampoo composition.
  • the present invention is not limited thereto.
  • the conditioning agent is caprylic/capric triglyceride, C12-13 alkyl lactate, di-C12-13 alkyl maleate, dimer dilinoleyl dimer dilinoleate, glyceryl oleate, At least one selected from the group consisting of glycol distearate, lauryl lactate, dicaprylyl ether and cocoglycerize may be additionally included, but the present invention is not limited thereto.
  • the shampoo composition may include one or more selected from the group consisting of amphoteric surfactants, cationic polymers, purified water, fragrances, pH adjusters and preservatives, but is not limited thereto.
  • the amphoteric surfactant is lauramidopropyl betaine, cocamidopropyl betaine, lauryl hydroxysultaine, coco-betaine, lauryl betaine, disodium cocoamphodiacetate, sodium cocoamphodi
  • At least one selected from the group consisting of acetate, lauramidopropyl hydroxysultaine, cocamidopropyl hydroxysultaine, sodium sweet almond amphoacetate, sodium lauroamphoacetate and barbasuamidopropyl betaine is additionally included
  • the present invention is not limited thereto.
  • the shampoo composition is a cationic polymer 0.01 to 0.5% by weight, 0.01 to 0.4% by weight, 0.01 to 0.3% by weight, 0.01 to 0.2% by weight, 0.01 to 0.1% by weight, 0.1 to 0.5% by weight, 0.1 to 0.4 % by weight, 0.2 to 0.5% by weight, 0.2 to 0.4% by weight, for example, 0.3% by weight may be included, but is not limited thereto.
  • the cationic polymer is polyquaternium-10, polyquaternium-7, polyquaternium-22, polyquaternium-47, polyquaternium-67, guarhydroxypropyltrimonium chloride and hydroxypropylguar. At least one selected from the group consisting of hydroxypropyltrimonium chloride may be additionally included, but is not limited thereto.
  • the pH adjusting agent may be one or more selected from the group consisting of tromethamine, sodium hydroxide, potassium hydroxide, citric acid and sodium citrate, but is limited thereto no.
  • the preservative may be one or more selected from the group consisting of 1,2-hexanediol, pentylene glycol, ethylhexyl glycerin, phenoxyethanol and caprylyl glycol. It is not limited.
  • the present invention relates to a conditioning shampoo composition having a lamellar structure, and by mixing an anionic surfactant, a nonionic surfactant, a higher alcohol, and a conditioning agent in an appropriate mixing ratio, the lamellar structure is effectively formed to improve the feeling of hair conditioning use It has excellent cleaning performance, has the advantage of excellent conditioning for hair, and has the effect of resolving the problem of sticky and stiff feeling of use of existing shampoo compositions.
  • Example 1 is a graph showing the results of confirming the lamellar structure of Example 1 according to an experimental example of the present invention.
  • Example 2 is a graph showing the results of confirming the lamellar structure of Example 2 according to an experimental example of the present invention.
  • Example 3 is a graph showing the results of confirming the lamellar structure of Example 3 according to an experimental example of the present invention.
  • FIG. 6 is a graph showing the results of evaluating the comb texture of wet hair after using Examples 1 to 3 and Comparative Examples 6 and 7 according to an experimental example of the present invention.
  • anionic surfactants nonionic surfactants; And it relates to a shampoo composition comprising a lamellar structure comprising a; and an oil phase comprising a higher alcohol and a conditioning agent.
  • Examples 1 to 3 were prepared according to each component and content shown in Table 1 below.
  • Example 2 Example 3 One Prime Minister anionic surfactant Disodium Laureth Sulfosuccinate 15.0 3.0 1.5 2 Prime Minister Sodium Cocoyl Cethionate 10.0 2.0 1.0 3 paid part nonionic surfactant Lauramide mipa 2.5 0.5 0.25 4 paid part oil phase high-grade alcohol cetearyl alcohol 2.5 0.5 0.25 5 paid part Conditioning agent (moisture blocker) Caprylic/Capric Triglycerides 2.0 0.4 0.2 6 Prime Minister anionic surfactant Disodium Laureth Sulfosuccinate - 1.8 9.6 7 Prime Minister anionic surfactant Sodium C14-16 Olefinsulfonate - 9.1 - 8 Prime Minister amphoteric surfactant Lauramidopropyl Betaine - 1.8 - 9 Prime Minister amphoteric surfactant Cocamidopropyl Betaine - - 3.6 10 Prime Minister amphoteric surfactant lauryl hydroxysultaine - 1.5 - 11 Prime Minister cationic
  • purified water, anionic surfactant, and pH adjuster were weighed in a beaker and then uniformly mixed at a temperature of 80 to 85° C. at 500 rpm for 5 minutes using an Agimixer to prepare an aqueous phase.
  • the mixture was mixed with the aqueous phase at a temperature of 80 to 85° C. and uniformly mixed for 5 minutes using a homomixer.
  • Example 1 was prepared by removing air bubbles.
  • Example 1 The remaining raw materials were weighed and added to Example 1 prepared above.
  • Examples 2 and 3 were prepared by uniformly mixing with an agitator at room temperature.
  • the input of the component is for the feeling of use of the shampoo for the purpose of increasing the foaming power, not the purpose of forming a lamellar structure.
  • compositions of Examples 1, 2 and 3 were obtained to form a lamellar structure.
  • Comparative Examples 1 to 7 were prepared according to each component and content shown in Table 2 below.
  • Purified water, anionic surfactant, and pH adjuster among the components listed in Table 2 were weighed in a beaker and then uniformly mixed at a temperature of 80 to 85° C. at 500 rpm for 5 minutes using an Agimixer to prepare an aqueous phase. After weighing the higher alcohol, nonionic surfactant, and oil as the oil phase in a beaker, the mixture was mixed with the aqueous phase at a temperature of 80 to 85° C. and uniformly mixed for 5 minutes using a homomixer. Then, after cooling to 30 °C, the bubbles were removed to prepare Comparative Examples 1 to 5.
  • Comparative Example 6 all the raw materials were weighed in a beaker and then uniformly mixed for 10 minutes at 500 rpm at room temperature using an Agi-mixer, and then bubbles were removed to prepare the contents.
  • Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 7 Ratio of (anionic surfactant)/(oil phase) 5.56 5.56 5.56 7.5 6.25 12.5 12.5 12.5 5.56
  • the interfacial area was calculated using a Small Angle X-ray Scattering (SAXS) device.
  • SAXS Small Angle X-ray Scattering
  • the small-angle X-ray scattering device uses a scattering phenomenon that occurs at a very small angle in proportion to the interfacial area between the structure and the particles, and can calculate the interfacial area by analyzing the scattering curve.
  • Example 1 the q-value (x-axis) ratio was observed to be 1:2:3:4, confirming that a lamellar structure was formed.
  • Example 2 the q-value (x-axis) ratio was observed to be 1: 2, and a lamellar structure was formed, and as shown in FIG. 3, Example 3 had a q-value (x-axis) A ratio of 1: 2 was observed to confirm that a lamellar structure was formed.
  • Comparative Example 5 additionally contains a nonionic surfactant, but the addition of the nonionic surfactant did not help much when forming the lamellar structure, so the main factor in forming the lamellar structure is (anionic surfactant phase) / It is the ratio of (oil phase), and the higher this ratio, the more it means that the formation of the lamellar structure is hindered.
  • the weight ratio of the anionic surfactant to the oil phase and the content of the lamellar structure composition were important to form the lamellar structure.
  • the weight ratio of the anionic surfactant to the oil phase is not limited to 5.56:1, and since the amount of the anionic surfactant activated due to the combination of the anionic surfactant and the cationic polymer decreases, even at a weight ratio other than 5.56:1, the lamellar structure could be observed.
  • the Work (J) value is a value indicating the degree of force applied to combing, that is, the goodness of brushing.
  • the cationic polymer and the surfactant work together to form a (+) charged complex called coacervate on the hair surface. This is because it coats and softens it.
  • the Work (J) value is a value indicating the degree of force applied to combing, that is, the goodness of brushing.
  • the present invention relates to a shampoo composition having a lamellar structure comprising an anionic surfactant, a nonionic surfactant, a higher alcohol and a conditioning agent.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
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Abstract

La présente invention concerne une composition de shampoing avec après-shampoing formant une structure lamellaire et peut fournir une composition de shampoing ayant un excellent effet d'après-shampoing.
PCT/KR2021/007140 2020-06-11 2021-06-08 Composition de shampoing avec après-shampoing ayant une structure lamellaire WO2021251723A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2020-0071106 2020-06-11
KR20200071106 2020-06-11
KR1020210073244A KR102500882B1 (ko) 2020-06-11 2021-06-07 라멜라 구조를 갖는 컨디셔닝 샴푸 조성물
KR10-2021-0073244 2021-06-07

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WO2021251723A1 true WO2021251723A1 (fr) 2021-12-16

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19990036226A (ko) * 1995-08-07 1999-05-25 알 브이 테이트 (로드니 비버스 테이트), 에이치 드로이. 씨. 지. 오닌크, 이. 에디, 산드라 웨드워즈 (에스 제이 에드워즈) 라멜라상을 유도하는 가용성 구조제를 포함하는 액체 세정조성물
KR20090087470A (ko) * 2006-12-08 2009-08-17 유니레버 엔.브이. 농축 계면활성제 조성물
US20130090279A1 (en) * 2011-10-07 2013-04-11 The Procter & Gamble Company Shampoo Composition Containing a Gel Network
KR20160014306A (ko) * 2014-07-29 2016-02-11 아인코스 주식회사 호두 및 밤 복합 발효추출물의 나노 에멀젼을 함유하는 탈모방지 및 발모촉진 화장료 조성물
KR101851388B1 (ko) * 2017-08-25 2018-06-07 주식회사 세화 피앤씨 진세노사이드의 경피흡수 촉진용 조성물, 이의 제조방법 및 상기 조성물을 함유하는 탈모방지 화장료 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19990036226A (ko) * 1995-08-07 1999-05-25 알 브이 테이트 (로드니 비버스 테이트), 에이치 드로이. 씨. 지. 오닌크, 이. 에디, 산드라 웨드워즈 (에스 제이 에드워즈) 라멜라상을 유도하는 가용성 구조제를 포함하는 액체 세정조성물
KR20090087470A (ko) * 2006-12-08 2009-08-17 유니레버 엔.브이. 농축 계면활성제 조성물
US20130090279A1 (en) * 2011-10-07 2013-04-11 The Procter & Gamble Company Shampoo Composition Containing a Gel Network
KR20160014306A (ko) * 2014-07-29 2016-02-11 아인코스 주식회사 호두 및 밤 복합 발효추출물의 나노 에멀젼을 함유하는 탈모방지 및 발모촉진 화장료 조성물
KR101851388B1 (ko) * 2017-08-25 2018-06-07 주식회사 세화 피앤씨 진세노사이드의 경피흡수 촉진용 조성물, 이의 제조방법 및 상기 조성물을 함유하는 탈모방지 화장료 조성물

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