WO2021251252A1 - 蛍光板、波長変換部材、および、光源装置 - Google Patents
蛍光板、波長変換部材、および、光源装置 Download PDFInfo
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- WO2021251252A1 WO2021251252A1 PCT/JP2021/021145 JP2021021145W WO2021251252A1 WO 2021251252 A1 WO2021251252 A1 WO 2021251252A1 JP 2021021145 W JP2021021145 W JP 2021021145W WO 2021251252 A1 WO2021251252 A1 WO 2021251252A1
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- Prior art keywords
- fluorescent plate
- fluorescent
- voids
- phase
- light
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- 238000006243 chemical reaction Methods 0.000 title claims description 30
- 230000005284 excitation Effects 0.000 claims abstract description 18
- 239000011800 void material Substances 0.000 claims description 27
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- 239000010949 copper Substances 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- JVPLOXQKFGYFMN-UHFFFAOYSA-N gold tin Chemical compound [Sn].[Au] JVPLOXQKFGYFMN-UHFFFAOYSA-N 0.000 description 3
- 230000017525 heat dissipation Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
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- 229910052737 gold Inorganic materials 0.000 description 2
- 239000011361 granulated particle Substances 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
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- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
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- 239000012141 concentrate Substances 0.000 description 1
- WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 description 1
- SBYXRAKIOMOBFF-UHFFFAOYSA-N copper tungsten Chemical compound [Cu].[W] SBYXRAKIOMOBFF-UHFFFAOYSA-N 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7774—Aluminates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/44—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V29/00—Protecting lighting devices from thermal damage; Cooling or heating arrangements specially adapted for lighting devices or systems
- F21V29/50—Cooling arrangements
- F21V29/502—Cooling arrangements characterised by the adaptation for cooling of specific components
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V29/00—Protecting lighting devices from thermal damage; Cooling or heating arrangements specially adapted for lighting devices or systems
- F21V29/50—Cooling arrangements
- F21V29/70—Cooling arrangements characterised by passive heat-dissipating elements, e.g. heat-sinks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V7/00—Reflectors for light sources
- F21V7/22—Reflectors for light sources characterised by materials, surface treatments or coatings, e.g. dichroic reflectors
- F21V7/24—Reflectors for light sources characterised by materials, surface treatments or coatings, e.g. dichroic reflectors characterised by the material
- F21V7/26—Reflectors for light sources characterised by materials, surface treatments or coatings, e.g. dichroic reflectors characterised by the material the material comprising photoluminescent substances
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V9/00—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters
- F21V9/30—Elements containing photoluminescent material distinct from or spaced from the light source
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V9/00—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters
- F21V9/30—Elements containing photoluminescent material distinct from or spaced from the light source
- F21V9/32—Elements containing photoluminescent material distinct from or spaced from the light source characterised by the arrangement of the photoluminescent material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
- G03B21/14—Details
- G03B21/16—Cooling; Preventing overheating
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
- G03B21/14—Details
- G03B21/20—Lamp housings
- G03B21/2006—Lamp housings characterised by the light source
- G03B21/2033—LED or laser light sources
- G03B21/204—LED or laser light sources using secondary light emission, e.g. luminescence or fluorescence
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B21/00—Projectors or projection-type viewers; Accessories therefor
- G03B21/14—Details
- G03B21/20—Lamp housings
- G03B21/2066—Reflectors in illumination beam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
- F21Y2115/00—Light-generating elements of semiconductor light sources
- F21Y2115/10—Light-emitting diodes [LED]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
- F21Y2115/00—Light-generating elements of semiconductor light sources
- F21Y2115/30—Semiconductor lasers
Definitions
- the present invention relates to a fluorescent screen, a wavelength conversion member, and a light source device.
- Patent Document 1 discloses a technique for compounding YAG: Ce, which is a phosphor material, in Al 2 O 3 which is a translucent phase.
- Patent Document 2 discloses a technique for scattering light in a void by utilizing the difference in refractive index between the fluorescent phase and the translucent phase and the void.
- An object of the present invention is to provide a technique for improving the durability against thermal shock while improving the light extraction efficiency in a fluorescent plate.
- the present invention has been made to solve at least a part of the above-mentioned problems, and can be realized as the following forms.
- a fluorescent plate includes a fluorescent phase that emits fluorescence by excitation light and a plurality of voids, and the plurality of voids have a plurality of specific voids having a circle equivalent diameter of 0.4 ⁇ m or more and 50 ⁇ m or less, and the fluorescent plate.
- the ratio of the number of the specific voids having a circularity of more than 0.6 and 1 or less among the plurality of specific voids is 50% or more.
- the fluorescent plate has a plurality of voids, and the light inside the fluorescent plate is scattered on the surface of the fluorescent phase in the plurality of voids, so that the light extraction efficiency can be improved.
- the plurality of voids have a plurality of specific voids having a circle equivalent diameter of 0.4 ⁇ m or more and 50 ⁇ m or less.
- 50% or more of the specific voids included in the cross section have a circularity of more than 0.6 and 1 or less. That is, the fluorescent plate has a large number of specific voids having a shape relatively close to a circle.
- the fluorescent plate having a large number of specific voids having such a shape is less likely to be damaged by thermal shock. As a result, it is possible to improve the durability against thermal shock while improving the light extraction efficiency.
- the ratio of the specific voids having a circularity of more than 0.6 and 1 or less among the plurality of specific voids may be 70% or more.
- 70% or more of the specific voids included in the cross section have a circularity of more than 0.6 and 1 or less.
- the ratio of the specific voids having a circularity smaller than 0.4 among the plurality of specific voids may be 8% or less.
- the number of specific voids having a circularity smaller than 0.4 is 8% or less of the plurality of specific voids included in the cross section.
- the ratio of the specific voids having a circularity smaller than 0.4 among the plurality of specific voids may be 3% or less.
- the number of specific voids having a circularity smaller than 0.4 is 3% or less of the plurality of specific voids included in the cross section.
- the fluorescent plate of the above embodiment further includes a translucent phase that transmits the excitation light, and is the sum of the fluorescent phase and the translucent phase that occupy the fluorescent plate in the cross section of the fluorescent plate including the cross section of the void.
- the area ratio of the fluorescent phase to the light of the fluorescent phase may be 95% or less.
- a wavelength conversion member includes the above-mentioned fluorescent plate and a reflective member arranged on the fluorescent plate and reflecting the excitation light and the fluorescence.
- the wavelength conversion member includes a reflection member that reflects the fluorescence emitted from the fluorescent plate and the excitation light.
- the wavelength conversion member of the above-described form may further include a heat-dissipating member that releases the heat of the fluorescent plate to the outside.
- the wavelength conversion member includes a heat radiating member that releases the heat of the fluorescent plate to the outside.
- a light source device may include the above-mentioned wavelength conversion member and a light source for irradiating the fluorescent plate with the excitation light.
- the light source device includes a light source that irradiates the fluorescent plate with excitation light.
- the fluorescent plate emits fluorescence by the excitation light. Since the emitted fluorescence is reflected on the exposed surface of the fluorescent phase that is exposed in a relatively large amount in the void, the amount of fluorescence emitted to the outside of the fluorescent plate increases. Thereby, the light emission intensity of the light source device can be improved.
- the present invention can be realized in various aspects, for example, a method for manufacturing a fluorescent screen, a method for manufacturing a wavelength conversion member, a method for manufacturing a light source device, a system including a light source device, a method for controlling a light source device, and the like. It can be realized in the form of a computer program or the like for causing the manufacturing device to manufacture the light source device.
- FIG. 1 It is a schematic diagram of the light source apparatus provided with the fluorescent plate of 1st Embodiment. It is an enlarged sectional view of a fluorescent plate. This is an example of the result of image processing of a sample SEM photograph. It is a figure which shows the result of the evaluation test of a sample.
- FIG. 1 is a schematic view of a light source device 3 including the fluorescent screen 1 of the first embodiment.
- the fluorescent plate 1 of the present embodiment is different from the light L1 when it is irradiated with the light L1 emitted by the light source 9 such as a light emitting diode (LED: Light Emitting Diode) or a semiconductor laser (LD: Laser Diode) included in the light source device 3. It emits light of a wavelength as fluorescence.
- the fluorescence emitted by the fluorescence plate 1 is radiated in a predetermined direction as light L2 together with the light that did not contribute to the generation of fluorescence in the fluorescence plate 1. As shown in FIG.
- the light source device 3 of the present embodiment is a reflection type light source device and is used in various optical devices such as head lamps, lighting, and projectors.
- the light source device 3 includes the above-mentioned light source 9 and a wavelength conversion member 2.
- the wavelength conversion member 2 includes a fluorescent plate 1, a reflection member 6, a heat dissipation member 7, and a bonding layer 8. For convenience of explanation, the relationship between the sizes of the members in FIG. 1 is shown so as to be different from the actual relationship.
- the fluorescent plate 1 is a flat plate member formed of a ceramic sintered body.
- the fluorescent plate 1 is formed with an incident surface 1a on which the light L1 is incident and a back surface 1b located on the opposite side of the incident surface 1a.
- the fluorescent plate 1 emits fluorescence by using the light L1 incident from the incident surface 1a as excitation light.
- the fluorescent plate 1 generates heat when it emits fluorescence.
- the detailed configuration of the fluorescent plate 1 will be described later.
- the reflective member 6 is a thin film containing silver (Ag) as a main component, and is formed on the back surface 1b of the fluorescent plate 1.
- the reflecting member 6 reflects the light transmitted through the fluorescent plate 1 among the light L1 emitted by the light source 9 and the fluorescence toward the back surface 1b of the fluorescence emitted by the fluorescent plate 1 in the direction of the incident surface 1a.
- the reflective member 6 may be made of a material having a high reflectance such as a silver alloy or aluminum (Al).
- the heat radiating member 7 is a flat plate member made of a material having higher thermal conductivity than the fluorescent plate 1, such as copper, copper molybdenum alloy, copper tungsten alloy, aluminum, and aluminum nitride.
- the heat radiating member 7 radiates the heat of the fluorescent plate 1 transmitted through the bonding layer 8 to the outside.
- the heat radiating member 7 may be a single-layered member made of the above-mentioned material, or may be a multi-layered member made of the same or different materials. Further, a metal film that enhances the adhesion to the bonding layer 8 may be arranged on the surface 7a of the heat radiating member 7 on the fluorescent plate 1 side.
- the bonding layer 8 is arranged between the reflecting member 6 and the heat radiating member 7, and is formed of gold (Au) and tin (Sn).
- the bonding layer 8 joins the fluorescent plate 1 and the heat radiating member 7, and transfers the heat generated by the fluorescent plate 1 to the heat radiating member 7.
- the bonding layer 8 may be solder formed from other materials in addition to being formed from gold and tin, or may be obtained by sintering fine powder such as silver or copper (Cu). May be good.
- FIG. 2 is an enlarged cross-sectional view of the fluorescent plate 1.
- the fluorescent plate 1 has a fluorescent phase 10, a translucent phase 20, and a void 30.
- the fluorescent phase 10 is composed of a plurality of fluorescent crystal particles.
- the fluorescent crystal particles have a composition represented by the chemical formula A 3 B 5 O 12 : Ce (so-called garnet structure).
- a 3 B 5 O 12 : Ce means that Ce is dissolved in A 3 B 5 O 12 and a part of the element A is replaced with Ce.
- Chemical formula A 3 B 5 O 12 : Element A and element B in Ce are each composed of at least one element selected from the following element groups.
- Element A Lanthanoids excluding Sc, Y, Ce (however, Gd may be further contained as element A).
- Element B Al (However, Ga may be further contained as element B)
- the composition and element types of the fluorescent crystal particles constituting the fluorescent phase 10 are not limited to the above-mentioned composition and element types, and one fluorescent phase 10 is composed of a plurality of types of fluorescent crystal particles. You may.
- the translucent phase 20 is composed of a plurality of translucent crystal particles.
- the translucent crystal particles have a composition represented by the chemical formula Al 2 O 3.
- the translucent phase 20 transmits light inside the fluorescent plate 1 and also serves as a heat transfer path for efficiently transmitting the heat generated when the fluorescent phase 10 emits fluorescence to the heat radiating member 7.
- the refractive index of the translucent phase 20 is smaller than that of the fluorescent phase 10.
- the void 30 is formed by being surrounded by the fluorescent phase 10 and the translucent phase 20.
- the fluorescent plate 1 includes a plurality of voids 30 as shown in FIG.
- the plurality of voids 30 have a plurality of specific voids 30a having a circle equivalent diameter of 0.4 ⁇ m or more and 50 ⁇ m or less.
- the equivalent circle diameter refers to the diameter of a perfect circle corresponding to the area of the target area.
- the average circle-equivalent diameter of the plurality of specific voids 30a is 1 ⁇ m or more and less than 10 ⁇ m.
- the refractive index of the specific void 30a is smaller than the refractive index of the translucent phase 20.
- the refractive index of the specific void 30a is smaller than the refractive index of the fluorescent phase 10.
- a minute gap naturally formed between the fluorescent phase 10 and the translucent phase 20 which cannot be observed by a normal method, or an unintentionally formed in the manufacturing process of the fluorescent plate 1 described later. It does not include cracks.
- the portion of the fluorescent plate 1 excluding the void 30 is composed of a fluorescent phase 10 having a volume ratio of 60% and a translucent phase 20 having a volume ratio of 40%. That is, in the cross section of the fluorescent plate 1 as shown in FIG. 2, the area ratio of the fluorescent phase 10 to the total of the fluorescent phase 10 and the translucent phase 20 in the fluorescent plate 1 is 60%, and the area ratio of the translucent phase 20 is 60%. , 40%. In the cross section of the fluorescent plate 1 including the cross section of the void 30 as shown in FIG. 2, the area ratio of the fluorescent phase 10 to the total of the fluorescent phase 10 and the translucent phase 20 in the fluorescent plate 1 is 95% or less. desirable.
- the light is appropriately scattered in the translucent phase 20, so that the optical path length in the fluorescent phase 10 becomes relatively long, and it is possible to suppress a decrease in the light absorption rate.
- the area ratio of the fluorescent phase 10 to the total of the area of the fluorescent phase 10 and the area of the translucent phase 20 in the cross section of the fluorescent plate 1 is larger than 20% and further larger than 30%.
- the ratio of the number of the specific voids 30a having a circularity of more than 0.6 and 1 or less among the plurality of specific voids 30a is 70% or more.
- the ratio of the number of specific voids 30a having a circularity Ci smaller than 0.4 is 3% or less.
- the fluorescent plate 1 of the present embodiment has a large number of specific voids 30a having a shape relatively close to a circle.
- the manufacturing method of the fluorescent plate 1 will be described.
- the raw materials weighed so that the fluorescent phase 10 and the translucent phase 20 were 6: 4 were put into a ball mill together with ethanol, and pulverization and mixing were performed for 16 hours. ..
- the slurry obtained by this pulverization and mixing was dried, and granulation was performed using the dried slurry.
- the granulated particles, the pore-forming material, and the binder were kneaded with a ball mill for 1 hour or more, then water was added and kneaded, and the mixture was formed into a sheet shape using an extruder.
- the fluorescent plate 1 is manufactured by firing the produced sheet-shaped molded product at 1700 ° C. in an air atmosphere and sintering it.
- the wavelength conversion member 2 including the fluorescent plate 1 when the wavelength conversion member 2 including the fluorescent plate 1 is manufactured, silver is vapor-deposited or sputtered on the back surface 1b of the fluorescent plate 1 to form a film of the reflective member 6.
- the gold-tin solder foil is sandwiched between the reflective member 6 and the heat-dissipating member 7 formed on the fluorescent plate 1 and heated in a reflow oven in a nitrogen atmosphere or a hydrogen atmosphere.
- the fluorescent plate 1 and the heat radiating member 7 are joined to each other, and the wavelength conversion member 2 is manufactured.
- the gold-tin solder paste may be applied to bond the fluorescent plate 1 and the heat radiating member 7.
- the light source 9 is set so that the incident surface 1a of the fluorescent plate 1 included in the wavelength conversion member 2 is irradiated with light, and the wavelength conversion member 2 and the light source 9 are provided. And package. As a result, the light source device 3 is manufactured.
- the sample used for the evaluation test was carried out by a method according to the above-mentioned manufacturing method of the fluorescent plate 1.
- the kneading conditions when kneading the granulated particles with the pore-forming material, the binder, and water were changed to control the shearing force.
- the degree of kneading is increased, the circularity of the voids formed in the sample tends to increase.
- the plurality of samples prepared in this manner have different distributions with respect to circularity for the plurality of voids. In this evaluation test, eight samples were prepared.
- FIG. 3 is an example of the result of image processing of a sample SEM photograph.
- the circularity of the voids having a circle-equivalent diameter of 0.4 ⁇ m or more and 50 ⁇ m or less was calculated for each of the prepared samples by using the following method. Specifically, first, the sample is cut, the mirrored cut surface is observed by FE-SEM, and then the cross-sectional image at any five points is binarized by image processing (WinROOF). Obtained.
- FIG. 3 is an example S of the result of image processing of the SEM photograph of the sample, and shows the binarized result in which the void 30s is shown by the black portion. Next, from the acquired image, the area ratio of the voids in the cross section of the sample was calculated.
- the cross-sectional image in which the occupancy of the voids in the cross section of the sample is 2.5% or more and 3.2% or less is included in the image.
- the circularity of all voids having a circular equivalent diameter of 1 ⁇ m or more and 10 ⁇ m or less was calculated.
- the circularity at this time was calculated from the analysis result by image processing using the same formula (2) as the above formula (1).
- Ci 4 ⁇ ⁇ ⁇ Sv / Lp 2 ...
- Sv is, for example, the area of one void 30s in the analysis image of the SEM photograph of the sample shown in FIG. 3, and Lp is the perimeter of one void 30s.
- FIG. 4 is a diagram showing the results of the sample evaluation test.
- mirror processing was performed so that the thickness of the sample was 80 ⁇ m, and the durability against thermal shock when irradiated with a blue laser was evaluated. Specifically, the output of the blue laser irradiated to the sample was increased, and the output of the blue laser when the sample was damaged was used as an evaluation index for evaluating the durability of the sample against thermal shock. Further, in this evaluation test, light in the reflection direction when a sample for luminance measurement having a mirror-finished surface and a thickness of 200 ⁇ m is irradiated with a laser having a wavelength of 450 nm (laser diameter: 0.4 mm, laser output: 5 W).
- Samples 1 to 3 are samples prepared by changing the ratio of voids having a circularity of more than 0.6 and 1 or less.
- Samples 4 and 5 are samples prepared by changing the proportion of voids having a circularity smaller than 0.4.
- Samples 6 to 8 are samples in which the area ratio of the fluorescent phase 10 to the total of the area of the fluorescent phase 10 and the area of the translucent phase 20 in the cross section of the fluorescent plate 1 is changed with respect to the samples 1 to 5.
- the sample 5 has the same proportion of voids having a circularity of more than 0.6 and 1 or less as that of the sample 3 having the largest circularity among the five samples, and has five voids having a circularity of less than 0.4. It is the smallest 3% sample among the samples.
- the durability of the sample 5 against thermal shock was the highest among the five samples, and no damage was confirmed even when the laser output was larger than 20 W / mm 2. Thus, in the fluorescent plate, it was confirmed that there is a correlation between the circularity of the voids and the durability against thermal shock.
- the inside of the fluorescent plate is sufficiently densified by raising the firing temperature, and has high mechanical strength.
- the method of densifying the inside of the fluorescent plate has a problem that the light is diffused at the grain boundaries of the crystal particles in the fluorescent plate, so that the light spreads over a wide range and the light cannot be efficiently collected.
- a region having a relatively large difference in the refractive index from the translucent phase or the fluorescent phase is formed by leaving a void having a refractive index lower than that of the translucent phase or the fluorescent phase inside the fluorescent plate. It is possible to prevent the diffusion of light and promote the scattering of light.
- the method of forming a void it is difficult to control the shape of the void and it tends to depend on the shape of the pore-forming material, so that it tends to be a rhombus or an elongated shape. Further, if the number of voids is increased, the fluorescent plate itself becomes brittle, so that the durability against thermal shock tends to decrease. Furthermore, since the excitation light is converted into heat in the crystal defects existing in the fluorescent plate, if the voids are angular, the thermal shock concentrates as stress on the corners of the voids and the fluorescent plate is easily damaged. Durability may decrease.
- the fluorescent plate 1 has a plurality of voids 30, and the light inside the fluorescent plate 1 is the fluorescent phase 10 and the translucent phase 20 in the plurality of voids 30. Since it is scattered on the surface of the light, the efficiency of light extraction can be improved.
- the plurality of voids 30 have a plurality of specific voids 30a having a circle equivalent diameter of 0.4 ⁇ m or more and 50 ⁇ m or less.
- 70% or more of the specific voids 30a included in the cross section have a circularity of more than 0.6 and 1 or less. That is, the fluorescent plate 1 has a large number of specific voids 30a having a shape relatively close to a circle.
- the fluorescent plate 1 having a large number of specific voids 30a having such a shape is damaged by the thermal shock. It becomes difficult. As a result, it is possible to improve the durability against thermal shock while improving the light extraction efficiency.
- the number of specific voids 30a having a circularity smaller than 0.4 is 3% of the plurality of specific voids 30a included in the cross section. It is as follows. As a result, since there are few voids having angular portions on which stress due to thermal shock is likely to act, the fluorescent plate 1 is less likely to be damaged by thermal shock. Therefore, it is possible to further improve the durability against thermal shock while improving the light extraction efficiency.
- the area ratio of the fluorescent phase 10 to the total of the fluorescent phase 10 and the translucent phase 20 in the fluorescent plate 1 is 95%. It is 60%, which is the following, and the area ratio of the translucent phase 20 is 40%.
- the light is appropriately scattered in the translucent phase 20, so that the optical path length in the fluorescent phase 10 becomes relatively long, and it is possible to suppress a decrease in the light absorption rate. Thereby, the light extraction efficiency can be improved.
- the wavelength conversion member 2 includes a reflection member 6 that reflects the fluorescence emitted from the fluorescent plate 1 and the excitation light.
- a reflection member 6 that reflects the fluorescence emitted from the fluorescent plate 1 and the excitation light.
- the wavelength conversion member 2 includes a heat dissipation member 7 that releases the heat of the fluorescent plate 1 to the outside.
- a heat dissipation member 7 that releases the heat of the fluorescent plate 1 to the outside.
- the light source device 3 includes a light source 9 that irradiates the fluorescent plate 1 with the light L1.
- the fluorescent plate 1 emits fluorescence by a part of the light of the light L1. Since the fluorescence emitted by the fluorescent plate 1 is reflected on the surface of the fluorescent phase 10 exposed in a relatively large amount in the void 30, the amount of light emitted to the outside of the fluorescent plate 1 increases. Thereby, the light emission intensity of the light source device 3 can be improved.
- the ratio of the number of specific voids 30a having a circularity of more than 0.6 and 1 or less among the plurality of specific voids 30a of the fluorescent plate 1 is 70% or more. It may be 50% or more. If it is 50% or more, since it does not have an angular portion on which stress due to thermal shock is likely to act, the fluorescent plate 1 having a large number of specific voids 30a having such a shape is less likely to be damaged by thermal shock.
- the ratio of the number of specific voids 30a having a circularity smaller than 0.4 among the plurality of specific voids 30a possessed by the fluorescent plate 1 is 3% or less. However, it may be 8% or less, or more than 8%. As the ratio of the number of specific voids 30a having a circularity smaller than 0.4 is smaller, the number of angular portions on which stress due to thermal shock is likely to act is further reduced, so that the durability against thermal shock can be improved.
- the plurality of voids 30 of the fluorescent plate 1 have a plurality of specific voids 30a having a circular equivalent diameter of 0.4 ⁇ m or more and 50 ⁇ m or less, and 70 of these specific voids 30a are 70. It is assumed that the circularity of the specific void 30a of% or more is larger than 0.6 and becomes 1 or less. Further, the plurality of voids 30 have a thermal shock when the circle equivalent diameter is 0.8 ⁇ m or more and 10 ⁇ m or less, and the circularity is larger than 0.6 and the ratio of the number of 1 or less is 90% or more. Durability against can be further improved.
- the area ratio of the fluorescent phase 10 to the total of the area of the fluorescent phase 10 and the area of the transparent phase 20 in the fluorescent plate 1 is 60%, and the area of the transparent phase 20 is 20%.
- the ratio was assumed to be 40%.
- the area ratio of the fluorescent phase in the cross section of the fluorescent plate is not limited to this.
- the area ratio of the fluorescent phase 10 is preferably 95% or less because light is appropriately scattered and the optical path length in the fluorescent phase 10 is lengthened.
- the area ratio of the fluorescent phase 10 is preferably larger than 20% in order to secure a certain degree of intensity of the fluorescence emitted by the fluorescent phase 10, and when it is larger than 30%, stable and high luminance is emitted.
- the light source device 3 is a reflection type light source device.
- the fluorescent plate 1 may be applied to a transmission type light source device.
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Abstract
Description
図1は、第1実施形態の蛍光板1を備える光源装置3の模式図である。本実施形態の蛍光板1は、光源装置3が備える発光ダイオード(LED:Light Emitting Diode)や半導体レーザー(LD:Laser Diode)などの光源9が発する光L1が照射されると、光L1とは異なる波長の光を蛍光として発する。蛍光板1が発する蛍光は、蛍光板1での蛍光の発生に寄与しなかった光とともに、光L2として、所定の方向に放射される。本実施形態の光源装置3は、図1に示すように、反射型の光源装置であって、ヘッドランプ、照明、プロジェクタなどの各種光学機器において使用される。光源装置3は、上述の光源9と、波長変換部材2と、を備える。波長変換部材2は、蛍光板1と、反射部材6と、放熱部材7と、接合層8と、を備える。なお、説明の便宜上、図1における各部材のそれぞれの大きさの関係は、実際の関係とは異なるように図示されている。
元素A:Sc、Y、Ceを除くランタノイド(ただし、元素AとしてさらにGdを含んでいてもよい)
元素B:Al(ただし、元素BとしてさらにGaを含んでいてもよい)
なお、蛍光相10を構成する蛍光性結晶粒子の組成および元素の種類は、上述の組成および元素の種類に限定されず、1つの蛍光相10に、複数種の蛍光性結晶粒子から構成されていてもよい。
Ci=4×π×Sv/Lp2 ・・・(1)
ただし、0<Ci≦1
ここで、Svは、蛍光板1の断面での特定空隙30aの面積(単位:m2)であり、Lpは、蛍光板1の断面での特定空隙30aの周囲長(単位:m)である。すなわち、本実施形態の蛍光板1は、比較的円に近い形状の特定空隙30aを多数有している。
Ci=4×π×Sv/Lp2 ・・・(2)
ここで、Svは、例えば、図3に示すサンプルのSEM写真の解析画像では1つの空隙30sの面積であり、Lpは、1つの空隙30sの周囲長である。
本発明は上記の実施形態に限られるものではなく、その要旨を逸脱しない範囲において種々の態様において実施することが可能であり、例えば次のような変形も可能である。
上述の実施形態では、蛍光板1が有する複数の特定空隙30aのうち、円形度が0.6より大きく1以下となる特定空隙30aの個数の割合は、70%以上になっているとしたが、50%以上であってもよい。50%以上であれば、熱衝撃による応力が作用しやすい角張った部分を有していないため、このような形状の特定空隙30aを多数有する蛍光板1は、熱衝撃によって破損しにくくなる。
上述の実施形態では、蛍光板1が有する複数の特定空隙30aのうち、円形度が0.4より小さい特定空隙30aの個数の割合は、3%以下になっているとした。しかしながら、8%以下であってもよいし、8%より多くてもよい。円形度が0.4より小さい特定空隙30aの個数の割合が小さいほど、熱衝撃による応力が作用しやすい角張った部分はさらに少なくなるため、熱衝撃に対する耐久性が向上させることができる。
上述の実施形態では、蛍光板1の複数の空隙30は、円相当径が0.4μm以上50μm以下である複数の特定空隙30aを有しており、これらの特定空隙30aのうち、個数割合で70%以上の特定空隙30aの円形度が0.6より大きく1以下となるとした。複数の空隙30は、さらに、円相当径が、0.8μm以上10μm以下の空隙30において、円形度が0.6より大きく1以下の個数の割合が90%以上となっている場合、熱衝撃に対する耐久性はさらに向上させることができる。
上述の実施形態では、蛍光板1の断面において、蛍光板1に占める蛍光相10の面積と透光相20の面積との合計に対する蛍光相10の面積比は、60%となり、透光相20の面積比は、40%であるとした。しかしながら、蛍光板の断面における蛍光相の面積比は、これに限定されない。蛍光相10の面積比は、光が適度に散乱し蛍光相10での光路長を長くするため、95%以下であることが望ましい。また、蛍光相10の面積比は、蛍光相10が発する蛍光の強度を一定程度確保するため、20%より大きい方が望ましく、30%より大きくなると、安定して高い輝度を発するようになる。
上述の実施形態では、光源装置3は、反射型の光源装置であるとした。しかしながら、蛍光板1は、透過型の光源装置に適用されてもよい。
1a…入射面
1b…裏面
2…波長変換部材
3…光源装置
6…反射部材
7…放熱部材
9…光源
10…蛍光相
20…透光相
30…空隙
30a…特定空隙
Claims (8)
- 蛍光板であって、
励起光によって蛍光を発する蛍光相と、
複数の空隙と、を備え、
前記複数の空隙は、円相当径が0.4μm以上50μm以下である複数の特定空隙を有し、
前記蛍光板の断面において、前記複数の特定空隙のうち、円形度が0.6より大きく1以下となる前記特定空隙の個数の割合は、50%以上である、
ことを特徴とする蛍光板。 - 請求項1に記載の蛍光板であって、
前記複数の特定空隙のうち、円形度が0.6より大きく1以下となる前記特定空隙の割合は、70%以上である、
ことを特徴とする蛍光板。 - 請求項1または請求項2に記載の蛍光板であって、
前記複数の特定空隙のうち、円形度が0.4より小さい前記特定空隙の割合は、8%以下である、
ことを特徴とする蛍光板。 - 請求項3に記載の蛍光板であって、
前記複数の特定空隙のうち、円形度が0.4より小さい前記特定空隙の割合は、3%以下である、
ことを特徴とする蛍光板。 - 請求項1から請求項4のいずれか一項に記載の蛍光板であって、
前記励起光を透過する透光相を備え、
前記空隙の断面を含む前記蛍光板の断面において、前記蛍光板に占める前記蛍光相と前記透光相との合計に対する前記蛍光相の面積比は、95%以下である、
ことを特徴とする蛍光板。 - 波長変換部材であって、
請求項1から請求項5のいずれか一項に記載の蛍光板と、
前記蛍光板に配置され、前記励起光と前記蛍光を反射する反射部材と、を備える、
ことを特徴とする波長変換部材。 - 請求項6に記載の波長変換部材は、さらに、
前記蛍光板の熱を外部に放出する放熱部材を備える、
ことを特徴とする波長変換部材。 - 光源装置であって、
請求項6または請求項7に記載の波長変換部材と、
前記蛍光板に前記励起光を照射する光源と、を備える、
光源装置。
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KR1020227027567A KR20220124791A (ko) | 2020-06-08 | 2021-06-03 | 형광판, 파장 변환 부재, 및 광원 장치 |
EP21821991.3A EP4163540A4 (en) | 2020-06-08 | 2021-06-03 | FLUORESCENT PLATE, WAVELENGTH CONVERSION ELEMENT, AND LIGHT SOURCE DEVICE |
CN202180015272.7A CN115103978B (zh) | 2020-06-08 | 2021-06-03 | 荧光板、波长转换构件和光源装置 |
US18/000,973 US20230213171A1 (en) | 2020-06-08 | 2021-06-03 | Fluorescent plate, wavelength conversion member, and light source device |
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