WO2021196317A1 - Novel combination shielding structure for preventing surrounding rock ground pressure disasters caused by mining - Google Patents

Novel combination shielding structure for preventing surrounding rock ground pressure disasters caused by mining Download PDF

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Publication number
WO2021196317A1
WO2021196317A1 PCT/CN2020/086432 CN2020086432W WO2021196317A1 WO 2021196317 A1 WO2021196317 A1 WO 2021196317A1 CN 2020086432 W CN2020086432 W CN 2020086432W WO 2021196317 A1 WO2021196317 A1 WO 2021196317A1
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parts
energy
shielding structure
inner layer
reflective inner
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PCT/CN2020/086432
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French (fr)
Chinese (zh)
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吕祥锋
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北京科技大学
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21DSHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
    • E21D11/00Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

Definitions

  • the invention relates to the field of prevention and control of deep mining ground pressure disasters, in particular to a novel combined shielding structure used for protection of ground pressure disasters in mining surrounding rocks.
  • the purpose of the embodiments of the present invention is to provide a new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks, which adopts a combined shielding structure plan that combines an absorbing outer layer and a reflective inner layer, which can effectively shield and protect elasticity. It can impact the stress wave to destroy the roadway.
  • the present invention adopts the following technical solutions:
  • a new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks is arranged between the roadway and the surrounding rock.
  • the surrounding rock is located on the outside of the roadway.
  • the reflective inner layer is composed of an energy-absorbing outer layer made of materials with a buffering and energy-absorbing effect, and the reflective inner layer is made of a new type of porous material that reflects, disperses and buffers elastic energy shock and stress waves, and is composed of a spray filling method.
  • the reflective inner layer formed by the spray filling method is an integrated structure.
  • the reflective inner layer includes the following raw materials in parts by weight: 18-24 parts of olefin resin, 14-19.2 parts of styrene resin, 4.8-7.2 parts of carbon material powder, 2.1-3.2 parts of glass fiber, and 1 part of calcium carbonate. -2 parts, 1-2 parts of citric acid, 0.35-0.6 parts of tin and 17.6-23.8 parts of silica powder.
  • the method for preparing the novel porous material for the reflective inner layer includes the following steps:
  • step (3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 20-25 minutes;
  • the spray filling method is to spray and fill the new porous material melt prepared above between the roadway and the energy-absorbing outer layer by spray filling, and form a reflective inner layer after curing.
  • the energy-absorbing outer layer is composed of various flexible porous materials with the characteristics of light material, low density, and energy-absorbing buffer.
  • the energy-absorbing outer layer can first absorb and buffer the shock stress wave for the first time, and when the attenuated shock stress wave reaches the reflective inner layer, it is buffered and attenuated again and reflected back.
  • the energy-absorbing outer layer can reach the surrounding rock after the second energy absorption and buffering of the energy-absorbing outer layer.
  • the elastic energy propagates to the roadway in the form of shock stress wave.
  • the energy-absorbing outer layer absorbs and buffers the shock stress wave for the first time, and the attenuated shock stress wave reaches the reflection.
  • the inner layer is again buffered and attenuated, and reflected back to the energy-absorbing outer layer.
  • the energy-absorbing outer layer absorbs and buffers the reflected shock stress wave for the second time, effectively avoiding the re-damage of the surrounding rock by the reflected stress wave. , It also further protects the safety of the roadway, and can effectively avoid the roadway from being damaged by impact.
  • the reflective inner layer is a porous material formed by a three-dimensional interconnected network, which has a good reflection effect on incident stress waves.
  • the porous material includes a plurality of nanopores having an average cross-sectional size of up to 800 nanometers, which can further realize buffering and energy absorption.
  • the carbon material powder includes at least one of carbon fiber, carbon nanotube, and carbon powder.
  • the present invention provides a new type of combined shielding structure for protection against ground pressure hazards in mining surrounding rocks, in particular a reflective inner layer made of a new type of porous material prepared by a new process, and an energy-absorbing outer layer.
  • a new type of combined shielding structure for ground pressure hazards in mining surrounding rocks is formed. This structure, through the combined application of the energy-absorbing outer layer and the reflective inner layer, can well protect the roadway in the event of ground pressure disasters in deep mining and ensure life and property. Security.
  • the present invention sprays and fills a thinner reflective inner layer and a double-layer combined shielding structure with the energy-absorbing outer layer, which not only absorbs the energy at the incident wave stage
  • the layer absorbs energy, and the energy is absorbed by the energy-absorbing outer layer again in the reflection stage, which prolongs the energy-absorbing time of the energy-absorbing outer layer.
  • the shielding layer composed of a single-layer energy-absorbing outer layer absorbs energy only in the incident wave stage.
  • the combined shielding structure is more effective in absorbing energy, and at the same time, it can effectively ensure the safety of the roadway by reflecting the dispersion of the inner layer on the stress wave.
  • the double-layer combined shielding structure of the present invention can effectively eliminate the secondary damage of the surrounding rock caused by the reflected wave through the secondary energy absorption of the energy-absorbing outer layer of the reflected wave.
  • the reflected wave generated by the reflection of the shielding layer formed by the inner layer of the layer reflection will cause secondary damage to the surrounding rock, so the double-layer combined shielding structure of the present invention can effectively avoid the secondary damage of the surrounding rock.
  • the present invention uses spray filling to construct the reflective inner layer, avoiding excessive use of fixing devices during the shielding layer setting process. Due to the influence of the surrounding rock structure and other factors, too many fixing devices may sometimes cause damage to the surrounding rock, and The shielding layer combined completely by the fixing device has a low degree of integration, which will reduce its shielding and protection effect in actual use. Therefore, the present invention uses a spray filling method to set a reflective inner layer to realize the combined shielding structure into an integrated structure, which also solves the problem.
  • a spray filling method to set a reflective inner layer to realize the combined shielding structure into an integrated structure, which also solves the problem.
  • the new material used in the reflective inner layer of the present invention has a good reflection effect on shock stress waves and a better effect on dispersing stress waves;
  • the new porous material of the reflective inner layer can be used by spray filling method.
  • the reflective inner layer formed by spray filling has a higher degree of integration, the effect of dispersing and reflecting stress waves is better, and the use is simpler and more convenient;
  • the new combined shielding structure through the absorption and buffering of the elastic energy shock stress wave of the energy-absorbing outer porous material and the reflection of the reflective inner layer, the shock stress wave will go through many times during the process of reaching and leaving the combined shielding structure.
  • Energy absorption and buffering can not only effectively protect the roadway from being damaged by the shock stress wave, but also avoid the secondary damage to the surrounding rock caused by the reflected stress wave, which can achieve a better roadway safety guarantee effect;
  • the new type of combined shielding structure which combines energy-absorbing and reflective materials, is the first time in the application of shielding structure, and it is worthy of further research and promotion.
  • the combined shielding structure composed of the reflective inner layer and the energy-absorbing outer layer of the present invention has good application prospects and popularization value.
  • Figure 1 is a structural schematic diagram of a new type of combined shielding structure used for mining surrounding rock and ground pressure disaster protection
  • Figure 2 is a flow chart of the preparation process of the new porous material for the reflective inner layer in the new combined shielding structure.
  • Equipment needed pressure sensor (measure the peak pressure of the impact stress wave at different positions of the shielding structure), support body (support the fixed test sample), shock stress wave blocking device (used to block the direct impact stress of the explosion when detecting the reflected stress wave) Impact of waves), explosives with specified performance (select spherical TNT), explosive suspension brackets and other related equipment.
  • the ground of the test site needs to be hardened or padded with steel plates.
  • the test sample selects a 10cm-thick reflective inner layer of new porous material board, the length and width are 100cm, 500gB explosive, the test distance is 1 meter, and the barrier baffle is set 2cm in front of the new porous material board.
  • the plate is facing the center of the new porous material plate with a circular hole with a radius of 5 cm.
  • the barrier baffle and the backing plate are fixed by the support.
  • the test shows that the reflective inner layer of the new porous material plate in the combined shielding structure has good rigidity and can effectively disperse the impact of local stress waves, avoiding the damage of the local roadway caused by the stress wave impact of the mining surrounding rock pressure disaster. And cause serious consequences.
  • the test sample is a 10cm-thick reflective inner layer new porous material plate, 500gB explosive, and the test distance is 1 meter.
  • the new porous material plate is attached to the support fixed by the support, on the front of the new porous material plate.
  • pressure sensors 1, 2 and 3 there are pressure sensors 1, 2 and 3 respectively.
  • the test results show that the peak pressure at position 1 is 0.52MPa, and the peak pressure at position 2. It is 0.26MPa, and No. 3 is 0.34MPa.
  • the comparative test shows that the reflective inner layer material has significantly better stress wave reflection performance than commercially available materials.
  • Tin addition test discard the tin in the raw material composition of the new porous material, and make the porous material plate with the same composition of other raw materials.
  • the experimental conditions are the same as in Example 2.
  • the test result is that the peak pressure at position 1 is 0.51 MPa, and the peak pressure in No. 2 is 0.36. MPa, No. 3 is 0.03MPa;
  • Tin substitution test The tin material in the new porous material composition is replaced with aluminum and zinc. Under the same conditions, when replaced with aluminum, the test result is that the peak pressure at position 1 is 0.51 MPa, and the peak pressure at position 2 is 0.30 MPa, 3. No. is 0.14MPa; when changing to zinc, the result is that the peak pressure at No. 1 position is 0.50 MPa, No. 2 is 0.29 MPa, and No. 3 is 0.12 MPa;
  • the 20cm-thick energy-absorbing outer layer and the 10cm-thick reflective inner layer are laminated to form a 30cm-thick combined shielding structure. Cut into squares of the same size and follow the test method of Example 2.
  • the test result is that the combined shielding structure has a peak pressure of 0.51 MPa at No. 1 position, 0.02 MPa at No. 2 and 0.03 MPa at No. 3; foamed aluminum structure, the result is The peak pressure at No. 1 position is 0.50 MPa, No. 2 is 0.21 MPa, and No. 3 is 0.03 MPa;
  • Tests show that the combined shielding structure composed of the energy-absorbing outer layer and the reflective inner layer of the present invention has good stress wave protection performance, which is better than that of commercially available materials.
  • a new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks is set between the roadway 1 and the surrounding rock 7.
  • the surrounding rock 7 is located outside the roadway 1, and is characterized in that:
  • the combined shielding structure is composed of an energy-absorbing outer layer 3 and a reflective inner layer 2.
  • the energy-absorbing outer layer 3 is composed of a material with a buffering and energy-absorbing effect.
  • the porous material is constructed by spray filling.
  • the reflective inner layer 2 includes the following raw materials by weight: 18 parts of olefin resin, 14 parts of styrene resin, 4.8 parts of carbon material powder, 2.1 parts of glass fiber, 1 part of calcium carbonate, 1 part of citric acid, 0.35 parts of tin and 17.6 parts of silica powder;
  • step (3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 20 minutes;
  • the energy-absorbing outer layer 3 can be made of commercially available foamed aluminum material with a thickness of 30cm. , And then pave the roadway, the distance between the roadway and the foamed aluminum is controlled to be about 10cm, and the new porous material is sprayed between the roadway and the foamed aluminum. After natural cooling and solidification, it forms a combined shielding structure with the energy-absorbing outer layer. In actual operation, according to the actual situation, the appropriate thickness of the energy-absorbing outer layer material and the appropriate thickness of the reflective inner layer material can be selected to achieve effective protection.
  • isolation and support molds can be erected between the roadway and the aluminum foam layer according to actual needs.
  • the combined shielding structure can effectively protect the roadway from damage to the roadway and the enclosure caused by rock bursts when mining deep underground.
  • the secondary damage of the rock has a good protective effect on the safety of life and property.
  • step (3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 25 minutes;
  • the energy-absorbing outer layer 3 can be made of commercially available reinforced polyurethane foam with a thickness of 35 cm. Then pave the roadway on the rock. The distance between the roadway and the reinforced polyurethane foam is controlled to be about 10cm. The new porous material is sprayed between the mold and the reinforced polyurethane foam. After natural cooling and solidification, it forms a combined shielding structure with the energy-absorbing outer layer. . In actual operation, according to the actual situation, the appropriate thickness of the energy-absorbing outer layer material and the appropriate thickness of the reflective inner layer material can be selected to achieve effective protection.
  • isolation and support molds can be erected between the roadway and the reinforced polyurethane foam layer as required.
  • the combined shielding structure can effectively protect the roadway from damage and damage caused by rock impact when mining deep underground.
  • the secondary damage to the surrounding rock has a good protective effect on the safety of life and property.
  • step (3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 22 minutes;
  • the energy-absorbing outer layer 3 can be made of a commercially available foamed aluminum material with a thickness of 35cm. , And then pave the roadway, the distance between the roadway and the foamed aluminum is controlled at about 15cm, and the new porous material is sprayed between the roadway and the foamed aluminum. After natural cooling and solidification, it forms a combined shielding structure with the energy-absorbing outer layer. In actual operation, according to the actual situation, the appropriate thickness of the energy-absorbing outer layer material and the appropriate thickness of the reflective inner layer material can be selected to achieve effective protection.
  • isolation and support molds can be erected between the roadway and the aluminum foam layer as required.
  • the combined shielding structure can effectively protect the roadway from damage to the roadway and surrounding rock by the rock burst when mining deep underground. The secondary damage has a very good protective effect on the safety of life and property.

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Abstract

Disclosed is a novel combination shielding structure for preventing surrounding rock ground pressure disasters caused by mining. The combination shielding structure is composed of an energy-absorbing outer layer (3) and a reflective inner layer (2), and is arranged between a roadway (1) and surrounding rock (7). The surrounding rock (7) is located on the outer side of the combination shielding structure, and the roadway (1) is located on the inner side of the combination shielding structure. The reflective inner layer (2) in the novel combination shielding structure comprises the following raw materials in parts by weight: 18-24 parts of an olefin resin, 14-19.2 parts of a styrene resin, 4.8-7.2 parts of a carbon material powder, 2.1-3.2 parts of glass fibers, 1-2 parts of calcium carbonate, 1-2 parts of citric acid, 0.35-0.6 parts of tin and 17.6-23.8 parts of a silicon dioxide powder. The energy-absorbing outer layer (3) is composed of a flexible structural material having buffering and energy absorption effects. In the novel combination shielding structure, the energy-absorbing outer layer (3) can adsorb and buffer an elastic energy impact stress wave (4); the reflective inner layer (2) further buffers and reflects an incident wave; and the energy-absorbing outer layer (3) plays a role in secondary energy absorption and buffering against the reflected wave, such that secondary impact damage to the surrounding rock (7) by the reflected wave can be reduced, and a good protective effect is provided on the roadway (1).

Description

一种用于采动围岩地压灾害防护的新型组合屏蔽结构A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks 技术领域Technical field
本发明涉及深部采动地压灾害防治领域,具体是一种用于采动围岩地压灾害防护的新型组合屏蔽结构。The invention relates to the field of prevention and control of deep mining ground pressure disasters, in particular to a novel combined shielding structure used for protection of ground pressure disasters in mining surrounding rocks.
背景技术Background technique
深部开采地压灾害发生时会释放大量弹性能,弹性能传播至巷道围岩会造成巷道的严重摧毁和人员伤亡事故,给矿山开采带来重大影响。目前,国内外采动巷道围岩防护均从弹性能的吸收角度进行防治,对于屏蔽弹性能冲击应力波没有明确的防护方法,人们也在进行相关方面的研究。A large amount of elastic energy will be released when a deep mining ground pressure disaster occurs. The elastic energy spread to the surrounding rock of the roadway will cause serious destruction of the roadway and casualties, which will have a significant impact on mining. At present, the protection of surrounding rock of mining roadways at home and abroad is carried out from the perspective of elastic energy absorption. There is no clear protection method for shielding elastic energy shock stress waves, and people are also conducting related researches.
发明内容Summary of the invention
本发明实施例的目的在于提供一种用于采动围岩地压灾害防护的新型组合屏蔽结构,采用将吸收外层和反射内层相结合的组合屏蔽结构方案,能有效的屏蔽和防护弹性能冲击应力波对巷道破坏。The purpose of the embodiments of the present invention is to provide a new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks, which adopts a combined shielding structure plan that combines an absorbing outer layer and a reflective inner layer, which can effectively shield and protect elasticity. It can impact the stress wave to destroy the roadway.
为了解决上述技术问题,本发明采用如下技术方案:In order to solve the above technical problems, the present invention adopts the following technical solutions:
一种用于采动围岩地压灾害防护的新型组合屏蔽结构,设置于巷道和围岩之间,所述围岩位于巷道外侧,其特征在于,所述组合屏蔽结构由吸能外层和反射内层构成,吸能外层由具有缓冲吸能效果材料构成,反射内层由具有反射、分散和缓冲弹性能冲击应力波的新型多孔材料采用喷填方式构成。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks is arranged between the roadway and the surrounding rock. The surrounding rock is located on the outside of the roadway. The reflective inner layer is composed of an energy-absorbing outer layer made of materials with a buffering and energy-absorbing effect, and the reflective inner layer is made of a new type of porous material that reflects, disperses and buffers elastic energy shock and stress waves, and is composed of a spray filling method.
优选的,所述喷填方式形成的反射内层为一体化结构。Preferably, the reflective inner layer formed by the spray filling method is an integrated structure.
优选的,所述反射内层包括以下重量份的原料:烯烃类树脂18-24 份、苯乙烯类树脂14-19.2份、碳材料粉4.8-7.2份、玻璃纤维2.1-3.2份、碳酸钙1-2份、柠檬酸1-2份、锡0.35-0.6份和二氧化硅粉17.6-23.8份。Preferably, the reflective inner layer includes the following raw materials in parts by weight: 18-24 parts of olefin resin, 14-19.2 parts of styrene resin, 4.8-7.2 parts of carbon material powder, 2.1-3.2 parts of glass fiber, and 1 part of calcium carbonate. -2 parts, 1-2 parts of citric acid, 0.35-0.6 parts of tin and 17.6-23.8 parts of silica powder.
优选的,所述反射内层新型多孔材料的制备方法包括以下步骤:Preferably, the method for preparing the novel porous material for the reflective inner layer includes the following steps:
(1)将烯烃类树脂、苯乙烯类树脂混合,加热熔化,形成熔体;(1) Mix olefin resin and styrene resin, heat and melt to form a melt;
(2)将碳材料粉、碳酸钙、锡粉、二氧化硅粉投入球磨机中球磨5-10h;(2) Put carbon material powder, calcium carbonate, tin powder, and silica powder into a ball mill for ball milling for 5-10 hours;
(3)将步骤(2)中研磨均匀的粉末加入步骤(1)熔体中,搅拌20-25min;(3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 20-25 minutes;
(4)熔体中加入玻璃纤维,继续搅拌20-25min;(4) Add glass fiber to the melt and continue to stir for 20-25 minutes;
(5)加入研磨后的柠檬酸,搅拌10-15min;(5) Add the ground citric acid and stir for 10-15min;
(6)维持温度,保持熔体状态40-50min;(6) Maintain the temperature and keep the melt state for 40-50 minutes;
(7)将经过上述步骤处理后的熔体直接喷填在需要部位,自然冷却后,固化成型。(7) The melt processed by the above steps is directly sprayed and filled on the required parts, and after natural cooling, it is solidified and formed.
优选的,所述喷填方式是将上述制备的新型多孔材料熔体采用喷填的方式喷填在巷道和吸能外层之间,固化后形成反射内层。Preferably, the spray filling method is to spray and fill the new porous material melt prepared above between the roadway and the energy-absorbing outer layer by spray filling, and form a reflective inner layer after curing.
优选的,所述吸能外层是由各种具有材质轻、密度低和缓冲吸能特点的柔性多孔材料构成。Preferably, the energy-absorbing outer layer is composed of various flexible porous materials with the characteristics of light material, low density, and energy-absorbing buffer.
具体的,在发生冲击地压灾害时,所述吸能外层可以首先第一次吸收和缓冲冲击应力波,当衰减的冲击应力波到达反射内层时,再次被缓冲衰减,并被反射回吸能外层,历经吸能外层的第二次吸能和缓冲才能达到围岩。Specifically, in the event of a rock shock disaster, the energy-absorbing outer layer can first absorb and buffer the shock stress wave for the first time, and when the attenuated shock stress wave reaches the reflective inner layer, it is buffered and attenuated again and reflected back. The energy-absorbing outer layer can reach the surrounding rock after the second energy absorption and buffering of the energy-absorbing outer layer.
采动围岩地压灾害发生时释放大量弹性能,弹性能以冲击应力波的方式向巷道传播,吸能外层对冲击应力波进行第一次吸收和缓冲,衰减后的冲击应力波到达反射内层时,再次被缓冲衰减,并被反射回吸能外层,吸能外层对反射回的冲击应力波进行第二次吸收和缓冲,有效的避免了反射应力波对围岩的再次破坏,也进一步保护了巷道安全,能有效避免巷道被冲击破坏。A large amount of elastic energy is released when the surrounding rock pressure disaster occurs. The elastic energy propagates to the roadway in the form of shock stress wave. The energy-absorbing outer layer absorbs and buffers the shock stress wave for the first time, and the attenuated shock stress wave reaches the reflection. When the inner layer is attenuated, it is again buffered and attenuated, and reflected back to the energy-absorbing outer layer. The energy-absorbing outer layer absorbs and buffers the reflected shock stress wave for the second time, effectively avoiding the re-damage of the surrounding rock by the reflected stress wave. , It also further protects the safety of the roadway, and can effectively avoid the roadway from being damaged by impact.
优选的,所述反射内层为三维互联网络形成的多孔材料,对应力入射波具有良好的反射作用。Preferably, the reflective inner layer is a porous material formed by a three-dimensional interconnected network, which has a good reflection effect on incident stress waves.
优选的,所述多孔材料包括具有最大800纳米的平均横截面尺寸的多个纳米孔,可以进一步实现缓冲和吸能。Preferably, the porous material includes a plurality of nanopores having an average cross-sectional size of up to 800 nanometers, which can further realize buffering and energy absorption.
优选的,所述碳材料粉包括碳纤维、碳纳米管和碳粉中的至少一种。Preferably, the carbon material powder includes at least one of carbon fiber, carbon nanotube, and carbon powder.
本发明提供了一种用于采动围岩地压灾害防护的新型组合屏蔽结构,特别采用了一种新工艺制备得到的一种新型多孔材料制成的反射内层,与吸能外层共同组成一种新型采动围岩地压灾害组合屏蔽结构,该结构通过吸能外层和反射内层的组合应用,很好的实现了深部开采地压灾害发生时对巷道的保护,确保生命财产的安全。The present invention provides a new type of combined shielding structure for protection against ground pressure hazards in mining surrounding rocks, in particular a reflective inner layer made of a new type of porous material prepared by a new process, and an energy-absorbing outer layer. A new type of combined shielding structure for ground pressure hazards in mining surrounding rocks is formed. This structure, through the combined application of the energy-absorbing outer layer and the reflective inner layer, can well protect the roadway in the event of ground pressure disasters in deep mining and ensure life and property. Security.
与同样厚度由单层吸能外层构成的屏蔽层相比,本发明通过喷填较薄的反射内层并与吸能外层构成的双层组合屏蔽结构,不仅入射波阶段被吸能外层吸能,反射阶段再次被吸能外层吸能,延长了吸能外层的吸能时间,而单层吸能外层构成的屏蔽层只在入射波阶段吸能,所以本发明双层组合屏蔽结构吸能更有效,同时通过反射内层对应力 波的分散作用,能有效保障巷道安全。Compared with the shielding layer composed of a single-layer energy-absorbing outer layer of the same thickness, the present invention sprays and fills a thinner reflective inner layer and a double-layer combined shielding structure with the energy-absorbing outer layer, which not only absorbs the energy at the incident wave stage The layer absorbs energy, and the energy is absorbed by the energy-absorbing outer layer again in the reflection stage, which prolongs the energy-absorbing time of the energy-absorbing outer layer. However, the shielding layer composed of a single-layer energy-absorbing outer layer absorbs energy only in the incident wave stage. The combined shielding structure is more effective in absorbing energy, and at the same time, it can effectively ensure the safety of the roadway by reflecting the dispersion of the inner layer on the stress wave.
与由单层反射内层构成的屏蔽层相比,本发明双层组合屏蔽结构通过吸能外层对反射波的二次吸能,能有效消除反射波对围岩的二次破坏,而单层反射内层构成的屏蔽层反射产生的反射波会对围岩产生二次破坏,所以本发明双层组合屏蔽结构能有效避免围岩的二次破坏。Compared with the shielding layer composed of a single-layer reflective inner layer, the double-layer combined shielding structure of the present invention can effectively eliminate the secondary damage of the surrounding rock caused by the reflected wave through the secondary energy absorption of the energy-absorbing outer layer of the reflected wave. The reflected wave generated by the reflection of the shielding layer formed by the inner layer of the layer reflection will cause secondary damage to the surrounding rock, so the double-layer combined shielding structure of the present invention can effectively avoid the secondary damage of the surrounding rock.
此外,本发明通过喷填方式进行反射内层的构建,避免了在屏蔽层设置过程中过多采用固定装置,由于围岩结构等因素的影响,过多固定装置有时会造成围岩破坏,且完全通过固定装置组合的屏蔽层,一体化程度不高,会降低其在实际使用中屏蔽保护效果,因而本发明通过喷填方式设置反射内层,实现组合屏蔽结构成为一体化结构,也解决了多层屏蔽组合结构在实际设置中的难题之一。In addition, the present invention uses spray filling to construct the reflective inner layer, avoiding excessive use of fixing devices during the shielding layer setting process. Due to the influence of the surrounding rock structure and other factors, too many fixing devices may sometimes cause damage to the surrounding rock, and The shielding layer combined completely by the fixing device has a low degree of integration, which will reduce its shielding and protection effect in actual use. Therefore, the present invention uses a spray filling method to set a reflective inner layer to realize the combined shielding structure into an integrated structure, which also solves the problem. One of the difficult problems of the multi-layer shielding combination structure in the actual setting.
本发明的有益效果主要有:The beneficial effects of the present invention mainly include:
①本发明反射内层所用的新型材料,相对于现有多孔材料,对冲击应力波具有很好反射作用,同时有较好的分散应力波作用;① Compared with the existing porous materials, the new material used in the reflective inner layer of the present invention has a good reflection effect on shock stress waves and a better effect on dispersing stress waves;
②反射内层所用原材料成本不高,制备工艺简化,适于推广;②The cost of raw materials used in the reflective inner layer is not high, and the preparation process is simplified, which is suitable for promotion;
③反射内层新型多孔材料可以采用喷填方法使用,喷填形成的反射内层一体化程度更高,分散和反射应力波效果更好,使用也更简单、方便;③The new porous material of the reflective inner layer can be used by spray filling method. The reflective inner layer formed by spray filling has a higher degree of integration, the effect of dispersing and reflecting stress waves is better, and the use is simpler and more convenient;
④新型组合屏蔽结构,通过吸能外层多孔材料的对弹性能冲击应力波的吸收和缓冲作用以及反射内层的反射作用,使得冲击应力波到达和离开组合屏蔽结构过程中,历经多次的吸能和缓冲,不仅能有效的保护避免巷道被冲击应力波的破坏,而且避免了反射应力波对围岩 的二次破坏,可以实现较好的巷道安全保障效果;④ The new combined shielding structure, through the absorption and buffering of the elastic energy shock stress wave of the energy-absorbing outer porous material and the reflection of the reflective inner layer, the shock stress wave will go through many times during the process of reaching and leaving the combined shielding structure. Energy absorption and buffering can not only effectively protect the roadway from being damaged by the shock stress wave, but also avoid the secondary damage to the surrounding rock caused by the reflected stress wave, which can achieve a better roadway safety guarantee effect;
⑤新型组合屏蔽结构,将吸能和反射两种性质材料联用在一起,属于屏蔽结构应用中的首次,值得进一步深入研究和推广。⑤ The new type of combined shielding structure, which combines energy-absorbing and reflective materials, is the first time in the application of shielding structure, and it is worthy of further research and promotion.
因而本发明的采用反射内层和吸能外层构成的组合屏蔽结构具有很好的应用前景和推广价值。Therefore, the combined shielding structure composed of the reflective inner layer and the energy-absorbing outer layer of the present invention has good application prospects and popularization value.
附图说明Description of the drawings
图1为用于采动围岩地压灾害防护的新型组合屏蔽结构的结构示意图,Figure 1 is a structural schematic diagram of a new type of combined shielding structure used for mining surrounding rock and ground pressure disaster protection,
其中:1-巷道,2-反射内层,3-吸能外层,4-冲击应力波,5-入射波,6-反射波,7-围岩;Among them: 1-roadway, 2-reflective inner layer, 3-energy absorbing outer layer, 4-shock stress wave, 5-incident wave, 6-reflected wave, 7-surrounding rock;
图2为新型组合屏蔽结构中反射内层新型多孔材料的制备工艺流程图。Figure 2 is a flow chart of the preparation process of the new porous material for the reflective inner layer in the new combined shielding structure.
具体实施方式Detailed ways
为了更好的理解本发明的技术方案,下面结合附图对本发明实施例进行详细描述。In order to better understand the technical solutions of the present invention, the following describes the embodiments of the present invention in detail with reference to the accompanying drawings.
应当明确,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。It should be clear that the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
在本发明实施例中使用的术语是仅仅出于描述特定实施例的目的,而非旨在限制本发明。在本发明实施例和所附权利要求书中所使 用的单数形式的“一种”、“所述”和“该”也旨在包括多数形式,除非上下文清楚地表示其他含义。The terms used in the embodiments of the present invention are only for the purpose of describing specific embodiments, and are not intended to limit the present invention. The singular forms of "a", "said" and "the" used in the embodiments of the present invention and the appended claims are also intended to include plural forms, unless the context clearly indicates other meanings.
实施例1Example 1
所需器材:压力传感器(测量屏蔽结构不同位置在冲击应力波作用时的峰值压力)、支撑体(支撑固定试验样本)、冲击应力波阻隔装置(检测反射应力波时用以阻隔爆炸直接冲击应力波的冲击影响)、指定性能的炸药(选用球形TNT)、炸药悬空支架以及其他相关器材,此外,试验场地地面需要进行硬化处理或者铺垫钢板。Equipment needed: pressure sensor (measure the peak pressure of the impact stress wave at different positions of the shielding structure), support body (support the fixed test sample), shock stress wave blocking device (used to block the direct impact stress of the explosion when detecting the reflected stress wave) Impact of waves), explosives with specified performance (select spherical TNT), explosive suspension brackets and other related equipment. In addition, the ground of the test site needs to be hardened or padded with steel plates.
局部应力波冲击试验:试验样本选用10cm厚度的反射内层新型多孔材料板,长宽分别为100cm,500gB炸药,试验距离1米,新型多孔材料板正前方2cm处设置阻隔挡板,在阻隔挡板正对新型多孔材料板中心位置留有半径5cm圆形小孔,阻隔挡板和靠板通过支撑体固定,新型多孔材料板贴靠在模拟巷道的靠板上,在新型多孔材料板正面正对阻隔板小孔位置以及新型多孔材料板和靠板之间设有压力传感器,其中,正对小孔新型多孔材料板正面设有压力传感器1号,1号传感器正对的新型多孔材料板背面设有压力传感器2号,在2号位置周围正三角方向辐射距离10cm设置3、4、5号压力传感器、20cm设置6、7、8号压力传感器、30cm设置9、10、11号压力传感器,检测结果:1号位置压力峰值为0.51MPa,2号为0.08MPa,3号为0.07MPa,4号为0.06MPa,5号为0.07MPa,6号为0.05MPa,7号为0.06MPa,8号为0.05MPa,9号为0.04MPa,10号为0.04MPa,11号 为0.03MPa。Local stress wave impact test: The test sample selects a 10cm-thick reflective inner layer of new porous material board, the length and width are 100cm, 500gB explosive, the test distance is 1 meter, and the barrier baffle is set 2cm in front of the new porous material board. The plate is facing the center of the new porous material plate with a circular hole with a radius of 5 cm. The barrier baffle and the backing plate are fixed by the support. There are pressure sensors at the position of the small holes in the barrier and between the new porous material plate and the backing plate. Among them, there is pressure sensor No. 1 on the front of the small hole new porous material plate, and the back of the new porous material plate facing the No. 1 sensor. Pressure sensor No. 2 is installed. No. 3, 4, and No. 5 pressure sensors are set at a radiation distance of 10cm in the positive triangle around No. 2 position, No. 6, 7, and No. 8 pressure sensors are set at 20cm, and No. 9, 10, and 11 pressure sensors are set at 30cm. Test results: The peak pressure at No. 1 position is 0.51 MPa, No. 2 is 0.08 MPa, No. 3 is 0.07 MPa, No. 4 is 0.06 MPa, No. 5 is 0.07 MPa, No. 6 is 0.05 MPa, No. 7 is 0.06 MPa, No. 8 It is 0.05 MPa, No. 9 is 0.04 MPa, No. 10 is 0.04 MPa, and No. 11 is 0.03 MPa.
该试验表明组合屏蔽结构中的反射内层新型多孔材料板,具有很好的刚性特点,能有效的分散局部应力波冲击,避免采动围岩地压灾害发生点应力波冲击对巷道局部造成破坏并引发严重后果。The test shows that the reflective inner layer of the new porous material plate in the combined shielding structure has good rigidity and can effectively disperse the impact of local stress waves, avoiding the damage of the local roadway caused by the stress wave impact of the mining surrounding rock pressure disaster. And cause serious consequences.
实施例2Example 2
反射内层反射试验:试验样本选用10cm厚度的反射内层新型多孔材料板,500gB炸药,试验距离1米,新型多孔材料板贴靠在通过支撑体固定的支撑体上,在新型多孔材料板正面,新型多孔材料板背面与靠板之间,经阻隔装置阻隔的反射面0.5米距离处,分别设有1、2和3号压力传感器,检测结果,1号位置压力峰值为0.52MPa,2号为0.26MPa,3号为0.34MPa。Reflective inner layer reflection test: The test sample is a 10cm-thick reflective inner layer new porous material plate, 500gB explosive, and the test distance is 1 meter. The new porous material plate is attached to the support fixed by the support, on the front of the new porous material plate. , Between the back of the new porous material board and the backing board, at a distance of 0.5 meters from the reflective surface blocked by the barrier device, there are pressure sensors 1, 2 and 3 respectively. The test results show that the peak pressure at position 1 is 0.52MPa, and the peak pressure at position 2. It is 0.26MPa, and No. 3 is 0.34MPa.
试验表明反射内层材料,具有应力波反射特性。Experiments show that the reflective inner layer material has stress wave reflection characteristics.
实施例3Example 3
市购泡沫铝材料与新型多孔材料板对比试验:同样大小、厚度的市购泡沫铝材料和本发明的新型多孔材料板,试验条件同实施例2,新型多孔材料板,结果为,1号位置压力峰值为0.51MPa,2号为0.21MPa,3号为0.32MPa;泡沫铝材料板,结果为,1号位置压力峰值为0.50MPa,2号为0.33MPa,3号为0.03MPa;Comparison test between commercially available foamed aluminum material and new porous material board: Commercially purchased foamed aluminum material of the same size and thickness and the new porous material board of the present invention, the test conditions are the same as in Example 2, the new porous material board, the result is, No. 1 position The peak pressure is 0.51MPa, No. 2 is 0.21MPa, No. 3 is 0.32MPa; foam aluminum material board, the result is that the peak pressure of No. 1 position is 0.50MPa, No. 2 is 0.33MPa, No. 3 is 0.03MPa;
对比试验说明反射内层材料对应力波反射性能明显优于市购材料。The comparative test shows that the reflective inner layer material has significantly better stress wave reflection performance than commercially available materials.
实施例4Example 4
锡添加试验:将新型多孔材料原料构成中的锡舍弃,其他原料构 成相同,制成多孔材料版,实验条件同实施例2,检测结果为,1号位置压力峰值为0.51MPa,2号为0.36MPa,3号为0.03MPa;Tin addition test: discard the tin in the raw material composition of the new porous material, and make the porous material plate with the same composition of other raw materials. The experimental conditions are the same as in Example 2. The test result is that the peak pressure at position 1 is 0.51 MPa, and the peak pressure in No. 2 is 0.36. MPa, No. 3 is 0.03MPa;
锡取代试验:将新型多孔材料原料构成中的锡材料,换成铝和锌,同样条件下,换成铝时,检测结果为,1号位置压力峰值为0.51MPa,2号为0.30MPa,3号为0.14MPa;换成锌时,结果为,1号位置压力峰值为0.50MPa,2号为0.29MPa,3号为0.12MPa;Tin substitution test: The tin material in the new porous material composition is replaced with aluminum and zinc. Under the same conditions, when replaced with aluminum, the test result is that the peak pressure at position 1 is 0.51 MPa, and the peak pressure at position 2 is 0.30 MPa, 3. No. is 0.14MPa; when changing to zinc, the result is that the peak pressure at No. 1 position is 0.50 MPa, No. 2 is 0.29 MPa, and No. 3 is 0.12 MPa;
试验表明反射内层原料中的锡对于反射性质有较强影响。Experiments show that tin in the raw material of the reflective inner layer has a strong influence on the reflective properties.
实施例5Example 5
吸能外层和反射内层组合对比试验:本发明中20cm厚度的吸能外层和10cm厚度的反射内层叠合成30cm厚度的组合屏蔽结构,市购泡沫铝材料,裁切成30cm厚度,并裁切成同样大小的方块,同样按照实施例2试验方法,试验结果为,组合屏蔽结构,1号位置压力峰值为0.51MPa,2号为0.02MPa,3号为0.03MPa;泡沫铝结构,结果为,1号位置压力峰值为0.50MPa,2号为0.21MPa,3号为0.03MPa;Energy-absorbing outer layer and reflective inner layer combination test: In the present invention, the 20cm-thick energy-absorbing outer layer and the 10cm-thick reflective inner layer are laminated to form a 30cm-thick combined shielding structure. Cut into squares of the same size and follow the test method of Example 2. The test result is that the combined shielding structure has a peak pressure of 0.51 MPa at No. 1 position, 0.02 MPa at No. 2 and 0.03 MPa at No. 3; foamed aluminum structure, the result is The peak pressure at No. 1 position is 0.50 MPa, No. 2 is 0.21 MPa, and No. 3 is 0.03 MPa;
试验表明,本发明用吸能外层和反射内层组成的组合屏蔽结构具有良好的应力波防护性能,要优于市购材料。Tests show that the combined shielding structure composed of the energy-absorbing outer layer and the reflective inner layer of the present invention has good stress wave protection performance, which is better than that of commercially available materials.
实施例6Example 6
一种用于采动围岩地压灾害防护的新型组合屏蔽结构,如附图1所示,设置于巷道1和围岩7之间,所述围岩7位于巷道1外侧,其特征在于,所述组合屏蔽结构由吸能外层3和反射内层2构成,吸能外层3由具有缓冲吸能效果材料构成,反射内层2由具有反射、分散和缓冲弹性能冲击应力波的新型多孔材料采用喷填方式构成。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks, as shown in Figure 1, is set between the roadway 1 and the surrounding rock 7. The surrounding rock 7 is located outside the roadway 1, and is characterized in that: The combined shielding structure is composed of an energy-absorbing outer layer 3 and a reflective inner layer 2. The energy-absorbing outer layer 3 is composed of a material with a buffering and energy-absorbing effect. The porous material is constructed by spray filling.
其中反射内层2包括以下重量份的原料:烯烃类树脂18份、苯乙烯类树脂14份、碳材料粉4.8份、玻璃纤维2.1份、碳酸钙1份、柠檬酸1份、锡0.35份和二氧化硅粉17.6份;The reflective inner layer 2 includes the following raw materials by weight: 18 parts of olefin resin, 14 parts of styrene resin, 4.8 parts of carbon material powder, 2.1 parts of glass fiber, 1 part of calcium carbonate, 1 part of citric acid, 0.35 parts of tin and 17.6 parts of silica powder;
将上述重量份的原料制成反射内层2所用新型多孔材料的过程:The process of making the above-mentioned parts by weight of the raw materials into the new porous material used in the reflective inner layer 2:
(1)将烯烃类树脂、苯乙烯类树脂混合,加热至175℃熔化,形成熔体;(1) Mix olefin resin and styrene resin, and heat to 175°C to melt to form a melt;
(2)将碳材料粉、碳酸钙、锡粉、二氧化硅粉投入球磨机中球磨5h;(2) Put carbon material powder, calcium carbonate, tin powder, and silica powder into the ball mill for ball milling for 5 hours;
(3)将步骤(2)中研磨均匀的粉末加入步骤(1)熔体中,搅拌20min;(3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 20 minutes;
(4)熔体中加入玻璃纤维,继续搅拌20min;(4) Add glass fiber to the melt and continue stirring for 20 minutes;
(5)加入研磨后的柠檬酸,搅拌10min;(5) Add the ground citric acid and stir for 10 minutes;
(6)维持温度,保持熔体状态40min。(6) Maintain the temperature and maintain the melt state for 40 minutes.
经过上述过程可得到用于喷射反射内层2的新型多孔材料,吸能外层3可以采用市购30cm厚度的泡沫铝材料,先将吸能外层30cm厚度的泡沫铝材料固定在围岩上,再铺设巷道,巷道和泡沫铝之间距离控制在10cm左右,在巷道和泡沫铝之间喷填新型多孔材料,自然冷却固化后与吸能外层一起构成组合屏蔽结构。实际操作时,可根据实际情况,选择适宜厚度的吸能外层材料以及喷填适宜厚度的反射内层材料,实现有效的防护作用。新型组合屏蔽结构在搭建过程中,可根据实际需要在巷道和泡沫铝层之间架设隔离和支撑模具,该组合屏蔽结构在地下深部开采时,能有效防护冲击地压对巷道的破坏和对围岩 的二次损害,对生命财产安全有很好的保护作用。After the above process, a new type of porous material used for spraying the reflective inner layer 2 can be obtained. The energy-absorbing outer layer 3 can be made of commercially available foamed aluminum material with a thickness of 30cm. , And then pave the roadway, the distance between the roadway and the foamed aluminum is controlled to be about 10cm, and the new porous material is sprayed between the roadway and the foamed aluminum. After natural cooling and solidification, it forms a combined shielding structure with the energy-absorbing outer layer. In actual operation, according to the actual situation, the appropriate thickness of the energy-absorbing outer layer material and the appropriate thickness of the reflective inner layer material can be selected to achieve effective protection. During the construction of the new type of combined shielding structure, isolation and support molds can be erected between the roadway and the aluminum foam layer according to actual needs. The combined shielding structure can effectively protect the roadway from damage to the roadway and the enclosure caused by rock bursts when mining deep underground. The secondary damage of the rock has a good protective effect on the safety of life and property.
实施例7Example 7
一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其中反射内层2包括以下重量份的原料:A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks, wherein the reflective inner layer 2 includes the following raw materials by weight:
烯烃类树脂24份、苯乙烯类树脂19.2份、碳材料粉7.2份、玻璃纤维3.2份、碳酸钙2份、柠檬酸2份、锡0.6份和二氧化硅粉23.8份24 parts of olefin resin, 19.2 parts of styrene resin, 7.2 parts of carbon material powder, 3.2 parts of glass fiber, 2 parts of calcium carbonate, 2 parts of citric acid, 0.6 parts of tin, and 23.8 parts of silica powder
将上述重量份的原料制成反射内层2所用新型多孔材料的过程:The process of making the above-mentioned parts by weight of the raw materials into the new porous material used in the reflective inner layer 2:
(1)将烯烃类树脂、苯乙烯类树脂混合,加热至170℃熔化,形成熔体;(1) Mix olefin resin and styrene resin, and heat to 170°C to melt to form a melt;
(2)将碳材料粉、碳酸钙、锡粉、二氧化硅粉投入球磨机中球磨10h;(2) Put carbon material powder, calcium carbonate, tin powder, and silica powder into a ball mill for 10 hours;
(3)将步骤(2)中研磨均匀的粉末加入步骤(1)熔体中,搅拌25min;(3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 25 minutes;
(4)熔体中加入玻璃纤维,继续搅拌25min;(4) Add glass fiber to the melt and continue to stir for 25 minutes;
(5)加入研磨后的柠檬酸,搅拌15min;(5) Add the ground citric acid and stir for 15 minutes;
(6)维持温度,保持熔体状态50min。(6) Maintain the temperature and maintain the melt state for 50 minutes.
经过上述过程可得到用于喷射反射内层2的新型多孔材料,吸能外层3可以采用市购35cm厚度的增强聚氨酯泡沫塑料,先将吸能外层35cm厚度的增强聚氨酯泡沫塑料固定在围岩上,再铺设巷道,巷道和增强聚氨酯泡沫塑料之间距离控制在10cm左右,在模具和增强聚氨酯泡沫塑料之间喷填新型多孔材料,自然冷却固化后与吸能外层 一起构成组合屏蔽结构。实际操作时,可根据实际情况,选择适宜厚度的吸能外层材料以及喷填适宜厚度的反射内层材料,实现有效的防护作用。新型组合屏蔽结构在搭建过程中,可根据需要在巷道和增强聚氨酯泡沫塑料层之间架设隔离和支撑模具,该组合屏蔽结构在地下深部开采时,能有效防护冲击地压对巷道的破坏和对围岩的二次损害,对生命财产安全有很好的保护作用。After the above process, a new type of porous material for spraying the reflective inner layer 2 can be obtained. The energy-absorbing outer layer 3 can be made of commercially available reinforced polyurethane foam with a thickness of 35 cm. Then pave the roadway on the rock. The distance between the roadway and the reinforced polyurethane foam is controlled to be about 10cm. The new porous material is sprayed between the mold and the reinforced polyurethane foam. After natural cooling and solidification, it forms a combined shielding structure with the energy-absorbing outer layer. . In actual operation, according to the actual situation, the appropriate thickness of the energy-absorbing outer layer material and the appropriate thickness of the reflective inner layer material can be selected to achieve effective protection. During the construction of the new combined shielding structure, isolation and support molds can be erected between the roadway and the reinforced polyurethane foam layer as required. The combined shielding structure can effectively protect the roadway from damage and damage caused by rock impact when mining deep underground. The secondary damage to the surrounding rock has a good protective effect on the safety of life and property.
实施例8Example 8
一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其中反射内层2包括以下重量份的原料:A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks, wherein the reflective inner layer 2 includes the following raw materials by weight:
烯烃类树脂22份、苯乙烯类树脂16份、碳材料粉5.5份、玻璃纤维2.5份、碳酸钙1.5份、柠檬酸1.5份、锡0.45份和二氧化硅粉20.5份;22 parts of olefin resin, 16 parts of styrene resin, 5.5 parts of carbon material powder, 2.5 parts of glass fiber, 1.5 parts of calcium carbonate, 1.5 parts of citric acid, 0.45 parts of tin, and 20.5 parts of silica powder;
将上述重量份的原料制成反射内层2所用新型多孔材料的过程:The process of making the above-mentioned parts by weight of the raw materials into the new porous material used in the reflective inner layer 2:
(1)将烯烃类树脂、苯乙烯类树脂混合,加热至170℃熔化,形成熔体;(1) Mix olefin resin and styrene resin, and heat to 170°C to melt to form a melt;
(2)将碳材料粉、碳酸钙、锡粉、二氧化硅粉投入球磨机中球磨8h;(2) Put carbon material powder, calcium carbonate, tin powder, and silica powder into a ball mill for ball milling for 8 hours;
(3)将步骤(2)中研磨均匀的粉末加入步骤(1)熔体中,搅拌22min;(3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 22 minutes;
(4)熔体中加入玻璃纤维,继续搅拌22min;(4) Add glass fiber to the melt and continue to stir for 22 minutes;
(5)加入研磨后的柠檬酸,搅拌12min;(5) Add the ground citric acid and stir for 12 minutes;
(6)维持温度,保持熔体状态45min。(6) Maintain the temperature and maintain the melt state for 45 minutes.
经过上述过程可得到用于喷射反射内层2的新型多孔材料,吸能外层3可以采用市购35cm厚度的泡沫铝材料,先将吸能外层35cm厚度的泡沫铝材料固定在围岩上,再铺设巷道,巷道和泡沫铝之间距离控制在15cm左右,在巷道和泡沫铝之间喷填新型多孔材料,自然冷却固化后与吸能外层一起构成组合屏蔽结构。实际操作时,可根据实际情况,选择适宜厚度的吸能外层材料以及喷填适宜厚度的反射内层材料,实现有效的防护作用。新型组合屏蔽结构在搭建过程中,可根据需要在巷道和泡沫铝层之间架设隔离和支撑模具,该组合屏蔽结构在地下深部开采时,能有效防护冲击地压对巷道的破坏和对围岩的二次损害,对生命财产安全有很好的保护作用。After the above process, a new type of porous material for the jet reflective inner layer 2 can be obtained. The energy-absorbing outer layer 3 can be made of a commercially available foamed aluminum material with a thickness of 35cm. , And then pave the roadway, the distance between the roadway and the foamed aluminum is controlled at about 15cm, and the new porous material is sprayed between the roadway and the foamed aluminum. After natural cooling and solidification, it forms a combined shielding structure with the energy-absorbing outer layer. In actual operation, according to the actual situation, the appropriate thickness of the energy-absorbing outer layer material and the appropriate thickness of the reflective inner layer material can be selected to achieve effective protection. During the construction of the new combined shielding structure, isolation and support molds can be erected between the roadway and the aluminum foam layer as required. The combined shielding structure can effectively protect the roadway from damage to the roadway and surrounding rock by the rock burst when mining deep underground. The secondary damage has a very good protective effect on the safety of life and property.
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。In addition, it should be understood that although this specification is described in accordance with the implementation manners, not each implementation manner only includes an independent technical solution. This narration in the specification is only for the sake of clarity, and those skilled in the art should regard the specification as a whole The technical solutions in the various embodiments can also be appropriately combined to form other implementations that can be understood by those skilled in the art.

Claims (10)

  1. 一种用于采动围岩地压灾害防护的新型组合屏蔽结构,设置于巷道和围岩之间,所述围岩位于巷道外侧,其特征在于,所述组合屏蔽结构由吸能外层和反射内层构成,吸能外层由具有缓冲吸能效果材料构成,反射内层由具有反射、分散和缓冲弹性能冲击应力波的新型多孔材料采用喷填方式构成。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks is arranged between the roadway and the surrounding rock. The surrounding rock is located on the outside of the roadway. The reflective inner layer is composed of an energy-absorbing outer layer made of materials with a buffering and energy-absorbing effect, and the reflective inner layer is made of a new type of porous material that reflects, disperses and buffers elastic energy shock and stress waves, and is composed of a spray filling method.
  2. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述喷填方式形成的反射内层为一体化结构。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, characterized in that the reflective inner layer formed by the spray filling method is an integrated structure.
  3. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述反射内层包括以下重量份的原料:烯烃类树脂18-24份、苯乙烯类树脂14-19.2份、碳材料粉4.8-7.2份、玻璃纤维2.1-3.2份、碳酸钙1-2份、柠檬酸1-2份、锡0.35-0.6份和二氧化硅粉17.6-23.8份。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, wherein the reflective inner layer comprises the following raw materials in parts by weight: 18-24 parts by weight of olefin resin, benzene 14-19.2 parts of vinyl resin, 4.8-7.2 parts of carbon material powder, 2.1-3.2 parts of glass fiber, 1-2 parts of calcium carbonate, 1-2 parts of citric acid, 0.35-0.6 parts of tin, and 17.6-23.8 parts of silica powder share.
  4. 根据权利要求2所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述反射内层的新型多孔材料制备方法包括以下步骤:A novel combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 2, characterized in that the preparation method of the new porous material of the reflective inner layer comprises the following steps:
    (1)将烯烃类树脂、苯乙烯类树脂混合,加热至熔化,形成熔体;(1) Mix olefin resin and styrene resin, and heat to melt to form a melt;
    (2)将碳材料粉、碳酸钙、锡粉、二氧化硅粉投入球磨机中球磨5-10h;(2) Put carbon material powder, calcium carbonate, tin powder, and silica powder into a ball mill for ball milling for 5-10 hours;
    (3)将步骤(2)中研磨均匀的粉末加入步骤(1)熔体中,搅拌20-25min;(3) Add the uniformly ground powder in step (2) to the melt in step (1), and stir for 20-25 minutes;
    (4)熔体中加入玻璃纤维,继续搅拌20-25min;(4) Add glass fiber to the melt and continue to stir for 20-25 minutes;
    (5)加入研磨后的柠檬酸,搅拌10-15min;(5) Add the ground citric acid and stir for 10-15min;
    (6)维持温度,保持熔体状态40-50min;(6) Maintain the temperature and keep the melt state for 40-50 minutes;
    (7)将经过上述步骤处理后的熔体直接喷填在需要部位,自然冷却后,固化成型。(7) The melt processed by the above steps is directly sprayed and filled on the required parts, and after natural cooling, it is solidified and formed.
  5. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述喷填方式是将权利要求4制备的新型多孔材料熔体采用 喷填方式喷填在巷道和吸能外层之间,固化后形成反射内层。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, wherein the spray filling method is to use the new porous material melt prepared in claim 4 by spray filling method. Spray filling between the roadway and the energy-absorbing outer layer, and form a reflective inner layer after curing.
  6. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述吸能外层是由各种具有材质轻、密度低和缓冲吸能特点的柔性多孔材料构成。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, characterized in that the energy-absorbing outer layer is made of various light materials, low density, and energy-absorbing characteristics. Made of flexible porous material.
  7. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,在发生冲击地压灾害时,所述吸能外层可以首先第一次吸收和缓冲冲击应力波,当衰减的冲击应力波到达反射内层时,再次被缓冲衰减,并被反射回吸能外层,历经吸能外层的第二次吸能和缓冲才能达到围岩。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, characterized in that, in the event of a rock burst disaster, the energy-absorbing outer layer can first absorb and Buffer shock stress wave. When the attenuated shock stress wave reaches the reflection inner layer, it is buffered and attenuated again, and is reflected back to the energy-absorbing outer layer. After the second energy absorption and buffering of the energy-absorbing outer layer, it can reach the surrounding rock.
  8. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述反射内层为三维互联网络形成的多孔材料,对应力入射波具有良好的反射作用。A new type of combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, wherein the reflective inner layer is a porous material formed by a three-dimensional interconnection network, which has good resistance to stress incident waves. Reflection effect.
  9. 根据权利要求1所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述反射内层材料包括具有最大800纳米的平均横截面尺寸的多个纳米孔,可以进一步实现缓冲和吸能。The novel combined shielding structure for protection against ground pressure disasters in mining surrounding rocks according to claim 1, wherein the reflective inner layer material comprises a plurality of nanopores with an average cross-sectional size of up to 800 nanometers. , Can further realize buffering and energy absorption.
  10. 根据权利要求3所述的一种用于采动围岩地压灾害防护的新型组合屏蔽结构,其特征在于,所述碳材料粉包括碳纤维、碳纳米管和碳粉中的至少一种。The novel combined shielding structure for protection against ground pressure disasters of mining surrounding rocks according to claim 3, wherein the carbon material powder comprises at least one of carbon fiber, carbon nanotube and carbon powder.
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