WO2021193751A1 - 電極組成物、全固体二次電池用電極シート及び全固体二次電池、並びに、全固体二次電池用電極シート及び全固体二次電池の製造方法 - Google Patents

電極組成物、全固体二次電池用電極シート及び全固体二次電池、並びに、全固体二次電池用電極シート及び全固体二次電池の製造方法 Download PDF

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WO2021193751A1
WO2021193751A1 PCT/JP2021/012346 JP2021012346W WO2021193751A1 WO 2021193751 A1 WO2021193751 A1 WO 2021193751A1 JP 2021012346 W JP2021012346 W JP 2021012346W WO 2021193751 A1 WO2021193751 A1 WO 2021193751A1
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solid
active material
secondary battery
state secondary
group
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English (en)
French (fr)
Japanese (ja)
Inventor
陽 串田
宏顕 望月
安田　浩司
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Fujifilm Corp
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Fujifilm Corp
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Priority to CN202180017766.9A priority Critical patent/CN115191042B/zh
Priority to EP21774547.0A priority patent/EP4131477A4/en
Priority to KR1020227029173A priority patent/KR102904901B1/ko
Priority to JP2022510617A priority patent/JP7357144B2/ja
Publication of WO2021193751A1 publication Critical patent/WO2021193751A1/ja
Priority to US17/899,630 priority patent/US20230006245A1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to an electrode composition, an all-solid-state secondary battery electrode sheet and an all-solid-state secondary battery, and a method for manufacturing an all-solid-state secondary battery electrode sheet and an all-solid-state secondary battery.
  • the negative electrode, the electrolyte, and the positive electrode are all solid, which can greatly improve the safety and reliability of the battery using the organic electrolyte. It is also said that it will be possible to extend the service life. Further, the all-solid-state secondary battery can have a structure in which electrodes and electrolytes are directly arranged side by side and arranged in series. Therefore, it is possible to increase the energy density as compared with a secondary battery using an organic electrolyte, and it is expected to be applied to an electric vehicle, a large storage battery, or the like.
  • the constituent layers (solid electrolyte layer, negative electrode active material layer, positive electrode active material layer, etc.) of such an all-solid secondary battery are formed of solid particles (inorganic solid electrolyte, active material, conductive auxiliary agent, etc.). Therefore, the interfacial contact state between the solid particles is restricted, and the interfacial resistance tends to increase (the ionic conductivity decreases). Moreover, when repeatedly charged and discharged, voids are generated between the solid particles, which causes an increase in interfacial resistance and causes a deterioration in the cycle characteristics of the all-solid secondary battery.
  • Patent Document 1 describes a negative electrode.
  • Patent Document 1 does not study from the above viewpoint, and the characteristics of an active material having a large specific surface area are described. It was found that it is important to solve the above problems in order to realize an all-solid secondary battery that shows excellent battery performance by making full use of it.
  • the present invention is an electrode composition that exhibits excellent dispersion stability while containing an active material having a large specific surface area, and also realizes excellent cycle characteristics while exhibiting strong adhesion to a current collector.
  • An object of the present invention is to provide an electrode composition capable of forming a layer (active material layer).
  • the present invention also provides an all-solid-state secondary battery electrode sheet and an all-solid-state secondary battery, and an all-solid-state secondary battery electrode sheet and an all-solid-state secondary battery manufacturing method using this electrode composition. The task is to do.
  • the present inventors have an SP value of 19.0 MPa 1 for an active material having a specific surface area of 10 m 2 / g or more in the presence of a sulfide-based inorganic solid electrolyte.
  • a binder made of a polymer having a component derived from a (meth) acrylic monomer or the like of / 2 or more in combination even an active material having a large specific surface area of 10 m 2 / g or more can be reaggregated over time. Alternatively, it was found that sedimentation can be suppressed and excellent dispersibility immediately after preparation can be maintained.
  • Electrode composition for The active material has a specific surface area of 10 m 2 / g or more and has a specific surface area of 10 m 2 / g or more.
  • ⁇ 2> The electrode composition according to ⁇ 1>, wherein the polymer binder is dissolved in a dispersion medium.
  • ⁇ 3> The electrode composition according to ⁇ 1> or ⁇ 2>, wherein the active material has a silicon element as a constituent element.
  • ⁇ 4> The electrode composition according to any one of ⁇ 1> to ⁇ 3>, wherein the constituent component has a polar group containing active hydrogen or a heterocyclic group.
  • R, R 1 , R 2 and R 3 represent hydrogen atoms or substituents.
  • L represents a linking group.
  • L 1 , L 2 and L 3 represent a single bond or linking group.
  • X is -O -, - S- or -NR M - indicates, R M is a hydrogen atom or a substituent.
  • Z indicates -OH or -COOH.
  • ⁇ 6> The electrode composition according to any one of ⁇ 1> to ⁇ 5>, wherein the polymer forming the polymer binder is a (meth) acrylic polymer or a vinyl polymer.
  • ⁇ 7> The electrode composition according to any one of ⁇ 1> to ⁇ 6>, which contains a conductive auxiliary agent.
  • An electrode sheet for an all-solid-state secondary battery having a layer composed of the electrode composition according to any one of ⁇ 1> to ⁇ 7> above on the surface of a current collector.
  • An all-solid-state secondary battery including a positive electrode active material layer, a solid electrolyte layer, and a negative electrode active material layer in this order.
  • An all-solid-state secondary battery in which at least one layer of a positive electrode active material layer and a negative electrode active material layer is composed of the electrode composition according to any one of ⁇ 1> to ⁇ 7>.
  • the present invention can form an electrode layer which is excellent in dispersion stability while containing an active material having a large specific surface area and can realize excellent cycle characteristics while exhibiting strong adhesion to a current collector.
  • Electrode compositions can be provided. Further, the present invention can provide an electrode sheet for an all-solid-state secondary battery and an all-solid-state secondary battery having an electrode layer composed of the electrode composition. Furthermore, the present invention can provide a method for manufacturing an electrode sheet for an all-solid-state secondary battery and an all-solid-state secondary battery using this electrode composition.
  • FIG. 2 is a vertical cross-sectional view schematically showing the coin-type all-solid-state secondary battery produced in the examples.
  • the numerical range represented by using "-" means a range including the numerical values before and after "-" as the lower limit value and the upper limit value.
  • the indication of a compound is used to mean that the compound itself, its salt, and its ion are included.
  • (meth) acrylic means one or both of acrylic and methacryl. The same applies to (meth) acrylate.
  • substituents for which substitution or non-substitution is not specified may have an appropriate substituent in the group. Therefore, in the present invention, even if it is simply described as a YYY group, this YYY group includes a mode having a substituent in addition to a mode having no substituent. This is also synonymous with compounds that do not specify substitution or non-substitution.
  • Preferred substituents include, for example, the substituent T described later.
  • the substituents or the like may be the same or different from each other. Means that.
  • the polymer means a polymer, but is synonymous with a so-called polymer compound.
  • the polymer binder means a binder composed of a polymer, and includes the polymer itself and a binder formed containing the polymer.
  • a composition containing an active material and used as a material for forming an active material layer of an all-solid-state secondary battery is referred to as an electrode composition.
  • an electrode composition a composition containing a sulfide-based inorganic solid electrolyte and used as a solid electrolyte layer forming material for an all-solid secondary battery is called a (sulfide-based) inorganic solid electrolyte-containing composition, and this composition is usually an active material. Does not contain.
  • the electrode composition includes a positive electrode composition containing a positive electrode active material and a negative electrode composition containing a negative electrode active material.
  • either one or both of the positive electrode composition and the negative electrode composition may be collectively referred to as an electrode composition.
  • either one or both of the positive electrode active material layer and the negative electrode active material layer may be collectively referred to as an active material layer or an electrode active material layer, and either a positive electrode active material or a negative electrode active material.
  • One or both of them may be simply referred to as an active material or an electrode active material.
  • the electrode composition of the present invention contains a sulfide-based inorganic solid electrolyte having ionic conductivity of a metal belonging to Group 1 or Group 2 of the Periodic Table, a polymer binder, an active material, and a dispersion medium.
  • the polymer binder is adsorbed on the active material in terms of initial dispersibility and dispersion stability (collectively referred to as dispersion characteristics) immediately after the preparation of the electrode composition (particularly the active material). However, it may or may not be adsorbed on the sulfide-based inorganic solid electrolyte.
  • the electrode composition of the present invention is preferably a slurry in which an active material and further a sulfide-based inorganic solid electrolyte are dispersed in a dispersion medium.
  • the polymer binder preferably has a function of dispersing solid particles in a dispersion medium.
  • the polymer binder functions as a binder for binding solid particles such as an active material, a sulfide-based inorganic solid electrolyte, and a coexisting conductive auxiliary agent in the active material layer. It also functions as a binder that binds the current collector and solid particles.
  • the polymer binder may or may not have a function of binding solid particles to each other.
  • the electrode composition of the present invention is excellent in dispersion stability even though it contains an active material having a large specific surface area.
  • the surface of the current collector has an active material layer that can realize excellent cycle characteristics while exhibiting a strong binding force (adhesion force) to the current collector.
  • An electrode sheet for an all-solid-state secondary battery and an all-solid-state secondary battery having excellent cycle characteristics can be realized.
  • the reason is not yet clear, but it can be considered as follows. That is, in the active material layer containing an active material having a large specific surface area of 10 m 2 / g or more, a large number of lithium ion conduction paths by the active material are constructed. Therefore, even if a part of the conduction paths is blocked (collapsed) by repeating charging and discharging, most of the remaining conduction paths are connected. Moreover, it is considered that the collapse of the conduction path can be suppressed even if high-speed charging / discharging at a large current is repeated in order to meet the recent high demands for all-solid-state secondary batteries.
  • the polymer binder has a component derived from a specific monomer having an SP value of 19.0 MPa 1/2 or more and the surface of the active material (usually, a portion where the oxidized polarity becomes high). It is considered that the interaction with (is) is strengthened. Therefore, this polymer binder promotes adsorption to the active material in the electrode composition, and even an active material having a large specific surface area of 10 m 2 / g or more can be highly dispersed (initial dispersion). It has excellent properties) and can suppress reaggregation or sedimentation over time (exhibits excellent dispersion stability).
  • the above-mentioned interaction is not particularly limited as long as the polymer binder and the active material are adsorbed, and may be a chemical interaction or a physical interaction.
  • the details of the above reasons have been explained focusing on the active material having a large specific surface area and the polymer binder, but the dispersion stability and adhesion due to the solid particles (sulfide-based inorganic solid electrolyte, conductive auxiliary agent, etc.) coexisting with the active material. It is considered that the influence of the decrease in the amount of the polymer binder is small, and the polymer binder functions on these solid particles in the same manner as the active material and exerts the above-mentioned action and effect.
  • the electrode composition of the present invention exhibits the above-mentioned excellent properties, it can be preferably used as an electrode sheet for an all-solid-state secondary battery or a material for forming an active material layer of an all-solid-state secondary battery.
  • it can be preferably used as a material for forming a negative electrode sheet for an all-solid secondary battery or a negative electrode active material layer containing a negative electrode active material having a large expansion and contraction due to charging and discharging, and excellent cycle characteristics can be achieved in this embodiment as well.
  • the electrode composition of the present invention is preferably a non-aqueous composition.
  • the non-aqueous composition includes not only a water-free aspect but also a form in which the water content (also referred to as water content) is preferably 500 ppm or less.
  • the water content is more preferably 200 ppm or less, further preferably 100 ppm or less, and particularly preferably 50 ppm or less.
  • the water content indicates the amount of water contained in the electrode composition (mass ratio to the electrode composition), specifically, filtered through a 0.02 ⁇ m membrane filter and measured using Karl Fischer titration. Value.
  • the electrode composition of the present invention contains a sulfide-based inorganic solid electrolyte.
  • the formed electrode active material layer has excellent deformability, and the contact area between solid particles such as the sulfide-based inorganic solid electrolyte and the active material in the layer. Furthermore, the contact area between the current collector and the electrode active material layer can be increased.
  • the inorganic solid electrolyte is an inorganic solid electrolyte
  • the solid electrolyte is a solid electrolyte capable of transferring ions inside the solid electrolyte. Since it does not contain organic substances as the main ionic conductive material, it is an organic solid electrolyte (polyelectrolyte represented by polyethylene oxide (PEO), organic such as lithium bis (trifluoromethanesulfonyl) imide (LiTFSI)). It is clearly distinguished from electrolyte salts). Further, since the inorganic solid electrolyte is a solid in a steady state, it is usually not dissociated or liberated into cations and anions.
  • PEO polyethylene oxide
  • LiTFSI lithium bis (trifluoromethanesulfonyl) imide
  • the sulfide-based inorganic solid electrolyte is not particularly limited as long as it has the ionic conductivity of a metal belonging to Group 1 or Group 2 of the periodic table, and generally does not have electron conductivity. ..
  • the all-solid-state secondary battery of the present invention is a lithium-ion battery, it is preferable that the sulfide-based inorganic solid electrolyte has lithium ion ionic conductivity.
  • a sulfide-based inorganic solid electrolyte material usually used for an all-solid secondary battery can be appropriately selected and used.
  • the sulfide-based inorganic solid electrolyte preferably contains a sulfur atom, has ionic conductivity of a metal belonging to Group 1 or Group 2 of the Periodic Table, and has electronic insulation.
  • the sulfide-based inorganic solid electrolyte preferably contains at least Li, S and P as elements and has lithium ion conductivity, but other than Li, S and P may be used depending on the purpose or case. It may contain elements.
  • Examples of the sulfide-based inorganic solid electrolyte include a lithium ion conductive sulfide-based inorganic solid electrolyte satisfying the composition represented by the following formula (S1).
  • L a1 M b1 P c1 S d1 A e1 (S1)
  • L represents an element selected from Li, Na and K, and Li is preferable.
  • M represents an element selected from B, Zn, Sn, Si, Cu, Ga, Sb, Al and Ge.
  • A represents an element selected from I, Br, Cl and F.
  • a1 to e1 indicate the composition ratio of each element, and a1: b1: c1: d1: e1 satisfy 1 to 12: 0 to 5: 1: 2 to 12: 0 to 10.
  • a1 is preferably 1 to 9, more preferably 1.5 to 7.5.
  • b1 is preferably 0 to 3, more preferably 0 to 1.
  • d1 is preferably 2.5 to 10, more preferably 3.0 to 8.5.
  • e1 is preferably 0 to 5, more preferably 0 to 3.
  • composition ratio of each element can be controlled by adjusting the blending amount of the raw material compound when producing the sulfide-based inorganic solid electrolyte as described below.
  • the sulfide-based inorganic solid electrolyte may be amorphous (glass) or crystallized (glass-ceramic), or only a part thereof may be crystallized.
  • Li-PS-based glass containing Li, P and S, or Li-PS-based glass ceramics containing Li, P and S can be used.
  • Sulfide-based inorganic solid electrolytes include, for example, lithium sulfide (Li 2 S), phosphorus sulfide (for example, diphosphorus pentasulfide (P 2 S 5 )), simple phosphorus, simple sulfur, sodium sulfide, hydrogen sulfide, and lithium halide (eg, lithium halide). It can be produced by the reaction of at least two or more raw materials in sulfides of LiI, LiBr, LiCl) and the element represented by M (for example, SiS 2 , SnS, GeS 2).
  • the ratio of Li 2 S and P 2 S 5 is, Li 2 S: at a molar ratio of P 2 S 5, preferably 60: 40 ⁇ It is 90:10, more preferably 68:32 to 78:22.
  • the lithium ion conductivity can be made high.
  • the lithium ion conductivity can be preferably 1 ⁇ 10 -4 S / cm or more, and more preferably 1 ⁇ 10 -3 S / cm or more. There is no particular upper limit, but it is practical that it is 1 ⁇ 10 -1 S / cm or less.
  • Li 2 S-P 2 S 5 Li 2 S-P 2 S 5 -LiCl, Li 2 S-P 2 S 5 -H 2 S, Li 2 S-P 2 S 5 -H 2 S-LiCl, Li 2 S-LiI-P 2 S 5 , Li 2 S-LiI-Li 2 O-P 2 S 5 , Li 2 S-LiBr-P 2 S 5 , Li 2 S-Li 2 O-P 2 S 5 , Li 2 S-Li 3 PO 4- P 2 S 5 , Li 2 S-P 2 S 5- P 2 O 5 , Li 2 S-P 2 S 5- SiS 2 , Li 2 S-P 2 S 5- SiS 2 -LiCl, Li 2 S-P 2 S 5 -SnS, Li 2 S-P 2 S 5 -Al 2 S 3, Li 2 S-GeS 2, Li 2
  • the mixing ratio of each raw material does not matter.
  • an amorphization method can be mentioned.
  • the amorphization method include a mechanical milling method, a solution method and a melt quenching method. This is because processing at room temperature is possible and the manufacturing process can be simplified.
  • the sulfide-based inorganic solid electrolyte is preferably particles.
  • the shape of the particles is not particularly limited and may be flat, amorphous or the like, but spherical or granular is preferable.
  • the average particle size (volume average particle size) of the sulfide-based inorganic solid electrolyte is not particularly limited, but is preferably 0.01 ⁇ m or more, and more preferably 0.1 ⁇ m or more.
  • the upper limit is preferably 100 ⁇ m or less, and more preferably 50 ⁇ m or less.
  • the average particle size of the sulfide-based inorganic solid electrolyte is measured by the following procedure.
  • the sulfide-based inorganic solid electrolyte particles are prepared by diluting a 1% by mass dispersion sample in a 20 mL sample bottle with water (heptane in the case of a water-unstable substance).
  • the diluted dispersion sample is irradiated with 1 kHz ultrasonic waves for 10 minutes, and immediately after that, it is used for the test.
  • data was captured 50 times using a laser diffraction / scattering particle size distribution measuring device LA-920 (trade name, manufactured by HORIBA) using a measuring quartz cell at a temperature of 25 ° C. Obtain the volume average particle size.
  • JIS Japanese Industrial Standards
  • Z 8828 2013 "Particle size analysis-Dynamic light scattering method" as necessary. Five samples are prepared for each level and the average value is adopted.
  • the specific surface area of the sulfide-based inorganic solid electrolyte usually has a value smaller than the specific surface area of the active material described later, but the specific surface area is not limited to this, and is appropriately set.
  • the sulfide-based inorganic solid electrolyte may contain one type or two or more types.
  • the content of the sulfide-based inorganic solid electrolyte in the electrode composition is not particularly limited, but in terms of adhesion and dispersibility, the solid content is 100% by mass and the total content with the active material is 50% by mass.
  • the above is preferable, 70% by mass or more is more preferable, and 90% by mass or more is particularly preferable.
  • the upper limit is preferably 99.9% by mass or less, more preferably 99.5% by mass or less, and particularly preferably 99% by mass or less.
  • the content of only the sulfide-based inorganic solid electrolyte in the electrode composition is appropriately set so that the total content of the active material is within the above range.
  • the solid content refers to a component that does not disappear by volatilizing or evaporating when the electrode composition is dried at 150 ° C. for 6 hours under an atmospheric pressure of 1 mmHg and a nitrogen atmosphere. Typically, it refers to a component other than the dispersion medium described later.
  • the electrode composition of the present invention contains an active material capable of inserting and releasing ions of a metal belonging to Group 1 or Group 2 of the periodic table.
  • the active material contained in the electrode composition of the present invention is in the form of particles at least in the electrode composition.
  • the shape of the particles is not particularly limited and may be flat, amorphous or the like, but spherical or granular is preferable.
  • the active material (particles) has a specific surface area of 10 m 2 / g or more. In the present invention, when used in combination with a polymer binder described later, it is possible to improve a significantly low dispersion property in an active material having a large specific surface area, and such an active material having a large specific surface area can be used.
  • the specific surface area of the active material is preferably set within a range in which improvement of dispersion characteristics and improvement of cycle characteristics can be achieved in a well-balanced manner.
  • the lower limit is preferably 12 m 2 / g or more, more preferably 15 m 2 / g or more, and further preferably 20 m 2 / g or more.
  • the upper limit value is preferably 50 m 2 / g or less, more preferably 45 m 2 / g or less, and further preferably 40 m 2 / g or less.
  • the specific surface area means the BET specific surface area, and is a value calculated by the BET (one point) method by the nitrogen adsorption method.
  • the active material used in the electrode composition, or the active material extracted from the electrode sheet for the all-solid-state secondary battery or the active material layer of the all-solid-state secondary battery as described below is used with the following measuring device. The value shall be the value measured under the following conditions.
  • BET specific surface area- Specific surface area / pore distribution measuring device Measured by gas adsorption method (nitrogen) using BELSORP MINI (trade name, manufactured by Microtrac Bell). 0.3 g of the active material is packed in a sample tube having an inner diameter of 3.6 mm, and nitrogen is flowed at 80 ° C. for 6 hours to dry the sample tube, which is used for measurement. -How to extract active material from the active material layer- 0.5 g of the active material layer is added to 50 g of butyl butyrate, and the mixture is centrifuged at 3000 rpm for 1 hour.
  • the active material extracted from the active material layer can be obtained by washing this precipitate twice with 25 g of N-methylformamide and then vacuum-drying it at 100 ° C. for 2 hours.
  • the active material having a specific surface area in the above range a commercially available product may be used, or an appropriately prepared product may be used.
  • the method for adjusting the specific surface area is not particularly limited, and a known method can be applied. Examples thereof include a method for adjusting the average particle size, a modification condition, and the like, which will be described later.
  • the average particle size of the active material used in the present invention is not particularly limited and is appropriately set in consideration of the specific surface area and the like. For example, in terms of both dispersion characteristics and cycle characteristics, it is preferably 10 ⁇ m or less, more preferably 1 ⁇ m or less, and even more preferably 0.6 ⁇ m or less.
  • the lower limit of the average particle size is practically 0.01 ⁇ m or more, for example, preferably 0.03 ⁇ m or more, and more preferably 0.05 ⁇ m or more.
  • the average particle size of the active material can be measured in the same manner as the average particle size of the sulfide-based inorganic solid electrolyte.
  • the method for adjusting the average particle size is not particularly limited, and a known method can be applied, and examples thereof include a method using a normal crusher or a classifier.
  • the crusher or classifier for example, a mortar, a ball mill, a sand mill, a vibrating ball mill, a satellite ball mill, a planetary ball mill, a swirling airflow type jet mill, a sieve, or the like is preferably used.
  • wet pulverization in which a dispersion medium such as water or methanol coexists can be performed. It is preferable to perform classification in order to obtain a desired average particle size.
  • the classification is not particularly limited, and can be performed using a sieve, a wind power classifier, or the like. Both dry and wet classifications can be used.
  • the active material examples include a negative electrode active material and a positive electrode active material.
  • the negative electrode active material is an active material capable of inserting and releasing ions of a metal belonging to Group 1 or Group 2 of the periodic table, and is preferably one capable of reversibly inserting and releasing lithium ions.
  • the material is not particularly limited as long as it has the above characteristics, and is a negative electrode activity capable of forming an alloy with a carbonaceous material, a metal oxide, a metal composite oxide, a single lithium substance, a lithium alloy, or lithium. Examples include substances. Of these, carbonaceous materials, metal composite oxides, or elemental lithium are preferably used from the viewpoint of reliability.
  • An active material that can be alloyed with lithium is preferable in that the capacity of the all-solid-state secondary battery can be increased. Since the active material layer formed of the electrode composition of the present invention can maintain a strong bonded state between solid particles, a negative electrode active material capable of forming an alloy with lithium can be used as the negative electrode active material. This makes it possible to increase the capacity of the all-solid-state secondary battery and extend the life of the battery.
  • the carbonaceous material used as the negative electrode active material is a material substantially composed of carbon.
  • carbon black such as acetylene black (AB), graphite (artificial graphite such as natural graphite and vapor-grown graphite), and PAN (polyacrylonitrile) -based resin or furfuryl alcohol resin.
  • a carbonaceous material obtained by firing a resin can be mentioned.
  • various carbon fibers such as PAN-based carbon fiber, cellulose-based carbon fiber, pitch-based carbon fiber, vapor-phase-grown carbon fiber, dehydrated PVA (polypoly alcohol) -based carbon fiber, lignin carbon fiber, glassy carbon fiber and activated carbon fiber.
  • carbonaceous materials can also be divided into non-graphitizable carbonaceous materials (also referred to as hard carbon) and graphite-based carbonaceous materials depending on the degree of graphitization. Further, the carbonaceous material preferably has the plane spacing or density and the size of crystallites described in JP-A-62-22066, JP-A-2-6856, and JP-A-3-45473.
  • the carbonaceous material does not have to be a single material, and a mixture of natural graphite and artificial graphite described in JP-A-5-90844, graphite having a coating layer described in JP-A-6-4516, and the like should be used. You can also.
  • As the carbonaceous material hard carbon or graphite is preferably used, and graphite is more preferably used.
  • the metal or semi-metal element oxide applied as the negative electrode active material is not particularly limited as long as it is an oxide capable of storing and releasing lithium, and is a composite of a metal element oxide (metal oxide) and a metal element.
  • metal oxide metal oxide
  • examples thereof include oxides or composite oxides of metal elements and semi-metal elements (collectively referred to as metal composite oxides) and oxides of semi-metal elements (semi-metal oxides).
  • metal composite oxides oxides or composite oxides of metal elements and semi-metal elements
  • oxides of semi-metal elements semi-metal elements
  • amorphous oxides are preferable, and chalcogenides, which are reaction products of metal elements and elements of Group 16 of the Periodic Table, are also preferable.
  • the metalloid element means an element exhibiting properties intermediate between a metal element and a non-metalloid element, and usually contains six elements of boron, silicon, germanium, arsenic, antimony and tellurium, and further selenium. , Polonium and Astatin.
  • amorphous means an X-ray diffraction method using CuK ⁇ rays, which has a broad scattering band having an apex in a region of 20 ° to 40 ° in 2 ⁇ value, and a crystalline diffraction line is used. May have.
  • the strongest intensity of the crystalline diffraction lines seen at the 2 ⁇ value of 40 ° to 70 ° is 100 times or less of the diffraction line intensity at the apex of the broad scattering band seen at the 2 ⁇ value of 20 ° to 40 °. It is preferable that it is 5 times or less, and it is particularly preferable that it does not have a crystalline diffraction line.
  • the amorphous oxide of the metalloid element or the chalcogenide is more preferable, and the elements of the Group 13 (IIIB) to 15 (VB) of the Periodic Table (for example).
  • Al, Ga, Si, Sn, Ge, Pb, Sb and Bi) alone or a combination of two or more (composite) oxides, or chalcogenides are particularly preferred.
  • preferable amorphous oxides and chalcogenides include, for example, Ga 2 O 3 , GeO, PbO, PbO 2 , Pb 2 O 3 , Pb 2 O 4 , Pb 3 O 4 , Sb 2 O 3 , Sb 2.
  • Negative negative active materials that can be used in combination with amorphous oxides such as Sn, Si, and Ge include carbonaceous materials that can occlude and / or release lithium ions or lithium metals, lithium alone, lithium alloys, and lithium.
  • a negative electrode active material that can be alloyed with is preferably mentioned.
  • the oxide of a metal or a metalloid element contains at least one of titanium and lithium as a constituent component from the viewpoint of high current density charge / discharge characteristics.
  • the lithium-containing metal composite oxide include a composite oxide of lithium oxide and the metal (composite) oxide or the chalcogenide, and more specifically, Li 2 SnO 2.
  • the negative electrode active material for example, a metal oxide, contains a titanium element (titanium oxide).
  • Li 4 Ti 5 O 12 (lithium titanate [LTO]) has excellent high-speed charge / discharge characteristics because the volume fluctuation during occlusion and release of lithium ions is small, and deterioration of electrodes is suppressed and lithium ion secondary This is preferable in that the battery life can be improved.
  • the lithium alloy as the negative electrode active material is not particularly limited as long as it is an alloy usually used as the negative electrode active material of the secondary battery, and examples thereof include a lithium aluminum alloy containing lithium as a base metal and 10% by mass of aluminum added. Be done.
  • the negative electrode active material that can be alloyed with lithium is not particularly limited as long as it is usually used as the negative electrode active material of the secondary battery.
  • Such an active material has a large expansion and contraction due to charging and discharging of an all-solid-state secondary battery and accelerates a decrease in cycle characteristics.
  • the electrode composition of the present invention contains the active material in combination with a polymer binder described later. Therefore, it is possible to effectively suppress the deterioration of the cycle characteristics due to charging and discharging.
  • Examples of such an active material include a (negative electrode) active material having a silicon element or a tin element (alloy, etc.), and metals such as Al and In, and a negative electrode active material having a silicon element that enables a higher battery capacity.
  • a silicon element-containing active material is preferable, and a silicon element-containing active material having a silicon element content of 50 mol% or more of all the constituent elements is more preferable.
  • a negative electrode containing these negative electrode active materials for example, a Si negative electrode containing a silicon element-containing active material, a Sn negative electrode containing a tin element active material, etc.
  • a carbon negative electrode graphite, acetylene black, etc.
  • silicon element-containing active material examples include silicon materials such as Si and SiOx (0 ⁇ x ⁇ 1), and silicon-containing alloys containing titanium, vanadium, chromium, manganese, nickel, copper, lanthanum, and the like (for example,).
  • LaSi 2 , VSi 2 , La-Si, Gd-Si, Ni-Si) or organized active material (eg LaSi 2 / Si), as well as other silicon and tin elements such as SnSiO 3 , SnSiS 3 Examples include active materials containing.
  • SiOx itself can be used as a negative electrode active material (metalloid oxide), and since Si is generated by the operation of an all-solid-state secondary battery, a negative electrode active material that can be alloyed with lithium (its). It can be used as a precursor substance).
  • the negative electrode active material having a tin element include Sn, SnO, SnO 2 , SnS, SnS 2 , and the active material containing the above-mentioned silicon element and tin element.
  • a composite oxide with lithium oxide for example, Li 2 SnO 2 can also be mentioned.
  • the above-mentioned negative electrode active material can be used without particular limitation, but in terms of battery capacity, a negative electrode active material that can be alloyed with silicon is a preferred embodiment as the negative electrode active material.
  • a negative electrode active material that can be alloyed with silicon is a preferred embodiment as the negative electrode active material.
  • the above-mentioned silicon material or silicon-containing alloy (alloy containing a silicon element) is more preferable, and it is further preferable to contain silicon (Si) or a silicon-containing alloy.
  • the negative electrode active material contained in the electrode composition may be one kind or two or more kinds.
  • the mass (mg) (grain amount) of the negative electrode active material per unit area (cm 2) of the negative electrode active material layer is not particularly limited. It can be appropriately determined according to the designed battery capacity, and can be, for example, 1 to 100 mg / cm 2 .
  • the content of the negative electrode active material in the electrode composition is not particularly limited, and is preferably 10 to 90% by mass, more preferably 20 to 85% by mass, and 30 to 80% by mass in terms of solid content of 100% by mass. It is more preferably%, and further preferably 40 to 75% by mass.
  • the positive electrode active material is an active material capable of inserting and releasing ions of a metal belonging to Group 1 or Group 2 of the periodic table, and is preferably one capable of reversibly inserting and releasing lithium ions.
  • the material is not particularly limited as long as it has the above characteristics, and may be a transition metal oxide, an organic substance, an element that can be composited with Li such as sulfur, or the like by decomposing the battery.
  • the 1 (Ia) group elements of the transition metal oxide to elemental M b (Table metal periodic other than lithium, the elements of the 2 (IIa) group, Al, Ga, In, Ge , Sn, Pb, Elements such as Sb, Bi, Si, P and B) may be mixed.
  • the mixing amount is preferably 0 to 30 mol% relative to the amount of the transition metal element M a (100 mol%). That the molar ratio of li / M a was synthesized were mixed so that 0.3 to 2.2, more preferably.
  • transition metal oxide examples include (MA) a transition metal oxide having a layered rock salt type structure, (MB) a transition metal oxide having a spinel type structure, (MC) a lithium-containing transition metal phosphate compound, and (MD).
  • MB transition metal oxide having a layered rock salt type structure
  • MC transition metal oxide having a spinel type structure
  • MD lithium-containing transition metal phosphate compound
  • MD lithium-containing transition metal phosphate compound
  • ME lithium-containing transition metal silicic acid compound and the like can be mentioned.
  • transition metal oxide having a layered rock salt structure examples include LiCoO 2 (lithium cobalt oxide [LCO]), LiNi 2 O 2 (lithium nickel oxide), LiNi 0.85 Co 0.10 Al 0. 05 O 2 (Lithium Nickel Cobalt Aluminate [NCA]), LiNi 1/3 Co 1/3 Mn 1/3 O 2 (Lithium Nickel Manganese Cobalt Oxide [NMC]) and LiNi 0.5 Mn 0.5 O 2 ( Lithium manganese nickel oxide).
  • LiCoO 2 lithium cobalt oxide
  • LiNi 2 O 2 lithium nickel oxide
  • LiNi 0.85 Co 0.10 Al 0. 05 O 2 Lithium Nickel Cobalt Aluminate [NCA]
  • LiNi 1/3 Co 1/3 Mn 1/3 O 2 Lithium Nickel Manganese Cobalt Oxide [NMC]
  • LiNi 0.5 Mn 0.5 O 2 Lithium manganese nickel oxide
  • (MB) Specific examples of the transition metal oxide having a spinel structure, LiMn 2 O 4 (LMO) , LiCoMnO 4, Li 2 FeMn 3 O 8, Li 2 CuMn 3 O 8, Li 2 CrMn 3 O 8 and Li 2 Nimn 3 O 8 can be mentioned.
  • Examples of the (MC) lithium-containing transition metal phosphate compound include olivine-type iron phosphate salts such as LiFePO 4 and Li 3 Fe 2 (PO 4 ) 3 , iron pyrophosphates such as LiFeP 2 O 7 , and LiCoPO 4.
  • Examples thereof include cobalt phosphates of Li 3 V 2 (PO 4 ) 3 (lithium vanadium phosphate) and other monooblique nacicon-type vanadium phosphate salts.
  • (MD) as the lithium-containing transition metal halogenated phosphate compound for example, Li 2 FePO 4 F such fluorinated phosphorus iron salt, Li 2 MnPO 4 hexafluorophosphate manganese salts such as F and Li 2 CoPO 4 F Fluorophosphate cobalts such as.
  • Examples of the (ME) lithium-containing transition metal silicic acid compound include Li 2 FeSiO 4 , Li 2 MnSiO 4 , and Li 2 CoSiO 4 .
  • a transition metal oxide having a (MA) layered rock salt type structure is preferable, and LCO or NMC is more preferable.
  • the positive electrode active material obtained by the firing method may be used after being washed with water, an acidic aqueous solution, an alkaline aqueous solution, or an organic solvent.
  • the positive electrode active material contained in the electrode composition may be one kind or two or more kinds.
  • the mass (mg) (grain amount) of the positive electrode active material per unit area (cm 2) of the positive electrode active material layer is not particularly limited. It can be appropriately determined according to the designed battery capacity, and can be, for example, 1 to 100 mg / cm 2 .
  • the content of the positive electrode active material in the electrode composition is not particularly limited, and is preferably 10 to 97% by mass, more preferably 30 to 95% by mass, still more preferably 40 to 93% by mass, based on 100% by mass of the solid content. , 50-90% by mass is particularly preferable.
  • the chemical formula of the compound obtained by the above firing method can be calculated from the inductively coupled plasma (ICP) emission spectroscopic analysis method as a measuring method and the mass difference of the powder before and after firing as a simple method.
  • ICP inductively coupled plasma
  • the surfaces of the positive electrode active material and the negative electrode active material may be surface-coated with another metal oxide.
  • the surface coating agent include metal oxides containing Ti, Nb, Ta, W, Zr, Al, Si or Li. Specific examples thereof include spinel titanate, tantalate oxide, niobate oxide, lithium niobate compound and the like.
  • the surface of the electrode containing the positive electrode active material or the negative electrode active material may be surface-treated with sulfur or phosphorus.
  • the surface of the positive electrode active material or the particle surface of the negative electrode active material may be surface-treated with active light rays or an active gas (plasma or the like) before and after the surface coating.
  • the polymer binder (also referred to as a binder) contained in the electrode composition of the present invention is used in combination with the above-mentioned active material having a specific surface area of 10 m 2 / g or more, and interacts with the active material. Improves dispersion stability in the electrode composition. Further, the dispersion stability can be improved for solid particles other than the active material. Further, by using the sulfide-based inorganic solid electrolyte and the active material in combination, high adhesion to the current collector and high adhesion between the solid particles are exhibited.
  • the binder is preferably soluble and soluble in the dispersion medium contained in the electrode composition. Thereby, the dispersion characteristics of the electrode composition can be further enhanced. Further, in the present invention, the binder is dissolved in the dispersion medium, which can further enhance the adhesion between the solid particles or the current collector to enhance the effect of improving the cycle characteristics of the all-solid-state secondary battery.
  • the term is not limited to a mode in which all the binders are dissolved in the dispersion medium, and for example, the solubility in the dispersion medium is 80% or more. The method for measuring the solubility is as follows.
  • a specified amount of the binder to be measured is weighed in a glass bottle, 100 g of a dispersion medium of the same type as the dispersion medium contained in the electrode composition is added thereto, and the rotation speed is 80 rpm on the mix rotor at a temperature of 25 ° C. Stir for 24 hours.
  • the transmittance of the mixed solution after stirring for 24 hours thus obtained is measured under the following conditions. This test (transmittance measurement) is performed by changing the amount of the binder dissolved (the above-specified amount), and the upper limit concentration X (mass%) at which the transmittance is 99.8% is defined as the solubility of the binder in the above dispersion medium.
  • the binder when the binder does not exhibit the above-mentioned solubility with respect to the dispersion medium contained in the electrode composition, it is preferable that the binder is present as particles in the electrode composition (dispersion medium).
  • the shape is not particularly limited and may be flat, amorphous or the like, but spherical or granular is preferable.
  • the average particle size of the particulate binder in the electrode composition is not particularly limited, but is preferably 10 nm or more, more preferably 50 nm or more, and further preferably 200 nm or more.
  • the upper limit is preferably 5 ⁇ m or less, more preferably 1 ⁇ m or less, and more preferably 500 nm or less.
  • the average particle size of the binder can be measured in the same manner as the average particle size of the inorganic solid electrolyte.
  • the average particle size of the binder can be adjusted by, for example, the type of dispersion medium, the composition of the binder-forming polymer, and the like.
  • the polymer forming the polymer binder (also referred to as a binder-forming polymer) is particularly limited as long as it has a component derived from a (meth) acrylic monomer or a vinyl monomer having an SP value of 19.0 MPa 1/2 or more. However, as will be described later, (meth) acrylic polymers or vinyl polymers are preferred.
  • the polymer forming the polymer binder may be one kind or two or more kinds.
  • the constituent component of the binder-forming polymer at least is a component derived from a monomer having an SP value of 19.0 MPa 1/2 or more.
  • the constituent components derived from the monomer having such an SP value are not particularly limited and may have no polar group (for example, an alkyl group having 1 to 6 carbon atoms), but have a polar group. Is preferable.
  • the alkyl group and the polar group interact with the surface of the above-mentioned active material having a specific surface area of 10 m 2 / g or more to adsorb the binder to the active material.
  • the SP value of the monomer that leads to the above-mentioned constituent components is 19.0 MPa 1/2 or more, solid particles.
  • the dispersion characteristics of the active material can be improved, and the adhesion can be strengthened.
  • Solid particles, in particular in terms of further improvements in dispersion characteristics and adhesion of the active material is preferably at 19.5MPa 1/2 or more, more preferably 20.0 MPa 1/2 or more, 20.5 MPa It is more preferably 1/2 or more.
  • the upper limit of the SP value can be appropriately set according to the specific surface area of the active material and the like, and is, for example, 28.0 MPa 1/2 or less in that excellent dispersion characteristics can be maintained without impairing the strong adhesion. It is preferably 26.5 MPa 1/2 or less, and more preferably.
  • the SP value of the monomer can be adjusted according to the type and number of polar groups introduced into the monomer.
  • the SP value of the monomer is the SP value as a monomer (homopolymer), and is a value obtained by the Hoy method (HL Hoy JOURNAL OF PAINT TECHNOLOGY Vol. 42, No. 541, 1970, 76-118, and POLYMER. HANDBOOK 4 th, 59 chapters, VII 686 page Table 5, Table 6 and the following formula see) the SP value in Table 6 (in terms of the MPa 1/2) (e.g., 1cal 1/2 cm -3/2 ⁇ 2.05J 1 / 2 cm -3/2 ⁇ 2.05MPa 1/2) was used.
  • the polar group contained in the above-mentioned polar group-containing constituent component is not particularly limited as long as the SP value of the monomer can be set to 19.0 MPa 1/2 or more, but for example, it is directly applied to a hetero atom such as active hydrogen (oxygen, nitrogen, etc.).
  • a hetero atom such as active hydrogen (oxygen, nitrogen, etc.).
  • Polar groups containing bonded hydrogen atoms hydroxyl groups, carboxy groups, sulfonic acid groups, phosphoric acid groups, phosphonic acid groups, amino groups, etc.
  • heterocyclic groups groups containing ether bonds (alkoxy groups, polyoxy groups, etc.) ), A nitrile group, an amide group and the like.
  • heterocyclic group examples include the corresponding group in the substituent T described later, and a group having an aliphatic heterocyclic structure described by the following formula (M1) is preferable.
  • the polar group is preferably a polar group containing active hydrogen or a heterocyclic group in terms of improving dispersion characteristics and adhesion, and further improving cycle characteristics.
  • the polar group-containing constituent is a constituent derived from a (meth) acrylic monomer or a vinyl monomer in terms of spreading to a dispersion medium in addition to appropriate adsorption by the polar group to the active material.
  • the (meth) acrylic monomer includes a monomer having a (meth) acryloyloxy group or a (meth) acryloylamino group, a (meth) acrylonitrile compound, and the like.
  • the (meth) acrylic monomer is not particularly limited, and is, for example, a (meth) acrylic compound (M) such as a (meth) acrylic acid compound, a (meth) acrylic acid ester compound, a (meth) acrylamide compound and a (meth) acrylonitrile compound. ), And among them, the (meth) acrylic acid ester compound is preferable.
  • the (meth) acrylic acid ester compound is not particularly limited, and examples thereof include esters such as aliphatic or aromatic hydrocarbons or aliphatic or aromatic heterocyclic compounds, and these hydrocarbons, heterocyclic compounds and the like.
  • the number of carbon atoms, the type or number of heteroatoms of the above is not particularly limited, and is appropriately set.
  • the number of carbon atoms can be 1 to 30.
  • the vinyl monomer is a monomer containing a vinyl group other than the (meth) acrylic compound (M), and is not particularly limited.
  • a vinyl group-containing aromatic compound styrene compound, vinyl naphthalene compound, etc.
  • a vinyl group are contained.
  • Heterocyclic compounds (vinylcarbazole compounds, vinylpyridine compounds, vinylimidazole compounds, vinyl group-containing aromatic heterocyclic compounds such as N-vinylcaprolactam, vinyl group-containing non-aromatic (aliphatic) heterocyclic compounds, etc.), allyl compounds, Examples thereof include vinyl compounds such as vinyl ether compounds, vinyl ketone compounds, vinyl ester compounds, dialkyl itaconate compounds, and unsaturated carboxylic acid anhydrides. Examples of the vinyl compound include "vinyl-based monomers" described in JP-A-2015-88486.
  • the polar group-containing constituent component is preferably a component derived from the (meth) acrylic monomer or vinyl monomer having the polar group, but in terms of further improvement of dispersion characteristics and adhesion, and further improvement of cycle characteristics. , It is more preferable to have a structure represented by the following formula (M1) or formula (M2).
  • the structure represented by the above formula (M1) is a component having a heterocyclic group (however, when X is ⁇ NH-, it also corresponds to a component having a polar group containing active hydrogen), and is described above.
  • the structure represented by the formula (M2) is a component having a polar group containing active hydrogen.
  • the atom, the substituent, the linking group and the like represented by each reference numeral are selected in an appropriate combination in consideration of the above SP value.
  • R, R 1 , R 2 and R 3 represent hydrogen atoms or substituents, respectively.
  • R, R 1 , R 2 or R 3 is not particularly limited, and examples thereof include a substituent T described later, and among them, an alkyl group, an aryl group, a halogen atom and the like are preferable.
  • R, R 1 , R 2 and R 3 a hydrogen atom, an alkyl group or a halogen atom is preferable, respectively, and a hydrogen atom, methyl or ethyl is more preferable. More preferably, R 1 and R 3 are hydrogen atoms and R 2 is methyl.
  • L represents a linking group.
  • the linking group that can be taken as L is appropriately selected from the following linking groups so that the structure represented by the formula (M1) is derived from the (meth) acrylic monomer or vinyl monomer.
  • the linking group can take as L, -CO-O-group, -CO-N (R N) - group (.
  • R N is as follows) more preferably a group containing, -CO-O-alkylene group, or -CO-N (R N) - alkylene group is particularly preferred.
  • L 1 and L 2 represent a single bond or a linking group, respectively, and preferably at least one of L 1 and L 2 is a linking group.
  • the linking group that can be taken as L 1 and L 2 is appropriately selected from the following linking groups, and an alkylene group or an alkaneylene group is preferable, and an alkylene group is more preferable.
  • X indicates -O-, -S- or -NR M- , and -O- is preferable.
  • RM indicates a hydrogen atom or a substituent. Substituents which can be taken as R M is not particularly limited, and a later-described substituent T. R M is a hydrogen atom or an alkyl group.
  • the ring structure configured to include a L 1, L 2 and X are not particularly limited as long as it appropriately combining L 1, L 2 and X, described above, containing polar groups
  • a ring structure that can be a heterocyclic group that can be a polar group of the constituents is preferable, an aliphatic heterocyclic structure is more preferable, an aliphatic saturated heterocyclic structure is further preferable, and a cyclic ether structure is particularly preferable.
  • the number of ring members of the ring structure in the formula (M1) is not particularly limited, but is preferably a 3- to 10-membered ring, more preferably a 4- to 8-membered ring, and a 4- to 6-membered ring. Is more preferable.
  • ring structure in the formula (M1) for example, an epoxy ring structure, an oxetane ring structure, a tetrahydrofuran ring structure, and a tetrahydropyran ring structure are preferably mentioned.
  • L 3 represents a single bond or linking group.
  • the linking group is appropriately selected from the following linking groups so that the structure represented by the formula (M2) is derived from a (meth) acrylic monomer or a vinyl monomer.
  • NS The linking group can take as L 3, -CO-O- group, -CO-N (R N) - group (.
  • R N is as follows) more preferably a group containing, -CO-O- alkylene group, or -CO-N (R N) - alkylene group is particularly preferred.
  • Z indicates -OH or -COOH.
  • the linking group is not particularly limited, but for example, an alkylene group (preferably 1 to 12 carbon atoms, more preferably 1 to 6 carbon atoms, further preferably 1 to 3 carbon atoms), an alkenylene group (2 to 3 carbon atoms).
  • an arylene group (number of carbon atoms is preferably 6 to 24, more preferably 6 to 10), an oxygen atom, a sulfur atom, an imino group (-NR N -: R N is hydrogen Atomic, alkyl group with 1 to 6 carbon atoms or aryl group with 6 to 10 carbon atoms), carbonyl group, phosphate linking group (-OP (OH) (O) -O-), phosphonic acid linking Examples thereof include a group (-P (OH) (O) -O-), or a group related to a combination thereof.
  • a polyalkyleneoxy chain can also be formed by combining an alkylene group and an oxygen atom.
  • a group composed of a combination of an alkylene group, an arylene group, a carbonyl group, an oxygen atom, a sulfur atom and an imino group is preferable, and a group composed of a combination of an alkylene group, an arylene group, a carbonyl group, an oxygen atom and an imino group is preferable.
  • -CO-O- group, -CO-N (R N) - group (. R N are as defined above) more preferably a group containing, -CO-O- group, or -CO-O- An alkylene group is particularly preferred.
  • the number of atoms constituting the linking group is preferably 1 to 36, more preferably 1 to 24, and even more preferably 1 to 12.
  • the number of connecting atoms of the linking group is preferably 10 or less, and more preferably 8 or less.
  • the lower limit is 1 or more.
  • the number of atoms constituting the linking group and the number of linking atoms are as described above, but the polyalkyleneoxy chain constituting the linking group is not limited to the above.
  • Each of the linking groups may or may not have a substituent. Examples of the substituent which may be possessed include a substituent T, and a halogen atom and the like are preferably mentioned.
  • the monomer having an SP value of 19.0 MPa 1/2 or more and the constituent components derived from this monomer include the following monomers and the constituent component M2 shown in Examples, but the present invention is not limited thereto.
  • the binder-forming polymer preferably has at least a component derived from a styrene compound as a polar group-containing component, and is derived from a component derived from a (meth) acrylic monomer and a vinyl monomer other than the styrene compound. It is more preferable to have at least one of the constituent components and a constituent component derived from the styrene compound (styrene constituent component).
  • the content of the above-mentioned polar group-containing constituents in the binder-forming polymer is appropriately set according to the SP value, and is not particularly limited and may be 100 mol%, but the dispersion stability of the solid particles is high. In terms of points, it is preferably more than 0 mol% and 90 mol% or less, and more preferably more than 0 mol% and 85 mol% or less.
  • the content of C A (mol%) of the polar group-containing component other than the styrene component (excluding components having no polar group.) is appropriately set in consideration of the above range However, it is preferably more than 0 mol% and 80 mol% or less, more preferably 0.1 to 60 mol%, further preferably 1 to 40 mol%, and 1 to 30 mol%. It is particularly preferable to be present, and most preferably 1 to 15 mol%.
  • the content of the constituents having no polar group (for example, the constituent having an alkyl group) in the binder-forming polymer is appropriately set, and can be set to, for example, 0 to 90 mol%. ..
  • the styrene component, the content of the binder forming polymer C S (mol%) is set appropriately in consideration of the above range, preferably 20 to 90 mol%, 20 to 80 moles %, More preferably 40 to 80 mol%, and particularly preferably 70 to 80 mol%.
  • binder-forming polymer has two or more comprising styrene component as a polar group-containing component, for content C S of the styrene component (mol%), and the other content of the polar group-containing component C A (mol % molar ratio) [C a / C S], the dispersion stability, in terms of the current collector adhesion and cycle characteristics, it is preferably 0.001 to 10, and 0.005 to 5 More preferably, it is more preferably 0.01 to 1.
  • the binder-forming polymer may have other constituents in addition to the polar group-containing constituents described above.
  • the other constituents are not particularly limited as long as they can form a copolymer with the above-mentioned polar group-containing constituents, and the SP value is less than 19.0 MPa 1/2 , preferably the SP value.
  • a component derived from a (meth) acrylic monomer or a vinyl monomer having a value of less than 19.0 MPa 1/2 can be mentioned.
  • These constituents can be selected from the compounds described as the monomers leading to the polar group-containing constituents, except that the SP values are different.
  • the (meth) acrylic acid alkyl ester compound is preferable, and the alkyl group constituting the alkyl ester preferably has 4 or more carbon atoms, preferably 6 or more, in terms of enhancing the solubility of the binder-forming polymer in the dispersion medium.
  • the alkyl group constituting the alkyl ester preferably has 4 or more carbon atoms, preferably 6 or more, in terms of enhancing the solubility of the binder-forming polymer in the dispersion medium.
  • 8 or more is more preferable, and 10 or more is further preferable.
  • the upper limit is not particularly limited, and is preferably 20 or less, and more preferably 14 or less.
  • the content of the other constituents in the binder-forming polymer is not particularly limited, but is preferably 5 to 99 mol%, more preferably 15 to 95 mol%.
  • the binder-forming polymer does not have a styrene component as a polar group-containing component, the content of the other components is appropriately set in consideration of the above range, but may be 30 to 90 mol%.
  • the lower limit is more preferably 40 mol% or more, further preferably 50 mol% or more, and particularly preferably 80 mol% or more.
  • the content of the other components is appropriately set in consideration of the above range, but is preferably 15 to 50 mol%, preferably 15 to 50 mol%. It is more preferably 40 mol%, further preferably 15 to 30 mol%. Further, the molar ratio of the content of the polar group-containing component to the content of other components is not particularly limited as long as the above content is satisfied, and can be appropriately set.
  • the type of the binder-forming polymer is not particularly limited as long as it has the above-mentioned polar group-containing constituent components, and various known polymers can be adopted, and vinyl polymers or (meth) acrylic polymers are preferable.
  • the vinyl polymer is not particularly limited, and examples thereof include a polymer containing a vinyl monomer other than the (meth) acrylic compound (M) in an amount of 50 mol% or more.
  • Examples of the vinyl monomer include the above-mentioned vinyl compounds.
  • the vinyl polymer includes polyvinyl alcohol, polyvinyl acetal, polyvinyl acetate, a copolymer containing these, and the like.
  • this vinyl polymer may have constituent components derived from the (meth) acrylic compound (M) that forms the (meth) acrylic polymer described later.
  • the content of the constituent component derived from the vinyl monomer is preferably the same as the content of the constituent component derived from the (meth) acrylic compound (M) in the (meth) acrylic polymer.
  • the content of the constituent component derived from the (meth) acrylic compound (M) is not particularly limited as long as it is less than 50 mol% in the polymer, but is preferably 0 to 40 mol%, and is preferably 5 to 35 mol%. Is more preferable.
  • the (meth) acrylic polymer is not particularly limited, but for example, a polymer obtained by (co) polymerizing at least one of the above-mentioned (meth) acrylic compounds (M) is preferable. Further, a (meth) acrylic polymer composed of a copolymer of the (meth) acrylic compound (M) and another polymerizable compound (N) is also preferable.
  • the other polymerizable compound (N) is not particularly limited, and examples thereof include the above-mentioned vinyl compounds.
  • the content of the other polymerizable compound (N) in the (meth) acrylic polymer is not particularly limited, but can be, for example, 50 mol% or less. Examples of the (meth) acrylic polymer include those described in Japanese Patent No. 6295332.
  • the content of the constituent components in the (meth) acrylic polymer is not particularly limited and may be appropriately selected and set in the following range, for example.
  • the above-mentioned content of the polar group-containing constituents is as described above.
  • the content of the constituent component (including the polar group-containing constituent component) derived from the (meth) acrylic compound (M) in the (meth) acrylic polymer is not particularly limited and may be 100 mol%.
  • the constituent component derived from the polymerizable compound (N) is contained, the content is preferably 1 to 90 mol%, more preferably 10 to 80 mol%, still more preferably 20 to 70 mol%.
  • the lower limit is particularly preferably more than 50 mol%.
  • the content of this component in the (meth) acrylic polymer is not particularly limited, but is 1 mol% or more and 50 mol%. It is preferably 10 mol% or more and 50 mol% or less, and particularly preferably 20 mol% or more and 50 mol% or less. It is also possible to adopt 10 mol% as the upper limit value.
  • the binder-forming polymer may have a substituent.
  • the substituent is not particularly limited, and preferably, a group selected from the following substituent T can be mentioned.
  • the binder-forming polymer can be synthesized by selecting a raw material compound (monomer) and polymerizing the raw material compound by a known method.
  • T- Alkyl groups preferably alkyl groups having 1 to 20 carbon atoms, such as methyl, ethyl, isopropyl, t-butyl, pentyl, heptyl, 1-ethylpentyl, benzyl, 2-ethoxyethyl, 1-carboxymethyl, etc.
  • alkenyl groups preferably alkyl groups having 1 to 20 carbon atoms, such as methyl, ethyl, isopropyl, t-butyl, pentyl, heptyl, 1-ethylpentyl, benzyl, 2-ethoxyethyl, 1-carboxymethyl, etc.
  • an alkenyl group having 2 to 20 carbon atoms for example, vinyl, allyl, oleyl, etc.
  • an alkynyl group preferably an alkynyl group having 2 to 20 carbon atoms, for example, ethynyl, butadynyl, phenylethynyl, etc.
  • a cycloalkyl group having 3 to 20 carbon atoms for example, cyclopropyl, cyclopentyl, cyclohexyl, 4-methylcyclohexyl, etc., is usually used in the present specification to include a cycloalkyl group.
  • An aryl group (preferably an aryl group having 6 to 26 carbon atoms, for example, phenyl, 1-naphthyl, 4-methoxyphenyl, 2-chlorophenyl, 3-methylphenyl, etc.), an aralkyl group (preferably having 7 carbon atoms).
  • ⁇ 23 aralkyl groups eg, benzyl, phenethyl, etc.
  • heterocyclic groups preferably heterocyclic groups having 2 to 20 carbon atoms, more preferably 5 or 5 having at least one oxygen atom, sulfur atom, nitrogen atom. It is a 6-membered heterocyclic group.
  • the heterocyclic group includes an aromatic heterocyclic group and an aliphatic heterocyclic group.
  • a tetrahydropyran ring group for example, a tetrahydropyran ring group, a tetrahydrofuran ring group, 2-pyridyl, 4-pyridyl, 2-. Imidazolyl, 2-benzoimidazolyl, 2-thiazolyl, 2-oxazolyl, pyrrolidone group, etc.), alkoxy group (preferably an alkoxy group having 1 to 20 carbon atoms, for example, methoxy, ethoxy, isopropyloxy, benzyloxy, etc.), aryloxy group.
  • an aryloxy group having 6 to 26 carbon atoms for example, phenoxy, 1-naphthyloxy, 3-methylphenoxy, 4-methoxyphenoxy, etc.
  • a heterocyclic oxy group a group in which an —O— group is bonded to the heterocyclic group
  • an alkoxycarbonyl group preferably an alkoxycarbonyl group having 2 to 20 carbon atoms, for example, ethoxycarbonyl, 2-ethylhexyloxycarbonyl.
  • aryloxycarbonyl groups preferably aryloxycarbonyl groups with 6-26 carbon atoms, such as phenoxycarbonyl, 1-naphthyloxycarbonyl, 3-me Chilphenoxycarbonyl, 4-methoxyphenoxycarbonyl, etc.
  • heterocyclic oxycarbonyl group group in which -O-CO- group is bonded to the above heterocyclic group
  • amino group preferably amino group having 0 to 20 carbon atoms, alkyl It contains an amino group and an arylamino group, and includes, for example, amino (-NH 2 ), N, N-dimethylamino, N, N-diethylamino, N-ethylamino, anirino, etc., and a sulfamoyl group (preferably having 0 to 20 carbon atoms).
  • Sulfamoyl group of, for example, N, N-dimethylsulfamoyl, N-phenylsulfamoyl, etc. acyl group (alkylcarbonyl group, alkenylcarbonyl group, alkynylcarbonyl group, arylcarbonyl group, heterocyclic carbonyl group, etc.
  • an acyl group having 1 to 20 carbon atoms for example, acetyl, propionyl, butyryl, octanoyl, hexadecanoyl, acryloyl, methacryloyl, crotonoyle, benzoyl, naphthoyl, nicotineol, etc., and an acyloxy group (alkylcarbonyloxy group, alkenylcarbonyloxy).
  • heterocyclic thio group group in which -S- group is bonded to the above heterocyclic group
  • alkylsulfonyl group preferably alkylsulfonyl group having 1 to 20 carbon atoms.
  • RP is a hydrogen atom or a substituent (preferably a group selected from the substituent T). Further, each group listed in these substituents T may be further substituted with the above-mentioned substituent T.
  • the alkyl group, alkylene group, alkenyl group, alkenylene group, alkynyl group and / or alkynylene group and the like may be cyclic or chain-like, or may be linear or branched.
  • the polymer binder or the binder-forming polymer preferably has the following physical properties or properties.
  • the SP value (unit: MPa 1/2 ) of the binder-forming polymer is not particularly limited, but is preferably 17.0 to 22.0, for example, 17.5 to 22.0 in terms of dispersion stability of solid particles. It is more preferably 21.0, and even more preferably 18.0 to 20.0.
  • the SP value of the binder-forming polymer can be adjusted according to the type, content, etc. of the above-mentioned constituent components.
  • the SP value of the binder-forming polymer is calculated from the following formula by obtaining the SP value of each component as described above.
  • the SP value of the constituent component obtained in accordance with the above document is converted into the SP value (MPa 1/2) and used.
  • the mass fraction of the constituent component is the mass fraction of the constituent component (the raw material compound that derives this constituent component) in the binder-forming polymer.
  • the water concentration of the polymer binder is preferably 100 ppm (mass basis) or less.
  • the polymer binder may be crystallized and dried, or the polymer binder dispersion may be used as it is.
  • the binder-forming polymer is preferably amorphous.
  • the term "amorphous" as a polymer typically means that no endothermic peak due to crystal melting is observed when measured at the glass transition temperature.
  • the binder-forming polymer may be a non-crosslinked polymer or a crosslinked polymer. Further, when the cross-linking of the polymer proceeds by heating or application of a voltage, the molecular weight may be larger than the above molecular weight.
  • the polymer has a mass average molecular weight in the range described below at the start of use of the all-solid-state secondary battery.
  • the mass average molecular weight of the binder-forming polymer is not particularly limited. For example, 15,000 or more is preferable, 30,000 or more is more preferable, and 50,000 or more is further preferable.
  • the upper limit is substantially 5,000,000 or less, preferably 4,000,000 or less, more preferably 3,000,000 or less, and even more preferably 1,000,000 or less.
  • the molecular weight of a polymer such as a polymer or a polymer chain refers to the mass average molecular weight in terms of standard polystyrene by gel permeation chromatography (GPC) unless otherwise specified.
  • GPC gel permeation chromatography
  • condition 1 or condition 2 (priority) method can be basically mentioned.
  • an appropriate eluent may be appropriately selected and used. (Condition 1) Column: Connect two TOSOH TSKgel Super AWM-H (trade name, manufactured by Tosoh Corporation) Carrier: 10 mM LiBr / N-methylpyrrolidone Measurement temperature: 40 ° C.
  • Carrier flow rate 1.0 ml / min Sample concentration: 0.1% by mass Detector: RI (refractive index) detector (condition 2) Column: A column connected with TOSOH TSKgel Super HZM-H, TOSOH TSKgel Super HZ4000, and TOSOH TSKgel Super HZ2000 (all trade names, manufactured by Tosoh Corporation) is used.
  • Carrier tetrahydrofuran Measurement temperature: 40 ° C
  • Carrier flow rate 1.0 ml / min Sample concentration: 0.1% by mass Detector: RI (refractive index) detector
  • the electrode composition of the present invention may contain one kind or two or more kinds of polymer binders.
  • the content of the polymer binder in the electrode composition is not particularly limited, but is 0.1 to 10.0% by mass in 100% by mass of the solid content in terms of dispersion stability, collector adhesion and cycle characteristics. It is preferably 0.2 to 8% by mass, more preferably 0.3 to 6% by mass, and particularly preferably 0.5 to 3% by mass.
  • the mass ratio of the total mass (total amount) of the sulfide-based inorganic solid electrolyte and the active material to the total mass of the polymer binder at 100% by mass of the solid content [(mass of the sulfide-based inorganic solid electrolyte + active material).
  • Mass) / (total mass of polymer binder)] is preferably in the range of 1,000 to 1. This ratio is more preferably 500 to 2, and even more preferably 100 to 10.
  • the electrode composition of the present invention contains a dispersion medium that disperses or dissolves each of the above components.
  • the dispersion medium may be an organic compound that is liquid in the environment of use, and examples thereof include various organic solvents. Specifically, an alcohol compound, an ether compound, an amide compound, an amine compound, a ketone compound, and an aromatic compound. , Aliper compounds, nitrile compounds, ester compounds and the like.
  • the dispersion medium may be a non-polar dispersion medium (hydrophobic dispersion medium) or a polar dispersion medium (hydrophilic dispersion medium), but a non-polar dispersion medium is preferable because it can exhibit excellent dispersibility.
  • the non-polar dispersion medium generally refers to a property having a low affinity for water, and in the present invention, for example, an ester compound, a ketone compound, an ether compound, a perfume compound, an aliphatic compound and the like can be mentioned.
  • Examples of the alcohol compound include methyl alcohol, ethyl alcohol, 1-propyl alcohol, 2-propyl alcohol, 2-butanol, ethylene glycol, propylene glycol, glycerin, 1,6-hexanediol, cyclohexanediol, sorbitol, xylitol, and 2 -Methyl-2,4-pentanediol, 1,3-butanediol, 1,4-butanediol can be mentioned.
  • ether compound examples include alkylene glycol (diethylene glycol, triethylene glycol, polyethylene glycol, dipropylene glycol, etc.), alkylene glycol monoalkyl ether (ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, diethylene glycol monomethyl ether, etc.).
  • alkylene glycol diethylene glycol, triethylene glycol, polyethylene glycol, dipropylene glycol, etc.
  • alkylene glycol monoalkyl ether ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, diethylene glycol monomethyl ether, etc.
  • amide compound examples include N, N-dimethylformamide, N-methyl-2-pyrrolidone, 2-pyrrolidinone, 1,3-dimethyl-2-imidazolidinone, ⁇ -caprolactam, formamide, N-methylformamide and acetamide. , N-Methylacetamide, N, N-dimethylacetamide, N-methylpropanamide, hexamethylphosphoric triamide and the like.
  • Examples of the amine compound include triethylamine, diisopropylethylamine, tributylamine and the like.
  • Examples of the ketone compound include acetone, methyl ethyl ketone, methyl isobutyl ketone (MIBK), cyclopentanone, cyclohexanone, cycloheptanone, dipropyl ketone, dibutyl ketone, diisopropyl ketone (DIPK), diisobutyl ketone (DIBK), and isobutyl propyl ketone. , Se-butyl propyl ketone, pentyl propyl ketone, butyl propyl ketone and the like.
  • Examples of the aromatic compound include benzene, toluene, xylene and the like.
  • Examples of the aliphatic compound include hexane, heptane, octane, nonane, decane, dodecane, cyclohexane, methylcyclohexane, ethylcyclohexane, cycloheptane, cyclooctane, decalin, paraffin, gasoline, naphtha, kerosene, and light oil.
  • Examples of the nitrile compound include acetonitrile, propionitrile, isobutyronitrile and the like.
  • ester compound examples include ethyl acetate, butyl acetate, propyl acetate, propyl butyrate, isopropyl butyrate, butyl butyrate, isobutyl butyrate, butyl pentanate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, isobutyl isobutyrate, and pivalic acid.
  • Examples thereof include propyl, isopropyl pivalate, butyl pivalate, and isobutyl pivalate.
  • ether compounds, ketone compounds, aromatic compounds, aliphatic compounds and ester compounds are preferable, and ester compounds, ketone compounds or ether compounds are more preferable.
  • the number of carbon atoms of the compound constituting the dispersion medium is not particularly limited, and is preferably 2 to 30, more preferably 4 to 20, further preferably 6 to 15, and particularly preferably 7 to 12.
  • the dispersion medium preferably has, for example, an SP value (unit: MPa 1/2 ) of 14 to 24, more preferably 15 to 22, and 16 to 20. Is more preferable.
  • the difference (absolute value) between the SP values of the dispersion medium and the polymer binder is not particularly limited, but the molecular chains of the polymer forming the polymer binder in the dispersion medium are expanded to improve the dispersibility of the solid particles.
  • the electrode composition of the present invention contains two or more kinds of binders, it is preferable that at least one kind of binder satisfies the difference (absolute value) of the above SP values. It is also one of the preferable embodiments that all the binders satisfy the difference (absolute value) of the SP values.
  • the SP value of the dispersion medium is a value obtained by converting the SP value calculated by the Hoy method described above into the unit MPa 1/2.
  • the SP value of the dispersion medium means the SP value of the entire dispersion medium, and is the sum of the products of the SP value of each dispersion medium and the mass fraction. .. Specifically, it is calculated in the same manner as the above-mentioned method for calculating the SP value of the polymer, except that the SP value of each dispersion medium is used instead of the SP value of the constituent components.
  • the SP value (the unit is omitted) of the dispersion medium is shown below.
  • MIBK MIBK (18.4), diisopropyl ether (16.8), dibutyl ether (17.9), diisopropyl ketone (17.9), DIBK (17.9), butyl butyrate (18.6), butyl acetate (18) .9), toluene (18.5), ethylcyclohexane (17.1), cyclooctane (18.8), isobutyl ethyl ether (15.3), N-methylpyrrolidone (NMP, 25.4)
  • the dispersion medium preferably has a boiling point of 50 ° C. or higher at normal pressure (1 atm), and more preferably 70 ° C. or higher.
  • the upper limit is preferably 250 ° C. or lower, and more preferably 220 ° C. or lower.
  • the electrode composition of the present invention may contain only one type of dispersion medium and may contain two or more types.
  • the content of the dispersion medium in the electrode composition is not particularly limited and can be appropriately set.
  • 20 to 80% by mass is preferable, 30 to 70% by mass is more preferable, and 40 to 60% by mass is particularly preferable.
  • the electrode composition of the present invention preferably contains a conductive auxiliary agent, and for example, a silicon element-containing active material as a negative electrode active material is preferably used in combination with a conductive auxiliary agent.
  • the conductive auxiliary agent is not particularly limited, and those known as general conductive auxiliary agents can be used.
  • electron conductive materials such as natural graphite, artificial graphite and other graphite, acetylene black, Ketjen black, furnace black and other carbon blacks, needle coke and other amorphous carbon, vapor-grown carbon fiber or carbon nanotubes.
  • It may be a carbon fiber such as carbon fibers such as graphene or fullerene, a metal powder such as copper or nickel, or a metal fiber, and a conductive polymer such as polyaniline, polypyrrole, polythiophene, polyacetylene, or polyphenylene derivative. May be used.
  • a carbon fiber such as carbon fibers such as graphene or fullerene
  • a metal powder such as copper or nickel
  • a metal fiber such as a metal powder such as copper or nickel
  • a metal fiber such as a metal powder such as copper or nickel
  • a metal fiber such as a metal powder such as copper or nickel
  • a metal fiber such as polyaniline, polypyrrole, polythiophene, polyacetylene, or polyphenylene derivative. May be used.
  • metal ions preferably Li
  • a conductive auxiliary agent is one that does not insert and release ions) and does not function as an active material.
  • conductive auxiliary agents those that can function as active materials in the active material layer when the battery is charged and discharged are classified as active materials instead of conductive auxiliary agents. Whether or not the battery functions as an active material when it is charged and discharged is not unique and is determined by the combination with the active material.
  • the electrode composition of the present invention may contain one kind of conductive auxiliary agent or two or more kinds.
  • the shape of the conductive auxiliary agent is not particularly limited, but is preferably in the form of particles.
  • the average particle size in this case is not particularly limited and is appropriately set.
  • the specific surface area usually has a value smaller than the specific surface area of the active material described later, but is not limited to this, and is appropriately set.
  • the content of the conductive auxiliary agent in the electrode composition is preferably 0 to 10% by mass with respect to 100% by mass of solid content.
  • the electrode composition of the present invention may contain an inorganic solid electrolyte other than the sulfide-based inorganic solid electrolyte.
  • examples thereof include oxide-based sulfide-based inorganic solid electrolytes, halide-based sulfide-based inorganic solid electrolytes, and hydride-based inorganic solid electrolytes that are usually used in all-solid-state secondary batteries.
  • the content of the inorganic solid electrolyte other than the sulfide-based inorganic solid electrolyte in the electrode composition is not particularly limited and is appropriately set as long as the effects of the present invention are not impaired.
  • the electrode composition of the present invention preferably contains a lithium salt (supporting electrolyte).
  • the lithium salt the lithium salt usually used for this kind of product is preferable, and there is no particular limitation.
  • the lithium salt described in paragraphs 882 to 985 of JP2015-088486 is preferable.
  • the electrode composition of the present invention contains a lithium salt, the content of the lithium salt is preferably 0.1 part by mass or more, more preferably 5 parts by mass or more, based on 100 parts by mass of the solid electrolyte.
  • the upper limit is preferably 50 parts by mass or less, more preferably 20 parts by mass or less.
  • the electrode composition of the present invention may not contain a dispersant other than this polymer binder, but may contain a dispersant.
  • the dispersant those usually used for all-solid-state secondary batteries can be appropriately selected and used. Generally, compounds intended for particle adsorption, steric repulsion and / or electrostatic repulsion are preferably used.
  • an ionic liquid as components other than the above-mentioned components, an ionic liquid, a thickener, a cross-linking agent (such as one that undergoes a cross-linking reaction by radical polymerization, condensation polymerization, or ring-opening polymerization) and polymerization initiation are appropriately performed. It can contain agents (such as those that generate acids or radicals by heat or light), defoaming agents, leveling agents, dehydrating agents, antioxidants and the like.
  • the ionic liquid is contained in order to further improve the ionic conductivity, and known ones can be used without particular limitation. Further, a polymer other than the polymer forming the polymer binder described above, a commonly used binder and the like may be contained.
  • a sulfide-based inorganic solid electrolyte, a polymer binder, an active material and a dispersion medium, a conductive auxiliary agent, an appropriately lithium salt, and any other components are mixed, for example, in various mixers usually used. do. Thereby, it can be prepared as a mixture, preferably as a slurry.
  • the mixing method is not particularly limited, and the mixture may be mixed all at once or sequentially.
  • the mixing environment is not particularly limited, and examples thereof include under dry air and under an inert gas.
  • the electrode sheet for an all-solid-state secondary battery of the present invention (sometimes simply referred to as an electrode sheet) is in the form of a sheet capable of forming an electrode (a laminate of an active material layer and a current collector) of an all-solid-state secondary battery. It is a molded body, and includes various aspects depending on its use.
  • the electrode sheet of the present invention has an active material layer composed of the above-mentioned electrode composition of the present invention on the surface of a current collector. Therefore, the active material layer and the current collector are firmly adhered to each other (the current collector adhesion is strong), and the solid particles are also firmly adhered to each other, and the active material layer exhibits high strength.
  • This electrode sheet is in close contact with the active material layer even when it is wound around a winding core by an industrial manufacturing method, for example, a highly productive roll-to-roll method, or during or after the manufacturing process. Can be maintained. Furthermore, the occurrence of defects (chips, cracks, cracks, peeling, etc.) of the active material layer can be suppressed.
  • this electrode sheet as an electrode (a laminate of an active material layer and a current collector) of an all-solid-state secondary battery, excellent cycle characteristics can be imparted to the all-solid-state secondary battery.
  • the electrode sheet of the present invention may be an electrode sheet having an active material layer on the surface of the current collector.
  • the electrode sheet also includes an embodiment having a current collector, an active material layer and a solid electrolyte layer in this order, and an embodiment having a current collector, an active material layer, a solid electrolyte layer and an active material layer in this order.
  • the electrode sheet may have other layers in addition to the above-mentioned layers. Examples of other layers include a protective layer (release sheet), a current collector, a coat layer, and the like.
  • the base material is not particularly limited as long as it can support the active material layer, and examples thereof include a material described in the current collector described later, a sheet body (plate-shaped body) such as an organic material and an inorganic material.
  • a sheet body such as an organic material and an inorganic material.
  • the organic material include various polymers, and specific examples thereof include polyethylene terephthalate, polypropylene, polyethylene, and cellulose.
  • the inorganic material include glass, ceramic and the like.
  • the active material layer provided on the surface of the current collector is formed of the electrode composition of the present invention.
  • the content of each component is not particularly limited, but is preferably synonymous with the content of each component in the solid content of the electrode composition of the present invention. ..
  • the layer thickness of each layer constituting the electrode sheet of the present invention is the same as the layer thickness of each layer described in the all-solid-state secondary battery described later.
  • each layer constituting the all-solid-state secondary battery sheet may have a single-layer structure or a multi-layer structure.
  • the constituent layers such as the solid electrolyte layer are formed of ordinary materials.
  • the method for producing the electrode sheet for an all-solid-state secondary battery of the present invention is not particularly limited, and the electrode sheet can be produced by forming an active material layer on the surface of the current collector using the electrode composition of the present invention.
  • a method of forming a film (coating and drying) the electrode composition of the present invention on the surface of a current collector (base material) to form a layer (coating and drying layer) composed of the electrode composition can be mentioned. Thereby, a sheet having a current collector and a coating dry layer can be produced.
  • the coating dry layer is a layer formed by applying the electrode composition of the present invention and drying the dispersion medium (that is, the electrode composition of the present invention is used, and the electrode composition of the present invention is used.
  • the dispersion medium may remain as long as the effect of the present invention is not impaired, and the residual amount is, for example, 3% by mass or less in each layer. can do.
  • this coating dry layer contains a polymer binder.
  • each step such as coating and drying will be described in the following method for manufacturing an all-solid-state secondary battery.
  • the adhesion between the current collector and the active material layer can be strengthened.
  • the coating dry layer can also be pressurized.
  • the pressurizing conditions and the like will be described in the method for manufacturing an all-solid-state secondary battery described later.
  • the obtained coated dry layer is appropriately subjected to pressure treatment or the like to become an active material layer.
  • the base material, the protective layer (particularly the release sheet) and the like can be peeled off.
  • the method for producing a sheet for an all-solid secondary battery of the present invention is an industrial production method, for example, a roll-to-roll method with high productivity, by using the electrode composition of the present invention, or during or during the production process. It can also be applied to a manufacturing method in which the sheet is wound around a winding core later, and a sheet for an all-solid secondary battery can be manufactured with high productivity.
  • the all-solid secondary battery of the present invention comprises a positive electrode active material layer, a negative electrode active material layer facing the positive electrode active material layer, and a solid electrolyte layer arranged between the positive electrode active material layer and the negative electrode active material layer.
  • the positive electrode active material layer is preferably formed on the positive electrode current collector and constitutes the positive electrode.
  • the negative electrode active material layer is preferably formed on the negative electrode current collector to form the negative electrode. It is also preferable that at least one layer of the negative electrode active material layer and the positive electrode active material layer is formed of the electrode composition of the present invention, and the negative electrode active material layer and the positive electrode active material layer are formed of the electrode composition of the present invention. It is one of the embodiments.
  • forming the active material layer of the all-solid secondary battery with the electrode composition of the present invention means that the electrode sheet for the all-solid secondary battery of the present invention (provided that the active material formed with the electrode composition of the present invention is used).
  • the sheet from which these layers have been removed is used to form a laminate (electrode) of the active material layer and the current collector.
  • the active material layer formed of the electrode composition of the present invention preferably contains the same component species and the content thereof in the solid content of the electrode composition of the present invention. If the active material layer or the solid electrolyte layer is not formed by the electrode composition of the present invention, a known material can be used.
  • the all-solid-state secondary battery of the present invention exhibits excellent cycle characteristics and enables high-speed charging / discharging at a large current in addition to charging / discharging under normal conditions. In addition, it is possible to take out a large current by showing low resistance and high ionic conductivity.
  • the thicknesses of the negative electrode active material layer, the solid electrolyte layer, and the positive electrode active material layer are not particularly limited.
  • the thickness of each layer is preferably 10 to 1,000 ⁇ m, more preferably 20 ⁇ m or more and less than 500 ⁇ m, respectively, in consideration of the dimensions of a general all-solid-state secondary battery.
  • the thickness of at least one of the positive electrode active material layer and the negative electrode active material layer is 50 ⁇ m or more and less than 500 ⁇ m.
  • the all-solid-state secondary battery of the present invention may be used as an all-solid-state secondary battery with the above structure, but in order to form a dry battery, it should be further enclosed in a suitable housing.
  • the housing may be made of metal or resin (plastic).
  • a metallic material for example, one made of aluminum alloy or stainless steel can be mentioned.
  • the metallic housing is divided into a positive electrode side housing and a negative electrode side housing, and electrically connected to the positive electrode current collector and the negative electrode current collector, respectively. It is preferable that the housing on the positive electrode side and the housing on the negative electrode side are joined and integrated via a gasket for preventing a short circuit.
  • FIG. 1 is a cross-sectional view schematically showing an all-solid-state secondary battery (lithium ion secondary battery) according to a preferred embodiment of the present invention.
  • the all-solid secondary battery 10 of the present embodiment has a negative electrode current collector 1, a negative electrode active material layer 2, a solid electrolyte layer 3, a positive electrode active material layer 4, and a positive electrode current collector 5 in this order when viewed from the negative electrode side. ..
  • Each layer is in contact with each other and has an adjacent structure.
  • the lithium ions (Li + ) accumulated in the negative electrode are returned to the positive electrode side, and electrons are supplied to the operating portion 6.
  • a light bulb is used as a model for the operating portion 6, and the light bulb is turned on by electric discharge.
  • the all-solid-state secondary battery 10 exhibits the above-mentioned excellent characteristics.
  • the all-solid secondary battery having the layer structure shown in FIG. 1 When the all-solid secondary battery having the layer structure shown in FIG. 1 is placed in a 2032 type coin case, the all-solid secondary battery is referred to as an all-solid secondary battery laminate, and the all-solid secondary battery laminate is referred to as an all-solid secondary battery laminate.
  • a battery manufactured in a 2032 type coin case (for example, the coin type all-solid secondary battery 13 shown in FIG. 2) may be referred to as an all-solid secondary battery.
  • the positive electrode active material layer and the negative electrode active material layer are formed of the electrode composition of the present invention.
  • the positive electrode in which the positive electrode active material layer and the positive electrode current collector are laminated, and the negative electrode in which the negative electrode active material layer and the negative electrode current collector are laminated are formed by the electrode sheet of the present invention.
  • the sulfide-based inorganic solid electrolyte and the polymer binder contained in the positive electrode active material layer 4 and the negative electrode active material layer 2 may be of the same type or different from each other, and the ratio of the positive electrode active material to the negative electrode active material.
  • the surfaces may be the same or different.
  • the negative electrode active material layer can be a lithium metal layer.
  • the lithium metal layer include a layer formed by depositing or molding a lithium metal powder, a lithium foil, a lithium vapor deposition film, and the like.
  • the thickness of the lithium metal layer can be, for example, 1 to 500 ⁇ m regardless of the thickness of the negative electrode active material layer.
  • the positive electrode current collector 5 and the negative electrode current collector 1 are preferably electron conductors.
  • either or both of the positive electrode current collector and the negative electrode current collector may be collectively referred to as a current collector.
  • a current collector As a material for forming the positive electrode current collector, in addition to aluminum, aluminum alloy, stainless steel, nickel and titanium, the surface of aluminum or stainless steel is treated with carbon, nickel, titanium or silver (a thin film is formed). Of these, aluminum and aluminum alloys are more preferable.
  • As a material for forming the negative electrode current collector in addition to aluminum, copper, copper alloy, stainless steel, nickel and titanium, carbon, nickel, titanium or silver is treated on the surface of aluminum, copper, copper alloy or stainless steel.
  • aluminum, copper, copper alloy and stainless steel are more preferable.
  • the shape of the current collector is usually a film sheet, but a net, a punched body, a lath body, a porous body, a foam body, a molded body of a fiber group, or the like can also be used.
  • the thickness of the current collector is not particularly limited, but is preferably 1 to 500 ⁇ m. Further, it is also preferable that the surface of the current collector is made uneven by surface treatment.
  • a layer formed of a known material can be applied to the solid electrolyte layer and further to the active material layer.
  • a functional layer, a member, or the like is appropriately interposed or arranged between or outside each of the negative electrode current collector, the negative electrode active material layer, the solid electrolyte layer, the positive electrode active material layer, and the positive electrode current collector. You may. Further, each layer may be composed of a single layer or a plurality of layers.
  • the all-solid-state secondary battery can be manufactured by a conventional method. Specifically, the all-solid secondary battery is known by forming at least one active material layer using the electrode composition of the present invention or the like, or forming at least one electrode using the electrode sheet of the present invention. It can be produced by forming a solid electrolyte layer, and appropriately the other active material layer or an electrode using the above materials.
  • the all-solid-state secondary battery of the present invention includes (intervenes) a step of applying (via) the electrode composition of the present invention on the surface of a current collector to form a coating film (film formation) (the present invention).
  • an electrode composition containing a positive electrode active material is formed on a metal foil which is a positive electrode current collector as a positive electrode material (positive electrode composition) to form a positive electrode active material layer, which is used for an all-solid secondary battery.
  • a positive electrode sheet is prepared.
  • a solid electrolyte composition for forming the solid electrolyte layer is formed on the positive electrode active material layer to form the solid electrolyte layer.
  • an electrode composition containing a negative electrode active material as a negative electrode material is formed on the solid electrolyte layer to form a negative electrode active material layer.
  • a negative electrode current collector metal foil
  • an all-solid secondary battery having a structure in which a solid electrolyte layer is sandwiched between the positive electrode active material layer and the negative electrode active material layer can be obtained. Can be done. This can be enclosed in a housing to obtain a desired all-solid-state secondary battery.
  • a negative electrode active material layer, a solid electrolyte layer and a positive electrode active material layer are formed on the negative electrode current collector, and the positive electrode current collectors are superposed to manufacture an all-solid secondary battery. You can also do it.
  • a positive electrode sheet for an all-solid-state secondary battery is produced. Further, an electrode composition containing a negative electrode active material as a negative electrode material (negative electrode composition) is formed on a metal foil which is a negative electrode current collector to form a negative electrode active material layer, which is used for an all-solid secondary battery. A negative electrode sheet is prepared. Next, a solid electrolyte layer is formed on the active material layer of any one of these sheets as described above. Further, the other of the positive electrode sheet for the all-solid secondary battery and the negative electrode sheet for the all-solid secondary battery is laminated on the solid electrolyte layer so that the solid electrolyte layer and the active material layer are in contact with each other.
  • an all-solid-state secondary battery can be manufactured.
  • the following method can be mentioned. That is, as described above, a positive electrode sheet for an all-solid-state secondary battery and a negative electrode sheet for an all-solid-state secondary battery are produced. Separately from this, the electrode composition is formed into a film on the base material to prepare a solid electrolyte sheet for an all-solid secondary battery composed of a solid electrolyte layer. Further, the positive electrode sheet for the all-solid-state secondary battery and the negative electrode sheet for the all-solid-state secondary battery are laminated so as to sandwich the solid electrolyte layer peeled from the base material. In this way, an all-solid-state secondary battery can be manufactured.
  • a positive electrode sheet for an all-solid-state secondary battery or a negative-negative sheet for an all-solid-state secondary battery, and a solid electrolyte sheet for an all-solid-state secondary battery are produced.
  • the positive electrode sheet for the all-solid secondary battery or the negative electrode sheet for the all-solid secondary battery and the solid electrolyte sheet for the all-solid secondary battery were brought into contact with the positive electrode active material layer or the negative electrode active material layer and the solid electrolyte layer. Overlay and pressurize in the state. In this way, the solid electrolyte layer is transferred to the positive electrode sheet for the all-solid-state secondary battery or the negative electrode sheet for the all-solid-state secondary battery.
  • the pressurizing method and pressurizing conditions in this method are not particularly limited, and the methods and pressurizing conditions described later in the pressurization of the applied composition can be applied.
  • the solid electrolyte layer or the like can also be formed by pressure-molding a sulfide-based inorganic solid electrolyte or a solid electrolyte composition or the like on a substrate or an active material layer under the pressure conditions described later.
  • the electrode composition of the present invention is used as the electrode composition (at least one of the negative electrode composition and the positive electrode composition) that forms a film on the surface of the current collector.
  • examples of these materials include compositions usually used.
  • a lithium metal layer can also be used as a negative electrode (a laminate of a negative electrode active material layer and a negative electrode current collector). Furthermore, it belongs to Group 1 or Group 2 of the periodic table, which is accumulated in the negative electrode current collector by initialization or charging during use, which will be described later, without forming a negative electrode active material layer during the manufacture of an all-solid secondary battery.
  • a negative electrode active material layer can also be formed by combining metal ions with electrons and precipitating them as a metal on a negative electrode current collector or the like.
  • the coating method of the electrode composition or the like of the present invention is not particularly limited and can be appropriately selected.
  • coating preferably wet coating
  • spray coating spin coating coating
  • dip coating coating dip coating coating
  • slit coating stripe coating
  • bar coating coating can be mentioned.
  • the applied composition is preferably dried (heat treated).
  • the drying treatment may be performed after each of the electrode compositions has been applied, or may be performed after the multiple layers have been applied.
  • the drying temperature is not particularly limited, and for example, 30 ° C. or higher is preferable, 60 ° C. or higher is more preferable, and 80 ° C. or higher is further preferable.
  • the upper limit is not particularly limited, but for example, 300 ° C. or lower is preferable, 250 ° C. or lower is more preferable, and 200 ° C. or lower is further preferable, in that damage to each member of the all-solid-state secondary battery can be prevented.
  • the pressurizing method include a hydraulic cylinder press machine and the like.
  • the pressing force is not particularly limited, and is generally preferably in the range of 5 to 1500 MPa.
  • the applied electrode composition may be heated at the same time as pressurization.
  • the heating temperature is not particularly limited, and is generally in the range of 30 to 300 ° C. It can also be pressed at a temperature higher than the glass transition temperature of the sulfide-based inorganic solid electrolyte. It is also possible to press at a temperature higher than the glass transition temperature of the binder-forming polymer.
  • the temperature does not exceed the melting point of this polymer.
  • the pressurization may be performed in a state where the dispersion medium is dried in advance, or may be performed in a state where the dispersion medium remains.
  • each composition may be applied at the same time, and the application drying press may be performed simultaneously and / or sequentially. After coating on separate substrates, they may be laminated by transfer.
  • the manufacturing process for example, the atmosphere during coating, heating or pressurization, is not particularly limited, and is in air, in dry air (dew point -20 ° C or less), in an inert gas (for example, in argon gas, in helium gas, nitrogen). (In gas) or the like.
  • the pressing time may be short (for example, within several hours) and high pressure may be applied, or medium pressure may be applied for a long time (1 day or more).
  • an all-solid-state secondary battery restraint screw tightening pressure, etc.
  • the press pressure may be uniform or different with respect to the pressed portion such as the sheet surface.
  • the press pressure can be changed according to the area or film thickness of the pressed portion. It is also possible to change the same part step by step with different pressures.
  • the pressed surface may be smooth or roughened.
  • the all-solid-state secondary battery manufactured as described above is preferably initialized after manufacturing or before use.
  • the initialization is not particularly limited, and can be performed, for example, by performing initial charging / discharging with the press pressure increased, and then releasing the pressure until the pressure reaches the general working pressure of the all-solid-state secondary battery.
  • the method for producing an all-solid secondary battery of the present invention can be carried out by an industrial production method, for example, a highly productive roll-to-roll method, by using the electrode composition of the present invention, or by winding during or after the production process. It can also be applied to a manufacturing method in which the battery is wound around a core, and an all-solid secondary battery that realizes the above-mentioned excellent battery performance can be manufactured with high productivity.
  • the all-solid-state secondary battery of the present invention can be applied to various applications.
  • the application mode is not particularly limited, but for example, when mounted on an electronic device, a laptop computer, a pen input personal computer, a mobile personal computer, an electronic book player, a mobile phone, a cordless phone handset, a pager, a handy terminal, a mobile fax, or a mobile phone.
  • Other consumer products include automobiles, electric vehicles, motors, lighting equipment, toys, game equipment, road conditioners, watches, strobes, cameras, medical equipment (pacemakers, hearing aids, shoulder massagers, etc.). Furthermore, it can be used for various munitions and space. It can also be combined with a solar cell.
  • Synthesis Example 12 Synthesis of Polymer T-2 (Preparation of Binder Solution T-2)]
  • Synthesis Example 1 the same as in Synthesis Example 1 except that a compound for deriving each component so that the polymer T-2 has the following chemical formula and the composition (type and content of components) shown in Table 1 is used.
  • the polymer T-2 (acrylic polymer) was synthesized to obtain a binder solution T-2 (concentration 40% by mass) composed of the polymer T-2.
  • the polymers S-1 to S-10, T-1 and T-2 are shown below.
  • the number at the bottom right of each component indicates the content (mol%) in the polymer.
  • Table 1 shows the composition, SP value, mass average molecular weight, SP value of each component, average particle size of the binder, and the form (solution or dispersion) of the binder in the composition described later. ..
  • the SP value of the polymer and each component, the mass average molecular weight of the polymer, and the average particle size of the binder were measured or calculated by the above method. When two kinds of components corresponding to specific constituent components are contained, they are described in two stages. The morphology of the binder was visually determined, but the binder described as "dissolved” in the table satisfied the solubility measured by the solubility measurement.
  • LMA Dodecyl methacrylate (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • LA Dodecyl acrylate (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • 6FDA 4,4'-(hexafluoroisopropyridene) diphthalic anhydride (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • DAE 4,4'-diaminodiphenyl ether (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • EtHexA 2-ethylhexyl acrylate (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • -Component M2- The component M2 represents a component derived from a (meth) acrylic monomer or a vinyl monomer having an SP value of 19.0 MPa 1/2 or more.
  • DGMEM 2- (2-methoxyethoxy) ethyl methacrylate (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • AN Acrylonitrile (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.)
  • VP Vinyl pyridine (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • OXE-30 (3-ethyloxetane-3-yl) methyl methacrylate (manufactured by Osaka Organic Chemical Industry Co., Ltd.)
  • THFA Tetrahydrofurfuryl acrylate (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.)
  • HEM 2-Hydroxyethyl methacrylate (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.)
  • HEA 2-Hydroxyethyl acrylate (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.)
  • St Styrene (man
  • NMC LiNi 1/3 Co 1/3 Mn 1/3 O 2
  • NMC1 NMC with a specific surface area of 13 m 2 / g and an average particle size of 0.3 ⁇ m (manufactured by Toyoshima Seisakusho Co., Ltd.)
  • NMC2 NMC (manufactured by Aldrich) with a specific surface area of 4 m 2 / g and an average particle size of 1.0 ⁇ m.
  • Si was prepared as the negative electrode active material.
  • Si1 Si with a specific surface area of 23 m 2 / g and an average particle size of 0.1 ⁇ m (manufactured by Aldrich)
  • Si2 Si with a specific surface area of 2 m 2 / g and an average particle size of 2.8 ⁇ m (manufactured by Alfa Aesar)
  • Li 2 S lithium sulfide
  • P 2 S diphosphorus pentasulfide
  • Example 1 Each electrode composition shown in Table 2 was prepared as follows. ⁇ Preparation of positive electrode composition> 60 g of zirconia beads having a diameter of 5 mm was put into a 45 mL container made of zirconia (manufactured by Fritsch), 9.9 g of LPS synthesized in Synthesis Example A, and 14 g of butyl butyrate (total amount) as a dispersion medium. This container was set on a planetary ball mill P-7 (trade name) manufactured by Fritsch, and stirred at 25 ° C. at a rotation speed of 200 pm for 30 minutes.
  • planetary ball mill P-7 trade name
  • ⁇ Preparation of negative electrode composition 60 g of zirconia beads having a diameter of 5 mm were put into a 45 mL container made of zirconia (manufactured by Fritsch), 8.7 g of LPS synthesized in Synthesis Example A, and 0.1 g of a binder solution or dispersion liquid shown in Table 2 (solid content mass). , And 20.8 g (total amount) of the dispersion medium shown in Table 2 was added.
  • This container was set on a planetary ball mill P-7 (trade name) manufactured by Fritsch, and mixed at a temperature of 25 ° C. and a rotation speed of 300 pm for 60 minutes.
  • NK-1 to NK-10 and NKc21 to NKc23 were prepared by mixing at a temperature of 25 ° C. and a rotation speed of 100 rpm for 10 minutes, respectively.
  • composition content indicates the content (mass%) with respect to the total amount of the composition
  • solid content content indicates the content (mass%) with respect to 100% by mass of the solid content of the composition.
  • NMC1 and NMC2 NMC prepared above Si1 and Si2: Si prepared above AB: Acetylene black (specific surface area is 62 m 2 / g)
  • VGCF Carbon nanotubes (specific surface area 13 m 2 / g)
  • the solid content ratio [WA / WB] of the solid content WA after standing to the solid content WB before standing was determined.
  • the ease of sedimentation (precipitation) of solid particles was evaluated as the dispersion stability of the solid electrolyte composition depending on which of the following evaluation criteria the solid content ratio was included in. In this test, the closer the solid content ratio is to 1.0, the better the dispersion stability is, and the evaluation standard "D" or higher is the pass level.
  • the results are shown in Table 3.
  • the composition of the present invention had sufficient dispersibility immediately after preparation as an electrode forming material.
  • the test piece was set with its active material layer on the opposite side of the mandrel (current collector on the mandrel side) and in the width direction parallel to the axis of the mandrel.
  • the test was carried out by changing the diameter of the mandrel in the order of 32 mm, 25 mm, 19 mm, 16 mm, 12 mm, 10 mm, 6 mm, 5 mm, 3 mm and 2 mm, and the active material layer was peeled from the current collector (aluminum foil or copper foil). The minimum diameter that was not measured was measured, and it was evaluated whether this minimum diameter corresponds to any of the following evaluation criteria.
  • the solid electrolyte sheet 201 for the all-solid secondary battery prepared below was formed by the solid electrolyte layer. It is layered so as to be in contact with the negative electrode active material layer, pressurized (50 MPa) at 25 ° C. using a press machine, transferred (laminated), and then further pressurized (600 MPa) at 25 ° C. to form a solid having a thickness of 30 ⁇ m. Negative electrode sheets for all-solid secondary batteries provided with an electrolyte layer (thickness of the negative electrode active material layer 42 ⁇ m) 107 to 112, 117 to 120 and c21 to c23 were prepared, respectively.
  • the solid electrolyte sheet 201 for the all-solid-state secondary battery used for manufacturing the all-solid-state secondary battery was produced as follows. (Preparation of Inorganic Solid Electrolyte-Containing Composition 201) 60 g of zirconia beads having a diameter of 5 mm were put into a 45 mL container made of zirconia (manufactured by Fritsch), and 7.43 g of LPS synthesized in Synthesis Example A above, KYNAR FLEX 2500-20 (trade name, PVdF-HFP: polyvinylidene fluoride hexafluorofluorofluoride).
  • a propylene copolymer (manufactured by Arkema) was added in an amount of 0.17 g as a solid content mass, and butyl butyrate was added as a dispersion medium in an amount of 16 g. After that, this container was set in a planetary ball mill P-7 (trade name) manufactured by Fritsch.
  • the inorganic solid electrolyte-containing composition (slurry) 201 was prepared by mixing at a temperature of 25 ° C. and a rotation speed of 150 rpm for 10 minutes.
  • the inorganic solid electrolyte-containing composition 201 prepared above is applied onto an aluminum foil having a thickness of 20 ⁇ m using a baker-type applicator (trade name: SA-201, manufactured by Tester Sangyo Co., Ltd.) and heated at 80 ° C. for 2 hours. , Inorganic solid electrolyte-containing composition was dried (dispersion medium was removed). Then, using a heat press machine, the inorganic solid electrolyte-containing composition dried at a temperature of 120 ° C. and a pressure of 40 MPa for 10 seconds was heated and pressurized to prepare a solid electrolyte sheet 201 for an all-solid secondary battery. .. The film thickness of the solid electrolyte layer was 48 ⁇ m.
  • the above all-solid-state secondary battery No. In the production of 101, the positive electrode sheet No. 1 for an all-solid secondary battery provided with a solid electrolyte layer. Instead of 101, the sheet No. shown in the “electrode active material layer” column of Table 4 is shown. All-solid-state secondary battery No. 1 except that the positive electrode sheet for the all-solid-state secondary battery provided with the solid electrolyte layer represented by In the same manner as in the production of 101, the positive electrode sheet No. 1 for an all-solid-state secondary battery. 102-106, 113-116 and c11 evaluation all-solid-state secondary battery (half cell) No. 102 to 106, 113 to 116 and c101 were produced, respectively.
  • a positive electrode sheet (positive electrode active material layer) punched out from the positive electrode sheet CS for an all-solid secondary battery prepared below with a diameter of 14.0 mm was superposed on the solid electrolyte layer.
  • a stainless steel foil (positive electrode current collector) is further layered on top of the laminate 12 (stainless steel foil-aluminum foil-positive electrode active material layer-solid electrolyte layer-negative electrode active material layer-copper foil) for an all-solid secondary battery. Laminated body) was formed. After that, by crimping the 2032 type coin case 11, the negative electrode sheet No. 1 for the all-solid-state secondary battery shown in FIG. 107 All-solid-state secondary battery for evaluation (full cell) No. 107 was manufactured.
  • the all-solid-state secondary battery No. A positive electrode sheet CS for a solid secondary battery used in the production of 107 was prepared.
  • positive electrode composition 180 zirconia beads having a diameter of 5 mm were put into a 45 mL container made of zirconia (manufactured by Fritsch), 2.7 g of LPS synthesized in the above synthesis example A, KYNAR FLEX 2500-20 (trade name, PVdF-HFP: polyfluoridene fluoride).
  • Vinylidene hexafluoropropylene copolymer (manufactured by Arkema Co., Ltd.) was added in an amount of 0.3 g as a solid content mass, and butyl butyrate was added in an amount of 22 g.
  • This container was set on a planetary ball mill P-7 (trade name) manufactured by Fritsch, and stirred at 25 ° C. and a rotation speed of 300 rpm for 60 minutes. Then, 7.0 g of LiNi 1/3 Co 1/3 Mn 1/3 O 2 (NMC, specific surface area 13 m 2 / g, average particle size 0.3 ⁇ m) was added as a positive electrode active material, and similarly, a planetary ball mill was added.
  • NMC LiNi 1/3 Co 1/3 Mn 1/3 O 2
  • a container was set on P-7, and mixing was continued at 25 ° C. and a rotation speed of 100 rpm for 5 minutes to prepare a positive electrode composition CS.
  • the positive electrode composition CS obtained above is applied onto an aluminum foil (positive electrode current collector) having a thickness of 20 ⁇ m with a baker-type applicator (trade name: SA-201, manufactured by Tester Sangyo Co., Ltd.) and heated at 100 ° C. for 2 hours. Then, the positive electrode composition CS was dried (dispersion medium was removed). Then, using a heat press machine, the dried positive electrode composition is pressurized at 25 ° C. (10 MPa, 1 minute) to prepare a positive electrode sheet CS for an all-solid secondary battery having a positive electrode active material layer having a thickness of 75 ⁇ m. bottom.
  • the above all-solid-state secondary battery No. In the production of 107, the negative electrode sheet No. 1 for an all-solid secondary battery provided with a solid electrolyte layer. Instead of 107, the sheet No. shown in the “Electrode active material layer” column of Table 4 is shown. All-solid-state secondary battery No. 1 except that the negative electrode sheet for the all-solid-state secondary battery provided with the solid electrolyte layer represented by Negative electrode sheet No. for all-solid-state secondary battery in the same manner as in the production of 107. 108-112, 117-120 and c21-23 evaluation all-solid-state secondary battery (full-cell) No. 108 to 112, 117 to 120 and c201 to c203 were produced, respectively.
  • the battery was charged at high speed with a current density of 1.0 mA / cm 2 until the battery voltage reached 3.6 V. Then, the battery was discharged at high speed until the battery voltage reached 2.5 V at a current density of 1.0 mA / cm 2.
  • One high-speed charge and one high-speed discharge were defined as one high-speed charge / discharge cycle, and high-speed charge / discharge was repeated under the same conditions.
  • the discharge capacity of each evaluation all-solid-state secondary battery was measured with a charge / discharge evaluation device: TOSCAT-3000 (trade name) after each high-speed charge / discharge cycle.
  • the all-solid-state secondary batteries c101 and c201 are included in the evaluation standard "E", and the number of high-speed charge / discharge cycles is 210 cycles and 106 cycles, respectively.
  • the discharge capacities in the first cycle of high-speed charge / discharge showed sufficient values to function as the all-solid-state secondary battery.
  • the evaluation all-solid-state secondary battery of the present invention maintained excellent cycle characteristics even when a normal charge / discharge cycle was repeated under the same conditions as the above initialization instead of the above-mentioned high-speed charge / discharge.
  • -Evaluation criteria half cell- A: 600 cycles or more B: 500 cycles or more, less than 600 cycles C: 400 cycles or more, less than 500 cycles D: 300 cycles or more, less than 400 cycles E: 200 cycles or more, less than 300 cycles F: less than 200 cycles -Evaluation criteria (full cell)- A: 500 cycles or more B: 400 cycles or more and less than 500 cycles C: 300 cycles or more and less than 400 cycles D: 200 cycles or more and less than 300 cycles E: 100 cycles or more and less than 200 cycles F: less than 100 cycles
  • the electrode composition which does not contain the sulfide-based inorganic solid electrolyte shown in Comparative Examples PKc11 and NKc21 to NKc23 in combination with the active material and the polymer binder specified in the present invention is inferior in dispersion stability.
  • the sheets c11 and c21 to c23 produced using these compositions are inferior in adhesion to the current collector, and the discharge capacities of the all-solid-state secondary batteries c101 and c201 to c203 are significantly reduced by high-speed charging and discharging.
  • the sulfide-based inorganic solid electrolytes shown in PK-1 to PK-10 and NK-1 to NK-10 of the present invention are contained in combination with the active material and the polymer binder specified in the present invention.
  • All of the electrode compositions can suppress reaggregation or sedimentation with time even if they contain an active material having a large specific surface area, and maintain sufficient dispersibility even after 4 days have passed.
  • the adhesion of the electrode sheet for the all-solid secondary battery to the current collector can be enhanced, and the discharge capacity can be reduced even in high-speed charging and discharging. It is possible to realize an all-solid secondary battery that exhibits excellent cycle characteristics. It is considered that this effect is exerted by adsorbing the polymer binder to the active material and further to the sulfide-based inorganic solid electrolyte in the electrode composition containing the active material having a large specific surface area.

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WO2023132304A1 (ja) * 2022-01-04 2023-07-13 パナソニックホールディングス株式会社 正極材料および電池
EP4603519A4 (en) * 2022-10-12 2026-01-21 Hansol Chemical Co Ltd COPOLYMER FOR SEPARATOR AND SECONDARY BATTERY INCLUDED

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