Classifications

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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
  • C21D1/60—Aqueous agents
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  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
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  • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
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  • C21D6/00—Heat treatment of ferrous alloys
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  • C21D6/00—Heat treatment of ferrous alloys
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  • C21D6/00—Heat treatment of ferrous alloys
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  • C21D6/00—Heat treatment of ferrous alloys
  • C21D6/008—Heat treatment of ferrous alloys containing Si
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
  • C21D8/0226—Hot rolling
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  • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
  • C21D8/0236—Cold rolling
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  • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
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  • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
  • C21D8/0273—Final recrystallisation annealing
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  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
  • C21D9/54—Furnaces for treating strips or wire
  • C21D9/56—Continuous furnaces for strip or wire
  • C21D9/573—Continuous furnaces for strip or wire with cooling
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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  • C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
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  • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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  • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
• • C—CHEMISTRY; METALLURGY
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
• • C—CHEMISTRY; METALLURGY
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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  • C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
• • C—CHEMISTRY; METALLURGY
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  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
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  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
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  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/62—Quenching devices
  • C21D1/63—Quenching devices for bath quenching
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/005—Ferrite
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  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/008—Martensite
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  • C21D6/00—Heat treatment of ferrous alloys
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P10/00—Technologies related to metal processing
  • Y02P10/20—Recycling

Definitions

• the present invention relates to steel plates and members used for automobile parts and the like, and methods for manufacturing them. More specifically, the present invention relates to steel sheets, members, and methods for producing them, which have high strength and are excellent in shape uniformity and delayed fracture resistance.
• shape uniformity and delayed fracture resistance are improved by controlling the area ratio of ferrite and martensite. Specifically, by forming a composite structure steel in which the metal structure contains a tempered martensite phase having a volume fraction of 50 to 80% and a ferrite phase having a volume fraction of 20 to 50%, hydrogen intrusion is suppressed and shape uniformity is suppressed. Also, an ultra-high strength steel plate having good delayed fracture resistance is provided.
• Patent Document 2 provides a technique for suppressing deterioration of the shape of a steel sheet due to martensitic transformation that occurs during water quenching by restraining the steel sheet with a roll in water.
• the steel plate used for the automobile body is pressed and used, good shape uniformity is a necessary characteristic. Furthermore, the amount of high-strength steel sheets used for materials for automobile parts is increasing recently, and it is necessary to have good delayed fracture resistance, which is a concern with the increase in strength. Since automobile parts are collected at the total width of the steel sheet (hereinafter, also referred to as the total width of the steel sheet), the delayed fracture resistance must be excellent without variation even at the total width of the steel sheet. Therefore, it is necessary to have high strength, excellent shape uniformity, and excellent delayed fracture resistance in the entire width of the steel sheet.
• Patent Document 1 provides a technique having excellent shape uniformity and delayed fracture resistance by microstructure control, the shape is deteriorated due to transformation expansion occurring during martensitic transformation, and therefore the shape is uniform from the present invention. The effect of improving sexuality seems to be inferior.
• Patent Document 2 provides a technique for improving shape uniformity, it is not a technique having excellent delayed fracture resistance.
• An object of the present invention is to provide a steel sheet, a member, and a method for manufacturing the same, which have high strength and excellent shape uniformity and delayed fracture resistance.
• the present inventors have conducted extensive research on the requirements for a steel sheet having a tensile strength of 750 MPa or more and excellent shape uniformity and delayed fracture resistance. As a result, it was found that it is necessary to set the residual stress at the center of the plate width to 800 MPa or less in order to obtain excellent delayed fracture resistance. In addition, the present inventors have found that the strength is increased by increasing the martensite fraction to 20% or more in terms of area ratio by rapid cooling. On the other hand, since the martensitic transformation during water cooling occurs rapidly and non-uniformly, the transformation strain deteriorates the shape uniformity of the steel sheet.
• the present inventors have obtained a steel sheet having excellent delayed fracture resistance by reducing the residual stress at the center of the plate width.
• a steel sheet having excellent shape uniformity and delayed fracture resistance over the entire width of the steel sheet can be obtained, and the present invention has been completed.
• the gist of the present invention is as follows. [1] It has a steel structure having martensite: 20% or more and 100% or less, ferrite: 0% or more and 80% or less, and the balance: 5% or less in terms of area ratio.
• the residual stress at the center of the plate width when V-shaped bending is 800 MPa or less.
• the residual stress at the edge of the plate width is 90% or more and 110% or less of the residual stress at the center of the plate width.
• the component composition is further increased by mass%.
• the component composition is further increased by mass%.
• the component composition is further increased by mass%.
• the component composition is further increased by mass%.
• the hot-rolled steel sheet obtained in the hot rolling step is held at an annealing temperature of 1 AC or higher for 30 seconds or longer, then water quenching is started at Ms or higher, water-cooled to 100 ° C or lower, and then 100 ° C or higher. It has an annealing step of heating again at 300 ° C. or lower.
• the steel sheet is restrained from the front surface and the back surface of the steel sheet by two rolls installed sandwiching the steel sheet.
• a method for manufacturing a steel sheet in which the restraint pressure ratio at the center of the plate width to the end of the plate width at the restraint positions of the two rolls is 1.05 or more and 2.0 or less.
• the cold-rolled steel sheet obtained in the cold rolling step is held at an annealing temperature of 1 AC or higher for 30 seconds or longer, then water quenching is started at Ms or higher, water-cooled to 100 ° C or lower, and then 100 ° C or higher. It has an annealing step of heating again at 300 ° C. or lower.
• the steel sheet is restrained from the front surface and the back surface of the steel sheet by two rolls installed sandwiching the steel sheet.
• a method for manufacturing a steel sheet in which the restraint pressure ratio at the center of the plate width to the end of the plate width at the restraint positions of the two rolls is 1.05 or more and 2.0 or less.
• the present invention it is possible to provide steel sheets, members, and methods for manufacturing them, which have high strength and excellent shape uniformity and delayed fracture resistance.
• the steel sheet of the present invention By applying the steel sheet of the present invention to a structural member for automobiles, it is possible to achieve both high strength of the steel sheet for automobiles and improvement of delayed fracture resistance. That is, according to the present invention, the performance of the automobile body is improved.
• the steel sheet of the present invention has a steel structure having martensite: 20% or more and 100% or less, ferrite: 0% or more and 80% or less, and the balance: 5% or less in terms of area ratio, and when V-shaped bending is performed.
• the residual stress at the center of the plate width (hereinafter, also simply referred to as "residual stress at the center of the plate width") is 800 MPa or less, and when V-shaped bending is performed, the residual stress at the end of the plate width becomes the residual stress at the center of the plate width.
• it is 90% or more and 110% or less, and the maximum warp amount of the steel sheet when sheared with a length of 1 m in the longitudinal direction of the steel sheet is 15 mm or less.
• the effect of the present invention can be obtained, so that the composition of the steel sheet is not particularly limited.
• the thickness of the steel plate is preferably 0.2 mm or more and 3.2 mm or less.
• the steel structure of the steel sheet of the present invention has martensite: 20% or more and 100% or less, ferrite: 0% or more and 80% or less, and the balance: 5% or less in terms of area ratio.
• Area ratio of martensite 20% or more and 100% or less In order to obtain high strength of TS ⁇ 750 MPa, the area ratio of martensite is 20% or more. If the area ratio of martensite is less than 20%, either ferrite, retained austenite, pearlite, or bainite increases, and the strength decreases. The total area ratio of martensite may be 100%. From the viewpoint of improving the strength, the area ratio of martensite is preferably 30% or more. Martensite is the sum of as-quenched fresh martensite and tempered tempered martensite.
• martensite refers to a hard structure generated from austenite below the martensitic transformation point (also simply referred to as Ms point), and tempered martensite refers to a structure that is tempered when martensite is reheated. ..
• Area ratio of ferrite 0% or more and 80% or less From the viewpoint of ensuring the strength of the steel sheet, the area ratio of ferrite is 80% or less. The area ratio may be 0%.
• ferrite is a structure formed by transformation from austenite at a relatively high temperature and composed of BCC lattice crystal grains.
• the steel structure of the steel sheet of the present invention may contain a metallic phase inevitably contained as a remaining portion other than martensite and ferrite.
• the area ratio of the remaining portion is acceptable if it is 5% or less.
• Phases contained in the balance include, for example, retained austenite, pearlite, and bainite.
• retained austenite refers to austenite that remains at room temperature without being transformed into martensite.
• the pearlite referred to in the present invention is a structure composed of ferrite and needle-like cementite.
• the bainite referred to in the present invention refers to a hard structure formed from austenite at a relatively low temperature (above the martensitic transformation point) and in which fine carbides are dispersed in needle-shaped or plate-shaped ferrite.
• Residual stress at the center of the plate width during V-shaped bending is 800 MPa or less
• the V-shaped bending in the present invention is bending at a bending angle of 90 ° so that the bending ridge direction is parallel to the width direction of the steel sheet. Means to do.
• the steel sheet of the present invention has excellent delayed fracture resistance.
• the critical load stress obtained when the delayed fracture test described in the examples is performed is equal to or higher than the yield strength (hereinafter, also simply referred to as YS).
• the critical load stress is preferably (YS + 100) MPa or more, more preferably (YS + 200) MPa or more.
• the residual stress is preferably 780 MPa or less, more preferably 700 MPa or less, and further preferably 600 MPa or less.
• the residual stress at the edge of the plate width is 90% or more and 110% or less of the residual stress at the center of the plate width.
• the steel plate of the present invention has excellent delayed fracture resistance even at the entire width of the steel plate. Specifically, when the steel plate is V-bent and the critical load stress is obtained at the center of the plate width and the end of the plate width, the critical load stress at the end of the plate width is 90% of the critical load stress at the center of the plate width. It is 110% or more, preferably 92% or more and 108% or less, and more preferably 95% or more and 105% or less.
• the residual stress at the edge of the plate width In order for the critical load stress at the edge of the plate width to be 90% or more and 110% or less of the critical load stress at the center of the plate width, the residual stress at the edge of the plate width remains at the center of the plate width during V-shaped bending. It needs to be 90% or more and 110% or less with respect to the stress. From the viewpoint of improving the excellent delayed fracture resistance, the residual stress at the edge of the plate width is preferably 92% or more and 108% or less with respect to the residual stress at the center of the plate width during V-shaped bending, more preferably. It is 95% or more and 105% or less.
• the maximum amount of warpage of a steel sheet when sheared at a length of 1 m in the longitudinal direction of the steel sheet is 15 mm or less.
• the steel sheet of the present invention has good shape uniformity. Specifically, the maximum amount of warpage of a steel sheet when sheared with a length of 1 m in the longitudinal direction (rolling direction) of the steel sheet is 15 mm or less.
• the maximum amount of warpage is preferably 13 mm or less, more preferably 12 mm or less, still more preferably 10 mm or less.
• the lower limit of the maximum warp amount is not limited, and 0 mm is most preferable.
• the "maximum amount of warpage of a steel sheet when sheared at a length of 1 m in the longitudinal direction of the steel sheet" in the present invention means that after the steel sheet is sheared at the original width of the steel sheet at the original width of the steel sheet in the longitudinal direction of the steel sheet (rolling direction) at a length of 1 m.
• the distance here is a distance in a direction (vertical direction) perpendicular to the horizontal plane of the horizontal table.
• the amount of warpage is measured with the other side of the steel sheet on the upper side, and the maximum value of the measured amount of warpage is defined as the maximum amount of warpage.
• the sheared steel plate is placed on the horizontal table so that the corners of the steel sheet and the horizontal table have more contact points (two or more points). The amount of warpage is determined by lowering the horizontal plate from a position above the steel plate until it contacts the steel plate, and at the position where it contacts the steel plate, the thickness of the steel plate is determined from the distance between the horizontal table and the horizontal plate. Pull and ask.
• the steel sheet of the present invention has high strength.
• the high strength referred to in the present invention means that the tensile strength measured by the method described in Examples is 750 MPa or more.
• the tensile strength of the steel sheet is preferably 950 MPa or more, more preferably 1150 MPa or more, still more preferably 1300 MPa or more.
• the upper limit of the tensile strength of the steel sheet is not particularly limited, but is preferably 2500 MPa or less from the viewpoint of easy balancing with other characteristics.
• % which is a unit of the content of the component, means “mass%”.
• C 0.05% or more and 0.60% or less
• C is an element that improves hardenability and is necessary for securing a predetermined area ratio of martensite. Further, C is necessary from the viewpoint of increasing the strength of martensite and ensuring the strength.
• the amount of C is preferably 0.05% or more from the viewpoint of maintaining excellent delayed fracture resistance and obtaining a predetermined strength. From the viewpoint of obtaining TS ⁇ 950 MPa, the lower limit of the C content is more preferably 0.11% or more. Further, from the viewpoint of further increasing the tensile strength, the lower limit of the C content is more preferably 0.125% or more.
• the C content is preferably 0.60% or less.
• the C content is more preferably 0.50% or less, still more preferably 0.40% or less.
• Si 0.01% or more and 2.0% or less Si is a strengthening element by solid solution strengthening.
• the Si content is preferably 0.01% or more.
• the Si content is more preferably 0.02% or more, still more preferably 0.03% or more.
• the Si content is preferably 2.0% or less.
• the Si content is more preferably 1.7% or less, still more preferably 1.5% or less.
• Mn 0.1% or more and 3.2% or less Mn is contained in order to improve the hardenability of steel and secure the area ratio of a predetermined martensite. If the Mn content is less than 0.1%, the strength tends to decrease due to the formation of ferrite on the surface layer of the steel sheet. Therefore, the Mn content is preferably 0.1% or more. The Mn content is more preferably 0.2% or more, still more preferably 0.3% or more. On the other hand, Mn is an element that particularly promotes the formation and coarsening of MnS, and when the Mn content exceeds 3.2%, the residual stress at the center of the plate width increases due to the increase in coarse inclusions. Delayed fracture resistance tends to deteriorate. Therefore, the Mn content is preferably 3.2% or less. The Mn content is more preferably 3.0% or less, still more preferably 2.8% or less.
• P 0.050% or less
• P is an element that reinforces steel, but if its content is high, it segregates at the grain boundaries and the residual stress at the center of the plate width increases, which tends to deteriorate the delayed fracture resistance. There is. Therefore, the P content is preferably 0.050% or less.
• the P content is more preferably 0.030% or less, still more preferably 0.010% or less.
• the lower limit of the P content is not particularly limited, but at present, the lower limit that can be industrially implemented is about 0.003%.
• S 0.0050% or less
• inclusions such as MnS, TiS, Ti (C, S) are excessively formed, and the delayed fracture resistance tends to deteriorate.
• the S content is preferably 0.0050% or less from the viewpoint that the delayed fracture resistance suppresses deterioration.
• the S content is more preferably 0.0020% or less, still more preferably 0.0010% or less, and particularly preferably 0.0005% or less.
• the lower limit of the S content is not particularly limited, but at present, the lower limit that can be industrially implemented is about 0.0002%.
• Al 0.005% or more and 0.10% or less Al is added to sufficiently deoxidize and reduce coarse inclusions in steel.
• the Al content is preferably 0.005% or more.
• the Al content is more preferably 0.010% or more.
• the amount of Al is preferably 0.10% or less.
• the Al content is more preferably 0.08% or less, still more preferably 0.06% or less.
• N 0.010% or less
• N is an element that forms a nitride such as TiN, (Nb, Ti) (C, N), AlN, and a carbonitride-based coarse inclusion in steel. If N is excessively contained, the delayed fracture resistance deteriorates due to the formation of coarse inclusions.
• the N content is preferably 0.010% or less in order to prevent deterioration of the delayed fracture resistance.
• the N content is preferably 0.007% or less, more preferably 0.005% or less.
• the lower limit of the N content is not particularly limited, but at present, the lower limit that can be industrially implemented is about 0.0006%.
• the steel sheet of the present invention contains the above-mentioned components as a basic component, and the balance is composed of Fe (iron) and unavoidable impurities.
• the steel sheet of the present invention may contain the following components as optional components as long as the actions of the present invention are not impaired. If the following optional components are contained below the lower limit, the components shall be included in the unavoidable impurities.
• Cr At least one selected from 0.01% or more and 0.50% or less, Mo: 0.01% or more and less than 0.15%, V: 0.001% or more and 0.05% or less Cr, Mo , V can be contained for the purpose of obtaining the effect of improving the hardenability of steel.
• the Cr content and the Mo content are both 0.01% or more.
• the Cr content and the Mo content are more preferably 0.02% or more, still more preferably 0.03% or more, respectively.
• V content it is preferably 0.001% or more, more preferably 0.002% or more, still more preferably 0.003% or more.
• the Cr content is preferably 0.50% or less, and more preferably 0.1% or less.
• the Mo content is preferably less than 0.15%, more preferably 0.10% or less.
• the V content is preferably 0.05% or less, more preferably 0.04% or less, still more preferably 0.03% or less.
• Nb At least one selected from 0.001% or more and 0.020% or less and Ti: 0.001% or more and 0.020% or less Nb and Ti have increased strength through miniaturization of old ⁇ grains. Contribute to. In order to obtain such an effect, it is preferable to contain Nb and Ti in an amount of 0.001% or more, respectively.
• the contents of Nb and Ti are more preferably 0.002% or more, still more preferably 0.003% or more, respectively.
• Nb-based materials such as NbN, Nb (C, N), (Nb, Ti) (C, N) that remain undissolved during slab heating in the hot rolling process Coarse precipitates, TiN, Ti (C, N), Ti (C, S), TiS and other Ti-based coarse precipitates increase, and the residual stress at the center of the plate width increases, resulting in delayed fracture resistance. Deteriorates. Therefore, the Nb and Ti contents are preferably 0.020% or less, respectively. The Nb and Ti contents are more preferably 0.015% or less, still more preferably 0.010% or less, respectively.
• Cu At least one selected from 0.001% or more and 0.20% or less and Ni: 0.001% or more and 0.10% or less
• Cu and Ni improve the corrosion resistance in the usage environment of automobiles.
• the corrosion product coats the surface of the steel sheet and has the effect of suppressing hydrogen intrusion into the steel sheet.
• the Cu content and the Ni content are each more preferably 0.002% or more.
• the Cu content is preferably 0.20% or less.
• the Cu content is more preferably 0.15% or less, still more preferably 0.10% or less.
• the Ni content is preferably 0.10% or less.
• the Ni content is more preferably 0.08% or less, still more preferably 0.06% or less.
• B 0.0001% or more and less than 0.0020%
• B is an element that improves the hardenability of steel, and by containing B, martensite having a predetermined area ratio is generated even when the Mn content is small. The effect of making it is obtained.
• the B content is preferably 0.0001% or more.
• the B content is preferably 0.0002% or more, and more preferably 0.0003% or more.
• the B content is 0.0020% or more, the solid solution rate of cementite at the time of annealing is delayed, and carbides containing Fe as a main component such as unsolidified cementite remain. As a result, the residual stress at the center of the plate width increases, and the delayed fracture resistance deteriorates. Therefore, the B content is preferably less than 0.0020%.
• the B content is more preferably 0.0015% or less, still more preferably 0.0010% or less.
• Sb At least one selected from 0.002% or more and 0.1% or less and Sn: 0.002% or more and 0.1% or less Sb and Sn suppress oxidation and nitriding of the surface layer of the steel sheet. It suppresses the reduction of C and B due to oxidation and nitriding of the surface layer of the steel sheet. Further, by suppressing the reduction of C and B, the formation of ferrite on the surface layer of the steel sheet is suppressed, which contributes to high strength.
• the Sb content and the Sn content are preferably 0.002% or more in either case.
• the Sb content and Sn content are more preferably 0.003% or more, still more preferably 0.004% or more, respectively.
• the content exceeds 0.1% in both the Sb content and the Sn content, Sb and Sn segregate at the old ⁇ grain boundaries and the residual stress at the center of the plate width increases, resulting in delayed fracture resistance.
• the characteristics deteriorate. Therefore, it is preferably 0.1% or less in both the Sb content and the Sn content.
• the Sb content and Sn content are more preferably 0.08% or less, still more preferably 0.06% or less, respectively.
• the steel sheet of the present invention may contain Ta, W, Ca, Mg, Zr, and REM as other elements as long as the effects of the present invention are not impaired, and the contents of these elements are different. If it is 0.1% or less, it is acceptable.
• the method for producing a steel sheet of the present invention includes a hot rolling step, a cold rolling step performed as needed, and an annealing step.
• the method for producing a steel sheet of the present invention includes, for example, a hot rolling step of heating a steel slab having the above-mentioned preferable composition and then hot rolling, a cold rolling step performed as needed, and hot rolling.
• the hot-rolled steel sheet obtained in the process or the cold-rolled steel sheet obtained in the cold rolling process is held at a quenching temperature of AC 1 point or higher for 30 seconds or longer, and then water-hardening is started at Ms point or higher to 100 ° C. It has a annealing step of water-cooling to the following and then heating again at 100 ° C.
• the steel plate is restrained from the front and back surfaces of the steel plate by two rolls installed sandwiching the steel plate, and the restraint pressure ratio at the center of the plate width to the plate width end at the restraint position of the two rolls is 1.05 or more and 2.0 or less. ..
• the temperature at which the steel slab, steel plate, etc. shown below is heated or cooled means the surface temperature of the steel slab, steel plate, etc.
• Hot rolling step is a step of heating a steel slab having the above-mentioned composition and then hot rolling.
• the steel slab having the above-mentioned composition is subjected to hot rolling.
• the slab heating temperature is not particularly limited, but by setting it to 1200 ° C. or higher, it is possible to promote the solid solution of sulfide and reduce Mn segregation, reduce the amount of coarse inclusions and carbides described above, and tolerate delayed fracture. The characteristics are improved. Therefore, the slab heating temperature is preferably 1200 ° C. or higher. It is more preferably 1230 ° C. or higher, and even more preferably 1250 ° C. or higher.
• the upper limit of the slab heating temperature is not particularly limited, but is preferably 1400 ° C. or lower.
• the heating rate during slab heating is not particularly limited, but is preferably 5 to 15 ° C./min.
• the slab heating time during slab heating is not particularly limited, but is preferably 30 to 100 minutes.
• the finish rolling temperature is not particularly limited, but is preferably 840 ° C. or higher. If the finish rolling temperature is less than 840 ° C, it takes time for the temperature to drop, and inclusions and coarse carbides may be generated, which not only deteriorates the delayed fracture resistance but also deteriorates the internal quality of the steel sheet. is there. Therefore, the finish rolling temperature is preferably 840 ° C. or higher. The finish rolling temperature is more preferably 860 ° C. or higher. On the other hand, the upper limit of the finish rolling temperature is not particularly limited, but the finish rolling temperature is preferably 950 ° C. or lower because it becomes difficult to cool down to the subsequent winding temperature. The finish rolling temperature is more preferably 920 ° C. or lower.
• the winding temperature is preferably 630 ° C. or lower. More preferably, it is 600 ° C. or lower.
• the lower limit is not particularly limited, but is preferably 500 ° C. or higher in order to prevent deterioration of cold rollability.
• the hot-rolled steel sheet after winding may be pickled.
• the pickling conditions are not particularly limited.
• the cold rolling process is a process of cold rolling a hot-rolled steel sheet obtained in the hot rolling process.
• the reduction rate of cold rolling is not particularly limited, but if the reduction rate is less than 20%, the flatness of the surface may be poor and the structure may become uneven, so the reduction rate should be 20% or more. preferable.
• the cold rolling step is not an essential step, and the cold rolling step may be omitted as long as the steel structure and mechanical properties satisfy the scope of the present invention.
• the annealing step is to hold a cold-rolled steel sheet or a hot-rolled steel sheet at a quenching temperature of 1 AC or higher for 30 seconds or longer, then start water quenching at Ms or higher, water-cool to 100 ° C or lower, and then 100. This is a step of heating again at ° C. or higher and 300 ° C. or lower.
• the steel sheet is restrained from the front surface and the back surface by two rolls installed sandwiching the steel sheet, and the two rolls.
• the restraint pressure ratio at the center of the plate width to the end of the plate width at the restraint position of is 1.05 or more and 2.0 or less.
• the annealing temperature needs to be AC 1 point or more. It is preferably (AC 1 point + 10 ° C.) or higher.
• the upper limit of the annealing temperature is not particularly limited, but the annealing temperature is preferably 900 ° C. or lower from the viewpoint of optimizing the temperature at the time of water quenching and preventing deterioration of shape uniformity.
• the AC1 point referred to here is calculated by the following formula. Further, in the following formula, (% element symbol) means the content (mass%) of each element.
• AC 1 point (° C) 723 + 22 (% Si) -18 (% Mn) + 17 (% Cr) + 4.5 (% Mo) + 16 (% V)
• Retention time at annealing temperature is 30 seconds or more If the annealing retention time is less than 30 seconds, the dissolution of carbides and austenite transformation do not proceed sufficiently, so the carbides remaining during the subsequent heat treatment become coarse and the plate Delayed fracture resistance deteriorates due to the increase in residual stress at the center of the width. Therefore, the annealing holding time is 30 seconds or more, preferably 35 seconds or more.
• the upper limit of the annealing holding time is not particularly limited, but the annealing holding time is preferably 900 seconds or less from the viewpoint of suppressing coarsening of the austenite particle size and preventing an increase in the amount of invading hydrogen.
• Water quenching start temperature is above Ms point Quenching start temperature is an important factor for determining the martensite fraction, which is the controlling factor of strength.
• the quenching start temperature is less than the Ms point, martensite transformation occurs before quenching, so that self-tempering of martensite occurs and the shape uniformity deteriorates. Therefore, the water quenching start temperature is above the Ms point. It is preferably (Ms point + 50 ° C.) or higher.
• the upper limit of the water quenching start temperature is not particularly limited, and the annealing temperature may be used.
• the Ms point referred to here is calculated by the following formula.
• Ms point (°C) 550-350 ⁇ (% C) / (% V M) ⁇ 100 ⁇ -40 (% Mn) -17 (% Ni) -17 (% Cr) -21 (% Mo)
• Restraining the steel sheet from the front and back surfaces of the steel sheet with two rolls during water cooling in water quenching is an important factor for obtaining the shape correction effect, and the residual stress in the center of the sheet width and the residual stress fluctuation in the entire width of the steel sheet are affected. Control of constraint conditions is an important factor for reduction.
• the present invention is characterized in that the deformation strain during water cooling is corrected by restraint to improve the shape uniformity of the steel sheet, and the leveler correction and the correction by skin pass rolling, which increase the residual stress and deteriorate the delayed fracture resistance, are not required. There is. Residual stress can be reduced because leveler processing and skin pass rolling, which are performed when correcting the deterioration of shape uniformity, are not required. Further, since the residual stress fluctuation in the entire width of the steel sheet is reduced under the restraint condition, the delayed fracture resistance is improved in the entire width of the steel sheet.
• the restraint temperature When the surface temperature of the steel sheet (hereinafter referred to as the restraint temperature) when restraining the steel sheet from the front and back surfaces of the steel sheet with two rolls is (Ms point + 150 ° C) or less, the restraint temperature exceeds (Ms point + 150 ° C). Since the martensitic transformation occurs later, the deterioration of the shape uniformity due to the transformation expansion of the martensitic transformation cannot be suppressed, and the shape uniformity deteriorates. Therefore, the restraint temperature is (Ms point + 150 ° C.) or less, preferably (Ms point + 100 ° C.) or less, and more preferably (Ms point + 50 ° C.) or less.
• the lower limit of the restraint temperature is not particularly limited, and it is preferably 0 ° C. or higher at which water does not freeze.
• the restraint pressure ratio of the center of the plate width to the restraint position of the two rolls is 1.05 or more and 2.0 or less.
• the restraint pressure ratio of the center of the plate width to the restraint position of the two rolls is 1.
• the restraint pressure ratio is 1.05 or more.
• the restraint pressure ratio is preferably 1.10 or more.
• the restraint pressure ratio exceeds 2.0, the residual stress value at the center of the plate width becomes high, so that the delayed fracture resistance deteriorates. Therefore, the restraint pressure ratio is 2.0 or less.
• the confining pressure ratio is preferably 1.7 or less, more preferably 1.5 or less.
• the restraint pressure is not particularly limited, but from the viewpoint of more effectively obtaining the effect of the present invention, the restraint pressure (load load) per 1 mm 2 of the steel sheet is 50 to It is preferably 300 N / mm 2.
• the restraining pressure (load) referred to here is the total pressure applied to the steel sheet from the front surface and the back surface of the steel sheet. Further, it is preferable that the restraining pressure by the two rolls is uniformly applied from the front surface and the back surface of the steel sheet.
• the means for restraining the steel plate at the center of the plate width with a restraining pressure larger than that at the end of the plate width is not particularly limited.
• the roll diameter of the portion in contact with the center of the plate width is made larger than the roll diameter of the portion in contact with the end of the plate width.
• the roll diameter of the portion in contact with the center of the plate width can be increased due to the difference in the coefficient of thermal expansion.
• a restraining pressure can be stably applied to the steel sheet.
• a roll is used in which the temperature at the center of the plate width and the end of the plate width are constant and the roll diameter of the portion in contact with the center of the plate width is larger than the roll diameter of the portion in contact with the end of the plate width. You may decide.
• the guide roll for pressing the roll that comes into direct contact with the steel plate is divided into the center portion of the plate width of the steel plate and the plate width end portion of the steel plate, and the force of pressing from the guide roll is applied to the plate. It is possible to control the size at the center of the plate width rather than at the width end.
• the temperature of the steel sheet after being discharged from the water tank needs to be 100 ° C. or lower.
• the temperature after water cooling is preferably 80 ° C. or lower.
• the reheating temperature is 100 ° C. or higher.
• the reheating temperature is preferably 130 ° C. or higher.
• the shape uniformity deteriorates due to transformation shrinkage due to tempering. From the above, the reheating temperature is 300 ° C. or lower.
• the reheating temperature is preferably 260 ° C. or lower.
• the hot-rolled steel sheet after the hot-rolling process may be heat-treated to soften the structure. Further, after the annealing step, temper rolling for shape adjustment may be performed. Further, the surface of the steel sheet may be plated with Zn, Al or the like.
• the center of the plate width in the present invention is set to ⁇ 200 mm with respect to the position in the width direction of 1/2 of the width of the manufactured steel plate, assuming that the width end portion of the steel plate is removed by trimming during manufacturing. Good.
• the member of the present invention is formed by subjecting the steel sheet of the present invention to at least one of molding and welding.
• the method for manufacturing a member of the present invention includes a step of performing at least one of molding and welding on the steel sheet manufactured by the method for manufacturing a steel sheet of the present invention.
• the steel sheet of the present invention has high strength and is excellent in shape uniformity and delayed fracture resistance.
• the member obtained by using the steel sheet of the present invention has high strength, good dimensional accuracy, and excellent delayed fracture resistance, and therefore can be suitably used for, for example, a structural member for automobiles.
• general processing methods such as press processing can be used without limitation.
• welding general welding such as spot welding and arc welding can be used without limitation.
• the front surface and the back surface of the steel sheet are provided with two rolls installed sandwiching the steel sheet so that the restraining pressure (load load) per 1 m 2 of the roll steel sheet is 50 to 300 N / mm 2.
• a restraining pressure (load) was applied to the steel sheet at a uniform pressure.
• the area ratio was the average value of the three area ratios obtained from separate SEM images with a magnification of 1500 times.
• the measurement location was 1/4 of the plate thickness.
• Martensite has a white structure, and tempered martensite has fine carbides precipitated inside.
• Ferrite has a black structure. Further, depending on the surface orientation of the block grains and the degree of etching, it may be difficult for carbides to appear inside. In that case, it is necessary to sufficiently perform etching to confirm. Further, the area ratio of the remaining portion other than ferrite and martensite was calculated by subtracting the total area ratio of ferrite and martensite from 100%.
• Residual stress was measured by X-ray diffraction. Specifically, a sample of 100 mm in the rolling direction and 30 mm in the width direction is taken from the center of the plate width and the end of the plate width of each steel plate, and the steel plate sample is placed on a die having an angle of 90 °. By pressing the steel sheet with a punch having an angle of °, V-shaped bending was performed so that the bending ridge direction was parallel to the width direction of the steel sheet. The V-shaped bending process was performed under the conditions of punch moving speed: 30 mm / min, load: 15 ton, and holding time (pushing time) at maximum load: 5 seconds. Next, using bolts, nuts and taper washers, the bent steel plate (member) was bolted from both sides of the plate surface. The tightening amount was 30 mm.
• the measurement point of the residual stress in the steel sheet after the bending process was the center of the thickness of the end face of the bending ridge, and the X-ray irradiation diameter was 150 ⁇ m.
• the measurement direction was perpendicular to the plate thickness direction and perpendicular to the bending ridge line direction.
• the sample at the plate width end was taken at a position of 0 to 30 mm in the width direction from the plate width end of the steel plate.
• the steel sheet is manufactured by applying a load so as to be symmetrical with respect to the center of the plate width in the plate width direction, the residual stress is measured only at one end and the residual stress is measured at the other end. Residual stress was considered to be the same value.
• the critical load stress was measured by a delayed fracture test. Specifically, a sample of 100 mm in the rolling direction and 30 mm in the width direction was taken from the center of the plate width of each steel plate, and the sample was V-shaped bent by the same method as the above-mentioned residual stress measuring method. Next, using bolts, nuts and taper washers, the bent steel plate (member) was bolted from both sides of the plate surface. By CAE analysis using the YU model, the relationship between the load stress and the tightening amount was calculated from the stress-strain curve obtained from the tensile test, and molded members having various load stresses were produced.
• the molded member was immersed in hydrochloric acid having a pH of 1 (25 ° C.), and the maximum load stress that did not cause delayed fracture was evaluated as the critical load stress.
• the judgment of delayed fracture was performed visually and with an image magnified to a magnification of 20 with a stereomicroscope, and the case where the image was immersed for 96 hours and no cracks occurred was regarded as no destruction.
• the term “crack” as used herein refers to the case where a crack having a crack length of 200 ⁇ m or more occurs.
• the steel sheet obtained in each example was sheared in the longitudinal direction of the steel sheet (rolling direction) at the original width of the steel sheet to a length of 1 m, and the sheared steel sheet was placed on a horizontal table.
• the sheared steel sheet was placed on a horizontal table so that the corners of the steel sheet and the horizontal table had more contact points (two or more points).
• the amount of warpage is determined by lowering the horizontal plate from a position above the steel plate until it contacts the steel plate, and at the position where it contacts the steel plate, the thickness of the steel plate is determined from the distance between the horizontal table and the horizontal plate. I asked for it.
• the amount of warpage was measured with the other side of the steel sheet on the upper side, and the maximum value of the measured amount of warpage was taken as the maximum amount of warpage.
• the clearance of the blade of the shearing machine when cutting the steel sheet in the longitudinal direction is 4% (the upper limit of the control range is 10%).
• the critical load stress is YS or more
• the critical load stress ratio to the plate width end at the center of the plate width is 90% or more and 110% or less
• the length is 1 m in the longitudinal direction of the steel sheet.
• a steel sheet having a maximum warp of 15 mm or less was accepted, and Table 2 shows an example of the invention. Steel sheets that do not satisfy at least one of these were rejected and are shown as comparative examples in Table 2.
• the hot-rolled steel sheet and the cold-rolled steel sheet obtained as described above were annealed under the conditions shown in Table 4 or 5 to produce a steel sheet.
• the blanks in Table 3 indicate that they were not added intentionally, and include not only the case where they are not contained (0% by mass) but also the cases where they are unavoidably contained.
• the critical load stress is YS or more
• the critical load stress ratio to the plate width end at the center of the plate width is 90% or more and 110% or less
• the length is 1 m in the longitudinal direction of the steel sheet.
• Steel sheets having a maximum warp amount of 15 mm or less were accepted, and are shown as examples of inventions in Tables 6 and 7. Steel sheets that do not satisfy at least one of these were rejected and are shown as comparative examples in Tables 6 and 7.

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