WO2020244611A1 - 一种具有过滤voc气体性能的汽车空调过滤材料及其工艺 - Google Patents

一种具有过滤voc气体性能的汽车空调过滤材料及其工艺 Download PDF

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Publication number
WO2020244611A1
WO2020244611A1 PCT/CN2020/094515 CN2020094515W WO2020244611A1 WO 2020244611 A1 WO2020244611 A1 WO 2020244611A1 CN 2020094515 W CN2020094515 W CN 2020094515W WO 2020244611 A1 WO2020244611 A1 WO 2020244611A1
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Prior art keywords
woven fabric
fabric layer
fiber non
activated carbon
filter material
Prior art date
Application number
PCT/CN2020/094515
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English (en)
French (fr)
Inventor
夏建华
Original Assignee
浙江佳海新材料有限公司
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Publication date
Application filed by 浙江佳海新材料有限公司 filed Critical 浙江佳海新材料有限公司
Priority to US17/295,636 priority Critical patent/US20220080342A1/en
Publication of WO2020244611A1 publication Critical patent/WO2020244611A1/zh

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    • B01D39/18—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being cellulose or derivatives thereof
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Definitions

  • the invention relates to the technical field of filter materials, in particular to an automobile air-conditioning filter material with the performance of filtering VOC gas and a process thereof.
  • VOC gas refers to volatile organic compounds, which is the most common air in non-industrial environments.
  • One of the common pollutants is styrene, propylene glycol, glycane, phenol, toluene, ethylbenzene, xylene, and formaldehyde.
  • the traditional adsorption of VOC gas uses activated carbon particles.
  • the filter materials for automobile air conditioners on the market use nanofiber membranes as the filter material. After the nanofiber membranes are combined with activated carbon particles, the activated carbon particles will change in the subsequent processing. The nanofiber membrane is pierced and the nanofiber membrane is damaged, so that the filtering performance of the composite filter material is reduced or lost.
  • the problem to be solved by the present invention is that the activated carbon particles will damage the nanofiber membrane during the subsequent processing, thereby reducing or losing the filtering performance of the composite filter material.
  • the present invention provides an automobile air-conditioning filter material with the performance of filtering VOC gas and its process, which has excellent air permeability, high VOC gas adsorption capacity, and excellent PM2.5 filtering capacity.
  • the present invention provides an automobile air-conditioning filter material with the performance of filtering VOC gas, comprising a sandwich structure 100 and an activated carbon fiber non-woven fabric layer 200.
  • One side of the sandwich structure 100 is an activated carbon fiber non-woven fabric layer 200.
  • the activated carbon fiber The non-woven fabric layer 200 is composed of activated carbon fibers interlaced with each other, and the activated carbon fiber non-woven fabric layer 200 is composited with the sandwich structure 100 through a hot melt adhesive 210.
  • An automobile air-conditioning filter material with the performance of filtering VOC gas provided by the present invention is further configured that the sandwich structure 100 includes a viscose fiber non-woven fabric layer 110, a TPU nanofiber layer 120 and a PP long fiber non-woven fabric layer 130
  • the viscose fiber non-woven fabric layer 110 is a TPU nano-fiber layer 120
  • the TPU nano-fiber layer 120 is a PP long-fiber non-woven fabric layer 130
  • the PP long-fiber non-woven fabric layer 130 is one On the side is an activated carbon fiber non-woven fabric layer 200.
  • the automotive air-conditioning filter material with the performance of filtering VOC gas provided by the present invention is further configured as the PP long fiber non-woven fabric layer 130, the TPU nano fiber layer 120 and the viscose fiber non-woven fabric layer 110 in a composite manner to form a sandwich Structure 100.
  • An automobile air-conditioning filter material with the performance of filtering VOC gas provided by the present invention is further arranged such that the hot-melt adhesive 210 is uniformly distributed in the sandwich structure 100 and activated carbon fiber non-woven in one of dots, fibers and lines. Between the cloth layer 200.
  • the automotive air conditioner filter material with the performance of filtering VOC gas provided by the present invention is further configured that the activated carbon fiber non-woven fabric layer 200 weighs 50GSM-500GSM per square meter.
  • the automotive air conditioner filter material with the performance of filtering VOC gas provided by the present invention is further arranged such that the viscose fiber non-woven fabric layer 110 is located on the windward side, and the activated carbon fiber non-woven fabric layer 200 is located on the windward side.
  • the invention also provides a preparation process of an automobile air-conditioning filter material with the performance of filtering VOC gas, including:
  • the TPU nanofiber layer 120 is made
  • the viscose fiber non-woven fabric layer 110, the TPU nanofiber layer 120, and the PP long-fiber non-woven fabric layer 130 are thermally composited or ultrasonically composited to form a sandwich structure 100;
  • the activated carbon fiber non-woven fabric layer 200 is made
  • the prepared activated carbon fiber non-woven fabric layer 200 and viscose fiber non-woven fabric layer 110, TPU nano-fiber layer 120 and PP long-fiber non-woven fabric layer 130 are formed into a sandwich structure 100 by thermal compounding or ultrasonic compounding for thermal melting Glue compound
  • the method for preparing an automobile air-conditioning filter material with the performance of filtering VOC gas provided by the present invention can be further configured as the hot melt adhesive 210 used in the hot melt adhesive 210 compounding in step f in the shape of dots, fibers or lines Evenly distributed.
  • the present invention uses activated carbon fiber non-woven fabric layer 200 instead of activated carbon particles.
  • the activated carbon fiber has stronger VOC gas 430 adsorption capacity than activated carbon particles, and the activated carbon fiber is made into a non-woven fabric to prevent the activated carbon fiber layer from damaging the TPU nanofiber layer.
  • the composite of the activated carbon fiber non-woven fabric layer 200 and the sandwich structure 100 is the last process, thereby avoiding the problem that the TPU nanofiber layer 120 will be damaged if other processes are performed after the composite.
  • the present invention adopts the sandwich structure 100, and the TPU nanofiber layer 120 is located between the viscose fiber non-woven fabric layer 110 and the PP long-fiber non-woven fabric layer 130 to avoid damage to the TPU nanofiber layer 120 to the greatest extent.
  • the PP long-fiber non-woven fabric layer 130 is placed between the TPU nanofiber layer 120 and the activated carbon fiber non-woven fabric layer 200 to prevent the TPU nanofiber layer 120 from contacting the activated carbon fiber non-woven fabric layer 200 and cause the TPU nanofiber layer 120 to be damaged. The problem.
  • the activated carbon fiber non-woven fabric layer 200 of the present invention is located on the air outlet surface so that it can filter the VOC gas 430 outside the car, and can also absorb the VOC gas 430 generated inside the car, so that the air 400 inside the car is refreshed.
  • the viscose fiber non-woven fabric layer 110 of the present invention is located on the windward side to block external foreign matter first, and avoid the TPU nano fiber layer 120, the PP long fiber non-woven fabric layer 130 and the activated carbon fiber non-woven fabric layer 200 from being damaged. damage.
  • the activated carbon fiber non-woven fabric layer 200 is composited with the sandwich structure 100, instead of the original activated carbon particles, the glue material is used to stick the activated carbon particles on the sandwich structure 100, which solves the problem that the glue material wraps the activated carbon particles so that the activated carbon particles are The surface area is greatly reduced, thereby reducing the problem of the adsorption capacity of the VOC gas 430.
  • Figure 1 is a schematic diagram of the filter material structure
  • Figure 2 is a schematic diagram of activated carbon fiber non-woven fabric layer structure
  • Figure 3 is a schematic diagram of the hot melt adhesive structure in dots
  • Figure 4 is a schematic diagram of a fibrous distributed hot melt adhesive structure
  • Fig. 5 is a schematic diagram of the structure of hot melt adhesive distributed in a line shape
  • Figure 6 is a schematic diagram of the filtration process of the filter material
  • an automotive air conditioner filter material with the performance of filtering VOC gas includes a sandwich structure 100 and an activated carbon fiber non-woven fabric layer 200.
  • One side of the specific sandwich structure 100 is an activated carbon fiber non-woven fabric layer 200.
  • the activated carbon fiber The non-woven fabric layer 200 is composited with the sandwich structure 100 through the hot melt adhesive 210.
  • the sandwich structure 100 is used to block and adsorb particulate matter in the air 400, and the activated carbon fiber non-woven fabric layer 200 is used to adsorb VOC gas 430 contained in the gas. It achieves the effect of removing peculiar smell, thereby reducing the content of VOC gas 430 inhaled by people in the car.
  • the sandwich structure 100 includes a viscose fiber non-woven fabric layer 110, a TPU nanofiber layer 120 and a PP long-fiber non-woven fabric layer 130;
  • the viscose fiber non-woven fabric layer 110 is a base layer for carrying and Protect the TPU nanofiber layer 120 and the PP long fiber non-woven fabric layer 130, while the TPU nanofiber layer 120 is used to filter and block particles 410 with an average particle diameter of 1 ⁇ m or greater in the air 400, and the PP long fiber non-woven fabric layer 130 Used to adsorb the remaining particles 420 with a diameter of less than 1 ⁇ m in the filtered air 400;
  • one side of the viscose fiber non-woven fabric layer 110 is a TPU nanofiber layer 120
  • the other side of the TPU nanofiber layer 120 is a PP long fiber non-woven fabric Layer 130
  • the other side of PP long-fiber non-woven fabric layer 130 is activated carbon fiber non-woven fabric layer 200, the specific PP long-fiber non-woven fabric layer 130
  • the activated carbon fiber non-woven fabric layer 200 is composed of activated carbon fibers interlaced with each other.
  • the specific activated carbon fiber non-woven fabric layer 200 weighs 50 GSM to 500 GSM per square meter, so that the activated carbon fiber non-woven fabric layer 200 has a good
  • the ability to absorb the VOC gas 430 contained in the gas also has excellent gas permeability.
  • the hot melt adhesive 210 is uniformly distributed between the sandwich structure 100 and the activated carbon fiber non-woven fabric layer 200 in a dot shape, a staggered fiber shape, and a line shape to connect the sandwich structure 100 and
  • the activated carbon fiber non-woven fabric layer 200 is composited, and the filter material obtained after being composited with the activated carbon fiber non-woven fabric layer 200 has a static adsorption efficiency of toluene of more than 40% and an adsorption efficiency of formaldehyde of more than 90%.
  • the viscose fiber non-woven fabric layer 110 is located on the windward side for the windward, blocking foreign matter 300 from damaging the filter material, thereby protecting the entire filter material, and the activated carbon fiber non-woven fabric layer 200 is located on the windward surface , Used to adsorb VOC gas 430, which is located on the air outlet to facilitate its absorption of VOC gas 430 in the filtered air 400 from the car.
  • the viscose fiber non-woven fabric layer 110 blocks foreign objects 300, which are garbage and/or stones, and the air 400 penetrates the viscose fiber non-woven fabric layer 110 to contact the TPU nanofiber layer 120 Filter out particles 410 with an average particle diameter of 1 ⁇ m or greater.
  • the filtered air 400 penetrates the TPU nanofiber layer 120 to reach the PP long-fiber non-woven fabric layer 130, and the PP long-fiber non-woven fabric layer 130 reduces the diameter of the After the 1 ⁇ m particles 420 are adsorbed, the air 400 passes through the PP long-fiber non-woven fabric layer 130 and contacts the activated carbon fiber non-woven fabric layer 200.
  • the air 400 passes through the activated carbon fiber non-woven fabric layer 200, it passes through the gap between the activated carbon fibers At this time, most of the VOC gas 430 in the air 400 is adsorbed on the activated carbon fiber, and the remaining air 400 enters the interior of the car.
  • the VOC gas 430 in the air 400 inside the car will also be slowly absorbed by the activated carbon fiber non-woven fabric layer 200, thereby making the air 400 inside the car refreshing and odorless.
  • the invention provides a method for preparing an automobile air-conditioning filter material with the performance of filtering VOC gas, including the following steps:
  • the viscose fiber is made into a non-woven fabric by a spunbonding method as the base layer of the filter material, and then the viscose fiber non-woven fabric layer 110 is calendered by a calender roll to ensure that the TPU nanofiber layer 120 is attached to a smooth surface.
  • the TPU nanofiber layer 120 is made
  • the mixed solvent of TPU granular resin, N-dimethylformamide and methyl ethyl ketone is mixed in a closed container to make a TPU solution.
  • the TPU solution is produced into a TPU nanofiber layer 120 by a nanofiber membrane production equipment.
  • the fiber non-woven fabric layer 110 and the TPU nanofiber layer 120 are extruded by a calender roller to form a two-layer composite structure.
  • the polypropylene polymer resin is passed through a melt blowing device to form a PP long-fiber non-woven fabric layer 130.
  • the viscose fiber non-woven fabric layer 110, the TPU nanofiber layer 120, and the PP long-fiber non-woven fabric layer 130 are combined by heat or ultrasonic to form a sandwich structure 100.
  • the activated carbon fiber non-woven fabric layer 200 is made
  • the activated carbon fiber is made into a non-woven fabric by a spunlace method, so that the activated carbon fiber non-woven fabric layer 200 has excellent air permeability.
  • a section of each roll of filter material is cut out, and the ability to filter and adsorb particles is tested.
  • the filter adsorption capacity and the adsorption capacity of VOC gas 430 are tested.
  • the detection method is a common detection method. After the detection, the qualified filter material is tested for both. The irregular edges of the side due to compounding are cut straight, and then stored in rolls.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Air-Conditioning For Vehicles (AREA)
  • Filtering Materials (AREA)

Abstract

一种具有过滤VOC气体性能的汽车空调过滤材料，包括三明治结构(100)与活性炭纤维无纺布层(200)，三明治结构(100)一侧为活性炭纤维无纺布层(200)，活性炭纤维无纺布层(200)由活性炭纤维构成，活性炭纤维无纺布层(200)通过热熔胶(210)与三明治结构(100)复合。

Description

一种具有过滤VOC气体性能的汽车空调过滤材料及其工艺
本申请要求于2019年6月5日提交中国专利局、申请号为201910484410.0、发明名称为“一种具有过滤VOC气体性能的汽车空调过滤材料及其工艺”的中国专利申请的优先权，其全部内容通过引用结合在本申请中。
技术领域
本发明涉及过滤材料技术领域，具体涉及到一种具有过滤VOC气体性能的汽车空调过滤材料及其工艺。
背景技术
目前市面上所用的汽车空调用的过滤材料，除了需要具有过滤PM2.5颗粒物等功能外，还必须具有吸附VOC气体的功能，VOC气体指的是挥发性有机物，是非工业环境中最常见的空气污染物之一，常见的有苯乙烯、丙二醇、甘烷、酚、甲苯、乙苯、二甲苯、甲醛等。
而传统的吸附VOC气体都是采用活性炭颗粒物，目前市面上的汽车空调用的过滤材料中会采用纳米纤维膜作为过滤材料，而纳米纤维膜与活性炭颗粒物复合后，在后续加工过程中活性炭颗粒物会刺破纳米纤维膜，使得纳米纤维膜损坏，从而使得该复合过滤材料的过滤性能下降或者丧失。
发明内容
(一)要解决的技术问题
本发明要解决的问题是在后续加工过程中活性炭颗粒物会造成纳米纤维膜的损坏，从而使该复合过滤材料的过滤性能下降或者丧失的问题。
(二)技术方案
为解决所述技术问题，本发明提供一种具有过滤VOC气体性能的汽车空调过滤材料及其工艺，具有优良的透气性，高的VOC气体吸附能力，以及优良的PM2.5的过滤能力。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料，包括三明治结构100与活性炭纤维无纺布层200，所述三明治结构100一侧为活性炭纤维无纺布层200，所述活性炭纤维无纺布层200由活性炭纤维 相互交错构成，所述活性炭纤维无纺布层200通过热熔胶210与三明治结构100复合。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料进一步的设置为所述三明治结构100包括，粘胶纤维无纺布层110、TPU纳米纤维层120与PP长纤无纺布层130；所述粘胶纤维无纺布层110一侧为TPU纳米纤维层120，所述TPU纳米纤维层一侧120为PP长纤无纺布层130，所述PP长纤无纺布层130一侧为活性炭纤维无纺布层200。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料进一步的设置为所述PP长纤无纺布层130、TPU纳米纤维层120与粘胶纤维无纺布层110采用复合方式形成三明治结构100。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料进一步的设置为所述热熔胶210成点状、纤维状和线条状中的一种均匀分布在三明治结构100与活性炭纤维无纺布层200之间。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料进一步的设置为所述活性炭纤维无纺布层200每平方米重为50GSM～500GSM。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料进一步的设置为所述粘胶纤维无纺布层110位于迎风面，所述活性炭纤维无纺布层200位于出风面。
本发明还提供了一种具有过滤VOC气体性能的汽车空调过滤材料的制备工艺，包括：
a、制成粘胶纤维无纺布层110；
b、制成TPU纳米纤维层120；
c、制成PP长纤无纺布层130；
d、将粘胶纤维无纺布层110、TPU纳米纤维层120与PP长纤无纺布层130通过热复合或者超声波复合形成三明治结构100；
e、制成活性炭纤维无纺布层200；
f、将制成的活性炭纤维无纺布层200与粘胶纤维无纺布层110、TPU纳米纤维层120与PP长纤无纺布层130通过热复合或者超声波复合形成三明治结构100进行热熔胶复合；
g、对成品后的过滤材料进行质量检验，后进行切边处理，最后入库储存。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法可进一步的设置为步骤f的热熔胶210复合中采用的热熔胶210以点状、纤维状或线条状的形状均匀分布。
(三)有益效果
1、本发明采用活性炭纤维无纺布层200代替活性炭颗粒物，活性炭纤维比活性炭颗粒物的VOC气体430吸附能力更强，而且将活性炭纤维制成无纺布避免了活性炭纤维层损坏TPU纳米纤维层的可能性，同时活性炭纤维无纺布层200与三明治结构100的复合为最后一道工序，进而避免了复合后再进行其他工序会造成TPU纳米纤维层120破损的问题。
2、本发明采用三明治结构100，将TPU纳米纤维层120位于粘胶纤维无纺布层110与PP长纤无纺布层130之间，最大程度的避免了TPU纳米纤维层120的被损坏，同时PP长纤无纺布层130在TPU纳米纤维层120与活性炭纤维无纺布层200之间起到避免TPU纳米纤维层120与活性炭纤维无纺布层200接触使得TPU纳米纤维层120被损坏的问题。
3、本发明的活性炭纤维无纺布层200位于出风面使得其能过滤汽车外部的VOC气体430，同时也可以吸附汽车内部产生的VOC气体430，使得汽车内部空气400清爽。
4、本发明的粘胶纤维无纺布层110位于迎风面，起到首先阻挡外部异物，避免了TPU纳米纤维层120、PP长纤无纺布层130与活性炭纤维无纺布层200遭到损坏。
5、本发明采用活性炭纤维无纺布层200与三明治结构100复合，代替原来的活性炭颗粒物，采用胶质材料黏贴在三明治结构100上，解决了胶质材料包裹住活性炭颗粒物，使得活性炭颗粒物的表面积大大降低，从而降低对VOC气体430的吸附能力的问题。
说明书附图
图1为过滤材料结构示意图；
图2为活性炭纤维无纺布层结构示意图；
图3为点状分布的热熔胶结构示意图；
图4为纤维状分布的热熔胶结构示意图；
图5为线条状分布的热熔胶结构示意图；
图6为过滤材料过滤过程示意图；
图1～图6中，100-三明治结构；110-粘胶纤维无纺布层；120-TPU纳米纤维层；130-PP长纤无纺布层；200-活性炭纤维无纺布层；210-热熔胶；300-异物；400-空气；410-直径为1μm或者大于1μm的颗粒；420-直径小于1μm的颗粒；430-VOC气体。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步详细描述。以下实施例用于说明本发明，但不用来限制本发明的范围。
如图1所示，一种具有过滤VOC气体性能的汽车空调过滤材料，包括三明治结构100与活性炭纤维无纺布层200，具体的三明治结构100一侧为活性炭纤维无纺布层200，活性炭纤维无纺布层200通过热熔胶210与三明治结构100复合，三明治结构100用于阻挡和吸附空气400中的颗粒物质，而活性炭纤维无纺布层200用于吸附气体中含有的VOC气体430，达到去除异味的作用，进而减少人在车内吸入的VOC气体430的含量。
如图1所示，三明治结构100包括，粘胶纤维无纺布层110、TPU纳米纤维层120与PP长纤无纺布层130；粘胶纤维无纺布层110为基层，用于承载与保护TPU纳米纤维层120和PP长纤无纺布层130，而TPU纳米纤维层120用于过滤阻挡空气400中平均颗粒直径为1μm或者大于1μm的颗粒410，而PP长纤无纺布层130用于吸附过滤后空气400中剩余的直径小于1μm的颗粒420；其中粘胶纤维无纺布层110一侧为TPU纳米纤维层120，TPU纳米纤维层120另一侧为PP长纤无纺布层130，PP长纤无纺布层130另一侧为活性炭纤维无纺布层200，具体的PP长纤无纺布层130、TPU纳米纤维层120与粘胶纤维无纺布层110采用复合方式形成三明治结构100，采用三明治结构100使得粘胶纤维无纺布层110与PP长纤无纺布层130能很好的保护脆弱的TPU纳米纤维层120。
如图2所示，活性炭纤维无纺布层200由活性炭纤维相互交错构成，具体的活性炭纤维无纺布层200每平方米重为50GSM～500GSM，使得活 性炭纤维无纺布层200在有良好的吸附气体中含有的VOC气体430的能力的同时也具备优良的透气性。
如图3～5所示，热熔胶210成点状、交错纤维状和线条状中的一种均匀分布在三明治结构100与活性炭纤维无纺布层200之间，用于将三明治结构100与活性炭纤维无纺布层200复合，经试验得到与活性炭纤维无纺布层200复合后得到的过滤材料其对甲苯的静态吸附效率达到40％以上，对甲醛的吸附效率达到90％以上。
如图6所示，粘胶纤维无纺布层110位于迎风面用于迎风，阻挡异物300破坏过滤材料，从而起到了保护整个过滤材料的作用，而活性炭纤维无纺布层200位于出风面，用于吸附VOC气体430，其位于出风面方便其吸收汽车为与过滤后的空气400中的VOC气体430的吸附。
如图6所示，使用时，粘胶纤维无纺布层110挡住异物300，异物300是为垃圾和/或石子，而空气400透过粘胶纤维无纺布层110接触TPU纳米纤维层120过滤掉平均颗粒直径为1μm或者大于1μm的颗粒410，被过滤后的空气400透过TPU纳米纤维层120接触到PP长纤无纺布层130，PP长纤无纺布层130将其中直径小于1μm的颗粒420进行吸附之后空气400透过PP长纤无纺布层130与活性炭纤维无纺布层200接触，在空气400透过活性炭纤维无纺布层200时，经过活性炭纤维之间的间隙时，空气400中大部分的VOC气体430被吸附到活性炭纤维上，其余的空气400进入汽车内部。
同时，在汽车内部的空气400中的VOC气体430也会缓慢的被活性炭纤维无纺布层200吸附，进而使得汽车内部空气400清爽无异味。
本发明提供的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，包括以下步骤：
a、制成粘胶纤维无纺布层110；
将粘胶纤维通过纺粘法制成无纺布，作为过滤材料的基层，之后将粘胶纤维无纺布层110经过压光辊压光处理，保证来TPU纳米纤维层120附着一面平滑。
b、制成TPU纳米纤维层120；
将TPU颗粒状树脂、N-二甲基甲酰胺与丁酮的混合溶剂在密闭容器 中混合后制成TPU溶液，通过纳米纤维膜生产设备将TPU溶液生产成TPU纳米纤维层120，将粘胶纤维无纺布层110与TPU纳米纤维层120通过压光辊挤压形成两层复合结构。
c、制成PP长纤无纺布层130；
将聚丙烯高分子树脂经过熔喷装置制成PP长纤无纺布层130。
d、将粘胶纤维无纺布层110、TPU纳米纤维层120与PP长纤无纺布层130通过热复合或者超声波复合形成三明治结构100。
e、制成活性炭纤维无纺布层200；
将活性炭纤维通过水刺法制成无纺布，使得活性炭纤维无纺布层200具有优良的透气性能。
f、在制成的活性炭纤维无纺布层200上均匀涂抹有点状、纤维状、线条状的融胶然后与粘胶纤维无纺布层110、TPU纳米纤维层120与PP长纤无纺布层130通过热复合或者超声波复合形成三明治结构100的进行热熔胶210复合，且活性炭纤维无纺布层200位于PP长纤无纺布层130外侧，进而形成四层结构。
g、对成品后的过滤材料进行质量检验，后进行切边处理，最后入库储存；
每一卷过滤材料截取出一段，进行过滤吸附颗粒能力的检测其过滤吸附能力与VOC气体430的吸附能力的检测，检测方法为常见的检测方法，检测后，对合格的过滤材料，将其两侧因复合产生的不整齐的边切齐，然后绕卷储存。
综上所述，上述实施方式并非是本发明的限制性实施方式，凡本领域的技术人员在本发明的实质内容的基础上所进行的修饰或者等效变形，均在本发明的技术范畴。

Claims (11)

  1. 一种具有过滤VOC气体性能的汽车空调过滤材料，其特征在于，包括三明治结构(100)与活性炭纤维无纺布层(200)，所述三明治结构(100)一侧为活性炭纤维无纺布层(200)，所述活性炭纤维无纺布层(200)由活性炭纤维相互交错构成，所述活性炭纤维无纺布层(200)通过热熔胶(210)与三明治结构(100)复合；
    所述三明治结构(100)包括，粘胶纤维无纺布层(110)、TPU纳米纤维层(120)与PP长纤无纺布层(130)；所述粘胶纤维无纺布层(110)一侧为TPU纳米纤维层(120)，所述TPU纳米纤维层(120)另一侧为PP长纤无纺布层(130)，所述PP长纤无纺布层(130)另一侧为活性炭纤维无纺布层(200)。
  2. [根据细则91更正 04.08.2020]
    根据权利要求1所述的一种具有过滤VOC气体性能的汽车空调过滤材料，其特征在于，所述PP长纤无纺布层(130)、TPU纳米纤维层(120)与粘胶纤维无纺布层(110)采用复合方式形成三明治结构(100)；
    所述复合的方式为热复合或超声波复合。
  3. [根据细则91更正 04.08.2020]　
    根据权利要求1所述的一种具有过滤VOC气体性能的汽车空调过滤材料，其特征在于，所述热熔胶(210)成点状、纤维状和线条状中的一种均匀分布在三明治结构(100)与活性炭纤维无纺布层(200)之间。
  4. 根据权利要求1所述的一种具有过滤VOC气体性能的汽车空调过滤材料，其特征在于，所述活性炭纤维无纺布层(200)每平方米重为50GSM～500GSM。
  5. [根据细则91更正 04.08.2020]　
    根据权利要求1所述的一种具有过滤VOC气体性能的汽车空调过滤材料，其特征在于，所述粘胶纤维无纺布层(110)位于迎风面，所述活性炭纤维无纺布层(200)位于出风面。
  6. [根据细则91更正 04.08.2020]
    权利要求1～5任意一项所述一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，其特征在于，包括以下步骤：
    a、制成粘胶纤维无纺布层(110)；
    b、制成TPU纳米纤维层(120)；
    c、制成PP长纤无纺布层(130)；
    d、将粘胶纤维无纺布层(110)、TPU纳米纤维层(120)与PP长纤无纺布层(130)通过热复合或者超声波复合形成三明治结构(100)；
    e、制成活性炭纤维无纺布层(200)；
    f、将制成的活性炭纤维无纺布层(200)与三明治结构(100)进行热熔胶(210)复合，所述活性炭纤维无纺布层(200)位于PP长纤无纺布层130外侧；
    g、对成品后的过滤材料进行质量检验，后进行切边处理，最后入库储存；
    所述步骤a、b和c之间没有时间顺序的限制，所述步骤a、b、c、d与e之间没有时间顺序的限制。
  7. [根据细则91更正 04.08.2020]　
    根据权利要求6所述的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，其特征在于，步骤f的热熔胶(210)复合中采用的热熔胶(210)以点状、纤维状或线条状的形状均匀分布。
  8. [根据细则91更正 04.08.2020]
    根据权利要求6所述的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，其特征在于，所述步骤a包括以下步骤：
    将粘胶纤维通过纺粘法制成无纺布，之后将无纺布进行压光辊压光处理。
  9. [根据细则91更正 04.08.2020]
    根据权利要求6所述的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，其特征在于，所述步骤b包括以下步骤：
    将TPU颗粒状树脂、N-二甲基甲酰胺与丁酮的混合溶剂在密闭容器中混合后制成TPU溶液，通过纳米纤维膜生产设备将TPU溶液生产成TPU纳米纤维层(120)。
  10. [根据细则91更正 04.08.2020]
    根据权利要求6所述的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，其特征在于，所述步骤c包括以下步骤：
    将聚丙烯高分子树脂经过熔喷装置制成PP长纤无纺布层(130)。
  11. [根据细则91更正 04.08.2020]
    根据权利要求6所述的一种具有过滤VOC气体性能的汽车空调过滤材料的制备方法，其特征在于，所述步骤e包括以下步骤：
    将活性炭纤维通过水刺法制成活性炭纤维无纺布层(200)。
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