WO2020184395A1 - 吸水性樹脂粒子及びその製造方法、吸収体、吸収性物品、並びに、浸透速度の調整方法 - Google Patents
吸水性樹脂粒子及びその製造方法、吸収体、吸収性物品、並びに、浸透速度の調整方法 Download PDFInfo
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- WO2020184395A1 WO2020184395A1 PCT/JP2020/009508 JP2020009508W WO2020184395A1 WO 2020184395 A1 WO2020184395 A1 WO 2020184395A1 JP 2020009508 W JP2020009508 W JP 2020009508W WO 2020184395 A1 WO2020184395 A1 WO 2020184395A1
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- water
- resin particles
- absorbent resin
- gel
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Definitions
- the present invention relates to water-absorbent resin particles, a method for producing the same, an absorber, an absorbent article, and a method for adjusting the permeation rate.
- Patent Document 1 discloses water-absorbent resin particles having a particle size that are suitably used for absorbent articles such as diapers.
- Patent Document 2 describes a method of using a hydrogel-absorbing polymer having specific saline flow inducibility, pressure-lowering performance, etc. as an effective absorbent member for accommodating a body fluid such as urine. It is disclosed.
- the liquid provided for the absorbent article does not sufficiently permeate the absorbent article, the excess liquid may flow on the surface of the absorbent article and leak to the outside of the absorbent article. Therefore, it is required that the liquid permeates the absorbent article at an excellent permeation rate.
- One aspect of the present invention provides water-absorbent resin particles having a gel flow rate of 10 to 70 g / min measured by the following procedures (1) to (3).
- a gel is obtained by mixing 1 part by mass of the water-absorbent resin particles and 199 parts by mass of water.
- the gel is housed in the funnel with the circular lower end opening having a diameter of 8 mm closed.
- the amount of outflow of the gel per unit time when 3 minutes have passed after opening the lower end opening is measured as the gel flow rate.
- Another aspect of the present invention provides an absorber containing the above-mentioned water-absorbent resin particles.
- Another aspect of the present invention provides an absorbent article comprising the absorber described above.
- Another aspect of the present invention provides a method for producing water-absorbent resin particles, which comprises a step of selecting water-absorbent resin particles based on the gel flow rate measured by the following procedures (1) to (3).
- a gel is obtained by mixing 1 part by mass of the water-absorbent resin particles and 199 parts by mass of water.
- the gel is housed in the funnel with the circular lower end opening having a diameter of 8 mm closed.
- the amount of outflow of the gel per unit time when 3 minutes have passed after opening the lower end opening is measured as the gel flow rate.
- Another aspect of the present invention is a method for adjusting the permeation rate in an absorbent article including an absorber, wherein the absorber contains water-absorbent resin particles, and the adjusting method is described in (1) to (3) below.
- a method for adjusting the permeation rate which comprises a step of adjusting the gel flow rate measured by the procedure of).
- a gel is obtained by mixing 1 part by mass of the water-absorbent resin particles and 199 parts by mass of water.
- the gel is housed in the funnel with the circular lower end opening having a diameter of 8 mm closed.
- the amount of outflow of the gel per unit time when 3 minutes have passed after opening the lower end opening is measured as the gel flow rate.
- an absorbent article having an excellent permeation rate can be obtained by adjusting the gel flow rate.
- water-absorbent resin particles capable of obtaining an absorbent article having an excellent permeation rate, a method for producing the same, and a method for adjusting the permeation rate. Further, according to another aspect of the present invention, it is possible to provide an absorber and an absorbent article using the water-absorbent resin particles. According to another aspect of the present invention, it is possible to provide applications of water-absorbent resin particles, absorbers and absorbent articles to absorbents. According to another aspect of the present invention, it is possible to provide applications of water-absorbent resin particles, absorbers and absorbent articles for adjusting the permeation rate in absorbent articles.
- Water-soluble means that it exhibits a solubility in water of 5% by mass or more at 25 ° C.
- the materials exemplified in the present specification may be used alone or in combination of two or more.
- the content of each component in the composition means the total amount of the plurality of substances present in the composition when a plurality of substances corresponding to each component are present in the composition, unless otherwise specified.
- Saline refers to a 0.9% by mass sodium chloride aqueous solution.
- the gel flow rate measured by the following procedures (1) to (3) is 10 to 70 g / min.
- a gel is obtained by mixing 1 part by mass of the water-absorbent resin particles and 199 parts by mass of water.
- the gel is housed in the funnel with the circular lower end opening having a diameter of 8 mm closed.
- the amount of outflow of the gel per unit time when 3 minutes have passed after opening the lower end opening is measured as the gel flow rate.
- the cause is not limited to the following contents. That is, the water-absorbent resin particles have cross-linking points to the extent that they do not dissolve when they swell by absorbing a liquid such as water, and the swelling is not significantly inhibited. On the other hand, even if there are cross-linking points that can be appropriately swollen, if the cross-linking points are unevenly distributed, the swelling of the gel is also biased. In this case, the occurrence of insufficient swelling leads to an unfavorable phenomenon such as gel blocking.
- the water-absorbent resin particles having the gel flow rate having a specific value have an excellent permeation rate in the absorbent article because the water-absorbent resin particles are appropriately crosslinked and the crosslinks of the particles are uniform. It is thought that it will be obtained.
- the gel flow rate is 15 g / min or more, 20 g / min or more, 25 g / min or more, 30 g / min or more, 35 g / min or more, 40 g / min or more, or from the viewpoint of easily obtaining an excellent permeation rate in an absorbent article. , 45 g / min or more is preferable.
- the gel flow rate is preferably 65 g / min or less, 60 g / min or less, 55 g / min or less, or 50 g / min or less from the viewpoint of easily obtaining an excellent permeation rate in the absorbent article.
- As the gel flow rate a gel flow rate at room temperature (25 ⁇ 2 ° C.) can be used.
- the gel used in the step (1) in the gel flow rate test can be obtained by mixing 1 part by mass of water-absorbent resin particles and 199 parts by mass of ion-exchanged water as a swelling gel with 200-fold swelling.
- the funnel used in step (2) has a circular lower end opening (discharge port) with a diameter of 8 mm.
- the lower end opening can be opened and closed with a damper or the like.
- the funnel has, for example, an upper end opening (supply port) for supplying gel, and the gel supplied from the upper end opening is discharged from the lower end opening.
- the funnel has, for example, a tapered shape that narrows from the upper end opening to the lower end opening.
- the inclination angle of the side wall of the funnel is, for example, 20 ° with respect to the axial direction of the funnel.
- the funnel can be installed horizontally.
- the constituent material of the funnel is, for example, stainless steel.
- step (3) the receiver that receives the gel is placed vertically downward with respect to the funnel, and the amount of gel outflow is measured from the opening of the lower end opening to 3 minutes.
- the gel can be discharged with the upper end of the receiver located 38 mm below the outlet of the funnel.
- the outflow amount (gel flow rate) per unit time of the gel can be obtained by dividing the outflow amount of the gel at the time when 3 minutes have passed by the elapsed time (3 minutes).
- the water-absorbent resin particles according to the present embodiment may be any water-absorbent resin particles as long as they can retain water, and the liquid to be absorbed may contain water.
- the water-absorbent resin particles according to the present embodiment are excellent in absorption of body fluids such as urine, sweat, and blood (for example, menstrual blood).
- the water-absorbent resin particles according to the present embodiment can be used as a constituent component of the absorber according to the present embodiment.
- the water retention amount of the physiological saline of the water-absorbent resin particles according to the present embodiment is preferably in the following range.
- the amount of water retained is 10 g / g or more, 15 g / g or more, 20 g / g or more, 25 g / g or more, 30 g / g or more, or 32 g / g or more from the viewpoint of easily obtaining an excellent permeation rate in an absorbent article. preferable.
- the amount of water retained is 80 g / g or less, less than 80 g / g, 75 g / g or less, 70 g / g or less, 65 g / g or less, 60 g / g or less, 55 g / g from the viewpoint of easily obtaining an excellent permeation rate in an absorbent article. It is preferably g or less, 50 g / g or less, 48 g / g or less, 45 g / g or less, 44 g / g or less, 43 g / g or less, 42 g / g or less, or 40 g / g or less. From these viewpoints, the amount of water retained is preferably 10 to 80 g / g, more preferably 30 to 60 g / g.
- the water absorption amount of the physiological saline under a load of 4.14 kPa of the water-absorbent resin particles according to the present embodiment is preferably in the following range.
- the amount of water absorption is 10 mL / g or more, 12 mL / g or more, 15 mL / g or more, 17 mL / g or more, 18 mL / g or more, 20 mL / g or more, 22 mL / g from the viewpoint of easily obtaining an excellent permeation rate in an absorbent article. It is preferably g or more, or 24 mL / g or more.
- the amount of water absorption is preferably 40 mL / g or less, 35 mL / g or less, 30 mL / g or less, or 28 mL / g or less from the viewpoint of easily suppressing excessive swelling in the absorbent article. From these viewpoints, the amount of water absorption is preferably 10 to 40 mL / g, more preferably 12 to 35 mL / g.
- the water absorption amount the water absorption amount at room temperature (25 ⁇ 2 ° C.) can be used. The amount of water absorption can be measured by the method described in Examples described later.
- Examples of the shape of the water-absorbent resin particles according to the present embodiment include substantially spherical, crushed, and granular shapes.
- the medium particle size of the water-absorbent resin particles (water-absorbent resin particles before water absorption) according to the present embodiment is preferably in the following range.
- the medium particle size is 250 ⁇ m or more, 280 ⁇ m or more, 300 ⁇ m or more, 310 ⁇ m or more, 320 ⁇ m or more, 330 ⁇ m or more, 340 ⁇ m or more, 350 ⁇ m or more, from the viewpoint of avoiding gel blocking and easily maintaining a good permeation rate of the absorbent article.
- 360 ⁇ m or more is preferable.
- the medium particle size is preferably 600 ⁇ m or less, 550 ⁇ m or less, 500 ⁇ m or less, 450 ⁇ m or less, 400 ⁇ m or less, 380 ⁇ m or less, or 370 ⁇ m or less from the viewpoint of easily keeping the tactile sensation of the absorbent article soft. From these viewpoints, the medium particle size is preferably 250 to 600 ⁇ m.
- the water-absorbent resin particles according to the present embodiment may have a desired particle size distribution at the time of being obtained by the production method described later, but the particle size distribution can be obtained by performing an operation such as particle size adjustment using classification with a sieve. May be adjusted.
- the water-absorbent resin particles according to the present embodiment are, for example, crosslinked polymers (derived from ethylenically unsaturated monomers) obtained by polymerizing a monomer containing an ethylenically unsaturated monomer as polymer particles.
- a crosslinked polymer having a structural unit to be used) can be included. That is, the water-absorbent resin particles according to the present embodiment can have a structural unit derived from an ethylenically unsaturated monomer, and are a crosslinked polymer having a structural unit derived from an ethylenically unsaturated monomer. It can contain polymer particles containing.
- a water-soluble ethylenically unsaturated monomer can be used as the ethylenically unsaturated monomer.
- the polymerization method include a reverse phase suspension polymerization method, an aqueous solution polymerization method, a bulk polymerization method, and a precipitation polymerization method.
- the reverse phase suspension polymerization method or the aqueous solution polymerization method is preferable from the viewpoint of ensuring good water absorption characteristics (water retention amount, etc.) of the obtained water-absorbent resin particles and easy control of the polymerization reaction.
- a reverse phase suspension polymerization method will be described as an example as a method for polymerizing an ethylenically unsaturated monomer.
- the ethylenically unsaturated monomer is preferably water-soluble, for example, (meth) acrylic acid and a salt thereof, 2- (meth) acrylamide-2-methylpropanesulfonic acid and a salt thereof, (meth) acrylamide, N. , N-dimethyl (meth) acrylamide, 2-hydroxyethyl (meth) acrylate, N-methylol (meth) acrylamide, polyethylene glycol mono (meth) acrylate, N, N-diethylaminoethyl (meth) acrylate, N, N-diethylamino Examples thereof include propyl (meth) acrylate and diethylaminopropyl (meth) acrylamide.
- the amino group may be quaternized.
- the ethylenically unsaturated monomer may be used alone or in combination of two or more.
- Functional groups such as the carboxyl group and amino group of the above-mentioned monomers can function as functional groups capable of cross-linking in the surface cross-linking step described later.
- the ethylenically unsaturated monomer is selected from the group consisting of (meth) acrylic acid and its salts, acrylamide, methacrylamide, and N, N-dimethylacrylamide. It is preferable to contain at least one compound selected, and more preferably to contain at least one compound selected from the group consisting of (meth) acrylic acid and salts thereof, and acrylamide. From the viewpoint of further enhancing the water absorption property (water retention amount and the like), the ethylenically unsaturated monomer further preferably contains at least one compound selected from the group consisting of (meth) acrylic acid and salts thereof. That is, the water-absorbent resin particles preferably have a structural unit derived from at least one selected from the group consisting of (meth) acrylic acid and salts thereof.
- a monomer other than the above-mentioned ethylenically unsaturated monomer may be used as the monomer for obtaining the water-absorbent resin particles.
- a monomer can be mixed with, for example, an aqueous solution containing the above-mentioned ethylenically unsaturated monomer and used.
- the amount of the ethylenically unsaturated monomer used is the total amount of the monomer (the total amount of the monomer for obtaining the water-absorbent resin particles. For example, the total amount of the monomer giving the structural unit of the crosslinked polymer. The same applies hereinafter). On the other hand, it is preferably 70 to 100 mol%.
- the ratio of (meth) acrylic acid and a salt thereof is more preferably 70 to 100 mol% with respect to the total amount of the monomer.
- “Ratio of (meth) acrylic acid and its salt” means the ratio of the total amount of (meth) acrylic acid and its salt.
- the water-absorbent resin particles containing a crosslinked polymer having a structural unit derived from the ethylenically unsaturated monomer and the above-mentioned ethylenically unsaturated monomer.
- it contains at least one compound selected from the group consisting of (meth) acrylic acid and a salt thereof, and the ratio of the (meth) acrylic acid and a salt thereof is the total amount of the monomer for obtaining the water-absorbent resin particles.
- 70 to 100 mol% of the total amount of the monomers giving the structural unit of the crosslinked polymer can be provided.
- the ethylenically unsaturated monomer is usually preferably used as an aqueous solution.
- concentration of the ethylenically unsaturated monomer in the aqueous solution containing the ethylenically unsaturated monomer (hereinafter, simply referred to as "monomeric aqueous solution”) is preferably 20% by mass or more and preferably 25 to 70% by mass. More preferably, 30 to 55% by mass is further preferable.
- Examples of the water used in the aqueous solution include tap water, distilled water, ion-exchanged water and the like.
- the aqueous monomer solution may be used by neutralizing the acid group with an alkaline neutralizer.
- the degree of neutralization of an ethylenically unsaturated monomer by an alkaline neutralizing agent increases the osmotic pressure of the obtained water-absorbent resin particles and further enhances the water absorption characteristics (water retention amount, etc.). It is preferably 10 to 100 mol%, more preferably 50 to 90 mol%, and even more preferably 60 to 80 mol% of the acidic group in the weight.
- alkaline neutralizing agent examples include alkali metal salts such as sodium hydroxide, sodium carbonate, sodium hydrogencarbonate, potassium hydroxide and potassium carbonate; ammonia and the like.
- the alkaline neutralizer may be used alone or in combination of two or more.
- the alkaline neutralizer may be used in the form of an aqueous solution to simplify the neutralization operation. Neutralization of the acid group of the ethylenically unsaturated monomer can be performed, for example, by adding an aqueous solution of sodium hydroxide, potassium hydroxide or the like to the above-mentioned monomer aqueous solution and mixing them.
- an aqueous monomer solution is dispersed in a hydrocarbon dispersion medium in the presence of a surfactant, and an ethylenically unsaturated monomer is polymerized using a radical polymerization initiator or the like.
- a radical polymerization initiator a water-soluble radical polymerization initiator can be used.
- Nonionic surfactants include sorbitan fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, sorbitol fatty acid ester, polyoxyethylene sorbitol fatty acid ester, and polyoxyethylene.
- Alkyl ether polyoxyethylene alkyl phenyl ether, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, alkylallyl formaldehyde condensed polyoxyethylene ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene polyoxypropyl alkyl ether, Examples thereof include polyethylene glycol fatty acid ester.
- Anionic surfactants include fatty acid salts, alkylbenzene sulfonates, alkylmethyl taurates, polyoxyethylene alkylphenyl ether sulfates, polyoxyethylene alkyl ether sulfonates, and polyoxyethylene alkyl ether phosphates. , Phosphate ester of polyoxyethylene alkyl allyl ether and the like.
- the surfactant may be used alone or in combination of two or more.
- the surfactant is a sorbitan fatty acid ester. It preferably contains at least one compound selected from the group consisting of polyglycerin fatty acid esters and sucrose fatty acid esters. From the viewpoint of easily obtaining an appropriate particle size distribution of the water-absorbent resin particles, and from the viewpoint of easily improving the water-absorbing characteristics (water retention amount, etc.) of the water-absorbent resin particles and the performance of the absorbent article using the same, the surfactant is used. , Sucrose fatty acid ester is preferably contained, and sucrose stearic acid ester is more preferable.
- the amount of the surfactant used is preferably 0.05 to 10 parts by mass with respect to 100 parts by mass of the aqueous monomer solution from the viewpoint of obtaining a sufficient effect on the amount used and economically. .08 to 5 parts by mass is more preferable, and 0.1 to 3 parts by mass is further preferable.
- a polymer-based dispersant may be used in combination with the above-mentioned surfactant.
- the polymer dispersant include maleic anhydride-modified polyethylene, maleic anhydride-modified polypropylene, maleic anhydride-modified ethylene / propylene copolymer, maleic anhydride-modified EPDM (ethylene / propylene / diene / terpolymer), and maleic anhydride.
- the polymer-based dispersant may be used alone or in combination of two or more.
- maleic anhydride-modified polyethylene maleic anhydride-modified polypropylene
- maleic anhydride-modified ethylene / propylene copolymer maleic anhydride / ethylene copolymer weight.
- maleic anhydride / propylene copolymer, maleic anhydride / ethylene / propylene copolymer, polyethylene, polypropylene, ethylene / propylene copolymer, oxidized polyethylene, oxidized polypropylene, and oxidized ethylene / propylene copolymer At least one selected from the group consisting of coalescing is preferable.
- the amount of the polymer-based dispersant used is preferably 0.05 to 10 parts by mass with respect to 100 parts by mass of the aqueous monomer solution from the viewpoint of obtaining a sufficient effect on the amount used and from the viewpoint of economic efficiency. , 0.08 to 5 parts by mass is more preferable, and 0.1 to 3 parts by mass is further preferable.
- the hydrocarbon dispersion medium may contain at least one compound selected from the group consisting of chain aliphatic hydrocarbons having 6 to 8 carbon atoms and alicyclic hydrocarbons having 6 to 8 carbon atoms.
- a chain aliphatic hydrocarbon such as n-hexane, n-heptane, 2-methylhexane, 3-methylhexane, 2,3-dimethylpentane, 3-ethylpentane, n-octane; cyclohexane , Methylcyclohexane, cyclopentane, methylcyclopentane, trans-1,2-dimethylcyclopentane, cis-1,3-dimethylcyclopentane, trans-1,3-dimethylcyclopentane and other alicyclic hydrocarbons; benzene, Examples include aromatic hydrocarbons such as toluene and xylene.
- the hydrocarbon dispersion medium may be used alone
- the hydrocarbon dispersion medium may contain at least one selected from the group consisting of n-heptane and cyclohexane from the viewpoint of being industrially easily available and having stable quality. From the same viewpoint, as the mixture of the above-mentioned hydrocarbon dispersion medium, for example, commercially available ExxonHeptane (manufactured by ExxonMobil: containing 75 to 85% of n-heptane and isomeric hydrocarbons) is used. You may.
- the amount of the hydrocarbon dispersion medium used is preferably 30 to 1000 parts by mass and 40 to 500 parts by mass with respect to 100 parts by mass of the monomer aqueous solution from the viewpoint of appropriately removing the heat of polymerization and easily controlling the polymerization temperature. Is more preferable, and 50 to 400 parts by mass is further preferable.
- the amount of the hydrocarbon dispersion medium used is 30 parts by mass or more, the polymerization temperature tends to be easily controlled.
- the amount of the hydrocarbon dispersion medium used is 1000 parts by mass or less, the productivity of polymerization tends to be improved, which is economical.
- the radical polymerization initiator is preferably water-soluble, and is, for example, a persulfate such as potassium persulfate, ammonium persulfate, sodium persulfate; methyl ethyl ketone peroxide, methyl isobutyl ketone peroxide, di-t-butyl peroxide, t.
- a persulfate such as potassium persulfate, ammonium persulfate, sodium persulfate
- methyl ethyl ketone peroxide methyl isobutyl ketone peroxide
- di-t-butyl peroxide di-t-butyl peroxide
- -Peroxides such as butyl cumylperoxide, t-butylperoxyacetate, t-butylperoxyisobutyrate, t-butylperoxypivalate, hydrogen peroxide; 2,2'-azobis (2-amidinopropane) ) 2 hydrochloride, 2,2'-azobis [2- (N-phenylamidino) propane] 2 hydrochloride, 2,2'-azobis [2- (N-allylamidino) propane] 2 hydrochloride, 2,2 '-Azobis [2- (2-imidazolin-2-yl) propane] dihydrochloride, 2,2'-azobis ⁇ 2- [1- (2-hydroxyethyl) -2-imidazolin-2-yl] propane ⁇ Dihydrochloride, 2,2'-azobis ⁇ 2-methyl-N- [1,1-bis (hydroxymethyl) -2-hydroxyethyl] propionamide ⁇ , 2,2'-azobis [2-methyl-N-
- the radical polymerization initiator may be used alone or in combination of two or more.
- examples of the radical polymerization initiator include potassium persulfate, ammonium persulfate, sodium persulfate, 2,2'-azobis (2-amidinopropane) dihydrochloride, and 2,2'-azobis [2- (2-imidazolin-2-).
- 2,2'-azobis (2-amidinopropane) dihydrochloride 2,2'-azobis [2- (2-imidazolin-2-yl) propane] dihydrochloride, and 2,2'-.
- At least one azo compound selected from the group consisting of azobis ⁇ 2- [1- (2-hydroxyethyl) -2-imidazolin-2-yl] propane ⁇ 2 hydrochloride is more preferable.
- the ratio of the azo compound is preferably 20 to 100 mol%, more preferably 35 to 90 mol%, still more preferably 50 to 85 mol%, based on the total amount of the radical polymerization initiator.
- the amount of the radical polymerization initiator used may be 0.05 to 10 mmol per 1 mol of the ethylenically unsaturated monomer.
- the amount of the radical polymerization initiator used is 0.05 mmol or more, the polymerization reaction does not require a long time and is efficient.
- the amount of the radical polymerization initiator used is 10 mmol or less, it is easy to suppress the occurrence of a rapid polymerization reaction.
- the above-mentioned radical polymerization initiator can also be used as a redox polymerization initiator in combination with a reducing agent such as sodium sulfite, sodium hydrogen sulfite, ferrous sulfate, and L-ascorbic acid.
- a reducing agent such as sodium sulfite, sodium hydrogen sulfite, ferrous sulfate, and L-ascorbic acid.
- the monomer aqueous solution used for the polymerization may contain a chain transfer agent.
- chain transfer agent include hypophosphates, thiols, thiolic acids, secondary alcohols, amines and the like.
- the monomer aqueous solution used for polymerization may contain a thickener.
- the thickener include hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, carboxymethyl cellulose, polyethylene glycol, polyacrylamide, polyethyleneimine, dextrin, sodium alginate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene oxide and the like. If the stirring speed at the time of polymerization is the same, the higher the viscosity of the aqueous monomer solution, the larger the medium particle size of the obtained particles tends to be.
- Cross-linking by self-cross-linking may occur during polymerization, but cross-linking may be performed by using an internal cross-linking agent.
- an internal cross-linking agent When an internal cross-linking agent is used, it is easy to control the water absorption characteristics (water retention amount, etc.) of the water-absorbent resin particles.
- the internal cross-linking agent is usually added to the reaction solution during the polymerization reaction.
- the internal cross-linking agent examples include di or tri (meth) acrylic acid esters of polyols such as ethylene glycol, propylene glycol, trimethylpropane, glycerin, polyoxyethylene glycol, polyoxypropylene glycol, and polyglycerin; Unsaturated polyesters obtained by reacting polyols with unsaturated acids (maleic acid, fumaric acid, etc.); bis (meth) acrylamides such as N, N'-methylenebis (meth) acrylamide; polyepoxides and (meth) Di or tri (meth) acrylic acid esters obtained by reacting with acrylic acid; di (meth) obtained by reacting polyisocyanate (tolylene diisocyanate, hexamethylene diisocyanate, etc.) with hydroxyethyl (meth) acrylate.
- polyols such as ethylene glycol, propylene glycol, trimethylpropane, glycerin, polyoxyethylene glycol, polyoxypropy
- Acrylic acid carbamil esters compounds having two or more polymerizable unsaturated groups such as allylated starch, allylated cellulose, diallyl phthalate, N, N', N "-triallyl isocyanurate, divinylbenzene; Poly such as (poly) ethylene glycol diglycidyl ether, (poly) propylene glycol diglycidyl ether, (poly) glycerin diglycidyl ether, (poly) glycerin triglycidyl ether, (poly) propylene glycol polyglycidyl ether, polyglycerol polyglycidyl ether, etc.
- Poly such as (poly) ethylene glycol diglycidyl ether, (poly) propylene glycol diglycidyl ether, (poly) glycerin diglycidyl ether, (poly) glycerin triglycidyl ether, (poly) propylene
- Glycidyl compound such as epichlorohydrin, epibromhydrin, ⁇ -methylepichlorohydrin; 2 reactive functional groups such as isocyanate compound (2,4-tolylene diisocyanate, hexamethylene diisocyanate, etc.) Examples thereof include compounds having more than one.
- the internal cross-linking agent may be used alone or in combination of two or more. As the internal cross-linking agent, a polyglycidyl compound is preferable, and a diglycidyl ether compound is used.
- the amount of the internal cross-linking agent used is from the viewpoint that an excellent permeation rate can be easily obtained in the absorbent article, and the water-soluble property is suppressed by appropriately cross-linking the obtained polymer, so that a sufficient water absorption amount can be obtained.
- 30 mmol or less is preferable, 0.01 to 10 mmol is more preferable, 0.012 to 5 mmol is further preferable, and 0.015 to 1 mmol is particularly preferable, per 1 mol of the ethylenically unsaturated monomer.
- 0.02 to 0.1 mmol is very preferred, and 0.025 to 0.06 mmol is very preferred.
- An ethylenically unsaturated monomer, a radical polymerization initiator, a surfactant, a polymer-based dispersant, a hydrocarbon dispersion medium, etc. (if necessary, an internal cross-linking agent) are mixed and heated under stirring to obtain oil.
- Reversed phase suspension polymerization can be performed in a medium water system.
- a monomer aqueous solution containing an ethylenically unsaturated monomer is used as a hydrocarbon dispersion medium in the presence of a surfactant (more polymer-based dispersant if necessary). Disperse.
- a surfactant more polymer-based dispersant if necessary.
- the timing of adding the surfactant, the polymer-based dispersant, etc. may be either before or after the addition of the aqueous monomer solution, as long as it is before the start of the polymerization reaction.
- the surfactant is prepared after the monomer aqueous solution is dispersed in the hydrocarbon dispersion medium in which the polymer-based dispersant is dispersed. It is preferable to carry out the polymerization after further dispersing the above.
- Reverse phase suspension polymerization can be carried out in one stage or in multiple stages of two or more stages. Reversed phase suspension polymerization is preferably carried out in 2 to 3 steps from the viewpoint of increasing productivity.
- the reaction mixture obtained in the first step polymerization reaction after the first step reverse phase suspension polymerization is subjected to an ethylenically unsaturated single amount.
- the body may be added and mixed, and the reverse phase suspension polymerization of the second and subsequent steps may be carried out in the same manner as in the first step.
- the above-mentioned radical polymerization initiator and / or internal cross-linking agent is used in the reverse phase of each stage of the second and subsequent stages.
- reverse phase suspension polymerization is carried out by adding within the range of the molar ratio of each component to the above-mentioned ethylenically unsaturated monomer.
- An internal cross-linking agent may be used in the reverse phase suspension polymerization in each of the second and subsequent stages, if necessary.
- an internal cross-linking agent it is added within the range of the molar ratio of each component to the above-mentioned ethylenically unsaturated monomer based on the amount of the ethylenically unsaturated monomer provided in each stage, and the suspension is reversed. It is preferable to carry out turbid polymerization.
- the temperature of the polymerization reaction varies depending on the radical polymerization initiator used, but by advancing the polymerization rapidly and shortening the polymerization time, the efficiency is improved and the heat of polymerization is easily removed to carry out the reaction smoothly. From the viewpoint, 20 to 150 ° C. is preferable, and 40 to 120 ° C. is more preferable.
- the reaction time is usually 0.5-4 hours.
- the completion of the polymerization reaction can be confirmed, for example, by stopping the temperature rise in the reaction system. As a result, the polymer of the ethylenically unsaturated monomer is usually obtained in the state of a hydrogel.
- cross-linking may be performed by adding a cross-linking agent to the obtained hydrogel polymer and heating it.
- a cross-linking agent By performing cross-linking after the polymerization, the degree of cross-linking of the hydrogel polymer can be increased and the water absorption characteristics (water retention amount, etc.) can be further improved.
- post-polymerization cross-linking agent examples include polyols such as ethylene glycol, propylene glycol, 1,4-butanediol, trimethylolpropane, glycerin, polyoxyethylene glycol, polyoxypropylene glycol, and polyglycerin; (poly) ethylene glycol diglycidyl ether.
- polyglycidyl compounds such as (poly) ethylene glycol diglycidyl ether, (poly) glycerin diglycidyl ether, (poly) glycerin triglycidyl ether, (poly) propylene glycol polyglycidyl ether, and polyglycerol polyglycidyl ether are preferable. ..
- the cross-linking agent may be used alone or in combination of two or more.
- the amount of the cross-linking agent after polymerization is set per 1 mol of ethylenically unsaturated monomer from the viewpoint that suitable water absorption characteristics (water retention amount, etc.) can be easily obtained by appropriately cross-linking the obtained hydrogel-like polymer. , 30 mmol or less, more preferably 10 mmol or less, further preferably 0.01 to 5 mmol, particularly preferably 0.012 to 1 mmol, extremely preferably 0.015 to 0.1 mmol, 0.02 to 0.02 to 0.05 mmol is highly preferred.
- the timing of adding the cross-linking agent after polymerization may be after the polymerization of the ethylenically unsaturated monomer used for polymerization, and in the case of multi-stage polymerization, it is preferable to add it after multi-stage polymerization.
- the post-polymerization cross-linking agent contains water in consideration of heat generation during and after polymerization, retention due to process delay, opening of the system when the cross-linking agent is added, and fluctuation of water content due to addition of water accompanying the addition of the cross-linking agent. From the viewpoint of rate (described later), it is preferable to add in the region of [moisture content immediately after polymerization ⁇ 3% by mass].
- polymer particles for example, polymer particles having a structural unit derived from an ethylenically unsaturated monomer
- a drying method for example, (a) a hydrogel-like polymer is dispersed in a hydrocarbon dispersion medium, and co-boiling distillation is performed by heating from the outside, and the hydrocarbon dispersion medium is refluxed to remove water.
- Examples thereof include (b) a method of taking out the hydrogel polymer by decantation and drying under reduced pressure, and (c) a method of filtering the hydrogel polymer with a filter and drying under reduced pressure. Above all, it is preferable to use the method (a) because of the simplicity in the manufacturing process.
- the particle size of the water-absorbent resin particles can be adjusted by adjusting the rotation speed of the stirrer during the polymerization reaction, or by adding a flocculant into the system after the polymerization reaction or in the early stage of drying. By adding a flocculant, the particle size of the obtained water-absorbent resin particles can be increased.
- an inorganic flocculant can be used as the flocculant.
- the inorganic flocculant for example, powdered inorganic flocculant
- the aggregating agent is preferably at least one selected from the group consisting of silica, aluminum oxide, talc and kaolin.
- the flocculant is previously dispersed in a hydrocarbon dispersion medium or water of the same type as that used in the polymerization, and then the hydrogel polymer is mixed under stirring.
- a method of mixing in a hydrocarbon dispersion medium containing the mixture is preferable.
- the amount of the flocculant added is preferably 0.001 to 1 part by mass, more preferably 0.005 to 0.5 part by mass, based on 100 parts by mass of the ethylenically unsaturated monomer used for the polymerization. 01 to 0.2 parts by mass is more preferable.
- the amount of the flocculant added is within the above range, water-absorbent resin particles having the desired particle size distribution can be easily obtained.
- surface cross-linking of the surface portion (surface and vicinity of the surface) of the hydrogel polymer is performed using a surface cross-linking agent in the drying step (moisture removing step) or subsequent steps. Is preferable.
- the surface cross-linking is preferably performed at a timing when the hydrogel polymer has a specific water content.
- the time of surface cross-linking is preferably when the water content of the hydrogel polymer is 5 to 50% by mass, more preferably 10 to 40% by mass, and even more preferably 15 to 35% by mass.
- the water content (mass%) of the hydrogel polymer is calculated by the following formula.
- Moisture content [Ww / (Ww + Ws)] x 100
- Ww Necessary when mixing a flocculant, a surface cross-linking agent, etc. to the amount obtained by subtracting the amount of water discharged to the outside of the system by the drying step from the amount of water contained in the monomer aqueous solution before polymerization in the entire polymerization step. The amount of water in the hydrogel polymer to which the amount of water used is added.
- Ws A solid content calculated from the amount of materials such as an ethylenically unsaturated monomer, a cross-linking agent, and an initiator that constitute a hydrogel polymer.
- Examples of the surface cross-linking agent include compounds having two or more reactive functional groups.
- Surface cross-linking agents include polyols such as ethylene glycol, propylene glycol, 1,4-butanediol, trimethylolpropane, glycerin, polyoxyethylene glycol, polyoxypropylene glycol, and polyglycerin; (poly) ethylene glycol diglycidyl ether.
- Examples thereof include an oxazoline compound; a carbonate compound such as ethylene carbonate; and a hydroxyalkylamide compound such as bis [N, N-di ( ⁇ -hydroxyethyl)] adipamide.
- the surface cross-linking agent may be used alone or in combination of two or more.
- a polyglycidyl compound is preferable, and (poly) ethylene glycol diglycidyl ether, (poly) glycerin diglycidyl ether, (poly) glycerin triglycidyl ether, (poly) propylene glycol polyglycidyl ether, and polyglycerol are used. At least one selected from the group consisting of polyglycidyl ether is more preferable.
- the amount of the surface cross-linking agent used is preferably 0.01 to 20 mmol per 1 mol of the ethylenically unsaturated monomer used for polymerization from the viewpoint that suitable water absorption characteristics (water retention amount, etc.) can be easily obtained. It is more preferably 0.05 to 10 mmol, further preferably 0.1 to 5 mmol, particularly preferably 0.15 to 1 mmol, and extremely preferably 0.2 to 0.5 mmol.
- polymer particles which are surface-cross-linked dried products can be obtained by distilling off water and a hydrocarbon dispersion medium by a known method, drying under heating and reduced pressure, and the like.
- the polymerization reaction can be carried out using various stirrers having stirring blades.
- a flat plate blade a lattice blade, a paddle blade, a propeller blade, an anchor blade, a turbine blade, a Faudler blade, a ribbon blade, a full zone blade, a max blend blade and the like can be used.
- the flat plate blade has a shaft (stirring shaft) and a flat plate portion (stirring portion) arranged around the shaft.
- the flat plate portion may have a slit or the like.
- the water-absorbent resin particles according to the present embodiment include, for example, a gel stabilizer and a metal chelating agent (ethylenediaminetetraacetic acid and its salt, diethylenetriamine-5acetic acid and its salt, for example, diethylenetriamine-5sodium acetate and the like).
- a gel stabilizer and a metal chelating agent ethylenediaminetetraacetic acid and its salt, diethylenetriamine-5acetic acid and its salt, for example, diethylenetriamine-5sodium acetate and the like.
- a fluidity improver (lubricant) for polymer particles can be further included. Additional components may be located inside the polymer particles, on the surface of the polymer particles, or both.
- the water-absorbent resin particles may contain a plurality of inorganic particles arranged on the surface of the polymer particles.
- the inorganic particles can be arranged on the surface of the polymer particles.
- the inorganic particles may be silica particles such as amorphous silica.
- the content of the inorganic particles may be in the following range based on the total mass of the polymer particles.
- the content of the inorganic particles may be 0.05% by mass or more, 0.1% by mass or more, 0.15% by mass or more, or 0.2% by mass or more.
- the content of the inorganic particles may be 5.0% by mass or less, 3.0% by mass or less, 1.0% by mass or less, or 0.5% by mass or less.
- the inorganic particles here usually have a minute size as compared with the size of the polymer particles.
- the average particle size of the inorganic particles may be 0.1 to 50 ⁇ m, 0.5 to 30 ⁇ m, or 1 to 20 ⁇ m.
- the average particle size can be measured by the pore electric resistance method or the laser diffraction / scattering method depending on the characteristics of the particles.
- the absorber according to this embodiment contains the water-absorbent resin particles according to this embodiment.
- the absorber according to the present embodiment may contain a fibrous substance, for example, a mixture containing water-absorbent resin particles and the fibrous substance.
- the structure of the absorber may be, for example, a structure in which the water-absorbent resin particles and the fibrous material are uniformly mixed, and the water-absorbent resin particles are sandwiched between the fibrous material formed in a sheet or layer. It may be a configuration or another configuration.
- the fibrous material examples include finely pulverized wood pulp; cotton; cotton linter; rayon; cellulosic fibers such as cellulose acetate; synthetic fibers such as polyamide, polyester and polyolefin; and a mixture of these fibers.
- the fibrous material may be used alone or in combination of two or more.
- hydrophilic fibers can be used as the fibrous material.
- the fibers may be adhered to each other by adding an adhesive binder to the fibrous material.
- the adhesive binder include heat-sealing synthetic fibers, hot melt adhesives, and adhesive emulsions.
- the adhesive binder may be used alone or in combination of two or more.
- the heat-bondable synthetic fiber examples include a total fusion type binder such as polyethylene, polypropylene, and an ethylene-propylene copolymer; a non-total fusion type binder having a side-by-side or core-sheath structure of polypropylene and polyethylene.
- a total fusion type binder such as polyethylene, polypropylene, and an ethylene-propylene copolymer
- non-total fusion type binder having a side-by-side or core-sheath structure of polypropylene and polyethylene.
- hot melt adhesive examples include ethylene-vinyl acetate copolymer, styrene-isoprene-styrene block copolymer, styrene-butadiene-styrene block copolymer, styrene-ethylene-butylene-styrene block copolymer, and styrene-ethylene-propylene-styrene block copolymer.
- a mixture of a base polymer such as amorphous polypropylene and a tackifier, a plasticizer, an antioxidant and the like.
- Examples of the adhesive emulsion include polymers of at least one monomer selected from the group consisting of methyl methacrylate, styrene, acrylonitrile, 2-ethylhexyl acrylate, butyl acrylate, butadiene, ethylene, and vinyl acetate.
- the absorber according to the present embodiment may contain an inorganic powder (for example, amorphous silica), a deodorant, an antibacterial agent, a pigment, a dye, a fragrance, an adhesive and the like.
- an inorganic powder for example, amorphous silica
- the absorber may contain inorganic powder in addition to the inorganic particles in the water-absorbent resin particles.
- the shape of the absorber according to the present embodiment may be, for example, a sheet shape.
- the thickness of the absorber (for example, the thickness of the sheet-shaped absorber) may be 0.1 to 20 mm or 0.3 to 15 mm.
- the content of the water-absorbent resin particles in the absorber is preferably in the following range based on the total mass of the absorber or the total of the water-absorbent resin particles and the fibrous material.
- the content of the water-absorbent resin particles is preferably 2% by mass or more, 10% by mass or more, 20% by mass or more, or 50% by mass or more from the viewpoint of easily obtaining sufficient water absorption characteristics.
- the content of the water-absorbent resin particles is 100% by mass or less, and is preferably 80% by mass or less, 70% by mass or less, or 60% by mass or less from the viewpoint of easily obtaining sufficient water absorption characteristics. From these viewpoints, the content of the water-absorbent resin particles is preferably 2 to 100% by mass, 10 to 80% by mass, 20 to 70% by mass, or 50 to 60% by mass.
- the content of the water-absorbent resin particles in the absorber is preferably 100 to 1000 g, more preferably 150 to 800 g, and even more preferably 200 to 700 g per 1 m 2 of the absorber from the viewpoint of easily obtaining sufficient water absorption characteristics.
- the content of the fibrous substance in the absorber is preferably 50 to 800 g, more preferably 100 to 600 g, and even more preferably 150 to 500 g per 1 m 2 of the absorber from the viewpoint of easily obtaining sufficient water absorption characteristics.
- the absorbent article according to the present embodiment includes an absorber according to the present embodiment.
- a core wrap that retains the shape of the absorber and prevents the constituent member of the absorber from falling off or flowing; the outermost part on the side where the liquid to be absorbed enters.
- Liquid permeable sheet to be arranged Examples thereof include a liquid permeable sheet arranged on the outermost side opposite to the side where the liquid to be absorbed enters.
- absorbent articles include diapers (for example, paper diapers), toilet training pants, incontinence pads, sanitary materials (sanitary napkins, tampons, etc.), sweat pads, pet sheets, toilet members, animal excrement treatment materials, and the like. ..
- FIG. 1 is a cross-sectional view showing an example of an absorbent article.
- the absorbent article 100 shown in FIG. 1 includes an absorbent body 10, core wraps 20a and 20b, a liquid permeable sheet 30, and a liquid permeable sheet 40.
- the liquid permeable sheet 40, the core wrap 20b, the absorbent body 10, the core wrap 20a, and the liquid permeable sheet 30 are laminated in this order.
- the absorber 10 has a water-absorbent resin particle 10a according to the present embodiment and a fiber layer 10b containing a fibrous material.
- the water-absorbent resin particles 10a are dispersed in the fiber layer 10b.
- the core wrap 20a is arranged on one side of the absorber 10 (upper side of the absorber 10 in FIG. 1) in contact with the absorber 10.
- the core wrap 20b is arranged on the other side of the absorber 10 (lower side of the absorber 10 in FIG. 1) in contact with the absorber 10.
- the absorber 10 is arranged between the core wrap 20a and the core wrap 20b.
- Examples of the core wraps 20a and 20b include tissues, non-woven fabrics, woven fabrics, synthetic resin films having liquid permeation holes, net-like sheets having a mesh, and the like.
- the core wrap 20a and the core wrap 20b have, for example, a main surface having the same size as the absorber 10.
- the liquid permeable sheet 30 is arranged on the outermost side on the side where the liquid to be absorbed enters.
- the liquid permeable sheet 30 is arranged on the core wrap 20a in contact with the core wrap 20a.
- Examples of the liquid permeable sheet 30 include non-woven fabrics made of synthetic resins such as polyethylene, polypropylene, polyester and polyamide, and porous sheets.
- the liquid permeable sheet 40 is arranged on the outermost side of the absorbent article 100 on the opposite side of the liquid permeable sheet 30.
- the liquid permeable sheet 40 is arranged under the core wrap 20b in contact with the core wrap 20b.
- liquid impermeable sheet 40 examples include a sheet made of a synthetic resin such as polyethylene, polypropylene, and polyvinyl chloride, and a sheet made of a composite material of these synthetic resins and a non-woven fabric.
- the liquid permeable sheet 30 and the liquid permeable sheet 40 have, for example, a main surface wider than the main surface of the absorber 10, and the outer edges of the liquid permeable sheet 30 and the liquid permeable sheet 40 are It extends around the absorber 10 and the core wraps 20a, 20b.
- the magnitude relationship between the absorbent body 10, the core wraps 20a and 20b, the liquid permeable sheet 30, and the liquid permeable sheet 40 is not particularly limited, and is appropriately adjusted according to the use of the absorbent article and the like. Further, the method of retaining the shape of the absorber 10 by using the core wraps 20a and 20b is not particularly limited, and as shown in FIG. 1, the absorber may be wrapped by a plurality of core wraps, and the absorber is wrapped by one core wrap. It may be.
- the absorber may be adhered to the top sheet.
- a hot melt adhesive is applied to the top sheet at predetermined intervals in a striped shape, a spiral shape, etc. in the width direction and adhered; starch, carboxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, etc. Examples thereof include a method of adhering using a water-soluble binder such as a water-soluble polymer.
- a method of adhering by heat-sealing of the heat-sealing synthetic fibers may be adopted.
- the liquid absorbing method according to the present embodiment includes a step of bringing the liquid to be absorbed into contact with the water-absorbent resin particles, the absorber or the absorbent article according to the present embodiment.
- the present embodiment is a method for adjusting the permeation rate (permeation rate of a liquid) in an absorbent article, and is a method for adjusting the permeation rate using the water-absorbent resin particles, an absorber or the absorbent article according to the present embodiment.
- the method for adjusting the permeation rate according to the present embodiment includes an adjusting step for adjusting the gel flow rate measured by the above-mentioned procedures (1) to (3) for the water-absorbent resin particles according to the present embodiment.
- the gel flow rate can be adjusted to each of the above ranges (for example, 10 to 70 g / min).
- the water-absorbing resin particles according to the present embodiment include a selection step of selecting the water-absorbent resin particles based on the gel flow rate measured by the above-mentioned procedures (1) to (3).
- a method for producing sex resin particles can be provided.
- the gel flow rate can be adjusted to each of the above ranges (for example, 10 to 70 g / min).
- the present embodiment it is possible to provide a method for producing an absorber using the water-absorbent resin particles obtained by the above-mentioned method for producing water-absorbent resin particles.
- the method for producing an absorber according to the present embodiment includes a particle manufacturing step for obtaining water-absorbent resin particles by the above-mentioned method for producing water-absorbent resin particles.
- the method for producing an absorber according to the present embodiment may include a step of mixing the water-absorbent resin particles and the fibrous material after the particle manufacturing step. According to the present embodiment, it is possible to provide a method for producing an absorbent article using the absorber obtained by the above-mentioned method for producing an absorber.
- the method for producing an absorbent article according to the present embodiment includes an absorber manufacturing step for obtaining an absorber by the above-mentioned method for manufacturing an absorber.
- the method for producing an absorbent article according to the present embodiment may include a step of obtaining an absorbent article by using the absorber and other constituent members of the absorbent article after the absorbent body manufacturing step. For example, an absorbent article is obtained by laminating the absorber and other constituent members of the absorbent article with each other.
- Example 1 A round-bottomed cylindrical separable flask having an inner diameter of 11 cm and an internal volume of 2 L equipped with a reflux condenser, a dropping funnel, a nitrogen gas introduction pipe, and a stirrer was prepared.
- the stirrer was equipped with a stirrer blade (flat blade) 200 whose outline is shown in FIG.
- the stirring blade 200 includes a shaft 200a and a flat plate portion 200b.
- the flat plate portion 200b is welded to the shaft 200a and has a curved tip.
- the flat plate portion 200b is formed with four slits S extending along the axial direction of the shaft 200a.
- the four slits S are arranged in the width direction of the flat plate portion 200b, the width of the two inner slits S is 1 cm, and the width of the two outer slits S is 0.5 cm.
- the length of the flat plate portion 200b is about 10 cm, and the width of the flat plate portion 200b is about 6 cm.
- 293 g of n-heptane was added as a hydrocarbon dispersion medium to the above-mentioned separable flask, and a maleic anhydride-modified ethylene-propylene copolymer (manufactured by Mitsui Chemicals Co., Ltd., High Wax 1105A) was added as a polymer-based dispersant.
- a mixture was obtained by adding 0.736 g.
- the dispersant was dissolved by heating the mixture to 80 ° C. with stirring, and then the mixture was cooled to 50 ° C.
- hydroxylethyl cellulose manufactured by Sumitomo Seika Co., Ltd., HEC AW-15F
- 2,2'-azobis (2-amidinopropane) dihydrochloride as a water-soluble radical polymerization initiator.
- 0.018 g (0.067 mmol) of potassium persulfate, and 0.0046 g (0.026 mmol) of ethylene glycol diglycidyl ether as an internal cross-linking agent are added and dissolved to dissolve the first step.
- An aqueous solution was prepared.
- the above-mentioned first-stage aqueous solution was added to the above-mentioned separable flask while stirring at a stirring speed of 425 rpm, and then the mixture was stirred for 10 minutes. Then, it was obtained by heating and dissolving 0.736 g of sucrose stearic acid ester (surfactant, manufactured by Mitsubishi Chemical Foods Co., Ltd., Ryoto Sugar Ester S-370, HLB value: 3) in 6.62 g of n-heptane. The detergent solution was added to the separable flask. Then, the inside of the system was sufficiently replaced with nitrogen while stirring at a stirring speed of 425 rpm. Then, the flask was immersed in a water bath at 70 ° C. to raise the temperature, and polymerization was carried out for 60 minutes to obtain a first-stage polymerization slurry solution.
- sucrose stearic acid ester surfactant, manufactured by Mitsubishi Chemical Foods Co., Ltd., Ryoto Sugar Este
- the inside of the separable flask described above was cooled to 25 ° C. while stirring at a stirring speed of 650 rpm, and then the entire amount of the aqueous solution of the second stage described above was added to the polymerized slurry solution of the first stage described above. Was added to. Subsequently, after replacing the inside of the system with nitrogen for 30 minutes, the flask was again immersed in a water bath at 70 ° C. to raise the temperature, and the polymerization reaction was carried out for 60 minutes to obtain a second-stage hydrogel polymer. It was.
- n-heptane was evaporated at 125 ° C. and dried to obtain polymer particles (dried product).
- polymer particles dried product
- 0.2% by mass of amorphous silica (Tokuseal NP-S manufactured by Oriental Silicas Corporation) is weighted based on the total mass of the polymer particles.
- amorphous silica Tokuseal NP-S manufactured by Oriental Silicas Corporation
- Example 2 In the hydrogel polymer after the second stage polymerization, 231.0 g of water-absorbent resin particles were obtained in the same manner as in Example 1 except that 224.3 g of water was extracted from the system by azeotropic distillation. Obtained. The medium particle size of the water-absorbent resin particles was 342 ⁇ m.
- Example 3 In the hydrogel polymer after the second stage polymerization, 232.1 g of water-absorbent resin particles were obtained in the same manner as in Example 1 except that 234.6 g of water was extracted from the system by azeotropic distillation. Obtained. The medium particle size of the water-absorbent resin particles was 355 ⁇ m.
- 0.010 g (0.057 mmol) of ethylene glycol diglycidyl ether was used as the internal cross-linking agent, the rotation speed of the stirrer was changed to 550 rpm in the preparation of the polymerized slurry liquid in the first stage, and the second stage.
- 0.090 g (0.333 mmol) of potassium persulfate was used without using 2,2'-azobis (2-amidinopropane) dihydrochloride as the water-soluble radical polymerization initiator, and the inside was used.
- Comparative Example 2 In the hydrogel polymer after the second stage polymerization, 253.9 g of water was extracted from the system by co-boiling distillation, and 0.1% by mass of amorphous was amorphous with respect to the mass of the polymer particles. 230.8 g of water-absorbent resin particles were obtained in the same manner as in Comparative Example 1 except that quality silica was mixed with the polymer particles. The medium particle size of the water-absorbent resin particles was 360 ⁇ m.
- hydroxylethyl cellulose manufactured by Sumitomo Seika Co., Ltd., HEC AW-15F
- 2,2'-azobis (2-amidinopropane) dihydrochloride 0 as a water-soluble radical polymerization initiator.
- the aqueous solution of the first stage was prepared by dissolving.
- the above-mentioned first-stage aqueous solution was added to the above-mentioned separable flask while stirring at a stirring speed of 550 rpm, and then the mixture was stirred for 10 minutes. Then, it was obtained by heating and dissolving 0.74 g of sucrose stearic acid ester (surfactant, manufactured by Mitsubishi Chemical Foods Co., Ltd., Ryoto Sugar Ester S-370, HLB value: 3) in 6.66 g of n-heptane. It was added to 7.4 g of a surfactant solution. Then, the inside of the system was sufficiently replaced with nitrogen while stirring at a stirring speed of 550 rpm. Then, the flask was immersed in a water bath at 70 ° C. to raise the temperature, and polymerization was carried out for 60 minutes to obtain a first-stage polymerization slurry solution.
- sucrose stearic acid ester surfactant, manufactured by Mitsubishi Chemical Foods Co., Ltd., Ryoto Sugar
- a water-soluble radical polymerization initiator 0.155 g (0.570 mmol) of 2,2'-azobis (2-amidinopropane) dihydrochloride and 0.013 g (0.048 mmol) of potassium persulfate were internally crosslinked.
- a second-stage aqueous solution was prepared by adding 0.009 g (0.052 mmol) of ethylene glycol diglycidyl ether as an agent and 12.5 g of ion-exchanged water and then dissolving the mixture.
- the inside of the separable flask described above was cooled to 25 ° C. while stirring at a rotation speed of 1000 rpm of the stirrer, and then the entire amount of the aqueous solution of the second stage described above was added to the polymerization slurry solution of the first stage described above. Was added to. Subsequently, after the inside of the system was sufficiently replaced with nitrogen, the flask was again immersed in a water bath at 70 ° C. to raise the temperature, and the second-stage polymerization was carried out for 30 minutes.
- the temperature of the second-stage reaction solution was raised in an oil bath at 125 ° C., and 245 g of water was removed from the system while refluxing n-heptane by azeotropic distillation of n-heptane and water. I pulled it out. Then, polymer particles (dried product) were obtained by evaporating n-heptane and drying it. The polymer particles were passed through a sieve having an opening of 1000 ⁇ m to obtain 233.2 g of water-absorbent resin particles. The medium particle size of the water-absorbent resin particles was 370 ⁇ m.
- the above-mentioned medium particle size of the water-absorbent resin particles was measured by the following procedure. That is, from the top, the JIS standard sieve has a mesh size of 600 ⁇ m, a mesh size of 500 ⁇ m, a mesh size of 425 ⁇ m, a mesh size of 300 ⁇ m, a mesh size of 250 ⁇ m, a mesh size of 180 ⁇ m, and a mesh size of 150 ⁇ m. , And the saucer in that order. 50 g of water-absorbent resin particles were placed in the best combined sieve and classified according to JIS Z 8815 (1994) using a low-tap shaker (manufactured by Iida Seisakusho Co., Ltd.).
- the mass of the particles remaining on each sieve was calculated as a mass percentage with respect to the total amount, and the particle size distribution was obtained.
- the relationship between the mesh size of the sieve and the integrated value of the mass percentage of the particles remaining on the sieve was plotted on a logarithmic probability paper by integrating on the sieve in order from the one having the largest particle size with respect to this particle size distribution. By connecting the plots on the probability paper with a straight line, the particle size corresponding to the cumulative mass percentage of 50% by mass was obtained as the medium particle size.
- the water retention amount (room temperature, 25 ⁇ 2 ° C.) of the physiological saline of the water-absorbent resin particles was measured by the following procedure. First, a cotton bag (Membrod No. 60, width 100 mm ⁇ length 200 mm) weighing 2.0 g of water-absorbent resin particles was placed in a beaker having an internal volume of 500 mL. After pouring 500 g of physiological saline into a cotton bag containing water-absorbent resin particles at a time so that maco cannot be formed, tie the upper part of the cotton bag with a rubber band and let it stand for 30 minutes to swell the water-absorbent resin particles.
- the measuring device Y is composed of a burette unit 61, a conduit 62, a measuring table 63, and a measuring unit 64 placed on the measuring table 63.
- the burette portion 61 has a burette 61a extending in the vertical direction, a rubber stopper 61b arranged at the upper end of the burette 61a, a cock 61c arranged at the lower end of the burette 61a, and one end extending into the burette 61a in the vicinity of the cock 61c. It has an air introduction pipe 61d and a cock 61e arranged on the other end side of the air introduction pipe 61d.
- the conduit 62 is attached between the burette portion 61 and the measuring table 63.
- the inner diameter of the conduit 62 is 6 mm.
- a hole having a diameter of 2 mm is formed in the central portion of the measuring table 63, and the conduit 62 is connected to the hole.
- the measuring unit 64 has a cylinder 64a (made of acrylic resin), a nylon mesh 64b adhered to the bottom of the cylinder 64a, and a weight 64c.
- the inner diameter of the cylinder 64a is 20 mm.
- the opening of the nylon mesh 64b is 75 ⁇ m (200 mesh).
- the water-absorbent resin particles 66 to be measured are uniformly sprinkled on the nylon mesh 64b.
- the diameter of the weight 64c is 19 mm, and the mass of the weight 64c is 119.6 g.
- the weight 64c is placed on the water-absorbent resin particles 66, and a load of 4.14 kPa can be applied to the water-absorbent resin particles 66.
- the scale of the burette 61a is engraved from top to bottom in increments of 0 mL to 0.5 mL, and the scale Va of the burette 61a before the start of water absorption and the burette 61a 120 minutes after the start of water absorption are used as the water level of the physiological saline.
- ⁇ Gel flow rate> (Preparation of swelling gel) 398 g of ion-exchanged water was weighed into a beaker having an internal volume of 1000 mL. Next, while stirring the ion-exchanged water at 1000 rpm using a magnetic stirrer bar (8 mm ⁇ ⁇ 30 mm, without ring), 2.0 g of water-absorbent resin particles were added to the ion-exchanged water (room temperature (25 ° C ⁇ ) so that maco could not be formed. 2 ° C.)). The mixture was allowed to stand for 30 minutes while continuing stirring, and the water-absorbent resin particles were sufficiently swollen to obtain a swollen gel.
- the gel flow rate (fluidity of swollen gel, room temperature (25 ° C ⁇ 2 ° C)) was measured using the measuring device Z shown in FIG.
- the measuring device Z includes a funnel 71, a damper 73, a cylinder 75, and a receiver 77.
- the funnel 71 has a supply port (upper end opening; diameter (inner diameter): 91 mm) for supplying the swelling gel and a discharge port (lower end opening. Diameter (inner diameter): 8 mm) for discharging the swelling gel as openings. It has a tapered shape that narrows from the supply port to the discharge port.
- the inclination angle of the side wall of the funnel 71 is 20 ° with respect to the axial direction of the funnel 71.
- the length from the supply port to the discharge port in the funnel 71 is 114 mm.
- the axially perpendicular cross section of the funnel 71 including the supply port and the discharge port is circular.
- the constituent material of the funnel 71 is stainless steel.
- the funnel 71 is fixed by gripping the outer peripheral portion on the supply port side with a support ring.
- the damper 73 is a member having a length of 47 mm and a width of 15 mm.
- the damper 73 is arranged at the discharge port of the funnel 71, and opens and closes the discharge port of the funnel 71.
- the cylinder 75 is a member having a length of 35 mm and an inner diameter of 20 mm.
- the cylinder 75 is arranged on the discharge port side of the funnel 71 so that the portion on the discharge port side of the funnel 71 is located inside.
- the receiver 77 is a beaker (manufactured by Sampler Tech Co., Ltd., sampler cup 500 mL) having an internal volume of 500 mL.
- ⁇ Making absorbent articles> Using an airflow type mixer (Padformer manufactured by Otec Co., Ltd.), 10 g of water-absorbent resin particles and 6.8 g of crushed pulp are uniformly mixed by air papermaking to form a sheet having a size of 40 cm x 12 cm. An absorber was prepared. Next, with two sheets of tissue paper having a basis weight of 16 g / m 2 having the same size as the sheet-shaped absorber sandwiching the upper and lower sides of the absorber, a load of 196 kPa is applied to the whole for 30 seconds and pressed. To obtain a laminate. Further, an absorbent article was prepared by arranging an air-through type porous liquid permeable sheet made of polyethylene-polypropylene having a basis weight of 22 g / m 2 having the same size as the absorber on the upper surface of the laminate.
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Abstract
Description
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。
含水率=[Ww/(Ww+Ws)]×100
Ww:全重合工程の重合前の単量体水溶液に含まれる水分量から、乾燥工程により系外部に排出された水分量を差し引いた量に、凝集剤、表面架橋剤等を混合する際に必要に応じて用いられる水分量を加えた含水ゲル状重合体の水分量。
Ws:含水ゲル状重合体を構成するエチレン性不飽和単量体、架橋剤、開始剤等の材料の仕込量から算出される固形分量。
(実施例1)
還流冷却器、滴下ロート、窒素ガス導入管、及び、撹拌機を備えた内径11cm、内容積2Lの丸底円筒型セパラブルフラスコを準備した。撹拌機には、図2に概形を示す撹拌翼(平板翼)200を取り付けた。撹拌翼200は、軸200a及び平板部200bを備えている。平板部200bは、軸200aに溶接されていると共に、湾曲した先端を有している。平板部200bには、軸200aの軸方向に沿って延びる4つのスリットSが形成されている。4つのスリットSは平板部200bの幅方向に配列されており、内側の二つのスリットSの幅は1cmであり、外側二つのスリットSの幅は0.5cmである。平板部200bの長さは約10cmであり、平板部200bの幅は約6cmである。続いて、上述のセパラブルフラスコに、炭化水素分散媒としてn-ヘプタン293gを添加し、高分子系分散剤として無水マレイン酸変性エチレン・プロピレン共重合体(三井化学株式会社製、ハイワックス1105A)0.736gを添加することにより混合物を得た。この混合物を撹拌しつつ80℃まで昇温することにより分散剤を溶解した後、混合物を50℃まで冷却した。
第2段目の重合後の含水ゲル状重合体において、共沸蒸留により224.3gの水を系外へ抜き出したこと以外は、実施例1と同様にして、吸水性樹脂粒子231.0gを得た。吸水性樹脂粒子の中位粒子径は342μmであった。
第2段目の重合後の含水ゲル状重合体において、共沸蒸留により234.6gの水を系外へ抜き出したこと以外は、実施例1と同様にして、吸水性樹脂粒子232.1gを得た。吸水性樹脂粒子の中位粒子径は355μmであった。
無水マレイン酸変性エチレン・プロピレン共重合体を溶解させる際に、撹拌機として、平板翼に代えて、翼径5cmの4枚傾斜パドル翼を2段有する撹拌翼を用いたこと、第1段目の水性液の調製において、水溶性ラジカル重合開始剤として2,2’-アゾビス(2-アミジノプロパン)2塩酸塩を用いずに、過硫酸カリウム0.0736g(0.272ミリモル)を用いると共に、内部架橋剤としてエチレングリコールジグリシジルエーテル0.010g(0.057ミリモル)を用いたこと、第1段目の重合スラリー液の調製において撹拌機の回転数を550rpmへ変更したこと、第2段目の水性液の調製において、水溶性ラジカル重合開始剤として2,2’-アゾビス(2-アミジノプロパン)2塩酸塩を用いずに、過硫酸カリウム0.090g(0.333ミリモル)を用いると共に内部架橋剤としてエチレングリコールジグリシジルエーテル0.0117g(0.067ミリモル)を用いたこと、第2段目の水性液の全量を第1段目の重合スラリー液に添加する際の撹拌機の回転数を1000rpmへ変更したこと、第2段目の重合後の含水ゲル状重合体に添加する45質量%のジエチレントリアミン5酢酸5ナトリウム水溶液の使用量を0.265gへ変更すると共に、共沸蒸留により247.9gの水を系外へ抜き出したこと、及び、重合体粒子の質量に対して0.5質量%の非晶質シリカを重合体粒子と混合したこと以外は、実施例1と同様にして、吸水性樹脂粒子231.0gを得た。吸水性樹脂粒子の中位粒子径は355μmであった。
第2段目の重合後の含水ゲル状重合体において、共沸蒸留により253.9gの水を系外へ抜き出したこと、及び、重合体粒子の質量に対して0.1質量%の非晶質シリカを重合体粒子と混合したこと以外は、比較例1と同様にして、吸水性樹脂粒子230.8gを得た。吸水性樹脂粒子の中位粒子径は360μmであった。
第2段目の重合後の含水ゲル状重合体において、共沸蒸留により271.4gの水を系外へ抜き出したこと、及び、当該共沸蒸留の後に添加する2質量%のエチレングリコールジグリシジルエーテル水溶液の使用量を6.40g(0.735ミリモル)へ変更したこと以外は、比較例1と同様にして、吸水性樹脂粒子230.6gを得た。吸水性樹脂粒子の中位粒子径は355μmであった。
第2段目の重合後の含水ゲル状重合体において、共沸蒸留により278.9gの水を系外へ抜き出したこと、及び、重合体粒子の質量に対して0.2質量%の非晶質シリカを重合体粒子と混合したこと以外は、比較例1と同様にして、吸水性樹脂粒子230.8gを得た。吸水性樹脂粒子の中位粒子径は358μmであった。
還流冷却器、滴下ロート、窒素ガス導入管、及び、撹拌機(翼径5cmの4枚傾斜パドル翼を2段有する撹拌翼)を備えた内径11cm、内容積2Lの丸底円筒型セパラブルフラスコを準備した。このフラスコに、炭化水素分散媒としてn-ヘプタン300gを添加し、高分子系分散剤として無水マレイン酸変性エチレン・プロピレン共重合体(三井化学株式会社製、ハイワックス1105A)0.74gを添加することにより混合物を得た。この混合物を撹拌しつつ分散剤を加温溶解した後、混合物を50℃まで冷却した。
吸水性樹脂粒子の上述の中位粒子径は下記手順により測定した。すなわち、JIS標準篩を上から、目開き600μmの篩、目開き500μmの篩、目開き425μmの篩、目開き300μmの篩、目開き250μmの篩、目開き180μmの篩、目開き150μmの篩、及び、受け皿の順に組み合わせた。組み合わせた最上の篩に、吸水性樹脂粒子50gを入れ、ロータップ式振とう器(株式会社飯田製作所製)を用いてJIS Z 8815(1994)に準じて分級した。分級後、各篩上に残った粒子の質量を全量に対する質量百分率として算出し粒度分布を求めた。この粒度分布に関して粒子径の大きい方から順に篩上を積算することにより、篩の目開きと篩上に残った粒子の質量百分率の積算値との関係を対数確率紙にプロットした。確率紙上のプロットを直線で結ぶことにより、積算質量百分率50質量%に相当する粒子径を中位粒子径として得た。
吸水性樹脂粒子の生理食塩水の保水量(室温、25±2℃)を下記手順で測定した。まず、吸水性樹脂粒子2.0gを量り取った綿袋(メンブロード60番、横100mm×縦200mm)を内容積500mLのビーカー内に設置した。吸水性樹脂粒子の入った綿袋内に生理食塩水500gを、ママコができないように一度に注ぎ込んだ後、綿袋の上部を輪ゴムで縛り、30分静置させることで吸水性樹脂粒子を膨潤させた。30分経過後の綿袋を、遠心力が167Gとなるように設定した脱水機(株式会社コクサン製、品番:H-122)を用いて1分間脱水した後、脱水後の膨潤ゲルを含んだ綿袋の質量Wa[g]を測定した。吸水性樹脂粒子を添加せずに同様の操作を行い、綿袋の湿潤時の空質量Wb[g]を測定し、下記式から吸水性樹脂粒子の生理食塩水の保水量を算出した。結果を表1に示す。
保水量[g/g]=(Wa-Wb)/2.0
吸水性樹脂粒子の荷重下の生理食塩水の吸水量(室温、25℃±2℃)を、図3に示す測定装置Yを用いて測定した。測定装置Yは、ビュレット部61、導管62、測定台63、及び、測定台63上に置かれた測定部64から構成される。ビュレット部61は、鉛直方向に伸びるビュレット61aと、ビュレット61aの上端に配置されたゴム栓61bと、ビュレット61aの下端に配置されたコック61cと、コック61cの近傍において一端がビュレット61a内に伸びる空気導入管61dと、空気導入管61dの他端側に配置されたコック61eとを有している。導管62は、ビュレット部61と測定台63との間に取り付けられている。導管62の内径は6mmである。測定台63の中央部には、直径2mmの穴があいており、導管62が連結されている。測定部64は、円筒64a(アクリル樹脂製)と、円筒64aの底部に接着されたナイロンメッシュ64bと、重り64cとを有している。円筒64aの内径は20mmである。ナイロンメッシュ64bの目開きは75μm(200メッシュ)である。そして、測定時にはナイロンメッシュ64b上に測定対象の吸水性樹脂粒子66が均一に撒布される。重り64cの直径は19mmであり、重り64cの質量は119.6gである。重り64cは、吸水性樹脂粒子66上に置かれ、吸水性樹脂粒子66に対して4.14kPaの荷重を加えることができる。
荷重下の吸水量[mL/g]=(Vb-Va)/0.1
(膨潤ゲルの作製)
内容積1000mLのビーカーにイオン交換水398gを量り取った。次に、マグネチックスターラーバー(8mmφ×30mm、リング無し)を用いて1000rpmでイオン交換水を撹拌させながら、ママコができないように吸水性樹脂粒子2.0gをイオン交換水(室温(25℃±2℃))に分散させた。撹拌を続けながら30分間放置し、吸水性樹脂粒子を充分に膨潤させて膨潤ゲルを得た。
ゲルフローレート[g/min]=ゲルフロー量[g]/3[min]
気流型混合装置(有限会社オーテック社製、パッドフォーマー)を用いて、吸水性樹脂粒子10g及び粉砕パルプ6.8gを空気抄造によって均一混合することにより、40cm×12cmの大きさのシート状の吸収体を作製した。次に、シート状の吸収体と同じ大きさを有する坪量16g/m2の2枚のティッシュッペーパーで吸収体の上下を挟んだ状態で全体に196kPaの荷重を30秒間加えてプレスすることにより積層体を得た。さらに、吸収体と同じ大きさを有する坪量22g/m2のポリエチレン-ポリプロピレン製のエアスルー型多孔質液体透過性シートを積層体の上面に配置することにより吸収性物品を作製した。
温度25±2℃の室内において、水平の台の上に吸収性物品を配置した。次に、内径3cmの投入口を有する容量100mLの液投入用シリンダー(両端が開口した円筒)を吸収性物品の主面の中心部に置いた。続いて、あらかじめ少量の青色1号で着色して25±1℃に調整した生理食塩水80mLをシリンダー内に一度に投入した(鉛直方向から供給した)。ストップウォッチを用いて、投入開始から、生理食塩水がシリンダー内から完全に消失するまでの吸収時間を測定した。この操作を30分間隔で更に2回(計3回)行い、3回目の吸収時間を浸透速度[秒]として得た。浸透速度は短い方が好ましい。結果を表1に示す。
Claims (9)
- 下記(1)~(3)の手順により測定されるゲルフローレートが10~70g/minである、吸水性樹脂粒子。
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。 - 荷重4.14kPa下における生理食塩水の吸水量が10~40mL/gである、請求項1に記載の吸水性樹脂粒子。
- (メタ)アクリル酸及びその塩からなる群より選ばれる少なくとも一種に由来する構造単位を有する、請求項1又は2に記載の吸水性樹脂粒子。
- 請求項1~3のいずれか一項に記載の吸水性樹脂粒子を含有する、吸収体。
- 前記吸水性樹脂粒子の含有量が当該吸収体の全質量を基準として50質量%以上である、請求項4に記載の吸収体。
- 請求項4又は5に記載の吸収体を備える、吸収性物品。
- おむつである、請求項6に記載の吸収性物品。
- 下記(1)~(3)の手順により測定されるゲルフローレートに基づき吸水性樹脂粒子を選定する工程を備える、吸水性樹脂粒子の製造方法。
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。 - 吸収体を備える吸収性物品における浸透速度の調整方法であって、
前記吸収体が吸水性樹脂粒子を含有し、
当該調整方法が、下記(1)~(3)の手順により測定されるゲルフローレートを調整する工程を備える、浸透速度の調整方法。
(1)前記吸水性樹脂粒子1質量部及び水199質量部を混合することによりゲルを得る。
(2)ロートにおける直径8mmの円形の下端開口を閉止した状態で前記ロートに前記ゲルを収容する。
(3)前記下端開口を開放して3分経過したときの前記ゲルの単位時間あたりの流出量を前記ゲルフローレートとして測定する。
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