WO2020058748A1 - Tôle d'acier laminée à froid et revêtue et son procédé de fabrication - Google Patents

Tôle d'acier laminée à froid et revêtue et son procédé de fabrication Download PDF

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Publication number
WO2020058748A1
WO2020058748A1 PCT/IB2018/057253 IB2018057253W WO2020058748A1 WO 2020058748 A1 WO2020058748 A1 WO 2020058748A1 IB 2018057253 W IB2018057253 W IB 2018057253W WO 2020058748 A1 WO2020058748 A1 WO 2020058748A1
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Prior art keywords
steel sheet
cold rolled
temperature
coated steel
anyone
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Application number
PCT/IB2018/057253
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English (en)
Inventor
Samaneh ALIBEIGI
Original Assignee
Arcelormittal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arcelormittal filed Critical Arcelormittal
Priority to PCT/IB2018/057253 priority Critical patent/WO2020058748A1/fr
Priority to US17/276,240 priority patent/US20220033925A1/en
Priority to PL19772880.1T priority patent/PL3853387T3/pl
Priority to HUE19772880A priority patent/HUE062231T2/hu
Priority to MX2021003290A priority patent/MX2021003290A/es
Priority to MA53640A priority patent/MA53640B1/fr
Priority to JP2021515544A priority patent/JP7422143B2/ja
Priority to EP19772880.1A priority patent/EP3853387B1/fr
Priority to CA3110629A priority patent/CA3110629C/fr
Priority to UAA202102067A priority patent/UA126725C2/uk
Priority to FIEP19772880.1T priority patent/FI3853387T3/fi
Priority to CN201980059157.2A priority patent/CN112689684B/zh
Priority to KR1020217011078A priority patent/KR102647462B1/ko
Priority to BR112021003583-4A priority patent/BR112021003583A2/pt
Priority to ES19772880T priority patent/ES2946086T3/es
Priority to PCT/IB2019/057795 priority patent/WO2020058829A1/fr
Publication of WO2020058748A1 publication Critical patent/WO2020058748A1/fr
Priority to ZA2021/01225A priority patent/ZA202101225B/en

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
    • B21C47/02—Winding-up or coiling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/12—Aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the present invention relates to cold rolled and coated steel sheets suitable for use as steel sheet for automobiles.
  • Automotive parts are required to satisfy two inconsistent necessities, viz. ease of forming and strength but in recent years a third requirement of improvement in fuel consumption is also bestowed upon automobiles in view of global environment concerns.
  • automotive parts must be made of material having high formability in order that to fit in the criteria of ease of fit in the intricate automobile assembly and at same time have to improve strength for vehicle crashworthiness and durability while reducing weight of vehicle to improve fuel efficiency.
  • US20140234657 is a patent application that claims for a hot-dip galvanized steel sheet having a microstructure, by volume fraction, equal to or more than 20% and equal to or less than 99% in total of one or two of martensite and bainite, a residual structure contains one or two of ferrite, residual austenite of less than 8% by volume fraction, and pearlite of equal to or less than 10% by volume fraction. Further US20140234657 reaches to a tensile strength of 980 MPa but unable to reaches the elongation of 25%. US8657969 claims for high strength galvanized steel sheet has a Tensile Strength of 590 MPa or more and excellent processability.
  • the component composition contains, by mass %, C: 0.05% to 0.3%, Si: 0.7% to 2.7%, Mn: 0.5% to 2.8%, P: 0.1 % or lower, S: 0.01 % or lower, Al: 0.1 % or lower, and N: 0.008% or lower, and the balance: Fe or inevitable impurities.
  • the microstructure contains, in terms of area ratio, ferrite phases: 30% to 90%, bainite phases: 3% to 30%, and martensite phases: 5% to 40%, in which, among the martensite phases, martensite phases having an aspect ratio of 3 or more are present in a proportion of 30% or more.
  • the purpose of the present invention is to solve these problems by making available cold-rolled steel and coated sheets that simultaneously have:
  • the steel sheets according to the invention may also present a yield strength 320 MPa or more
  • the steel sheets according to the invention may also present a yield strength to tensile strength ratio of 0.6 or more
  • such steel can also have a good suitability for forming, in particular for rolling with good weldability and coatability.
  • Another object of the present invention is also to make available a method for the manufacturing of these sheets that is compatible with conventional industrial applications while being robust towards manufacturing parameters shifts.
  • the cold rolled and heat treated steel sheet of the present invention may optionally be coated with zinc or zinc alloys, or with aluminium or aluminium alloys to improve its corrosion resistance.
  • Carbon is present in the steel between 0.13% and 0.18%. Carbon is an element necessary for increasing the strength of the steel sheet by producing low- temperature transformation phases such as bainite, further Carbon also plays a pivotal role in Austenite stabilization hence a necessary element for securing Residual Austenite. Therefore, Carbon plays two pivotal roles one in increasing the strength and another in retaining austenite to impart ductility.
  • Manganese content of the steel of present invention is between 1.1 % and 1.8%. This element is gammagenous.
  • the purpose of adding Manganese is essentially to obtain a structure that contains Austenite and impart strength to the steel. An amount of at least 1.1 % by weight of Manganese has been found in order to provide the strength and hardenability of the steel sheet as well as to stabilize Austenite. But when Manganese content is more than 1.8% it produces adverse effects such as it retards transformation of Austenite to Bainite during the over aging holding for Bainite transformation. In addition the Manganese content of above 1.8% also reduces the ductility and also deteriorates the weldability of the present steel hence the elongation targets may not be achieved.
  • a preferable content for the present invention may be kept between 1.2% and 1.8%, further more preferably 1.3% and 1.7%.
  • Silicon content of the steel of present invention is between 0.5% and 0.9%. Silicon is a constituent that can retard the precipitation of carbides during overageing, therefore, due to the presence of Silicon, carbon rich Austenite is stabilized at room temperature. Further, due to poor solubility of Silicon in carbide it effectively inhibits or retards the formation of carbides, hence also promotes the formation of Bainitic structure which is sought as per the present invention to impart steel with its essential features. However, disproportionate content of Silicon does not produce the mentioned effect and leads to a problem such as temper embrittlement. Therefore, the concentration is controlled within an upper limit of 0.9%.
  • a preferable content for the present invention may be kept between 0.6% and 0.8%
  • Aluminum is an essential element and is present in the steel between 0.6% and 1 %.
  • Aluminum is an alphagenous element and imparts total elongation to the steel of present invention.
  • a minimum of 0.6% of Aluminum is required to have a minimum Ferrite thereby imparting the elongation to the steel of present invention.
  • Aluminum is also used for removing oxygen from the molten state of the steel to clean steel of present invention by and it also prevents oxygen from forming a gas phase. But whenever the Aluminum is more than 1 % it forms AIN which is detrimental for the steel of Present invention therefore preferable range for the presence of the Aluminum is between 0.6% and 0.8%.
  • Phosphorus constituent of the steel of present invention is between 0.002% and 0.02%. Phosphorus reduces the spot weldability and the hot ductility, particularly due to its tendency to segregate at the grain boundaries or co-segregate with manganese. For these reasons, its content is limited to 0.02 % and preferably lower than 0.014%.
  • Sulfur is not an essential element but may be contained as an impurity in steel and from point of view of the present invention the Sulfur content is preferably as low as possible, but is 0.003% or less from the viewpoint of manufacturing cost. Further if higher Sulfur is present in steel it combines to form Sulfides especially with Manganese and reduces its beneficial impact on the steel of present invention.
  • Chromium is an optional element for the present invention. Chromium content may be present in the steel of present invention is between 0.05% and 1 %. Chromium is an essential element that provides strength and hardening to the steel but when used above 1% it impairs surface finish of steel. Further Chromium contents under 1 % coarsen the dispersion pattern of carbide in Bainitic structures, hence; keep the density of carbides low in Bainite.
  • Molybdenum is an optional element that constitutes 0.001 % to 0.5% of the Steel of present invention; Molybdenum plays an effective role in determining hardenability and hardness, delays the appearance of Bainite and avoids carbides precipitation in Bainite. However, the addition of Molybdenum excessively increases the cost of the addition of alloy elements, so that for economic reasons its content is limited to 0.5%.
  • Niobium is an optional element for the present invention.
  • Niobium content may be present in the steel of present invention between 0.001 and 0.1 % and is added in the Steel of present invention for forming carbo-nitrides to impart strength of the Steel of present invention by precipitation hardening.
  • Niobium will also impact the size of microstructural components through its precipitation as carbo-nitrides and by retarding the recrystallization during heating process. Thus finer microstructure formed at the end of the holding temperature and as a consequence after the completion of annealing that will lead to the hardening of the Steel of present invention.
  • Niobium content above 0.1 % is not economically interesting as a saturation effect of its influence is observed this means that additional amount of Niobium does not result in any strength improvement of the product.
  • Titanium is an optional element and may be added to the Steel of present invention between 0.001 % and 0.1 %. As Niobium, it is involved in carbo-nitrides formation so plays a role in hardening of the Steel of present invention. In addition Titanium also forms Titanium-nitrides which appear during solidification of the cast product. The amount of Titanium is so limited to 0.1 % to avoid formation of coarse Titanium-nitrides detrimental for formability. In case the Titanium content is below 0.001 % it does not impart any effect on the steel of present invention. Copper may be added as an optional element in an amount of 0.01 % to 2% to increase the strength of the steel and to improve its corrosion resistance. A minimum of 0.01 % of Copper is required to get such effect.
  • Nickel when its content is above 2%, it can degrade the surface aspects.
  • Nickel may be added as an optional element in an amount of 0.01 to 3% to increase the strength of the steel and to improve its toughness. A minimum of 0.01 % is required to produce such effects.
  • Nickel when its content is above 3%, Nickel causes ductility deterioration.
  • Calcium content in the steel of present invention is between 0.0001 % and 0.005%. Calcium is added to steel of present invention as an optional element especially during the inclusion treatment. Calcium contributes towards the refining of Steel by arresting the detrimental Sulfur content in globular form, thereby, retarding the harmful effects of Sulfur.
  • Vanadium is effective in enhancing the strength of steel by forming carbides or carbo-nithdes and the upper limit is 0.1 % due to the economic reasons.
  • Other elements such as Cerium, Boron, Magnesium or Zirconium can be added individually or in combination in the following proportions by weight: Cerium £0.1 %, Boron £ 0.003%, Magnesium £ 0.010% and Zirconium £ 0.010%. Up to the maximum content levels indicated, these elements make it possible to refine the grain during solidification. The remainder of the composition of the Steel consists of iron and inevitable impurities resulting from processing.
  • the microstructure of the Steel sheet comprises:
  • Ferrite constitutes from 60% to 75% of microstructure by area fraction for the Steel of present invention. Ferrite constitutes the primary phase of the steel as a matrix. In the present invention, Ferrite cumulatively comprises of Polygonal ferrite and acicular ferrite Ferrite imparts high strength as well as elongation to the steel of present invention. To ensure an elongation of 31 % and preferably 33% or more it is necessary to have 60% of Ferrite. Ferrite is formed during the cooling after annealing in steel of present invention. But whenever ferrite content is present above 75% in steel of present invention the strength is not achieved.
  • Bainite constitutes from 20% to 30% of microstructure by area fraction for the Steel of present invention.
  • Bainite cumulatively consists of Lath Bainite and Granular Bainite, To ensure tensile strength of 620 MPa and preferably 630 MPa or more it is necessary to have 20% of Bainite. Bainite is formed during over-aging holding.
  • Residual Austenite constitutes from 10% to 15% by area fraction of the Steel. Residual Austenite is known to have a higher solubility of Carbon than Bainite and, hence, acts as effective Carbon trap, therefore, retarding the formation of carbides in Bainite. Carbon percentage inside the Residual Austenite of present invention is preferably higher than 0.9% and preferably lower than 1.1 %. Residual Austenite of the Steel according to the invention imparts an enhanced ductility.
  • Martensite is an optional constituent and may be present between 0% and 5 % of microstructure by area fraction and found in traces.
  • Martensite for present invention includes both fresh martensite and tempered martensite.
  • Present invention form martensite due to the cooling after annealing and get tempered during overaging holding.
  • Fresh Martensite also form during cooling after the coating of cold rolled steel sheet.
  • Martensite imparts ductility and strength to the Steel of present invention when it is below 5%. When Martensite is in excess of 5 % it imparts excess strength but diminishes the elongation beyond acceptable limit.
  • the preferable limit for martensite is between 0% and 3%.
  • a total amount of Ferrite and Residual Austenite must always be between 70% and 80% to have total elongation of 31 % and a minimum of 70% is required to ensure the total elongation above 31 % while having a tensile strength of 600MPa.
  • Ferrite and residual austenite are soft phase in comparison to martensite and bainite therefore imparts for elongation and ductility but whenever the cumulative presence is more than 80% the strength drops beyond the acceptable limits.
  • the microstructure of the cold rolled and heat treated steel sheet is free from microstructural components, such as pearlite and cementite without impairing the mechanical properties of the steel sheets.
  • a steel sheet according to the invention can be produced by any suitable method.
  • a preferred method consists in providing a semi-finished casting of steel with a chemical composition according to the invention.
  • the casting can be done either into ingots or continuously in form of thin slabs or thin strips, i.e. with a thickness ranging from approximately 220mm for slabs up to several tens of millimeters for thin strip.
  • a slab having the above-described chemical composition is manufactured by continuous casting wherein the slab optionally underwent the direct soft reduction during the continuous casting process to avoid central segregation and to ensure a ratio of local Carbon to nominal Carbon kept below 1.10.
  • the slab provided by continuous casting process can be used directly at a high temperature after the continuous casting or may be first cooled to room temperature and then reheated for hot rolling.
  • the temperature of the slab which is subjected to hot rolling, isat least 1 150° C and must be below 1280°C.
  • the temperature of the slab is preferably sufficiently high so that hot rolling can be completed in the temperature range of Ac1 +50°C to Ac1 +250°C and preferably between Ac1 +50°C and Ac1 +200°C while always having final rolling temperature remains above Ac1 +50°C. Reheating at temperatures above 1280°C must be avoided because they are industrially expensive.
  • a final rolling temperature range between Ac1 +50°C to Ac1 +250°C is preferred to have a structure that is favorable to recrystallization and rolling. It is necessary to have final rolling pass to be performed at a temperature greater than Ac1 +50°C, because below this temperature the steel sheet exhibits a significant drop in rollability.
  • the sheet obtained in this manner is then cooled at a cooling rate above 30°C/s to the coiling temperature which must be below 625°C. Preferably, the cooling rate will be less than or equal to 200° C/s.
  • the hot rolled steel sheet is then coiled at a coiling temperature below 625°C to avoid ovalization and preferably below 600°C to avoid scale formation.
  • the preferred range for such coiling temperature is between 350° C and 600° C.
  • the coiled hot rolled steel sheet may be cooled down to room temperature before subjecting it to optional hot band annealing.
  • the hot rolled steel sheet may be subjected to an optional scale removal step to remove the scale formed during the hot rolling before optional hot band annealing.
  • the hot rolled sheet may then subjected to an optional Hot Band Annealing at temperatures between 400°C and 750°C for at least 12 hours and not more than 96 hours, the temperature remaining below 750°C to avoid transforming partially the hot-rolled microstructure and, therefore, losing the microstructure homogeneity.
  • an optional scale removal step of this hot rolled steel sheet may performed through, for example, pickling of such sheet.
  • This hot rolled steel sheet is subjected to cold rolling to obtain a cold rolled steel sheet with a thickness reduction between 35 to 90%.
  • the cold rolled steel sheet obtained from cold rolling process is then subjected to annealing to impart the steel of present invention with microstructure and mechanical properties.
  • step one cold rolled steel sheet is heated at a heating rate between 10°C/s and 40°C/s to a temperature range between 550°C and 650°C. Thereafter in subsequent second step of heating the cold rolled steel sheet is heated at a heating rate between 1 °C/s and 5°C/s to the soaking temperature of annealing.
  • the cold rolled steel sheet is preferably held at the soaking temperature during 10 to 500 seconds to ensure at least 30% transformation to Austenite microstructure of the strongly work-hardened initial structure. Then the cold rolled steel sheet is then cooled in two step cooling to an over-aging holding temperature. In step one of cooling the cold rolled steel sheet is cooled at cooling rate less than 5°C/s and preferably less than 3°C/s to a temperature range between 600°C and 720°C and preferably between 625°C and 720°C. During this step one of cooling ferrite matrix of the present invention is formed.
  • the cold rolled steel sheet is cooled to an overaging temperature range between 250°C and 470°C at a cooling rate between 10°C/s and 100°C/s. Then the cold rolled steel sheet is held in the over aging temperature range during 5 to 500 seconds. The cold rolled steel sheet is then brought to the temperature to a coating bath temperature range of 400°C and 480°C to facilitate coating of the cold rolled steel sheet. Then the cold rolled steel sheet is coated by any of the known industrial processes such as Electro galvanization, JVD, PVD, Hot dip(GI) etc.
  • Table 1 Steel sheets made of steels with different compositions are gathered in Table 1 , where the steel sheets are produced according to process parameters as stipulated in Table 2, respectively. Thereafter Table 3 gathers the microstructures of the steel sheets obtained during the trials and table 4 gathers the result of evaluations of obtained properties. Table 1
  • Table 2 gathers the annealing process parameters implemented on steels of Table 1.
  • the Steel compositions A and B serve for the manufacture of sheets according to the invention.
  • This table also specifies the reference steels which are designated in table as C and D .
  • Table 2 also shows tabulation of Ac1 and Ac3. These Ac1 and Ac3 are defined for the inventive steels and reference steels as follows:
  • the table 2 is as follows : Table 2
  • Table 3 exemplifies the results of the tests conducted in accordance with the standards on different microscopes such as Scanning Electron Microscope for determining the microstructures of both the inventive and reference steels. The results are stipulated herein:
  • Table 4 exemplifies the mechanical properties of both the inventive steel and reference steels.
  • tensile tests are conducted in accordance of JIS Z2241 standards.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
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Abstract

L'invention concerne une tôle d'acier laminée à froid et traitée thermiquement présentant une composition comprenant les éléments suivants satisfaisant : 0,13 % ≤ carbone ≤ 0,18 %, 1,1 % ≤ manganèse ≤ 1,8 %, 0,5 % ≤ silicium ≤ 0,9 %, 0,6 % ≤ aluminium ≤ 1 %, 0,002 % ≤ phosphore ≤ 0,02 %, 0 % ≤ soufre ≤ 0,003 %, 0 % ≤ azote ≤ 0,007 % et pouvant contenir un ou plusieurs des éléments facultatifs suivants : 0,05 % ≤ chrome ≤ 1 %, 0,001 % ≤ molybdène ≤ 0,5 %, 0,001 % ≤ niobium ≤ 0,1 %, 0,001 % ≤ titane ≤ 0,1 %, 0,01 % ≤ cuivre ≤ 2 %, 0,01 % ≤ nickel ≤ 3 %, 0,0001 % ≤ calcium ≤ 0,005 %, 0,% ≤ vanadium ≤ 0,1 %, 0 % ≤ bore ≤ 0,003 %, 0 % ≤ cérium ≤ 0,1 %, 0 % ≤ magnésium ≤ 0,010 %, 0 % ≤ zirconium < 0,010 %, la composition restante étant composée de fer et d'impuretés inévitables dues au traitement, la microstructure de ladite tôle d'acier comprenant en fraction surfacique, 60 à 75 % de ferrite, 20 à 30 % de bainite, 10 à 15 % d'austénite résiduelle et 0 % à 5 % de martensite, les quantités cumulées d'austénite résiduelle et de ferrite étant situées entre 70 % et 80 %.
PCT/IB2018/057253 2018-09-20 2018-09-20 Tôle d'acier laminée à froid et revêtue et son procédé de fabrication WO2020058748A1 (fr)

Priority Applications (17)

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PCT/IB2018/057253 WO2020058748A1 (fr) 2018-09-20 2018-09-20 Tôle d'acier laminée à froid et revêtue et son procédé de fabrication
EP19772880.1A EP3853387B1 (fr) 2018-09-20 2019-09-17 Tôle d'acier laminée à froid et revêtue et son procédé de fabrication
FIEP19772880.1T FI3853387T3 (fi) 2018-09-20 2019-09-17 Kylmävalssattu ja pinnoitettu teräslevy ja menetelmä sen valmistamiseksi
HUE19772880A HUE062231T2 (hu) 2018-09-20 2019-09-17 Hidegen hengerelt, bevonattal ellátott acéllemez és az elõállítására szolgáló eljárás
MX2021003290A MX2021003290A (es) 2018-09-20 2019-09-17 Hoja de acero laminada en frio y recubierta y un metodo de fabricacion de la misma.
MA53640A MA53640B1 (fr) 2018-09-20 2019-09-17 Tôle d'acier laminée à froid et revêtue et son procédé de fabrication
JP2021515544A JP7422143B2 (ja) 2018-09-20 2019-09-17 冷間圧延被覆鋼板及びその製造方法
US17/276,240 US20220033925A1 (en) 2018-09-20 2019-09-17 Cold rolled and coated steel sheet and a method of manufacturing thereof
CA3110629A CA3110629C (fr) 2018-09-20 2019-09-17 Tole d'acier laminee a froid et revetue et son procede de fabrication
UAA202102067A UA126725C2 (uk) 2018-09-20 2019-09-17 Холоднокатаний сталевий лист з покриттям та спосіб його одержання
PL19772880.1T PL3853387T3 (pl) 2018-09-20 2019-09-17 Walcowana na zimno i powlekana blacha stalowa i sposób jej wytwarzania
CN201980059157.2A CN112689684B (zh) 2018-09-20 2019-09-17 经冷轧和涂覆的钢板及其制造方法
KR1020217011078A KR102647462B1 (ko) 2018-09-20 2019-09-17 냉간 압연 및 코팅된 강판 및 그 제조 방법
BR112021003583-4A BR112021003583A2 (pt) 2018-09-20 2019-09-17 chapa de aço laminada a frio, método de produção, uso e veículo
ES19772880T ES2946086T3 (es) 2018-09-20 2019-09-17 Chapa de acero laminada en frío y revestida y un procedimiento de fabricación de la misma
PCT/IB2019/057795 WO2020058829A1 (fr) 2018-09-20 2019-09-17 Tôle d'acier laminée à froid et revêtue et son procédé de fabrication
ZA2021/01225A ZA202101225B (en) 2018-09-20 2021-02-23 Cold rolled and coated steel sheet and a method of manufacturing thereof

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CN115181898B (zh) * 2021-04-02 2023-10-13 宝山钢铁股份有限公司 一种1280MPa级别低碳低合金Q&P钢及其快速热处理制造方法
CA3220321A1 (fr) * 2021-06-16 2022-12-22 Arcelormittal Procede de production d'une piece en acier, et piece en acier
CN115323275B (zh) * 2022-09-05 2023-07-04 东北大学 一种高强高韧的稀土温轧低碳低锰trip钢及其制备方法

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BR112021003583A2 (pt) 2021-05-18
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CA3110629A1 (fr) 2020-03-26
HUE062231T2 (hu) 2023-10-28
WO2020058829A1 (fr) 2020-03-26
CN112689684B (zh) 2022-12-09
PL3853387T3 (pl) 2023-07-10
FI3853387T3 (fi) 2023-06-15
CN112689684A (zh) 2021-04-20
US20220033925A1 (en) 2022-02-03
KR102647462B1 (ko) 2024-03-13
CA3110629C (fr) 2023-03-14
MA53640B1 (fr) 2023-05-31
EP3853387B1 (fr) 2023-05-10
JP2022501504A (ja) 2022-01-06
ZA202101225B (en) 2022-01-26
KR20210061382A (ko) 2021-05-27
JP7422143B2 (ja) 2024-01-25
ES2946086T3 (es) 2023-07-12
MA53640A (fr) 2022-03-30

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