WO2020035081A1 - 一种改性炭材料及降低碳质材料着火温度的方法 - Google Patents
一种改性炭材料及降低碳质材料着火温度的方法 Download PDFInfo
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- WO2020035081A1 WO2020035081A1 PCT/CN2019/107902 CN2019107902W WO2020035081A1 WO 2020035081 A1 WO2020035081 A1 WO 2020035081A1 CN 2019107902 W CN2019107902 W CN 2019107902W WO 2020035081 A1 WO2020035081 A1 WO 2020035081A1
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/04—Raw material of mineral origin to be used; Pretreatment thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/447—Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/22—Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/0204—Metals or alloys
- C10L2200/0209—Group I metals: Li, Na, K, Rb, Cs, Fr, Cu, Ag, Au
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/0254—Oxygen containing compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/08—Specifically adapted fuels for small applications, such as tools, lamp oil, welding
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Definitions
- the invention belongs to the technical field of tobacco products, and particularly relates to a modified carbon material for heating a non-combustible cigarette with a carbon source, a preparation method and an application thereof.
- New tobacco products can be roughly divided into four categories: the first category is electronic cigarettes, the second category is heated non-combustion tobacco products, the third category is mouthful of tobacco, and the fourth category is some other types of tobacco products.
- non-burning tobacco products that have been heated have gained market favor because they fully retain the texture of traditional tobacco.
- the main feature of heating non-burning tobacco products is to use external heat sources to heat the tobacco rather than ignite the tobacco, which is the most essential difference from traditional tobacco.
- Carbonaceous heat source is one of its main heat sources, and its performance is directly related to the quality of tobacco.
- the properties of the carbonaceous heat source directly affect the properties of the carbonaceous heat source.
- the raw materials for preparing carbonaceous heat sources are biomass materials, such as coconut shell, bamboo, fruit wood, and paper and cellulose.
- the carbonaceous heat source prepared from biomass materials has many disadvantages. If the combustion performance of the carbonaceous heat source is to be precisely regulated, it will be difficult to achieve.
- Chinese patent CN107033938 discloses a method for preparing a carbon material for a carbon heating cigarette heating body with controlled combustion performance.
- the method uses pure cellulose as a carbon source, controls different pyrolysis temperatures, and obtains a series of carbon materials with different combustion characteristics. , And then mix them to achieve the regulation of combustion performance.
- the ignitability, uniformity of heat release, and controllability of the burning rate of the carbonaceous heat source obtained by the patent still need to be improved.
- the technical problem to be solved by the present invention is to address the above-mentioned shortcomings of the prior art, and to provide a modified carbon material for heating a non-combustible cigarette with a carbon source and a method for preparing the same. At the same time, the combustion characteristics of modified carbon materials are easy to regulate carbon.
- the first aspect of the present invention discloses a modified carbon material, which includes a carbonaceous material and a water-insoluble modifier combined therewith; the modifier is CuO.
- the carbonaceous material is one of biomass carbon or carbon black or a mixture thereof.
- Biochar refers to the carbon materials obtained from biomass materials, such as coconut shell, bamboo, fruit wood, oak, and paper and cellulose.
- the mass of the modifier is 0.1-10 wt% of CuO in the carbonaceous material.
- a second aspect of the invention discloses a method for reducing the ignition temperature of a carbonaceous material, increasing the peak thermal power, and / or reducing the peak thermal power temperature, including the following steps:
- the carbonaceous material is immersed in a copper sulfate solution for 5 to 36 hours, and the ratio of the carbonaceous material and copper sulfate is controlled so that the final CuO mass in the modified carbon material accounts for 0.1-10 wt% of the carbonaceous material;
- step (2) adding an alkali solution to the solution in step (1) to make the pH value ⁇ 12, and filtering after maintaining for 0.5-2h, and the solid obtained by drying is the modified carbon material according to claim 1;
- the modified carbon material is used as a combustion heat source.
- the concentration of the copper sulfate solution in step (1) is 0.5-3 wt%.
- the alkali solution in step (2) is a sodium hydroxide solution or a potassium hydroxide solution, and its concentration is 1-50% by weight.
- the drying temperature described in step (2) is 80-95 ° C.
- the ignition temperature is reduced by at least 150 ° C
- the peak thermal power is increased by at least 50%
- the peak thermal power temperature is decreased by at least 95 ° C.
- the present invention uses CuO as a modifier to modify carbonaceous materials for the first time.
- the obtained modified carbon material is used for charcoal heating and non-combustion cigarettes.
- the heat source has the advantages of wide combustion characteristics and controllable combustion characteristics; that is, the invention uses CuO.
- the modified carbon material modified as a modifier has the characteristics of easy ignition, uniform heat release, and controllable combustion rate.
- the ignition temperature is reduced by at least 150 ° C, the peak thermal power is increased by at least 50%, and the peak thermal power temperature is decreased by at least 95 ° C.
- the preparation method of the present invention is simple. According to actual needs, commonly used carbon powder, that is, biomass carbon and industrially produced carbon black, can be selected, the production cost is lower, and the method is suitable for large-scale process controllable preparation.
- FIG. 1 is a process flow diagram of a method for preparing a modified carbon material according to the present invention.
- FIG. 2 is a thermogravimetric curve of modified carbon powder and 10000 mesh oak carbon powder in Examples 1-7.
- FIG. 3 is a differential thermogravimetric curve of modified carbon powder and 10000 mesh oak carbon powder in Examples 1-7.
- FIG. 4 is a DSC curve of modified carbon powder and 10000 mesh oak carbon powder in Examples 1-7.
- FIG. 5 is a thermogravimetric curve of modified carbon powder and C311 carbon black in Examples 8-14.
- FIG. 7 is a DSC curve of modified carbon powder and C311 carbon black in Examples 8-14.
- FIG. 8 is a thermogravimetric curve of the mixed carbon powder of Example 15.
- FIG. 9 is a DSC curve of the mixed carbon powder of Example 15.
- step (2) Stir the soaking solution in step (1), and slowly add a 10% by weight sodium hydroxide solution during the stirring process until the pH value reaches 13, stop adding the sodium hydroxide solution, and continue stirring the solution for 1h. Suction filtration and washing are performed until the powder is neutral, dried at 90 ° C, and milled to obtain the modified carbon powder (2wt% CuO).
- step (2) Stir the soaking solution in step (1), and slowly add a 20% by weight sodium hydroxide solution during the stirring process until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Suction filtration and washing are performed until the powder is neutral, dried at 90 ° C, and milled to obtain the modified carbon powder (4 wt% CuO).
- step (2) Stir the soaking solution in step (1), and slowly add a 20% by weight sodium hydroxide solution during the stirring process until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Perform suction filtration and cleaning to neutrality, dry at 90 ° C, and mill to obtain the modified carbon powder (6wt% CuO).
- step (2) Stir the soaking solution in step (1), and slowly add a 20% by weight sodium hydroxide solution during the stirring process until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Suction filtration and washing are performed until the powder is neutral, dried at 90 ° C, and milled to obtain the modified carbon powder (8 wt% CuO).
- step (2) Stir the soaking solution in step (1). During the stirring process, slowly add a 1% by weight sodium hydroxide solution until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Perform suction filtration and washing to neutrality, dry at 90 ° C, and mill to obtain the modified carbon powder (1wt% CuO).
- step (2) Stir the soaking solution in step (1). During the stirring process, slowly add a 1% by weight sodium hydroxide solution until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Suction filtration and washing are performed until the powder is neutral, dried at 90 ° C, and milled to obtain the modified carbon powder (1% wtCuO).
- step (2) Stir the soaking solution in step (1). During the stirring process, slowly add a 1% by weight sodium hydroxide solution until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Suction filtration and washing are performed until the powder is neutral, dried at 90 ° C, and milled to obtain the modified carbon powder (0.5 wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) is immersed in a CuSO 4 solution with a concentration of 6.25 g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 6.25: 100), Soak for 24h.
- step (2) Stir the soaking solution in step (1), and slowly add a 10% by weight sodium hydroxide solution during the stirring process until the pH value reaches 13, stop adding the sodium hydroxide solution, and continue stirring the solution for 1h. Perform centrifugal cleaning to neutrality, dry at 90 ° C, and mill to obtain the modified carbon powder (2wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) is immersed in a CuSO 4 solution with a concentration of 12.5g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 12.5: 100), Soak for 24h.
- step (2) Stir the soaking solution in step (1), and slowly add a 20% by weight sodium hydroxide solution during the stirring process until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Centrifugal cleaning to neutrality, drying at 90 to obtain the modified carbon powder, and grinding to obtain the modified carbon powder (4wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) is immersed in a CuSO 4 solution with a concentration of 18.75 g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 18.75: 100), Soak for 24h.
- step (2) Stir the soaking solution in step (1), and slowly add a 20% by weight sodium hydroxide solution during the stirring process until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Centrifugal cleaning to neutrality, drying at 90 ° C., and milling, to obtain the modified carbon powder (6wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) is immersed in a CuSO 4 solution with a concentration of 25 g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 1: 4) and soaked. 24h.
- step (2) Stir the soaking solution in step (1), and slowly add a 20% by weight sodium hydroxide solution during the stirring process until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Centrifugal cleaning to neutrality, drying at 90 ° C., and milling, to obtain the modified carbon powder (8wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) is immersed in a CuSO 4 solution with a concentration of 3.13 g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 3.13: 100), Soak for 24h.
- step (2) Stir the soaking solution in step (1). During the stirring process, slowly add a 1% by weight sodium hydroxide solution until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Centrifugal cleaning to neutrality, drying at 90 ° C., and milling, to obtain the modified carbon powder (1 wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) in a CuSO 4 solution with a concentration of 1.56g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 1.56: 100), Soak for 24h.
- step (2) Stir the soaking solution in step (1). During the stirring process, slowly add a 1% by weight sodium hydroxide solution until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. Centrifugal cleaning to neutrality, drying at 90 ° C., and milling, to obtain the modified carbon black (1 wt% CuO).
- C311 carbon black (C311 is a brand of carbon black) is immersed in a CuSO 4 solution with a concentration of 1.56g / L (the mass ratio of CuSO 4 ⁇ 5H 2 O solids to C311 carbon black solids is 1.56: 100), Soak for 24h.
- step (2) Stir the soaking solution in step (1). During the stirring process, slowly add a 1% by weight sodium hydroxide solution until the pH reaches 13, stop adding the sodium hydroxide solution, and continue to stir the solution for 1h. After centrifugal washing to neutrality, drying at 90 ° C, and milling, a CuO modified carbon powder is obtained, which is recorded as modified carbon black (0.5% CuO).
- a NETZSCH STA449F3 thermal analyzer was used to perform the thermal analysis test on Examples 1-14 and unmodified oak charcoal and C311 carbon black.
- the heating rate was 10 ° C / min, and the atmosphere was simulated air.
- the specific combustion characteristics are calculated according to the standard GB / T 33304-2016, as shown in Tables 1 and 2.
- Table 1 shows the combustion characteristics of modified oak charcoal powder compounded with different proportions of CuO.
- Table 2 Combustion characteristics of modified C311 carbon black.
- the thermal weight, differential thermal weight, and DSC curve of oak carbon powder modified with different contents of CuO show a regular shift to the low temperature region, and the ignition temperature has been achieved from 454.7- Regulation at 488.8 ° C.
- Other combustion characteristics parameters can also be effectively changed.
- the DSC curve fractal of 4wt% CuO modified oak charcoal has the shortest peak shape, and its heat release is relatively gentle during the programmed temperature rise.
- the thermal weight, differential thermal weight, and DSC curve of C311 carbon black modified with different contents of CuO are significantly shifted to the low temperature area compared to C311 carbon black, and the ignition temperature is achieved. Regulation from 412.1-600.0 ° C.
- Other combustion characteristic parameters can also be effectively changed, such as the peak thermal power is significantly increased, and the peak thermal power temperature is significantly reduced.
- the modified carbon powder and the oak carbon powder in Example 2 were stirred and mixed in a kneader at a mass ratio of 3: 7 to obtain a new modified carbon powder, and the thermal analysis performance was further tested. From the curves of FIG. 8 and FIG. 9, it can be seen that the peak shape of the new modified carbon powder obtained after mixing is more dwarf than the modified carbon powder of Example 2 and the original oak carbon powder, and it is heated up in the program The heat release is relatively smooth.
- This example illustrates the modified carbon powder modified by CuO. The higher the content of CuO, the better.
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Abstract
Description
Claims (6)
- 一种改性炭材料,其特征在于,其包括碳质材料和与其结合的不溶于水的改性剂;所述改性剂为CuO;所述碳质材料为生物质炭或炭黑中的一种或者其混合物,所述改性剂的质量占所述碳质材料的0.1-10wt%。
- 一种降低碳质材料着火温度、提高峰值热功率和/或降低峰值热功率温度的方法,其特征在于,包括如下步骤:(1)将碳质材料浸泡于硫酸铜溶液中保持5-36h,所述碳质材料与硫酸铜比例控制为使得最终所述改性炭材料中CuO质量占碳质材料的0.1-10wt%;(2)向步骤(1)的溶液中加入碱溶液,使pH值≥12,保持0.5-2h后过滤,干燥得到的固体物即为权利要求1所述的改性炭材料;(3)将所述改性炭材料用作燃烧热源。
- 根据权利要求2所述的方法,其特征在于,步骤(1)中所述硫酸铜溶液浓度为0.5-3wt%。
- 根据权利要求2所述的方法,其特征在于,步骤(2)中所述碱溶液为氢氧化钠溶液或氢氧化钾溶液,其浓度为1-50wt%。
- 根据权利要求2所述的方法,其特征在于,步骤(2)中所述的干燥温度为80-95℃。
- 根据权利要求2所述的方法,其特征在于,所述着火温度降低至少150℃,所述峰值热功率提高至少50%,所述峰值热功率温度降低至少95℃。
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EP19849601.0A EP3777569B1 (en) | 2018-08-13 | 2019-09-25 | Modified carbon material and method for reducing carbonaceous material ignition temperature |
AU2019320955A AU2019320955B2 (en) | 2018-08-13 | 2019-09-25 | Modified carbon material and method for reducing carbonaceous material ignition temperature |
US17/049,027 US11234456B2 (en) | 2018-08-13 | 2019-09-25 | Modified carbon material and method for reducing carbonaceous material ignition temperature |
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EP3777569B1 (en) | 2023-03-22 |
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