WO2020004551A1 - 眼鏡レンズ - Google Patents
眼鏡レンズ Download PDFInfo
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- WO2020004551A1 WO2020004551A1 PCT/JP2019/025616 JP2019025616W WO2020004551A1 WO 2020004551 A1 WO2020004551 A1 WO 2020004551A1 JP 2019025616 W JP2019025616 W JP 2019025616W WO 2020004551 A1 WO2020004551 A1 WO 2020004551A1
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- film
- spectacle lens
- convex portion
- coating
- shape
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- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/022—Ophthalmic lenses having special refractive features achieved by special materials or material structures
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- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
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- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C2202/00—Generic optical aspects applicable to one or more of the subgroups of G02C7/00
- G02C2202/24—Myopia progression prevention
Definitions
- the present invention relates to spectacle lenses.
- Patent Document 1 (US Patent Application Publication No. 2017/131567) describes a spectacle lens that suppresses the progress of refractive error such as myopia.
- a spherical minute convex portion (substrate convex portion in the present specification) having a diameter of about 1 mm is formed on the convex surface on the object side of the spectacle lens.
- a spectacle lens light rays incident from a surface on the object side are usually emitted from a surface on the eyeball side to focus on the retina of the wearer (predetermined position A in this specification).
- the light that has passed through the minute convex portion focuses the light beam incident on the spectacle lens at a position B closer to the object side than a predetermined position A.
- the progress of myopia is suppressed.
- An object of one embodiment of the present invention is to provide a technique capable of sufficiently exhibiting the effect of suppressing myopia even after a film is formed on a lens substrate.
- the present inventors have conducted intensive studies to solve the above-mentioned problems.
- the coating covers the surface having the substrate protrusion.
- the outermost surface shape of the coating has a coating convex portion derived from the substrate convex portion.
- the focal point is formed at a position closer to the object side than the predetermined position A by the convex portion of the base material.
- a film is formed on the lens substrate, whether or not a focus is formed at or near the same position as the substrate convex portion depends on the outermost surface shape of the film, that is, the film convex portion shape.
- the present inventors have conceived the following method. It has been found that in the case where the shape of the convex portion on the outermost surface of the spectacle lens is the approximate shape of the convex portion of the base material, the effect of suppressing myopia can be sufficiently exerted.
- the shape of the substrate convex portion that is, the partial spherical shape
- the virtual partial spherical shape is compared with the actual film convex shape, if the difference remains at a predetermined value, the effect of suppressing myopia can be further exerted.
- a first aspect of the present invention provides: In a spectacle lens that emits light rays incident from the object-side surface from the eyeball-side surface and converges to a predetermined position A, A lens substrate having a plurality of substrate protrusions on at least one of the object-side surface and the eyeball-side surface, A coating covering the surface having the base projections, With The shape of the convex portion on the outermost surface of the spectacle lens on the side having the substrate convex portion is such that the light beam incident on the spectacle lens converges at a position B closer to the object side than the predetermined position A. It is a spectacle lens which is a part approximate shape.
- a second aspect of the present invention is an aspect according to the first aspect, wherein The outermost surface shape of the coating has a coating convex portion derived from the substrate convex portion, The coating convex portion converges a light beam incident on the spectacle lens to a position B closer to the object side than the predetermined position A, A spectacle lens, wherein the maximum value of the absolute value of the difference in the lens thickness direction between the spherical surface optimally approximated to the film convex shape and the actual film convex shape is 0.1 ⁇ m or less.
- a third aspect of the present invention is an aspect according to the second aspect, wherein The coating convex portion converges the light beam incident on the spectacle lens to a position B that is more than 0 mm and less than or equal to 10 mm closer to the object side than the predetermined position A.
- a fourth aspect of the present invention is an aspect according to the second or third aspect, wherein Obtained by a ray tracing calculation, among a number of light rays that are evenly incident on a predetermined range of the object-side surface of the spectacle lens and pass through the coating, do not pass near the predetermined position A, and The number of stray light rays that do not pass near the position B near the object side is 30% or less of the number of incident light rays.
- a fifth aspect of the present invention is an aspect according to any one of the second to fourth aspects, wherein In the astigmatism distribution with respect to the outermost surface shape of the coating, a cross-sectional curve of the astigmatism at the root of the coating projection is 0.20 mm or less.
- a sixth aspect of the present invention is an aspect according to any one of the first to fifth aspects, wherein The coating has a ⁇ / 4 film in contact with the lens substrate, a hard coat film formed on the ⁇ / 4 film, and an anti-reflection film formed on the hard coat film.
- a seventh aspect of the present invention is an aspect according to the sixth aspect, wherein The refractive index of the lens substrate is higher than the ⁇ / 4 film, and the refractive index of the ⁇ / 4 film is higher than the hard coat film.
- the effect of suppressing myopia can be sufficiently exhibited even after a film is formed on a lens substrate.
- FIG. 1 is a cross-sectional view illustrating an example of an eyeglass lens according to one embodiment of the present invention.
- FIG. 2 illustrates a case where the spectacle lens according to one embodiment of the present invention emits light rays incident from the object-side surface from the eyeball-side surface through a portion other than the coating convex portion (that is, the base portion), so that the spectacle lens on the retina of the eyeball.
- FIG. 4 is a schematic side sectional view showing a state where light is converged to a predetermined position A.
- FIG. 3 illustrates a case where the spectacle lens according to one embodiment of the present invention uses the coating convex portion to emit light rays incident from the object-side surface from the eyeball-side surface and converge to a position B closer to the object side than a predetermined position A.
- FIG. 4 is a schematic cross-sectional view showing a coating convex portion and a virtual partial spherical shape of an actual spectacle lens.
- FIG. 5 is a flowchart showing the flow of the method for inspecting an eyeglass lens according to one embodiment of the present invention.
- FIG. 6 is a diagram (part 1) for describing a method of specifying a position where a light beam converges.
- FIG. 7 is a diagram (part 2) for describing a method of specifying a position where a light beam is focused.
- FIG. 8 is a diagram (part 3) for describing a method of specifying a position where a light beam is focused.
- FIG. 9 is a flowchart illustrating a method of specifying a position where a light beam converges.
- FIG. 10 shows design values (that is, no film), which passes through the apex of the base material convex portion (ie, the center of the base material convex portion in plan view) in the astigmatism distribution for the base material convex portion and its vicinity.
- FIG. 10 shows design values (that is, no film), which passes through the apex of the base material convex portion (ie, the center of the base material convex portion in plan view) in the astigmatism distribution for the base material convex portion and its vicinity.
- FIG. 5 is a diagram showing a plot (solid line) of an astigmatism distribution (that is, an astigmatism cross-sectional curve) in a section to be formed.
- FIG. 11 shows the astigmatism distribution (that is, the astigmatism distribution) in the cross section passing through the vertex of the coating projection (that is, the center of the coating projection in plan view) in the actual astigmatism distribution for the coating projection and its vicinity.
- FIG. 4 is a diagram showing a plot (solid line) of an aberration cross-section curve).
- FIG. 12A is a schematic cross-sectional view showing the convex portions of the coating and the base material of the actual spectacle lens.
- FIG. 12B is a schematic cross-sectional view in which the vertices of the coating film protrusion and the base material protrusion are matched.
- FIG. 1 is a cross-sectional view illustrating an example of an eyeglass lens 1 according to one embodiment of the present invention.
- FIG. 1 shows an example in which the object-side surface 3 is convex and the eyeball-side surface 4 is concave (a so-called meniscus lens).
- the spectacle lens 1 has a surface 3 on the object side and a surface 4 on the eyeball side.
- the “object-side surface 3” is a surface located on the object side when the spectacles provided with the spectacle lens 1 are worn by the wearer, and the “eyeball-side surface 4” is the opposite, that is, the spectacles This is the surface located on the eyeball side when the glasses provided with the lens 1 are worn by the wearer.
- the spectacle lens 1 is a conventional spectacle lens except for a minute convex portion described in Patent Literature 1 (that is, a base convex portion 6 described later and a coating convex portion 11 thereon).
- a function is provided in which light rays incident from the object-side surface 3 are emitted from the eyeball-side surface 4 and converged at a predetermined position A.
- FIG. 2 shows that the spectacle lens 1 according to one embodiment of the present invention emits light rays incident from the object-side surface 3 from the eyeball-side surface 4 by a portion other than the coating convex portion 11 (that is, the base portion). It is a schematic side sectional view showing signs that it converges to predetermined position A on retina 20A of No. 20.
- the spectacle lens 1 includes the lens substrate 2.
- the lens substrate 2 also has an object-side surface 3 and an eyeball-side surface 4.
- the shape of both surfaces of the lens substrate 2 may be determined according to the type of the spectacle lens 1, and may be any of a convex surface, a concave surface, a flat surface, or a combination thereof.
- ⁇ A coating is formed so as to cover at least one of the object-side surface and the eyeball-side surface of the lens substrate 2, and the spectacle lens 1 is configured.
- a plurality of substrate protrusions 6 are formed on at least one of the object-side surface 3 and the eyeball-side surface 4.
- the film convex portion 11 are converged at a position B closer to the object side than a predetermined position A.
- FIG. 3 shows that the spectacle lens 1 according to one embodiment of the present invention uses the coating convex portion 11 to emit light rays incident from the object-side surface 3 from the eyeball-side surface 4 so as to be closer to the object side than a predetermined position A.
- FIG. 4 is a schematic side sectional view showing a state of being converged to a position B.
- the convergence position B is arranged according to each of a plurality of film protrusions 11 B 1, B 2, B 3, present as ⁇ ⁇ ⁇ B N.
- Convergence position B herein, arrangement B 1, B 2, B 3, a representation summarizing ⁇ ⁇ ⁇ B N.
- the shape of the convex portion (eg, coating convex portion 11) on the outermost surface of the spectacle lens on the side having the base convex portion 6 is such that the light beam incident on the spectacle lens is positioned at the predetermined position.
- This is an approximate shape of the base material convex portion that converges to a position B closer to the object side than A.
- the base material convex part approximate shape refers to a shape in which a spherical surface (hereinafter, referred to as a virtual partial spherical shape) that is optimally approximated to the coating film convex part 11 shape and the base material convex part 6 shape are approximated.
- the maximum absolute value of the difference in the lens thickness direction between the spherical surface optimally approximated to the shape of the film projection 11 and the actual shape of the film projection 11 is 0.1 ⁇ m or less (preferably 0.06 ⁇ m). The following is preferred.
- the base projection 6 has a substantially partial spherical shape, and a focus is formed at a position B near the object side. No matter how the coating is formed on the lens substrate 2 and the coating convex portion 11 becomes blunter than the substrate convex portion 6, at least the vertex portion of the coating convex portion 11 has the base convex portion. 6.
- a spherical surface optimally approximated to the substantially partial spherical shape is imagined from the substantially partial spherical shape at the vertex of the coating convex portion 11. Thereby, a virtual partial spherical shape is obtained. Then, the virtual partial spherical shape is compared with the actual coating convex portion 11 shape.
- FIG. 4 is a schematic cross-sectional view showing the actual coating convex portion 11 and the virtual partial spherical shape of the spectacle lens 1.
- the solid line indicates the coating convex portion 11 of the actual spectacle lens 1
- the broken line indicates the virtual partial spherical shape
- the dashed line indicates the base portion of the actual spectacle lens 1
- the horizontal line indicates the virtual partial spherical shape and the actual partial spherical shape.
- the difference in the lens thickness direction between the shape of the coating convex portion 11 is shown.
- the virtual partial spherical shape is a spherical partial shape that is optimally approximated to the actual shape of the coating convex portion 11 of the spectacle lens 1.
- This virtual partial spherical shape is obtained by, for example, the least square method.
- the spherical shape is arranged so as to overlap the shape of the coating convex portion 11.
- An imaginary partial spherical shape is set such that the sum of those values is minimized.
- a virtual partial spherical shape may be obtained from the positions of the vertices of the coating convex portion 11 and a plurality of points in the vicinity thereof. In that case, the difference may be examined by matching the vertex of the virtual partial spherical shape with the vertex of the coating convex portion 11 of the actual spectacle lens 1.
- the coating convex portion 11 is very close to the partial spherical shape. As a result, the effect of suppressing myopia can be sufficiently exhibited. Further, by applying this rule, the effect of suppressing myopia can be sufficiently exerted. In addition, the cross section of the actually manufactured spectacle lens 1 is botherged, and the shape of the film convex portion is changed to the shape of the substrate convex portion. This eliminates the need to check whether or not the information is faithfully reflected.
- the rising start portion As the rising start portion from the shape of the base portion on the outermost surface, a point at which the curve of the shape of the coating convex portion 11 turned into an increase in the curve obtained by differentiating once may be used as the rising start portion. Further, the rising portion of the peak of the astigmatism sectional curve shown in FIG. 11B described later may be used as the rising start portion.
- the rising end portion may be set in the same manner.
- the light beam passes through the vicinity of a predetermined position A obtained by the ray tracing calculation. It is preferable that the number of stray light rays not passing through the vicinity of the position B near the object side be set to 30% or less of the number of incident light rays.
- the stray light beam is a light beam that enters from the object-side surface 3 of the spectacle lens 1 and exits from the eyeball-side surface 4 and does not pass near a predetermined position A where the light beam converges by the spectacle lens 1 itself. It refers to a light beam that does not pass near the position B where the light beam converges due to the material protrusion 6 and thus the coating protrusion 11.
- the stray light beam causes blurring in the wearer's field of view. Therefore, it is preferable to reduce the ratio of the stray light rays in the light rays entering from the object-side surface 3 of the spectacle lens 1 and exiting from the eyeball-side surface 4.
- the coating is the coating. If the shape change from the convex surface, which is the object-side surface 3 serving as the base, at the base of the coating convex portion 11 is too slow, it becomes a shape away from the spherical shape of the substrate convex portion 6 and is the object-side surface 3. The shape is separated from the convex surface. In this case, the focus is not focused on the retina 20A of the wearer (near the predetermined position A in the present specification), and the focus is not focused on the vicinity of the position B near the object side.
- the effect of suppressing myopia even after a film is formed on the lens substrate 2 is sufficient. It can be demonstrated in.
- ⁇ Use ray tracing calculation to set the ratio of stray light rays.
- the “predetermined range” may be any optical region on the object-side surface.
- the optical region refers to a portion having a curved surface shape that achieves a power set for each wearer on the object side surface and the opposing eyeball side surface.
- the ratio of the stray light rays exceeds 0% (or 1% or more, further 3%). Above) and 30% or less. Further, since it is preferable to reduce the ratio of stray light rays, it is preferably set to 20% or less, and more preferably to 15% or less.
- FIG. 5 is a flowchart showing the flow of the method for inspecting an eyeglass lens according to one embodiment of the present invention.
- step 101 the shape of the actual object-side surface of the spectacle lens 1 (hereinafter also referred to as a convex surface) is measured, and curved surface data representing the shape of the convex surface 3 is created (shape). Measurement step).
- the shape of the convex surface 3 is measured by, for example, a non-contact three-dimensional microscope that performs length measurement using light interference.
- the three-dimensional shape of the convex surface 3 is acquired, for example, as discrete three-dimensional data (x, y, z).
- step 102 curved surface data is generated from the obtained data indicating the convex shape of the spectacle lens 1 (curved surface data generating step).
- a set of B-spline curves may be generated. If there is noise in the measured discrete three-dimensional data, for example, a moving average process may be performed and the average value may be used.
- step 103 an actual model of the spectacle lens 1 is set based on the curved surface data (model setting step).
- the eyeball model may use information on the wearer (for example, the axial length of the eye, the amount of eye adjustment, and the like).
- the spectacle lens model 30 with respect to the eyeball model 32 may be arranged in consideration of the inclination of the spectacle lens when attached to the frame (forward tilt angle and frame tilt angle).
- step 104 the position where the light beam converges most when the light beam actually passes through the spectacle lens 1 is specified by a ray tracing process (convergence position specifying step). More specifically, for a model based on the actual curved surface data of the spectacle lens 1, a PSF (Point spread function) representing the luminance distribution of the light after the light emitted from a point light source at infinity passes. Ask for.
- a PSF Point spread function
- PSF is obtained by tracing a number of rays emitted from a point light source and calculating the density of spots on an arbitrary surface. Then, by comparing the PSFs of a plurality of arbitrary surfaces, the position (surface) where the light ray is most concentrated among the plurality of arbitrary surfaces is specified.
- the diameter of the light beam may be set based on the trend diameter, and may be, for example, 4 ⁇ .
- FIG. 6 to 8 are diagrams for explaining a method of specifying a position where a light beam converges.
- FIG. 9 is a flowchart illustrating a method of specifying a position where a light beam is focused.
- step 201 it is assumed that a light beam passes through the coating convex portion 36 on the model on the object-side surface (convex surface) 33 on the model. Then, from a 0 mm position on the retina 32A of the eyeball model 32 to a predetermined distance (for example, a position of about 16 mm which is the thickness of the vitreous body of the eyeball) to a predetermined distance ⁇ d (for example, 0.1 mm) from the retina 32A. )
- the measurement planes P1, 1 to P1, n are set at intervals.
- the separation ⁇ d may be set to 0.2 mm or 1/50 of the axial length.
- a ray tracing process is performed to calculate the ray density on each of the measurement planes P1, 1 to P1, n.
- the calculation of the light beam density may be performed, for example, by setting a grid-like grid (for example, 0.1 mm ⁇ 0.1 mm) on each measurement surface and calculating the number of light beams passing through each grid.
- step 203 in order to specify the measurement surface on which the light beam incident on the convex portion has the maximum density, the measurement surface having the first maximum density from the predetermined distance among the measurement surfaces P1, 1 to P1, n P1, i is specified.
- the calculation of the light density was started from the measurement plane P1, and after the detection of the first maximum value, the calculated value of the light density was reduced to about an intermediate value between the value on the measurement plane P1 and the first maximum value. By the way, the calculation in this step may be terminated.
- step 204 the measurement planes P2, 1 and P2, 2 are set at the position of the separation distance ⁇ d / 2 before and after the maximum density measurement plane P1, i. Then, in step 205, the light beam densities on the measurement planes P2, 1 and P2, 2 are calculated. Next, in step 206, the measurement planes P2 and 1, the measurement planes P2 and 2, and the measurement plane with the maximum density in the measurement planes P1 and i are specified.
- step 207 the same steps as steps 204 to 206 are repeated until the separation distance becomes sufficiently small. That is, as shown in FIG. 8, before and after the measurement surface (P2, 2 in FIG. 8) having the maximum density immediately before, a new separation distance ( ⁇ d / 4 in FIG. 8) which is half of the immediately preceding separation distance.
- a step of setting a new measurement plane (P3, 1 and P3, 2 in FIG. 8) at a position, a step of calculating the density of light rays on the new measurement plane, a step of setting the measurement plane having the maximum density immediately before and a new step The step of specifying the largest measurement surface among the measurement surfaces is repeated. Through the above steps, it is possible to specify the position where the light beam is focused in the optical axis direction (the lens thickness direction, the Z axis).
- the convergence position of the light beam on a plane perpendicular to the optical axis direction (that is, on the specified measurement plane) is specified.
- the PSF described above is used for this specification.
- a portion where light rays (points on the measurement surface) are most concentrated by the PSF is defined as a convergence position B of the light rays on the measurement surface.
- an area within a range of, for example, a radius of 0.1 mm from the convergence position B is defined as the “near the position B”.
- the number of rays after the subtraction does not converge in the vicinity of the position A where the rays converge in the spectacle lens 1 itself, and also does not converge in the vicinity of the position B near the object side where the rays converge in the coating convex portion 11. .
- Such a light beam is referred to as stray light in this specification.
- the coating convex portion 11 converge the light beam incident on the spectacle lens 1 to a position B which is more than 0 mm and less than 10 mm closer to the object side than the predetermined position A.
- the outermost surface of the spectacle lens 1 according to one embodiment of the present invention causes the light beam incident on the spectacle lens 1 to exceed 0 mm and 10 mm or less on the object side with respect to the predetermined position A.
- the shape converges to the position B shifted to within the range.
- the range is preferably 0.1 to 7 mm, more preferably 0.1 to 5 mm, and still more preferably 0.3 to 3 mm.
- a protrusion distance L c of said coating protrusions 11, the relationship between the protrusion distance L l of said substrate protrusion 6 is preferably satisfies the equation (1) below. 0.6 ⁇ L c / L 1 ⁇ 1.5 Expression (1) If this condition is satisfied, even if a film is formed on the substrate convex portion 6, the film convex portion 11 derived from the substrate convex portion 6 moves the convergence position B of the light beam incident on the spectacle lens 1 to the predetermined value. The position is sufficiently brought closer to the object side than the position A. This means that the film projection 11 and the spectacle lens 1 of one embodiment of the present invention can exhibit a sufficient myopia suppression effect.
- the protruding distance is a distance in the optical axis direction (the lens thickness direction, the Z axis) from the base portion of the outermost surface shape of the spectacle lens 1 to the vertex of the coating convex portion 11.
- the half value width of the cross-sectional curve of the astigmatism at the base of the coating convex portion 11 in the astigmatism distribution with respect to the outermost surface shape of the coating is 0.20 mm or less.
- FIG. 10 shows design values (that is, no film), and shows vertices of the base material protrusion 6 (that is, the center of the base material protrusion 6 in plan view) in the astigmatism distribution with respect to the base material protrusion 6 and its vicinity.
- FIG. 7 is a diagram showing a plot (solid line) of an astigmatism distribution (that is, an astigmatism cross-sectional curve) in a cross section passing through ().
- FIG. 11 shows the astigmatism distribution in the cross section passing through the vertex of the film convex portion 11 (that is, the center of the film convex portion in plan view) in the actual astigmatism distribution with respect to the film convex portion 11 and the vicinity thereof.
- FIG. 4 is a diagram showing a plot (solid line) of an astigmatism cross-section curve).
- the horizontal axis represents the X-axis, that is, the horizontal position when the object-side surface 3 of the spectacle lens 1 is viewed in plan, and the unit is mm.
- the Y-axis that is, the vertical (vertical) direction when the object-side surface 3 of the spectacle lens 1 is viewed in plan may be used.
- the left vertical axis shows the value of astigmatism (and the average power), and the unit is diopter.
- the right vertical axis indicates the height of the coating projection 11 or the base projection 6, and the unit is mm.
- the protrusion 11 of the coating or the protrusion 6 of the base material is a portion of 0.3 to 1.3 mm on the horizontal axis.
- the astigmatism cross-sectional curve is substantially constant in design, both in the base portion 6 and in the substantially horizontal portion, which is the base portion, and the portion between the base portion 6 and the base portion. Only the shape apart from the spherical shape is obtained. Therefore, only this portion shows a high astigmatism value.
- the shape of the base of the coating projection 11 from the base portion changes too slowly.
- the astigmatism cross-sectional curve is used to show that there is not so much a half-shaped portion which is one of the causes of the stray light beam between the base portion and the coating convex portion 11.
- the degree of change in the shape of the root of the film projection 11 is defined by the astigmatism cross-sectional curve for the film projection 11.
- the half-width of the actual spectacle lens in FIG. 11 may be the peak width at the half of the peak apex value (diopter).
- the half width of the astigmatism cross-sectional curve By defining the half width of the astigmatism cross-sectional curve to be 0.20 mm or less, it is shown that the astigmatism changes sharply from the base portion to the film convex portion 11, and thus the spectacle lens 1 according to one embodiment of the present invention. However, a sufficient myopia suppression effect can be exhibited.
- the coating includes a ⁇ / 4 film (not shown) in contact with the lens substrate 2, a hard coat film 8 formed on the ⁇ / 4 film, and a reflection film formed on the hard coat film 8. It is preferable to have the protective film 10.
- the ⁇ / 4 film is not particularly limited as long as it has an optically ⁇ / 4 thickness, and a film used for an antireflection filter or the like may be used.
- a film used for an antireflection filter or the like may be used.
- the thickness may be 70 to 90 nm.
- the hard coat film 8 is not particularly limited as long as it improves the scratch resistance of the spectacle lens 1.
- a known antireflection film 10 may be used.
- the refractive index of the lens substrate 2 is preferably higher than that of the ⁇ / 4 film, and the refractive index of the ⁇ / 4 film is preferably higher than that of the hard coat film 8.
- the size of the base member 6 and the arrangement of the plurality of base members 6 on the surface of the lens base 2 are not particularly limited.
- the visibility of the base member 6 from the outside It can be determined from the viewpoint of imparting the design property by the base member 6 and adjusting the refractive power by the base member 6.
- the height of the base member 6 may be, for example, 0.1 to 10 ⁇ m, and the radius of curvature of the surface of the base member 6 may be, for example, 50 to 250 mmR.
- the distance between the adjacent base protrusions 6 (the distance between the end of a certain base protrusion 6 and the end of the base protrusion 6 adjacent to the base protrusion 6) is, for example, the base protrusion.
- the value may be the same as the value of the radius of the portion 6.
- the plurality of substrate protrusions 6 can be arranged substantially uniformly, for example, near the center of the lens.
- the lens substrate 2 may be, for example, a plastic lens substrate or a glass lens substrate.
- the glass lens substrate may be, for example, a lens substrate made of inorganic glass.
- a plastic lens substrate is preferable from the viewpoint of being lightweight and difficult to break.
- Plastic lens substrates include styrene resins including (meth) acrylic resins, polycarbonate resins, allyl resins, allyl carbonate resins such as diethylene glycol bisallyl carbonate resin (CR-39), vinyl resins, polyester resins, and polyether resins.
- a cured product (generally referred to as a transparent resin) obtained by curing the curable composition to be contained is exemplified.
- the curable composition may be referred to as a polymerizable composition.
- an unstained one (colorless lens) or a dyed one (stained lens) may be used as the lens substrate 2.
- the thickness and diameter of the lens substrate 2 are not particularly limited.
- the thickness may be about 1 to 30 mm, and the diameter may be about 50 to 100 mm.
- the refractive index of the lens substrate 2 may be, for example, about 1.60 to 1.75.
- the refractive index of the lens substrate 2 is not limited to the above range, and may be within the above range or may be vertically separated from the above range.
- the term “refractive index” refers to a refractive index for light having a wavelength of 500 nm.
- the lens substrate 2 can be molded by a known molding method such as casting polymerization. For example, by using a molding die having a molding surface with a plurality of concave portions and performing molding of the lens substrate 2 by casting polymerization, the lens substrate 2 having the substrate convex portion 6 on at least one surface is obtained.
- a cured film formed by curing a curable composition containing a curable compound can be given.
- a cured film is generally called a hard coat film 8 and contributes to an improvement in durability of the spectacle lens 1.
- the curable compound means a compound having a curable functional group
- the curable composition means a composition containing one or more curable compounds.
- a curable composition containing an organosilicon compound as a curable compound can be given, and a curable composition containing metal oxide particles together with the organosilicon compound. Things can also be mentioned.
- the curable composition capable of forming the cured film include a curable composition described in JP-A-63-10640.
- organosilicon compound represented by the following general formula (I) and a hydrolyzate thereof can also be given.
- R 1 represents an organic group having a glycidoxy group, an epoxy group, a vinyl group, a methacryloxy group, an acryloxy group, a mercapto group, an amino group, a phenyl group and the like
- R 2 has 1 carbon atom.
- R 3 represents an alkyl group having 1 to 6 carbon atoms or an aryl group having 6 to 10 carbon atoms
- b each represent 0 or 1.
- the alkyl group having 1 to 4 carbon atoms represented by R 2 is a linear or branched alkyl group, and specific examples include a methyl group, an ethyl group, a propyl group, and a butyl group.
- Examples of the acyl group having 1 to 4 carbon atoms represented by R 2 include an acetyl group, a propionyl group, an oleyl group, and a benzoyl group.
- Examples of the aryl group having 6 to 10 carbon atoms represented by R 2 include a phenyl group, a xylyl group, and a tolyl group.
- the alkyl group having 1 to 6 carbon atoms represented by R 3 is a linear or branched alkyl group, and specific examples include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group and the like. Is mentioned.
- Examples of the aryl group having 6 to 10 carbon atoms represented by R 3 include a phenyl group, a xylyl group, and a tolyl group.
- Specific examples of the compound represented by the general formula (I) include the compounds described in paragraph 0073 of JP-A-2007-077327. Since the organosilicon compound represented by the general formula (I) has a curable group, the hard coat film 8 can be formed as a cured film by performing a curing treatment after application.
- the metal oxide particles can contribute to adjusting the refractive index of the cured film and improving the hardness.
- Specific examples of the metal oxide particles include tungsten oxide (WO 3 ), zinc oxide (ZnO), silicon oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), titanium oxide (TiO 2 ), and zirconium oxide (ZrO). 2 ), tin oxide (SnO 2 ), beryllium oxide (BeO), antimony oxide (Sb 2 O 5 ), and other particles. These particles can be used alone or in combination of two or more metal oxide particles.
- the particle size of the metal oxide particles is preferably in the range of 5 to 30 nm from the viewpoint of achieving both the scratch resistance and the optical characteristics of the cured film.
- the content of the metal oxide particles in the curable composition can be appropriately set in consideration of the refractive index and hardness of the formed cured film, and is usually about 5 to 80% by mass per solid content of the curable composition. It may be. Further, the metal oxide particles are preferably colloidal particles from the viewpoint of dispersibility in the cured film.
- the cured film is prepared by mixing a curable composition prepared by mixing the above components and, if necessary, an organic solvent, a surfactant (leveling agent), and optional components such as a curing agent, with the base material of the lens substrate 2.
- a coating film is formed by directly applying to the surface having the protrusions 6 or indirectly through another film to form a coating film.
- the coating film is subjected to a curing treatment (for example, heating and / or Or light irradiation). Details of the application of the curable composition will be described later. For example, when the curing treatment is performed by heating, the lens substrate 2 on which the coating film of the curable composition is formed is placed in an environment at an ambient temperature of 50 to 150 ° C. for about 30 minutes to 2 hours, so that the The curing reaction of the curable compound is advanced.
- the viscosity of the curable composition for forming a film on the surface of the lens substrate 2 having the substrate protrusions 6 may be in the range of 1 to 50 mPa ⁇ s from the viewpoint of suitability for application by spin coating. It is more preferably in the range of 1 to 40 mPa ⁇ s, and still more preferably in the range of 1 to 20 mPa ⁇ s.
- the viscosity in the present invention and the present specification refers to the viscosity at a liquid temperature of 25 ° C.
- a film generally called a primer film and contributing to the improvement of adhesion between layers can also be mentioned.
- a coating liquid capable of forming such a film a composition in which a resin component such as a polyurethane resin is dispersed in a solvent (water, an organic solvent, or a mixed solvent thereof) (hereinafter, referred to as a “dry-curable composition”) ").
- the solidification of such a composition proceeds by removing the solvent by drying. Drying can be performed by a drying process such as air drying or heat drying.
- the viscosity of the dry-solidifying composition for forming a film on the surface of the lens substrate 2 having the substrate convex portions 6 is in the range of 1 to 50 mPa ⁇ s from the viewpoint of application suitability by spin coating. Is preferably in the range of 1 to 40 mPa ⁇ s, and more preferably in the range of 1 to 20 mPa ⁇ s.
- the supply of the coating liquid for forming a film on the surface of the lens substrate 2 having the substrate convex portion 6 is performed by spin coating.
- the spin coating is performed, for example, by arranging the lens substrate 2 on a spin coater with the surface having the substrate convex portion 6 facing vertically upward and rotating the lens substrate 2 on the spin coater.
- the application can be performed by supplying the application liquid from above (for example, by discharging the application liquid from a nozzle disposed above the surface).
- the rotation speed of the lens substrate 2 in spin coating is preferably in the range of 10 to 3000 rpm (rotations per minute), and more preferably in the range of 50 to 2500 rpm from the viewpoint of forming a film having a more uniform film thickness. More preferably, it is more preferably in the range of 100 to 2000 rpm.
- a film can be formed by performing a process (for example, a curing process, a drying process, or the like) according to the type of the coating solution.
- the thickness of the film formed through the above steps may be, for example, in the range of 0.5 to 100 ⁇ m. However, the thickness of the film is determined according to the function required of the film, and is not limited to the above-described range.
- One or more films can be further formed on the film.
- a film examples include various films such as an antireflection film 10, a water-repellent or hydrophilic antifouling film, and an antifogging film.
- Known techniques can be applied to the method of forming these films.
- one surface of the lens substrate 2 does not have the substrate convex portion 6, one or more coatings can be formed on such a surface of the lens substrate 2.
- Such a coating include various coatings usually provided on the spectacle lens 1 (for example, a hard coat film 8, a primer film, an antireflection film 10, an antifouling film, an antifogging film, and the like).
- a publicly known technique can be applied to the above.
- the maximum value of the absolute value of the difference in the lens thickness direction between the film projection shape and the substrate projection shape is 0.1 ⁇ m or less (preferably 0.06 ⁇ m or less).
- the substantially partial spherical shape of the actual film projection 11 is compared with the actual partial spherical shape of the lens substrate 2.
- FIG. 12A is a schematic cross-sectional view showing the coating projection 11 and the base projection 6 of the actual spectacle lens 1.
- FIG. 12B is a schematic cross-sectional view in which the apex of the film projection 11 and the apex of the base material projection 6 are matched.
- the solid line indicates the coating convex portion 11 of the actual spectacle lens 1
- the broken line indicates the substrate convex portion 6
- the vertical line portion indicates the lens thickness direction between the coating convex shape and the substrate convex shape. Show the difference.
- the maximum value of the absolute value of this difference is 0.1 ⁇ m or less (preferably 0.06 ⁇ m or less), it is considered that the shape of the base projection 6 existing under the coating film can be faithfully followed. As a result, it has been found that the effect of suppressing myopia can be sufficiently exerted. By applying this rule, the effect of suppressing myopia can be sufficiently exhibited. Note that the similarity between the shape of the film convex portion 11 and the shape of the substrate convex portion 6 may be defined.
- the maximum value of the absolute value of the absolute value of the difference in the lens thickness direction between the spherical surface optimally approximated to the shape of the film convex portion 11 and the actual shape of the film convex portion 11 is set to 0.1.
- the thickness is 1 ⁇ m or less has been described.
- the spectacle lens 1 according to the present invention is not limited to the definition of the difference.
- the convex portion on the outermost surface of the spectacle lens 1 on the side having the base convex portion 6 allows a light beam incident on the spectacle lens 1 to reach a predetermined position even after the film is formed.
- the technical idea of the spectacle lens of one embodiment of the present invention described above can be applied to a spectacle lens having a function of suppressing hyperopia.
- the “projection” of the coating projection 11 and the substrate projection 6 is changed to “recess”.
- the coating concave portion causes the light beam incident on the spectacle lens to converge to a position B ′ closer to the “eyeball side” than the predetermined position A.
- the “convex portion” is changed to the “concave portion”, and the focus is converged to a position B ′ closer to the “eyeball side” than the predetermined position A.
- it is a spectacle lens having a hyperopia suppression function.
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Abstract
Description
眼鏡レンズの最表面にある凸部の形状を基材凸部近似形状とする場合、近視抑制効果が十分に発揮可能となるという知見を得た。
好適には、実際の被膜凸部形状から基材凸部形状(すなわち部分球面形状)を仮想する。この仮想部分球面形状と実際の被膜凸部形状とを比べたときに差異が所定の値に留まる場合、近視抑制効果が更に発揮可能となるという知見を得た。
本発明の第1の態様は、
物体側の面から入射した光線を眼球側の面から出射させて所定の位置Aに収束させる眼鏡レンズにおいて、
前記物体側の面と前記眼球側の面とのうち少なくとも一方の面に基材凸部を複数有するレンズ基材と、
前記基材凸部を有する面を覆う被膜と、
を備え、
前記基材凸部を有する側の眼鏡レンズの最表面にある凸部の形状は、前記眼鏡レンズに入射した光線を、前記所定の位置Aよりも物体側寄りの位置Bに収束させる基材凸部近似形状である、眼鏡レンズである。
前記被膜の最表面形状は、前記基材凸部に由来する被膜凸部を有し、
前記被膜凸部は、前記眼鏡レンズに入射した光線を、前記所定の位置Aよりも物体側寄りの位置Bに収束させ、
前記被膜凸部形状に対して最適近似させた球面と、実際の被膜凸部形状との間のレンズ厚さ方向での差の絶対値の最大値が0.1μm以下である、眼鏡レンズである。
前記被膜凸部は、前記眼鏡レンズに入射した光線を、前記所定の位置Aよりも物体側に0mmを超え且つ10mm以下の範囲で寄せた位置Bに収束させる。
光線追跡計算により得られる、前記眼鏡レンズの前記物体側の面の所定範囲内に均等に入射して前記被膜を通過する多数の光線のうち、前記所定の位置A近傍を通過せず、且つ、前記物体側寄りの位置B近傍も通過しない迷光光線の本数は入射光線本数の30%以下である。
前記被膜の最表面形状に対する非点収差分布における前記被膜凸部の根元での非点収差の断面曲線が0.20mm以下である。
前記被膜は、前記レンズ基材と接するλ/4膜と、前記λ/4膜の上に形成されたハードコート膜と、前記ハードコート膜の上に形成された反射防止膜とを有する。
前記レンズ基材の屈折率は前記λ/4膜よりも高く、前記λ/4膜の屈折率は前記ハードコート膜よりも高い。
図1では、物体側の面3が凸面であり、眼球側の面4が凹面である例(いわゆるメニスカスレンズの例)を挙げる。
図5は、本発明の一態様による眼鏡レンズの検査方法の流れを示すフローチャートである。
以上の工程により、光軸方向(レンズ厚さ方向、Z軸)における、光線が集光する位置を特定可能となる。
0.6≦Lc/Ll≦1.5 ・・・式(1)
この条件を満たせば、基材凸部6に被膜が形成されたとしても、基材凸部6に由来する被膜凸部11は、眼鏡レンズ1に入射した光線の収束位置Bを、前記所定の位置Aよりも物体側に十分に寄せられる。これは、被膜凸部11ひいては本発明の一態様の眼鏡レンズ1が、十分な近視抑制効果を発揮できることを意味する。
なお、突出距離は、眼鏡レンズ1の最表面形状のベース部分から被膜凸部11の頂点までの光軸方向(レンズ厚さ方向、Z軸)の距離である。
図11は、実際の被膜凸部11およびその近傍に対する非点収差分布における、被膜凸部11の頂点(すなわち平面視での被膜凸部の中心)を通過する断面での非点収差分布(すなわち非点収差断面曲線)のプロット(実線)を示す図である。
左縦軸は非点収差(および平均度数)の値を示し単位はディオプターである。
右縦軸は被膜凸部11または基材凸部6の高さを示し単位はmmである。
なお、被膜凸部11または基材凸部6は横軸において0.3~1.3mmの部分である。また、平均度数分布(すなわち平均度数分布断面曲線)のプロット(点線)、および被膜凸部11または基材凸部6のZ軸の高さのプロット(破線)も示す。
基材凸部6のサイズおよびレンズ基材2の表面における複数の基材凸部6の配置の態様は、特に限定されるものではなく、例えば、基材凸部6の外部からの視認性、基材凸部6によるデザイン性付与、基材凸部6による屈折力調整等の観点から決定できる。基材凸部6の高さは、例えば0.1~10μmとしてもよく、基材凸部6の表面の曲率半径は、例えば50~250mmRとしてもよい。また、隣り合う基材凸部6間の距離(ある基材凸部6の端部とこの基材凸部6と隣り合う基材凸部6の端部との距離)は、例えば基材凸部6の半径の値と同じ程度としてもよい。また、複数の基材凸部6は、例えばレンズ中心付近にほぼ均一に配置できる。
レンズ基材2の基材凸部6を有する表面上に形成される被膜の一態様としては、硬化性化合物を含む硬化性組成物を硬化して形成される硬化膜が挙げられる。かかる硬化膜は、一般にハードコート膜8と呼ばれ、眼鏡レンズ1の耐久性向上に寄与する。硬化性化合物とは硬化性官能基を有する化合物を意味し、硬化性組成物とは硬化性化合物を一種以上含む組成物を意味する。
(R1)a(R3)bSi(OR2)4-(a+b) ・・・(I)
R2で表される炭素数1~4のアシル基としては、例えば、アセチル基、プロピオニル基、オレイル基、ベンゾイル基等が挙げられる。
R2で表される炭素数6~10のアリール基としては、例えば、フェニル基、キシリル基、トリル基等が挙げられる。
R3で表される炭素数1~6のアルキル基は、直鎖または分岐のアルキル基であって、具体例としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基等が挙げられる。
R3で表される炭素数6~10のアリール基としては、例えば、フェニル基、キシリル基、トリル基等が挙げられる。
前記一般式(I)で表される化合物の具体例としては、特開2007-077327号公報の段落0073に記載されている化合物を挙げられる。一般式(I)で表される有機ケイ素化合物は硬化性基を有するため、塗布後に硬化処理を施すことにより、硬化膜としてハードコート膜8を形成できる。
。
レンズ基材2の基材凸部6を有する表面上に被膜を形成するための塗布液の供給は、スピンコートにより行われる。塗布をスピンコートで行うことにより、基材凸部6周辺に液溜まりが生じること等に起因して被膜の膜厚が不均一になることを抑制できる。スピンコートによる塗布は、例えば、スピンコーターに基材凸部6を有する表面を鉛直上方を向けてレンズ基材2を配置し、スピンコーター上でレンズ基材2を回転させた状態で、前記表面上に上方から塗布液を供給する(例えば前記表面の上方に配置されたノズルから塗布液を吐出する)ことにより行える。ここでスピンコートにおけるレンズ基材2の回転速度は、膜厚がより均一な被膜を形成する観点から、10~3000rpm(rotations per minute)の範囲とすることが好ましく、50~2500rpmの範囲とすることがより好ましく、100~2000rpmの範囲とすることが更に好ましい。
また、レンズ基材2の一方の表面が基材凸部6を有さない場合、そのようなレンズ基材2表面にも一層以上の被膜を形成できる。かかる被膜としては、眼鏡レンズ1に通常設けられる各種被膜(例えば、ハードコート膜8、プライマー膜、反射防止膜10、防汚膜、防曇膜等)を挙げることができ、これら被膜の形成方法についても公知技術を適用できる。
2 レンズ基材
3 物体側の面(凸面)
4 眼球側の面(凹面)
6 基材凸部
8 ハードコート膜
10 反射防止膜
11 被膜凸部
20 眼球
20A 網膜
30 眼鏡レンズモデル
32 眼球モデル
32A 網膜
33 モデル上での物体側の面(凸面)
36 モデル上での被膜凸部
Claims (7)
- 物体側の面から入射した光線を眼球側の面から出射させて所定の位置Aに収束させる眼鏡レンズにおいて、
前記物体側の面と前記眼球側の面とのうち少なくとも一方の面に基材凸部を複数有するレンズ基材と、
前記基材凸部を有する面を覆う被膜と、
を備え、
前記基材凸部を有する側の眼鏡レンズの最表面にある凸部の形状は、前記眼鏡レンズに入射した光線を、前記所定の位置Aよりも物体側寄りの位置Bに収束させる基材凸部近似形状である、眼鏡レンズ。 - 前記被膜の最表面形状は、前記基材凸部に由来する被膜凸部を有し、
前記被膜凸部は、前記眼鏡レンズに入射した光線を、前記所定の位置Aよりも物体側寄りの位置Bに収束させ、
前記被膜凸部形状に対して最適近似させた球面と、実際の前記被膜凸部形状との間のレンズ厚さ方向での差の絶対値の最大値が0.1μm以下である、請求項1に記載の眼鏡レンズ。 - 前記被膜凸部は、前記眼鏡レンズに入射した光線を、前記所定の位置Aよりも物体側に0mmを超え且つ10mm以下の範囲で寄せた位置Bに収束させる、請求項2に記載の眼鏡レンズ。
- 光線追跡計算により得られる、前記眼鏡レンズの前記物体側の面の所定範囲内に均等に入射して前記被膜を通過する多数の光線のうち、前記所定の位置A近傍を通過せず、且つ、前記物体側寄りの位置B近傍も通過しない迷光光線の本数は入射光線本数の30%以下である、請求項2または3に記載の眼鏡レンズ。
- 前記被膜の最表面形状に対する非点収差分布における前記被膜凸部の根元での非点収差の断面曲線の半値幅が0.20mm以下である、請求項2~4のいずれかに記載の眼鏡レンズ。
- 前記被膜は、前記レンズ基材と接するλ/4膜と、前記λ/4膜の上に形成されたハードコート膜と、前記ハードコート膜の上に形成された反射防止膜とを有する、請求項1~5のいずれかに記載の眼鏡レンズ。
- 前記レンズ基材の屈折率は前記λ/4膜よりも高く、前記λ/4膜の屈折率は前記ハードコート膜よりも高い、請求項6に記載の眼鏡レンズ。
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US17/255,411 US11880094B2 (en) | 2018-06-29 | 2019-06-27 | Eyeglass lens |
EP19826596.9A EP3816714A4 (en) | 2018-06-29 | 2019-06-27 | LENS |
KR1020207035198A KR102501015B1 (ko) | 2018-06-29 | 2019-06-27 | 안경 렌즈 |
SG11202010894UA SG11202010894UA (en) | 2018-06-29 | 2019-06-27 | Eyeglass lens |
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JP2021051006A (ja) * | 2019-09-25 | 2021-04-01 | ホヤ レンズ タイランド リミテッドHOYA Lens Thailand Ltd | 光学特性評価方法、眼鏡レンズの製造方法および眼鏡レンズ |
WO2021181885A1 (ja) | 2020-03-09 | 2021-09-16 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ |
CN113406811A (zh) * | 2020-03-17 | 2021-09-17 | 豪雅镜片泰国有限公司 | 眼镜镜片 |
WO2021186878A1 (ja) | 2020-03-17 | 2021-09-23 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ |
WO2021229889A1 (ja) | 2020-05-14 | 2021-11-18 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ |
WO2022044630A1 (en) | 2020-08-26 | 2022-03-03 | Hoya Lens Thailand Ltd. | Spectacle lens, design method for the same, and design system for the same |
WO2022059333A1 (ja) | 2020-09-18 | 2022-03-24 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ及びその設計方法 |
WO2022190610A1 (ja) | 2021-03-08 | 2022-09-15 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ及びその設計方法 |
WO2022201749A1 (ja) | 2021-03-22 | 2022-09-29 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ、および眼鏡レンズの設計方法 |
WO2023120007A1 (ja) | 2021-12-21 | 2023-06-29 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ、および眼鏡レンズの設計方法 |
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SG11202010901SA (en) * | 2018-06-29 | 2020-12-30 | Hoya Lens Thailand Ltd | Eyeglass lens |
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WO2022190610A1 (ja) | 2021-03-08 | 2022-09-15 | ホヤ レンズ タイランド リミテッド | 眼鏡レンズ及びその設計方法 |
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US20210278699A1 (en) | 2021-09-09 |
KR20210006439A (ko) | 2021-01-18 |
JP7213246B2 (ja) | 2023-01-26 |
EP3816714A1 (en) | 2021-05-05 |
CN112136076B (zh) | 2022-09-02 |
SG11202010894UA (en) | 2020-12-30 |
JPWO2020004551A1 (ja) | 2021-04-22 |
KR102501015B1 (ko) | 2023-02-21 |
CN112136076A (zh) | 2020-12-25 |
US11880094B2 (en) | 2024-01-23 |
EP3816714A4 (en) | 2022-03-30 |
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