WO2020002189A1 - Associations de principes actifs - Google Patents

Associations de principes actifs Download PDF

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Publication number
WO2020002189A1
WO2020002189A1 PCT/EP2019/066593 EP2019066593W WO2020002189A1 WO 2020002189 A1 WO2020002189 A1 WO 2020002189A1 EP 2019066593 W EP2019066593 W EP 2019066593W WO 2020002189 A1 WO2020002189 A1 WO 2020002189A1
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spp
methyl
species
plants
active
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PCT/EP2019/066593
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German (de)
English (en)
Inventor
Peter Jeschke
Marita JOHN
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Bayer Aktiengesellschaft
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Publication of WO2020002189A1 publication Critical patent/WO2020002189A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines

Definitions

  • the present application relates to mixtures of compounds of the formula (I) below with at least one further active ingredient or product which is preferably an insecticide or an acaricide or a nematicide or a fungicide, an antimicrobial compound or a biological crop protection agent.
  • active ingredients are suitable for controlling animal and microbial pests and as plant strengthening agents.
  • active substance combinations (synonymous with “active substance combinations” in the present application are the terms “active substance mixtures” and “mixtures”) containing a compound of the formula (I) and one or more active substances or products from the groups described below are synergistically effective and are suitable for controlling animal and microbial pests and as plant strengthening agents.
  • the present invention thus relates to active compound combinations comprising a compound of the formula (I)
  • a 1 and A 2 each represent CH and
  • R is a radical from the series H, F 2 HC, F 2 CIC, H 3 CF 2 C, F 3 C, Br, H 3 C, F and CI, or b) A 1 is N and A 2 is CH stands and
  • R is F 3 C or c) A 1 is CH and A 2 is N and RF 3 C stands, and one or more active ingredients or products from the groups described below.
  • the compounds of the formula (I) are therefore the compounds No. 1 to No. 11 listed in the following tables.
  • active compound combinations comprising a compound of the formula (I) and one or more active compounds or products from the groups described below are synergistically active and are suitable for controlling animal and microbial pests and as plant strengthening agents.
  • the mixtures according to the invention are preferably suitable for controlling animal and microbial pests.
  • the mixtures according to the invention are particularly preferably suitable for controlling animal pests.
  • the mixtures according to the invention are furthermore particularly preferably suitable for controlling microbial pests.
  • the mixtures according to the invention are particularly preferably also suitable as plant strengthening agents.
  • the active compound combinations according to the invention contain, in addition to Compound of formula (I) one or more mixing partners from the groups described below.
  • active substances mentioned can be used alone or in combination with other active substances for controlling animal pests.
  • the combination of tioxazafen and flupyradifurone can, if appropriate also in combination with other active ingredients, be used successfully to control nematodes, insects and other animal pests.
  • Acetylcholinesterase (AChE) inhibitors such as carbamates, e.g. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, lsoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Xmarbarboxam, Carboxulfate, Trimoxamatex, Carboxane Xylylcarb or organophosphate, e.g.
  • AChE Acetylcholinesterase
  • GABA-controlled chloride channel antagonists such as, for example, cyclodiene organochlorins, for example chlordanes and endosulfan or phenylpyrazoles (fiproles), for example ethiprols and fipronil.
  • Sodium channel modulators / voltage-dependent sodium channel blockers such as pyrethroids, for example acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin , Cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lRhr) -transin [(lRhr) -transin (EZ) - (lR) -is
  • Nicotinic Acetylcholine Receptor (nAChR) agonists such as neonicotinoids e.g. Acetamiprid, Dinotefuran, Imidacloprid, Nitenpyram, Thiacloprid and Thiamethoxam or Nicotine or Sulfoxaflor or Flupyradifurone.
  • nAChR Nicotinic Acetylcholine Receptor
  • Nicotinergic acetylcholine receptor (nAChR) allosteric activators such as spinosins e.g. Spinetoram and Spinosad.
  • chloride channel activators such as avermectine / milbemycine e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.
  • Juvenile hormone imitators such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen.
  • Active substances with unknown or non-specific mechanisms of action such as alkyl halides, e.g. Methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or borax or Brechweinstein.
  • mite growth inhibitors e.g. Clofentezine, hexythiazox and diflovidazine or etoxazole.
  • Microbial disruptors of the insect intestinal membrane e.g. Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, Cry3Ab, my3Ab, mC3Ab.
  • Inhibitors of oxidative phosphorylation such as diafenthiuron or organotin compounds such as azocyclotin, cyhexatin and fenbutatin oxide or propargite or tetradifone.
  • Decouplers of oxidative phosphorylation by breaking the H proton gradient such as chlorfenapyr, DNOC and sulfluramide.
  • Nicotinic acetylcholine receptor antagonists such as bensultap, cartap hydrochloride, thiocyclam and thiosultap sodium.
  • Inhibitors of chitin biosynthesis type 0, such as, for example, bistrifluron, chlorofluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, fufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
  • Chitin biosynthesis inhibitors type 1, such as buprofezin.
  • Ecdysone receptor agonists such as chromafenozide, halofenozide, methoxyfenozide and tebufenozide.
  • Inhibitors of acetyl-CoA carboxylase such as tetronic and tetramic acid derivatives, e.g. Spirobudiclofen, Spirodiclofen, Spiromesifen and Spirotetramat.
  • Complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide.
  • active ingredients such as, for example, afidopyropen, afoxolaner, azadirachtin, benclothiaz, benzoximate, bifenazate, broflanilide, bromopropylate, quinomethionate, cryolite, cyclaniliprole, cycloxaprid, cyhalodiamide dicloromezotiaz, dicofol, diflovidufen, flifulfonazine, flifulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfone, flofulfone Fluralaner, Fluxametamide, Fufenozide, guadipyr, heptafluthrin, imidaclothiz, iprodione, lotilaner,
  • the active compound combinations according to the invention preferably contain one or more mixing partners from the active compounds or products (preparations) listed below. This group of preferred mixed partners is referred to below as "Group A mixed partners":
  • Mixtures according to the invention comprising compound no. 1 and one or more mixing partners selected from group A are preferred.
  • Mixtures according to the invention containing compound no. 1 and exactly one (1) mixing partner selected from group A are also preferred.
  • Mixtures according to the invention are also preferred, comprising the compound No. 2 and one or several mixed partners selected from group A mixed partners.
  • Mixtures according to the invention containing compound No.2 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.
  • Mixtures according to the invention containing compound No.3 and one or more mixing partners selected from Group A are also preferred.
  • Mixtures according to the invention containing compound No.3 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.
  • Mixtures according to the invention containing compound no. 4 and one or more mixing partners selected from group A are also preferred.
  • Mixtures according to the invention containing compound No.4 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.
  • Mixtures according to the invention containing compound no. 5 and one or more mixing partners selected from group A are also preferred.
  • Mixtures according to the invention containing compound 5 and exactly one (1) mixing partner selected from group A are also preferred.
  • Mixtures according to the invention containing compound no. 6 and one or more mixing partners selected from group A are also preferred.
  • Mixtures according to the invention containing compound no. 6 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.
  • Mixtures according to the invention are also preferred which contain the compound No. 7 and one or more mixing partners selected from group A mixing partners.
  • Mixtures according to the invention are also preferred which contain the compound No. 7 and exactly one (1) mixing partner selected from Group A mixing partner.
  • Mixtures according to the invention containing compound no. 8 and one or more mixing partners selected from group A are also preferred.
  • Mixtures according to the invention containing compound 8 and exactly one (1) mixing partner selected from group A are also preferred.
  • Mixtures according to the invention are also preferred, comprising the compound No. 9 and one or several mixed partners selected from group A mixed partners.
  • Mixtures according to the invention containing compound No.9 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.
  • Mixtures according to the invention are also preferred, containing compound No.10 and one or more mixing partners selected from Group A mixing partners.
  • Mixtures according to the invention containing compound No.10 and exactly one (1) mixing partner selected from Group A are also preferred.
  • Mixtures according to the invention containing compound no. 11 and one or more mixing partners selected from group A are also preferred.
  • Mixtures according to the invention containing compound 11 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.
  • the insecticidal and / or acaricidal and / or the plant-strengthening and / or yield-increasing effect of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unforeseeable real synergistic effect and not just an addition to the effect.
  • the active compound combinations according to the invention can also be mixed with a further active compound, for example an insecticide / acaricide / nematicide.
  • the active compound combinations according to the invention are suitable with good plant tolerance, favorable warm-blood toxicity and good environmental compatibility for protecting plants and plant organs, for increasing crop yields, improving the quality of the crop and for combating animal pests, in particular insects, arachnids, helminths, nematodes and mollusks , which occur in agriculture, horticulture, animal husbandry, in forests, in gardens and leisure facilities, in the protection of stored goods and materials as well as in the hygiene sector. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the pests mentioned above include:
  • Pests from the Arthropoda strain in particular from the Arachnida class, for example Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp.
  • Bryobia graminum Bryobia praetiosa
  • Centruroides spp. Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranychus s.
  • Eriophyes spp. Glycyphagus domesticus, Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus spp., Neutrombicula autumnalis, Nuphersa spp., Oligonych., Oligonych spp., Panonychus spp., Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsoneusususus,.
  • Apogonia spp. Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferrugineus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerachna spp., Epicaerachna spp.
  • Melanotus spp. Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamynusisy.
  • Rhopalosiphum spp. Saissetia spp., Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninall Tileppa, sappharappa, sappharappa, saphata sara.
  • Toxoptera spp. Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the order of Hymenoptera, for example Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Fasius spp., Finepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp.
  • Paravespula spp. Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp .; from the order of the Isopoda, for example Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera, for example Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of Fepidoptera, for example Achroia grisella, Acronict
  • Animal parasites from the strains of the Plathelminthes and Nematoda e.g. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Anoplocephala spp., Ascarid sppia.
  • Plant pests from the Nematoda tribe i.e. plant-parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodericotpp ., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchichus spp.
  • Pratylenchus spp. Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., Tylenchch ., Xiphinema spp .;
  • active compound combinations comprising compounds of the formula (I) and one or more fungicidal active compounds from the groups described below and / or one or more biological crop protection agents are synergistically active and are suitable for controlling animal and microbial pests and as plant strengthening agents.
  • All of the above-mentioned mixing partners of classes (1) to (15) can, if they are capable of doing so on account of their functional groups, form salts with suitable bases or acids. All of the fungicidal mixture partners mentioned in classes (1) to (15) can optionally include tautomeric forms.
  • Inhibitors of ergosterol biosynthesis for example (1,001) cyproconazole, (1,002) difenoconazole, (1,003) epoxiconazole, (1,004) fenhexamide, (1,005) fenpropidine, (1,006) fenpropimorph, (1,007) fenpyrazamine, (1,008) fluquinconazole, ( 1,009) flutriafol, (1,010) imazalil, (1,011) imazalil sulfate, (1,012) ipconazole, (1,013) metconazole, (1,014) myclobutanil, (1,015) paclobutrazole, (1,016) prochloraz, (1,017) propiconazole, (1,018) prothioconazole (1,019) pyrisoxazole, (1,020) spiroxamine, (1,021) tebuconazole, (1,022) tetraconazo
  • Respiratory chain inhibitors on complex I or II for example (2,001) benzovindiflupyr, (2,002) bixafen, (2,003) boscalid, (2,004) carboxin, (2,006) flutolanil, (2,007) fluxapyroxad, (2,008) furametpyr, (2,009) isofetamide , (2,010) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2,011) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2,012) isopyrazam (anti-epimeric racemat 1RS, 4SR, 9SR), ( 2.013) isopyrazam (mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti-epimeric racemate 1RS, 4SR, 9SR), (2.014) isopyrazam (syn-epimeric enantiomer 1R
  • Respiratory chain inhibitors on complex III for example (3,001) ametoctradine, (3,002) amisulbromo, (3,003) azoxystrobin, (3,004) coumethoxystrobin, (3,005) coumoxystrobin, (3,006) cyazofamide, (3,007) dimoxystrobin, (3,007) (3,009) famoxadone, (3,010) fenamidon, (3,011) flufenoxystrobin, (3,012) fluoxastrobin, (3,013) kresoxim-methyl, (3,014) metominostrobin, (3,015) orysastrobin, (3,016) picoxystrobin, (3,017) pyraclostrobin, (3,018) Pyrametostrobin, (3.019) pyraoxystrobin, (3.020) trifloxystrobin (3.021) (2E) -2- ⁇ 2 - [( ⁇ [(IE) -l- (3-
  • inhibitors of mitosis and cell division for example (4,001) carbendazim, (4,002) diethofencarb,
  • Inhibitors of amino acid and / or protein biosynthesis for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline (7.005) pyrimethanil, (7.006) 3- (5-fluoro- 3,3,4,4-tetramethyl-3,4-dihydroisoquinoline-l-yl) quinoline.
  • inhibitors of ATP production for example (8.001) silthiofam.
  • Inhibitors of cell wall synthesis for example (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamide, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E) -3 - (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -l- (morpholin-4-yl) prop-2-en- 1 -one, (9.009) (2Z) -3- (4-tert-Butylphenyl) -3- (2-chloropyridin-4-yl) - 1 - (morpholin-4-yl) prop-2-en-1 -one.
  • Inhibitors of lipid and membrane synthesis for example (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl.
  • Inhibitors of melanin biosynthesis for example (11,001) tricyclazole, (11,002) 2,2,2-trifluoroethyl- ⁇ 3-nicthyl-1 - [(4-mct liy I heu zoy I) ani i no
  • Inhibitors of nucleic acid synthesis for example (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).
  • Signal transduction inhibitors for example (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozolin.
  • the active compound combinations according to the invention preferably contain one or more mixing partners from the active compounds listed below. This group of preferred mixed partners is referred to below as “Group B mixed partners”:
  • Azoxystrobin benzovindiflupyr, bixafen, carbendazim, carboxin, cyproconazole, cyprodinil, difenoconazole, diniconazole, dimethomorph, ethaboxam, fenamidone, fludioxonil, fluopicolide, fluoxastrobin, flutriafol, flutoluxpoloxilil, fluxifoxanil, fluxifoxanil mefenoxam, Mefentrifluconazole, metalaxyl, metconazole, myclobutanil, Oxathiapiprolin, pencycuron, penflufen, penthiopyrad, picoxystrobin Picarbutrazox, prochloraz, prothioconazole, Pydiflumetofen, pyraclostrobin, pyrimethanil, Quinofumelin, sedaxane, silthiofam, tebuconazole, t
  • Mixtures according to the invention containing compound no. 1 and one or more mixing partners selected from group B mixing partners are preferred.
  • Mixtures according to the invention containing compound no. 1 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.
  • Mixtures according to the invention containing compound no. 2 and one or more mixing partners selected from group B are also preferred.
  • Mixtures according to the invention containing compound No.2 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.
  • Mixtures according to the invention comprising compound no. 3 and one or more mixing partners selected from group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound No.3 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound no. 4 and one or more mixing partners selected from group B are also preferred.
  • Mixtures according to the invention containing compound no. 4 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.
  • Mixtures according to the invention containing compound no. 5 and one or more mixing partners selected from group B are also preferred.
  • Mixtures according to the invention containing compound No.5 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound no. 6 and one or more mixing partners selected from group B are also preferred.
  • Mixtures according to the invention containing compound 6 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.
  • Mixtures according to the invention containing compound no. 7 and one or more mixing partners selected from group B are also preferred. Mixtures according to the invention containing compound no. 7 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.
  • Mixtures according to the invention containing compound no. 8 and one or more mixing partners selected from group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound no. 8 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.
  • Mixtures according to the invention containing compound no. 9 and one or more mixing partners selected from group B are also preferred.
  • Mixtures according to the invention containing compound No.9 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound No.10 and one or more mixing partners selected from Group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound No.10 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound 11 and one or more mixing partners selected from group B mixing partners are also preferred.
  • Mixtures according to the invention containing compound 11 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.
  • fungicide in particular one of classes (1) to (15)
  • the resulting mixtures have an increased microbicidal action (compared to the microbial compound (s) within classes (1) to (15) ) and can be used to combat unwanted microorganisms such as fungi and bacteria in crop protection and material protection.
  • Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection to combat Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
  • pathogens of fungal and bacterial diseases that fall under the generic names listed above may be mentioned as examples, but not by way of limitation: Diseases caused by powdery mildew pathogens such as
  • Blumeria species such as, for example, Blumeria graminis
  • Podosphaera species such as, for example, Podosphaera leucotricha
  • Sphaerotheca species such as, for example, Sphaerotheca fuliginea
  • Uncinula species such as, for example, Uncinula necator
  • Gymnosporangium species such as, for example, Gymnosporangium sabinae
  • Hemileia species such as, for example, Hemileia vastatrix
  • Phakopsora species such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae
  • Puccinia species such as, for example, Puccinia recondita
  • Uromyces species such as, for example, Uromyces appendiculatus
  • Bremia species such as, for example, Bremia lactucae
  • Peronospora species such as, for example, Peronospora pisi or P. brassicae;
  • Phytophthora species such as, for example, Phytophthora infestans
  • Plasmopara species such as, for example, Plasmopara viticola
  • Pseudoperonospora species such as, for example, Pseudoperonospora humuli or
  • Pythium species such as, for example, Pythium ultimum
  • Leaf blotch diseases and leaf wilting caused by e.g.
  • Alternaria species such as, for example, Alternaria solani;
  • Cerco spora species such as, for example, Cercospora beticola
  • Cladosporium species such as, for example, Cladosporium cucumerinum
  • Cochliobolus species such as, for example, Cochliobolus sativus
  • Drechslera (Conidial form: Drechslera, Syn: Helminthosporium);
  • Colletotrichum species such as, for example, Colletotrichum lindemuthanium;
  • Cycloconium species such as, for example, Cycloconium oleaginum
  • Diaporthe species such as, for example, Diaporthe citri;
  • Elsinoe species such as, for example, Elsinoe fawcettii;
  • Gloeosporium species such as, for example, Gloeosporium laeticolor
  • Glomerella species such as, for example, Glomerella cingulata
  • Guignardia species such as, for example, Guignardia bidwelli;
  • Leptosphaeria species such as, for example, Leptosphaeria maculans;
  • Magnaporthe species such as, for example, Magnaporthe grisea
  • Mycosphaerella species such as, for example, Mycosphaerella graminicola and Mycosphaerella fijiensis; Phaeosphaeria species, such as, for example, Phaeosphaeria nodorum;
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramularia species such as, for example, Ramularia collo-cygni;
  • Rhynchosporium species such as, for example, Rhynchosporium secalis
  • Septoria species such as, for example, Septoria apii;
  • Typhula species such as, for example, Typhula incarnata
  • Venturia species such as, for example, Venturia inaequalis
  • Corticium species such as, for example, Corticium graminearum
  • Fusarium species such as, for example, Fusarium oxysporum
  • Gaeumannomyces species such as, for example, Gaeumannomyces graminis
  • Rhizoctonia species such as, for example, Rhizoctonia solani
  • Tapesia species such as, for example, Tapesia acuformis
  • Thielaviopsis species such as, for example, Thielaviopsis basicola;
  • Ear and panicle diseases (including corn on the cob), caused by e.g.
  • Alternaria species such as, for example, Alternaria spp .;
  • Aspergillus species such as, for example, Aspergillus flavus;
  • Cladosporium species such as, for example, Cladosporium cladosporioides
  • Claviceps species such as, for example, Claviceps purpurea
  • Fusarium species such as, for example, Fusarium culmorum
  • Gibberella species such as, for example, Gibberella zeae
  • Monographella species such as, for example, Monographella nivalis;
  • Sphacelotheca species such as, for example, Sphacelotheca reiliana
  • Tilletia species such as, for example, Tilletia caries
  • Urocystis species such as, for example, Urocystis occulta
  • Ustilago species such as, for example, Ustilago nuda
  • Aspergillus species such as, for example, Aspergillus flavus;
  • Botrytis species such as, for example, Botrytis cinerea
  • Penicillium species such as, for example, Penicillium expansum and Penicillium purpurogenum;
  • Sclerotinia species such as, for example, Sclerotinia sclerotiorum
  • Verticilium species such as, for example, Verticilium alboatrum
  • Phytophthora species such as, for example, Phytophthora cactorum
  • Pythium species such as, for example, Pythium ultimum
  • Rhizoctonia species such as, for example, Rhizoctonia solani
  • Sclerotium species such as, for example, Sclerotium rolfsii
  • Nectria species such as, for example, Nectria galligena
  • Monilinia species such as, for example, Monilinia laxa; Deformations of leaves, flowers and fruits caused by e.g.
  • Taphrina species such as, for example, Taphrina deformans
  • Esca species such as, for example, Phaeomoniella chlamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea; Flower and seed diseases caused by e.g.
  • Botrytis species such as, for example, Botrytis cinerea
  • Rhizoctonia species such as, for example, Rhizoctonia solani;
  • Helminthosporium species such as, for example, Helminthosporium solani; Diseases caused by bacterial pathogens such as
  • Xanthomonas species such as, for example, Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as, for example, Pseudomonas syringae pv. Lachrymans;
  • Erwinia species such as, for example, Erwinia amylovora
  • the following diseases of soybeans can preferably be combated:
  • Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora) infundaulifera.
  • Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye Leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifoliicta, Phyllostica leaf, Star Blight (Phomopsis sojae), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma Glycines Leaf, Stemphylium botryosum), target spot (Corynespora cassiicola)
  • Black Root Rot (Calonectria crotalariae), Charcoal Rot (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Rot, and Pod and Collar Rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Rot (Mycol Neocosmospora (Neocosmopspora vasinfecta), Pod and Stern Blight (Diaporthe phaseolorum), Stern Canker (Diaporthe phaseolorum var.
  • Preferred mixing ratios in which a compound of the formula (I) can be combined with the specified mixing partners are 3000: 1 to 1: 3000, 1000: 1 to 1: 1000, 750: 1 to 1: 750, 500: 1 to 1 : 500, 250: 1 to 1: 250, 200: 1 to 1: 200, 100: 1 to 1: 100, 95: 1 to 1: 95, 90: 1 to 1: 90, 85: 1 to 1: 85 , 80: 1 to 1:80, 75: 1 to 1: 75, 70: 1 to 1: 70, 65: 1 to 1: 65, 60: 1 to 1: 60, 55: 1 to 1:55, 45 : 1 to 1: 45, 40: 1 to 1:40, 35: 1 to 1:35, 30: 1 to 1:30, 20: 1 to 1:20, 15: 1 to 1:15, 10: 1 to 1:10, 9: 1 to 1: 9, 8: 1 to 1: 8, 7: 1 to 1: 7, 6: 1 to 1: 6 4: 1 to 1: 4, 3: 1 to 1: 3,
  • compounds of the formula (I) can be mixed with herbicides.
  • herbicidal mixture partners are: Acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim- sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminocyclopyrachlor-potassium, aminocyclopyrachlor-ammonium, aminopolachyramethyl, aminopolachyridium amyl amine aminate amine amine amine amine aminate amine amine amine amine amine amine amine aminophenachloromethyl amine aminate amine amine amine amine amine amine amine amine aminocyclopyrachloromethyl amine amine amine amine amine aminocyclopyrachloromethyl amine amine amine amine aminocyclopyrachloromethane atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin, be
  • Fruit / Vegetable Herbicides Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam;
  • Cereal herbicides isoproturon, bromoxynil, ioxynil, phenoxies, chlorosulfuron, clodinafop, diclofop, diflufenican, fenoxaprop, florasulam, fluroxypyr, metsulfuron, triasulfuron, flucarbazone, iodosulfuron, propolinidoxonosulfonone, propoxyidoxonazuronesulfonone Sulfosulfuron, pyrasulfotole, pyroxsulam, flufenacet, tralkoxydim, pyroxasulfone;
  • Corn herbicides Atrazine. Alachlor, Bromoxynil, Acetochlor, Dicamba, Clopyralid, (.S ') - I) micthcnainid, Glufosinate, Glyphosate, Isoxaflutole, (.S') - Metolachlor, Mesotrione, Nicosulfuron, Primisulfuron, Rimsulfuron, Sulcotrione, Topione Sulfurzone, Foramsulfurone Zone Saflufenacil, Thiencarbazone, Flufenacet, Pyroxasulfon; Rice herbicides: butachlor.
  • Sugar beet herbicides Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Fenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop;
  • Rapeseed herbicides Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim;
  • Mixtures of the compound of the formula (Ia) or mixtures of the active compound combinations according to the invention with glyphosate are particularly preferred. Mixtures of the compound of the formula (Ia) or mixtures of the active compound combinations according to the invention with glufosinates are also particularly preferred.
  • Suitable safeners are e.g. B. Cyprosulfamide, Isoxadifen-ethyl and Mefenpyr-diethyl.
  • Compounds of the formula (I) and mixtures according to the invention can also advantageously be mixed with FCOs or used in conjunction with FCOs.
  • Fipo-chito-oligosaccharides are able to influence plant growth and development.
  • FCOs mainly from Rhizobia spp. secreted play a key role in the stimulation of nodules in feguminoses by activating signals in certain growth hormones, nutrients and in plant metabolism.
  • FCOs have direct and indirect effects on various physiological processes. They supply the rhizosphere, microbial population with minerals, biochemical substances and nutrients and transport trace elements and growth regulators to stimulate plant growth.
  • Fipo-chito-oligosaccharides secreted by rhizosphere bacteria play a key role in stimulating nodules in the roots of feguminoses by activating signals at very low concentrations that initiate cell division at different locations in the root.
  • the structure of FCOs from different nodule bacteria (or rhizobia) has been elucidated (V. Suganaya et al., IJTA, 33 (1), 2015 and the literature cited therein).
  • the present invention further relates to formulations and use forms prepared therefrom as crop protection agents and / or pesticides such.
  • B. drench, drip and spray broths comprising at least one of the active compounds according to the invention.
  • the use forms contain further crop protection agents and / or pesticides and / or effect-enhancing adjuvants such as penetration enhancers, e.g. B. vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetative fatty acids such as rapeseed oil or soybean oil methyl esters or alkanol alkoxylates and / or spreading agents such as alkylsiloxanes and / or salts z.
  • B. vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetative fatty acids such as rapeseed oil or soybean oil methyl esters or alkanol alkoxylates and / or spreading agents such as al
  • organic or inorganic ammonium or phosphomium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or the retention-promoting agents such.
  • B. glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizers.
  • Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS) ; these and other possible types of formulations are described, for example, by Crop Life International and in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576.
  • the formulations may contain, in addition to one or more active substances according to the invention, further agrochemical active substances.
  • auxiliaries such as, for example, extenders, solvents, promoters of spontaneity, carriers, emulsifiers, dispersants, antifreezes, biocides, thickeners and / or other auxiliaries, such as, for example, adjuvants.
  • An adjuvant in this context is a component that improves the biological effect of the formulation without the component itself having a biological effect.
  • Examples of adjuvants are agents which promote retention, spreading behavior, adherence to the leaf surface or penetration.
  • formulations are made in a known manner, e.g. by mixing the active ingredients with auxiliaries such as extenders, solvents and / or solid carriers and / or other auxiliaries such as surface-active substances.
  • auxiliaries such as extenders, solvents and / or solid carriers and / or other auxiliaries such as surface-active substances.
  • the formulations are prepared either in suitable plants or before or during use.
  • Auxiliaries that can be used are substances that are suitable for imparting special properties, such as certain physical, technical and / or biological properties, to the formulation of the active ingredient or the use forms prepared from these formulations (such as usable crop protection agents such as spray liquors or seed dressings).
  • Suitable extenders are, for example, water, polar and non-polar organic chemical liquids, for example from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, can be etherified and / or esterified), the ketones (such as acetone, cyclohexanone), esters (also fats and oils) and (poly) ethers, the simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, the sulfones and sulfoxides (such as dimethyl sulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes
  • alcohols and polyols which may also be substituted, can
  • organic solvents can also be used as auxiliary solvents.
  • auxiliary solvents e.g. organic solvents
  • aromatics such as xylene, toluene or alkylnaphthalenes
  • chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride
  • aliphatic hydrocarbons such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • alcohols such as butanol or glycol and their ethers and esters
  • ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons such as e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, e.g. Methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide and water.
  • aromatic hydrocarbons e.g. Xylene, toluene or alkylnaphthalenes
  • chlorinated aromatic or aliphatic hydrocarbons e
  • Suitable carriers can be used.
  • the following are particularly suitable as carriers: e.g. Ammonium salts and natural rock meals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock meals, such as highly disperse silica, aluminum oxide and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used.
  • Suitable carriers for granules are: e.g.
  • broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.
  • Liquefied gaseous extenders or solvents can also be used.
  • Particularly suitable extenders or carriers are those which are gaseous at normal temperature and pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
  • emulsifiers and / or foaming agents, dispersants or wetting agents with ionic or nonionic properties or mixtures of these surface-active substances are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or Naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurate derivatives), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds Sulphates, sulphonates and phosphates, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, protein hydrolyzates
  • dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are present.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are present.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, anti-leveling agents or other agents which improve chemical and / or physical stability can also be present.
  • Foam-producing agents or defoamers may also be present.
  • formulations and use forms derived therefrom can also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and fecithins, and synthetic phospholipids.
  • additional auxiliaries can be mineral and vegetable oils.
  • auxiliaries can be contained in the formulations and the use forms derived therefrom.
  • additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestering agents, complexing agents, humectans, spreading agents.
  • the active ingredients can be combined with any solid or liquid additive that is commonly used for formulation purposes.
  • penetration promoters are all those substances that are usually used to improve the penetration of agrochemical active substances into plants.
  • Penetration promoters are defined in this context by the fact that they flow from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant penetrate and thereby increase the mobility of the active substances in the cuticle.
  • the method described in the literature can be used to determine this property.
  • Examples include alcohol alkoxylates such as coconut fat ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil methyl esters, fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • alcohol alkoxylates such as coconut fat ethoxylate (10) or isotridecyl ethoxylate (12)
  • fatty acid esters such as rapeseed oil or soybean oil methyl esters
  • fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • plants and parts of plants can be treated.
  • Plants are understood here to mean all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
  • the plants which can be treated with the active compound combinations according to the invention include, for. B.
  • turf, vines, cereals for example wheat, barley, rye, oats, rice, corn and millet, triticale
  • Beets for example sugar beets and fodder beets
  • Fruits for example pome fruit, stone fruit and soft fruit, for example apples, pears, plums, peaches, almonds, cherries and berries, e.g. B.
  • Legumes for example beans, lentils, peas and soybeans;
  • Oil crops for example rapeseed, mustard, poppy seeds, olives, sunflowers, coconut, castor oil plants, cocoa beans and peanuts;
  • Cucumber plants for example pumpkin, cucumber and melons;
  • Fiber plants for example cotton, flax, hemp and jute;
  • Citrus fruits for example oranges, lemons, grapefruit and mandarins;
  • Vegetables for example spinach, (head) salad, asparagus, cabbages, carrots, onions, tomatoes, potatoes and peppers;
  • Laurel plants for example avocado, cinnamomum, camphor, or plants such as tobacco, nuts, coffee, eggplant, sugar cane, tea, pepper, grapevines, hops, bananas, natural rubber plants and ornamental plants, for example flowers, shrubs, deciduous trees and conifers such as conifers. This list is not a limitation.
  • Plant parts are to be understood to mean all above-ground and underground parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes .
  • the plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.
  • the treatment of the plants and plant parts according to the invention with the active compound combinations is carried out directly or by acting on their environment, habitat or storage space according to usual treatment methods, e.g. by dipping, (spraying) spraying, (spraying), sprinkling, vaporizing, atomizing, pouring, atomizing, (scattering) scattering, foaming, brushing, spreading, injecting, pouring (drenching), drip irrigation and in the case of propagation material, in particular seeds, also by means of dry pickling, wet pickling, slurry pickling, incrustation, single- or multi-layer coating.
  • usual treatment methods e.g. by dipping, (spraying) spraying, (spraying), sprinkling, vaporizing, atomizing, pouring, atomizing, (scattering) scattering, foaming, brushing, spreading, injecting, pouring (drenching), drip irrigation and in the case of propagation material, in particular seeds, also by means of dry pickling, wet
  • a preferred direct treatment for the plants is leaf application, i.e. the active compound combinations according to the invention are applied to the foliage, the treatment frequency and the application rate being adapted to the infestation pressure of the respective pest.
  • the active compound combinations according to the invention reach the plants via the root system.
  • the plants are then treated by the action of the active compound combinations according to the invention on the plant's habitat.
  • This can be, for example, by drenching, mixing into the soil or the nutrient solution, i.e. the location of the plant (e.g. soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations according to the invention, or by the soil application, i.e. the active compound combinations according to the invention are introduced in solid form (e.g. in the form of granules) into the location of the plants.
  • this can also be done by metering the invention into a solid application form (e.g. as granules) in a flooded rice field.
  • the present invention therefore also relates in particular to a method for protecting seed and germinating plants from attack by pests by treating the seed with the active compound combinations according to the invention.
  • the method according to the invention for protecting seed and germinating plants from pest infestation comprises a method in which the seed is treated simultaneously with the active ingredient of the formula (Ia) and mixing partner in one operation. It also includes a process in which the seed is treated at different times with the active ingredient of the formula (Ia) and mixing partner.
  • the invention also relates to the use of the active compound combinations according to the invention for the treatment of seeds for protecting the seeds and the plant resulting therefrom from animal pests.
  • the invention further relates to seeds which have been treated with the active compound combinations according to the invention for protection against animal pests.
  • the invention also relates to seeds which have been treated at the same time with the active ingredient of the formula (Ia) and mixing partner.
  • the invention further relates to seeds which have been treated at different times with the active ingredient of the formula (Ia) and mixing partner.
  • the individual active ingredients of the composition according to the invention can be present on the seed in different layers his.
  • the layers which contain the active ingredient of the formula (Ia) and mixing partner can optionally be separated by an intermediate layer.
  • the invention also relates to seeds in which the active ingredient of the formula (Ia) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.
  • the invention relates to seeds which, after treatment with the active compound combinations according to the invention, are subjected to a film coating process in order to avoid dust abrasion on the seeds.
  • One of the advantages of the present invention is that, because of the special systemic properties of the agents according to the invention, the treatment of the seeds with these agents not only protects the seeds themselves, but also the plants resulting therefrom after emergence from animal pests. In this way, the immediate treatment of the crop at the time of sowing or shortly thereafter can be omitted.
  • active ingredient combinations according to the invention can also be used in particular with transgenic seeds.
  • plant species and plant cultivars which occur wildly or are obtained by conventional biological breeding methods, such as hybridization or protoplast fusion, and parts thereof are treated.
  • the traditional propagation and breeding methods can be supported or supplemented by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or by bioengineering methods and genetic engineering methods.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated.
  • heterologous gene essentially means a gene that is provided or assembled outside of the plant or plant cell and that, when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, gives the transformed plant new or improved agronomic or other characteristics imparts by expressing a protein or polypeptide of interest or by down-regulating or switching off another gene present in the plant or other genes present in the plant (eg using antisense technology, cosuppression technology, RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)).
  • RNAi technology RNA interference technology
  • miRNA technology microRNA technology
  • Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.
  • the treatment according to the invention can also cause superadditive (“synergistic") effects.
  • superadditive for example, reduced application rates and / or widening of the spectrum of action and / or an increase in the action of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance , easier harvesting, acceleration of ripening, higher crop yields, larger fruits, higher plant height, more intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruit, higher storage life and / or workability of the harvested products possible that go beyond the expected effects.
  • the preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which, through the genetic engineering modification, have received genetic material which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • transgenic plants are the important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted.
  • the traits are particularly emphasized as the increased defense of the plants against insects by toxins arising in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF as well as their combinations) are produced in the plants (hereinafter "Bt plants”).
  • the properties (“traits”) which are particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example “PAT” gene).
  • the genes conferring the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants.
  • Examples of "Bt plants” are corn varieties, cotton varieties, soy varieties and potato varieties which are marketed under the trade names YIELD GARD ® (e.g. corn, cotton, soy), KnockOut ® (e.g. corn), StarLink ® (e.g.
  • herbicide-tolerant plants are maize varieties, cotton varieties and soy varieties that are sold under the trade names Roundup Ready ® (tolerance to glyphosate e.g. corn, cotton, soy), Liberty Link ® (tolerance to phosphinotricin, e.g. rape), IMI ® (tolerance to Imidazolinone) and STS ® (tolerance to sulfonylureas such as maize).
  • Herbicide-resistant plants (bred conventionally for herbicide tolerance) plants also sold under the name Clearfield ® varieties (eg maize) are mentioned. Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").
  • the plants listed can be treated particularly advantageously according to the invention with the active compound mixtures according to the invention.
  • the preferred ranges given above for the active ingredient combinations also apply to the treatment of these plants.
  • Plant treatment with the active ingredient combinations specifically listed in the present text should be particularly emphasized.
  • a synergistic effect is always present when the effect of the active ingredient combinations is greater than the expected effect calculated according to Colby from the effects of the individually applied active ingredients.
  • X means the degree of destruction, expressed in% of the untreated control, when the active compound A is used in an application rate of m g / ha or in a concentration of m ppm,
  • Y means the degree of destruction, expressed in% of the untreated control, when the active compound B is used in an application rate of n g / ha or in a concentration of n ppm and
  • E means the degree of destruction, expressed in% of the untreated control, when the active compounds A and B are used in application rates of m and ng / ha or in a concentration of m and n ppm, then If the actual kill rate is greater than the calculated kill rate (E), the combination is superadditive in its kill, ie there is a synergistic effect.
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by diluting with water containing emulsifier.
  • Chinese cabbage leaf slices (Brassica pekinensis), which are affected by all stages of the green peach aphid (Myzus persicae), are sprayed with an active ingredient preparation of the desired concentration.
  • the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed.
  • the determined kill rates are calculated using the Colby formula (see sheet 1).
  • Emulsifier alkylaryl polyglycol ether
  • the kill is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed.
  • the determined kill rates are calculated using the Colby formula (see sheet 1). In these tests, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. To prepare further test concentrations, dilute with water containing emulsifier.
  • Rice plants (Oryza sativa) are sprayed with the active ingredient preparation of the desired concentration and then infected with the brown-backed rice leafhopper (Nilaparvata lugens).
  • the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed.
  • the determined kill rates are calculated using the Colby formula (see sheet 1).
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further Test concentrations are obtained by dilution with water containing emulsifiers. If it is necessary to add ammonium salts and / or penetration enhancers, these are each added to the preparation solution in a concentration of 1000 ppm.
  • Savoy plants (Brassica oleracea), which are heavily infested with the green peach aphid (Myzus persicae), are treated by spraying with the active ingredient preparation in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined mortality values are calculated using the Colby formula (see sheet 1). In this test, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:

Abstract

L'invention concerne des associations de principes actifs contenant, d'une part, des composés connus de la formule (I) et, d'autre part, au moins un autre principe actif, et destinées à la lutte contre des parasites animaux.
PCT/EP2019/066593 2018-06-27 2019-06-24 Associations de principes actifs WO2020002189A1 (fr)

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Cited By (1)

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