WO2019186266A2 - Procédé de fabrication d'une couche monocristalline de matériau ain et substrat pour croissance par épitaxie d'une couche monocristalline de matériau ain - Google Patents
Procédé de fabrication d'une couche monocristalline de matériau ain et substrat pour croissance par épitaxie d'une couche monocristalline de matériau ain Download PDFInfo
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- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/38—Nitrides
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/18—Epitaxial-layer growth characterised by the substrate
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- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B23/00—Single-crystal growth by condensing evaporated or sublimed materials
- C30B23/02—Epitaxial-layer growth
- C30B23/025—Epitaxial-layer growth characterised by the substrate
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/18—Epitaxial-layer growth characterised by the substrate
- C30B25/183—Epitaxial-layer growth characterised by the substrate being provided with a buffer layer, e.g. a lattice matching layer
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/36—Carbides
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/40—AIIIBV compounds wherein A is B, Al, Ga, In or Tl and B is N, P, As, Sb or Bi
- C30B29/403—AIII-nitrides
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B33/00—After-treatment of single crystals or homogeneous polycrystalline material with defined structure
- C30B33/06—Joining of crystals
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- H—ELECTRICITY
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02367—Substrates
- H01L21/0237—Materials
- H01L21/02373—Group 14 semiconducting materials
- H01L21/02381—Silicon, silicon germanium, germanium
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02436—Intermediate layers between substrates and deposited layers
- H01L21/02439—Materials
- H01L21/02441—Group 14 semiconducting materials
- H01L21/02447—Silicon carbide
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
- H01L21/0254—Nitrides
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02587—Structure
- H01L21/0259—Microstructure
- H01L21/02598—Microstructure monocrystalline
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02436—Intermediate layers between substrates and deposited layers
- H01L21/02439—Materials
- H01L21/02488—Insulating materials
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
- H01L21/02546—Arsenides
Definitions
- the present invention relates to a method of manufacturing a monocrystalline layer of aluminum nitride material (AIN) and a substrate for the epitaxial growth of such a monocrystalline layer of AlN material.
- AIN aluminum nitride material
- Some materials are not currently available as a monocrystalline wafer substrate in large diameter. And some materials are possibly available in large diameter but not according to certain characteristics or specifications in terms of quality, particularly vis-à-vis the density of defects or the electrical or optical properties required.
- the present invention aims to overcome these limitations of the state of the art by providing a method of manufacturing a monocrystalline layer of AlN material and a substrate for the epitaxial growth of such a monocrystalline layer of AlN material. By this it is possible to overcome the size problem of the monocrystalline AIS material substrates currently available.
- the invention relates to a method for producing a monocrystalline layer of AlN material comprising transferring a monocrystalline seed layer of SiC-6H material to a substrate material support. silicon followed by epitaxial growth of the monocrystalline layer of AlN material.
- the monocrystalline seed layer has a thickness less than 10 ⁇ m, preferably less than 2 ⁇ m, and more preferably less than 0.2 ⁇ m.
- the transfer of the monocrystalline seed layer of SiC-6H material to the silicon material support substrate comprises a step of assembling a monocrystalline substrate of SiC-6H material on the support substrate followed by a step thinning said monocrystalline substrate of SiC-6H material.
- the thinning step comprises the formation of an embrittlement zone delimiting a portion of the monocrystalline substrate of SiC-6H material intended to be transferred onto the support substrate of silicon material.
- the formation of the embrittlement zone is obtained by implantation of atomic and / or ionic species.
- the thinning step comprises a detachment at the weakening zone so as to transfer said portion of the monocrystalline substrate of SiC-6H material to the silicon material support substrate, in particular the detachment comprises application of a thermal and / or mechanical stress.
- the assembly step is a molecular adhesion step.
- the monocrystalline seed layer of SiC-6H material is in the form of a plurality of blocks each transferred to the silicon material support substrate.
- the silicon material support substrate comprises a removable interface configured to be disassembled by laser peeling and / or chemical etching and / or mechanical biasing.
- the invention also relates to a substrate for epitaxial growth of a monocrystalline layer of AlN material, characterized in that it comprises a monocrystalline seed layer of SiC-6H material on a support substrate of silicon material.
- the monocrystalline seed layer of SiC-6H material is in the form of a plurality of cobblestones.
- the silicon material support substrate comprises a removable interface configured to be disassembled by laser peeling and / or chemical etching and / or mechanical biasing.
- the invention also relates to a method for manufacturing a monocrystalline layer of Al x ln y Ga z AsiP m Nn material having a mesh parameter close to that of the AlN material comprising the transfer of a monocrystalline seed layer of SrTiC> 3 material. on a support substrate of silicon material followed by growth by epitaxy of a monocrystalline layer of Al x ln y Ga z AsiP m N n material .
- the invention also relates to a method for manufacturing a monocrystalline layer of Al x ln y Ga z AsiP m N n material having a mesh parameter close to that of the AlN material comprising the transfer of a monocrystalline seed layer of YSZ material or Ce0 2 or MgO or Al 2 0 3 , on a support substrate of silicon material followed by growth by epitaxy of a monocrystalline layer of Al x ln y Ga z AsiPmNn material.
- the invention also relates to a substrate for growth by epitaxy of a monocrystalline layer of Al x ln y Ga z AsiP m N n material having a mesh parameter close to that of the AlN material, characterized in that it comprises a monocrystalline seed layer. of material SrTiO3 or YSZ or Ce0 2 or MgO or Al 2 0 3 on a support substrate of silicon material.
- FIG. 1 illustrates a method of manufacturing a monocrystalline layer of AlN material according to one embodiment of the invention as well as a substrate for the epitaxial growth of such a monocrystalline layer of AlN material according to this embodiment. of the invention
- FIG. 2 illustrates a method of manufacturing a monocrystalline layer of AlN material according to another embodiment of the invention as well as a substrate for growth by epitaxy. such a monocrystalline layer of AlN material according to this other embodiment of the invention;
- FIG. 3 illustrates a method of manufacturing a monocrystalline layer of AlN material according to yet another embodiment of the invention as well as a substrate for the epitaxial growth of such a monocrystalline layer of AlN material according to this other. embodiment of the invention
- FIG. 4 illustrates a method of manufacturing a monocrystalline layer of AlN material according to yet another embodiment of the invention as well as a substrate for the epitaxial growth of such a monocrystalline layer of AlN material according to this other. embodiment of the invention
- FIG. 5 illustrates a method for manufacturing a monocrystalline layer of AlN material according to yet another embodiment of the invention as well as a substrate for the epitaxial growth of such a monocrystalline layer of AlN material according to this other. embodiment of the invention
- FIG. 1 illustrates a support substrate 100 of silicon material on which a monocrystalline seed layer 200 of SiC-6H material is transferred.
- the support substrate 100 of silicon material can also be replaced by a support substrate 100 of sapphire material.
- the use of silicon has the advantage of opening up the field of application of AIN material films not only to large 300 mm equipment but also to make the microelectronics industry compatible for which the requirements in terms of acceptance on the production line of exotic material other than silicon, in particular AIN, are high.
- the assembly step 1 'of the monocrystalline seed layer 200 of SiC-6H material on the support substrate 100 of silicon material is preferentially done by a molecular bonding step.
- This molecular adhesion step comprises a bonding step, preferably at ambient temperature, and is followed by a consolidation annealing of the bonding interface which is usually carried out at elevated temperatures up to 900 ° C. or even 1100 ° C. for a period of a few minutes to a few hours.
- the assembly step 1 'of the monocrystalline seed layer on the support substrate is also preferentially by a molecular adhesion step using typical conditions of the same order of magnitude as mentioned. above.
- FIG. 1 schematically represents the assembly step 1 'of a monocrystalline substrate 20 of SIC-6H material on the support substrate 100 of silicon material. It follows a step of thinning 2 'of the monocrystalline substrate 20 of SiC-6H material after being assembled on the support substrate 100 of silicon material.
- FIG. 1 schematically represents the thinning step 2 'which can be implemented for example by chemical and / or mechanical etching (polishing, grinding, milling, etc.).
- the monocrystalline seed layer 200 of SiC-6H material can be obtained which will serve as the monocrystalline seed of a 3 'growth step by epitaxy of the monocrystalline layer 300 of AlN material made on the substrate for epitaxial growth of a layer.
- monocrystalline material INS 10 shown schematically in Figure 1.
- the skilled person could adjust the parameters used for a epitaxial growth of a monocrystalline layer of AIN material usually used during homoepitaxy or heteroepitaxy on a bulk monocrystalline substrate in order to optimize the 3 'growth step by epitaxy of the monocrystalline layer 300 of AIN material made on the substrate for epitaxial growth of a monocrystalline layer of AIN material 10 of the present invention.
- the epitaxy of the material AIN is therefore by MOCVD or MBE or HVPE known to those skilled in the art.
- the present invention is, moreover, not limited to an epitaxy of the AlN material but extends to certain Al x ln y Ga z AsiP m N n composites having a mesh parameter close to that of the AlN material.
- the thermal expansion coefficient of the support substrate 100 predominates the thermal behavior of the substrate for epitaxial growth of a monocrystalline layer of AlN material 10 during the 3 'epitaxial growth step of the monocrystalline layer 300. of AIN material. This is due to the thin thickness, preferably less than 1 miti, of the monocrystalline seed layer 200 of SiC-6H material relative to the total thickness of the substrate for epitaxial growth of a monocrystalline layer of AIN material 10 which is of the order of several tens to hundreds of pm.
- the SiC-6H material is also chosen to provide a monocrystalline seed layer having a mesh parameter as close as possible to the mesh parameter chosen for the monocrystalline layer 300 of AlN material, preferably the relaxed state mesh parameter in order to allow epitaxial growth inducing as few defects as possible in the monocrystalline layer 300 of AlN material.
- the material of the support substrate 100 advantageously also has a thermal expansion coefficient that is particularly close to the thermal expansion coefficient of the AlN material for the same reasons of reducing defects in the monocrystalline layer 300 obtained by epitaxy.
- a support substrate 100 of sapphire material for the present invention would be used.
- FIG. 2 diagrammatically represents an embodiment of the method for manufacturing a monocrystalline layer of AlN material that differs from the embodiment described with reference to FIG.
- the monocrystalline substrate 20 'of SiC-6H material is subjected to a 0 "implantation step of atomic and / or ionic species to form an embrittlement zone delimiting a portion 200 'of monocrystalline substrate 20' of SiC-6H material intended to be transferred onto the support substrate 100 'of silicon material
- the thinning step 2 "comprises a detachment at this embrittlement zone so as to transfer said portion 200 'of the monocrystalline substrate 20' of SiC-6H material to the support substrate 100 'of silicon material, in particular this detachment comprises the application of a thermal and / or mechanical stress.
- the advantage of this embodiment is thus to be able to recover the remaining portion 201 of the monocrystalline substrate 20 'of starting SiC-6H material that can be used again to undergo the same process again and thus reduce costs .
- the substrate for epitaxial growth of a monocrystalline layer of AlN material 10 'thus illustrated in FIG. 2 serves for the growth step 3 "of the monocrystalline layer 300' of AlN material as already described during the process described in connection with Figure 1.
- the implantation step 0 is done with hydrogen ions.
- An interesting alternative well known to those skilled in the art is to replace all or part of the hydrogen ions with helium ions.
- a hydrogen implantation dose will typically be between 6x10 16 cm 2 and 1x10 17 cm 2 .
- the implantation energy will typically be between 50 to 170 keV.
- the detachment is typically at temperatures between 550 and 750 ° C. Thicknesses of the monocrystalline seed layer of the order of 200 nm to 1.5 ⁇ m are thus obtained.
- additional technological steps are advantageously added in order to reinforce the interface of bonding, either to recover a good roughness, or to heal the defects possibly generated during the implantation step or to prepare the surface of the seed layer for epitaxial growth. These steps are, for example, polishing, chemical etching (wet or dry), annealing, chemical cleaning. They can be used alone or in combination that those skilled in the art can adjust.
- FIG. 3 differs from the embodiments described with reference to FIG. 1 and FIG. 2 in that the substrate for epitaxial growth of a monocrystalline layer of AIN material (10, 10 ') comprises a demountable interface 40' configured to to be dismantled.
- a support substrate 100 of silicon material it may be a rough surface, for example silicon material assembled with the monocrystalline seed layer during the assembly step. Or a rough interface may be present within the support substrate 100 of silicon material, the latter for example obtained by assembling two silicon wafers.
- Another embodiment would be to introduce at the level of the face to be assembled with the monocrystalline seed layer a porous silicon layer capable of fracturing during the application of a mechanical and / or thermal stress, for example by insertion of a plate edge blade known to those skilled in the art or by the application of annealing.
- this interface is chosen so as to withstand the other mechanical and / or thermal stresses undergone during the process of the present invention (eg detachment, growth by epitaxy, etc.).
- a sapphire material support substrate it may be a stack of silicon oxide, silicon nitride and silicon oxide (so-called ONO type structure) made on the face of the sapphire to assemble with the monocrystalline seed layer.
- Such a stack is susceptible to detachment at the level of the silicon nitride layer during a laser application passing through the sapphire support substrate (detachment or detachment type "laser lift off").
- detachment or detachment type "laser lift off” The skilled person will identify other methods of realization of this removable interface.
- FIG. 4 diagrammatically represents an embodiment of the method for manufacturing a monocrystalline layer of AlN material which differs from the embodiments described with reference to FIG. 1, FIG. 2 and FIG. 3 in that the seed layer
- the monocrystalline 2000 'material SiC-6H is in the form of a plurality of blocks (2001', 2002 ', 2003') each transferred to the support substrate 100 "of silicon material.
- the different pavers can be in any form (square, hexagonal, strips, ...) and with different sizes ranging from a few mm 2 to several cm 2 .
- the spacing between the chips may also vary significantly depending on whether a maximum density of coverage is sought (in this case preferentially a spacing of less than 0.2 mm will be chosen) or, on the contrary, maximum dissemination of the blocks within the substrate ( in this case the spacing may be several millimeters and even centimeters).
- a maximum density of coverage in this case preferentially a spacing of less than 0.2 mm will be chosen
- maximum dissemination of the blocks within the substrate in this case the spacing may be several millimeters and even centimeters.
- the skilled person could apply the transfer he wants and is not limited to a particular method. Thus one could consider applying the technical information described in connection with the method illustrated schematically in Figure 1 or the technical information described in connection with the method illustrated schematically in Figure 2, see even a combination of both.
- FIGS. 1 to 4 thus open the possibility of co-integration of components made in the monocrystalline layer of AlN material with components made in the support substrate of silicon material.
- the latter may simply be a silicon substrate, but it may also be an SOI type substrate comprising a silicon oxide layer separating a silicon substrate from a thin layer of silicon.
- access to the support substrate can be done simply by lithography and etching known to those skilled in the art.
- FIG. 5 diagrammatically represents an embodiment which differs from the embodiment described with reference to FIG. 4 in that the support substrate 100 "as well as subsequently the substrate for epitaxial growth of a monocrystalline layer of AIN material 10 "comprises a removable interface 40 configured to be disassembled, for example by a laser lift off technique and / or chemical etching and / or mechanical stressing. This would make it possible to remove a portion of the support substrate 100 "as already mentioned in connection with FIG. 3.
- An example would be the use of a support substrate 100 of the SOI type comprising a silicon oxide layer separating a silicon substrate. a thin layer of silicon.
- This oxide layer could be used as a removable interface 40 by selective etching of this oxide layer, for example by immersion in a hydrofluoric acid (HF) bath.
- HF hydrofluoric acid
- This option of dismantling by chemical etching of a buried layer is particularly advantageous when it comes in combination with the treatment of a plurality of small substrates. Indeed, the radius of action under-engraving is generally limited to a few centimeters or even a few millimeters if it is desired to maintain commercially reasonable conditions and processing times.
- the treatment of a plurality of small substrates allows the start of several chemical etching fronts thanks to possible access of the buried layer between each block, and no longer only on the extreme edges of the substrates which can be up to 300mm in diameter . In the case of an SOI support substrate it is thus possible to partially remove the thin layer of silicon between the blocks to allow the start of several etching fronts.
- the thin silicon layer having a predetermined thickness (which can vary between 5 nm and 600 nm, or even thicker depending on the intended application) could thus be used to form microelectronic components and thus enable the co-integration of components with base of AIN materials in the same substrate.
- the monocrystalline layer (3001, 3002, 3003) one could also imagine an assembly of this structure on a final substrate and dismount at the demountable interface 40 a portion of the support substrate 100 ".
- the final substrate can thus provide additional functionalities that are, for example, incompatible with growth parameters previously performed (for example, flexible plastic type end substrate or final substrate comprising metal lines).
- the removable interface is not necessarily located inside the support substrate but can also be at the interface with the seed layer of SiC-6H material assembled on this support substrate (for example a stack a layer of silicon nitride between two silicon oxide layers allows a laser detachment, particularly suitable for a sapphire-type support substrate) as already described in connection with FIG.
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Abstract
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Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201980021416.2A CN111902571A (zh) | 2018-03-28 | 2019-03-26 | AlN材料单晶层的制造方法和外延生长AlN材料单晶膜的衬底 |
JP2020549815A JP7451846B2 (ja) | 2018-03-28 | 2019-03-26 | AlN材料の単結晶膜を生成するための方法、及びAlN材料の単結晶膜をエピタキシャル成長させるための基板 |
SG11202009411SA SG11202009411SA (en) | 2018-03-28 | 2019-03-26 | Method for producing a single-crystal film of aln material and substrate for the epitaxial growth of a single-crystal film of aln material |
KR1020207030232A KR102640296B1 (ko) | 2018-03-28 | 2019-03-26 | AlN 재질의 단결정 층을 제조하는 방법 및 AlN 재질의 단결정 층의 에피택셜 성장을 위한 기판 |
EP19759725.5A EP3775333A2 (fr) | 2018-03-28 | 2019-03-26 | Procédé de fabrication d'une couche monocristalline de matériau ain et substrat pour croissance par épitaxie d'une couche monocristalline de matériau ain |
US17/041,371 US20210032772A1 (en) | 2018-03-28 | 2019-03-26 | Method for producing a single-crystal film of aln material and substrate for the epitaxial growth of a single-crystal film of aln material |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR1800254 | 2018-03-28 | ||
FR1800254A FR3079532B1 (fr) | 2018-03-28 | 2018-03-28 | Procede de fabrication d'une couche monocristalline de materiau ain et substrat pour croissance par epitaxie d'une couche monocristalline de materiau ain |
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WO2019186266A2 true WO2019186266A2 (fr) | 2019-10-03 |
WO2019186266A3 WO2019186266A3 (fr) | 2019-11-21 |
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PCT/IB2019/000205 WO2019186266A2 (fr) | 2018-03-28 | 2019-03-26 | Procédé de fabrication d'une couche monocristalline de matériau ain et substrat pour croissance par épitaxie d'une couche monocristalline de matériau ain |
Country Status (8)
Country | Link |
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US (1) | US20210032772A1 (fr) |
EP (1) | EP3775333A2 (fr) |
JP (1) | JP7451846B2 (fr) |
KR (1) | KR102640296B1 (fr) |
CN (1) | CN111902571A (fr) |
FR (1) | FR3079532B1 (fr) |
SG (1) | SG11202009411SA (fr) |
WO (1) | WO2019186266A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021210391A1 (fr) * | 2020-04-14 | 2021-10-21 | 学校法人関西学院 | Procédé de production de substrat de nitrure d'aluminium, substrat de nitrure d'aluminium et procédé pour supprimer l'apparition de fissures dans une couche de nitrure d'aluminium |
WO2021210390A1 (fr) * | 2020-04-14 | 2021-10-21 | 学校法人関西学院 | Procédé de production d'un substrat semi-conducteur, substrat semi-conducteur et procédé de prévention de l'apparition de fissures dans une couche de croissance |
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CN1132223C (zh) * | 1995-10-06 | 2003-12-24 | 佳能株式会社 | 半导体衬底及其制造方法 |
CA2220600C (fr) * | 1996-11-15 | 2002-02-12 | Canon Kabushiki Kaisha | Methode de fabrication d'articles a semi-conducteur |
DE69728022T2 (de) * | 1996-12-18 | 2004-08-12 | Canon K.K. | Vefahren zum Herstellen eines Halbleiterartikels unter Verwendung eines Substrates mit einer porösen Halbleiterschicht |
FR2767604B1 (fr) * | 1997-08-19 | 2000-12-01 | Commissariat Energie Atomique | Procede de traitement pour le collage moleculaire et le decollage de deux structures |
JP2001209981A (ja) * | 1999-02-09 | 2001-08-03 | Ricoh Co Ltd | 光ディスク基板成膜装置、光ディスク基板成膜方法、基板ホルダーの製造方法、基板ホルダー、光ディスクおよび相変化記録型光ディスク |
FR2835096B1 (fr) * | 2002-01-22 | 2005-02-18 | Procede de fabrication d'un substrat auto-porte en materiau semi-conducteur monocristallin | |
FR2817394B1 (fr) * | 2000-11-27 | 2003-10-31 | Soitec Silicon On Insulator | Procede de fabrication d'un substrat notamment pour l'optique, l'electronique ou l'optoelectronique et substrat obtenu par ce procede |
US7407869B2 (en) * | 2000-11-27 | 2008-08-05 | S.O.I.Tec Silicon On Insulator Technologies | Method for manufacturing a free-standing substrate made of monocrystalline semiconductor material |
US8507361B2 (en) * | 2000-11-27 | 2013-08-13 | Soitec | Fabrication of substrates with a useful layer of monocrystalline semiconductor material |
FR2817395B1 (fr) * | 2000-11-27 | 2003-10-31 | Soitec Silicon On Insulator | Procede de fabrication d'un substrat notamment pour l'optique, l'electronique ou l'optoelectronique et substrat obtenu par ce procede |
FR2835097B1 (fr) * | 2002-01-23 | 2005-10-14 | Procede optimise de report d'une couche mince de carbure de silicium sur un substrat d'accueil | |
DE60336543D1 (de) * | 2003-05-27 | 2011-05-12 | Soitec Silicon On Insulator | Verfahren zur Herstellung einer heteroepitaktischen Mikrostruktur |
FR2857982B1 (fr) * | 2003-07-24 | 2007-05-18 | Soitec Silicon On Insulator | Procede de fabrication d'une couche epitaxiee |
US7476594B2 (en) * | 2005-03-30 | 2009-01-13 | Cree, Inc. | Methods of fabricating silicon nitride regions in silicon carbide and resulting structures |
US20070069225A1 (en) * | 2005-09-27 | 2007-03-29 | Lumileds Lighting U.S., Llc | III-V light emitting device |
US8635214B2 (en) * | 2006-07-26 | 2014-01-21 | International Business Machines Corporation | Improving results from search providers using a browsing-time relevancy factor |
US9564320B2 (en) * | 2010-06-18 | 2017-02-07 | Soraa, Inc. | Large area nitride crystal and method for making it |
FR2963848B1 (fr) * | 2010-08-11 | 2012-08-31 | Soitec Silicon On Insulator | Procede de collage par adhesion moleculaire a basse pression |
JP6369566B2 (ja) * | 2014-12-22 | 2018-08-08 | 信越化学工業株式会社 | ナノカーボン膜作製用複合基板及びナノカーボン膜の作製方法 |
FR3041364B1 (fr) * | 2015-09-18 | 2017-10-06 | Soitec Silicon On Insulator | Procede de transfert de paves monocristallins |
US10283463B2 (en) * | 2017-04-11 | 2019-05-07 | International Business Machines Corporation | Terahertz detector comprised of P-N junction diode |
-
2018
- 2018-03-28 FR FR1800254A patent/FR3079532B1/fr active Active
-
2019
- 2019-03-26 SG SG11202009411SA patent/SG11202009411SA/en unknown
- 2019-03-26 CN CN201980021416.2A patent/CN111902571A/zh active Pending
- 2019-03-26 EP EP19759725.5A patent/EP3775333A2/fr active Pending
- 2019-03-26 US US17/041,371 patent/US20210032772A1/en active Pending
- 2019-03-26 KR KR1020207030232A patent/KR102640296B1/ko active IP Right Grant
- 2019-03-26 JP JP2020549815A patent/JP7451846B2/ja active Active
- 2019-03-26 WO PCT/IB2019/000205 patent/WO2019186266A2/fr unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021210391A1 (fr) * | 2020-04-14 | 2021-10-21 | 学校法人関西学院 | Procédé de production de substrat de nitrure d'aluminium, substrat de nitrure d'aluminium et procédé pour supprimer l'apparition de fissures dans une couche de nitrure d'aluminium |
WO2021210390A1 (fr) * | 2020-04-14 | 2021-10-21 | 学校法人関西学院 | Procédé de production d'un substrat semi-conducteur, substrat semi-conducteur et procédé de prévention de l'apparition de fissures dans une couche de croissance |
EP4137614A4 (fr) * | 2020-04-14 | 2024-05-22 | Kwansei Gakuin Educational Found | Procédé de production de substrat de nitrure d'aluminium, substrat de nitrure d'aluminium et procédé pour supprimer l'apparition de fissures dans une couche de nitrure d'aluminium |
Also Published As
Publication number | Publication date |
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KR102640296B1 (ko) | 2024-02-22 |
JP7451846B2 (ja) | 2024-03-19 |
EP3775333A2 (fr) | 2021-02-17 |
CN111902571A (zh) | 2020-11-06 |
SG11202009411SA (en) | 2020-10-29 |
US20210032772A1 (en) | 2021-02-04 |
KR20200138284A (ko) | 2020-12-09 |
JP2021518324A (ja) | 2021-08-02 |
FR3079532B1 (fr) | 2022-03-25 |
WO2019186266A3 (fr) | 2019-11-21 |
FR3079532A1 (fr) | 2019-10-04 |
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