WO2019168353A1 - Composition cosmétique ayant une texture de yogourt solide - Google Patents

Composition cosmétique ayant une texture de yogourt solide Download PDF

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Publication number
WO2019168353A1
WO2019168353A1 PCT/KR2019/002386 KR2019002386W WO2019168353A1 WO 2019168353 A1 WO2019168353 A1 WO 2019168353A1 KR 2019002386 W KR2019002386 W KR 2019002386W WO 2019168353 A1 WO2019168353 A1 WO 2019168353A1
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Prior art keywords
cellulose
composition
texture
cosmetic composition
appearance
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PCT/KR2019/002386
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English (en)
Korean (ko)
Inventor
김예원
안순애
정해진
최양규
Original Assignee
주식회사 아모레퍼시픽
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Publication of WO2019168353A1 publication Critical patent/WO2019168353A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to a cosmetic composition prepared by combining a cellulose-based polymer compound and an acrylate-based polymer to have a texture of solid yogurt, and more particularly, has a smooth and elastic appearance that is the texture of solid yogurt, and when applied to the skin.
  • the present invention relates to a cosmetic composition that imparts a moisturizing feeling and improves a bleeding phenomenon which is a disadvantage of the cosmetic composition having a conventional yoghurt texture.
  • packs have been used for a long time as major cosmetics to keep skin healthy and beautiful through moisturizing action to moisturize and maintain skin, purifying action to adsorb and remove skin contaminants, and promoting blood purification.
  • These pack cosmetics can be used for topical or whole body as well as face, neck, shoulders, arms, legs, etc. Peel-off-type, cream, clay Tissue-off-type and wash-off-type used for phase, jelly phase, aerosol, peeling-type peeling after solidification, nonwoven gel, non-woven fabric impregnated coating type, etc. It is manufactured variously. Since each of them has advantages and disadvantages, the formulating researchers compensate for their shortcomings by selecting the appropriate type of formulation according to various consumer preferences.
  • pack cosmetics except non-woven coatings, cover the face temporarily to block external air inflow or evaporation of water.They are polyvinyl alcohol, polyvinylpyrrolidone, hydroxyethyl cellulose, and carboxymethyl. Polymer compounds such as cellulose, vinyl acetate emulsion, xanthan gum and carboxyvinyl polymer are used.
  • these pack cosmetics are difficult to wash off after drying as a poorly soluble substance, and when peeling, there is a problem that skin irritation is concerned due to physical irritation.
  • the skin moisturizing function of the cosmetic is a basic function that the cosmetics should have, for this purpose has been used to increase the moisturizing ability in the pack cosmetic composition.
  • a moisturizer to increase the moisturizing ability, a large amount of the moisturizer should be used and the coating was not properly formed when the skin had a problem in that the adhesion and adhesion is inferior.
  • Cosmetics of pack formulations containing functional substances are prepared by adding water or lotion to the nonwoven fabric and other supports, or by adding functional extracts, but the support such as nonwoven fabric becomes stiff when the makeup lotion or functional extract is added or has a poor feeling of use.
  • protein materials such as natural or animal proteins such as collagen, silk, and fibroin proteins are difficult to handle due to the weak strength of the material itself and are sensitive to temperature, making it difficult to form gels at room temperature or by lyophilization.
  • the cosmetic pack form also has a disadvantage in that it takes a considerable time to dry after application and form a film, so it is difficult to sufficiently penetrate the cosmetic agent within the short time and must be removed.
  • the pack composition of the staple yogurt formulation is used as a skin external preparation or cosmetic composition due to the moisturizing and soft texture, but the conventional product that implements the texture of the staple yogurt using xanthan gum and mannan gum They have a low palatability due to their unique discomfort, and when used directly on the skin, there is a problem of causing discomfort due to severe drowning phenomenon (see Patent Documents 1 and 2).
  • a cosmetic composition containing cetyl hydroxyethyl cellulose and an acrylate polymer, hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer, in an appropriate weight ratio has a smooth and elastic appearance, which is the texture of solid yogurt, and is applied to the skin.
  • Patent Document 1 Korean Registered Patent No. 10-0560407 (registered March 3, 2006)
  • Patent Document 2 Korea Patent Registration No. 10-1359947 (2014.2.03 registration)
  • An object of the present invention is to provide a cosmetic composition having a similar appearance and texture to solid yogurt.
  • the present invention is a cosmetic composition having the appearance and texture of a solid yogurt containing a cellulose-based polymer compound and an acrylate-based polymer as an active ingredient, the weight ratio of the cellulose-based polymer compound and acrylate-based polymer It provides a cosmetic composition having the appearance and texture of a solid yogurt, characterized in that 0.8 ⁇ 1.2: 0.8 ⁇ 1.2, preferably 0.9 ⁇ 1.1: 0.9 ⁇ 1.1, most preferably 0.8 ⁇ 1.0: 0.8 ⁇ 1.0.
  • the invention also provides the use of a mixture of a cellulose-based polymer compound and an acrylate-based polymer, more precisely, the appearance and texture improver of a cosmetic composition in the manufacture of a cosmetic composition or cosmetic having the appearance and texture of a solid yoghurt. .
  • Cosmetic composition having the appearance and texture of the solid yogurt containing the cellulose-based polymer compound and the acrylate-based polymer as an active ingredient in a specific weight ratio according to the present invention not only has the appearance and texture of the yogurt in the formulation of the cosmetic composition, but also moisturizes It has high properties and viscosity and can be used for manufacturing cosmetics having a skin moisturizing function with excellent feeling.
  • Example 1 shows a result of measuring the distance (unit: cm) flowing for 1 minute by tilting the glass plate at about 45 ° after placing a predetermined amount (1 g) on the glass plate of the compositions of Example 5 and Comparative Examples 14-16.
  • the present invention provides a cosmetic composition having the appearance and texture of a solid yoghurt containing a cellulose-based polymer compound and an acrylate-based polymer as an active ingredient, wherein the weight ratio of the cellulose-based polymer compound and the acrylate-based polymer is 0.8 to 1.2. : 0.8 to 1.2, preferably 0.9 to 1.1: 0.9 to 1.1, most preferably 0.8 to 1.0: 0.8 to 1.0, the cosmetic composition having the appearance and texture of the solid yogurt.
  • the composition When out of the weight ratio range of the cellulose-based polymer compound and the acrylate-based polymer, the composition loses the smoothness and elasticity of the surface and loses the appearance and texture of the solid yoghurt due to the low viscosity.
  • the content of the cellulose-based polymer compound in the state of maintaining the weight ratio of the cellulose-based polymer compound and the acrylate-based polymer is 0.1 to 2.0% by weight, preferably 0.3 to 0.7 based on the total weight of the composition % By weight, most preferably 0.4 to 0.6% by weight, and if the content of the cellulose-based polymer compound is less than 0.1% by weight, the solid yogurt may not have an appearance (smooth and elastic appearance, and formulation recovery).
  • the flow reduction effect is reduced, and when the content of the cellulose-based polymer compound exceeds 2.0% by weight, the feeling of use of the composition (formulation) is reduced (it is too hard and flowability is difficult to apply to the face). Since there exists, it is preferable to use suitably within the said range.
  • the content of the acrylate-based polymer in the state of maintaining the weight ratio of the cellulose-based polymer compound and the acrylate-based polymer is 0.1 to 2.0% by weight, preferably 0.3 to 0.7 based on the total weight of the composition % By weight, most preferably 0.4 to 0.6% by weight, if the content of the acrylate-based polymer is less than 0.1% by weight, the appearance (smooth surface) of the solid yogurt is lost, and the usability (easiness of slipping) is lowered.
  • the cellulose-based polymer compound is cetyl hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl ethyl cellulose, It may be at least one selected from the group consisting of carboxymethyl cellulose and carboxypropyl cellulose, but is not limited thereto.
  • it is cetyl hydroxyethyl cellulose.
  • the acrylate polymer is hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer, sodium acrylate / sodium acryloyldimethyl taurate copolymer, acrylate / C10-30 alkyl acrylate It may be one or more selected from the group consisting of cross polymers and acrylate / vinyisodecanoate cross polymers, but is not limited thereto.
  • the polymer is hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer. .
  • the composition may be characterized in that it further comprises xanthan gum, the content of the xanthan gum is 0.001 to 1.0% by weight, preferably 0.01 to 0.10% by weight, based on the total weight of the composition Preferably from 0.04 to 0.06% by weight, if the content of the xanthan gum is less than 0.001% by weight, there is a problem in that the effect of imparting softness upon application of the composition (formulation) is reduced, and the content of the xanthan gum is If it exceeds 1.0% by weight, only the xanthan gum is strongly increased without significant increase in effect, and therefore it is preferable to use it within the above range.
  • the composition is a moisturizer (polyol, etc.), oils, waxes, viscosity regulators, thickeners, pH regulators, fats, organic solvents, solubilizers, concentrations in consideration of the limit of use in accordance with the rules on cosmetic safety Agents, gelling agents, emollients, antioxidants, suspending agents, stabilizers, foaming agents, fragrances, surfactants, water, ionic emulsifiers, nonionic emulsifiers, fillers, metal ion sequestrants, chelating agents, preservatives, It may further contain auxiliaries commonly used in the field of cosmetics or dermatology, such as vitamins, wetting agents, dyes, pigments, hydrophilic actives, lipophilic actives, lipid vesicles or any other ingredients commonly used in cosmetics. In addition, the composition of the present invention may further contain a skin absorption promoting substance to increase the skin condition improving effect.
  • the composition in order to impart useful functionality to the skin and / or hair, includes a moisturizing component such as glycerin, an antioxidant / anti-aging component such as an antioxidant, a whitening component such as a tyrosinase inhibitor, a keratin regeneration accelerator, Moisturizing, anti-aging, whitening, protection, wound healing of skin and / or hair by further containing appropriate amount of protective ingredients such as sunscreen, wound healing ingredients such as hyaluronic acid, collagen, elastin, and salt-containing ingredients such as anti-inflammatory agents It may be given a function such as, but is not limited thereto.
  • a moisturizing component such as glycerin
  • an antioxidant / anti-aging component such as an antioxidant
  • a whitening component such as a tyrosinase inhibitor
  • a keratin regeneration accelerator Moisturizing, anti-aging, whitening, protection, wound healing of skin and / or hair by further containing appropriate amount of protective ingredients such as sunscreen, wound healing
  • the composition may have a hardness (N) of 10 to 20N, preferably 10 to 18N, most preferably 11 to 14N so that the composition may adhere well to the skin, and the hardness of the composition may be If it is less than the range, the adhesion to the skin is lowered. On the contrary, if it exceeds the range, the feeling of use is lowered due to excessive rigidity, and the dripping property is reduced.
  • N hardness
  • the hardness (N) of the composition is based on the results of 2 minutes of measurement at 30 ° C. while pressing 2 cm with 2 kg of FULL SCALE.
  • the composition may be characterized by maintaining appropriate stability when the weight ratio of the cellulose-based polymer compound and the acrylate-based polymer is maintained at 0.8 ⁇ 1.2: 0.8 ⁇ 1.2.
  • the stability of the composition is stable, slightly unstable, by observing the stability of the emulsion for one week under a temperature cycle condition of changing the temperature range of 60 ° C. or the temperature range of -15 ° C. to 45 ° C. at 12 hour intervals in order to evaluate under severe conditions. It is based on the result of evaluating emulsion stability by checking whether the water phase part or oil phase part is separated.
  • the composition may be characterized by having a uniformly clumped shape and semi-solid properties.
  • the composition may be prepared in an oil-in-water type (Oil in Water.O / W emulsion) or water-in-oil type (Water in Oil.W / O emulsion), and preferably prepared in an oil-in-water type emulsion method. .
  • the composition may be formulated as a cosmetic cream, gel, lotion, pack, patch-type products, etc., but is not limited thereto, and may be formulated in a variety of formulations of cosmetic products, the functionality of the product to be implemented In consideration of cost, and other conditions, the cellulose-based polymer compound and the acrylate-based polymer may be mixed in a proper content ratio to form a product.
  • the composition may be characterized in that the cosmetic composition of the pack formulation having a similar appearance and texture to solid yogurt, also known as floating yogurt by combining the cellulose-based polymer compound and the acrylate-based polymer.
  • Pack formulation refers to a formulation prepared to be applied to the face to form a film.
  • An example of a preferred pack is to temporarily apply a thin coating on the face to block external air inflow or moisture evaporation to make the skin soft and effective.
  • the pack which has the characteristic of easy infiltration of the is mentioned.
  • the pack formulation includes not only a formulation spread directly on the face but also a formulation prepared by applying or coating the composition on a permeable membrane such as a thin cloth or paper or nonwoven fabric.
  • a cosmetic composition having the composition (component and content) shown in Table 1 and Table 2 below.
  • the cosmetic composition was prepared by a conventional emulsion production method, but each of the raw materials were combined in the composition of Table 1 and Table 2 below, and then prepared by heating at about 75 °C or more for about 10 minutes or more.
  • Tables 1 and 2 below show the composition of the cosmetic composition (oil-in-water (O / W) emulsion) (unit: wt%).
  • the surface has elasticity (circular restoring force), smooth, and excellent in leaving property (very similar to the appearance and texture of solid yoghurt).
  • the surface has a feeling of elasticity (circular restoring force), slightly smooth, and slightly drifting (similar to the appearance and texture of solid yoghurt).
  • Comparative example 5 Comparative example 6 Comparative example 7 Comparative example 8 Comparative example 9 Comparative example 10 Comparative example 11 Comparative example 12 Appearance and Texture state X X X X X X X X X Application lowness lowness lowness lowness lowness lowness lowness lowness lowness lowness lowness lowness lowness
  • composition according to Examples 1-4 i.e. a formulation combining 0.4-0.5% by weight of cetyl hydroxyethylcellulose and 0.4-0.5% by weight of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer
  • the appearance and texture were in good condition, and the formulation combining 0.5 wt% cetyl hydroxyethylcellulose and 0.4 wt% hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer of Example 2
  • the texture appeared to be in a very good condition and was found to have the appearance (smoothness / elasticity of the surface) and driftingness most similar to the solid yoghurt.
  • Example 4 prepared by adding a small amount of xanthan gum to the composition of Example 2 so as not to feel unpleasant odor peculiar to xanthan gum, the applicability of the composition was also significantly improved while maintaining the appearance and texture of the xanthan gum. It was confirmed that there is an effect to.
  • Table 5 shows the composition of the cosmetic composition (oil-in-water (O / W) emulsion) (unit: wt%).
  • Moisturizing properties of each cosmetic composition (emulsion formulation: Example 5 and Comparative Examples 13-16) prepared in Reference Example 2 above were evaluated based on the following evaluation criteria.
  • Evaluation Criteria Sensory evaluation was performed on 10 cosmetic cosmetic sensory expert evaluation groups of the compositions according to Examples 5 and Comparative Examples 13 to 16 above, and the average value of the improvement of skin moisturization after using the composition was measured on a 5-point scale. Evaluation scores were obtained ([Score]: 4.0-5 points (very high skin moisturizing), 3.0-3.9 (with skin moisturizing), 1.0-2.9 (low skin moisturizing), 0-0.9 (no skin moisturizing)).
  • composition according to Example 5 has an effect of significantly improving the skin moisturizing power than the composition according to Comparative Examples 13-16.
  • the composition according to Example 5 was significantly lower than the composition according to Comparative Examples 13 to 16, and it was confirmed that the viscosity was improved. Therefore, when using the composition according to Example 5 when applying the skin it was confirmed that the effect of preventing the flow of the composition is excellent to significantly improve the feeling of use.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique préparée de manière à avoir une texture de yaourt solide par combinaison d'un composé polymère à base de cellulose et d'un polymère à base d'acrylate et, plus spécifiquement, une composition cosmétique ayant un aspect lisse et élastique, qui est celle d'une texture de yaourt solide, et, lorsqu'elle est appliquée sur la peau, fournir de l'hydratation et, simultanément, réduire l'égouttement, qui est un inconvénient d'une composition cosmétique classique ayant une texture de yaourt.
PCT/KR2019/002386 2018-02-28 2019-02-27 Composition cosmétique ayant une texture de yogourt solide WO2019168353A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2018-0024557 2018-02-28
KR1020180024557A KR20190103752A (ko) 2018-02-28 2018-02-28 고상 요구르트의 질감을 갖는 화장료 조성물

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WO2019168353A1 true WO2019168353A1 (fr) 2019-09-06

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Publication number Priority date Publication date Assignee Title
KR102148277B1 (ko) * 2020-04-27 2020-08-26 한국콜마주식회사 이종의 유기 점증제를 포함하는 수분산 제형의 자외선 차단용 화장료 조성물

Citations (5)

* Cited by examiner, † Cited by third party
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KR20090118468A (ko) * 2008-05-14 2009-11-18 주식회사 엘지생활건강 수중유형의 화장료 조성물
KR20120059199A (ko) * 2010-11-30 2012-06-08 (주)아모레퍼시픽 마스크팩용 화장료 조성물
KR20120136141A (ko) * 2011-06-08 2012-12-18 주식회사 엘지생활건강 즉각적인 피부 주름 개선용 화장료 조성물
KR101667937B1 (ko) * 2016-01-05 2016-10-24 한국콜마주식회사 필-오프타입 팩 화장료 조성물 및 이의 제조 방법
KR20170034169A (ko) * 2015-09-18 2017-03-28 (주)아모레퍼시픽 묻어남이 개선된 화장료 조성물

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Publication number Priority date Publication date Assignee Title
KR100560407B1 (ko) 2004-03-11 2006-03-13 주식회사 태평양 호상 요구르트의 질감을 갖는 화장료 조성물
KR101359947B1 (ko) 2007-03-30 2014-02-10 (주)아모레퍼시픽 보습 복합물을 함유한 피부 보습용 화장료 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20090118468A (ko) * 2008-05-14 2009-11-18 주식회사 엘지생활건강 수중유형의 화장료 조성물
KR20120059199A (ko) * 2010-11-30 2012-06-08 (주)아모레퍼시픽 마스크팩용 화장료 조성물
KR20120136141A (ko) * 2011-06-08 2012-12-18 주식회사 엘지생활건강 즉각적인 피부 주름 개선용 화장료 조성물
KR20170034169A (ko) * 2015-09-18 2017-03-28 (주)아모레퍼시픽 묻어남이 개선된 화장료 조성물
KR101667937B1 (ko) * 2016-01-05 2016-10-24 한국콜마주식회사 필-오프타입 팩 화장료 조성물 및 이의 제조 방법

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TW201936160A (zh) 2019-09-16
TWI802658B (zh) 2023-05-21

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