WO2019146725A1 - 光検出装置 - Google Patents
光検出装置 Download PDFInfo
- Publication number
- WO2019146725A1 WO2019146725A1 PCT/JP2019/002352 JP2019002352W WO2019146725A1 WO 2019146725 A1 WO2019146725 A1 WO 2019146725A1 JP 2019002352 W JP2019002352 W JP 2019002352W WO 2019146725 A1 WO2019146725 A1 WO 2019146725A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- array substrate
- polysilicon layer
- layer
- apd
- substrate
- Prior art date
Links
- 239000000758 substrate Substances 0.000 claims abstract description 103
- 238000010791 quenching Methods 0.000 claims abstract description 55
- 230000000171 quenching effect Effects 0.000 claims abstract description 53
- 239000004065 semiconductor Substances 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 50
- 229920005591 polysilicon Polymers 0.000 claims description 50
- 238000001514 detection method Methods 0.000 claims description 37
- 238000000098 azimuthal photoelectron diffraction Methods 0.000 description 70
- 229910052751 metal Inorganic materials 0.000 description 21
- 239000002184 metal Substances 0.000 description 21
- 238000010586 diagram Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000003071 parasitic effect Effects 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 230000005684 electric field Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910000530 Gallium indium arsenide Inorganic materials 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910016570 AlCu Inorganic materials 0.000 description 1
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910004613 CdTe Inorganic materials 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- -1 InAlGaAs Inorganic materials 0.000 description 1
- 229910000661 Mercury cadmium telluride Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/42—Photometry, e.g. photographic exposure meter using electric radiation detectors
- G01J1/4228—Photometry, e.g. photographic exposure meter using electric radiation detectors arrangements with two or more detectors, e.g. for sensitivity compensation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/42—Photometry, e.g. photographic exposure meter using electric radiation detectors
- G01J1/44—Electric circuits
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/42—Photometry, e.g. photographic exposure meter using electric radiation detectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J11/00—Measuring the characteristics of individual optical pulses or of optical pulse trains
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/1446—Devices controlled by radiation in a repetitive configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/14609—Pixel-elements with integrated switching, control, storage or amplification elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/14634—Assemblies, i.e. Hybrid structures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/14636—Interconnect structures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14643—Photodiode arrays; MOS imagers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/02016—Circuit arrangements of general character for the devices
- H01L31/02019—Circuit arrangements of general character for the devices for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02027—Circuit arrangements of general character for the devices for devices characterised by at least one potential jump barrier or surface barrier for devices working in avalanche mode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/08—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
- H01L31/10—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by potential barriers, e.g. phototransistors
- H01L31/101—Devices sensitive to infrared, visible or ultraviolet radiation
- H01L31/102—Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier
- H01L31/107—Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier the potential barrier working in avalanche mode, e.g. avalanche photodiodes
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
- H04N25/00—Circuitry of solid-state image sensors [SSIS]; Control thereof
- H04N25/70—SSIS architectures; Circuits associated therewith
- H04N25/71—Charge-coupled device [CCD] sensors; Charge-transfer registers specially adapted for CCD sensors
- H04N25/75—Circuitry for providing, modifying or processing image signals from the pixel array
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
- H04N25/00—Circuitry of solid-state image sensors [SSIS]; Control thereof
- H04N25/70—SSIS architectures; Circuits associated therewith
- H04N25/79—Arrangements of circuitry being divided between different or multiple substrates, chips or circuit boards, e.g. stacked image sensors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/42—Photometry, e.g. photographic exposure meter using electric radiation detectors
- G01J1/44—Electric circuits
- G01J2001/4413—Type
- G01J2001/442—Single-photon detection or photon counting
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/42—Photometry, e.g. photographic exposure meter using electric radiation detectors
- G01J1/44—Electric circuits
- G01J2001/4446—Type of detector
- G01J2001/446—Photodiode
- G01J2001/4466—Avalanche
Definitions
- the present invention relates to a light detection device.
- Patent Document 1 There is known a light detection device in which a plurality of avalanche photodiodes are two-dimensionally arranged (for example, Patent Document 1).
- the plurality of avalanche photodiodes operate in Geiger mode.
- the plurality of avalanche photodiodes are formed on a semiconductor substrate made of a compound semiconductor.
- a passive quenching element is placed in series with the avalanche photodiode to quench avalanche multiplication.
- the resistance value of the passive quenching element it is determined whether or not the avalanche multiplication process occurring inside the avalanche photodiode connected to the passive quenching element is appropriately quenched. If the resistance value of the quenching element is insufficient, appropriate quenching may not be performed due to the occurrence of a latching current or the like. For proper quenching, it is necessary to select the necessary and sufficient quenching element resistance value.
- One aspect of the present invention aims to provide a light detection device in which improvement in light detection sensitivity and light detection time resolution are compatible in a configuration in which a plurality of avalanche photodiodes are formed on a semiconductor substrate made of a compound semiconductor. .
- a light detection device includes an avalanche photodiode array substrate and a circuit substrate.
- the avalanche photodiode array substrate is made of a compound semiconductor.
- An avalanche photodiode array substrate is mounted on the circuit substrate.
- a plurality of avalanche photodiodes are two-dimensionally arrayed on the avalanche photodiode array substrate.
- the plurality of avalanche photodiodes operate in Geiger mode.
- the circuit boards are connected in parallel with one another and have a plurality of output units.
- the plurality of output units form at least one channel.
- Each output unit has a passive quenching element and a capacitive element.
- the passive quenching element is connected in series with at least one of the plurality of avalanche photodiodes.
- the capacitive element is connected in series with the at least one avalanche photodiode and in parallel with the passive quenching element.
- a plurality of output units having passive quenching elements and capacitive elements are provided on a circuit board separate from the avalanche photodiode array substrate. Therefore, the space in which the plurality of output units can be formed can be expanded as compared to the case where the plurality of output units are disposed on the avalanche photodiode array substrate. If the output unit is provided on a circuit board separate from the avalanche photodiode array substrate, the parasitic capacitance generated between the configuration of the avalanche photodiode and the output unit can be reduced. In this case, it is also possible to use another manufacturing process than the avalanche diode array substrate. Thus, the design of multiple output units may be facilitated.
- the capacitive element of the light detection device is connected in series to at least one avalanche photodiode and connected in parallel to the passive quenching element. Therefore, the capacitance of the capacitive element can improve the peak value of the pulse signal from the avalanche photodiode connected in series with the capacitive element. Therefore, pulse signals from a plurality of avalanche photodiodes can be easily detected, and the light detection time resolution can be further improved.
- the passive quenching element may be formed by the first polysilicon layer provided on the circuit substrate.
- the capacitive element is formed of a second polysilicon layer provided on the circuit substrate, a dielectric layer stacked on the second polysilicon layer, and a third polysilicon layer stacked on the dielectric layer. It is also good.
- the first polysilicon layer is formed at the same height as the second polysilicon layer or the third polysilicon layer in the thickness direction of the circuit substrate. In this case, the plurality of output units can be formed by a simple manufacturing process.
- a light detection device capable of securing the accuracy of light detection with an easy design in a configuration in which a plurality of avalanche photodiodes are formed on a semiconductor substrate made of a compound semiconductor.
- FIG. 1 is a perspective view of a light detection device according to an embodiment.
- FIG. 2 is a view showing a cross-sectional configuration of the light detection device.
- FIG. 3 is a plan view of the circuit board.
- FIG. 4 is a plan view of the light detection region of the avalanche photodiode array substrate.
- FIG. 5 is a diagram showing the configuration of a circuit board.
- FIG. 6 is a diagram showing a circuit configuration used for the light detection device.
- FIG. 7 is a diagram showing a circuit configuration used for a light detection device according to a modification of the present embodiment.
- FIG. 8 is a plan view of the mounting area of the circuit board.
- FIG. 9 is a diagram showing components of a pulse signal from an avalanche photodiode.
- FIG. 10 is a diagram showing the characteristics of the recharge pulse.
- FIG. 11 is a diagram showing the characteristics of the fast pulse.
- FIG. 1 is a perspective view of a light detection device according to the present embodiment.
- FIG. 2 is a view showing a cross-sectional configuration of the light detection device according to the present embodiment. Hatching is omitted in FIG. 2 in order to improve the visibility.
- FIG. 3 is a plan view of the circuit board.
- FIG. 4 is a plan view showing a part of the avalanche photodiode array substrate.
- FIG. 6 is a diagram showing a circuit configuration used for the light detection device according to the present embodiment.
- FIG. 8 is a plan view showing a part of the circuit board.
- the light detection device 1 includes an avalanche photodiode array substrate 10 and a circuit board 50, as shown in FIG.
- the "avalanche photodiode” is referred to as "APD”.
- the "avalanche photodiode array substrate” is referred to as "APD array substrate”.
- the circuit board 50 is disposed to face the APD array substrate 10.
- Each of the APD array substrate 10 and the circuit substrate 50 has a rectangular shape in plan view.
- the APD array substrate 10 includes a main surface 10A, a main surface 10B, and a side surface 10C facing each other.
- the circuit board 50 includes a main surface 50A, a main surface 50B, and a side surface 50C facing each other.
- the main surface 10B of the APD array substrate 10 faces the main surface 50A of the circuit board 50.
- a plane parallel to the main surfaces of the APD array substrate 10 and the circuit substrate 50 is an XY axis plane, and a direction orthogonal to each main surface is a Z axis direction.
- the side surface 50C of the circuit board 50 is located outside the side surface 10C of the APD array substrate 10 in the XY plane planar direction. That is, the area of the circuit board 50 is larger than the area of the APD array substrate 10 in plan view.
- the side surface 10C of the APD array substrate 10 and the side surface 50C of the circuit substrate 50 may be flush with each other. In this case, the outer edge of the APD array substrate 10 coincides with the outer edge of the circuit substrate 50 in plan view.
- a glass substrate may be disposed on the major surface 10A of the APD array substrate 10.
- the glass substrate and the APD array substrate 10 are optically connected by an optical adhesive.
- the glass substrate may be formed directly on the APD array substrate 10.
- the side surface 10C of the APD array substrate 10 and the side surface of the glass substrate may be flush with each other. In this case, the outer edge of the APD array substrate 10 and the outer edge of the glass substrate coincide with each other in plan view.
- the side surface 10C of the APD array substrate 10, the side surface 50C of the circuit substrate 50, and the side surface of the glass substrate may be flush with each other. In this case, the outer edge of the APD array substrate 10, the outer edge of the circuit substrate 50, and the outer edge of the glass substrate coincide with each other in plan view.
- the APD array substrate 10 is mounted on a circuit board 50. As shown in FIG. 2, the APD array substrate 10 and the circuit substrate 50 are connected by bump electrodes 25. Specifically, when viewed from the thickness direction of the APD array substrate 10, as shown in FIG. 3, the APD array substrate 10 is formed of bump electrodes 25 on the mounting area ⁇ arranged at the center of the circuit board 50. It is connected. In the present embodiment, the mounting area ⁇ has a rectangular shape.
- the circuit board 50 has a ground line 3, a cathode line 5, and an anode line 7 around the mounting area ⁇ .
- the ground line 3, the cathode line 5, and the anode line 7 extend from the mounting area ⁇ .
- the ground line 3 is connected to a ground electrode 63 described later.
- the cathode line 5 is electrically connected to the APD array substrate 10 mounted in the mounting area ⁇ , and is used to apply a voltage to the APD array substrate 10.
- the anode line 7 is connected to metal layers 65 and 66 described later, and is used to read out a signal from the APD array substrate 10.
- the APD array substrate 10 has a plurality of APDs 20 operating in Geiger mode.
- the plurality of APDs 20 are two-dimensionally arrayed in the light detection area ⁇ of the semiconductor substrate 11 when viewed in the thickness direction of the APD array substrate 10, as shown in FIG.
- the light detection area ⁇ has a rectangular shape, and when viewed from the thickness direction of the APD array substrate 10, overlaps with the mounting area ⁇ of the circuit board 50.
- the APD array substrate 10 has an N-type semiconductor substrate 11 made of a compound semiconductor.
- the semiconductor substrate 11 has a substrate 12 made of InP that forms the major surface 10A.
- a buffer layer 13 made of InP, an absorption layer 14 made of InGaAsP, an electric field relaxation layer 15 made of InGaAsP, and a multiplication layer 16 made of InP are sequentially formed on the substrate 12 from the main surface 10A to the main surface 10B.
- the absorption layer 14 may be made of InGaAs.
- the semiconductor substrate 11 may be formed of GaAs, InGaAs, AlGaAs, InAlGaAs, CdTe, HgCdTe or the like.
- Each APD 20 is surrounded by the insulating portion 21 as viewed in the thickness direction of the APD array substrate 10 as shown in FIGS. 2 and 4.
- Each APD 20 has a P-type active area 22 formed by doping an impurity in the multiplication layer 16 from the main surface 10B side.
- the impurity to be doped is, for example, Zn (zinc).
- the insulating portion 21 is formed, for example, by forming a polyimide film in a trench formed by wet etching or dry etching.
- the active area 22 is formed in a circular shape as viewed in the thickness direction, and the insulating portion 21 is formed in an annular shape along the edge of the active area 22.
- the insulating portion 21 reaches the substrate 12 from the main surface 10 B side of the semiconductor substrate 11 in the thickness direction of the APD array substrate 10.
- FIG. 5 is a view showing a part of an avalanche photodiode array substrate used in a light detection device according to a modification of the present embodiment.
- the active area 22 may be formed in a substantially rectangular shape as viewed in the thickness direction.
- the substantially rectangular shape is a rectangular shape having rounded corners. Thereby, the concentration of the electric field at the corners of the active area 22 is suppressed.
- the insulating portion 21 is annularly formed along the edge of the substantially rectangular active area 22.
- the APD array substrate 10 has an insulating layer 23 and a plurality of electrode pads 24.
- the insulating layer 23 covers the semiconductor substrate 11 on the main surface 10B side.
- the electrode pad 24 is formed on the semiconductor substrate 11 on the main surface 10 B side for each APD 20 and is in contact with the active area 22.
- the electrode pad 24 is exposed from the insulating layer 23 and is connected to the circuit board 50 through the bump electrode 25.
- the circuit board 50 is connected to the APD array substrate 10 on the main surface 50A side through the bump electrode 25 as shown in FIG.
- the circuit board 50 has a plurality of output units 30.
- the plurality of output units 30 are connected in parallel with one another to form one channel 40, as shown in FIG.
- Each of the plurality of output units 30 is connected in series to each APD 20 provided on the APD array substrate 10.
- Each output unit 30 has a passive quenching element 31 and a capacitive element 32 connected in parallel to each other.
- the passive quenching element 31 and the capacitive element 32 are both connected in series to the APD 20.
- FIG. 7 is a diagram for explaining a circuit configuration used for a light detection device according to a modification of the present embodiment.
- a plurality of channels 40 may be formed on the circuit board 50.
- each channel 40 is formed by a plurality of output units 30 connected in parallel with one another.
- At least one of the plurality of channels 40 may be formed by a plurality of output units 30 connected in parallel with one another.
- the circuit board 50 has a silicon substrate 51 and a wiring layer 61 stacked on the silicon substrate 51.
- the silicon substrate 51 has a P + layer 52, a P ⁇ layer 53 and a P + layer 54 in order from the main surface 50B side to the main surface 50A side.
- the P + layer 52 is provided by doping the P ⁇ layer 53 with an impurity.
- the P + layer 54 is provided by doping the P ⁇ layer 53 with an impurity.
- the impurity to be doped into P - layer 53 is, for example, boron.
- an oxide film layer 60 formed in an element isolation process by thermal oxidation is provided between the silicon substrate 51 and the wiring layer 61.
- the P + layer 54 is exposed from the oxide film layer 60 and in contact with the wiring layer 61.
- Wiring layer 61 includes insulating layer 62, ground electrode 63, electrode pad 64, metal layers 65 and 66, vias 67, 68, 69 and 70, polysilicon layers 71, 72 and 73, and dielectric layers. And 74.
- the ground electrode 63, the electrode pad 64, the metal layers 65 and 66, the vias 67, 68, 69 and 70, the polysilicon layers 71, 72 and 73, and the dielectric layer 74 are provided for each APD 20.
- the ground electrode 63, the electrode pad 64, and the metal layers 65 and 66 are formed in the same layer. In other words, the ground electrode 63, the electrode pad 64, and the metal layers 65 and 66 are formed at the same height in the thickness direction of the circuit board 50.
- the insulating layer 62 is formed of, for example, SiO 2 .
- the ground electrode 63, the electrode pad 64, and the metal layers 65 and 66 are formed of, for example, Al, AlCu, or AlSiCu.
- the ground electrode 63, the electrode pad 64, and the metal layers 65 and 66 may be formed of the same material.
- the vias 67, 68, 69, 70 are formed of, for example, W (tungsten).
- the dielectric layer 74 is formed of, for example, SiO 2 or Si 3 N 4 .
- the wiring layer 61 is covered by the insulating layer 62.
- the P + layer 54 of the silicon substrate 51 is connected to the via 67 exposed from the insulating layer 62 of the wiring layer 61 to the silicon substrate 51 side.
- the P + layer 54 is connected to the ground electrode 63 through the via 67.
- the ground electrode 63 is disposed at the height at which the ground electrode 63 is disposed in the thickness direction of the circuit board 50, with respect to the electrode pad 64 and the metal layers 65 and 66 via the insulating layer 62.
- the ground electrode 63 is not directly connected to the electrode pad 64 and the metal layers 65 and 66.
- the electrode pad 64 is exposed from the insulating layer 62 and connected to the APD 20 through the bump electrode 25.
- the electrode pads 64 are two-dimensionally arranged on the main surface 50A side as shown in FIG.
- the electrode pad 64 is connected to the polysilicon layer 71 through the via 68.
- the polysilicon layer 71 is connected to the metal layer 65 through the via 69.
- the electrode pad 64 is disposed at a height at which the electrode pad 64 is disposed in the thickness direction of the circuit board 50, with respect to the metal layers 65 and 66 via the insulating layer 62.
- the electrode pad 64 is not directly connected to the metal layers 65 and 66.
- the polysilicon layer 71 is included in the first polysilicon layer.
- the polysilicon layer 71 constitutes a passive quenching element 31.
- the passive quenching element 31 is connected in series to the APD 20 through the bump electrode 25, the electrode pad 64, and the via 68. That is, the pulse signal from the APD 20 is input to the passive quenching element 31 through the bump electrode 25, the electrode pad 64, and the via 68.
- the pulse signal input to the passive quenching element 31 is output from the channel 40 through the passive quenching element 31, the via 69 and the metal layer 65.
- the electrode pad 64 is connected to the metal layer 66 at a height at which the electrode pad 64 is disposed in the thickness direction of the circuit board 50.
- Metal layer 66 is connected to polysilicon layer 72 through via 70.
- Polysilicon layer 72 is stacked on dielectric layer 74.
- the dielectric layer 74 is stacked on the polysilicon layer 73.
- the polysilicon layer 73 is connected to the metal layer 65 through a via (not shown).
- the polysilicon layer 71 and the polysilicon layer 73 are formed at the same height in the thickness direction of the circuit board 50.
- the polysilicon layer 71 and the polysilicon layer 72 may be formed at the same height in the thickness direction of the circuit board 50.
- the polysilicon layer 72 is included in the third polysilicon layer.
- the polysilicon layer 73 is included in the second polysilicon layer.
- the polysilicon layer 72, the dielectric layer 74, and the polysilicon layer 73 constitute a capacitive element 32.
- the capacitive element 32 is connected in series to the APD 20 through the bump electrode 25, the electrode pad 64, and the via 68. That is, the pulse signal from the APD 20 is input to the polysilicon layer 72 of the capacitive element 32 through the bump electrode 25, the electrode pad 64, and the via 68.
- a pulse signal is output from the polysilicon layer 73 of the capacitive element 32.
- the pulse signal output from the capacitive element 32 is output from the channel 40 through a via and metal layer 65 (not shown).
- the passive quenching element 31 and the capacitive element 32 are both electrically connected to the electrode pad 64 and the metal layer 65. Therefore, the passive quenching element 31 and the capacitive element 32 are connected in parallel to each other.
- FIG. 9 shows a pulse signal output from the APD 20.
- the pulse signal 26 from the APD 20 is divided into a fast pulse 27 and a recharge pulse 28.
- the fast pulse 27 is a pulse component having a peak value of the pulse signal.
- the charge pulse 28 is a component having a pulse width longer than that of the fast pulse 27 and detected after the fast pulse 27 is detected.
- FIG. 10 shows the waveform of the pulse signal output from the APD 20 with the capacitive element 32 removed from the output unit 30 and the resistance value of the passive quenching element 31 as a parameter.
- FIG. 10 is an integer graph in which the unit of the vertical axis is current (A) and the unit of the horizontal axis is time (s).
- Data a, b, c, and d are data of pulse signals when passive quenching elements 31 having different resistance values are provided in the output unit 30. In the order of the data a, b, c, d, passive quenching elements 31 having higher resistance values are provided.
- the slope of the recharge pulse 28 is steeper.
- the steeper the slope of the recharge pulse 28 the shorter the time required for quenching, and the shorter the dead time when the APD 20 can not detect light.
- the passive quenching element 31 having a large resistance value it is possible to realize appropriate quenching in which the occurrence of a latching current or the like is suppressed.
- the dead time increases as the resistance value increases.
- the pulse width of the pulse signal from the APD 20 connected to the passive quenching element 31 also changes according to the resistance value of the passive quenching element 31.
- the dead time of the APD 20 connected in series with the passive quenching element 31 increases as the resistance value of the passive quenching element 31 increases. Therefore, there is a need for a circuit design having a passive quenching element 31 with an optimum resistance value in order to achieve both appropriate quenching and reduction of dead time and to secure light detection sensitivity and light detection time resolution.
- a plurality of output units 30 each having a passive quenching element 31 and a capacitive element 32 are provided on a circuit board 50 separate from the APD array substrate 10. Therefore, as compared with the case where the plurality of output units 30 are arranged on the APD array substrate 10, the space in which the plurality of output units 30 can be formed can be expanded. Thus, the design of multiple output units 30 may be facilitated.
- the plurality of output units 30 are provided on the circuit board 50 separate from the APD array substrate 10, parasitic capacitance generated between the configuration of the APD 20 and the output units 30 can be reduced. It is also possible to use another manufacturing process than the APD array substrate 10. The ability to use manufacturing processes suitable for each of the APD array substrate 10 and the circuit substrate 50 can also facilitate the design of the plurality of output units 30.
- FIG. 11 shows the waveform of a pulse signal output from the APD 20 with the passive quenching element 31 as a constant value and the capacitance of the capacitive element 32 as a parameter.
- FIG. 11 is a one-variable graph in which the unit of the vertical axis is current (A) and the unit of the horizontal axis is time (s).
- Data a is data of a pulse signal when the capacitive element 32 is removed from the output unit 30.
- the data b, c, d are data of pulse signals when the output element 30 is provided with capacitive elements 32 having different capacitances. In the order of the data b, c, d, the capacitive element 32 having higher capacitance is provided.
- the provision of the capacitive element 32 improves the peak value of the fast pulse 27.
- the higher the capacitance of the capacitive element 32 the larger the peak value of the fast pulse 27. Therefore, by providing the capacitive element 32, the time resolution of pulse signals from the plurality of APDs 20 is improved.
- the peak value of the fast pulse 27 is larger, pulse signals from a plurality of APDs 20 can be easily detected.
- the light detection device 1 includes a capacitive element 32 connected in series to at least one APD 20 and connected in parallel to the passive quenching element 31. According to the above configuration, the peak value of the pulse signal from the APD 20 connected in series with the capacitive element 32 can be improved by the capacitance of the capacitive element 32 by the characteristics described using FIG. Therefore, pulse signals from a plurality of APDs 20 can be easily detected, and the light detection time resolution can be improved.
- the light detection device 1 can count the number of incident photons while achieving desired light detection sensitivity and light detection time resolution.
- the light detection device 1 includes the polysilicon layers 71 and 73 provided on the circuit substrate 50, the dielectric layer 74 provided on the polysilicon layer 73, and the polysilicon layer 72 provided on the dielectric layer 74. And.
- the passive quenching element 31 is formed by the polysilicon layer 71
- the capacitive element 32 is formed by the polysilicon layer 73, the dielectric layer 74, and the polysilicon layer 72.
- the polysilicon layer 71 is formed at the same height as the polysilicon layer 72 or the polysilicon layer 73 in the thickness direction of the circuit substrate 50. In this case, the plurality of output units 30 can be formed by a simple manufacturing process.
- the passive quenching element 31 may be formed of a metal thin film instead of the polysilicon layer 71.
- the capacitive element 32 may be formed of two metal layers instead of the polysilicon layers 72 and 73. In this case, the capacitive element 32 has a configuration in which two parallel metal layers sandwich the dielectric layer 74.
- SYMBOLS 1 Photodetector, 10 ... APD array substrate, 20 ... APD, 30 ... Output unit, 31 ... Passive quenching element, 32 ... Capacitive element, 40 ... Channel, 50 ... Circuit board, 71, 72, 73 ... Polysilicon Layer, 74 ... dielectric layer.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- Computer Hardware Design (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Multimedia (AREA)
- Signal Processing (AREA)
- Light Receiving Elements (AREA)
- Solid State Image Pick-Up Elements (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
- Geophysics And Detection Of Objects (AREA)
- Gyroscopes (AREA)
- Measuring Pulse, Heart Rate, Blood Pressure Or Blood Flow (AREA)
Abstract
Description
Claims (2)
- 光検出装置であって、
ガイガーモードで動作する複数のアバランシェフォトダイオードが2次元配列されている、化合物半導体からなるアバランシェフォトダイオードアレイ基板と、
前記アバランシェフォトダイオードアレイ基板が実装されている回路基板と、を備え、
前記回路基板は、互いに並列に接続されて、少なくとも1つのチャンネルを形成する複数の出力ユニットを有し、
各前記出力ユニットは、前記複数のアバランシェフォトダイオードの少なくとも1つと直列に接続されたパッシブクエンチング素子と、前記少なくとも1つのアバランシェフォトダイオードと直列に接続されていると共に前記パッシブクエンチング素子と並列に接続されている容量素子とを有する。 - 請求項1に記載の光検出装置であって、
前記パッシブクエンチング素子は、前記回路基板に設けられた第1ポリシリコン層によって形成され、
前記容量素子は、前記回路基板に設けられた第2ポリシリコン層と、前記第2ポリシリコン層上に積層された誘電体層と、前記誘電体層上に積層された第3ポリシリコン層とによって形成され、
前記第1ポリシリコン層は、前記回路基板の厚み方向において、前記第2ポリシリコン層又は前記第3ポリシリコン層と同一の高さに形成されている。
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP23177334.2A EP4230974A1 (en) | 2018-01-26 | 2019-01-24 | Photodetector device |
KR1020207024014A KR20200110782A (ko) | 2018-01-26 | 2019-01-24 | 광 검출 장치 |
CN201980009407.1A CN111630355B (zh) | 2018-01-26 | 2019-01-24 | 光检测装置 |
CN202310802726.6A CN116845125A (zh) | 2018-01-26 | 2019-01-24 | 光检测装置 |
JP2019567165A JPWO2019146725A1 (ja) | 2018-01-26 | 2019-01-24 | 光検出装置 |
US16/963,312 US11125616B2 (en) | 2018-01-26 | 2019-01-24 | Photodetector device comprising each of a plurality of passive quenching elements connected in series to at least one avalanche photodiode and a capacitative element connected in parallel to the passive quenching element |
EP19744603.2A EP3745102B1 (en) | 2018-01-26 | 2019-01-24 | Photodetector device |
US17/384,915 US11860032B2 (en) | 2018-01-26 | 2021-07-26 | Photodetector device having avalanche photodiodes two-dimensionally arranged on a compound semiconductor layer and quenching element connected in series to the photodiodes |
US18/223,277 US20230358607A1 (en) | 2018-01-26 | 2023-07-18 | Photodetector device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018011824 | 2018-01-26 | ||
JP2018-011824 | 2018-01-26 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/963,312 A-371-Of-International US11125616B2 (en) | 2018-01-26 | 2019-01-24 | Photodetector device comprising each of a plurality of passive quenching elements connected in series to at least one avalanche photodiode and a capacitative element connected in parallel to the passive quenching element |
US17/384,915 Continuation US11860032B2 (en) | 2018-01-26 | 2021-07-26 | Photodetector device having avalanche photodiodes two-dimensionally arranged on a compound semiconductor layer and quenching element connected in series to the photodiodes |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2019146725A1 true WO2019146725A1 (ja) | 2019-08-01 |
Family
ID=67395017
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2019/002352 WO2019146725A1 (ja) | 2018-01-26 | 2019-01-24 | 光検出装置 |
Country Status (7)
Country | Link |
---|---|
US (3) | US11125616B2 (ja) |
EP (2) | EP4230974A1 (ja) |
JP (1) | JPWO2019146725A1 (ja) |
KR (1) | KR20200110782A (ja) |
CN (2) | CN116845125A (ja) |
TW (2) | TWI806960B (ja) |
WO (1) | WO2019146725A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110987201A (zh) * | 2019-12-20 | 2020-04-10 | 国开启科量子技术(北京)有限公司 | 一种单光子探测器死时间控制电路实现方法及装置 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012531753A (ja) | 2009-06-26 | 2012-12-10 | アムプリフィケイション テクノロジーズ インコーポレイテッド | 半導体アバランシェ増幅による低レベル信号検出 |
JP2013089919A (ja) * | 2011-10-21 | 2013-05-13 | Hamamatsu Photonics Kk | 光検出装置 |
JP2016519435A (ja) * | 2013-04-19 | 2016-06-30 | ライトスピン テクノロジーズ、インク. | 集積アバランシェ・フォトダイオード・アレイ |
JP2016122716A (ja) * | 2014-12-24 | 2016-07-07 | 株式会社東芝 | 光検出装置およびこの光検出装置を備えたct装置 |
JP2018173379A (ja) * | 2017-03-31 | 2018-11-08 | 株式会社デンソー | 光検出器及び測距装置 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6188056B1 (en) | 1998-06-24 | 2001-02-13 | Stmicroelectronics, Inc. | Solid state optical imaging pixel with resistive load |
JP5562207B2 (ja) * | 2010-10-29 | 2014-07-30 | 浜松ホトニクス株式会社 | フォトダイオードアレイ |
GB2495908B8 (en) * | 2011-10-19 | 2017-06-14 | Vitec Group Plc | A camera support apparatus |
US9634156B2 (en) * | 2012-05-25 | 2017-04-25 | Sensl Technologies Ltd. | Semiconductor photomultiplier and readout method |
US9299732B2 (en) * | 2013-10-28 | 2016-03-29 | Omnivision Technologies, Inc. | Stacked chip SPAD image sensor |
JP6193171B2 (ja) * | 2014-04-11 | 2017-09-06 | 株式会社東芝 | 光検出器 |
US10012534B2 (en) * | 2014-07-02 | 2018-07-03 | The Johns Hopkins University | Photodetection circuit having at least one counter operative in response to a mode switching circuit and operating method thereof |
US9209320B1 (en) * | 2014-08-07 | 2015-12-08 | Omnivision Technologies, Inc. | Method of fabricating a single photon avalanche diode imaging sensor |
US10014340B2 (en) * | 2015-12-28 | 2018-07-03 | Taiwan Semiconductor Manufacturing Co., Ltd. | Stacked SPAD image sensor |
-
2019
- 2019-01-24 WO PCT/JP2019/002352 patent/WO2019146725A1/ja unknown
- 2019-01-24 US US16/963,312 patent/US11125616B2/en active Active
- 2019-01-24 KR KR1020207024014A patent/KR20200110782A/ko not_active Application Discontinuation
- 2019-01-24 EP EP23177334.2A patent/EP4230974A1/en active Pending
- 2019-01-24 EP EP19744603.2A patent/EP3745102B1/en active Active
- 2019-01-24 CN CN202310802726.6A patent/CN116845125A/zh active Pending
- 2019-01-24 CN CN201980009407.1A patent/CN111630355B/zh active Active
- 2019-01-24 JP JP2019567165A patent/JPWO2019146725A1/ja active Pending
- 2019-01-25 TW TW108102887A patent/TWI806960B/zh active
- 2019-01-25 TW TW112120328A patent/TW202340684A/zh unknown
-
2021
- 2021-07-26 US US17/384,915 patent/US11860032B2/en active Active
-
2023
- 2023-07-18 US US18/223,277 patent/US20230358607A1/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012531753A (ja) | 2009-06-26 | 2012-12-10 | アムプリフィケイション テクノロジーズ インコーポレイテッド | 半導体アバランシェ増幅による低レベル信号検出 |
JP2013089919A (ja) * | 2011-10-21 | 2013-05-13 | Hamamatsu Photonics Kk | 光検出装置 |
JP2016519435A (ja) * | 2013-04-19 | 2016-06-30 | ライトスピン テクノロジーズ、インク. | 集積アバランシェ・フォトダイオード・アレイ |
JP2016122716A (ja) * | 2014-12-24 | 2016-07-07 | 株式会社東芝 | 光検出装置およびこの光検出装置を備えたct装置 |
JP2018173379A (ja) * | 2017-03-31 | 2018-11-08 | 株式会社デンソー | 光検出器及び測距装置 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110987201A (zh) * | 2019-12-20 | 2020-04-10 | 国开启科量子技术(北京)有限公司 | 一种单光子探测器死时间控制电路实现方法及装置 |
Also Published As
Publication number | Publication date |
---|---|
KR20200110782A (ko) | 2020-09-25 |
CN111630355B (zh) | 2023-07-25 |
TW201933588A (zh) | 2019-08-16 |
TW202340684A (zh) | 2023-10-16 |
CN111630355A (zh) | 2020-09-04 |
US11125616B2 (en) | 2021-09-21 |
US20210356319A1 (en) | 2021-11-18 |
EP3745102A4 (en) | 2021-09-08 |
CN116845125A (zh) | 2023-10-03 |
JPWO2019146725A1 (ja) | 2021-03-04 |
EP3745102A1 (en) | 2020-12-02 |
TWI806960B (zh) | 2023-07-01 |
EP4230974A1 (en) | 2023-08-23 |
EP3745102B1 (en) | 2023-07-19 |
US20200370954A1 (en) | 2020-11-26 |
US20230358607A1 (en) | 2023-11-09 |
US11860032B2 (en) | 2024-01-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11056525B2 (en) | Semiconductor photomultiplier | |
US9659980B2 (en) | Semiconductor photomultiplier | |
JP5791461B2 (ja) | 光検出装置 | |
JP5832852B2 (ja) | 光検出装置 | |
JP6282368B2 (ja) | 光検出装置 | |
US20210028202A1 (en) | Photodetector | |
WO2013058001A1 (ja) | 光検出装置 | |
WO2020202880A1 (ja) | アバランシェフォトダイオードセンサおよびセンサ装置 | |
WO2011129149A1 (ja) | 半導体光検出素子 | |
WO2016147504A1 (ja) | 光検出装置 | |
US20230358607A1 (en) | Photodetector device | |
JP6140868B2 (ja) | 半導体光検出素子 | |
JP5927334B2 (ja) | 光検出装置 | |
JP5911629B2 (ja) | 光検出装置 | |
JP6186038B2 (ja) | 半導体光検出素子 | |
JP6244403B2 (ja) | 半導体光検出素子 | |
JP6282307B2 (ja) | 半導体光検出素子 | |
JP6116728B2 (ja) | 半導体光検出素子 | |
JP4459472B2 (ja) | 光検出器 | |
JP5989872B2 (ja) | 光検出装置の接続構造 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 19744603 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2019567165 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20207024014 Country of ref document: KR Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2019744603 Country of ref document: EP Effective date: 20200826 |