WO2019114198A1 - 一种氰化尾渣焙烧回收有价金属同步制备陶粒的方法 - Google Patents
一种氰化尾渣焙烧回收有价金属同步制备陶粒的方法 Download PDFInfo
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- WO2019114198A1 WO2019114198A1 PCT/CN2018/088702 CN2018088702W WO2019114198A1 WO 2019114198 A1 WO2019114198 A1 WO 2019114198A1 CN 2018088702 W CN2018088702 W CN 2018088702W WO 2019114198 A1 WO2019114198 A1 WO 2019114198A1
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Definitions
- the invention belongs to the technical field of comprehensive recycling of metallurgical waste residue, and particularly relates to a method for synchronously preparing ceramsite by calcination of cyanide tailings to recover valuable metals.
- the cyanide gold extraction method is an economical and simple method for extracting gold from ore, concentrate or tailings, and has a series of advantages such as high recovery rate and strong adaptability to ore. Since its introduction at the end of the 19th century, this method has been widely used in world gold production and has become the main method for the selection and smelting of modern gold mines. At present, 90% of the world's gold mines use cyanidation to raise gold, and China's gold selection plant using cyanide gold extraction method has reached more than 80%. However, its shortcomings are also obvious, and the production process produces a large amount of cyanide tailings. Cyanide tailings were originally considered waste and the traditional treatment method was storage or landfill.
- the re-recycling of tailings slag includes two aspects: first, recycling, extracting useful components from tailings, that is, re-election of tailings; second, utilizing, developing new products with tailings as basic raw materials.
- most of the research on cyanide tailings has focused on how to further extract valuable elements such as Au, Ag, Fe, S in tailings more efficiently, and lack of relevant research on the disposal methods of residual residue after treatment.
- the remaining waste residue is also a very important secondary mineral resource, and also contains a large number of available non-metallic mineral materials, mainly quartz, feldspar, pyroxene, garnet, amphibole, and aluminosilicates such as altered clay and mica.
- Minerals and calcium and magnesium carbonate minerals such as calcite and dolomite can be widely
- cyanide tailings As the main raw material will become an important development direction.
- the non-metallic mineral components in the cyanide tailings are the same as those required for the ceramic raw materials.
- the main raw material for the production of ceramsite the general preparation of ceramsite is carried out by high-temperature sintering. Considering the method of high-temperature sintering combined with the method of chlorination roasting, the heavy metal is volatilized in the form of chloride and the ceramsite is simultaneously fired. The entire process control is done in the same roasting equipment, reducing process steps and reducing energy consumption and pollution.
- the method for synthesizing ceramsite by using cyanide tailings roasting and recovering valuable metals can not only solve the environmental problems caused by waste slag, but also realize the harmless value-added utilization of waste slag and create huge economic benefits. Therefore, the method for synthesizing ceramsite by calcination of cyanide tailings and recovery of valuable metals has very important significance and value.
- the valuable metals in the cyanide tailings are recovered by roasting, and high-performance ceramsite is simultaneously prepared, thereby reducing environmental pollution, improving economic benefits, and achieving the effects of hazardous waste recycling and safe disposal.
- Ball mill mixing The cyanide tailings, bentonite, calcium chloride, coal powder and albite are by weight ratio: 100: (5 ⁇ 10): (4 ⁇ 10): (1 ⁇ 7): ( 5 ⁇ 20) performing ball milling and mixing to obtain a mixture;
- the baking material obtained in the step (3) is once calcined, the calcination temperature is 700-900 ° C, and the calcination time is 0.5-3 h, and the roasting material and the soot are obtained once;
- the primary calcined material obtained in the step (4) is calcined at a high temperature, the calcination temperature is 1050 to 1200 ° C, and the calcination time is controlled to 0.5 to 3 h to obtain a secondary calcined material and soot;
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- steps (4), (5) and (7) are carried out in the same roasting equipment.
- the heavy metal content of the prepared ceramsite is much lower than the value specified in GB5085.3-2007, and the physical properties meet the standard of GB/T 14685-2011.
- the invention combines the related technologies of chlorination volatilization and ceramsite preparation, can not only effectively improve the volatilization efficiency of heavy metals in cyanide tailings, but also can simultaneously fire ceramsite products, which reduces the Environmental pollution has also created economic value.
- the invention can produce volatile ceramsite by volatilization and recovery of valuable metal in the process of roasting and sintering cyanide tailings by reasonable compounding, thereby achieving the effect of resource recovery and high value utilization of cyanide tailings, and can create good economic benefits. And environmental benefits, with significant energy saving and consumption reduction effects.
- Figure 1 is a flow chart showing the process for preparing ceramsite by calcination of cyanide tailings to recover valuable metals.
- the primary calcined material obtained in the step (4) is calcined at a high temperature, the calcination temperature is 1050 ° C, and the calcination time is controlled to 0.5 h to obtain a secondary calcined material and soot;
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- the leaching content of several heavy metals in the finished ceramsite produced by using cyanide tailings is (mg/L): Ag: 0.0015, Cu: 0.043, Zn: 0.0013, As: 0.0014, Pb: 0.0015
- the Hg content is lower than the detection limit of the instrument; the physical properties of the ceramsite are as follows: the water absorption rate is 13% in one hour, the bulk density is 1025 kg/m 3 , and the cylinder compressive strength is 11.5 MPa.
- the primary calcined material obtained in the step (4) is calcined at a high temperature, the calcination temperature is 1200 ° C, and the calcination time is controlled to 3 h to obtain a secondary calcined material and soot;
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- the leaching content of several heavy metals in the finished ceramsite produced by using cyanide tailings is (mg/L): Ag: 0.001, Cu: 0.041, Zn: 0.0011, As: 0.0012, Pb: 0.0013
- the Hg content is lower than the detection limit of the instrument; the physical properties of the ceramsite are as follows: the water absorption rate is 15% in one hour, the bulk density is 1150 kg/m 3 , and the cylinder compressive strength is 12.5 MPa.
- (1) ball-milling mixture cyanide tailings, bentonite, calcium chloride, coal powder and albite are ball-milled by weight ratio of 100:7:5:3:10 to obtain a mixture;
- the primary calcined material obtained in the step (4) is calcined at a high temperature, the calcination temperature is 1100 ° C, and the calcination time is controlled to 1 h to obtain a secondary calcined material and soot;
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- the leaching content of several heavy metals in the finished ceramsite produced by using cyanide tailings is (mg/L): Ag: 0.001, Cu: 0.047, Zn: 0.001, As: 0.0014, Pb: 0.0017
- the Hg content is lower than the detection limit of the instrument; the physical properties of the ceramsite are as follows: the water absorption rate is 12.4% in one hour, the bulk density is 1035 kg/m 3 , and the cylinder compressive strength is 11.7 MPa.
- the primary calcined material obtained in the step (4) is calcined at a high temperature, the calcination temperature is 1050 ° C, and the calcination time is controlled to 0.5 h to obtain a secondary calcined material and soot;
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- the leaching content of several heavy metals in the finished ceramsite produced by using cyanide tailings is (mg/L): Ag: 0.0011, Cu: 0.041, Zn: 0.0016, As: 0.0013, Pb: 0.0016
- the Hg content is lower than the detection limit of the instrument; the physical properties of the ceramsite are as follows: the water absorption rate is 13.4% in one hour, the bulk density is 1013 kg/m 3 , and the cylinder pressure strength is 11.3 MPa.
- the primary calcined material obtained in the step (4) is calcined at a high temperature, the calcination temperature is 1200 ° C, and the calcination time is controlled to 3 h to obtain a secondary calcined material and soot;
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- the leaching content of several heavy metals in the finished ceramsite produced by using cyanide tailings is (mg/L): Ag: 0.0014, Cu: 0.045, Zn: 0.0012, As: 0.0017, Pb: 0.0018
- the Hg content is lower than the detection limit of the instrument; the physical properties of the ceramsite are as follows: the water absorption rate is 11.3% in one hour, the bulk density is 965 kg/m 3 , and the cylinder compressive strength is 10.8 MPa.
- Dust collection the dust obtained in steps (4) and (5) is subjected to dust collection treatment to obtain multi-metal soot for centralized treatment;
- the leaching content of several heavy metals in the finished ceramsite produced by using cyanide tailings is (mg/L): Ag: 0.001, Cu: 0.047, Zn: 0.001, As: 0.0014, Pb: 0.0017
- the Hg content is lower than the detection limit of the instrument; the physical properties of the ceramsite are as follows: the water absorption rate is 11.4% in one hour, the bulk density is 985 kg/m 3 , and the cylinder compressive strength is 10.5 MPa.
- a method for simultaneously preparing a ceramsite by calcining a cyanide tailings and recovering valuable metals by using the cyanidation tailings slag is provided, and the cyanidation tailings and the chlorinating agent and the like are rationally compounded and ball milled.
- the raw material ball is prepared, and the heavy metal in the tailings is volatilized in the form of chloride by two calcination methods, and the volatile smoke is uniformly collected and concentrated, and the volatilized pellet is fired to meet the national standard. And finished ceramics with good performance.
- the method not only can effectively remove various metals in the cyanide tailings, but also combines the new chlorination process, has the characteristics of high volatilization rate, energy saving, no pollution, wide adaptability, etc., and can eliminate environmental pollution. Moreover, the volatilized pellets can be simultaneously fired into ceramsite, and environmental benefits and economic benefits are obtained at the same time.
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Abstract
Description
Claims (2)
- 一种氰化尾渣焙烧回收有价金属同步制备陶粒的方法,其特征在于具体步骤如下:(1)球磨混料:将氰化尾渣、膨润土、氯化钙、煤粉和钠长石按一定重量比进行球磨混合,得到混合料;混合料中氰化尾渣、膨润土、氯化钙以、煤粉、钠长石重量比为100:(5~10):(4~10):(1~7):(5~20);(2)造粒:将步骤(1)所得混合料放入圆盘制粒机进行造粒,得到粒径为2~5cm的生料球;(3)烘干:将步骤(2)中所得的生料球在100~200℃下烘干3~5h,得到烘干料;(4)一次焙烧:将步骤(3)得到的烘干料进行一次焙烧,得到一次焙烧料和烟尘;焙烧温度为700~900℃,焙烧时间为0.5~3h;(5)二次焙烧:将步骤(4)的到的一次焙烧料在高温下进行焙烧,得到二次焙烧料和烟尘;焙烧温度为1050~1200℃,焙烧时间控制为0.5~3h;(6)收尘:将步骤(4)和(5)得到的烟尘进行收尘处理,得到多金属烟灰,进行集中处理;(7)冷却:将步骤(5)得到的二次焙烧料进行冷却,得到陶粒。
- 根据权利要求1要求的一种氰化尾渣焙烧回收有价金属同步制备陶粒的方法,其特征在于步骤(4)、(5)和(7)是在同一焙烧装备中进行。
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