WO2019098854A1 - Engrais au npk-si-humate, procédé de production et utilisation de ce dernier - Google Patents

Engrais au npk-si-humate, procédé de production et utilisation de ce dernier Download PDF

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Publication number
WO2019098854A1
WO2019098854A1 PCT/NO2018/050283 NO2018050283W WO2019098854A1 WO 2019098854 A1 WO2019098854 A1 WO 2019098854A1 NO 2018050283 W NO2018050283 W NO 2018050283W WO 2019098854 A1 WO2019098854 A1 WO 2019098854A1
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fertilizer
npk
humate
particulate
weight
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PCT/NO2018/050283
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English (en)
Inventor
Tor Søyland Hansen
Magne DÅSTØL
Odd SKOGERBØ
Vladimir MATYCHENKOV
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Elkem Asa
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Priority to RU2020120150A priority Critical patent/RU2741798C1/ru
Priority to US16/759,946 priority patent/US11254622B2/en
Priority to EP18857395.0A priority patent/EP3713900B1/fr
Priority to BR112020006467-0A priority patent/BR112020006467A2/pt
Priority to CN201880074774.5A priority patent/CN111630023A/zh
Publication of WO2019098854A1 publication Critical patent/WO2019098854A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C21/00—Methods of fertilising, sowing or planting
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C1/00—Ammonium nitrate fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C11/00—Other nitrogenous fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • C05C3/005—Post-treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C5/00—Fertilisers containing other nitrates
    • C05C5/005—Post-treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C5/00—Fertilisers containing other nitrates
    • C05C5/02—Fertilisers containing other nitrates containing sodium or potassium nitrate
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C9/00—Fertilisers containing urea or urea compounds
    • C05C9/005—Post-treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • C05D1/005—Fertilisers containing potassium post-treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C05D9/02—Other inorganic fertilisers containing trace elements
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • C05F11/04—Horticultural earth from peat
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • C05F5/002—Solid waste from mechanical processing of material, e.g. seed coats, olive pits, almond shells, fruit residue, rice hulls
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/10—Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12—Granules or flakes
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/20—Liquid fertilisers

Definitions

  • the present invention relates NPK-Si fertilizer products and their use in agriculture, environment protection, detoxification and other areas were effective silicon fertilizers are used.
  • the present application relates to combined organomineral NPK- Si-humate fertilizer products comprising a high content of silicon in the form of plant- available silicon, and the method for production of such combined organomineral NPK- Si-humate fertilizer products.
  • N Nitrogen
  • K potassium
  • P phosphorus
  • Nitrogen is vital because it is an important component of chlorophyll, the compound by which plants use sunlight energy to produce sugars from water and carbon dioxide (i.e., photosynthesis). It is also a major component of amino acids, the building blocks of proteins. Without proteins, plants wither and die. Some proteins act as structural units in plant cells while others act as enzymes, which is crucial for numerus biochemical reactions. Nitrogen is a component in the energy-transfer compounds, such as ATP (adenosine triphosphate). ATP allows cells to conserve and use the energy released in metabolism. Finally, nitrogen is a significant component of nucleic acids such as DNA, the genetic material that allows cells (and eventually whole plants) to grow and reproduce. In simple terms, nitrogen promotes plant growth.
  • ATP adenosine triphosphate
  • Phosphorous is an important component in plant DNA and RNA.
  • Phosphorus is also important for development of roots, flowers, seeds, fruit, energy for the plant and for uptake of other elements, including N.
  • Potassium is important for strong stem growing, movement of water and for uptake of other elements, including N, in plants. Potassium also plays a critical physiological role in carbohydrate and protein metabolism of plants, promotes flowering and fruiting. Straight fertilizers such as Calcium Ammonium Nitrate (CAN), Ammonium Nitrate (AN), Ammonium Sulphate (AS), Urea, Single Superphosphate (SSP), Triple
  • Superphosphate TSP
  • Potash Potassium Chloride
  • MOP Potash
  • DAP Di- Ammonium Phosphate
  • NPK Compound or complex fertilizers
  • NPK are more difficult to define as there is an infinite number of N/P/K-ratios and the processes applied in their production are numerous.
  • the product name“NPK” is normally followed by three numbers to indicate the percent of N, P (declared as P 2 O 5 ) and K (declared as K 2 0) which the product contains, e.g.
  • N nitrogen compounds
  • P 2 O 5 phosphorus compounds
  • K 2 O potassium compounds
  • the fertilizer may contain magnesium, boron, sulphur, micro-nutrients, etc.
  • the typical content of nutrients (labelled as N + P 2 O 5 + K 2 O) will normally be in the range of 40-60%.
  • Grades with no P 2 O 5 or no K 2 O are also included in the“NPK” product range, however also commonly named NP and NK fertilizers.
  • the most widespread NPK fertilizers in Europe contain nitrate and/or ammonium salts. Table 1 shows typical average range of nutrient content in commercially available NPK fertilizers.
  • NPK fertilizers can be produced in four, basically different, ways (ref.“Best Available Techniques for Pollution Prevention and Control in the European Fertilizer Industry, Booklet No. 8 of 8:“PRODUCTION OF NPK FERTILIZERS by the MIXED ACID ROUTE” Copyright 2000 - EFMA, which is hereby incorporated by reference):
  • NPK fertilizers exists, e.g. there is a standard using the element values, i.e. the amount of elemental N, P and/or K.
  • Plants mainly take up nutrients in the form of ions. Nitrogen is taken up as ammonium and nitrate. Potassium, as well as other metal cation nutrients, is taken up as ions. Phosphorous is mainly taken up as phosphates (hydrogen phosphates and dihydrogen phosphates). Boron is not taken up as a charged ion, but rather as boric acid.
  • Silicon (Si) has traditionally been considered as beneficial. Many cultivated plants take up more Si than N, P or K (Epstein, E. (2001)“Silicon in plants: facts vs.
  • silicon may be a highly beneficial element to enhance growth of plants, and prevent negative influence for many stresses.
  • Silicon fertilizing protects plants against biotic (diseases, insect attack) and abiotic stresses (unfavorable climate condition, salt, toxic influence), and reduces the content of mobile Al and heavy metals in soil and total content of Al and heavy metals in the cultivated plants (Meharg C, Meharg AA (2015)“Silicon, the silver bullet for mitigating biotic and abiotic stress, and improving grain quality, in rice?”
  • Environmental and Experimental Botany 120:8-17.
  • Silicon is the second most abundant element in the earth’s crust. However, plants can only take up Si in the form of monosilicic acid, or possibly lower oligomers of monosilicic acid, herein also denoted as bio-available Si or plant-available Si. Solutions of monosilicic acid are not thermodynamically stable, but will over time lead to polymerization of the monosilicic acid into polysilicic acid, and the Si becomes bio- unavailable. In natural Si containing minerals, the Si is predominantly present in crystalline form or bound with other elements as silicate minerals with low solubility and hence less accessible to the plants through the weathering of the minerals. The most common and widespread Si-fertilizers used are slags, i.e.
  • silicon fertilizers include potassium silicate, sodium silicate and calcium silicate.
  • alkaline media can increase the solubility of Si-rich silicate materials, however using such alkaline silicate solution has a drawback of high pH, which may be poisonous to the plants.
  • a high degree of dilution with water e.g. 1 : 100 may be required prior to fertilizing with an alkaline silicate solution, adding cost and
  • slag-based and mineral based Si-fertilizers are much higher than the required volume of traditional NPK-fertilizers.
  • Existing practice require two different fertilizing operations when applied by the farmers, and may require high volumes of Si-fertilizer (slag) and separate logistically arrangements as well, which impose both a practical and an economical problem to the farmers.
  • CN 1923766 discloses a NPK composite fertilizer including slag with calcium silicate. However, as stated above, fertilizing with silicate containing slags has some drawbacks.
  • RU 2223250 discloses a complete complex organomineral fertilizer consisting of organic fertilizer, mineral fertilizer NPK and natural zeolite-containing component.
  • prepared fertilizer provides plants with all nutrient substances, reduces soil acidity and provides it using by addition to wells without root burning and without deterioration of the yield quality.
  • the silicon is added as a natural zeolite-containing tripolite, which is a natural mineral, hence the solubility of silicon is low.
  • Si-fertilizer which adds Si in a soluble and plant- available form, preferably as monosilicic acid.
  • amorphous silica silicon dioxide, S1O2
  • microsilica amorphous silica
  • the solubility of Si from amorphous silica is much higher than from crystalline silica or Si-minerals. This means that the amount of Si-fertilizers in terms of kg/ha can be substantially reduced. In turn, this may open for making a combined product of Si and NPK-fertilizer.
  • the present invention combines a much more effective and more environmentally friendly Si-fertilizer with NPK fertilizer in one and the same product.
  • the present invention simplifies distribution and usage of Si- and NPK-fertilizers by the farmer.
  • the present invention provides a more cost effective and hence affordable NPK- Si-fertilizer for a wide range of agricultural products.
  • the Si fertilizer used in combination with a mineral NPK fertilizer, in the present invention is a humic substance based Si-fertilizer (hereafter also denoted Si-humate fertilizer) which has a high content of plant-available Si, which is long-time storage stable with respect to the contents of plant-available Si.
  • the Si-humate fertilizer is obtained by the reaction between humic substances and amorphous silica during an alkaline incubation process, and the product formed has a high content of plant- available Si in the form of a monosilicic acid-humate complex.
  • the product can be dried, still maintaining the high level of plant-available Si, which is also long time storage-stable.
  • the residues of the reaction between humic substances and amorphous silica which do not dissolve during the alkaline incubation process, provide long term positive effect on soil properties and cultivated plant production and quality.
  • Si-humate fertilizer having a high content of plant-available Si, the amount of Si-fertilizer (expressed in kg/ha; kilograms per hectare) can be significantly reduced compared with conventional Si-fertilizers.
  • the present invention relates to a combined organomineral NPK-Si-humate fertilizer comprising particulate mineral NPK fertilizer and a particulate humic substance based Si-fertilizer comprising monosilicic acid-humate complex. It has been demonstrated that the combined use of a humic substance based silicon fertilizer and a mineral NPK fertilizer has resulted in increased uptake of potassium and phosphorus by the plants. This increased uptake of potassium and phosphorus may result is a less rate of K and P in the NPK recipe, an advantage as suitable resources for potassium and phosphorus, (potash, apatite and/or other phosphate resources), are drastically declining in the world. Another advantage of less use of phosphorus is less spreading of heavy metals, which are commonly contaminating phosphate sources.
  • Results from such novel demonstration may play an important role of environmental impact, such as less soil degradation (increasing Corg (organic carbon) in soil vial additional plant root formation; improvement of soil pH, because equilibrium pH of microsilica is 7, while traditional NPK fertilizer is 4-5; optimize soil biota vial increasing population of Azotobacter microorganisms and micorrhiza, increasing soil adsorption capacity and reduction pollutants mobility), less euthrophia (nutrients leaching) and less use of nitrogen, of which a high portion is converted to NOx gases which may lead to global warming.
  • Another advantage identified by the present invention is reduction in use of pesticides.
  • the present combined organomineral NPK-Si-humate fertilizer improves plants ability to build water reservoirs in the plant and thereby is more resistant to drought periods (abiotic stress).
  • the present combined NPK-Si-humate fertilizer it is thus shown a novel rate of impact on uptake of P and K with impact for stimulating biomass growth.
  • the stimulation of the plant root system increased the plant adsorption for all elements, including K.
  • the increasing of the monosilicic acid concentration can transform plant unavailable P to plant available forms, which also improve cultivated plants P nutrition.
  • the present invention concerns a combined organomineral NPK-Si- humate fertilizer comprising at least one particulate mineral NPK fertilizer, which comprises at least one nutrient compound of nitrogen, phosphorous or potassium, and a particulate humic substance based silicon fertilizer comprising chelates of monosilicic acid-humate compounds.
  • the ratio of the at least one particulate mineral NPK fertilizer to the said particulate humic substance based silicon fertilizer is from 10:90 to 90: 10, based on the total dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium contained in the at least one NPK fertilizer, and the humic substance based silicon fertilizer.
  • N nitrogen
  • N0 3 nitrate
  • NH 4 + ammonium
  • the humic substance based silicon fertilizer is obtained by incubation of an aqueous suspension comprising 45-90 % by weight of a humic acid-containing raw material, 5-50 % by weight of amorphous silica, and 0.5-10 % by weight of an alkali, the amounts being based on the total weight of the dry components, followed by drying until a residual moisture of less than 15 % by weight.
  • the humic substance based silicon fertilizer comprises undissolved residues of the humic acid-containing raw material and undissolved residues of the amorphous silica.
  • the humic acid-containing raw material is selected from the group; coal, charcoal, brown coal, peat and humic soil, or a mixture of thereof.
  • the amorphous silica is selected from the group; microsilica, diatomaceous earth, rice husk ash and zeolites, or a mixture thereof.
  • the alk ali is chosen from the group; an alkali metal hydroxide, an alkaline earth metal hydroxide or a mixture thereof.
  • the ratio of the at least one particulate mineral NPK fertilizer to the said humic substance based silicon fertilizer is from 20:80 to 80:20, based on the total dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium contained in the at least one NPK fertilizer, and the humic substance based silicon fertilizer.
  • the at least one particulate mineral NPK fertilizer is in the form of a compound fertilizer containing nutrient compounds of N, P and K;
  • the at least one mineral NPK fertilizer is in the form of granules, prills, extrudates, pellets or agglomerates.
  • the content of nitrogen nutrient in the at least one NPK fertilizer is up to about 46 weight-% in terms of elemental N.
  • the content of phosphorous nutrient in the at least one NPK fertilizer is up to 55 weight-% in terms of P2O5.
  • the contents of potassium nutrient in the at least one NPK fertilizer is up to weight-62% in terms of K 2 0.
  • the NPK-Si-humate fertilizer product also comprises additional nutrients chosen from the group: calcium (Ca), sulphur (S) and magnesium (Mg), and/or micronutrients chosen from the group: zinc (Zn), copper (Cu), iron (Fe), boron (B) and molybdenum (Mo).
  • the organomineral NPK-Si-humate fertilizer is in the form of a physical mixture or blend of the at least one particulate mineral NPK fertilizer and the particulate humic substance based silicon fertilizer.
  • the organomineral NPK-Si- humate fertilizer is in the form of granules, prills, pellets, extrudates or agglomerates.
  • the present invention concerns a method for producing a combined organomineral NPK-Si-humate fertilizer according to the first aspect and any of the above first to seventeenth embodiments, comprising
  • NPK mineral fertilizer which comprises at least one nutrient compound of nitrogen, phosphorous or potassium
  • a particulate humic substance based silicon fertilizer which is obtainable by preparing an aqueous suspension comprising 45-90 % by weight of a humic acid- containing raw material, 5-50 % by weight of amorphous silica, and 0.5-10 % by weight of an alkali, the amounts being based on the total weight of the dry components, incubating the aqueous suspension, and thereafter drying the incubated suspension until a residual moisture of less than 15 % by weight, and
  • the at least one particulate mineral NPK fertilizer and particulate humic substance based silicon fertilizer are provided in a ratio such that the ratio of the at least one particulate NPK mineral fertilizer to the said particulate humic substance based silicon fertilizer is from 10:90 to 90: 10, based on the total dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium contained in the at least one NPK fertilizer, and the humic substance based silicon fertilizer.
  • the ratio of the at least one particulate mineral NPK fertilizer to the said particulate humic substance based silicon fertilizer is from 20:80 to 80:20, based on the total dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium contained in the at least one NPK fertilizer, and the humic substance based silicon fertilizer.
  • the humic acid-containing raw material is selected from coal, charcoal, brown coal, peat and humic soil, or a mixture of thereof.
  • the amorphous silica is selected from the group; microsilica, diatomaceous earth, rice husk ash and zeolites, or a mixture thereof.
  • the alkali is chosen among an alkali metal hydroxide, an alkaline earth metal hydroxide or a mixture thereof.
  • N nitrogen
  • N0 3 nitrate
  • NH 4 + ammonium
  • phosphorous (P) in the form of a phosphate (P0 4 3 ), hydrogen phosphate (HP0 4 2 ) and/or a dihydrogen phosphate (H 2 P0 4 ), and
  • potassium (c) potassium (K), in the form of a potassium salt (K + ).
  • K potassium (K)
  • the least one particulate mineral NPK fertilizer and the particulate humic substance based silicon fertilizer is mixed until a homogenous mixture is obtained.
  • the at least one mineral NPK fertilizer is in the form of granules, prills, extrudates, pellets or agglomerates.
  • the content of nitrogen nutrient in the at least one NPK fertilizer is up to about 46 weight-% in terms of elemental N.
  • the content of phosphorous nutrient in the at least one NPK fertilizer is up to 55 weight-% in terms of P 2 0 5.
  • the contents of potassium nutrient in the at least one NPK fertilizer is up to weight-62% in terms of K 2 0.
  • the NPK-Si-humate fertilizer product also comprises additional nutrients chosen from the group: calcium (Ca), sulphur (S) and magnesium (Mg), and/or micronutrients chosen from the group: zinc (Zn), copper (Cu), iron (Fe), boron (B) and molybdenum (Mo).
  • the present invention relates to the use of the combined organomineral NPK-Si-humate fertilizer according to the first aspect, and the first to the seventeenth embodiment of the invention according to the first aspect, for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil.
  • the present invention relates to the use of the combined organomineral NPK-Si-humate fertilizer according to the invention, for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil where the at least one particulate mineral NPK fertilizer, which comprises at least one nutrient compound of nitrogen,
  • particulate humic substance based silicon fertilizer comprising chelates of monosilicic acid-humate compounds, are applied as separate constituents.
  • the present invention relates to a method for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil, comprising applying a combined organomineral NPK-Si-humate fertilizer, according to the present invention.
  • the present invention relates to a method for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil, comprising applying a combined organomineral NPK-Si-humate fertilizer according to the present invention, where the at least one particulate mineral NPK fertilizer, which comprises at least one nutrient compound of nitrogen, phosphorous or potassium; and the particulate humic substance based silicon fertilizer, comprising chelates of monosilicic acid-humate compounds, are applied as separate constituents.
  • Figure 1 Test results showing increased uptake of P in corn roots with application of the combined organomineral fertilizer according to the present invention.
  • Figure 5 Test results showing increased uptake of K in corn roots with application of the combined organomineral fertilizer according to the present invention.
  • Figure 8 Test results showing increased uptake of K in sunflower shoots with application of the combined organomineral fertilizer according to the present invention.
  • Figure 11 Test results showing increased fresh biomass of sunflower roots with application of the combined organomineral fertilizer according to the present invention.
  • Figure 12 Test results showing increased fresh biomass of sunflower shoots with application of the combined organomineral fertilizer according to the present invention.
  • the present invention provides a combined organomineral NPK-Si-humate fertilizer comprising at least one particulate mineral NPK fertilizer and a particulate humic substance based silicon fertilizer comprising chelates of monosilicic acid-humate compounds, which alleviates at least some of the disadvantages connected with prior art silicon containing fertilizers.
  • plant-available Si and“bio-available Si” should be understood as denoting compounds of silicon which are in a transferable form to be taken up or absorbed by the roots of the plants, that is monosilicic acid, H 4 S1O 4 , commonly noted Si(OH) 4 , or possibly lower oligomers of monosilicic acid.
  • the plant-available Si in the present Si-humate fertilizer is believed to be formed by a complexing reaction between monosilicic acid and derivatives of humic acid dissolved as humates, thereby forming a water-soluble and storage stable monosilicic acid-humate chelate.
  • the chelates formed by complexing reactions prevent the monosilicic acid to polymerize into polysilicic acid, which is a bio-unavailable form of silicon.
  • the thus formed chelates (also denoted complex) are also water soluble, even after drying and longtime storage.
  • the term“storage-stable bio-available Si” in the present context it should be understood that the amount of bio-available Si in the Si-humate fertilizer part is maintained high compared with a freshly produced product, even after longtime storage.
  • longtime storage it should be noted that tests performed by the inventors using the Si-humate fertilizer, having been stored for one year, surprisingly gave approximately the same results, measured in crops yield and Si uptake, as a freshly produced product.
  • the Si-humate fertilizer may be prepared as described in the following:
  • the humic acid-containing raw material may be any humic substances.
  • the preferred humic acid-containing raw materials advantageously have a high content of humic acid.
  • Examples of such humic substances having a high content of humic acid are different types of coal, such as e.g. brown coal (lignite, leonardite), peat and humic soil.
  • the amount of humic acid-containing raw material should be from 45-95 % by weight, based on the total content of the dry materials. In an embodiment the amount of humic acid-containing raw material may be between 60-90 % by weight, e.g. 75-85 % by weight.
  • the amount of humic acid-containing raw material added in the mixture may rely on e.g. the content of humic acid in the raw material.
  • the humic acid-containing raw material should be grounded to a fine powder, particle of mm size, e.g. 0.1-3 mm, to increase the reaction kinetics.
  • the amorphous silica suitable for the method of production of the humic substance based Si-fertilizer, according to the present invention may be a low cost silica selected from the group; microsilica, diatomaceous earth, rice husk ash, perlite, zeolites and Ca- silicate minerals or a combination of these.
  • Amorphous silica is preferred silica source because it has a much higher solubility compared to crystalline forms of silica, which is already present in the soil.
  • the preferred amorphous silica are microsilica and rice husk ash because these have a high specific surface area which increases the dissolution rate of silica (provided it is available to the alkaline solution) to the desired monosilicic acid.
  • An amorphous silica suitable for the present invention should have a specific surface area about 5-50 m 2 /g (BET), and a particle size in the nano or micron area, e.g. 0.01-50 pm, preferably less than 5 pm.
  • the morphology and particle size distribution of the amorphous silica should be uniform, as this favors uniform dissolution of the particles in the alkali aqueous suspension.
  • Microsilica also known as silica fume
  • microsilica used in the specification and claims of this application refer to particulate, amorphous S1O2 which may be obtained from a process in which silica (quartz) is reduced to SiO-gas and the reduction product is oxidized in the vapor phase to form amorphous silica.
  • Microsilica may contain at least 70% by weight silica (S1O2), and preferably >95 % by weight Si0 2 , and has a specific gravity of 2.1 - 2.3g/cm 3 and a specific surface area of 5 - 50 m 2 /g (BET), typically 20m 2 /g.
  • the primary particles are substantially spherical and may have an average size of about 0.15 pm, as calculated by volume.
  • Microsilica is preferably obtained as a co-product in the production of silicon alloys in electric reduction furnaces, but may also be (co)-produced in other processes.
  • the amorphous silica is microsilica, it should however be noted that the amorphous silica may be other types, as stated above.
  • the amount of amorphous silica added to the mixture for preparing the Si-humate fertilizer is 5-50 % by weight. In an embodiment the amount of amorphous silica is between 10-30 % by weight, e.g. 15-25 % by weight.
  • the alkali should be a strong base such as alkali metal hydroxide, such as NaOH and KOH, an alkaline earth metal hydroxide, such as Ca(OH) 2 , or a mixture thereof
  • the alkali may be added to the mixture as a solid material.
  • the alkali neutralizes the humic acid in the humic acid containing raw material, thus bringing them to a water soluble form as humates.
  • the alkali also dissolves a significant amount of the amorphous silica.
  • the primary reaction product is monosilieic acid, Si(OH)4.
  • the amount of alkali added to the mixture is between 0.5-10 % by weight.
  • the amount of alkali added is less than the stoichiometric amount necessary to dissolve all silica and to convert all humic acid. However, the amount of alkali provides sufficient bio-available Si and humates for germination and initial growth period. The surplus amorphous silica will act as a slow release source, thus providing sufficient fertilizing in the later growth periods.
  • the initial pH in the suspension, before incubation, should be at least 9.5, and may be even as high as 13.
  • the amount of water in the aqueous suspension should be more than the necessary (stoichiometric) amount for the reactions, the maturation during incubation and the chelate formations.
  • the aqueous suspension should preferably have a water content such that the suspension is stirrable and preferably also flowable, to be transportable e.g. by pumping.
  • the amount of water may be 25-70 % by weight, based on the total weight of the suspension.
  • the dispersion should not contain too much water, as this will increase the energy demand for removing water in the drying step.
  • the water content is normally not more than about 50 % by weight, based on the total weight of suspension.
  • the water content is preferably from 25-40 % by weight, based on the total weight of the suspension.
  • any suitable mixer may be used for preparing the aqueous suspension, e.g. a dispersion mixer.
  • the humic acid containing raw material and the amorphous silica source are mixed before addition of water and the alkali.
  • This mixing sequence is however not mandatory as any mixing sequence may be used.
  • the thus obtained mixture should be thoroughly mixed into a homogenous suspension, thereby forming an alkaline suspension of dissolved and undissolved constituents.
  • the suspension is left for incubation for a time and a temperature, where the humic acid and the amorphous silica are partly dissolved, under the formation of humates and monosilicic acid.
  • the monosilicic acid is chelated by a complexing reaction with the water-soluble humates.
  • Monosilicic acid chemically bound as chelates with humates are prevented from polymerization into polysilicic acid.
  • the silicon is bound and remains in a bio- available form.
  • the incubation temperature is preferable between 20 to 70 °C.
  • the incubation time should be from 1 hour to several days. Incubation time at normal temperatures, i.e. ambient temperatures, is typically from 2 to 7 days. An incubation time between 3-5 days at normal (ambient) temperatures will typically be sufficient for leaching and complexing reactions.
  • the pH of the aqueous suspension will decrease from more than 9.5, or even higher, towards a neutral pH of about 6.5-7.
  • the incubation time may be reduced to a few hours, e.g. incubating at 50-60 °C for about 24 hours.
  • elevating incubation temperatures will reduce the incubation time.
  • Agitation and/or stirring of the suspension during incubation may also promote homogenization and solubilization of monosilicic acid and humic acids, and thus reduce the incubation time.
  • An optimized combination of agitation, temperature and alkaline may reduce incubation time to just about an hour. After incubation the suspension will typically have a pH of about 6.5-7.
  • the incubated suspension is typically dried by heating to a product temperature between 15 and 95 °C, to obtain a product having a residual moisture content of less than 15 % by weight.
  • the drying step may be performed in open air, or by use of any conventional drying equipment, possibly including heating means, to reduce the water content.
  • the drying time is depending on the air humidity and temperature.
  • a residual moisture content in the product of about 10 % are in most cases suitable, however it should be noted that the water content may deviate from this specific amount.
  • the product should not be completely dried, as such drying may transform the monosilicic acid chelates to silica, which is a bio-unavailable form of Si.
  • the dried product may be crushed and sieved as required, and/or granulated, to produce a product that is easy to handle and use, and compatible for mixing with a NPK fertilizer.
  • NPK NPK macronutrient fertilizers
  • NPK fertilizers are generally labeled with an NPK analysis, based on the relative content of the chemical elements N (nitrogen compounds), P (elemental or phosphorus compounds) and K (elemental or potassium compounds), and any other nutrients when present.
  • the content of the nutrients have traditionally been declared as N for nitrogen content; P 2 O 5 for phosphorous and K 2 0 for potassium, but it should be noted that the declaration of the nutrient can also be declared as content of element, and possibly other ways.
  • the NPK fertilizers according to the present invention may comprise the three major nutrients N, P and K; two major nutrients (binary fertilizer, NP, NK, PK); or only one of the major nutrient, also denoted straight or single nutrient fertilizers, including compounds of one of N, P and K. It should be understood that the N, P and K nutrients are present in the form of compounds in the fertilizer, as generally known in the art.
  • the NPK fertilizer according to the present invention thus contains at least one of the following nutrients:
  • NPK fertilizers suitable for the present invention may also comprise one or more secondary nutrients (Ca, S and Mg) and/or micro nutrients (Fe, Mn, Zn, B, Cu, Mo and Cl), as generally known in the field.
  • Fertilizers may contain fillers, and various fillers are available in the fertilizer industry.
  • the fillers are normally inactive, i.e. not a nutrient, but may improve soil properties,
  • the fillers often have a role for improving the stabilization of the fertilizer product during storage and handling (e.g. anticaking agents).
  • Good quality mineral NPK fertilizers consist almost entirely of the nutrient compounds, and only very small amounts of additives e.g. anticaking agents and filler.
  • a straight NPK fertilizer such as ammonium nitrate consists substantially of the ammonium and nitrate, which are the forms of nitrogen nutrient that are taken up by the plants.
  • straight P or K NPK fertilizer will substantially consist of the respective nutrient compositions. The same also applies for NPK fertilizers containing two of the major nutrients and NPK fertilizers comprising all three major fertilizers.
  • the relative amount of the NPK fertilizer portion is to be based on the sum of the nutrient compounds (i.e. any present nitrogen compounds, phosphorous compounds and potassium compounds in the at least one NPK fertilizer) and the Si-humate fertilizer portion.
  • the nutrient compounds i.e. any present nitrogen compounds, phosphorous compounds and potassium compounds in the at least one NPK fertilizer
  • the Si-humate fertilizer portion is not included in the dry weight basis.
  • NPK fertilizers may be produced as a compound fertilizer, where the ingredients are mixed before being formed into particles. Each particle contains N, P and K, ensuring a homogenous product.
  • the NPK fertilizers may also be produced as a blended fertilizer, which is a physical mixture of dry NPK fertilizer particles normally containing different nutrient compounds.
  • the process entails a physical blending of the ingredients in dry form.
  • the ingredients are in the form of separate particles, which may have different bulk density and particle sizes.
  • care must be taken such that segregation and caking of the fertilizer product is avoided.
  • the Si-humate fertilizer is one of the dry blending components thereby producing the inventive organomineral NPK-Si-humate fertilizer.
  • the combined organomineral NPK-Si-humate fertilizers according to present invention should have ratio of the mineral NPK fertilizer portion, i.e.
  • the at least one nutrient compound of nitrogen, phosphorous or potassium, to the Si-humate fertilizer portion from about 10:90 to 90: 10, based on the dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium, and the Si-humate fertilizer contained in the organomineral NPK-Si-humate fertilizer product.
  • the weight ratio of mineral NPK fertilizer to the Si- humate fertilizer is based on the sum of dry components of the at least one nutrient compounds of nitrogen, phosphorous or potassium in the mineral NPK fertilizer portion, and the Si-humate fertilizer portion contained in the combined NPK-Si-humate fertilizer product according to the present invention.
  • the organomineral NPK-Si-humate fertilizers may be produced in a wide variety of ranges, e.g. the ratio of the mineral NPK fertilizer components to the Si-humate fertilizer may be selected from the ranges; 20:80 to 80:20, from 30:70 to 70:30, from 40:60 to 60:40 or 50:50, based on dry weight of product. It should be noted that the NPK-Si-humate fertilizers according to the present invention may include compounds of all three major nutrients N, P and K; two of the major nutrients (NP, NK or PK), or only one of the major nutrients N, P and K.
  • the ratio between the portion of NPK mineral component to the portion of Si- humate fertilizer should be within the defined ranges; 10:90 to 90: 10, and subranges 20:80 to 80:20, from 30:70 to 70:30, from 40:60 to 60:40 or 50:50.
  • the amount of Si-humate fertilizer in the NPK-Si-humate fertilizer is more than about 90 % (based on dry weight of the product)
  • the amount of NPK nutrients in the fertilizer will in most cases become too low to cover the macronutrient requirement, resulting in reduced crop yield and reduced plant health.
  • a Si-humate fertilizer amount of less than about 10 % (based on dry weight of the product) will in most cases not cover the silicon nutrient demand of the plants, in addition the beneficial, synergistic effect of the combined NPK-Si-humate fertilizer, such as increased P uptake and increased biomass yield, becomes small.
  • Tests show that a ratio of mineral NPK fertiliser compounds to Si-humate fertilizer between 30:70 and 70:30 (based on dry weight of the product, as defined above) give very good results.
  • the addition of Si-humate fertilizer in combination with traditional NPK mineral fertilizer shows a synergistic effect, especially with respect to increased phosphorous uptake in plants and increased biomass, compared to tests where NPK fertilizer is applied alone (without Si-humate fertilizer).
  • the NPK-Si-humate fertilizer is preferably in the form of a blended fertilizer.
  • the blended NPK-Si-humate fertilizer may be a physical (mechanical) mixture of a compound NPK fertilizer and Si-humate fertilizer.
  • the blended NPK-Si-humate fertilizer may alternatively be a physical mixture of one, two or three single major NPK nutrients and Si-humate fertilizer, or the major NPK nutrients may be in the form of a NPK fertilizer containing two of the major nutrients (NK, NP or PK) mixed with Si- humate fertilizer.
  • the nutrients to be mixed should be in the form of separate, dry particles.
  • the Si-humate fertilizer should preferably be in the form of agglomerated particles or granulates so as to be compatible with the other ingredients in the blend.
  • the blended NPK-Si-humate fertilizer should have a particle size distribution and bulk density assuring a good quality fertilizer which is not prone to segregation of any of the nutrient particles during handling and application.
  • the product may also comprise one or more of secondary nutrients (Ca, S and Mg) and/or micro nutrients (Fe, Mn, Zn, B, Cu, Mo and Cl).
  • the present NPK-Si-humate fertilizer is used for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil.
  • the farmers fertilizing operations are simplified as the Si nutrient is distributed together with the NPK fertilizer in a combined product.
  • Some of the benefits with the fertilizer according to the present inventions are reduction of the volumes of fertilizers to be applied, and more simple logistically arrangements.
  • the combined NPK-Si-humate fertilizer according to the present invention may be applied as separate constituents, that is NPK fertilizer and Si-humate fertilizer are applied as separate constituents, but used in combination, according to the present invention.
  • Fresh plant tissue samples 0.20+0.01 g were cut into fragments about 1 - 2 cm in length and put into a plastic bottle. Then 50 mL of distilled water was added and the mixture was agitated for 24 h to provide diffusion of the apoplast solution into external solution. The mixture was filtrated and clean solution was analyzed for NO 3 by using compact NO 3 meter (Twin NO 3 Horiba, Japan). The samples of plant tissue after filtering were homogenized to crush all cell walls. Homogenized slurry was mixed with 50 mL of distilled water and agitated for 1 h. As a result, the diluted symplast solution was obtained and analyzed after centrifugation for monosilicic acid and soluble forms of NO 3 by the methods described above. Based on the data on plant tissue moisture, the contents of monosilicic acid and soluble forms of NO 3 were calculated on a dry weight.
  • BC and MS Brown coal (BC) and microsilica, 96-97 % S1O2 (MS) was weighted out in a weight ratio 5: 1, in total 60 kg.
  • the BC and MS was dry blended for 4 minutes. About 30 liters of water was added to the mixture of BC and MS, and the blending was continued. 0.6 kg KOH powder was added (1% by weight of dry mix), and the mixture was blended another 4 minutes.
  • the wet mixture (total weight about 90.6 kg) was retained in the mixer for 3 days at ambient temperature (20-25 °C) and blended 3-4 times every day, 4 minutes each time (incubation process). After 3 days incubation process, the mix was dried in open air for 2 days to about 10 % water content. The dried cake was put back into the mixer for de agglomeration. Tests using the NPK-Si-humate fertilizer according to the present invention
  • Si-humate fertilizer (Si-Agro A) used in the tests was 80 % brow coal, 19 % Microsilica, 1 % KOH, prepared by according to the method described in Example 1. The tests were executed as greenhouse tests. Calcareous soil with pH around 8.3 -8.5 was used, unless otherwise stated. In each test the fertilizers was applied by mixing the specified doses into the soil prior to adding seeds. Example 2. Uptake of phosphorous
  • the plant uptake of phosphorous (P) was measured.
  • the amount of P was measured on com (monocot) and sunflower (dicot), in the roots and in shoots (stem and leaves).
  • Each table include a control test showing the uptake after applying 0 wt%, 50 wt%, 70 wt% or 100 wt% of NPK.
  • 100 wt% NPK is equivalent to 300 kg/ha of NPK and 50 wt% is equivalent to 150 kg/ha of NPK.
  • the Si Agro A test shows the uptake of P in roots after applying 300 kg/ha of Si-Agro A and 0 wt%, 50 wt%, 70 wt% or 100 wt% of NPK.
  • 100 wt% and 50 wt % NPK is equivalent to 300 kg/ha and 150 kg/ha of NPK.
  • the numbers in the column“Increased P in wt%” shows the wt% increase in uptake of P in roots and shoots, respectively. The numbers are always compared to the results obtained with the Control when 0 % NPK is applied.
  • Si-Agro A 300 kg/ha
  • 0 % NPK gives a 129 wt% increase in P in the roots (Table 1). This is calculated from the measured mg P / kg of dry roots of 0.58 in the Control and 1.33 in the roots exposed to Si-Agro A
  • K potassium
  • NPK usage increased the K content of the corn with 91% in the roots and 95% in the shoots (stems and leaves).
  • Si- Agro A (300 kg/ha) product alone (without NPK) also lead to an increase of K uptake, but much less than the K uptake with NPK addition as the increase was only 27% or 26% in roots and shoots, respectively.
  • the uptake of K increased with 127% and 123% in roots and shoot, respectively. It is therefore less potential for replacement of NPK with Si-Agro A compared with the results obtained for phosphorous above.
  • Example for growth of sunflower gave similar result. By reducing the NPK with 50 % the root biomass was still 66% higher when applied with the Si-Agro A product compared with using normal rate of NPK alone, see table 12 and fig 11. For the stem and leaves the biomass was only slightly higher (10% more) for the 50% NPK reduction when replaced with the Si-Agro A product compared with normal rate of biomass, see table 13, and fig 12. Example 5. Uptake of nitrogen (N)
  • Nitrogen is vital because it is a major component of chlorophyll, the compound by which plants use sunlight energy to produce sugars from water and carbon dioxide (i.e. photosynthesis).
  • Nitrogen is a component in the energy-transfer compounds, such as ATP (adenosine triphosphate). ATP allows cells to conserve and use the energy released in metabolism. Finally, nitrogen is a significant component of nucleic acids such as DNA, the genetic material that allows cells (and eventually whole plants) to grow and reproduce.
  • Example 5 Test on production fields for paddy rice in Hunan, China.
  • Fertilizer was applied; Urea with 150 kg/ha N; Superphosphate with 135 kg P; and KC1 with l35kg/ha as K. This dosage referred to as 100% NPK usage. A 70% NPK dosage was also used. Both referred to as references.
  • Si-Agro A was applied in a separate field in combination with 70% NPK usage. Due to the prime target with heavy metal reduction in the rice for this particular test, 1000 kg Si-Agro A was used in order to react with and form immobile complex minerals of the heavy metal. Results in table under.
  • Table 16 Weight of rice grains, absolute crop yields (ton/ha) and relative crop yields (%).
  • the fertilizer according to the present invention was tested in full scale field trials in China by Hunan Institute of Economic Geography, using 3 different field locations (Xiangtan; Zhuzhou, Xiangyin). The field tests were executed during 2 nd season
  • NPK normal dosage of NPK
  • P (superphosphate) 135 kg P/ha
  • K (KC1) 135 kg K /ha) one day before seedling, and added with 30 kg N/ha one week after seedling.
  • the amount of Si- humate fertilizer was 1000 kg/ha.
  • the yield can be maintained at 10% above the level as using normal dosage of NPK.
  • One field even increased the yield with 36.7%.
  • a purpose for these field tests was to reduce uptake of heavy metal, especially

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Abstract

La présente invention concerne un engrais combiné organominéral NPK-Si-humate comprenant au moins un engrais NPK minéral particulaire, qui comprend au moins un composé nutritif azote, phosphore ou potassium; et un engrais au silicium à base de substance humique particulaire, comprenant des chélates de composés de type acide monosilicique-humate. L'invention concerne également un procédé de production dudit engrais combiné organominéral NPK-Si-humate.
PCT/NO2018/050283 2017-11-20 2018-11-20 Engrais au npk-si-humate, procédé de production et utilisation de ce dernier WO2019098854A1 (fr)

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RU2020120150A RU2741798C1 (ru) 2017-11-20 2018-11-20 Npk-si-гуматное удобрение, способ его получения и его применения
US16/759,946 US11254622B2 (en) 2017-11-20 2018-11-20 NPK-Si-humate fertilizer, method for production and use thereof
EP18857395.0A EP3713900B1 (fr) 2017-11-20 2018-11-20 Engrais au npk-si-humate, procédé de production et utilisation de ce dernier
BR112020006467-0A BR112020006467A2 (pt) 2017-11-20 2018-11-20 fertilizantes de npk-si-humato organomineral combinado, produto de fertilizante de npk-si-humato organomineral combinado, método para produzir um fertilizante de npk-si-humato organomineral combinado, métodos para suprir nutrientes e/ou condicionadores de solo para solo agrícola ou de estufa, e, uso do fertilizante de npk-si-humato organomineral
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