WO2019096961A1 - Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer - Google Patents
Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer Download PDFInfo
- Publication number
- WO2019096961A1 WO2019096961A1 PCT/EP2018/081476 EP2018081476W WO2019096961A1 WO 2019096961 A1 WO2019096961 A1 WO 2019096961A1 EP 2018081476 W EP2018081476 W EP 2018081476W WO 2019096961 A1 WO2019096961 A1 WO 2019096961A1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Definitions
- composition comprising a UV-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer
- the invention relates to a composition, especially a cosmetic composition and in particular a photoprotective composition, and to a process for treating keratin materials, in particular the skin and its integuments, using said composition.
- compositions have been proposed to date for protecting against the effects induced by UVA and/or UVB rays.
- These compositions generally contain organic or mineral screening agents, more particularly mixtures of organic liposoluble screening agents and/or water-soluble screening agents, combined with metal oxide pigments such as titanium dioxide or zinc oxide.
- organic screening agents can bring about degraded sensory properties, in particular more greasiness, more tack and/or more sheen.
- composition is considered to be stable when its macroscopic and microscopic appearances, its viscosity and its pH show little change, or even no change at all.
- the weight ratio of the sum of all the hydroxyethyl acrylate units to the sum of all the acrylate units bearing the group R1 ranges from 1 :30 to 1 :1 ,
- all the groups R1 are behenyl radicals.
- the 2-acrylamido-2-methylpropanesulfonic acid monomer according to the invention is partially or totally salified in the form of ammonium or sodium salt.
- styrene and derivatives thereof, such as 4-butylstyrene, a- methylstyrene and vinyltoluene;
- Y denotes an oxygen atom.
- the UV-screening agent(s) are present in the compositions according to the invention in an active material content ranging from 0.1 % to 60% by weight and in particular from 5% to 45% by weight, relative to the total weight of the composition.
- Benzophenone-1 sold under the trade name Uvinul 400 by BASF
- Benzophenone-2 sold under the trade name Uvinul D50 by BASF
- Benzophenone-3 or oxybenzone sold under the trade name Uvinul M40 by BASF
- the coated pigments are pigments that have undergone one or more surface treatments of chemical, electronic, mechanochemical and/or mechanical nature with compounds as described, for example, in Cosmetics & Toiletries, February 1990, Vol. 105, pages 53-64, such as amino acids, beeswax, fatty acids, fatty alcohols, anionic surfactants, lecithins, sodium, potassium, zinc, iron or aluminium salts of fatty acids, metal alkoxides (of titanium or aluminium), polyethylene, silicones, proteins (collagen, elastin), alkanolamines, silicon oxides, metal oxides or sodium hexametaphosphate.
- surface treatments of chemical, electronic, mechanochemical and/or mechanical nature with compounds as described, for example, in Cosmetics & Toiletries, February 1990, Vol. 105, pages 53-64 such as amino acids, beeswax, fatty acids, fatty alcohols, anionic surfactants, lecithins, sodium, potassium, zinc, iron or aluminium salts
- the coated iron oxide pigments are sold, for example, by the company Arnaud under the names Nanogard WCD 2008 (FE 45B FN), Nanogard WCD 2009 (FE 45B 556), Nanogard FE 45 BL 345 and Nanogard FE 45 BL or by the company BASF under the name Transparent Iron Oxide.
- composition according to the invention may also contain at least one polar organic solvent, which is preferably physiologically acceptable.
- polyol esters and pentaerythrityl esters for instance dipentaerythrityl tetrahydroxystearate/tetraisostearate
- This medium is adapted to the nature of the support onto which the composition is to be applied, and also to the form in which the composition is intended to be packaged.
- the composition is stable for 2 months at 4°C, 25°C and 45°C.
- composition according to the invention was compared with compositions comprising either another polymer (Example 6) or a surfactant system (Example 7).
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18800968.2A EP3710117B1 (en) | 2017-11-15 | 2018-11-15 | Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer |
| US16/763,629 US20200281829A1 (en) | 2017-11-15 | 2018-11-15 | Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer |
| CN202310600161.3A CN116650362A (zh) | 2017-11-15 | 2018-11-15 | 包含uv遮蔽剂、丙烯酸共聚物以及丙烯酰胺基甲基丙磺酸共聚物的组合物 |
| RU2020116462A RU2769315C2 (ru) | 2017-11-15 | 2018-11-15 | Композиция, содержащая уф-экранирующее, фильтрующее средство, акриловый сополимер и сополимер акриламидометилпропансульфокислоты |
| JP2020526179A JP7028971B2 (ja) | 2017-11-15 | 2018-11-15 | Uv遮蔽剤、アクリルコポリマー、及びアクリルアミドメチルプロパンスルホン酸コポリマーを含む組成物 |
| BR112020008448-4A BR112020008448B1 (pt) | 2017-11-15 | 2018-11-15 | Composição e processo não terapêutico para fotoproteção |
| ES18800968T ES3014880T3 (en) | 2017-11-15 | 2018-11-15 | Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer |
| CN201880073231.1A CN111356503A (zh) | 2017-11-15 | 2018-11-15 | 包含uv遮蔽剂、丙烯酸共聚物以及丙烯酰胺基甲基丙磺酸共聚物的组合物 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1760729A FR3073405B1 (fr) | 2017-11-15 | 2017-11-15 | Composition comprenant un filtre uv, un copolymere acrylique et un copolymere d’acide acrylamido methylpropane sulfonique |
| FR1760729 | 2017-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2019096961A1 true WO2019096961A1 (en) | 2019-05-23 |
Family
ID=60923726
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2018/081476 Ceased WO2019096961A1 (en) | 2017-11-15 | 2018-11-15 | Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20200281829A1 (https=) |
| EP (1) | EP3710117B1 (https=) |
| JP (1) | JP7028971B2 (https=) |
| CN (2) | CN116650362A (https=) |
| BR (1) | BR112020008448B1 (https=) |
| ES (1) | ES3014880T3 (https=) |
| FR (1) | FR3073405B1 (https=) |
| RU (1) | RU2769315C2 (https=) |
| WO (1) | WO2019096961A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025068356A1 (en) * | 2023-09-27 | 2025-04-03 | Clariant International Ltd | Use of a sulf-containing polymer for improving sun protection |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3073410B1 (fr) * | 2017-11-15 | 2019-10-11 | L'oreal | Emulsion comprenant un copolymere acrylique anionique et un polymere lipophile |
| US11291621B2 (en) * | 2019-10-04 | 2022-04-05 | Johnson & Johnson Consumer Inc. | Transparent sunscreen composition |
| WO2022020913A1 (en) * | 2020-07-31 | 2022-02-03 | L'oreal | Anhydrous cosmetic sunscreen composition, process of manufacturing the anhydrous cosmetic sunscreen composition and use of the anhydrous cosmetic sunscreen composition |
| FR3117799B1 (fr) * | 2020-12-18 | 2022-12-09 | Oreal | Composition comprenant des gélifiants aqueux, un tensioactif, des huiles, des charges et de l’acide ascorbique |
| US12589059B2 (en) | 2021-09-30 | 2026-03-31 | L'oreal | Mineral sunscreen compositions with high SPF and shelf stability |
| US20250235392A1 (en) * | 2021-12-17 | 2025-07-24 | L'oreal | Cosmetic or dermatological composition comprising a merocyanine and a gamma-butyrolactone and/or a gamma-butyrolactam |
| FR3130599B1 (fr) * | 2021-12-17 | 2025-02-14 | Oreal | Composition cosmétique ou dermatologique comprenant une mérocyanine et une gamma-butyrolactone et/ou un gamma-butyrolactame |
| FR3130596A1 (fr) * | 2021-12-17 | 2023-06-23 | L'oreal | Composition cosmétique et/ou dermatologique comprenant au moins une mérocyanine et au moins de l’acide ascorbique et/ou l’un de ses dérivés |
| FR3130594B1 (fr) * | 2021-12-17 | 2025-04-25 | Oreal | Composition cosmétique ou dermatologique comprenant une mérocyanine et du resvératrol et/ou un dérivé de resvératrol |
| FR3141059A1 (fr) * | 2022-10-20 | 2024-04-26 | L'oreal | Composition cosmétique ou dermatologique comprenant une mérocyanine et une gamma-butyrolactone et/ou un gamma-butyrolactame |
| FR3130605B1 (fr) | 2021-12-21 | 2023-11-24 | Oreal | Composition cosmétique comprenant un composé cellulosique particulaire, des particules d’aérogel de silice hydrophobe, et un polymère semi-cristallin |
| FR3130608B1 (fr) | 2021-12-21 | 2023-11-24 | Oreal | Composition cosmétique comprenant un composé cellulosique particulaire, des particules d’aérogel de silice hydrophobe, un polymère semi-cristallin et une cire d’origine végétale |
| WO2023141803A1 (en) * | 2022-01-26 | 2023-08-03 | L'oreal | Composition suitable for high content of oil |
| FR3143344A1 (fr) * | 2022-12-16 | 2024-06-21 | L'oreal | Composition comprenant un filtre UV, un polymère lipophile convenablement sélectionné, et un carraghénane |
| FR3149778A1 (fr) * | 2023-06-16 | 2024-12-20 | L'oreal | Composition comprenant au moins 1 % en poids d’acide ascorbique et un polymère lipophile convenablement sélectionné |
| FR3149786A1 (fr) | 2023-06-16 | 2024-12-20 | L'oreal | Composition comprenant un filtre UV, un polymère semi-cristallin contenant au moins une chaine d’alkyl acrylate et une gomme de scléroglucane |
| FR3149780A1 (fr) * | 2023-06-16 | 2024-12-20 | L'oreal | Composition comprenant au moins 1 % en poids d’acide ascorbique, un filtre UV organique hydrosoluble et des filtres UV addditionnels |
| FR3149779A1 (fr) * | 2023-06-16 | 2024-12-20 | L'oreal | Composition comprenant un filtre UV, au moins 1 % en poids d’acide ascorbique et une gomme de scléroglucane |
| FR3154543A1 (fr) | 2023-10-24 | 2025-04-25 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Procédé d’enrobage de particules à base d’un matériau de cathode |
| FR3156034A1 (fr) | 2023-12-01 | 2025-06-06 | L'oreal | Composition comprenant un filtre UV organique lipophile, un tensioactif géminé, un polymère semi-cristallin contenant au moins une chaine d’alkyl acrylate et un polyol |
| WO2025114438A1 (en) | 2023-12-01 | 2025-06-05 | L'oreal | Composition comprising a lipophilic organic uv-screening agent, a gemini surfactant and at least 8% by weight of a c1-c4 monoalcohol |
| FR3156037A1 (fr) | 2023-12-01 | 2025-06-06 | L'oreal | Composition comprenant un filtre UV organique lipophile, un tensioactif géminé et au moins 8 % en poids d’un mono-alcool en C1-C4 |
| FR3156035A1 (fr) | 2023-12-01 | 2025-06-06 | L'oreal | Composition comprenant un filtre UV organique lipophile, un tensioactif géminé et un tensioactif anionique dérivé d’un acide aminé |
| FR3160582B3 (fr) | 2024-03-29 | 2026-04-10 | Oreal | Compositions d’emulsion contenant de la bis-ethylhexyloxyphenol methoxyphenyl triazine et un polymere semi-cristallin |
| FR3160569B3 (fr) | 2024-03-29 | 2026-04-10 | Oreal | Compositions contenant de la bis-éthylhexyloxyphénol méthoxyphényl triazine, un polymère semi-cristallin et de la gomme de scléroglucane |
| WO2025137039A1 (en) | 2023-12-18 | 2025-06-26 | L'oreal | Stick compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine, lipophilic gelling agent, and a solvent system |
| WO2025133699A1 (en) | 2023-12-18 | 2025-06-26 | L'oreal | Compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine, semi-crystalline polymer and scleroglucan gum |
| WO2025137033A1 (en) | 2023-12-18 | 2025-06-26 | L'oreal | Emulsion compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine and semi-crystalline polymer |
| FR3160583B3 (fr) | 2024-03-29 | 2026-04-10 | Oreal | Compositions en baton contenant de la bis-ethylhexyloxyphenol methoxyphenyl triazine, un agent gelifiant lipophile, et un systeme de solvant |
| FR3157117A1 (fr) | 2023-12-22 | 2025-06-27 | L'oreal | Composition cosmétique de type émulsion huile-dans-eau à perception de poudré |
| FR3157118A1 (fr) | 2023-12-22 | 2025-06-27 | L'oreal | Composition cosmétique de type émulsion huile-dans-eau à perception de poudré |
| WO2025264300A1 (en) | 2024-06-18 | 2025-12-26 | L'oreal | Cosmetic compositions containg lauryl laurate and semicrystalline polymers |
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| WO2025068356A1 (en) * | 2023-09-27 | 2025-04-03 | Clariant International Ltd | Use of a sulf-containing polymer for improving sun protection |
Also Published As
| Publication number | Publication date |
|---|---|
| FR3073405B1 (fr) | 2020-06-19 |
| EP3710117B1 (en) | 2024-12-11 |
| RU2020116462A (ru) | 2021-12-15 |
| JP7028971B2 (ja) | 2022-03-02 |
| FR3073405A1 (fr) | 2019-05-17 |
| ES3014880T3 (en) | 2025-04-25 |
| CN116650362A (zh) | 2023-08-29 |
| CN111356503A (zh) | 2020-06-30 |
| JP2021502395A (ja) | 2021-01-28 |
| RU2020116462A3 (https=) | 2021-12-15 |
| RU2769315C2 (ru) | 2022-03-30 |
| US20200281829A1 (en) | 2020-09-10 |
| EP3710117C0 (en) | 2024-12-11 |
| EP3710117A1 (en) | 2020-09-23 |
| BR112020008448B1 (pt) | 2023-10-03 |
| BR112020008448A2 (pt) | 2020-10-20 |
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